CN101810187A - Pesticide combination containing thiamethoxam and pymetrozine - Google Patents
Pesticide combination containing thiamethoxam and pymetrozine Download PDFInfo
- Publication number
- CN101810187A CN101810187A CN201010138148A CN201010138148A CN101810187A CN 101810187 A CN101810187 A CN 101810187A CN 201010138148 A CN201010138148 A CN 201010138148A CN 201010138148 A CN201010138148 A CN 201010138148A CN 101810187 A CN101810187 A CN 101810187A
- Authority
- CN
- China
- Prior art keywords
- composition
- pesticide
- insect
- pymetrozine
- thiophene worm
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to the technical field of the pesticide, and relates to a pesticide combination containing thiamethoxam and pymetrozine, wherein the weight ratio of the thiamethoxam and pymetrozine is 9: 1 to 1: 9 and the pesticide combination can be made into different known preparations. By utilizing the synergic effect of the thiamethoxam and pymetrozine, the resistance of the injurious insects for organic nitrogen is overcome, and the prevention effect on the organic nitrogen-resistant insects such as rice planthopper and the like is remarkable.
Description
Technical field
The present invention relates to a kind of composition pesticide, particularly contain the composition pesticide of nicotinic insecticide thiophene worm piperazine and new type heterocycle class pyrrole aphid one pesticide.
Background technology
In agricultural production process, the problem that pest control is easy to generate most is the generation of pest resistance to insecticide.At present, cotton aphid, wheat aphid, vegetable aphid, rice hoppers have a strong impact on output and the quality of crop.Single agent effects such as common omethoate, Imidacloprid have not been very desirable, and dosage increases year by year, and environmental pollution is more and more serious.
Chinese patent application CN200710022838, the day for announcing is on June 11st, 2008, name is called and discloses organic nitrogen Mobucin and new type heterocycle class pyrrole aphid ketone mixed insecticide in " pyrrole aphid ketone and Mobucin mixed insecticide ", and wherein the weight ratio of organic nitrogen Mobucin and new type heterocycle class pyrrole aphid ketone is 1: 5 to 5: 1.This mixture utilizes the synergistic effect between pyrrole aphid ketone and Mobucin, remedies the deficiency of single agent agricultural chemicals, overcomes the pesticide resistance of insect, and rice fulgorid is had remarkable prevention effect.
Chinese patent application CN200810147174, the day for announcing is on March 11st, 2009, name is called in " a kind of desinsection Chemical composition that contains thiophene worm piperazine " and discloses thiophene worm piperazine and Avermectin mixed insecticide, wherein the percentage by weight of thiophene worm piperazine and Avermectin is 1～75: 10～0.1, is used to prevent and treat pest.
The inventor finds that the combination of nicotinic insecticide thiophene worm piperazine and new type heterocycle class pyrrole aphid ketone has synergy to insect, and particularly insect such as the rice fulgorid to the organic nitrogen resistance has synergy.
Summary of the invention
The object of the present invention is to provide a kind of composition pesticide that the organic nitrogen resistant insects is had good control efficiency.
Another purpose of the present invention is to provide a kind of method of pest control.
Technical scheme of the present invention is as described below:
A kind of composition pesticide comprises:
A) thiophene worm piperazine and
B) pyrrole aphid ketone,
Composition a) and composition b) weight ratio be 9: 1 to 1: 9.
Preferably, in the described composition pesticide composition a) and composition b) weight ratio be 9: 1 to 1: 1.
Further, above-mentioned composition pesticide also contains surfactant and the formulation auxiliary agents that is useful on agricultural chemicals except that active component.
Further, above-mentioned composition pesticide can be made into missible oil, wetting powder, granule, water dispersible granules, suspending agent or pulvis.
A kind of method of pest control, to insect or its location simultaneously or use a) thiophene worm piperazine and b in turn) pyrrole aphid ketone, composition a) and composition b) weight ratio be 9: 1 to 1: 9.
Further, described insect is the pest of Homoptera.
Preferably, described insect is a rice fulgorid.
In addition, can also use other agricultural chemicals to combine with above-mentioned active component, if its to composition a) and b) between interaction have no adverse effect.It is useful often for example to comprise extra insecticide or miticide, can widen sphere of action so that control the more insect of wide spectrum.
Said composition can also effectively overcome the susceptibility reduction of insect to any single component.
Composition of the present invention is effective to various pests, and particularly to the insect of organic nitrogen resistance, for example tea lesser leafhopper and rice fulgorid, Homoptera comprise aphid such as cotten aphid, tea aphid, rice leaf roller, and Lepidoptera comprises diamond-back moth, spodoptera etc.Thiophene worm piperazine is a kind of novel high-efficiency low-toxicity broad spectrum pesticide, it is second generation anabasine insecticide, the mechanism of action is similar to first generation anabasine insecticides such as Imidacloprids, but has higher activity, to insect have stomach toxicity, tag, systemic action, characteristics such as speed of action is fast, the lasting period is long, better to preventive effects such as sucking pest such as aphid, plant hopper, leafhopper, aleyrodids.And pyrrole aphid ketone is new type heterocycle class efficient selective insecticide, has that research report shows that it has efficiently, low toxicity, high selectivity, characteristics such as environmentally friendly, its mechanism of action uniqueness, adult is with after nymph contacts medicament, produce the lancet blocking effect, stop to get food and cause harm, hungry causing death.With two diverse medicaments of the mechanism of action with the proper proportion use that is mixed, can be from many aspects to the insect synergy, reach with the low dosage effective purpose that causes harm of Pest Control just.Dosage reduces simultaneously, has also alleviated the pressure of chemical pesticide to environment, can also delay the generation of pest resistance to insecticide.
The prevention and control field of composition of the present invention is included in plant protection, forestry protection.
Composition of the present invention can use in a variety of forms, and usually before use most convenient be mixed with aqueous solution form, a kind of preparation method of said composition is called as " bucket mix ", by the user each composition of commercial goods form is mixed in a certain amount of water.
Instant bucket mixes before for example using, the present composition can be mixed with independent formulation example such as mixture, and said preparation is water or the dilution of other thinners before use, except active component, above-mentioned composition can contain surfactant, and the example of described composition is as follows:
Composition of the present invention can missible oil, the conventional formulation form of wetting powder, granule or water dispersible granules is used.Composition of the present invention can be mixed with preparation in every way, and this depends on the Chemical Physics parameter of said composition.The example of possible suitable formulations is: missible oil (EC), wetting powder (WP), granule (GR), water dispersible granules (WDG), suspending agent (SC), pulvis (DP).
These special preparation types usually known and for example be described in: " Chinese agricultural chemicals Information Network " (the http://www.chinapesticide.gov.cn/service/zhcx/jxgg.html) of The Institute for the Control of Agrochemicals of the Ministry of Agriculture,PRC.
As a rule, need adding auxiliary agent such as surfactant, solvent, other additives also to be known and for example to be described in: the design of pesticide producing prescription, production technology and drug effect test stone application manual, the 9th piece of chapter 1 insecticides adjuvant.
Instant bucket mixes except for example mixture or before for example using, composition of the present invention can be mixed with composite preparation, dilute with water before use.Described composition also can contain surfactant except that active component, the example of described composition is as follows:
Missible oil is meant composition is dissolved in the organic solvent by a certain percentage as benzene,toluene,xylene, cyclohexanone, and add and prepare in the mixture of a certain amount of anion or nonionic surface active agent (emulsifier), the example of available emulsifier is: calcium dodecyl benzene sulfonate or nonionic emulsifier such as alkaryl polyglycol ether, expoxy propane, sorbitol fatty acid ester, alkyl, polyether.The oily liquids of a kind of homogeneous phase transparent that is mixed with, it with can form stable emulsion after water mixes.
Wetting powder be meant with composition by a certain percentage with the suitable surfactant and the mixture of inert substance (kaolin powder).Wetting powder is the preparation that can be dispersed in the water, wherein except active component and inert substance (kaolin powder), also contain a certain amount of anion or nonionic surface active agent (dispersant, moistening profit), for example alkylphenol-polyethenoxy base ether sulfonate, sodium lignin sulfonate, polyoxyethylene polyoxypropylene base ether block copolymers, neopelex, fatty alcohol.In order to be prepared into wetting powder, at conventional ultramicro grinding or comminution by gas stream, to make particle size reach requirement, and use double helical form mixer and colter formula mixer product to be mixed through repeatedly mixing.
Granule be meant with composition by a certain percentage with the mixture of suitable surfactant, thinner and inert substance (kaolin powder).By comminutor granulation fluidized bed prilling method for example, be that powder is kept under the flow regime, the spraying binder solution makes it the prilling process of aggegation.This method makes operations such as mixing, kneading, granulation, drying, classification all in a device, finishes in the following short time of air-tight state.
Water dispersible granules be meant with composition by a certain percentage with the suitable surfactant and the mixture of inert substance (kaolin powder).Through comminution by gas stream, make particle size reach requirement, and use double helical form mixer and colter formula mixer product to be mixed through repeatedly mixing.Again by conventional method such as fluidized bed prilling, mist projection granulating, disk granulation, see for example pesticide producing prescription design, production technology and drug effect test stone application manual for the preparation of fluidized bed prilling, disk granulation and mist projection granulating, method described in chapter 5 the 3rd saves 975 pages to 981 pages.
Suspending agent be meant with composition mixes with suitable surfactant, water or organic solvent by a certain percentage, evenly levigate through colloid mill, make to certain fineness for 1 to 2 time through the sand mill grinding again.The example of available emulsifier is: wetting agent has hydrocarbyl sulfonate, sulphate, dioctyl sodium sulfosuccinate and neopelex, dispersant has the formaldehyde condensation products of sodium lignin sulfonate or calcium, alkyl naphthalene sulfonate, and tackifier have xanthans, polyvinyl alcohol, heteroglycan.
Usually the plant protection products preparation contains 0.1-99 weight %, the particularly active component of 0.1-99 weight %.
In missible oil, active matter quality concentration is about 1-90 weight %, and the remainder of forming 100 weight % is made of the preparation composition of routine.In wetting powder, active matter quality concentration is about 5-90 weight %, preferred 10-80 weight %.In water dispersible granules active matter quality concentration is about 1-90 weight %, preferred 5-80 weight %.In suspending agent active matter quality concentration is about 2-90 weight %, preferred 5-80 weight %.
In addition, described formulations of active ingredients can contain tackifier, adhesive, wetting agent, dispersant, emulsifier, preservative, antifreezing agent, solvent, filler, colouring agent, defoamer and pH and the viscosity modifier of auxiliary agent as using in routine.
Pesticidal combination of the present invention can prepare by conventional method, for example by agitator, miniature high-speed clipper, small-sized grinder, blender each composition is mixed.
Can contain one or both active components of 0.0000001-98% weight, preferred 0.00001-90% weight, especially 0.0001-85% weight by the type of service of the present composition of commercialization formulation preparation.
Composition of the present invention is used with the usual manner that is fit to type of service, comprises effective amount of actives is administered to insect or its location.The consumption that the present composition needs is with differences such as external condition such as region, weather, soil, kinds, can in the tolerance, change, the active component of 0.0005-10.0 kilogram/hectare or higher consumption for example, but preferred 0.0001-5.0 kilogram/hectare, particularly 0.001-2.0 kilogram/hectare.
Therefore the present invention includes the method for pest control, insect especially wherein comprises and is selected from tea lesser leafhopper and rice fulgorid, and Homoptera comprises aphid such as cotten aphid, tea aphid, rice leaf roller, and Lepidoptera comprises diamond-back moth, spodoptera etc.
Be preferred on the economic crops crop of such as grain such as paddy rice, wheat, tea tree, fruit tree, soybean, rape, beet, tomato, other vegetables and cotton.
Embodiment
Embodiment 1
Rice fulgorid (Nilaparvata lugens) be adopt this field indoor with rice seedling raise many generations 3 age nymph be for experiment.
After taking by weighing the 99.7% former medicinal 0.5ml DMF dissolving of 0.0107g thiophene worm piperazine, add 0.2ml Tween80 emulsifier, stir, add the 99.3ml clear water, be made into the mother liquor of 100mg/L, get 8ml mother liquor adding 92ml again and contain in the water of 0.1%Tween 80 emulsifier, be mixed with the test liquid of 8mg/L, be diluted to 4,2,1,0.5 and 0.25mg/L with the water that contains 0.1%Tween 80 emulsifier by 2 multiple proportions examples again, totally 6 concentration are tested.
Take by weighing 0.0102g pyrrole aphid ketone 95% former medicine, after 0.7ml DMF dissolving, add 0.2ml Tween80 emulsifier, stir, add the 99.1ml clear water, be made into the mother liquor of 100mg/L, getting 20ml mother liquor adding 80ml again contains in the water of 0.1%Tween 80 emulsifier, be mixed with the test liquid of 20mg/L, be diluted to 10,5,2.5,1.25 and 0.625mg/L with the water that contains 0.1%Tween 80 emulsifier by 2 multiple proportions examples again, totally 6 concentration are tested.
Ratio according to thiophene worm piperazine and pyrrole aphid ketone 1: 1,3: 1,9: 1,1: 3 and 1: 9, measure 5,7.5,9,2.5 and the thiophene worm piperazine 100mg/L mother liquor of 1ml respectively, correspondingly again measure 5,2.5,1,7.5 and the pyrrole aphid ketone 100mg/L mother liquor of 9mL, the two mixes, supply add emulsifier water to 100ml, all be made into the test liquid of 10mg/L, be diluted to 5,2.5,1.25,0.625 and 0.3125mg/L with the water that contains 0.1%Tween 80 emulsifier by 2 multiple proportions examples respectively again, totally 6 concentration are tested (concrete concentration is seen attached list).
In the beaker that fills 0.2ml DMF, add 99.8mL and add the water of emulsifier as blank.
Test method:
Choose 15 strains of two leaves, one core rice seedling, dipping took out nature and dries after 30 seconds in molten for reagent, and encase root with wet absorbent cotton and preserve moisture, the outsourcing preservative film, (Φ 200 * 30mm), and every concentration repeats for 4 times to place teat glass.Insert with the slight rice fulgorid nymph in 3 age of anaesthetizing of ether with writing brush then, 15 ± 2 of every pipes, the mouth of pipe is tightened with white gauze.Dispose, place in the observation ward.
Data survey and statistical analysis:
Investigation method
Check examination worm death condition behind the 72h, the line item of going forward side by side, the examination worm is reactionless counts death to the dead criterion of examination worm in order to contact gently with tweezers.
The synergistic effect evaluation method
With reference to giving birth to the accurate method NY/T1154.7-2006 of mark, adopt Sun﹠amp; Johnson (1960) co-toxicity coefficient method (CTC) is obtained the co-toxicity coefficient (CTC) of the combination that respectively is mixed.Usually, co-toxicity coefficient less than 80 being antagonism, is summation action greater than 120 expression synergistic effects between 80～120.The co-toxicity coefficient computing formula is as follows:
Percentage composition+the medicament of A medicament in toxicity index * 100 mixtures of the theoretical toxicity index (TTI) of mixture=medicament A
The percentage composition of B medicament in the toxicity index of B * 100 mixtures
Data statistic analysis
All test datas all adopt SAS 6.12 statistical softwares to analyze.Calculate lethality (%) according to test data, obtain toxicity regression formula, correlation coefficient (r), LC50 and LC90 and 95% confidence limit thereof.
Evaluating drug effect
The toxicity test that the ratio of thiophene worm piperazine, pyrrole aphid ketone and the two 1: 1,3: 1,9: 1,1: 3 and 1: 9 is mixed to rice fulgorid the results are shown in Table 1.By table as seen, the result shows, thiophene worm piperazine and pyrrole aphid ketone are mixed with above-mentioned 5 ratios, all show as synergistic effect, its LC50 value is respectively 1.18,1.16,1.13,2.02 and 2.28mg/L, co-toxicity coefficient is respectively 181.63,151.38,142.53,136.11 and 140.45, and is wherein remarkable with 1: 1 synergistic effect.
Table 1 thiophene worm piperazine and pyrrole aphid ketone are mixed to the toxicity test result of rice fulgorid
| Reagent agent | The equation (Y=a+bx) of reaching the same goal | Correlation coefficient (r) | ??LC 50(95% confidence limit) (mg/L) | ??LC 90(95% confidence limit) (mg/L) | Co-toxicity coefficient (CTC) |
| Thiophene worm piperazine (T) | ??Y＝4.7764+2.024x | ??0.9849 | ??1.29(0.97～1.72) | ??5.54(3.57～8.61) | |
| Pyrrole aphid ketone (P) | ??Y＝2.9913+2.5072x | ??0.9974 | ??6.33(5.53～7.23) | ??20.53(16.34～25.79) | |
| ??T∶P(1∶1) | ??Y＝4.8171+2.5179x | ??0.9974 | ??1.18(1.04～1.35) | ??3.82(3.14～4.64) | ??181.63 |
| ??T∶P??(3∶1) | ??Y＝4.8648+2.1426x | ??0.9888 | ??1.16(0.88～1.52) | ??4.58(2.92～7.20) | ??151.38 |
| ??T∶P??(9∶1) | ??Y＝4.8767+2.2878x | ??0.9983 | ??1.13(1.02～1.26) | ??4.11(3.49～4.84) | ??142.53 |
| ??T∶P??(1∶3) | ??Y＝4.3236+2.2139x | ??0.9948 | ??2.02(1.67～2.44) | ??7.66(5.79～10.15) | ??136.11 |
| ??T∶P??(1∶9) | ??Y＝4.2048+2.2202x | ??0.9935 | ??2.28(185～2.81) | ??8.62(6.18～12.01) | ??140.45 |
As seen all observe synergy in all cases, the insect lethality in mixture is higher than more than 50% of single variety.
Claims (7)
1. composition pesticide that contains thiophene worm piperazine and pyrrole aphid ketone is characterized in that comprising:
A) thiophene worm piperazine and
B) pyrrole aphid ketone,
Composition a) and composition b) weight ratio be 9: 1 to 1: 9.
2. composition pesticide according to claim 1, it is characterized in that composition a) and composition b) weight ratio be 9: 1 to 1: 1.
3. composition pesticide according to claim 1 and 2 is characterized in that also containing the surfactant and the formulation auxiliary agents that are useful on agricultural chemicals.
4. composition pesticide according to claim 1 and 2 is characterized in that described composition pesticide can be made into missible oil, wetting powder, granule, water dispersible granules, suspending agent or pulvis.
5. the method for a pest control is characterized in that using to insect or its location and contains a) thiophene worm piperazine and b) composition of pyrrole aphid ketone, wherein composition a) and composition b) weight ratio be 9: 1 to 1: 9.
6. method according to claim 5 is characterized in that described insect is the pest of Homoptera.
7. method according to claim 6 is characterized in that described insect is a rice fulgorid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010138148.3A CN101810187B (en) | 2010-04-01 | 2010-04-01 | Pesticide combination containing thiamethoxam and pymetrozine |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010138148.3A CN101810187B (en) | 2010-04-01 | 2010-04-01 | Pesticide combination containing thiamethoxam and pymetrozine |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101810187A true CN101810187A (en) | 2010-08-25 |
| CN101810187B CN101810187B (en) | 2014-06-18 |
Family
ID=42617680
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201010138148.3A Active CN101810187B (en) | 2010-04-01 | 2010-04-01 | Pesticide combination containing thiamethoxam and pymetrozine |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101810187B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103329925A (en) * | 2013-07-12 | 2013-10-02 | 安徽美兰农业发展股份有限公司 | Water dispersible granule of thiamethoxam and pymetrozine composite pesticide and preparation method thereof |
| CN103355301A (en) * | 2012-03-31 | 2013-10-23 | 陕西韦尔奇作物保护有限公司 | Pesticide composition containing pyridalyl |
| CN111374136A (en) * | 2020-03-28 | 2020-07-07 | 山东省绿士农药有限公司 | Composition of pymetrozine and thiamethoxam and preparation method and application thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101194617A (en) * | 2007-05-24 | 2008-06-11 | 江苏丘陵地区镇江农业科学研究所 | Mixed insecticide of pymetrozine and mobucin |
| CN101352169A (en) * | 2008-09-12 | 2009-01-28 | 陈章艳 | Pesticide composition based on ivermectin |
| CN101380019A (en) * | 2008-08-22 | 2009-03-11 | 张少武 | Insecticidal composition containing thiamethoxam |
| CN101569312A (en) * | 2009-06-05 | 2009-11-04 | 贵州大学 | Pesticide compound containing pymetrozine and thiamethoxam, preparation method and application thereof |
| CN102105060A (en) * | 2008-06-05 | 2011-06-22 | 巴斯夫欧洲公司 | Synergistic fungicidal mixtures |
-
2010
- 2010-04-01 CN CN201010138148.3A patent/CN101810187B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101194617A (en) * | 2007-05-24 | 2008-06-11 | 江苏丘陵地区镇江农业科学研究所 | Mixed insecticide of pymetrozine and mobucin |
| CN102105060A (en) * | 2008-06-05 | 2011-06-22 | 巴斯夫欧洲公司 | Synergistic fungicidal mixtures |
| CN101380019A (en) * | 2008-08-22 | 2009-03-11 | 张少武 | Insecticidal composition containing thiamethoxam |
| CN101352169A (en) * | 2008-09-12 | 2009-01-28 | 陈章艳 | Pesticide composition based on ivermectin |
| CN101569312A (en) * | 2009-06-05 | 2009-11-04 | 贵州大学 | Pesticide compound containing pymetrozine and thiamethoxam, preparation method and application thereof |
Non-Patent Citations (1)
| Title |
|---|
| 刘步林: "粒剂,水分散粒剂，乳油", 《农药剂型加工技术》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103355301A (en) * | 2012-03-31 | 2013-10-23 | 陕西韦尔奇作物保护有限公司 | Pesticide composition containing pyridalyl |
| CN103355301B (en) * | 2012-03-31 | 2017-03-29 | 陕西韦尔奇作物保护有限公司 | A kind of composition pesticide containing pyridalyl |
| CN103329925A (en) * | 2013-07-12 | 2013-10-02 | 安徽美兰农业发展股份有限公司 | Water dispersible granule of thiamethoxam and pymetrozine composite pesticide and preparation method thereof |
| CN103329925B (en) * | 2013-07-12 | 2014-07-09 | 安徽美兰农业发展股份有限公司 | Water dispersible granule of thiamethoxam and pymetrozine composite pesticide and preparation method thereof |
| CN111374136A (en) * | 2020-03-28 | 2020-07-07 | 山东省绿士农药有限公司 | Composition of pymetrozine and thiamethoxam and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101810187B (en) | 2014-06-18 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101632385A (en) | Insecticidal composition containing pymetrozine | |
| CN101796957A (en) | Pyriproxyfen compound pesticide | |
| CN101632364A (en) | Sterilization composition | |
| CN105532713A (en) | Insecticidal composition comprising afidopyropen and flonicamid | |
| CN101810187B (en) | Pesticide combination containing thiamethoxam and pymetrozine | |
| CN104082335A (en) | Insecticide and acaricide composition having synergism | |
| CN105052984A (en) | Insecticidal composition for rice | |
| CN102150668A (en) | Herbicide composition, preparation and application thereof | |
| CN103609573A (en) | Insecticidal composition containing spinetoram and spirotetramat | |
| CN101617676B (en) | Pesticide compound | |
| CN103947655A (en) | Insecticidal composition containing ivermectin and spirodiclofen | |
| CN101700034B (en) | Pesticide composition | |
| CN101731249A (en) | Pesticide composition | |
| CN103229775A (en) | Pesticide mainly used for crops | |
| JP2001278721A (en) | Azadirachtin-containing insecticidal formulation with storage stability | |
| CN101669497A (en) | Mite-killing combination | |
| CN104012564A (en) | A pesticide composition used for weed control in corn fields | |
| CN100594789C (en) | Mix pesticide preparation of tubatoxin and antibiotic insecticide | |
| CN101790989A (en) | Pesticide composite containing thiamethoxam and indoxacarb | |
| CN103688979A (en) | Pesticidal composition containing thiamethoxam and spirotetramat | |
| CN103229781A (en) | Pesticide composition | |
| CN104814031A (en) | Insecticidal composition containing butene-fipronil and clothianidin | |
| CN101632375A (en) | Pyricularia amide compound sterilization composition | |
| CN105104390B (en) | Anti-mite composition containing cycloxaprid and spirodiclofen | |
| CN101263824A (en) | Insecticidal composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| ASS | Succession or assignment of patent right |
Owner name: SHANGHAI YUELIAN BIOTECHNOLOGY CO., LTD. Effective date: 20140423 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| C53 | Correction of patent of invention or patent application | ||
| CB03 | Change of inventor or designer information |
Inventor after: Lin Qiwen Inventor after: Yu Xiangfa Inventor after: Yu Demian Inventor before: Lin Qiwen Inventor before: Yu Xiangfa |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: LIN QIWEN YU XIANGFA TO: LIN QIWEN YU XIANGFA YU DEMIAN |
|
| TA01 | Transfer of patent application right |
Effective date of registration: 20140423 Address after: 201406, 169, Xing Xing Road, Shanghai, Fengxian District Applicant after: Shanghai Yuelian Chemical Co.,Ltd. Applicant after: Shanghai Yuelian Biological Technology Co., Ltd. Address before: 201406, 169, Xing Xing Road, Shanghai, Fengxian District Applicant before: Shanghai Yuelian Chemical Co.,Ltd. |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |