CN101809098B - Method and device for determining blend of paints for forming multicolor pattern harmonious with surrounding colors - Google Patents
Method and device for determining blend of paints for forming multicolor pattern harmonious with surrounding colors Download PDFInfo
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- CN101809098B CN101809098B CN2008801094422A CN200880109442A CN101809098B CN 101809098 B CN101809098 B CN 101809098B CN 2008801094422 A CN2008801094422 A CN 2008801094422A CN 200880109442 A CN200880109442 A CN 200880109442A CN 101809098 B CN101809098 B CN 101809098B
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- colored particles
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- tristimulus values
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/29—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for multicolour effects
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/80—Processes for incorporating ingredients
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Abstract
A paint for forming a multicolor pattern comprises a component for forming a transparent coating and three kinds of coloring particles. A method for determining a blend of paints for forming a multicolor pattern comprises a step (S4) of determining tristimulus values of target colors including the surrounding color and a color similar to the surrounding color, a step (S5) of selecting one of the target colors, a step (S6) of selecting three kinds of coloring particles from a database where information specifying coloring particles and tristimulus values associated with the information are recorded, and a step (S7) of determining the blending quantities of the coloring particles by solving simultaneous equations whose constants are tristimulus values of the target color, whose coefficients are the tristimulus values of the selected three kinds of coloring particles, and whose variables are the blending quantities of the selected three kinds of coloring particles.
Description
Technical field
The present invention relates to so to confirm that multicolor patterns forms the method and apparatus of the coating composition prescription of usefulness, the ambient color that makes the multicolor patterns that forms through applying coatings compsn on object film with multicolor patterns is in harmonious proportion.More specifically, the present invention relates to confirm to form the type of colored particles to be mixed in the coating composition of usefulness and the method and apparatus of quantity at multicolor patterns according to ambient color.
Background technology
In some cases, characteristic for the inner wall surface that makes buildings and outer wall surface etc., given the multicolor patterns design to above-mentioned wall.In order to give object with the multicolor patterns design, apply the coating composition that multicolor patterns forms usefulness, film on the surface of object, to form multicolor patterns.When give multicolor patterns when design to wall, not in many cases fully but partly give multicolor patterns to wall.Under these circumstances, the part that gives multicolor patterns being in harmonious proportion with ambient color is important.It is a kind of method that is used for so designing multicolor patterns that the conduct of mentioning is used to make the multicolor patterns method that is in harmonious proportion with ambient color of filming; Make that the color and the ambient color of multicolor patterns are close when when the distance of the fine pattern that can not distinguish multicolor patterns is observed.
In order to carry out this method, for example, a plurality of application samples that the multicolor patterns that will have a different ingredients forms the coating composition of usefulness are used for the actual part that will give the multicolor patterns design.Then, the color and the ambient color of each sample are relatively checked, selected to form the compsn that any one multicolor patterns is used in a plurality of prescriptions that will apply thus.Perhaps, each color card through relatively will be corresponding with ambient color and multicolor patterns above-mentioned a plurality of application samples of forming the coating composition of usefulness are checked.When the application sample that uses multicolor patterns to form the coating composition of usefulness confirms that reality has applied the pattern of part of pattern, be difficult to imagine that based on relative smaller applications sample in fact selected coating composition is coated to the situation in big zone.Thereby, there is the possibility that in fact forms with the inconsistent multicolor patterns of ambient color.In addition, have less colour-change, therefore, in some cases, can not select the application sample that is in harmonious proportion with ambient color because multicolor patterns forms the application sample of the coating composition of usefulness.
Patent file 1 discloses and a kind ofly has been used in a short period of time easily confirming that multicolor patterns forms the method for raw material coating composition (being also referred to as hereinafter, " polychrome coating ") of the coating composition of usefulness.More specifically, in patent file 1, prepare the picture that multicolor patterns is filmed; Resolve the kind of the color that forms picture; The area ratio of the color that confirm to form the picture that the multicolor patterns of being resolved films and every kind of color of occupying the image that multicolor patterns films; And confirm the formula rate of colored coating composition particle according to result's area ratio.
Patent file 1: the 9-220508 patented claim of japanese unexamined is open
Summary of the invention
The problem that the present invention will solve
But up to now, people also do not know to be used for confirming to form the technology that the multicolor patterns of filming with the multicolor patterns of ambient color mediation forms the coating composition prescription of usefulness.
For example, patent file 1 only discloses and has been used for the method that definite multicolor patterns that can form multicolor patterns according to the picture that multicolor patterns is filmed forms the coating composition prescription of usefulness.Patent file 1 both do not had open do not show that multicolor patterns is filmed yet and ambient color between mediation.
The present invention aims to provide definite method and the definite device that multicolor patterns forms the coating composition of usefulness; When will comprise polychrome applying coating that transparent coating forms composition and unsetting colored particles to coloured base material when forming multicolor patterns and film, said method and said device can be confirmed and the film polychrome formulation for coating material of formation usefulness of the multicolor patterns of the visual properties mediation of said ambient color and coloured base material.
The mode of dealing with problems
In the present invention; Confirm that so multicolor patterns forms the said prescription of the colored particles that comprises in the coating composition of usefulness; Make and provide this impression; Promptly when from distance (for example, about 5 meters to the 10 meters) visible observation of the fine pattern that can not distinguish said multicolor patterns, the color that the said multicolor patterns that on the base material with color identical or close with ambient color, forms is filmed is identical with said ambient color or close.
More specifically; The coating composition determination of formula method that multicolor patterns of the present invention forms usefulness refers to the method that so definite said multicolor patterns forms the coating composition prescription of usefulness; Make and to form the ambient color mediation of multicolor patterns that the coating composition of usefulness forms and this multicolor patterns through apply said multicolor patterns to coloured base material; The said coating composition that multicolor patterns forms usefulness comprises transparent coating and forms composition and three kinds of colored particles, and said method comprises: confirm tristimulus values or the tristimulus values close with these tristimulus values of the said ambient color first step as the tristimulus values of aim colour; Specify each second step of color of said three kinds of colored particles; Separate as each the third step of formula ratio in said three kinds of colored particles with three of definite simultaneous equation; In said simultaneous equation; The tristimulus values of said aim colour are defined as constant; The tristimulus values of said three kinds of colored particles are defined as coefficient, and the formula ratio of said colored particles is defined as variable.
Said first step confirms that the tristimulus values color identical or close with the tristimulus values of said ambient color is as a plurality of said aim colours; Said second step is associated with each other with as selecting three kinds of colored particles the set of element from the said tristimulus values of the information that will specify colored particles and said colored particles, and uses selected three kinds of colored particles to gather as colored particles; Before said third step, further comprise the 4th step of from a plurality of aim colours, selecting an aim colour; With the tristimulus values of said three kinds of colored particles of using the said colored particles set of said aim colour of in said the 4th step, selecting and the formation of in said second step, from said set, selecting, can carry out said third step.
In addition, said third step can comprise said three the 5th steps that whether comprise negative value in separating of judging said simultaneous equation; Separate six step of eliminating outside determined formula ratio with said three when in said three are separated, comprising negative value.
In addition, said third step can comprise judgement through with between said three colors of separating the tristimulus values representative that obtains in the said simultaneous equation of substitution of said simultaneous equation and the said ambient color at L
*a
*b
*Whether the aberration in the space is in the 7th step more than 5; With with said three separate eliminating eight step determined formula ratio outside 5 when above when said aberration.
In addition, said third step can comprise that said three when the said simultaneous equation of representing with per-cent are separated nine step of eliminating outside determined formula ratio with said three when comprising separating more than 90% in separating.
In addition, said third step can comprise that said three when the said simultaneous equation of representing with per-cent are separated ten step of eliminating outside determined formula ratio with said three when comprising separating below 5% in separating.
In addition, may further include definite L
*a
*b
*Be that color below 10 is as the 11 step of the color of said base material with the aberration of said ambient color in the color space.
In addition, may further include and repeat said first step is confirmed a colored particles set to said the 4th step, from the said colored particles set of having confirmed said formula ratio and the additive mixture of colors confirming to obtain with tristimulus values through using the said three kinds of colored particles that form said colored particles set with three corresponding formula ratios of said three kinds of colored particles is identical perhaps close color the 12 step as the color of said base material.
Provide a kind of multicolor patterns of the present invention to form the coating composition determination of formula device of usefulness; Said device comprises recording unit and treatment unit; And confirm that so said multicolor patterns forms the coating composition prescription of usefulness, make to form the ambient color mediation of multicolor patterns that the coating composition of usefulness forms and this multicolor patterns through on coloured base material, applying said multicolor patterns; The coating composition that said multicolor patterns forms usefulness comprises transparent coating formation composition and three kinds of colored particles; Said treatment unit has the tristimulus values of confirming said ambient color and tristimulus values close with this tristimulus value first function as the tristimulus values of a plurality of said aim colours; Be associated with each other and be recorded in and select second function of three kinds of color particles in the DB the said recording unit from the tristimulus values of the information of specifying said colored particles and said colored particles as the target colored particles; From a plurality of said aim colour that said first function is confirmed, select the 3rd function of an aim colour; With find the solution simultaneous equation, confirm that resulting separating is recorded in the 4th function that simultaneously said formula ratio is associated with the information of specifying said target colored particles in the said recording unit as the formula ratio of said target colored particles with said formula ratio; In said simultaneous equation; The tristimulus values of selected aim colour are defined as constant; The tristimulus values of three kinds of said target colored particles are defined as coefficient, and the formula ratio of said three kinds of said target colored particles is defined as variable.
The effect of invention
The present invention can be accurately and is confirmed that effectively the film said multicolor patterns that forms usefulness of the multicolor patterns that is in harmonious proportion with said ambient color forms the coating composition prescription of usefulness and the color of said base material.
Description of drawings
Fig. 1 is an explanatory view, shows to make to be used for carrying out according to an embodiment of the invention to confirm that the film multicolor patterns that forms usefulness of the multicolor patterns that is in harmonious proportion with ambient color forms the system configuration of method of the coating composition prescription of usefulness;
Fig. 2 is plan view and viewgraph of cross-section, and the conceptive multicolor patterns that shows of each view is filmed;
Fig. 3 is a schema, shows the coating composition determination of formula method that forms usefulness according to the multicolor patterns of an embodiment of the invention;
Fig. 4 is the photo of the multicolor patterns of reality.
Label declaration
101. treatment facility
102. image display
103. metering facility
104. object to be measured
Embodiment
To illustrate and describe embodiment of the present invention hereinafter.
Fig. 1 shows to be used for carrying out according to making of an embodiment of the invention and confirms that the film multicolor patterns that forms usefulness of the multicolor patterns that is in harmonious proportion with ambient color forms the view of computer system configurations of method of the coating composition prescription of usefulness.System comprises: treatment facility 101, and it has operating gear; Image display 102 (hereinafter, being called " display equipment "), it is connected to treatment facility 101 and can shows full-color image; With metering facility 103, it is obtained about the colouring information of the object 104 that has been given multicolor patterns and through given interface and sends information to treatment facility 101.
At first, form the coating composition of usefulness with describing the film multicolor patterns that forms usefulness of multicolor patterns.The coating composition that multicolor patterns forms usefulness comprises the carrier components that forms transparent coating and small atypic colored particles.Can the average particle diameter of colored particles suitably be confirmed in the scope from 0.1mm to 5mm, and the distribution of the particle dia of colored particles approaches lognormal distribution.When applying the coating composition of multicolor patterns formation usefulness, the colored particles of same color contacts and is overlapping, forms the continuous unsetting zone (spot) of same color thus.Colored particles through with different colours mixes, and can produce to form the coating composition that multiple multicolor patterns is filmed.
Here, the color of colored particles is confirmed by the kind and the quantity of the coloured material that comprises in the colored particles.The ratio of the carrier components of all coloring particle is subject to storage property, the workability when formation is filmed and the aspects such as performance of filming of coating composition.Form in the coating composition of usefulness at multicolor patterns, the stable angle the when design of filming from multicolor patterns to be formed usually perhaps forms multicolor patterns is used a kind of to three kinds of colored particles.In the present invention, describe, use three kinds of colored particles like the back.
Usually forming multicolor patterns through the coating composition that on coloured base material, applies multicolor patterns formation usefulness films.The color of base material is to confirm according to the design that multicolor patterns is filmed.Usually, make when multicolor patterns forms the hiding fully base material of the coating composition of usefulness, also can not experience inconsistent sensation even the color of base material confirmed as.
Fig. 2 is the conceptive view that the target coating state is shown.The left side of Fig. 2 is a plan view, among the figure, (A) expression base material, (B) expression use have formula ratio that the method described by the back confirms, multicolor patterns forms the multicolor patterns that the coating composition of usefulness forms.Fig. 2 (C) is a viewgraph of cross-section, and among the figure, the superiors are that multicolor patterns is filmed, and the multicolor patterns following layer of filming is undercoat and base material.Every kind of colored particles of little pattern representative in the superiors, the space between the colored particles is tackiness agent (carrier).
Next, with describing the coating composition determination of formula method that forms usefulness according to the multicolor patterns of an embodiment of the invention in detail.Fig. 3 is a schema, has described and has used the system shown in Fig. 1 to confirm that multicolor patterns forms the method for the coating composition prescription of usefulness.In the following description; The processing of being carried out by treatment facility 101 in response to operator's (planner or the like) operation is this processing, and in processing, the internal arithmetic element (hereinafter; Be called " CPU ") read to given data in the recording unit (hard disk drive or the like) internally; Output to inner temporary storing device (hereinafter, being called " storer "), and storer is as the WS.CPU is recorded in result in the recording unit according to circumstances.
In the inner recording unit of treatment facility 101, with the information (color name, code etc.) of specifying colored particles with as associated with each other about the tristimulus values of the colouring information of colored particles and be stored in the DB.Tristimulus values are a kind of psychophysical quantities, and it is expressed as the numerical value with the sensation form that is fit to the people with color.Specifically, can be XYZ value, L
*a
*b
*Value, rgb value or the like.The several different methods that has the tristimulus values of the color be used to obtain colored particles.The spectral reflectivity or the tristimulus values that for example, can obtain according to the color of the colored particles through measuring actual use obtain the tristimulus values in the desired color space.Perhaps, can carry out known CCM (computer color coupling) through the prescription of coloured material (coloured pigment, dyestuff or the like) to be mixed in the colored particles of using according to reality and calculate tristimulus values.
In step S1,, confirm the tristimulus values of ambient color to be in harmonious proportion then or be used to obtain the used data of tristimulus values by viewer's operational measure equipment 103.Measured data are sent to treatment facility 101 and are recorded in the recording unit.Color space is not limited, and can use three valuess that can color be shown as the numerical value with cross correlation.The several different methods that exists the adquisitiones of the tristimulus values of ambient color to use, and for example can be the method that describes below.
When multicolor patterns partly being coated to wall surface etc., the color of peripheral wall surface is served as the ambient color that multicolor patterns is filmed.Thereby, can directly measure the color of peripheral wall surface.The color measuring method is not limited to.Can use normally used colourimeter, spectrocolorimeter and spectrophotometer.When using nitometer, treatment facility 101 is obtained spectral reflectance factor as the data through measuring, and can obtain above mentioned tristimulus values through calculating.When direct tristimulus values reader is used as colourimeter, can be with actual measured value as tristimulus values.Perhaps, when use can not directly obtain the colourimeter of the tristimulus values in the color space in hope, treatment facility 101 used known function to convert the tristimulus values that in the color space, obtained in the desirable color space tristimulus values.
When can not directly measure the part that applied multicolor patterns around color the time, use nitometer can obtain the tristimulus values of ambient color.Perhaps, use pick up camera to carry out and applied multicolor patterns imaging on every side partly, treatment facility 101 can obtain tristimulus values from the view data that obtains through imaging then.
Hereinafter, suppose that treatment facility 101 is from direct sRGB (standard RGB) value (Rt, Gt, Bt) of measuring or calculating ambient color of the data that transmitted.
In step S2, treatment facility 101 confirms that the multicolor patterns that is in harmonious proportion with ambient color will form the color of base material above that.The color of base material is according to the tristimulus values of the ambient color of in step S1, confirming and definite.For the method for confirming the color of base material from the tristimulus values of ambient color, the several different methods that exists as describe at the back.Here, in order to simplify description, suppose to have the color (Rt, Gt, Bt) of the tristimulus values identical and select color as base material with the tristimulus values of ambient color.
Under situation about the color of base material being applied, when having confirmed tristimulus values, can confirm to form the coating composition that base material is used by known method through the colored coating coating composition.For example, be provided with determined tristimulus values as target after, through carrying out the prescription that known CCM can confirm coating composition.
In step S3, operator's operation processing equipment 101 is to specify the possible colored particles (at least three kinds) in the coating composition of multicolor patterns formation usefulness to be mixed from the DB of recording unit.Here, supposed to specify the N kind colored particles that has from 1 to N Code Number.
In step S4; Treatment facility 101 obtain with step S1 in the close tristimulus values (Rs, Gs, Bs) of tristimulus values (Rt, Gt, Bt) of the ambient color confirmed, and its tristimulus values with ambient color (Rt, Gt, Bt) are recorded as " tristimulus values of aim colour ".For example, in the sRGB space, it is below 1 or 1 that tristimulus values (Rs, Gs, Bs) are confirmed as the geometric distance that makes between the sRGB value (Rt, Gt, Bt) of tristimulus values (Rs, Gs, Bs) and ambient color.When adjusting to 1 or 1 when following at the aberration in the sRGB space, in fact color looks it is same color.Be noted here that because the sRGB value is expressed as digital value (that is, 0 to 255 integer under the situation of 8 bits), so obtained the tristimulus values (Ri, Gi, Bi) of limited aim colour.The set of the tristimulus values of aim colour (Ri, Gi, Bi) comprises the tristimulus values (Rt, Gt, Bt) of ambient color and the tristimulus values (Rs, Gs, Bs) close with ambient color.
At step S5, treatment facility 101 reads out in the tristimulus values (Ri, Gi, Bi) of one group of aim colour confirming among the step S4 from recording unit.
In step S6; Treatment facility 101 is not repeatedly selected three kinds of colored particles from specified colored particles among step S3; With (hereinafter as the colored particles that will confirm formula ratio; Be also referred to as " target colored particles "), and from recording unit, read the tristimulus values of target colored particles.Selected three kinds of target colored particles are defined as colored particles 1, colored particles 2 and colored particles 3, and corresponding tristimulus values are defined as (Rj, Gj, Bj) (j is 1,2 or 3).
In step S7; The tristimulus values of three kinds of target colored particles that use is read in step S6, treatment facility 101 obtain and the formula ratio of the target colored particles that the tristimulus values (Ri, Gi, Bi) of record-playback aim colour are used (according to the weight of every kind of colored particles shared ratio (weight percent) in the gross weight of colored particles).When mixing three kinds of colored particles (being colored particles 1, colored particles 2 and colored particles 3) in the coating composition that forms usefulness at colored pattern, the formula ratio of every kind of colored particles should be following: mass percent x% (colored particles 1), mass percent y% (colored particles 2) and mass percent z% (colored particles 3).Here, x+y+z=100.The average particle diameter of supposing colored particles is that 0.5m is to 1mm.Because particle dia is greater than wavelength of visible light, so proportional through the area that mixes the spot that color that three kinds of colored particles obtain and colored particles form.When the proportion of three kinds of colored particles of hypothesis much at one the time, think to have the additive mixture of colors characteristic.Thereby the equation 1 below setting up is to equation 3.
Ri=xR1+yR2+zR3... (equality 1)
Gi=xG1+yG2+zG3... (equality 2)
Bi=xB1+yB2+zB3... (equality 3)
These equations are simultaneous equation, and wherein, Ri, Gi and Bi are constants, and Rj, Gj and Bj (j is 1,2 or 3) are coefficients, and x, y and z are variablees.Therefore, through x, y and the z that from above-mentioned simultaneous equation, obtains, treatment facility 101 can be confirmed the formula ratio of colored particles 1, colored particles 2 and colored particles 3.Should be noted that it is known through numerical evaluation separating of linear simultaneous equation formula being carried out Calculation Method, thereby omit the description of known method.
In step S8, whether the formula ratio (x, y, z) of three kinds of target colored particles that obtain among the treatment facility 101 determining step S7 can be applied to the manufacturing that multicolor patterns forms the coating composition of usefulness.For example, when the formula ratio that is calculated is negative value, in fact can not produce the coating composition that multicolor patterns forms usefulness.Thereby whether the result of treatment facility 101 determining step S7 is included into following conditions.Then, only when not satisfying any one condition, process just gets into step S9; Otherwise step gets into step S10.
Among first condition: x, y and the z any one is negative value.
Second condition: at L
*a
*b
*In the color space, with the aberration of ambient color greater than 5.
The 3rd condition: a kind of formula ratio of colored particles is more than 90%.
The 4th condition: a kind of formula ratio of colored particles is below 5%.
During above the result of step S7 is included in the condition any one, use selected three kinds of colored particles can not form the target multicolor patterns.More specifically, when satisfying first condition, can not produce the coating composition that multicolor patterns forms usefulness like top description.
When satisfying second condition, the color of target multicolor patterns looks different with ambient color.In XYZ space or sRGB space, relation is according to the change in location in the space, so need to use the L that is suitable for human sensation between the aberration of geometric distance and human sensation
*a
*b
*Distance in the space is carried out and is judged.Thereby, in order the color of multicolor patterns and ambient color to be looked different situation gets rid of, second condition is confirmed as, convert the tristimulus values (Ri, Gi, Bi) of aim colour and the tristimulus values (Rt, Gt, Bt) of ambient color to L respectively
*a
*b
*Whether the aberration that obtains after the value is greater than 5.L
*a
*b
*Aberration is that two kinds of colors below 5 look it is identical color in the color space.Thereby, in this specification sheets, will be at L
*a
*b
*Be that color below 5 is called " with ambient color identical color " with the aberration of ambient color in the color space.
When satisfying the 3rd condition, multicolor patterns becomes dull, thereby is not preferred design aspect.In addition, when satisfying the 4th condition, in multicolor patterns, can not recognize spot.
In step S9, x, y and the z that treatment facility 101 will be confirmed in step S7 with about being recorded in the information of the related colored particles of x, y and z (specifying the information of three kinds of colored particles).
In step S10, treatment facility 101 judge whether to from specified N kind colored particles among step S3, repeatedly do not select three kinds of colored particles might make up and carried out the processing of step S7 to S9.When residue does not also have treated combination, handle and return step S6.Then, confirm a combination except the combination of having handled, make this combination then through the processing of step S7 to S9.When residue does not exist when also not having treated combination, handle entering step S11.Thereby, can confirm to reproduce combination and the formula ratio of this combination of colored particles of the tristimulus values (Ri, Gi, Bi) of an aim colour.
In step S11, treatment facility 101 judges for all aim colours of confirming among the step S4 whether carried out the processing of step S6 to S9.When residue does not also have the aim colour of processing, handle and return step S5.The aim colour of selection except treated aim colour makes this aim colour through the processing of step S6 to S9 of associating then.When not having residue also not have the aim colour of processing, processing finishes.
Thereby, can confirm the formula ratio of the color of base material, three kinds of colored particles and colored particles.Then, coating can be reproduced the coating composition of base material color.Further apply through will in determined formula ratio, determined colored particles mixing the coating composition that the multicolor patterns that produces forms usefulness with carrier components to base material.Thereby, can form the multicolor patterns that is in harmonious proportion with ambient color and film.Should be noted that the mass ratio of carrier components and all coloring particle is appointed as carrier/colored particles=60/40 in 70/30 scope, normally 65/35.In addition,, selected to have the color of the color (seeing step S2) of the tristimulus values identical in the above as base material with the tristimulus values of ambient color.But, can confirm the color of base material through the several different methods that the back is described.
Described embodiment of the present invention above, but the present invention is unqualified in above-described embodiment.
For example, about in step S1, obtaining the method for colouring information, when building that has applied multicolor patterns etc. is in programming phase or design phase, from schema or cad data, can obtain the tristimulus values of ambient color.When not being when directly from schema or cad data, obtaining the tristimulus values of ambient color, through color figure number (if known) the corresponding color card of measurement with ambient color, can be to obtain tristimulus values with top identical mode.When in cad data, comprising the data that relate to ambient color, can calculate tristimulus values through carrying out arithmetic processing.In addition, though with top to compare accuracy low, part that can be through will having applied multicolor patterns and a plurality of color cards relatively (that is, under visual observation, select with this part the proximate color card of color) confirmed ambient color.
About in step S2 to the confirming of base material color, can be with the color of identical with ambient color or close with ambient color color as base material." color identical with ambient color " refers at L
*a
*b
*In the color space with the aberration of ambient color in the color below 5.In addition, " color close with ambient color " refers at L
*a
*b
*Aberration with ambient color in the color space is greater than 5 and is the color below 10.In this case, consider the material cost of the coating composition that forms base material and the workability of coating, can the color close with ambient color be confirmed as the color of base material.For example, through using colourity and brightness, can easily discern the multicolor patterns superincumbent part of formation of filming with respect to the slight color that changes of ambient color.
Can be reduced in the amount of wanting the blended tinting pigment in the colored coating composition that forms base material then through brightness is increased so that its projecting a little color perhaps reduces colourity so that it is lower than the color that ambient color is confirmed base material.Can suitably adjust the brightness or the colourity of base material.For example, in order to adjust brightness, can be with L
*a
*b
*L in the color space
*Only increase by 5 to 10.Perhaps, not with L
*Value defined is under the situation of constant value, can be according to L on every side
*Value changes the L that will increase
*Value.For adjustment colourity, and with L
*Value is increased to the L of projecting color
*Value is opposite, can be with L
*C
*C in the h color space
*Value only reduces by 5 to 10.The colourity of base material can be according to C on every side
*Value changes.
In addition, at L
*a
*b
*The color space or L
*C
*It is preferred using tristimulus values in the h color space, because obtained the sensation approaching with the sensation that comes from visual observation.Here, can be with at L
*a
*b
*The color space or L
*C
*Tristimulus values in the h color space convert the sRGB value to, as the data layout in the sRGB space.
The simultaneous equation of confirming the formula ratio of colored particles is not limited to the equation 1 to 3 that uses the sRGB value, the L that can also use the sRGB value to change
*a
*b
*The simultaneous equation of value.In this case, can be through having at L
*a
*b
*Aberration with ambient color in the space is that aim colour is confirmed simultaneous equation in the definitions of color below 1.Because L
*a
*b
*The space to visual observation feel be fit to, so as top description use L
*a
*b
*Value is preferred.
Second, third is not limited to above-described numerical value with numerical value in the 4th condition, and can confirm according to circumstances.For example, can so change second condition, make " at L
*a
*b
*Aberration with ambient color in the space is more than 4 "; Can so change the 3rd condition, make " a kind of formula ratio of colored particles is more than 80% "; With can change the 4th condition with mode like this, make " a kind of formula ratio of colored particles is below 10% ".Can not consider in the 3rd condition and the 4th condition at least one.
Under second condition, color is defined in the color identical with ambient color, thereby second condition is preferred.But second condition is not confined to this.For example, can second condition be changed over the condition that allows the color close with ambient color, that is, and " at L
*a
*b
*In the color space with the aberration of ambient color greater than 10 ".
In addition, can the schema of Fig. 3 be changed over various ways and flowchart.For example, at first specify a combination of colored particles, can confirm the formula ratio of a plurality of target values then, rather than at first specify an aim colour, confirm the formula ratio of a plurality of combinations of colored particles then.
Be used for confirming in execution colored particles formula ratio processing (step S3 is to S11) afterwards, can carry out the processing (step S2) of the color that is used for definite base material.In this case; Can from a plurality of combinations (three kinds of colored particles) of confirming to the S11 at step S3, select to form the combination of a colored particles of the coating composition of usefulness as multicolor patterns, with the identical color of additive mixture of colors (Ri, Gi, Bi) of the colored particles of this combination can be as the color of base material.Thereby color that will be identical with additive mixture of colors is preferred as the color of base material.But the color close with additive mixture of colors can be as the color of base material.Here, " color identical with additive mixture of colors " refers at L
*a
*b
*In the color space with the aberration of additive mixture of colors in the color below 5." color close with additive mixture of colors " refers to that aberration with additive mixture of colors is greater than 5 and be the color below 10.
The for example situation of the formula ratio of the treatment facility calculating colored particles of computingmachine of using has been described above.But method of calculation are not confined to this.After having obtained take off data, someone can use take off data to calculate the formula ratio of colored particles.
Embodiment 1
Hereinafter, will the present invention more clearly be described with reference to following embodiment.
At first, as colored particles to be mixed in the coating composition that forms usefulness at multicolor patterns, prepared the 18 kinds of colored particles (N=18 in step S3) shown in the table 1, and measured the tristimulus values of every kind of colored particles.
[table 1]
| Sequence number | The particle name | Title | L * | a * | b * | X | Y | Z | R | G | B |
| 1 | Z10 | D02-80H | 80.38 | 16.03 | 5.77 | 60.88 | 57.35 | 55.34 | 235 | 186 | 186 |
| 2 | Z11 | D12-80H | 80.44 | 14.78 | 17.37 | 60.46 | 57.45 | 44.27 | 240 | 186 | 165 |
| 3 | Z12 | D17-80H | 80.34 | 9.82 | 22.91 | 58.22 | 57.27 | 39.38 | 234 | 190 | 154 |
| 4 | Z13 | D19-85F | 86.32 | 5.67 | 21.79 | 67.57 | 68.62 | 49.59 | 243 | 209 | 172 |
| 5 | Z14 | D22-85H | 85.15 | 3.54 | 28.09 | 64.35 | 66.28 | 41.99 | 239 | 207 | 157 |
| 6 | Z15 | D29-80H | 80.75 | -3.38 | 30.87 | 53.64 | 58.01 | 33.69 | 215 | 199 | 140 |
| 7 | Z16 | D37-80H | 81.25 | -13.91 | 20.84 | 50.45 | 58.91 | 42.45 | 188 | 208 | 159 |
| 8 | Z17 | D45-80H | 80.53 | -21.43 | 9.60 | 46.59 | 57.62 | 51.73 | 158 | 211 | 178 |
| 9 | Z18 | D55-80H | 80.30 | -21.57 | -0.65 | 46.19 | 57.20 | 62.11 | 144 | 211 | 196 |
| 10 | Z19 | D65-80H | 81.76 | -14.80 | -9.61 | 50.94 | 59.84 | 75.84 | 154 | 211 | 217 |
| 11 | Z20 | D69-80H | 81.67 | -8.83 | -11.72 | 53.06 | 59.67 | 78.35 | 167 | 208 | 221 |
| 12 | Z21 | D76-80H | 81.67 | -1.87 | -12.84 | 55.81 | 59.68 | 79.83 | 183 | 203 | 224 |
| 13 | Z22 | D82-70H | 73.37 | 6.29 | -12.35 | 45.48 | 45.71 | 61.82 | 179 | 175 | 199 |
| 14 | Z23 | D92-80H | 81.28 | 11.48 | -3.63 | 60.59 | 58.96 | 67.46 | 221 | 193 | 206 |
| 15 | Z24 | DN-80 | 81.43 | -0.29 | 1.07 | 56.02 | 59.24 | 62.36 | 201 | 201 | 197 |
| 16 | Z25 | DN-90 | 91.11 | 0.11 | 2.64 | 74.65 | 78.72 | 80.90 | 231 | 228 | 222 |
| 17 | Z26 | DN-95 | 97.25 | -0.61 | 0.90 | 87.83 | 93.03 | 98.45 | 246 | 247 | 243 |
| 18 | Z27 | DN-10 | 0.56 | 0.07 | -0.53 | 0.06 | 0.06 | 0.10 | 7 | 8 | 11 |
In table 1, colored particles is called Z10 to Z28.From D version coating in 2007 of Japanese coating TIA (being called hereinafter, " Nittoko Iromihon ") distribution color with every kind of colored particles of selection in the standard colour card.Because the color of every kind of colored particles is identical with color among the Nittoko Iromihon, so measured the color of D version coating in 2007 of Japanese coating TIA distribution with each sample of standard colour card (portable edition).For the measurement of color, using the D65 light source to use spectrophotometer under as irradiates light, 45 ° illumination angle, 0 ° the condition of light acceptance angle.Convert the spectral reflectance factor that is obtained to tristimulus values XYZ for the visual field of D65 light source and 10 °.After this, further implement L
*a
*b
*The conversion of value.In order to be transformed into the sRGB value, used the transition matrix of in http://www005.upp.so-net.ne.jp/fumoto/linkp25.htp, describing from the XYZ value.
As ambient color, used the D35-90A of Nittoko Iromihon.With with the identical mode of mode in colored particles, obtain the L of ambient color as follows
*a
*b
*Value and sRGB value.
(L
*，a
*，b
*)＝(92.14，2.04，4.94)
(R，G，B)＝(231，233，220)
Next, use colored particles z12, z17 and z26 in the table 1, confirm that the multicolor patterns that is in harmonious proportion with ambient color forms the coating composition prescription of usefulness.Here, by the method evaluation of in " AlgorithmEncyclopedia by Java " people such as (, technology review company, in May, 2003) Haruhiko Okumura, describing.The tristimulus values of colored particles z12, z17 and z26 (rgb value) as follows.
Z12 (R, G, B)=(234,190,154)
Z17 (R, G, B)=(158,211,178)
Z26 (R, G, B)=(246,247,243)
With these value substitution equations 1 to 3, to confirm formula ratio x, y and the z of colored particles z12, z17 and z26.As a result, obtain x=15 (mass percent), y=15 (mass percent) and z=70 (mass percent).
As the color of base material is the D35-90A of Nittoko Iromihon; At about 5 meters to 10 meters viewing distance place; This color looks and films identically on color that this films is to have the coating composition that forms usefulness through the multicolor patterns that calculates definite prescription through coating to obtain.
Embodiment 2
In addition, prescription is under the situation of from 18 kinds of all coloring particles of table 1, repeatedly not selecting three kinds of colored particles and the coating composition that forms multicolor patterns formation usefulness.More specifically, above-described processing is to carry out about 816 kinds of combinations of colored particles, and 816 kinds of combinations of this colored particles are to obtain through three kinds of colored particles from 18 kinds of colored particles, selecting.As a result, obtain 20 kinds of combinations shown in the table 2.Should be noted that the coating composition for actual multicolor patterns that can not make or inappropriate is formed usefulness forecloses, and has used above-described first to the 4th condition.
Table 2
| Sequence number | Particle 1 | Particle 2 | Particle 3 | Cooperation ratio 1 | Cooperation ratio 2 | Cooperation ratio 3 | The prediction aberration | The actual measurement aberration |
| 1 | Z12 | Z17 | Z26 | 0.15 | 0.15 | 0.70 | 0.00 | 1.5 |
| 2 | Z13 | Z18 | Z26 | 0.23 | 0.14 | 0.64 | 0.00 | |
| 3 | Z15 | Z20 | Z26 | 0.20 | 0.11 | 0.69 | 0.00 | |
| 4 | Z14 | Z19 | Z26 | 0.23 | 0.15 | 0.62 | 0.34 | 1.8 |
| 5 | Z10 | Z16 | Z26 | 0.06 | 0.21 | 0.73 | 0.68 | |
| 6 | Z15 | Z19 | Z26 | 0.18 | 0.07 | 0.75 | 0.68 | |
| 7 | Z14 | Z18 | Z26 | 0.17 | 0.10 | 0.72 | 1.03 | |
| 8 | Z16 | Z23 | Z26 | 0.24 | 0.13 | 0.63 | 1.03 | 2.3 |
| 9 | Z13 | Z17 | Z26 | 0.16 | 0.13 | 0.71 | 1.10 | |
| 10 | Z14 | Z17 | Z26 | 0.13 | 0.11 | 0.76 | 1.37 | |
| 11 | Z15 | Z18 | Z26 | 0.16 | 0.06 | 0.79 | 1.37 | |
| 12 | Z11 | Z17 | Z26 | 0.17 | 0.20 | 0.63 | 1.37 | |
| 13 | Z16 | Z25 | Z26 | 0.17 | 0.57 | 0.26 | 1.37 | |
| 14 | Z13 | Z16 | Z26 | 0.06 | 0.16 | 0.78 | 1.71 | |
| 15 | Z14 | Z16 | Z26 | 0.06 | 0.15 | 0.79 | 1.71 | |
| 16 | Z15 | Z16 | Z26 | 0.07 | 0.12 | 0.81 | 1.71 | |
| 17 | Z12 | Z18 | Z26 | 0.22 | 0.16 | 0.62 | 1.72 | |
| 18 | Z15 | Z17 | Z26 | 0.14 | 0.06 | 0.80 | 1.74 | |
| 19 | Z13 | Z19 | Z26 | 0.33 | 0.22 | 0.45 | 2.41 | |
| 20 | Z14 | Z20 | Z26 | 0.28 | 0.26 | 0.46 | 2.75 |
In the table 2, colored particles 1 is expressed in formula rate 1 in formula rate 3 (real number between 0 to 1) to the formula ratio (weight percent) of colored particles 3.In the table 2, the combination of colored particles z10, z11 and z12 is not shown.This be because; Under the situation of the combination of colored particles z10, z11 and z12; To equation 3, the formula ratio of z10, z11 and z12 is respectively 3.8 quality % ,-7.2 quality % and 4.5 quality % according to equation 1, and the formula ratio of z11 is negative value (7.2 quality %); Thereby, fill a prescription with this and can not make coating composition.
With the formula ratio manufacturing of every kind in the table 2 combination and the coating composition of coating multicolor patterns formation usefulness.As a result, obtain filming with the multicolor patterns of ambient color mediation.In the table 2, " prediction aberration " and " actual measurement aberration " refers at L
*a
*b
*Aberration between ambient color in the color space (92.14,2.04,4.94) and the multicolor patterns.Particularly, " prediction aberration " is through using the separating of equation of describing as embodiment to obtain aberration." actual measurement aberration " is the aberration that obtains through the value that the color of using the actual measurement multicolor patterns to film obtains, and this multicolor patterns is filmed and is to use the coating composition that forms usefulness with the equational multicolor patterns of separating as the formula ratio structure to form.
As an example, Fig. 4 shows photo, and each photo has been explained with the result of the coating composition of the formula ratio manufacturing multicolor patterns formation usefulness of the combination of the sequence number 1 of table 2 or sequence number 8 and applied same coating composition.The multicolor patterns that the left side of Fig. 4 illustrates when the combination of the colored particles of using sequence number 1 is filmed.The multicolor patterns that the right side of Fig. 4 illustrates when using the colored particles combination of Fig. 8 is filmed.
Industrial applicability
When giving the multicolor patterns design to the inner wall surface of buildings, outer wall surface etc., the present invention can be accurately and is confirmed that effectively the film multicolor patterns that forms usefulness of the multicolor patterns that is in harmonious proportion with ambient color forms prescription and the color of base material of the coating composition of usefulness.
Claims (9)
1. a multicolor patterns forms the coating composition determination of formula method of usefulness,
Said method is so confirmed said prescription; Make and to form the ambient color mediation of multicolor patterns that the coating composition of usefulness forms and this multicolor patterns through apply said multicolor patterns to coloured base material; The coating composition that said multicolor patterns forms usefulness comprises transparent coating formation composition and three kinds of colored particles
Said method comprises:
Confirm tristimulus values or the tristimulus values close of said ambient color first step as the tristimulus values of aim colour with these tristimulus values;
Specify second step of every kind of color of said three kinds of colored particles; With
Confirm that three of simultaneous equation separate the third step of formula ratio as each of said three kinds of colored particles; In said simultaneous equation; The tristimulus values of said aim colour are defined as constant, and the tristimulus values of said three kinds of colored particles are defined as coefficient, and the formula ratio of said colored particles is defined as variable; Wherein, each formula ratio of said three kinds of colored particles is not a negative value.
2. multicolor patterns according to claim 1 forms the coating composition determination of formula method of usefulness, wherein,
Said first step confirms that the tristimulus values color identical or close with the tristimulus values of said ambient color is as a plurality of said aim colours;
Said second step is associated with each other with as selecting three kinds of colored particles the set of key element from the tristimulus values of the information that will specify colored particles and said colored particles, and uses selected three kinds of colored particles to gather as colored particles;
Before said third step, further comprise the 4th step of from a plurality of said aim colours, selecting an aim colour; With
The tristimulus values of said three kinds of colored particles of the said colored particles set of said aim colour that use is selected in said the 4th step and the formation of in said second step, from said set, selecting are carried out said third step.
3. form the coating composition determination of formula method of usefulness according to claim 1 or 2 described multicolor patterns, wherein:
Said third step comprises:
Judge said three the 5th steps that whether comprise negative value in separating of said simultaneous equation; With
Separate six step of eliminating outside determined formula ratio with said three when in said three are separated, comprising negative value.
4. form the coating composition determination of formula method of usefulness according to claim 1 or 2 described multicolor patterns, wherein:
Said third step comprises:
Judgement through with between said three colors of separating the tristimulus values representative that obtains in the said simultaneous equation of substitution of said simultaneous equation and the said ambient color at L
*a
*b
*Whether the aberration in the space is in the 7th step more than 5; With
When said aberration is separated eliminating eight step determined formula ratio outside with said three 5 when above.
5. according to the coating composition determination of formula method of claim 1 or 2 described multicolor patterns formation usefulness, wherein, said third step comprises:
When said three of the said simultaneous equation of representing with per-cent separate nine step of eliminating outside determined formula ratio with said three when comprising separating more than 90% in separating.
6. according to the coating composition determination of formula method of claim 1 or 2 described multicolor patterns formation usefulness, wherein, said third step comprises:
When said three of the said simultaneous equation of representing with per-cent separate ten step of eliminating outside determined formula ratio with said three when comprising separating below 5% in separating.
7. according to the coating composition determination of formula method of claim 1 or 2 described multicolor patterns formation usefulness, further comprise:
Confirm L
*a
*b
*Be that color below 10 is as the 11 step of the color of said base material with the aberration of said ambient color in the color space.
8. multicolor patterns according to claim 2 forms the coating composition determination of formula method of usefulness, further comprises:
Repeatedly carry out said first step confirm a colored particles set to said the 4th step, from the said colored particles set of having confirmed said formula ratio and confirm with through ten two step of the identical or close color of the additive mixture of colors that uses the tristimulus values that form said three kinds of colored particles that a said colored particles gathers and obtain with three kinds of corresponding formula ratios of said three kinds of colored particles as the color of said base material.
9. a multicolor patterns forms the coating composition determination of formula device of usefulness; Said device comprises recording unit and treatment unit; And confirm that so said multicolor patterns forms the coating composition prescription of usefulness, make through on coloured base material, applying the ambient color mediation of multicolor patterns that said coating composition forms and this multicolor patterns;
The coating composition that said multicolor patterns forms usefulness comprises transparent coating formation composition and three kinds of colored particles; And
Said treatment unit has:
Confirm tristimulus values and the tristimulus values close of said ambient color first function as the tristimulus values of a plurality of aim colours with these tristimulus values,
Be associated with each other and said recording unit, selected second function of three kinds of colored particles in the data recorded storehouse from the information of appointment colored particles and the tristimulus values of said colored particles as the target colored particles;
From the determined a plurality of said aim colours of said first function, select an aim colour the 3rd function and
Find the solution simultaneous equation, confirm that resulting separating is recorded in the 4th function that simultaneously said formula ratio is associated with the information of specifying said target colored particles in the said recording unit as the formula ratio of said target colored particles with said formula ratio; In said simultaneous equation; The said tristimulus values of selected aim colour are defined as constant; The tristimulus values of said three kinds of target colored particles are defined as coefficient; And the formula ratio of said three kinds of target colored particles is defined as variable, and wherein, the formula ratio of each of said three kinds of colored particles is not a negative value.
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|---|---|---|---|
| JP2007250872A JP5796924B2 (en) | 2007-09-27 | 2007-09-27 | Method and program for determining the composition of a paint for forming a multi-colored pattern that harmonizes with the surrounding colors |
| JP2007-250872 | 2007-09-27 | ||
| PCT/JP2008/066260 WO2009041255A1 (en) | 2007-09-27 | 2008-09-09 | Method and device for determining blend of paints for forming multicolor pattern harmonious with surrounding colors |
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| JP2921365B2 (en) * | 1993-11-30 | 1999-07-19 | トヨタ自動車株式会社 | Paint color reproduction method and paint color selection method |
| JP2554014B2 (en) * | 1993-11-15 | 1996-11-13 | 日本ペイント株式会社 | Computer color matching method |
| JP3400878B2 (en) * | 1994-10-28 | 2003-04-28 | エスケー化研株式会社 | Natural stone tone coating method and natural stone tone paint composition used therefor |
| JP3565528B2 (en) * | 1996-02-15 | 2004-09-15 | 日本ペイント株式会社 | Apparatus for determining paint composition of paint for forming colorful patterns and method of determining paint composition for paint for forming colorful patterns |
| JP4562447B2 (en) * | 2003-08-08 | 2010-10-13 | ナトコ株式会社 | Non-hiding paint color matching apparatus, program thereof, painted product manufacturing apparatus, non-hiding paint color matching method, and painted product manufacturing method |
| JP5153153B2 (en) * | 2006-04-07 | 2013-02-27 | 関西ペイント株式会社 | Determination method of composition information of multi-color paint and visual information of base material, program thereof and recording medium |
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| CN101809098A (en) | 2010-08-18 |
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