CN101795663B

CN101795663B - Hair increasing dye and aerosol type hair increasing die

Info

Publication number: CN101795663B
Application number: CN2008801051018A
Authority: CN
Inventors: 头金集
Original assignee: PINOLE CO Ltd
Current assignee: PINOLE CO Ltd
Priority date: 2007-08-28
Filing date: 2008-04-17
Publication date: 2012-05-23
Anticipated expiration: 2028-04-17
Also published as: WO2009028234A1; TW200909002A; TWI399220B; CN101795663A; JP5215777B2; JP2009073827A; KR20090022984A

Abstract

It is intended to provide a hair increasing dye, wherein a powdery carrier comprising talc or the like is used only in a reduced amount or omitted so that the appearance of hair volume can be effectively enhanced and the run-off of the dye caused by moisture such as sweat or rain can be effectively prevented while stably coloring the hair at a definite hair dye concentration, and an aerosol type hair dye using the same. Namely, a hair increasing dye containing a colorant, a sticking agent and a solvent and an aerosol type hair dye using the same wherein the colorant is carbon particles.

Description

Additional issue illuminating colour and aerosol type additional issue illuminating colour

[technical field]

The invention relates to the painted hair dye of additional issue that is used for hair coloring and improves aesthetic feeling.Particularly about when stably hair being had hair dyed according to set hair dyeing concentration; Can improve aesthetic feeling effectively; And; Can suppress coloring agent effectively via the painted hair dye of the effusive additional issue of moisture such as antiperspirant, and use the aerosol type of the painted hair dye of this additional issue to issue additional painted hair dye.

[technical background]

In recent years, be that the painted hair dye of additional issue of purpose is widely used with the aesthetic feeling that improves hair.

Issue additional painted hair dye as this, adopted the fiber that will dye to spread mode to hair and so on, or make the silicate particles that applied attached on the hair in order to manifest various modes such as glossy mode.

But, adopted the painted hair dye of additional issue of these modes, exist hair to lose the submissive of nature, give the factitious impression of people sometimes, or only be that the gloss of hair changes, and do not improve problem such as aesthetic feeling in fact.

Therefore, disclose the aesthetic feeling that should improve hair more effectively, contained the painted hair dye of additional issue of the adhesive agent that coloring agent, resins etc. such as the dust carrier that is made up of Pulvis Talci etc., carbon black constitute.(for example, referring to patent documentation 1).

More concrete; Be to have adopted to be carried with dust carrier coloring agent such as carbon black, that constitute by Pulvis Talci etc.; Through the adhesive agent that constitutes by resin etc.; Hair to one one applies, and seems chap through making these hairs of one one, thereby improves the painted hair dye of additional issue of the mode of aesthetic feeling effectively.

In addition; Disclose with: will be carried with dust carrier coloring agent such as carbon black, that constitute by Pulvis Talci etc.; Through the adhesive agent that constitutes by resin etc.; After one one hair applied, use a nearly step of water-resistant resin such as acrylic acid caprylamide to apply additional issue method (for example, referring to patent documentation 2) as the hair of characteristic.

[patent documentation 1] special permission No. 3074443 communiques (scope of patent application)

[patent documentation 2] spy opens 2005-194210 communique (scope of patent application)

[disclosure of an invention]

[problem that invention will solve]

But, in having used patent documentation 1 under the situation of the painted hair dye of additional issue of record,, but have coloring agent such as carbon black moisture such as the antiperspirant through coming from scalp, rain and the problem of stripping easily though can improve aesthetic feeling to a certain extent.

Consequently, the moisture of this coloring agent occurred containing, flowed to face, neck sometimes, user has to often to be careful the situation of the environment for use of the painted hair dye of additional issue.

Near and; The painted hair dye of additional issue of record in patent documentation 1; Because used the dust carrier that constitutes by Pulvis Talci etc.; So exist because the white or the gray color of this dust carrier self, the color of coloring agent such as carbon black is encumbered, be difficult to the problem of having hair dyed and so on according to set hair dyeing concentration.

In addition; The additional issue method of the hair of record in patent documentation 2; Though can suppress coloring agent to a certain extent via moisture stripping and outflow, in fact must through the finger or comb repeatedly to hair rub, combing, lose cohesiveness until adhesive agent and water-resistant resin.

Therefore, under the situation of implementing this additional issue method, existence is not only very time-consuming, and to the tangible problem of the damage of hair.

In addition, the additional issue method of hair of record in patent documentation 2, the same with the painted hair dye of additional issue of record in the patent documentation 1, also exist because the influence of the dust carrier that is made up of Pulvis Talci etc. is difficult to the problem of having hair dyed according to set hair dyeing concentration.

Therefore, inventors of the present invention are through research with keen determination; The result finds, in the painted hair dye of additional issue, through using carbon particle as coloring agent; Can stably have hair dyed to hair according to set hair dyeing concentration; Simultaneously, through carbon particle self, can improve the aesthetic feeling of hair effectively as coloring agent.Closely and also find, rely on superior water absorption that this carbon particle had etc., even with the situation of contact with moisture such as antiperspirant under, also can suppress stripping and outflow effectively, thereby accomplish the present invention.

That is: the object of the invention; Be to be provided at when stably hair being had hair dyed according to set hair dyeing concentration; Can improve aesthetic feeling effectively; And, can suppress coloring agent effectively via the painted hair dye of the effusive additional issue of moisture such as antiperspirant, and use the aerosol type of the painted hair dye of this additional issue to issue additional painted hair dye.

[being used to solve the means of problem]

According to the present invention, be the painted hair dye of additional issue that contains coloring agent, adhesive agent, solvent, providing with coloring agent is that carbon particle is the painted hair dye of additional issue of characteristic, can address the above problem.

That is: through using carbon particle,, improve the aesthetic feeling of hair effectively even, also can pass through carbon particle self saving or having reduced under the situation of use of the dust carrier that constitutes by Pulvis Talci etc. as coloring agent.

In addition; Because can save or reduce the use of the dust carrier that constitutes by Pulvis Talci etc.; So can suppress white or gray color owing to this dust carrier self effectively, the color of coloring agent is encumbered, and is difficult to the problem of having hair dyed according to set hair dyeing concentration.

Near and, if carbon particle,, also can rely on superior water absorption that carbon particle had etc. even descending with the situation of contact with moisture such as the antiperspirant that comes from scalp, rain, these water effective ground are suppressed stripping and outflow.

In addition, when constituting the painted hair dye of additional issue of the present invention, several averaged particles of carbon particle directly are preferably the interior value of scope of 2～200 μ m.

Through constituting in this wise, when continuing to improve aesthetic feeling, can also reproduce hair original natural color and luster.

In addition, when constituting the painted hair dye of additional issue of the present invention, the addition of carbon particle with respect to adhesive agent 100 weight portions, is preferably the interior value of scope of 10～200 weight portions.

Through constituting in this wise, carbon particle is adhered to more equably to one one hair.

In addition, when constituting the painted hair dye of additional issue of the present invention, carbon particle preferably is made up of Linesless charcoal.

Like this, through using Linesless charcoal, can reproduce hair original natural color and luster more effectively as carbon particle.

In addition, when constituting the painted hair dye of additional issue of the present invention,, preferably contain the coloring agent beyond the carbon particle again as coloring agent.

Through constituting in this wise, can reproduce hair original natural color and luster more effectively, simultaneously, can also make it be applicable to the application target that fashion is dyed.

In addition, when constituting the painted hair dye of additional issue of the present invention, adhesive agent is preferably (methyl) alkyl acrylate copolymer.

Through constituting in this wise, continue to suppress to cause by adhering between the hair stiff in, carbon particle is adhered to one one hair securely.

In addition; When constituting the painted hair dye of additional issue of the present invention, (methyl) alkyl acrylate copolymer preferably contains the monomeric copolymer of (methyl) alkyl acrylate monomer and N-[2-(2-methyl-4-oxopentyl); And, preferably make amino alcohol that the carboxyl in this copolymer is carried out ester linkage.

Through constituting in this wise, because cohesivenesses etc. are preferably, thus carbon particle is adhered to one one hair securely, and on the other hand, in hair washing, can easily dispel the painted hair dye of additional issue.

In addition, when constituting the painted hair dye of additional issue of the present invention, solvent is preferably ethanol.

Like this, through using ethanol, coloring agent, adhesive agent are disperseed more equably as solvent.

In addition, when constituting the painted hair dye of additional issue of the present invention, the addition of solvent, with respect to adhesive agent 100 weight portions,

Be preferably the interior value of scope of 30～1,000 weight portion.

Through constituting in this wise, because the concentration of coloring agent, adhesive agent becomes suitable, so carbon particle is adhered to one one hair more equably.

In addition, another form of the present invention is to issue additional painted hair dye at the aerosol type that container contains coloring agent, adhesive agent, solvent, propellant, is to be that carbon particle is that the aerosol type of characteristic is issued additional painted hair dye with coloring agent.

That is: through being aerosol type, issuing additional painted hair dye and be smoke-like, so carbon particle is adhered to one one hair more equably by spraying.

In addition, when formation aerosol type of the present invention was issued additional painted hair dye, propellant was preferably dimethyl ether and oil liquefied gas, or its any one.

Through constituting in this wise, make the composition of the painted hair dye of additional issue not change, not only can be to pressurizeing in the container, but also can suppress harm to environment.

In addition, when formation aerosol type of the present invention was issued additional painted hair dye, the addition of propellant with respect to the capacity 100vol% of container, was preferably the interior value of scope of 30～85vol%.

Through constituting in this wise, the painted hair dye of additional issue that contains set carbon particle can be sprayed more equably.

[simple declaration of accompanying drawing]

[Fig. 1] (a)～(b) is the figure that is used to explain the difference of hair dyeing concentration.

[Fig. 2] Fig. 2 is the figure that is used to that the addition of coloring agent is described and improves the relation between the aesthetic feeling.

[Fig. 3] Fig. 3 is used to explain the addition of coloring agent and the figure of the relation between the hair dyeing concentration.

[Fig. 4] Fig. 4 is used to explain the addition of coloring agent and the figure of the relation between the resistance to water.

[Fig. 5] Fig. 5 is the figure that is used to explain in the bonding countermeasure of the carbon particle of spray nozzle lower end.

[Fig. 6] Fig. 6 is the figure that is used to explain the carbon particle manufacturing installation.

[explanation of symbol]

10: hair (being processed the back)

11: hair

12: carbon particle

12a～c: dust carrier

13: adhesive agent

20: aerosol type is issued additional painted hair dye

21: lid

22: jet

23: container

24: spray nozzle

25: stir ball

26: the lower end

27: the bottom surface

30: the carbon particle manufacturing installation

31: pulverizer

32: pressure fan

33: precipitron

34: the Linesless charcoal of not pulverizing

[optimal morphology that is used to carry out an invention]

[the 1st example]

The 1st example is the painted hair dye of additional issue that contains coloring agent, adhesive agent, solvent, is to be that carbon particle is the painted hair dye of additional issue of characteristic with coloring agent.

Below, just, distinguish each constitutive requirements as the painted hair dye of the additional issue of the 1st example, do bright specifically.

1. coloring agent

(1) kind

In the present invention, to use carbon particle to be characteristic as coloring agent.

Its reason is, because through using carbon particle as coloring agent, even saving or having reduced under the situation of use of the dust carrier that is made up of Pulvis Talci etc., also can pass through carbon particle self, improves the aesthetic feeling of hair effectively.

In addition, because can save or reduce the use of the dust carrier that is made up of Pulvis Talci etc., so can suppress effectively because the white or the gray color of this dust carrier self, becoming is difficult to the problem of having hair dyed according to set hair dyeing concentration.

Near and, because if carbon particle even descending with the situation of contact with moisture such as the antiperspirant that comes from scalp, rain, also can rely on the form and the characteristic of carbon particle, when suppressing effectively and stripping, the time and flow out.

That is: black different with carbon black or chain as the carbide of petroleum resinoid; If the carbon particle that derives from the natural material raw material is as coloring agent; Not only can reproduce Japanese hair original natural color and luster safely; Also because have set physical strength and proportion,, its dust carrier that seems chap is played a role as being used to so can one one apply hair.

Therefore; Can save or reduce the use of the dust carrier in the past that constitutes by Pulvis Talci etc.; Consequently; Can fundamentally solve because white of this dust carrier self or the influence of gray color, becoming is difficult to the problem of having hair dyed according to set hair dyeing concentration, can help stably to have hair dyed.

Near and, carbon particle not only color rendering properties is superior because have fine and close porous structure, the contact area with adhesive agent become big in, again because himself be water-insoluble, so can bring into play superior contact and resistance to water.Thus, even be exposed under the situation of moisture such as antiperspirant, also can suppress its stripping or outflow effectively at hair.

In addition; Even under the situation that for example carbon particle breaks away from from adhesive agent,, can adsorb moisture such as antiperspirant effectively because rely on its fine and close porous structure; So compare, can solve the problem that the moisture that contains coloring agent flows to face or vigorous neck effectively with coloring agent such as carbon black in the past.

In addition because carbon particle effectively moisture absorption issue additional moisture contained in the painted hair dye, so can expect to suppress the cohesion of composition silicon constituents etc. for example, that be easy to condense owing to moisture.

At this; Use Fig. 1; To when using carbon particle as coloring agent; Saved under the situation of use of the dust carrier in the past that constitutes by Pulvis Talci etc. (Fig. 1 (a)), and explained in the difference of using coloring agent such as carbon black and being used for carrying (Fig. 1 (b)) under the situation of dust carrier in the past that constitutes by Pulvis Talci etc. of holding this coloring agent as coloring agent.

At first, about improving aesthetic feeling, as from Fig. 1 (a) and (b) recognize, respectively through carbon particle 12 and dust carrier 12a～c, can make one one hair look chap.

Secondly,, recognize, because saved the use of the dust carrier in the past that constitutes by Pulvis Talci etc., so, can stably have hair dyed according to set hair dyeing concentration through carbon particle 12 at Fig. 1 (a) about hair dyeing concentration.

On the other hand, recognize at Fig. 1 (b), become inhomogeneous easily for the situation of holding of carrying of the coloring agent of the dust carrier 12a～c in the past that is made up of Pulvis Talci etc., the result is, obtains the set hair dyeing concentration difficulty that is easy to become.

Near and, Fig. 1 (a) and the words that (b) compare just can be recognized that the surperficial convex-concave of hair is variant.Infer its reason, probably be carbon particle 12 because its porous structure is easy to catch complicated unstable shape, consequently, compare with the situation of not using carbon particle 12 (10 '), the surperficial convex-concave of hair becomes big (10).

In a word, used the hair under the situation of carbon particle 12, be able to confirm than the feel chap of the reality of the hair under the situation of not using carbon particle 12.

Therefore; If the use shown in Fig. 1 (a) the painted hair dye of additional issue of carbon particle 12; Under directly visual situation,,, also can easily confirm the situation of adhering to hair 11 through the feel of hair even under directly not visual situation from needless to say.

In addition, like this, if the use shown in Fig. 1 (a) the painted hair dye of additional issue of carbon particle 12 because the surperficial convex-concave of hair becomes big, so the irregular reference of light appropriateness can be reproduced the color and luster and the sensation of hair original natural effectively.

Near and, the surperficial convex-concave through hair becomes big, even and be used for a nearly step and given under the situation of hair spray of colour developing or form retentivity, also can improve the tack of hair spray effectively.

As previously discussed, if words of the present invention,,, consequently, can access benefit miscellaneous so can save the use of the dust carrier in the past that constitutes by Pulvis Talci etc. because use carbon particle as coloring agent.

Therefore, in the present invention, preferably save the use of the dust carrier in the past that constitutes by Pulvis Talci etc., even under situation about using, preferably control its addition as much as possible.

Secondly; With Fig. 2～4; To when using carbon particle as coloring agent; Saved the painted hair dye of additional issue of the use of the dust carrier in the past that constitutes by Pulvis Talci etc.,, used as the raising aesthetic feeling in the painted hair dye of talcous additional issue of dust carrier, hair dyeing concentration and water-proof difference and explained with when using carbon black as coloring agent.

At first, in Fig. 2, transverse axis representes that the longitudinal axis representes to improve the characteristic curve of aesthetic feeling (relative evaluation) with respect to the addition of the coloring agent of adhesive agent 100 weight portions (weight portion).

In addition, characteristic curve A, (seeds: pine) as the characteristic curve under the situation of coloring agent, characteristic curve B is when using carbon black as coloring agent, uses Pulvis Talci as the characteristic curve under the situation of dust carrier to be to use carbon particle.Near and, characteristic curve C is when only using carbon black as coloring agent, does not use the characteristic curve under the situation of dust carrier.

At this, under the situation of characteristic curve B, with the addition of the blended mixed powder in carbon black/Pulvis Talci=30/100 (weight ratio), the addition that is regarded as coloring agent is described.

And, improve the relative evaluation of aesthetic feeling, be evaluation according to the raising aesthetic feeling of subject 10 people's subjectivity, the result who estimates according to following benchmark.

The 4:10 philtrum has 10 people to experience sufficient raising aesthetic feeling conscientiously.

The 3:10 philtrum has 7～9 people to experience sufficient raising aesthetic feeling conscientiously.

The 2:10 philtrum has 4～6 people to experience sufficient raising aesthetic feeling conscientiously.

The 1:10 philtrum has 0～3 people to experience sufficient raising aesthetic feeling conscientiously.

That is: as being understood from characteristic curve A, if used carbon particle as the painted hair dye of the additional issue of coloring agent, the addition with respect to the carbon particle of adhesive agent 100 weight portions adds more than about 10 weight portions, promptly possibly improve aesthetic feeling effectively.

In addition; As being understood from characteristic curve B; And used carbon black as coloring agent, with the painted hair dye of talcous additional issue as dust carrier in; Through making addition with respect to these mixture of adhesive agent 100 weight portions more than about 50 weight portions, also possibly improve aesthetic feeling more effectively.

On the other hand, C recognizes from characteristic curve, under the situation of only using carbon black as the painted hair dye of additional issue of coloring agent, improves aesthetic feeling and obviously becomes difficult.

Recognize through above result; No matter be to use carbon particle as the painted hair dye of the additional issue of coloring agent; Still and used carbon black as coloring agent, with the painted hair dye of talcous additional issue as dust carrier, about improving aesthetic feeling, all have superior effect.

And recognize on the other hand, using under the situation of carbon particle as coloring agent, even not and with dust carriers such as Pulvis Talci, also can improve aesthetic feeling effectively, and use under the situation of carbon black as coloring agent, then must and with dust carriers such as Pulvis Talci.

In addition, in Fig. 3, transverse axis representes with respect to the addition of the coloring agent of adhesive agent 100 weight portions (weight portion), the longitudinal axis represent the to have hair dyed characteristic curve of concentration (relative evaluation).

In addition, characteristic curve A, (seeds: pine) as the characteristic curve under the situation of coloring agent, characteristic curve B is when using carbon black as coloring agent, uses Pulvis Talci as the characteristic curve under the situation of dust carrier to be to use carbon particle.

In addition, about the definition of the addition of the coloring agent under the situation of characteristic curve B, identical with above-mentioned Fig. 2.

In addition, the relative evaluation of hair dyeing concentration is the evaluation according to the hair dyeing concentration of subject 10 people's subjectivity, the result who estimates according to following benchmark.

The 4:10 philtrum has 10 people to be judged as sufficient hair dyeing concentration.

The 3:10 philtrum has 7～9 people to be judged as sufficient hair dyeing concentration.

The 2:10 philtrum has 4～6 people to be judged as sufficient hair dyeing concentration.

The 1:10 philtrum has 0～3 people to be judged as sufficient hair dyeing concentration.

That is: as being understood from characteristic curve A; If used carbon particle as the painted hair dye of the additional issue of coloring agent; Addition with respect to the carbon particle of adhesive agent 100 weight portions is about more than the 10 weight portions, and hair dyeing concentration is improved sharp.

On the other hand; As being understood from characteristic curve B; And used carbon black as coloring agent, with the painted hair dye of talcous additional issue as dust carrier in; Even under the situation that the addition that makes these mixture increases, can make that also hair dyeing concentration reduces because of Pulvis Talci, so be difficult to had hair dyed fully concentration as dust carrier.

Recognize through above result; If used carbon particle as the painted hair dye of the additional issue of coloring agent; Hair dyeing concentration is improved effectively; And and used carbon black as coloring agent, with the painted hair dye of talcous additional issue as dust carrier in, even under the situation that its addition is increased, also be difficult to obtain set hair dyeing concentration.

Secondly, in Fig. 4, transverse axis representes that the longitudinal axis is represented the characteristic curve of resistance to water (relative evaluation) with respect to the addition of the coloring agent of adhesive agent 100 weight portions (weight portion).

In addition, water-proof relative evaluation is the hair to subject 1 people, will issue additional spraying of painted hair dye and drying after, 50 milliliters water is sprayed the result who estimates according to following benchmark with watering can.

4: the outflow of water of coloring agent of not confirmed stripping.

3: though in permissible range, be identified the outflow of water of coloring agent that only a small amount of stripping arranged.

2: if the degree that in extremely near distance, just can easily confirm, the outflow of water of coloring agent that has been identified stripping.

1: be identified the outflow of water of coloring agent that obviously stripping arranged.

That is: as being understood from characteristic curve A; If used carbon particle as the painted hair dye of the additional issue of coloring agent; With respect to the addition of the carbon particle of coloring agent 100 weight portions, the scope below about 200 weight portions promptly can stably keep resistance to water.

On the other hand; As being understood from characteristic curve B; And used carbon black as coloring agent, with the painted hair dye of talcous additional issue as dust carrier in, even under the few situation of the addition of these mixture, keep the sufficient resistance to water difficulty that also can become.

Recognize through above result,,, also can stably keep resistance to water in set scope even under the situation that the addition that makes carbon particle increases if used carbon particle as the painted hair dye of the additional issue of coloring agent.

And recognize on the other hand, and used carbon black as coloring agent, with the painted hair dye of talcous additional issue as dust carrier in, even its addition is in few scope, keeps set resistance to water also can become difficult.

In addition, carbon particle preferably is made up of wooden carbon.

Its reason is, because through using of the main constituent of wooden carbon as carbon particle, and can be more effectively and less expensive ground reproduction hair original natural color and luster.

That is: if the carbide of fibrous material wood carbon has even and tiny porous structure, not only in light weight, can also have the carbon particle in set scope averaged particles footpath through crushing operation or progressive operation, thereby easily obtain.Therefore, as less expensive coloring agent, even such as with the blended situation of aerosol type propellant under, also can disperse equably for a long time.

Consequently, can make the color and luster of hair finally reach more even, natural producing effects.

In addition, the carbon particle as beyond the wooden carbon does not have particular restriction, for example can be bamboo carbon, coconut carbon, coke, the smoked China ink of pine (resulting black carbon powder end when making burning such as Masson Pine) etc.

In addition, preferably Japan's medicine office is with the material of the certain quality standard of satisfying of square defined, i.e. medicinal charcoal.

Its reason is, because through using medicinal charcoal as carbon particle, can expect to make effects such as the health status of scalp is improved.

Near and, carbon particle preferably the method for the method through physics or chemistry by the material of porous materialization energetically, promptly so-called activated carbon.

Its reason is, through using activated carbon as carbon particle, because the contact area with adhesive agent is increased, so it is firmly fixed hair.In addition, if activated carbon can also be expected various benefits such as moisture sorption effect, deodorizing effect, nearly and in light weight effect.

In addition; Through using two polymethyl siloxanes etc. in advance to carrying out surface treatment in the surface of such carbon particle; Even under the situation about forming issuing additional painted hair dye as aerosol type; Also because can prevent the cohesion of carbon particle effectively, through for a long time it stably being sprayed, so be ideal form.

In addition, as coloring agent, preferably contain the coloring agent beyond the carbon particle again.

Its reason is, because as coloring agent, through containing the coloring agent beyond the carbon particle again, can reproduce the original color and luster of hair more effectively, simultaneously, can also make it be applicable to the application target that dyes as fashion.

That is: Japanese hair is not only merely to contain black pigment, also contains for example yellow and red pigments.

Therefore, the pigment through a nearly again step is contained yellow or redness etc. beyond carbon particle can reproduce the original color and luster of hair more effectively.

In addition,, can also dye, be applicable to that promptly the application target that dyes as so-called fashion also becomes possibility for the color and luster beyond the hair color through nearly one going on foot the coloring agent that contains beyond the carbon particle again.

Coloring agent as beyond this carbon particle does not have particular restriction, for example, as legal pigment (tar colorant), can be No. 2, redness, No. 203, blue color, No. 402, yellow, No. 201, brown, No. 401, green, No. 401, purple, No. 401, black etc.

In addition, as pigment, can be yellow titanium oxide, red ferric oxide, Black Rouge, ultramarine, dark purple, chromium oxide, carbon black, smithsonite, umber, humic acid, prepared Chinese ink etc.

In addition, as natural pigment, can be that phylloerythrin, quercetin, laccaic acid, chlorophyll, beet red, cacao color, curcumin, carminic acid, globulin, cuttlefish are black etc.

As the coloring agent of being put down in writing in the grand ceremonies such as pharmaceuticals, can be berberine hydrochloride, riboflavin, copper pheophytin Na, hematein, hematin, azulenes etc.

In addition, as painted adjuvant, also can be also with Alumen, aluminum sulfate, iron sulfate.

(2) count the averaged particles footpath

In addition, several averaged particles footpath of carbon particle is preferably the value in 2～200 mu m ranges.

Its reason is because directly be this scope through the averaged particles that makes carbon particle, when keeping improving aesthetic feeling, can also reproduce hair original natural color and luster.

That is: because if several averaged particles of carbon particle directly become the value of discontented 2 μ m, rely on the volume raising aesthetic feeling of carbon particle self to become difficult sometimes.On the other hand, if be because several averaged particles of carbon particle directly become the value that surpasses 200 μ m, its hair to one one adhered to equably become difficult, the color and luster that reproduces nature sometimes becomes difficult; Fully fixedly become difficult through adhesive agent, being easy to from the beginning sometimes, loss of hairs leaves.

Therefore, several averaged particles footpath of carbon particle, the value in 5～150 mu m ranges is better, the value in 10～100 mu m ranges is better.

On the other hand; Issuing additional as aerosol type under the situation that painted hair dye uses, for the time and prevent the obstruction of injection nozzle part effectively, the time and prevent the bonding in container; Several averaged particles footpath of carbon particle; Be preferably the value in 2～100 mu m ranges, the value in 3～80 mu m ranges is better, and the value in 5～30 mu m ranges is better.

In addition, about the assay method in several averaged particles footpath of these carbon particles etc., put down in writing in an embodiment.

In addition, use the carbon particle of the different plural number in number averaged particles footpath also to be advisable.

Its reason is because through using the carbon particle of the different plural number in number averaged particles footpath, can regulate the hair dyeing situation, to reproduce hair original natural color and luster more effectively.

In addition; Especially under the situation of issuing additional painted hair dye use as aerosol type, through using the carbon particle of the different plural number in number averaged particles footpath, the cohesion between the carbon particle of plural number is prevented from; Can the time and prevent the obstruction of injection nozzle part effectively, the time and prevent the bonding in container.

In addition, in carbon particle and under the situation with pigment etc., several averaged particles of these pigment etc. directly do not have particular restriction, but the value preferably in 0.01～10 mu m range, and the value in 0.05～2 mu m range is better.

(3) addition

In addition, the addition of carbon particle with respect to adhesive agent 100 weight portions, is preferably the value in 10～200 weight portion scopes.

Its reason is, because be this scope through the addition that makes carbon particle, carbon particle adhered to more equably to one one hair.

That is: because if the addition of carbon particle is the value of less than 3 weight portions, improves aesthetic feeling and become difficult sometimes.On the other hand, if be, in the time of between the carbon particle and overlapping unevenly, make carbon particle equably one one hair adhered to the difficulty that becomes sometimes because the addition of carbon particle surpasses 150 weight portions.

Therefore, the addition of carbon particle, with respect to adhesive agent 100 weight portions, the value in the scope of 30～180 weight portions is better, the value in the scope of 50～150 weight portions is better.

In addition, and situation with the coloring agent beyond the carbon particle under, the addition of these coloring agent; Do not have particular restriction; For example, desire is reproduced under the situation of general Japanese hair, with respect to carbon particle 100 weight portions; Be preferably the interior value of scope of 0.5～30 weight portion, the value in the scope of 1～20 weight portion is better.

2. adhesive agent

Adhesive agent in the present invention is to be used for as carbon particle of coloring agent etc. one one hair being adhered to and fixed material.

As this adhesive agent, preferably have set adhesion strength, and, preferably there is not overslaugh to come from the water white transparency sense of degree of the color coordination of coloring agent.

In addition, preferably be not easy dissolving with respect to moisture such as antiperspirant, on the other hand, when hair washing, the hydrophilic with the degree of can washing off.

As ideal adhesive agent, can be for example gloiopeltis, natural rubber, ester gum, degeneration paste, milk casein, polyethylene pyrrone, carboxy vinyl polymer, acrylic resin chain triacontanol amine solution, methoxy ethylene-maleic anhydride copolymer, polychlorostyrene dimethylated methylene phenylpiperidines, polymethacrylates, vinyl acetate. butenoic acid copolymer, carboxyl degeneration vinyl acetate copolymer etc.

In addition, as ideal especially adhesive agent, (methyl) alkyl acrylate copolymer of can giving an example out.

Its reason is because if (methyl) alkyl acrylate copolymer, continue to suppress to cause by adhering between the hair stiff in, carbon particle is adhered to one one hair securely.

That is: if the adhesive agent that constitutes by (methyl) alkyl acrylate copolymer; In the adhesive while with appropriateness; Because it is also very superior aspect light resistance, against weather and oil resistivity; Even so under the situation that has taken place to change in environments for use such as variation, or further and used under the situation of the hair spray that the market sells, carbon particle is adhered to securely to one one hair with weather.

In addition; In above-mentioned (methyl) alkyl acrylate copolymer; Also preferably contain the monomeric copolymer of (methyl) alkyl acrylate monomer and N-[2-(2-methyl-4-oxopentyl); And, preferably make amino alcohol that the carboxyl in this copolymer is carried out ester linkage and constitute (methyl) alkyl acrylate copolymer, promptly so-called acrylic resin chain triacontanol amine solution.

Its reason is, if so-called acrylic resin chain triacontanol amine solution, because cohesivenesses etc. are preferably; So carbon particle is adhered to one one hair securely; And on the other hand, in hair washing, can easily dispel the painted hair dye of additional issue.

3. solvent

(1) kind

In addition, as employed solvent in the present invention, can be for example ethanol, water, different alkane, acetone, N-Methyl pyrrolidone, butylene glycol, phenyl phenol, ethyl carbonate, the isopropyl alcohol etc. defended.

Wherein, ethanol preferably.

Its reason is, if ethanol is because coloring agent, adhesive agent are disperseed more equably.

That is: if ethanol because molecular weight and polarity are suitable, disperses so coloring agent, adhesive agent are distinguished effectively.

Near and, if ethanol, boiling point (under the atmospheric pressure, 78.4 ℃) is suitably being issued additional as aerosol type under the situation that painted hair dye uses, not only safe, volatility is good, with almost evaporation simultaneously of spraying, plays glutinous generation so can prevent hair.

(2) addition

In addition, the addition of solvent with respect to adhesive agent 100 weight portions, is preferably the value in 30～1, the 000 weight portion scope.

Its reason is, because be this scope through the addition that makes solvent, becomes suitable with the concentration of coloring agent, adhesive agent, and carbon particle is adhered to one one hair more equably.

That is: because if the addition of solvent becomes the value of less than 30 weight portions; The cohesiveness of issuing additional painted hair dye becomes excessive; Not only make carbon particle equably one one hair adhered to the difficulty that becomes, also becoming between the hair is easy to adhere to, and becomes stiff reason sometimes.On the other hand, if be, hair is applied both quantitative carbon particle and the adhesive agent difficulty that becomes sometimes effectively because the addition of solvent becomes the value of 1, the 000 weight portion of surpassing.

Therefore, the addition of solvent, with respect to adhesive agent 100 weight portions, the value in the scope of 50～800 weight portions is better, the value in the scope of 100～600 weight portions is better.

4. dust carrier

In addition, in the present invention,, add dust carrier and also be advisable if in both quantitative scopes.

This dust carrier is white and even gray powder, carry and hold coloring agent on one side, on one side hair is adhered to, be to be used for through making one one hair seem chap, thereby improve the material of aesthetic feeling effectively.

In the present invention, as the carbon particle of coloring agent,, also be possible so save the use of dust carrier because can bring into play function as this dust carrier.On the other hand, and with what do not have as the function of dust carrier, under the situation of the coloring agent beyond the carbon particle,, can use dust carrier in order to improve the color rendering properties of this coloring agent.

(1) kind

In addition; Kind as dust carrier; Not having particular restriction, can be for example silicon dioxide, magnesium silicate, Pulvis Talci, potter's clay, puddled soil, selenite, zinc oxide, titanium oxide, settleability calcium carbonate, calcium sulfate, whiting, pumice, Bombyx bombycis powder, powder crystallization cellulose, aleurone, Pilus Caprae seu Ovis powder, cotton fiber powder, paste, styrene resin foaming powder and urea resin powder etc.

(2) count the averaged particles footpath

In addition, several averaged particles footpath of dust carrier is preferably the value in 0.1～150 mu m range.

Its reason is because if several averaged particles of dust carrier directly become the value of discontented 0.1 μ m, to improve aesthetic feeling effectively and become difficult sometimes.On the other hand, if be that the color of dust carrier self causes exceedingly influencing to the color of hair sometimes because several averaged particles of dust carrier directly become the value that surpasses 150 μ m.

Therefore, several averaged particles footpath of dust carrier, the value in 1～100 mu m range is better, the value in 2～50 mu m ranges is better.

(3) addition

In addition, the addition of dust carrier, the addition that cans be compared to carbon particle most is few, more particularly, with respect to adhesive agent 100 weight portions, is preferably the value below the 3 weight portions.

Its reason is because be the value in this scope through the addition that makes dust carrier, when continuing the hair dyeing concentration that keeps set, can also improve the painted hair dyeing effect of additional issue that comes from the coloring agent beyond the carbon particle.

That is: because if the addition of dust carrier becomes the value above 3 weight portions, not having fully to carry the dust carrier of holding coloring agent excessively increases, and stably keeps hair dyeing concentration to become difficult sometimes.On the other hand, if the addition of dust carrier becomes too small value, bring into play its additive effect fully and become difficult sometimes.

Therefore, the addition of dust carrier, with respect to adhesive agent 100 weight portions, the value in the scope of 0.1～2 weight portion is better, the value in the scope of 0.5～1 weight portion is better.

5. other gradation composition

In addition, the gradation composition shown in preferably aptly below the adding.

(1) oil preparation

As paying the painted hair dye oil content of additional issue; In the hair colour developing of handling; Being used to bring into play as aerosol type and issuing additional the oil preparation that prevents effects such as stopping up under the situation that painted hair dye uses, can be for example Chinese toon oil, Semen Ricini oil, hydrogenation beef fat, lanoline, isotriacontane, Cera Flava, fluid paraffin wax, plant sterol, spermol, octadecanoid acid, tetradecanoic acid isopropyl, igneous rock, Sucker plucker, three sad (+)-2,3-Epoxy-1-propanols, two isostearic acids, two glycerol, phosphoric acid diglycerol, lactic acid hexadecanol, triethyl citrate etc.

(2) powder agent

In addition, as being used to pay various gradation composition dispersion effects in additional issue in the painted hair dye, in the hair of handling, being used to pay the powder agent of dry feeling etc., can be for example cyclodextrin, serine, Amihope LL (gourmet powder (strain)) etc.

(3) thickening agent

As being used for the viscosity of the painted hair dye of additional issue is improved; The dispersibility of carbon particle is improved; In the hair of handling, improving the thickening agent of aesthetic feeling, can be for example alginic acid ammonia Na, dibenzopyrans glue, cationization guar gum, hydroxy ethyl cellulose, carboxyl ethylene polymer etc.

(4) stabilizing agent

In addition, as the stabilizing agent of the viscosity that is used for keeping for a long time the painted hair dye of additional issue, can be for example sodium ascorbyl phosphate Mg, dextrin fatty acid ester, three polyphosphoric acid Na etc.

(5) interfacial agent

In addition; As in the painted hair dye of additional issue, being used to pay various gradation composition dispersion effects; In the hair of handling, being used to pay the interfacial agent of uniform hair dyeing sense etc., can be for example lecithin, Fructus Sapindi Mukouossi essence, collagen type interfacial agent, Poise C-80M etc. as natural type of interfacial agent.

In addition, can be for example alkylsurfuric acid Na, DBSA triethanolamine, polyoxyethylene (being designated hereinafter simply as POE) lauryl sulfate Na, POE coco-nut oil fatty acid amine sulfate, POE sulphonyl amber oil Na, N-coco-nut oil fatty acid-L-glutamate, Glu, N-acyl methyl taurine salt etc. as the cationic interfacial agent.

In addition, can be for example POE nonyl phenyl ether, POE sclerosis Semen Ricini oil, POE isocholesterol, (+)-2,3-Epoxy-1-propanol based oleic acid, sorbitan aluminium stearate, ten glycidyls, five isostearates etc. as nonionic class interfacial agent.

In addition, can be the stearic trimethyl ammonium chloride of chlorination cetyl trichlorine acute pyogenic infection of nails alkane, chloride laurylpyridine father-in-law, POE etc. for example as the anionic species interfacial agent.

In addition, can be the for example amino dipropionic acid Na of lauryl, lauryl dimethyl glycine Glycocoll betaine, Oleum Cocois alkyl-N-carboxy ethyl-N-hydroxyethyl imidazoline Glycocoll betaine Na etc. as sprocket class interfacial agent.

Near and, can be for example POE lauryl ether carboxylic acid, oleyl dimethyl oxidation amine etc. as polarity class interfacial agent.

(6) lubricant

In addition; As in the painted hair dye of additional issue, being used to pay various gradation composition dispersion effects; In the hair of handling, be used to pay uniform hair dyeing sense; Near and, be used to bring into play as aerosol type and issue additional the lubricant that prevents effects such as stopping up under the situation that painted hair dye uses, can be for example polyglycereol, silicone, degeneration silicone, Colophonium etc.

Wherein, as the two a kind of polymethyl siloxanes of silicone,, also can prevent the cohesion of carbon particle effectively, for a long time stable ejection even, issue additional as aerosol type under the situation of painted hair dye formation with the painted hair dye of additional issue of the present invention.

In addition, the addition of this lubricant with respect to adhesive agent 100 weight portions, is preferably the value in 0.1～30 weight portion scope, and the value in 1～20 weight portion scope is better.

(7) wetting agent

In addition, in the hair of handling, as the wetting agent that is used to pay so-called moist feeling, can be for example glycerol, 2-pyrrolidone-5-carboxylic acid's alkali, rare earth acid, Polyethylene Glycol, Aloe essence, panax ginseng extractum, when YAOJING etc.

(8) hair quality modifying agent

In addition, as the hair quality modifying agent in the hair of handling, can be for example hydrolytic collagen, polypeptide, cysteamine hydrochlorate, wool grease fatty acid, lecithin, ermine oil, mulberry is smart, zostera marina is smart, TGA etc.

(9) UV absorbent

In addition, as UV absorbent, can be for example cinoxate, hydroxy benzenes, secondary methoxy 2-Ethylhexyl cinnamate, secondary Methyl anthranilate etc. to the hair handled.

(10) nertralizer

In addition, as at the nertralizer of additional issue in the painted hair dye, can be for example hydrochloric acid, phosphoric acid, lactic acid, phytic acid, sodium hydroxide, ammonia, guanidine carbonate, amino methyl propanol, triethanolamine, morpholine etc.

(11) PH adjustment agent

In addition, as in the PH adjustment agent of additional issue in the painted hair dye, not having particular restriction, can be for example sodium carbonate, sodium succinate, sodium phosphate etc.

(12) ion blocks agent

In addition, as blocking agent, can be for example edetate, hydroxyl ethane phosphonic acids etc. at the ion of additional issue in the painted hair dye.

(13) spice

In addition, as spice, can be for example ethinyl estradiol, Flos Jasmini Sambac oil, rose water, natural perfume material, mediation spice, pyroligneous acid, caffein etc.

[the 2nd example]

The 2nd example is that the aerosol type that in container, comprises coloring agent, adhesive agent, solvent, propellant is issued additional painted hair dye, is to be that carbon particle is that the aerosol type of characteristic is issued additional painted hair dye with coloring agent.

That is: through being aerosol type, be smoke-like by injection, so carbon particle is adhered to one one hair more equably because issue additional painted hair dye.

Below, omit about the content of in the 1st example, explaining, be that the center describes with difference with the 1st example.

At first, as the employed container of spraying, not having particular restriction, can use known in the past spraying autoclave, generally is after in container, having filled content such as coloring agent, and it is ideal to mix compositions such as valve, button or lid again.

In addition, as shown in Figure 5 when composition aerosol type of the present invention is issued additional the container of painted hair dye, the distance L between the lower end 26 of spraying nozzle 24 and the bottom surface 27 of container 23 is the interior value of 0.1～2.5mm scope preferably.

Its reason is; Even because taking place in the lower end 26 of carbon particle at spraying nozzle 24 under the agglutinating situation; The lower end 26 of spraying nozzle 24 can not be pushed down with respect to the bottom surface 27 of container 23; Through keeping set interval to lay, be to become and be easy between the bottom surface 27 of the lower end 26 of spraying nozzle 24 and container, pass through in order to stir ball 25.

Consequently, keeping spraying nozzle 24 is being pushed open through stirring ball 25, between the bottom surface 27 of the lower end 26 of spraying nozzle 24 and container, pass through, is in order to make this carbon particle that has bondd redispersion effectively.

That is: because if this distance becomes the value of not enough 0.1mm; Make stir ball 25 between the bottom surface 27 of the lower end 26 of spraying nozzle 24 and container 23 through becoming difficult; Through with stir conflicting of ball 25, the bonding of adhering between the bottom surface 27 with the lower end 26 of this spraying nozzle 24 and container 23 carbon particle remove and become difficult sometimes.On the other hand, if be that the painted hair dye of residual additional issue that can not spray can exceedingly increase because this distance becomes the value above 2.5mm.

Therefore, the distance between the lower end of spraying nozzle and the bottom surface of container is that the value in 0.15～2mm scope is better, and the value in 0.2～1mm scope is better.

In addition, the propellant as using does not in the present invention have particular restriction, preferably dimethyl ether and oil liquefied gas, or its any one.

Its reason is because through using these compositions as propellant, need not make the composition of issuing additional painted hair dye to change, not only can in container, pressurize, can also suppress the harm to environment.

In addition, the addition of propellant, with respect to the capacity 100vol% of container, the value in 30～85vol% scope preferably.

Its reason is, is this scope through the addition that makes propellant, is because can the painted hair dye of additional issue be sprayed more equably.

If that is: because the addition of propellant becomes the value of not enough 30vol%, jet power is not enough, will issue additional painted hair dye and spray more equably and become difficult sometimes.On the other hand, if be that it is excessive that jet power becomes because the addition of propellant becomes the value above 85vol%, will issue additional painted hair dye and spray more equably and become difficult on the contrary sometimes, the easy sometimes turmoil of hair in use.

Therefore, the addition of propellant, with respect to the capacity 100vol% of container, the value in 40～80vol% scope is better, the value in 50～70vol% scope is better.

[embodiment]

[embodiment 1]

1. issue additional the manufacturing of painted hair dye

(1) manufacturing of carbon particle

(1)-1 pelletize

As shown in Figure 6, use the carbon particle manufacturing installation 30 that constitutes by pulverizer 31, pressure fan 32 and precipitron 33, with the Linesless charcoal of not pulverizing 34 (seeds: pine) make the carbon particle of set particle diameter.

More particularly,, drop into the Linesless charcoal of not pulverizing 34 of 1～2 long 80cm degree at every turn, pulverize until becoming the particle shape to pulverizer 31.Drive pressure fan 32 and precipitron 33 simultaneously with pulverizer 31, implemented this pulverizing.

In addition, in order to prevent the adverse current of carbon particle, under the 60% accumulative total state of not making illustrated air bag of in precipitron 33, being accommodated, changed new air bag into.

(1)-2 counts the mensuration in averaged particles footpath

In addition, use the combination of electron micrograph and portrait blood processor, measured several averaged particles footpath of carbon particle.

More particularly, after moving the photo of 30,000 times of multiplying powers that detection type ultramicroscope obtains carbon particle, use the CCD shooting after, the data of will draw a portrait are imported computer.Then, the general portrait process softwares such as WIN ROOF that use three paddy business (strain) to make, severals averaged particles of any carbon particle more than 100 of trying to achieve in the portrait to be mirrored are (major diameter) directly.Several averaged particles footpath as carbon particle.Resulting result is as shown in table 1.

(2) mix

With resulting carbon particle and other compositions, mix like following composition, obtain issuing additional the solution of painted hair dye.In addition, composition adding proportion (weight portion) separately is to be the value under the situation of 100 weight portions at adhesive agent.

(coloring agent)

Carbon particle 100 weight portions

(adhesive agent)

Acrylic resin chain triacontanol amine solution 100 weight portions

(mutual induction chemistry (strain) is made positive chi L-53)

(lubricant)

Two polymethyl siloxanes, 20 weight portions

(solvent)

99% ethanol, 260 weight portions

(3) fill

Then, with the solution of the painted hair dye of resulting additional issue with as the dimethyl ether of propellant, be filled into volume and be in 380 milliliters the spraying autoclave.In addition, the addition of the propellant of this moment, the volume 100vol% with respect to the spraying autoclave is 70vol%, the pressure in the spraying autoclave is 0.43MPa.

2. estimate

(1) evaluation of raising aesthetic feeling

Use resulting aerosol type to issue additional painted hair dye, carried out improving the evaluation of aesthetic feeling.

That is: resulting aerosol type is issued additional painted hair dye,, do not have the ground of omission and sprayed for 20 seconds subject 10 people's hair.

Then, estimate improving aesthetic feeling according to following benchmark.

◎: 10 philtrums have 10 people to experience sufficient raising aesthetic feeling conscientiously.

Zero: 10 philtrum has 7～9 people to experience sufficient raising aesthetic feeling conscientiously.

△: 10 philtrums have 4～6 people to experience sufficient raising aesthetic feeling conscientiously.

*: 10 philtrums have 0～3 people to experience sufficient raising aesthetic feeling conscientiously.

(2) evaluation of hair dyeing concentration

In addition, use resulting aerosol type to issue additional painted hair dye, carried out the evaluation of hair dyeing concentration.

Then, according to following benchmark hair dyeing concentration is estimated.

◎: 10 philtrums have 10 people to be judged as sufficient hair dyeing concentration.

Zero: 10 philtrum has 7～9 people to be judged as sufficient hair dyeing concentration.

△: 10 philtrums have 4～6 people to be judged as sufficient hair dyeing concentration.

*: 10 philtrums have 0～3 people to be judged as sufficient hair dyeing concentration.

(3) water-proof evaluation

In addition, use resulting aerosol type to issue additional painted hair dye, carried out water-proof evaluation.

That is: resulting aerosol type is issued additional painted hair dye,, do not have the ground of omission and sprayed for 20 seconds subject 1 people's hair.

Then, aerosol type issued additional the spraying of painted hair dye after, with the water of aerosol apparatus,, do not have the spraying of the ground of omission to the subject of natural drying after 1 minute hair with 50 milliliters.

Then, observe stripping the water of coloring agent whether flow out towards subject's forehead or neck, estimate according to following benchmark.

◎: the outflow of water of coloring agent of not confirmed stripping.

Zero: though in permissible range, be identified the outflow of water of coloring agent that only a small amount of stripping arranged.

△: if the degree that in extremely near distance, just can easily confirm, the outflow of water of coloring agent that has been identified stripping.

*: be identified the outflow of water of coloring agent that obviously stripping arranged.

[embodiment 2]

In embodiment 2, as shown in table 1, same with embodiment 1 except the several averaged particles with carbon particle directly become 50 μ m,, the manufacturing aerosol type estimates when issuing additional painted hair dye.Resulting result is as shown in table 2.

[embodiment 3]

In embodiment 3, as shown in table 1, same with embodiment 1 except the several averaged particles with carbon particle directly become 150 μ m,, the manufacturing aerosol type estimates when issuing additional painted hair dye.Resulting result is as shown in table 2.

[embodiment 4]

In embodiment 4, as shown in table 1, same with embodiment 1 except the several averaged particles with carbon particle directly become 1 μ m,, the manufacturing aerosol type estimates when issuing additional painted hair dye.Resulting result is as shown in table 2.

[embodiment 5]

In embodiment 5, as shown in table 1, same with embodiment 1 except the several averaged particles with carbon particle directly become 300 μ m,, the manufacturing aerosol type estimates when issuing additional painted hair dye.Resulting result is as shown in table 2.

[embodiment 6]

In embodiment 6; As shown in table 1, except as the coloring agent the carbon particle, further used outside red No. 202 2.5 weight portions and the yellow No. 401 1 weight portions; Same with embodiment 1,, the manufacturing aerosol type estimates when issuing additional painted hair dye.Resulting result is as shown in table 2.

[embodiment 7]

In embodiment 7; As shown in table 1, except as the coloring agent the carbon particle, further used outside red No. 202 20 weight portions and the yellow No. 401 10 weight portions; Same with embodiment 1,, the manufacturing aerosol type estimates when issuing additional painted hair dye.Resulting result is as shown in table 2.

[embodiment 8]

In embodiment 8, as shown in table 1, same except adhesive agent being become ethylene pyrrone/vinyl acetate copolymer with embodiment 1,, the manufacturing aerosol type estimates when issuing additional painted hair dye.Resulting result is as shown in table 2.

[embodiment 9]

In embodiment 9, as shown in table 1, same with embodiment 1 except not using two polymethyl siloxanes as lubricant,, the manufacturing aerosol type estimates when issuing additional painted hair dye.Resulting result is as shown in table 2.

[embodiment 10]

In embodiment 10, as shown in table 1, except the activated carbon that carbon particle become several averaged particles footpath 5 μ m (seeds: same pine) with embodiment 1, estimate when aerosol type is issued additional painted hair dye making.Resulting result is as shown in table 2.

[embodiment 11]

In embodiment 11, as shown in table 1, same with embodiment 1 except the bamboo carbon that carbon particle is become several averaged particles footpath 5 μ m,, the manufacturing aerosol type estimates when issuing additional painted hair dye.Resulting result is as shown in table 2.

[comparative example 1]

In comparative example 1; As shown in table 1; Except not using carbon particle, replace and use carbon black 30 weight portions and as severals averaged particles of dust carrier directly outside the Pulvis Talci 100 weight portions of 5 μ m as coloring agent; Same with embodiment 1,, the manufacturing aerosol type estimates when issuing additional painted hair dye.Resulting result is as shown in table 2.

[comparative example 2]

In comparative example 2, as shown in table 1, except not using carbon particle, replace and use outside the carbon black 100 weight portions as coloring agent, same with embodiment 1,, the manufacturing aerosol type estimates when issuing additional painted hair dye.Resulting result is as shown in table 2.

[table 1]

[table 2]

	Improve aesthetic feeling	Hair dyeing concentration	Resistance to water
				Embodiment
1	◎	◎	◎
				Embodiment 2	◎	◎	◎
Embodiment 3	◎	◎	○
				Embodiment 4	○	◎	○
Embodiment 5	◎	◎	△
				Embodiment 6	◎	◎	◎
Embodiment 7	◎	◎	○
				Embodiment 8	◎	◎	◎
Embodiment 9	◎	○	◎
				Embodiment 10	◎	◎	◎
Embodiment 11	◎	◎	◎
				Comparative example 1	◎	×	×
Comparative example 2	×	○	×

[utilizing on the industry probability]

If the painted hair dye of the additional issue that the present invention was correlated with and used the aerosol type of the painted hair dye of this additional issue to issue additional painted hair dye; In the painted hair dye of additional issue; Through using carbon particle as coloring agent; Bring into play superior resistance to water and color rendering properties, just become and to stablize and according to set hair dyeing concentration hair is had hair dyed chronically.

In addition, rely on carbon particle self, can improve aesthetic feeling effectively as coloring agent, near and, rely on superior water absorption that this carbon particle has etc., even with the situation of contact with moisture such as antiperspirant under, also become and can suppress stripping and outflow effectively.

Therefore, the painted hair dye of additional issue according to the present invention and used the aerosol type of the painted hair dye of this additional issue to issue additional painted hair dye becomes not because of factor affecting such as environments for use, can stably keep the state and the color and luster situation of hair.

In addition; The painted hair dye of the additional issue that the present invention was correlated with is not limited only to aerosol type and issues additional painted hair dye, through the kind and the use level of appropriate change adhesive agent; Because resistance to water and color rendering properties are superior, use emulsifiable paste so be applicable to also that poliosis dyes with emulsifiable paste or eyelashes correction.

Claims

1. an aerosol type is issued additional painted hair dye, it is characterized in that, is to issue additional painted hair dye at the aerosol type that container contains coloring agent, adhesive agent, solvent and propellant, and said coloring agent is a carbon particle,

And several averaged particles of said carbon particle directly are the interior value of scope of 2～100 μ m; The addition of said carbon particle with respect to said adhesive agent 100 weight portions, is the value in the scope of 10～200 weight portions,

And said carbon particle is a bamboo carbon.

2. aerosol type according to claim 1 is issued additional painted hair dye, wherein, as said coloring agent, further contains the coloring agent beyond the carbon particle.

3. aerosol type according to claim 1 is issued additional painted hair dye, and wherein, said adhesive agent is (methyl) alkyl acrylate copolymer.

4. aerosol type according to claim 3 is issued additional painted hair dye; Wherein, Said (methyl) alkyl acrylate copolymer; Be to contain (methyl) alkyl acrylate monomer and the monomeric copolymer of N-[2-(2-methyl-4-oxopentyl), and, make amino alcohol carry out ester linkage and form the carboxyl in this copolymer.

5. aerosol type according to claim 1 is issued additional painted hair dye, and wherein, said solvent is an ethanol.

6. aerosol type according to claim 1 is issued additional painted hair dye, and wherein, the addition of said solvent with respect to above-mentioned adhesive agent 100 weight portions, is the value in the scope of 30～1,000 weight portion.

7. aerosol type according to claim 1 is issued additional painted hair dye, and wherein, said propellant is dimethyl ether and oil liquefied gas, or wherein any one.

8. aerosol type according to claim 1 is issued additional painted hair dye, and wherein, the addition of said propellant with respect to the capacity 100vol% of said vesse, is the interior value of scope of 30～85vol%.