CN101805532A - Bi-component methyl methacrylate waterproof paint - Google Patents
Bi-component methyl methacrylate waterproof paint Download PDFInfo
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- CN101805532A CN101805532A CN 201010138371 CN201010138371A CN101805532A CN 101805532 A CN101805532 A CN 101805532A CN 201010138371 CN201010138371 CN 201010138371 CN 201010138371 A CN201010138371 A CN 201010138371A CN 101805532 A CN101805532 A CN 101805532A
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Abstract
The invention discloses bi-component methyl methacrylate waterproof paint, which comprises a component A and a component B, wherein the mass ratio of the component A and the component B is 1: 0.5 to 2, the component A comprises methacrylate and acrylate monomer, methacrylate prepolymer or acrylate prepolymer, initiator, polymerization inhibitor and filler, and the component B comprises methacrylate and acrylate monomer, methacrylate prepolymer or acrylate prepolymer, initiator and filler. The waterproof paint can be cured and formed at the atmospheric temperature or the low temperature, is convenient to repair, is simple and rapid to construct, is free from containing organic evaporating solvent, has excellent mechanics performance, elasticity, weather resistance, abrasion resistance and excellent waterproof performance, and can be widely applicable to the waterproof and anti-corrosion treatment of the concrete pavement of the express way and the special railway passenger transportation line and steel-structure bridge.
Description
Technical field
The present invention relates to a kind of waterproof paint, particularly a kind of bi-component methyl methacrylate waterproof paint.
Background technology
Architectural waterproof material mainly contains waterproof paint and waterproof roll two big classes.Building water-proof paint mainly contains asphalt waterproofing paint, cement-base waterproof coating and polyurethane water-proof paint.The asphalt waterproofing paint high and low temperature resistance is not good, and environmental-protecting performance is relatively poor, and construction quality is difficult to control; CN 1407043 discloses a kind of waterproof coating and production method thereof, though this waterproof paint preferably resolves the asphalt waterproofing paint high and low temperature resistance, but contains a large amount of volatile benzene kind solvents, and environmental-protecting performance is not good.Cement-base waterproof coating sticking power is general, and it is cumbersome to construct, and needs watering maintenance in 24 hours; The polyurethane water-proof paint tensile strength is lower, and too fast easy generation bubble of speed of response and pin hole influence waterproof effect.CN101486874 discloses the production method of a kind of high ferro with polyurethane water-proof paint, and this kind polyurethane water-proof paint contains a large amount of aromatic hydrocarbon oil and clorafin, and environmental-protecting performance is not good.CN 101475772 discloses a kind of high performance polyurethane waterproof coating material and preparation method thereof, and the tensile strength of its waterproof paint is 6.7MPa, but because the construction quality of its speed of response when being difficult to guarantee large-area construction soon.
Summary of the invention
The present invention works out a kind of high strength, snappiness, the excellent waterproof paint of weather resisteant energy based on the methyl methacrylate Raolical polymerizable.
The present invention is achieved through the following technical solutions
A kind of bi-component methyl methacrylate waterproof paint, wherein:
The A component comprises:
Methacrylic ester and acrylate monomer 10-60 part
Methacrylate prepolymers or acrylic ester prepolymer 10-60 part
Initiator 0.5-10 part
Stopper 0.1-1 part
Filler 5-40 part
The B component comprises:
Methacrylic ester and acrylate monomer 10-60 part
Methacrylate prepolymers or acrylic ester prepolymer 10-60 part
Promotor 0.1-10 part
Filler 5-40 part
Methacrylic ester of the above and acrylate monomer have following structural formula: methacrylic ester:
Acrylate: H
2C=CH-COOR
R=C wherein
nH
2n+1, n=1,2,3...20;
Methacrylate prepolymers of the above or acrylic ester prepolymer are one or more mixture of urethane methacrylate or urethane acrylate, epoxy methacrylates or epoxy acrylate;
The initiator of the above is one or more a mixture of isopropyl benzene hydroperoxide, dicumyl peroxide, methylethyl ketone peroxide, dibenzoyl peroxide, the benzoyl peroxide tert-butyl ester, tertbutyl peroxide, diisopropylbenzenehydroperoxide;
The promotor of the above is one or more mixture of Thiourea, amine and organic transition metal salt; Described thiocarbamide is one or more a mixture of ethylene thiourea, tetramethyl thiourea, phenylthiourea, trimethyl thiourea, ethylene thiourea; Described amine is N, accelerine, N, and N-Diethyl Aniline, N, the N-dimethyl is to one or more the mixture in monomethylaniline, butyraldehyde-n-aniline condensation thing (808), triethylamine, the benzyldimethylamine; Described organic transition metal salt organo-transition metal compound is a kind of or wherein several mixture of naphthenate, acetylacetonate or the naphthoate of cobalt, iron, nickel, manganese, vanadium, copper, chromium;
The stopper of the above is one or more a mixture of Resorcinol, para benzoquinone, p methoxy phenol, 2,6 ditertiary butyl p cresol;
The filler of the above is a kind of or wherein several mixture in aluminium hydroxide, barium sulfate, zinc oxide, mica, silicon powder, talcum powder, lime carbonate, kaolin, the white carbon black;
Two-pack methyl methacrylate waterproof paint of the present invention is compared over-all properties have been had and has significantly improved with other waterproof paint.Because methyl methacrylate monomer has all carried out polyreaction, organic solvent-free volatilization in the solidification process of whole waterproof paint, so the environmental-protecting performance excellence of this waterproof paint; Because add polyurethane-modified methyl methacrylate performed polymer and epoxide modified methyl methacrylate performed polymer, the intensity of waterproof paint, elasticity and weathering resistance are improved.Can closely bond with all kinds concrete road surface and steel structure bridge after the bi-component methyl methacrylate waterproof paint spraying, have excellent waterproof and antiseptic property.
Embodiment
Following examples are to further specify of the present invention, but the invention is not restricted to following embodiment.
Example 1
It is even that 20 parts of methyl methacrylates, 40 parts of Rocryl 410s, 60 parts of urethane methyl methacrylates are added the high speed dispersion stirrer for mixing; Then 40 parts of lime carbonate, 10 parts of isopropyl benzene hydroperoxides, 1 part of Resorcinol are added in the high speed dispersion stirrer thorough mixing and make the A component after evenly.
Getting 20 parts of methyl methacrylates, 40 parts of Rocryl 410s, 60 parts of urethane methyl methacrylates, to add the high speed dispersion stirrer for mixing even; Then 40 parts of lime carbonate, 10 parts of tetramethyl thioureas are added in the high speed dispersion stirrer thorough mixing and make the B component after evenly.
The A.B component is even by weight 1: 1 mixed, scrape and paint the thick sample of 2mm, solidifying back its tensile strength of test is 11.2MPa.
Example 2
It is even that 20 parts of methyl methacrylates, 10 parts of Rocryl 410s, 10 parts of butyl acrylates, 40 parts of urethane methyl methacrylates are added the high speed dispersion stirrer for mixing; Then 10 parts of lime carbonate, 10 parts of white carbon blacks, 3 parts of isopropyl benzene hydroperoxides, 3 parts of tertbutyl peroxides, 1 part of 2,6 ditertiary butyl p cresol are added in the high speed dispersion stirrer thorough mixing and make the A component after evenly.
Getting 20 parts of methyl methacrylates, 10 parts of Rocryl 410s, 10 parts of butyl acrylates, 40 parts of urethane methyl methacrylates, to add the high speed dispersion stirrer for mixing even; Then 2 parts in 10 parts of lime carbonate, 10 parts of white carbon black .4 part tetramethyl thioureas, triethylamine are added in the high speed dispersion stirrer thorough mixing and make the B component after evenly.
A, B component is even by weight 1: 0.5 mixed, scrape and paint the thick sample of 2mm, solidifying back its tensile strength of test is 12.2MPa.
Example 3
20 parts of methyl methacrylates, 20 parts of Rocryl 410s, 30 parts of urethane methyl methacrylates and 10 parts of epoxy methyl methacrylate adding high speed dispersion stirrer for mixing are even; Then 0.5 part in 30 parts in barium sulfate, 6 parts of isopropyl benzene hydroperoxides, 0.5 part of Resorcinol, para benzoquinone is added in the high speed dispersion stirrer thorough mixing and make the A component after evenly.
It is even to get 20 parts of methyl methacrylates, 20 parts of Rocryl 410s, 30 parts of urethane methyl methacrylates and 10 parts of epoxy methyl methacrylate adding high speed dispersion stirrer for mixing; Then 0.5 part in 30 parts in barium sulfate, 4 parts of tetramethyl thioureas, chromium acetylacetonate is added in the high speed dispersion stirrer thorough mixing and make the B component after evenly.
A, B component is even by weight 1: 2 mixed, scrape and paint the thick sample of 2mm, solidifying back its tensile strength of test is 13.5MPa.
Example 4
20 parts of methyl methacrylates, 30 parts of Rocryl 410s and 40 parts of urethane methyl methacrylate adding high speed dispersion stirrer for mixing are even; Then 1 part in 20 parts in lime carbonate, 3 parts of isopropyl benzene hydroperoxides, 3 parts of the benzoyl peroxide tert-butyl esters, Resorcinol is added in the high speed dispersion stirrer thorough mixing and make the A component after evenly.
It is even to get 20 parts of methyl methacrylates, 30 parts of Rocryl 410s and 40 parts of urethane methyl methacrylate adding high speed dispersion stirrer for mixing; Then 1.2 parts in 20 parts in lime carbonate, 0.3 part of manganese acetylacetonate of cobalt naphthenate is added in the high speed dispersion stirrer thorough mixing and make the B component after evenly.
A, B component is even by weight 1: 1 mixed, scrape and paint the thick sample of 2mm, solidifying back its tensile strength of test is 14.8MPa.
Example 5
10 parts of ethyl propenoates and 40 parts of urethane methyl methacrylate adding high speed dispersion stirrer for mixing are even; Then 1 part of 10 parts of silicon powders, 0.5 part of isopropyl benzene hydroperoxide and Resorcinol is added in the high speed dispersion stirrer thorough mixing and make the A component after evenly.
Getting 10 parts of ethyl propenoates and 40 parts of urethane methyl methacrylates, to add the high speed dispersion stirrer for mixing even; Then 0.1 part of 10 parts of silicon powders and manganese acetylacetonate is added in the high speed dispersion stirrer thorough mixing and make the B component after evenly.
A, B component is even by weight 1: 1 mixed, scrape and paint the thick sample of 2mm, solidifying back its tensile strength of test is 12.8MPa.
Example 6
10 parts of methyl methacrylates and 15 parts of urethane methyl methacrylate adding high speed dispersion stirrer for mixing are even; Then 0.1 part of 5 parts of silicon powders, 0.5 part of isopropyl benzene hydroperoxide and Resorcinol is added in the high speed dispersion stirrer thorough mixing and make the A component after evenly.
Getting 10 parts of ethyl propenoates and 15 parts of urethane methyl methacrylates, to add the high speed dispersion stirrer for mixing even; Then 0.1 part of 5 parts of silicon powders and manganese acetylacetonate is added in the high speed dispersion stirrer thorough mixing and make the B component after evenly.
A, B component is even by weight 1: 1 mixed, scrape and paint the thick sample of 2mm, solidifying back its tensile strength of test is 10.8MPa.
The above; only be the specific embodiment of the present invention, but protection scope of the present invention is not limited thereto, anyly is familiar with those skilled in the art in the technical scope that the present invention discloses; the variation that can expect easily or replacement all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain that claim was defined.
Claims (10)
1. a bi-component methyl methacrylate waterproof paint is made up of by weight 1.0: 0.5～2.0 mixing two kinds of components of A, B, wherein:
The A component contains by weight:
Methacrylic ester and acrylate monomer 10-60 part
Methacrylate prepolymers or acrylic ester prepolymer 10-60 part
Initiator 0.5-10 part
Stopper 0.1-1 part
Filler 5-40 part
The B component contains by weight:
Methacrylic ester and acrylate monomer 10-60 part
Methacrylate prepolymers or acrylic ester prepolymer 10-60 part
Promotor 0.1-10 part
Filler 5-40 part.
2. bi-component methyl methacrylate waterproof paint according to claim 1 is characterized in that methacrylic ester described in A, the B component and acrylate monomer have following structural formula:
Methacrylic ester:
Acrylate: H
2C=CH-COOR
R=C wherein
nH
2n+1, n=1,2,3...20.
3. bi-component methyl methacrylate waterproof paint according to claim 1 is characterized in that the prepolymer described in A, the B component is one or more a mixture of urethane methacrylate, urethane acrylate, epoxy methacrylates or epoxy acrylate.
4. bi-component methyl methacrylate waterproof paint according to claim 1 is characterized in that the described initiator of A component is one or more a mixture of isopropyl benzene hydroperoxide, dicumyl peroxide, methylethyl ketone peroxide, dibenzoyl peroxide, the benzoyl peroxide tert-butyl ester, tertbutyl peroxide, the stupid hydrogen peroxide of diisopropyl.
5. the described bi-component methyl methacrylate waterproof paint of claim 1 is characterized in that the described stopper of A component is one or more a mixture of Resorcinol, para benzoquinone, p methoxy phenol, 2,6 ditertiary butyl p cresol.
6. the described bi-component methyl methacrylate waterproof paint of claim 1 is characterized in that the described promotor of B component is one or more mixture of Thiourea, amine and organic transition metal salt.
7. according to the described bi-component methyl methacrylate waterproof paint of claim 1, it is characterized in that the described filler of A, B is a kind of or wherein several mixture in aluminium hydroxide, barium sulfate, zinc oxide, mica, silicon powder, talcum powder, lime carbonate, kaolin, the white carbon black.
8. the bi-component methyl methacrylate waterproof paint of stating according to claim 6 is characterized in that described thiocarbamide is one or more a mixture of ethylene thiourea, tetramethyl thiourea, phenylthiourea, trimethyl thiourea, ethylene thiourea.
9. the bi-component methyl methacrylate waterproof paint of stating according to claim 6, it is characterized in that described amine is N, accelerine, N, N-Diethyl Aniline, N, the N-dimethyl is to one or more the mixture in monomethylaniline, butyraldehyde-n-aniline condensation thing (808), triethylamine, the benzyldimethylamine.
10. the bi-component methyl methacrylate waterproof paint of stating according to claim 6 is characterized in that described organo-transition metal compound is a kind of or wherein several mixture of naphthenate, acetylacetonate or the naphthoate of cobalt, iron, nickel, manganese, vanadium, copper, chromium.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010138371 CN101805532A (en) | 2010-04-02 | 2010-04-02 | Bi-component methyl methacrylate waterproof paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010138371 CN101805532A (en) | 2010-04-02 | 2010-04-02 | Bi-component methyl methacrylate waterproof paint |
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| Publication Number | Publication Date |
|---|---|
| CN101805532A true CN101805532A (en) | 2010-08-18 |
Family
ID=42607492
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|---|---|---|---|
| CN 201010138371 Pending CN101805532A (en) | 2010-04-02 | 2010-04-02 | Bi-component methyl methacrylate waterproof paint |
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Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101974289A (en) * | 2010-11-08 | 2011-02-16 | 株洲时代电气绝缘有限责任公司 | Modified polyurethane waterproof paint as well as preparation method and construction method thereof |
| CN102382233A (en) * | 2011-08-09 | 2012-03-21 | 重庆市智翔铺道技术工程有限公司 | Light colored cementitious material and application thereof |
| CN102408657A (en) * | 2011-08-09 | 2012-04-11 | 重庆市智翔铺道技术工程有限公司 | Tunnel bituminous pavement light color functional layer based on light color cement material |
| CN102604507A (en) * | 2012-03-02 | 2012-07-25 | 苏州中材非金属矿工业设计研究院有限公司 | Polymethyl methacrylate composite coating and preparation method thereof |
| WO2012139470A1 (en) * | 2011-04-15 | 2012-10-18 | 广州秀珀化工股份有限公司 | Polymethyl methacrylate water-resistant paint and preparation method therefor |
| CN102993795A (en) * | 2011-09-16 | 2013-03-27 | 郑旷宇 | Solvent-free waterproof paint containing segmented copolymer |
| CN103483115A (en) * | 2013-10-11 | 2014-01-01 | 葛洲坝易普力股份有限公司 | Preparation method of emulsifier for preparing emulsion explosive |
| CN104403392A (en) * | 2014-11-07 | 2015-03-11 | 长安大学 | Road surface coating material and application thereof for reducing asphalt road surface temperature |
| CN106010191A (en) * | 2016-06-30 | 2016-10-12 | 刘世超 | Flame-retardant antibacterial polyurethane coating and preparation method thereof |
| CN106433257A (en) * | 2016-09-09 | 2017-02-22 | 重庆鹏方交通科技股份有限公司 | Long-acting waterproof binding material for concrete bridge deck and preparation method of long-acting waterproof binding material |
| CN108373519A (en) * | 2017-12-28 | 2018-08-07 | 西安工业大学 | Solvent-free quick-dry type super-high solid content methyl methacrylate coating resin and its synthetic method |
| CN109401604A (en) * | 2019-01-16 | 2019-03-01 | 程兆鹏 | A kind of application method of highway repairing curing agent |
| CN109722077A (en) * | 2018-12-29 | 2019-05-07 | 四川君尚亚克力制造有限公司 | A kind of environmental protection rapid-curing cutback road surface identification material and construction method |
| CN110539533A (en) * | 2018-05-29 | 2019-12-06 | 郑月友 | durable reaction-adhesion strong cross membrane self-adhesive waterproof roll and preparation method thereof |
| CN111349373A (en) * | 2018-12-21 | 2020-06-30 | 袁洪声 | Protective paint special for highway anti-collision guardrail and preparation method thereof |
| CN112323623A (en) * | 2020-09-15 | 2021-02-05 | 江苏固迈新材料技术有限公司 | Steel bridge deck pavement structure and pavement process thereof |
| CN113831811A (en) * | 2021-11-16 | 2021-12-24 | 福建省三棵树新材料有限公司 | PMMA waterproof coating for constructional steel structure nodes and preparation method thereof |
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Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101974289A (en) * | 2010-11-08 | 2011-02-16 | 株洲时代电气绝缘有限责任公司 | Modified polyurethane waterproof paint as well as preparation method and construction method thereof |
| CN101974289B (en) * | 2010-11-08 | 2012-10-03 | 株洲时代电气绝缘有限责任公司 | Modified polyurethane waterproof paint as well as preparation method and construction method thereof |
| WO2012139470A1 (en) * | 2011-04-15 | 2012-10-18 | 广州秀珀化工股份有限公司 | Polymethyl methacrylate water-resistant paint and preparation method therefor |
| CN102382233A (en) * | 2011-08-09 | 2012-03-21 | 重庆市智翔铺道技术工程有限公司 | Light colored cementitious material and application thereof |
| CN102408657A (en) * | 2011-08-09 | 2012-04-11 | 重庆市智翔铺道技术工程有限公司 | Tunnel bituminous pavement light color functional layer based on light color cement material |
| CN102382233B (en) * | 2011-08-09 | 2013-09-11 | 重庆市智翔铺道技术工程有限公司 | Light colored cementitious material and application thereof |
| CN102993795A (en) * | 2011-09-16 | 2013-03-27 | 郑旷宇 | Solvent-free waterproof paint containing segmented copolymer |
| CN102604507A (en) * | 2012-03-02 | 2012-07-25 | 苏州中材非金属矿工业设计研究院有限公司 | Polymethyl methacrylate composite coating and preparation method thereof |
| CN102604507B (en) * | 2012-03-02 | 2013-12-04 | 苏州中材非金属矿工业设计研究院有限公司 | Polymethyl methacrylate composite coating and preparation method thereof |
| CN103483115A (en) * | 2013-10-11 | 2014-01-01 | 葛洲坝易普力股份有限公司 | Preparation method of emulsifier for preparing emulsion explosive |
| CN104403392A (en) * | 2014-11-07 | 2015-03-11 | 长安大学 | Road surface coating material and application thereof for reducing asphalt road surface temperature |
| CN106010191A (en) * | 2016-06-30 | 2016-10-12 | 刘世超 | Flame-retardant antibacterial polyurethane coating and preparation method thereof |
| CN106433257A (en) * | 2016-09-09 | 2017-02-22 | 重庆鹏方交通科技股份有限公司 | Long-acting waterproof binding material for concrete bridge deck and preparation method of long-acting waterproof binding material |
| CN108373519A (en) * | 2017-12-28 | 2018-08-07 | 西安工业大学 | Solvent-free quick-dry type super-high solid content methyl methacrylate coating resin and its synthetic method |
| CN108373519B (en) * | 2017-12-28 | 2020-07-28 | 西安工业大学 | Solvent-free quick-drying type ultrahigh-solid-content methyl methacrylate coating resin and synthesis method thereof |
| CN110539533A (en) * | 2018-05-29 | 2019-12-06 | 郑月友 | durable reaction-adhesion strong cross membrane self-adhesive waterproof roll and preparation method thereof |
| CN111349373A (en) * | 2018-12-21 | 2020-06-30 | 袁洪声 | Protective paint special for highway anti-collision guardrail and preparation method thereof |
| CN109722077A (en) * | 2018-12-29 | 2019-05-07 | 四川君尚亚克力制造有限公司 | A kind of environmental protection rapid-curing cutback road surface identification material and construction method |
| CN109401604A (en) * | 2019-01-16 | 2019-03-01 | 程兆鹏 | A kind of application method of highway repairing curing agent |
| CN112323623A (en) * | 2020-09-15 | 2021-02-05 | 江苏固迈新材料技术有限公司 | Steel bridge deck pavement structure and pavement process thereof |
| CN113831811A (en) * | 2021-11-16 | 2021-12-24 | 福建省三棵树新材料有限公司 | PMMA waterproof coating for constructional steel structure nodes and preparation method thereof |
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Application publication date: 20100818 |