CN101798779B - Flame-retardant safe cigarette tipping base paper and preparation method thereof - Google Patents
Flame-retardant safe cigarette tipping base paper and preparation method thereof Download PDFInfo
- Publication number
- CN101798779B CN101798779B CN2010101417803A CN201010141780A CN101798779B CN 101798779 B CN101798779 B CN 101798779B CN 2010101417803 A CN2010101417803 A CN 2010101417803A CN 201010141780 A CN201010141780 A CN 201010141780A CN 101798779 B CN101798779 B CN 101798779B
- Authority
- CN
- China
- Prior art keywords
- retardant
- flame
- paper
- fire
- cigarette
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Paper (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Abstract
The invention relates to a cigarette tipping base paper and a preparation method thereof. In the technical scheme of the flame-retardant safe cigarette tipping base paper, the surface is applied with a flame-retardant component, the solid content of the flame-retardant component is 3-10 percent of the tipping base paper, the flame-retardant component consists of modified starch and halogen-free phosphate and nitrate flame-retardant agents, and the weight ratio of the modified starch and the halogen-free phosphate and nitrate flame-retardant agents is 1:1-1:8. The preparation method of the invention is simple and can be realized by adding low cost in the original production process of the cigarette tipping base paper. The product of the invention has the advantages of simple process, stable quality and outstanding flame retardance, and not only can enhance the flame retardance of the paper, but also can improve the surface strength of the paper. Therefore, the product is a new generation product of the cigarette tipping base paper.
Description
Technical field
The present invention relates to a kind of cigarette tipping paper and preparation method thereof.
Background technology
No matter at which country, the stub that arbitrarily abandons all is one of major reason of initiation fire, and the stub kindling material lands can cause that the house burns, factory's blast and forest fire, causes the heavy losses of aspects such as life, property.The cigarette tipping body paper is when producing filter tipped cigarette, filter tip and cigarette to be propped up cigarette special-purpose basic paper together.The cigarette body paper that past adopts does not have flame-retarding characteristic, stays bigger disaster hidden-trouble to natural environment.
(application number is Chinese invention patent: 200410047091.0) disclose and can prevent fires in a kind of cigarette industry from putting out safety type cigarette and preparation method thereof.Be coated with the flame retardant coating endless belt of fire retardant masking liquid on the cigarette yew paper, coating endless belt position is positioned at cigarette and props up pipe tobacco and mouth rod junction.It is prepared as on cigarette yew paper printing intaglio printing press, and the fire retardant masking liquid is placed on cigarette yew paper printing intaglio printing press arbitrarily in one or more groups black groove, with the fire retardant masking liquid be coated be attached on the cigarette yew paper after, cut into dish, cigarette becomes cigarette to prop up on cigarette machine again.
(application number is Chinese invention patent: 200910098165.6) disclose a kind of flame retardation cigarette paper and preparation method thereof; The length direction of flame retardation cigarette paper is provided with at least two low air permeability districts, and so-called low air permeability district is provided with low air permeability thin layer and forms on regular-size cigarette paper; The material of low air permeability thin layer mainly comprises ethyl cellulose.The preparation method of flame retardation cigarette paper; Comprise modulation, unreel, printing, rolling step; Wherein modulation is that 5%～25% ethyl cellulose, 1%～1.5% dispersant and 94%～73.5% solvent are used for the material of low air permeability thin layer in the high-speed stirred modulated, makes it to be ink-like; Printing is that the material that is ink-like that adopts printing technology to modulate is printed onto on the cigarette paper, forms uniformly low air permeability thin layer; The speed that unreels with rolling is 50M/MIN～150M/MIN.
Summary of the invention
In order to solve the technological deficiency that the cigarette body paper does not have flame-retarding characteristic; An object of the present invention is to provide a kind of flame-retardant safe cigarette tipping body paper; This fire-retardant cigarette body paper has flame-retarding characteristic, is possessed when not aspirating from the horizontal blanking function by the stub of fire-retardant cigarette body paper production.Another object of the present invention provides the preparation method of above-mentioned tipping body paper.
In order to realize first above-mentioned purpose, the technical scheme below the present invention has adopted:
A kind of flame-retardant safe cigarette tipping body paper; The surface application of this tipping body paper has fire-retardant composition; The solid content of fire-retardant composition is 3%～10% of the former paper weight of tipping; Fire-retardant composition is made up of converted starch and bittern-free phosphorous-nitrogen flame retardant, counts converted starch by weight ratio: the bittern-free phosphorous-nitrogen flame retardant is 1: 1～1: 8.
As preferably, the solid content of above-mentioned fire-retardant composition is 5%～9% of the former paper weight of tipping.
As preferably, above-mentioned bittern-free phosphorous-nitrogen flame retardant is 1: 2～1: 5.
As preferably, above-mentioned phosphorus-nitrogen containing flame retardant is selected from phosphoric melamine salt, Melamine Polyphosphate (MPP), 2,4,8; 10-four oxygen-3,9-hosphospiro [5,5] hendecane-3; 9-dioxy-3,9-two melamine salts (CN-329), two (2,6; 7-three oxygen-1-phosphorus-dicyclo [2,2,2] octane-1-oxygen methyl) one or more in the phosphate melamine salt.
In order to realize second above-mentioned purpose, the technical scheme below the present invention has adopted:
A kind of preparation method who prepares above-mentioned flame-retardant safe cigarette tipping body paper, this method are raw paper pulp with the bleached wood pulp, made of paperly form fully through pulling an oar, purifying, screen, copy, and wherein apply fire-retardant composition in paper machine oven dry portion.
The present invention is owing to adopted above-mentioned technical scheme, and the preparation method is simple, and making it in the technical process of original production cigarette body paper, increase lower cost can realize.The advantage of product of the present invention is: technology is simple, constant product quality, and flame retardant effect is outstanding, and not only improve the fire resistance of paper, and improve the surface strength of paper, be cigarette body paper renewal product.
The specific embodiment
Be described further in the time of will combining specific embodiment to this below, but be not limited to embodiment.
Embodiment 1
With the bleached wood pulp is raw paper pulp, made of paperly forms fully through pulling an oar, purifying, screen, copy, and wherein applies fire-retardant composition in paper machine oven dry portion, carries out follow-up drying then, cuts, and obtains the former paper product of fire-retardant cigarette.
The profile instance of fire-retardant composition:
Phosphoric melamine salt 100g
Converted starch 35g
Water 1000g
With modified starch 35 grams, be dissolved in the 700 gram water, dispersed with stirring is even, is warmed to 80-90 ℃, and gelatinization is 20 minutes under this temperature, and thin up to 1000 gram adds 100 then and restrains phosphoric melamine salts, continues to stir further dissolving and processes molten night.
Consumption: solid content is to the applied amount of paper 5%～9%, and the concentration that applies liquid is decided according to the adsorbance of basic paper, is inversely proportional between the two.
Embodiment 2
With the bleached wood pulp is raw paper pulp, made of paperly forms fully through pulling an oar, purifying, screen, copy, and wherein applies fire-retardant composition in paper machine oven dry portion, carries out follow-up drying then, cuts, and obtains the former paper product of fire-retardant cigarette.
The profile instance of fire-retardant composition:
Melamine Polyphosphate 120g
Converted starch 40g
Water 1000g
With modified starch 40 grams, be dissolved in the 700 gram water, dispersed with stirring is even, is warmed to 80-90 ℃, and gelatinization is 20 minutes under this temperature, and thin up to 1000 gram adds 120 then and restrains Melamine Polyphosphate, continues to stir further dissolving and processes molten night.
Consumption: solid content is to the applied amount of paper 5%-9%, and the concentration that applies liquid is decided according to the adsorbance of basic paper, is inversely proportional between the two.
Embodiment 3
With the bleached wood pulp is raw paper pulp, made of paperly forms fully through pulling an oar, purifying, screen, copy, and wherein applies fire-retardant composition in paper machine oven dry portion, carries out follow-up drying then, cuts, and obtains the former paper product of fire-retardant cigarette.
The profile instance of fire-retardant composition:
Melamine Polyphosphate 60g
Phosphoric melamine salt 50g
Converted starch 25g
Water 1000g
With modified starch 25 grams, be dissolved in the 700 gram water, dispersed with stirring is even; Be warmed to 80-90 ℃, gelatinization is 20 minutes under this temperature, thin up to 1000 gram; Add Melamine Polyphosphate 60g, phosphoric melamine salt 50g then, continue to stir further dissolving and process molten night.
Consumption: solid content is to the applied amount of paper 5%-9%, and the concentration that applies liquid is decided according to the adsorbance of basic paper, is inversely proportional between the two.
Test Example
The evaluation of fire-retardant cigarette body paper testing result and flame retardant effect.
Test condition: temperature 20 degree, humidity 60%
Flame retardant effect props up under static combustion with cigarette, can cease the horizontal blanking number or the oxygen index (OI) index is weighed testing result and evaluation
| NO1 | NO2 | NO3 | |
| 20 cigarettes are lighted when being placed on static combustion case internal combustion to filter tip, can be from horizontal blanking quantity | 20 | 19 | 18 |
NO1: embodiment 1
NO2: embodiment 2
NO3: embodiment 3.
Claims (3)
1. flame-retardant safe cigarette tipping body paper; It is characterized in that: the surface application of this tipping body paper has fire-retardant composition; The solid content of fire-retardant composition is 3%～10% of the former paper weight of tipping; Fire-retardant composition is made up of converted starch and bittern-free phosphorous-nitrogen flame retardant, counts converted starch by weight ratio: the bittern-free phosphorous-nitrogen flame retardant is 1: 1～1: 8; Described phosphorus-nitrogen containing flame retardant is selected from phosphoric melamine salt, Melamine Polyphosphate, 2,4,8; 10-four oxygen-3,9-hosphospiro [5,5] hendecane-3; 9-dioxy-3,9-two melamine salts, two (2,6; 7-three oxygen-1-phosphorus-dicyclo [2,2,2] octane-1-oxygen methyl) one or more in the phosphate melamine salt; Above-mentioned tipping body paper is raw paper pulp with the bleached wood pulp, made of paperly forms fully through pulling an oar, purifying, screen, copy, and applies described fire-retardant composition in paper machine oven dry portion.
2. a kind of flame-retardant safe cigarette tipping body paper according to claim 1 is characterized in that the solid content of fire-retardant composition is 5%～9% of the former paper weight of tipping.
3. a kind of flame-retardant safe cigarette tipping body paper according to claim 1 is characterized in that counting by weight ratio converted starch: the bittern-free phosphorous-nitrogen flame retardant is 1: 2～1: 5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101417803A CN101798779B (en) | 2010-04-07 | 2010-04-07 | Flame-retardant safe cigarette tipping base paper and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101417803A CN101798779B (en) | 2010-04-07 | 2010-04-07 | Flame-retardant safe cigarette tipping base paper and preparation method thereof |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011103521115A Division CN102505559A (en) | 2010-04-07 | 2010-04-07 | Method for preparing flame-retardant safe raw tipping paper for cigarette |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101798779A CN101798779A (en) | 2010-08-11 |
| CN101798779B true CN101798779B (en) | 2012-01-04 |
Family
ID=42594612
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010101417803A Active CN101798779B (en) | 2010-04-07 | 2010-04-07 | Flame-retardant safe cigarette tipping base paper and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101798779B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103031779A (en) * | 2012-12-11 | 2013-04-10 | 潍坊华港包装材料有限公司 | Cigarette tipping paper and production process thereof |
| CN103343489B (en) * | 2013-07-09 | 2016-02-17 | 浙江凯恩特种材料股份有限公司 | Flame-retardant nonwoven wallpaper and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1331267A (en) * | 2000-06-26 | 2002-01-16 | 淄博市临淄镭射技术研究所 | Natural water-base fire-retarding adhesive |
| CN1795771A (en) * | 2004-12-24 | 2006-07-05 | 长沙卷烟厂 | Fireproof self-extinguishing safe type cigarette and preparation method |
-
2010
- 2010-04-07 CN CN2010101417803A patent/CN101798779B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1331267A (en) * | 2000-06-26 | 2002-01-16 | 淄博市临淄镭射技术研究所 | Natural water-base fire-retarding adhesive |
| CN1795771A (en) * | 2004-12-24 | 2006-07-05 | 长沙卷烟厂 | Fireproof self-extinguishing safe type cigarette and preparation method |
Non-Patent Citations (1)
| Title |
|---|
| 周勇信."磷-氮系膨胀型纸质材料阻燃剂的研制及应用".《中国优秀硕士论文全文数据库工程科技Ⅰ辑》.2007,(第5期),第36页. |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101798779A (en) | 2010-08-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP0870437B1 (en) | Smoking article wrapper for controlling ignition proclivity of a smoking article without affecting smoking characteristics | |
| FI72774C (en) | Self-extinguishing cigarette and cover design for this. | |
| CN101686732B (en) | Smoking articles having reduced ignition proclivity characteristics | |
| CN1306886C (en) | Smoking articles with reduced ignition proclivity characteristics | |
| CN102199902B (en) | Cigarette paper with low ignition tendency and preparation method | |
| EP0133575B1 (en) | Reduced ignition proclivity smoking article wrapper and smoking article | |
| AU605932B2 (en) | Cigarette wrappers containing freshly precipitated magnesium hydroxide | |
| EP1333729B1 (en) | Process for producing smoking articles with reduced ignition proclivity characteristics and products made according to same | |
| KR101820072B1 (en) | Paper for an article to be smoked having incendiary potential-reducing properties | |
| EP1234514A2 (en) | A reduced ignition propensity smoking article | |
| AU2002240293A1 (en) | A reduced ignition propensity smoking article | |
| CN102493285A (en) | Fire retardant, cigarette paper with antiflaming belt and preparation method of cigarette paper | |
| CN104797147A (en) | Wrapper having reduced ignition proclivity characteristics | |
| CN101798779B (en) | Flame-retardant safe cigarette tipping base paper and preparation method thereof | |
| CN106120431A (en) | A kind of flame-retardant smoke inhibition Plant fiber's paper base material and preparation method thereof | |
| CN102505559A (en) | Method for preparing flame-retardant safe raw tipping paper for cigarette | |
| CN201762624U (en) | Fire-retardant safe type cigarette tipping base paper | |
| JP2010529307A (en) | Cigarette paper with jagged band | |
| CN105220559A (en) | The thin cigarette paper of the tight light black circle of grey of ash is wrapped in a kind of burning smoke less | |
| CN101550663A (en) | Flame retardation cigarette paper and preparation method thereof | |
| CN105220560A (en) | The preparation method of the thin cigarette paper of the tight light black circle of grey of ash is wrapped in a kind of burning smoke less | |
| CN105220561A (en) | A kind of cigarette paper containing non-wood-fiber | |
| CN101858044A (en) | Preparation method of cigarette paper additive | |
| CN1795771A (en) | Fireproof self-extinguishing safe type cigarette and preparation method | |
| CN117026691A (en) | Cigarette paper with ash-coated display patterns and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: ZHEJIANG KAIFENG PAPER INDUSTRY CO., LTD. Free format text: FORMER OWNER: KAIEN SPECIAL MATERIALS CO., LTD., ZHEJIANG Effective date: 20120626 Free format text: FORMER OWNER: ZHEJIANG KAIFENG PAPER INDUSTRY CO., LTD. Effective date: 20120626 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 323300 LISHUI, ZHEJIANG PROVINCE TO: 324400 QUZHOU, ZHEJIANG PROVINCE |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20120626 Address after: 324400 Zhejiang province Longyou County Industrial Park (North) Zhejiang Kaifeng Paper Co. Ltd. Patentee after: Zhejiang Kaifeng Paper Industry Co., Ltd. Address before: 323300 No. 108 Kaine Road, Suichang County, Zhejiang Co-patentee before: Zhejiang Kaifeng Paper Industry Co., Ltd. Patentee before: Kaien Special Materials Co., Ltd., Zhejiang |
|
| C56 | Change in the name or address of the patentee | ||
| CP03 | Change of name, title or address |
Address after: 324400 No. 30 Jinxing Avenue, Longyou Industrial Park, Zhejiang Province Patentee after: ZHEJIANG KAIFENG NEW MATERIAL CO., LTD. Address before: 324400 Zhejiang province Longyou County Industrial Park (North) Zhejiang Kaifeng Paper Co. Ltd. Patentee before: Zhejiang Kaifeng Paper Industry Co., Ltd. |