CN101796947A - Pesticide emulsion in water and preparation method thereof - Google Patents
Pesticide emulsion in water and preparation method thereof Download PDFInfo
- Publication number
- CN101796947A CN101796947A CN201010147003A CN201010147003A CN101796947A CN 101796947 A CN101796947 A CN 101796947A CN 201010147003 A CN201010147003 A CN 201010147003A CN 201010147003 A CN201010147003 A CN 201010147003A CN 101796947 A CN101796947 A CN 101796947A
- Authority
- CN
- China
- Prior art keywords
- water
- emulsion
- penconazole
- ether
- solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to the technical field of agricultural bactericide, in particular to a pesticide emulsion in water and a preparation method thereof. The pesticide emulsion in water comprises the effective ingredient of penconazole and also comprises emulsifier, antifreeze agent, antifoaming agent, solvent, thickening agent and water. The components are in the following percentage by weight: 1-30% of the penconazole, 1-15% of the emulsifier, 1-5% of the antifreeze agent, 0-0.5% of the antifoaming agent, 1-45% of the solvent, 0.1-3% of the thickening agent and the balance of the water. The preparation method of the emulsion in water comprises: dissolving the penconazole with a small quantity of the solvent and the emulsifier, and evenly stirring to obtain even oil phase; stirring and mixing the water, the antifoaming gent, the antifreeze agent and the thickening agent to form uniform aqueous phase; at normal temperature and under high-speed stirring, adding the oil phase into the aqueous phase, or adding the aqueous phase into the oil phase to form emulsion in water with favourable dispersion, wherein the stirring speed is 200-3000 rpm, and the stirring time is 30-60 minutes; detecting products with grain diameter below 2.00 micrometers by utilizing a laser particle distribution instrument. The preparation of the invention takes water as the substrate, has the advantages of safe production, storage and transportation, environment protection, favorable prevention effect on common diseases of fruit trees, vegetable and the like, safe and convenient use, low cost and the like.
Description
Technical field
The invention belongs to technical field of agricultural fungicide, be specifically related to a kind of pesticide emulsion in water and preparation method thereof, particularly a kind of pesticide emulsion in water that contains penconazole and preparation method thereof.
Technical background
Along with the concern of people, require to reduce Pesticidal products and use the environmental hazard of bringing environment.For adapting to this social desirability, in the Pesticidal products exploitation,, require pesticidal preparations to develop to solidification, water baseization direction paying attention to the exploitation low toxicity, efficiently in the pesticide new variety, pesticidal preparations being had higher requirement.Pesticide emulsion in water is a kind of pesticides new formulation, is the water-fast solution that the former medicine of water-fast liquid state or solid-state former medicine is dissolved in the organic solvent gained, is scattered in the water and forms.Owing to replaced for environment and the virulent organic solvent of people and animals as dispersion medium with water in the aqueous emulsion, thereby reduce the consumption of organic solvent, had advantages such as environmental protection, safety, become the important directions that the present formulations of pesticide develop.
The penconazole chemical name is 1-(2,4-two chloro-β-propylbenzene ethyl)-1-1H-1,2, the 4-triazole, belong to triazole bactericidal agent, the main mechanism of action is sterol demethylation inhibitor, destroys and stop the biosynthesis of the cell membrane important composition composition ergosterol of germ, cause cell membrane not form, make germ death.Because absorption in having well, therefore can be rapidly by plant absorbing, and in conducted inside; Have good protection and therapeutic activity.Can prevent and treat disease due to sac fungi, basidiomycetes and the imperfect fungus effectively, especially powdery mildew, scab etc. be had excellent preventive effect.
The main formulation of the penconazole bactericide product of using on the agricultural chemicals market is a missible oil at present.Missible oil needs to use a large amount of organic solvents in process of production, organic solvent itself is with regard to inflammable, explosive, easy poisoning, therefore in production, storage, transportation, easily burn, accidents such as blast, poisoning, and in use strengthened the pollution of environment and operator's harm.And aqueous emulsion is water base chemical preparation, does not contain a large amount of organic solvents, and production process does not have dust, the no three wastes, and environmental pollution is little, and energy consumption is low.But this efficient, low toxicity, environment amenable penconazole aqueous emulsion are effectively used at present as yet.
Summary of the invention
The objective of the invention is at the problems referred to above, the pesticide emulsion in water of a kind of efficient, low toxicity, environmental protection, safety is provided.Another object of the present invention is to provide a kind of preparation method of above-mentioned pesticide emulsion in water.
The present invention is achieved through the following technical solutions:
The present invention relates to a kind of pesticide emulsion in water, wherein active ingredient is penconazole, also comprises emulsifier, antifreeze, defoamer, solvent, thickener and water.
Wherein, described emulsifier is selected from agricultural newborn 500# (alkyl benzene calcium sulfonate), NP series phosphate (polyoxyethylene nonylphenol ether phosphate), 600# phosphate (phenethyl phenol polyethenoxy ether phosphate), phenethyl polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, farming newborn 400# (benzyl dimethyl phenol polyethenoxy ether), farming newborn 600# (phenethyl phenol polyethenoxy ether), Nongru-700 # (alkylphenol polyoxyethylene formaldehyde condensation products), farming newborn 1600# (phenethyl phenol polyethenoxy polyethenoxy ether), ethylene oxide-propylene oxide block copolymer, NP series (polyoxyethylene nonylphenol ether), BY series (castor oil polyoxyethylene ether), peaceful newborn 33# (alkylaryl polyoxyethylene polyoxypropylene ether), sapn series (sorbitan monostearate), tween series (sorbitan fatty acid ester APEO), in the AE0 series (fatty alcohol-polyoxyethylene ether) one or more.
Described antifreeze is selected from one or more in ethylene glycol, propane diols, glycerine, isopropyl alcohol, the butanols.
Described defoamer is an organosilicon.
Described solvent is selected from one or more in methyl alcohol, ethanol, cyclohexanone, toluene, dimethylbenzene, N-Methyl pyrrolidone, aromatic hydrocarbons or its compound.
Described thickener is selected from one or more in Magnesiumaluminumsilicate, CMC, sodium alginate, PVA, arabic acid glue, polyacrylic acid, the xanthans.
The weight percentage of each component is respectively penconazole 1～30% in the pesticide emulsion in water of the present invention, emulsifier 1～15%, antifreeze 1～5%, defoamer 0～0.5%, solvent 1～45%, thickener 0.1～3%, water surplus.
The preparation method of pesticide emulsion in water of the present invention is: by above-mentioned weight percentage, with penconazole a small amount of solvent and emulsifiers dissolve, stirring obtains even oil phase; Then water, defoamer, antifreeze, thickener are mixed, form the homogeneous water, under normal temperature and high-speed stirred, oil phase is joined water, or water joins oil phase, form finely disseminated aqueous emulsion, measure the product cut size obtain below 2.00 microns with the laser particle size distribution instrument; The mixing speed that the present invention selects is 200～3000 rev/mins; Mixing time is 30～60 minutes.
Compared with prior art, penconazole aqueous emulsion of the present invention has following advantage: the one, owing to do not contain poisonous, inflammable organic solvent, unassured fiery fried dangerous, no unpleasant toxic odor, little to eye irritation, reduced pollution, improved safety greatly production, storing and user to environment; The 2nd, be matrix with the water of cheapness, saved a large amount of organic solvents simultaneously, manufacturing cost is descended significantly; The 3rd, the requirement of packing container also be can not show a candle to the missible oil harshness, thereby reduce packing cost; The 4th, substitute organic solvent with water, to environment and person poultry safety, the probability that produces poisoning is reduced greatly.
Embodiment
For a better understanding of the present invention, the invention will be further described below in conjunction with embodiment.Should be appreciated that specific embodiment described herein only is used to explain the present invention, and be not used in qualification the present invention.Percentage among the embodiment all is weight percentage.
The preparation of embodiment 1:5% penconazole aqueous emulsion.
Penconazole 5%, agricultural newborn 600#3%, BY140#3%, ethylene glycol 5%, organosilicon 0.2%, dimethylbenzene 10%, xanthans 0.2%, water is mended to 100%.Get above-mentioned raw materials by weight percent, with penconazole solvent and emulsifiers dissolve, stirring obtains even oil phase; Then water, defoamer, antifreeze, thickener are mixed, form the homogeneous water, under normal temperature and high-speed stirred oil phase is joined water, or water joins oil phase, form finely disseminated aqueous emulsion, mixing speed is 200～3000 rev/mins; Mixing time is 30～60 minutes; Measure the product cut size obtain below 2.00 microns with the laser particle size distribution instrument.
The preparation of example 2:10% penconazole aqueous emulsion.
Penconazole 10%, agricultural newborn 600#2%, EL-40#2%, peaceful newborn 33#1.5%, glycerine 3%, organosilicon 0.2%, dimethylbenzene 10%, cyclohexanone 5%, xanthans 0.15%, water is mended to 100%.Get above-mentioned raw materials by weight percent, with penconazole solvent and emulsifiers dissolve, stirring obtains even oil phase; Then water, defoamer, antifreeze, thickener are mixed, form the homogeneous water, under normal temperature and high-speed stirred oil phase is joined water, or water joins oil phase, form finely disseminated aqueous emulsion, mixing speed is 200～3000 rev/mins; Mixing time is 30～60 minutes; Measure the product cut size obtain below 2.00 microns with the laser particle size distribution instrument.
The preparation of example 3:20% penconazole aqueous emulsion.
Penconazole 20%, agricultural newborn 1600#3%, 700#3%, NP-10P 2%, ethylene glycol 4%, organosilicon 0.3%, toluene 15%, cyclohexanone 10%, xanthans 0.15%, water is mended to 100%.Get above-mentioned raw materials by weight percent, with penconazole a small amount of solvent and emulsifiers dissolve, stirring obtains even oil phase; Then water, defoamer, antifreeze, thickener are mixed, form the homogeneous water, under normal temperature and high-speed stirred oil phase is joined water, or water joins oil phase, form finely disseminated aqueous emulsion, mixing speed is 200～3000 rev/mins; Mixing time is 30～60 minutes; Measure the product cut size obtain below 2.00 microns with the particle size distribution test instrument.
Embodiment 4: penconazole aqueous emulsion and penconazole missible oil compare the control efficiency of powdery mildew of cucumber.
In field test penconazole aqueous emulsion and corresponding cream preparation thereof control efficiency to powdery mildew of cucumber.For the examination cucumber variety is No. 1, greenhouse, Great Wall, 667m
2Plant about 2500 strains, make base manure, the conventional cultivation management with composite fertilizer 150kg, superphosphate 100kg, fertilizer 250kg.Reagent agent embodiment 2 (10% penconazole aqueous emulsion) and contrast medicament 10% penconazole missible oil carry out dilution process by 3000 times respectively, randomised block design, and every processing repeats every sub-district 15m 4 times
2, be blank with the clear water.At the powdery mildew of cucumber their early stage, adopt backpack hand high-pressure sprayer to handle (leaf positive and negative even medicine), carry out the spray medicine the 1st time, later on every dispenser in 7 days 1 time, totally 3 times.Respectively at 7 days investigation incidences before the 1st dispenser, before the 2nd dispenser, before the 3rd dispenser and after the 3rd dispenser, every sub-district is by getting 5 investigation at random, look into 3 strains at every, 5 leaf investigation are got in every strain upper, middle and lower, by 9 grade standard classifications, record incidence of leaf and sick level are calculated disease index, control efficiency.
The blade grade scale: 0 grade, no scab; 1 grade, lesion area is below 5%; 3 grades, lesion area 6%～10%; 5 grades, lesion area 11%～20%; 7 grades, lesion area 21%～50%; 9 grades, lesion area is more than 50%.
Disease index=∑ [(the sick numbers of sheets at different levels * relative level numerical value)] * 100/ (investigating total number of sheets * 9)
Control efficiency (%)=[1-(disease index behind disease index before the blank district medicine * chemicals treatment district medicine)/(disease index before disease index behind the blank district medicine * chemicals treatment district medicine)] * 100
Table 1 is prevented and treated the test of pesticide effectiveness result of powdery mildew of cucumber
Embodiment 5: penconazole aqueous emulsion and penconazole missible oil compare the control efficiency of pear scab.
In the aqueous emulsion of field test penconazole and corresponding cream preparation thereof control efficiency to pear scab.The test kind is a pear.The age of tree 13 years, line-spacing 5m, spacing in the rows 3m.Reagent agent embodiment 3 (20% penconazole aqueous emulsion) and contrast medicament 20% penconazole missible oil carry out dilution process by 5000 times respectively; With the clear water is blank.Repeat 4 times, 3 strains of every sub-district, district's group is arranged at random, and guard row is established in the minizone.At the pear scab their early stage, adopt backpack hand high-pressure sprayer to spray medicine first, dispenser same day be a fine day.Execute 1 time every 10～14d, connect and execute 3 times, 14d investigation preventive effect after the last dispenser.2 strains are investigated in every sub-district, every strain divide East, West, South, North, in 5 samplings, every 20 leaves and 20 fruit investigation of getting current-year branch, record incidence of leaf (really) number and sick level are calculated disease index, control efficiency.
The leaf stage division.0 grade: anosis; 1 grade: lesion area accounts for below 10% of one-piece blade area; 3 grades: lesion area accounts for 11%～25% of one-piece blade area; 5 grades: lesion area accounts for 26%～40% of one-piece blade area; 7 grades: lesion area accounts for 41%～65% of one-piece blade area; 9 grades: lesion area accounts for more than 65% of one-piece blade area.
The fruit stage division.0 grade: no scab; 1 grade: on each fruit 1～2 of scab is arranged; 3 grades: on each fruit 3～4 of scabs are arranged; 5 grades: on each fruit 5～6 of scabs are arranged; 7 grades: on each fruit 7～10 of scabs are arranged, the part scab links to each other and accounts for fruit area about 1/5; 9 grades: scab is arranged more than 10 on each fruit, scab links to each other and accounts for the fruit area more than 1/4.
Disease index=∑ [sick leaves at different levels (really) number * relative level numerical value] * 100/[investigates total leaf (really) number * 9]
Control efficiency (%)=(contrast disease index-processing disease index) * 100/ contrast disease index
Table 2 is prevented and treated the test of pesticide effectiveness result of pear scab
| Medicament kind | Extension rate | Sick leaf rate (%) | Disease index | Blade preventive effect (%) | Diseased fruit rate (%) | Disease index | Fruit preventive effect (%) |
| Embodiment 3 | ??5000 | ??4.70 | ??0.98 | ??92.85 | ??1.10 | ??0.37 | ??95.71 |
| 20% penconazole missible oil | ??5000 | ??5.30 | ??1.08 | ??92.12 | ??1.65 | ??0.44 | ??94.90 |
| Clear water contrast (CK) | ??-- | ??44.45 | ??13.70 | ??-- | ??30.60 | ??8.63 | ??-- |
From last table 1, table 2 result as can be known, the pesticide emulsion in water of the embodiment of the invention, compare with traditional cream preparation, under identical extension rate, use, drug effect is suitable, but pesticide emulsion in water of the present invention has replaced for environment and the virulent organic solvent of people and animals as dispersion medium with water, when saving cost, the pressure of environment is also reduced greatly.
The above only is preferred embodiment of the present invention, not in order to restriction the present invention, all any modifications of being done within the spirit and principles in the present invention, is equal to and replaces and improvement etc., all should be included within protection scope of the present invention.
Claims (8)
1. pesticide emulsion in water, wherein, active ingredient is penconazole, it is characterized in that, described pesticide emulsion in water also comprises emulsifier, antifreeze, defoamer, solvent, thickener and water.
2. pesticide emulsion in water according to claim 1, it is characterized in that described emulsifier is selected from agricultural newborn 500# (alkyl benzene calcium sulfonate), NP series phosphate (polyoxyethylene nonylphenol ether phosphate), 600# phosphate (phenethyl phenol polyethenoxy ether phosphate), phenethyl polyoxyethylene ether ammonium sulfate salt, alkyl biphenyl ether disulfonic acid magnesium salts, triethanolamine salt, farming newborn 400# (benzyl dimethyl phenol polyethenoxy ether), farming newborn 600# (phenethyl phenol polyethenoxy ether), Nongru-700 # (alkylphenol polyoxyethylene formaldehyde condensation products), farming newborn 1600# (phenethyl phenol polyethenoxy polyethenoxy ether), ethylene oxide-propylene oxide block copolymer, NP series (polyoxyethylene nonylphenol ether), BY series (castor oil polyoxyethylene ether), peaceful newborn 33# (alkylaryl polyoxyethylene polyoxypropylene ether), sapn series (sorbitan monostearate), tween series (sorbitan fatty acid ester APEO), in the AE0 series (fatty alcohol-polyoxyethylene ether) one or more.
3. pesticide emulsion in water according to claim 1 is characterized in that described antifreeze is selected from one or more in ethylene glycol, propane diols, glycerine, isopropyl alcohol, the butanols.
4. pesticide emulsion in water according to claim 1 is characterized in that, described defoamer is an organosilicon.
5. pesticide emulsion in water according to claim 1 is characterized in that, described solvent is selected from one or more in methyl alcohol, ethanol, cyclohexanone, toluene, dimethylbenzene, N-Methyl pyrrolidone, aromatic hydrocarbons or its compound.
6. pesticide emulsion in water according to claim 1 is characterized in that, described thickener is selected from one or more in Magnesiumaluminumsilicate, CMC, sodium alginate, PVA, arabic acid glue, polyacrylic acid, the xanthans.
7. pesticide emulsion in water according to claim 1 is characterized in that, the weight percentage of each component is respectively in the described aqueous emulsion: penconazole 1～30%, emulsifier 1～15%, antifreeze 1～5%, defoamer 0～0.5%, solvent 1～45%, thickener 0.1～3%, water surplus.
8. the preparation method of a pesticide emulsion in water according to claim 1 is characterized in that, according to the weight percentage of claim 7, penconazole with a small amount of solvent and emulsifier for mixing dissolving, is obtained even oil phase; Then water, defoamer, antifreeze, thickener are mixed, form the homogeneous water, under normal temperature and high-speed stirred, oil phase is joined water, or water joins oil phase, form finely disseminated aqueous emulsion.The selected mixing speed of this preparation method is 200～3000 rev/mins; Mixing time is 30～60 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010147003A CN101796947A (en) | 2010-04-15 | 2010-04-15 | Pesticide emulsion in water and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010147003A CN101796947A (en) | 2010-04-15 | 2010-04-15 | Pesticide emulsion in water and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101796947A true CN101796947A (en) | 2010-08-11 |
Family
ID=42592924
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201010147003A Pending CN101796947A (en) | 2010-04-15 | 2010-04-15 | Pesticide emulsion in water and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101796947A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102701841A (en) * | 2012-05-22 | 2012-10-03 | 芜湖市多威农化有限责任公司 | Biological antimicrobial chelerythrine aqueous emulsion and preparation method thereof |
| CN103952244A (en) * | 2014-04-18 | 2014-07-30 | 广东中实金属有限公司 | Water-based cleaning agent capable of reducing discharge of pollutants produced in circuit board cleaning |
| CN104418419A (en) * | 2013-08-28 | 2015-03-18 | 株式会社日立制作所 | Coagulation processing method, coagulation processing unit, and water processing apparatus |
| CN104591425A (en) * | 2013-10-30 | 2015-05-06 | 株式会社日立制作所 | Water processing method and water processing device |
| CN107027749A (en) * | 2017-05-24 | 2017-08-11 | 浙江工业大学 | A kind of compound emulsifying agent and its application in compounding chlopyrifos pesticides |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030050194A1 (en) * | 2001-09-07 | 2003-03-13 | Hopkinson Michael J. | Surfactant systems for agriculturally active compounds |
| CN101617671A (en) * | 2009-08-01 | 2010-01-06 | 深圳诺普信农化股份有限公司 | Combination sterilization composition |
| CN101617659A (en) * | 2009-08-12 | 2010-01-06 | 深圳诺普信农化股份有限公司 | Compound sterilizing composition |
| CN101637162A (en) * | 2009-09-08 | 2010-02-03 | 深圳诺普信农化股份有限公司 | Sterilization composition containing flutolanil |
| CN101647433A (en) * | 2009-07-21 | 2010-02-17 | 深圳诺普信农化股份有限公司 | Sterilization composition based on zoxamide |
| CN101669487A (en) * | 2009-08-23 | 2010-03-17 | 山东兆丰年生物科技有限公司 | Compound bactericidal composition containing penconazole |
-
2010
- 2010-04-15 CN CN201010147003A patent/CN101796947A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20030050194A1 (en) * | 2001-09-07 | 2003-03-13 | Hopkinson Michael J. | Surfactant systems for agriculturally active compounds |
| CN101647433A (en) * | 2009-07-21 | 2010-02-17 | 深圳诺普信农化股份有限公司 | Sterilization composition based on zoxamide |
| CN101617671A (en) * | 2009-08-01 | 2010-01-06 | 深圳诺普信农化股份有限公司 | Combination sterilization composition |
| CN101617659A (en) * | 2009-08-12 | 2010-01-06 | 深圳诺普信农化股份有限公司 | Compound sterilizing composition |
| CN101669487A (en) * | 2009-08-23 | 2010-03-17 | 山东兆丰年生物科技有限公司 | Compound bactericidal composition containing penconazole |
| CN101637162A (en) * | 2009-09-08 | 2010-02-03 | 深圳诺普信农化股份有限公司 | Sterilization composition containing flutolanil |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102701841A (en) * | 2012-05-22 | 2012-10-03 | 芜湖市多威农化有限责任公司 | Biological antimicrobial chelerythrine aqueous emulsion and preparation method thereof |
| CN102701841B (en) * | 2012-05-22 | 2014-03-12 | 芜湖市多威农化有限责任公司 | Biological antimicrobial chelerythrine aqueous emulsion and preparation method thereof |
| CN104418419A (en) * | 2013-08-28 | 2015-03-18 | 株式会社日立制作所 | Coagulation processing method, coagulation processing unit, and water processing apparatus |
| CN104591425A (en) * | 2013-10-30 | 2015-05-06 | 株式会社日立制作所 | Water processing method and water processing device |
| CN103952244A (en) * | 2014-04-18 | 2014-07-30 | 广东中实金属有限公司 | Water-based cleaning agent capable of reducing discharge of pollutants produced in circuit board cleaning |
| CN107027749A (en) * | 2017-05-24 | 2017-08-11 | 浙江工业大学 | A kind of compound emulsifying agent and its application in compounding chlopyrifos pesticides |
| CN107027749B (en) * | 2017-05-24 | 2021-04-09 | 浙江工业大学 | Composite emulsifier and application thereof in compound chlorpyrifos pesticide |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103598192B (en) | A kind of bactericidal composition containing tetramycin and Zhongshengmycin | |
| CN101796947A (en) | Pesticide emulsion in water and preparation method thereof | |
| CN103271077A (en) | Complex acaricide for farmland and fruiters | |
| CN105052983A (en) | Seed treating agent and special pesticide composition thereof | |
| CN101911955B (en) | Biogenic acaricidal water suspension composition and preparation method thereof | |
| CN103814923A (en) | Dispersible oil suspending agent containing pyraclostrobin | |
| CN104770368A (en) | Bactericidal composition containing coumoxystrobin and xinjunan and application thereof | |
| CN101258848B (en) | Triazophos-containing insecticidal solid microemulsion and preparation thereof | |
| CN102428935A (en) | Oxadiargyl and butachlor aqueous emulsion and preparation method thereof | |
| CN101601390A (en) | Difenoconazole and propiconazole emusion in water and preparation method thereof | |
| CN102318640A (en) | Karbofos emulsion in water and preparation method thereof | |
| CN102308791B (en) | Prochloraz emulsifiable granules and preparation method thereof | |
| CN103636624A (en) | Sterilizing composition containing tetramycin and symplectic bacteria amine acetate | |
| CN101444208B (en) | Kresoxim-methyl sterilizing aqueous emulsion and preparation method thereof | |
| CN105010361A (en) | Sterilization composition containing tetramycin and boscalid | |
| CN102669126A (en) | Composite containing methoxyfenozide and botanical pesticide | |
| CN105340915A (en) | Sterilization composition containing benziothiazolinone and Xinjunan acetate | |
| CN101530084A (en) | Preparation method of tebuconazole aqueous emulsion | |
| CN101595869B (en) | Abamectin indoxacarb suspending agent and preparation method thereof | |
| CN101554155A (en) | Triazolone microemulsion and preparation method thereof | |
| CN102027933B (en) | Disinfectant composition comprising tebuconazole and levorotatory alpha-terpilenol and production method thereof | |
| CN102805089A (en) | Insect and mite killing composition containing Cyflumetofen and emamectin benzoate | |
| CN105394039A (en) | Bactericidal composition containing oxine-copper and ethylicin | |
| CN105340894A (en) | Sterilization composition containing dithianon and bromothalonil | |
| CN101743954A (en) | Multi-effect azole suspending agent and method for preparing same |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20100811 |