The vent gas treatment of sulfonated naphthaldehyde water reducing agent production is utilized method and special equipment again
Technical field
The present invention relates to a kind of concrete admixture sulfonated naphthaldehyde water reducing agent building-up process exhaust gas treating method.
Background technology
Nineteen sixty-five the succeeding in developing of sulfonated naphthaldehyde water reducing agent, indicate that then the cement concrete material scientific and engineering has entered a New Times.According to statistics, sulfonated naphthaldehyde water reducing agent accounts for China's water reducer 70%.As long as the naphthalene water reducer of the 0.5%-1.0% of admixture by mass of cement just can make concrete flowability improve significantly; If be not purpose to improve liquidity and to improve intensity, then the admixture naphthalene water reducer then can make the cement consumption in the concrete reduce 10%-20%.The concrete of admixture water reducer not only performance improves significantly, and can utilize industrial solid castoff simultaneously in a large number, as flyash, blast furnace slag powder, steel-making slag powder, calcining coal gangue, metakaolin etc., make that cement consumption further reduces in the concrete.As seen, the development and production of naphthalene water reducer and extensive use have not only been made huge contribution to the performance raising aspect of concrete material, and have established important foundation for the concrete energy-saving and cost-reducing and flat raising of sharp waste water.Naphthalene water reducer occupies very special and crucial status in water reducer family, in considerable time from now on, this special and consequence can not shaken.But the development bottleneck of naphthalene water reducer is that environmental issue is that sulfonation process gives off naphthalene, water, sulfur dioxide sour gas vent gas treatment problem at present.
As shown in Figure 1 for having the equipment of conventional process tail gas now, this equipment only utilizes spray process to handle tail gas, its irrational place of this processing mode, mainly be to use the alkalescent water spray, producing some organic salt materials when absorbing the sour gas in the tail gas, these salts substances can disturb the condensation reaction quality, cause a large amount of shower waters can't reclaim use, can not efflux again, produced secondary pollution, can not change shower water for a long time, the concentration of water is more and more higher, and the effect that spray absorbs is just poor more, at last environment is polluted.
Summary of the invention
One of technical problem to be solved by this invention is to overcome the prior art deficiency, provide the vent gas treatment of the sulfonated naphthaldehyde water reducing agent production that a kind of vent gas treatment recovering effect is good, environmental pollution is little to utilize method again.
For solving the problems of the technologies described above, the present invention realizes by the following technical solutions:
A kind of vent gas treatment of sulfonated naphthaldehyde water reducing agent production is utilized method again, it is characterized in that, this method step is:
A, condensation are with the naphthalene in the tail gas, SO
2Acid gas condensation becomes naphthalene, sour coexist liq;
B, neutralization neutralize the acidic liquid that produces in the last step;
C, distillation, through a, the redistillation of b process liquids, naphthalene gas, the liquid of Xing Chenging has been removed can reclaim fully behind the composition that disturbs condensation reaction and has been used for hydrolysis of water reducer production process or condensation operation once more thus;
D, spray reclaim after the uncollected gas of condensation is through spray; This moment, shower water concentration was lower, can reclaim fully to be used for water reducer production and operation.
Wherein, spraying the shower water that is adopted is the weak base water of pH value between 7.5 to 10.0.
And temperature is 3~11 ℃ in condensing steps.And for being adopted as the water spray condensation that temperature is 3~11 ℃ of temperature.
Compare with the exhaust gas treating method of existing sulfonated naphthaldehyde water reducing agent production, the inventive method is more thorough for the processing of harmful substance in the tail gas, has eliminated the naphthalene in the tail gas, SO basically
2Pernicious gases such as acidity, reduced the tail gas pollution on the environment, and the liquid after the recycling can use during sulfonated naphthaldehyde water reducing agent produces once more, and is also higher to the recovery utilization rate of tail gas, further reduces the sulfonated naphthaldehyde water reducing agent production cost.
Another technical problem to be solved by this invention provides the vent gas treatment of the sulfonated naphthaldehyde water reducing agent production that a kind of vent gas treatment recovering effect is good, environmental pollution is little and utilizes special equipment again.
For solving the problems of the technologies described above, the present invention realizes by the following technical solutions:
The vent gas treatment special equipment that a kind of sulfonated naphthaldehyde water reducing agent is produced, comprise air inlet pipe and gas outlet in the tail gas outlet that is connected in the production of sulfonation formaldehyde naphthalene water reducer, between air inlet pipe and gas outlet, be connected with condensation still, distillation still and spray column in turn, the condensation still is connected with one in turn by pipeline and reclaims a liquid pool and a distillation still, spray column is communicated with a regulating tank by pipeline, and distillation still is communicated with No. two regulating tanks by pipeline.
As improvement to such scheme, reclaim between liquid pool and the distillation still, between spray column and the regulating tank and distillation still and No. two regulating tanks be provided with the liquid pump that power is provided for liquid flow.
As further improving, described condensation still comprises the kettle that passes through for tail gas, and kettle is provided with the sparge pipe of spray condensed water, and sparge pipe is communicated with the circulation liquid pool by liquid pump.
The said equipment is compared with existing equipment, liquid after the recycling is capable of circulation to be applied in the sulfonated naphthaldehyde water reducing agent production, greatly reduce the harmful substance contents of handling back tail gas, reduced pollution, further reduce the sulfonated naphthaldehyde water reducing agent production cost environment.
Description of drawings
The tail gas treatment device structural representation that accompanying drawing 1 is produced for existing sulfonated naphthaldehyde water reducing agent;
The vent gas treatment special equipment structural representation that accompanying drawing 2 is produced for sulfonated naphthaldehyde water reducing agent of the present invention.
The specific embodiment
For the ease of those skilled in the art's understanding, structural principle of the present invention is further described in detail below in conjunction with specific embodiment and accompanying drawing:
At first, the present invention proposes a kind of method of vent gas treatment of producing at sulfonated naphthaldehyde water reducing agent, this method is better to the filtration assimilation effect of harmful substance in the tail gas, and also can make production cost also lower.Steps of the method are:
A, condensation are with the naphthalene in the tail gas, SO
2Acid gas condensation becomes naphthalene, sour coexist liq;
B, neutralization neutralize the acidic liquid that produces in the last step;
C, distillation, through a, the redistillation of b process liquids, temperature to 180 ℃ is steamed the gas, the liquid that stay collection and has been removed can reclaim fully behind the composition that disturbs condensation reaction and be used for hydrolysis of water reducer production process or condensation operation;
D, spray reclaim after the uncollected gas of condensation is through spray, and this moment, shower water concentration was lower, can reclaim fully to be used for water reducer production and operation;
Wherein, spraying the shower water that is adopted is that temperature is 3~11 ℃ a weak base water.
For implementation method, also designed simultaneously the vent gas treatment special equipment that a kind of sulfonated naphthaldehyde water reducing agent is produced, this equipment comprises air inlet pipe 1 and the gas outlet 2 in the tail gas outlet that is connected in the production of sulfonated naphthalene water reducer, between air inlet pipe 1 and gas outlet 2, be connected with condensation still 3, distillation still 6 and spray column 4 in turn, condensation still 3 is connected with one in turn by pipeline and reclaims a liquid pool 5 and a distillation still 6, spray column 4 is communicated with a regulating tank 7 by pipeline, and distillation still 6 is communicated with No. two regulating tanks 8 by pipeline.
Wherein, condensation still 3 comprises the kettle 31 that passes through for tail gas, kettle 31 is provided with the sparge pipe 32 of spray condensed water, sparge pipe 32 is communicated with circulation liquid pool 33 by liquid pump, at tail gas during by condensation still 3, by the condensation of water at low temperature, make sour gas become acidic liquid, acidic liquid enters to reclaim in the liquid pool 5 and in reclaiming liquid pool 5 by pipeline and neutralizes.
Liquid through neutralization enters in the distillation still 6 by liquid pump again, in distillation still 6, heat the naphthalene fractionation in the liquid is come out, naphthalene gas, the liquid for the utilizing once more that form thus can enter in No. two regulating tanks 8 by liquid pump and store, and stay to be expendable organic salt impurity in the distillation still 6.
Can be by the gas behind the spray column 4 directly by pipeline 2 discharges from the gas outlet, the liquid in the spray column 4 then enters in a regulating tank 7 by liquid pump and stores.
Present embodiment equipment carries out recycling at various recycling materials in the tail gas, formed liquid can be directly used in the hydrolysis, condensation operation of sulfonated naphthaldehyde water reducing agent chemical process, and reduce the gas harmful substance contents of discharging greatly, finally realize energy-saving and emission-reduction.
The foregoing description only is a preferred implementation of the present invention, and in addition, the present invention can also have other implementations.That is to say that under the prerequisite that does not break away from the present invention's design, any conspicuous replacement all should fall within protection scope of the present invention.