CN101787188A - 阻燃pc/hips复合材料及其制备方法 - Google Patents
阻燃pc/hips复合材料及其制备方法 Download PDFInfo
- Publication number
- CN101787188A CN101787188A CN200910105327A CN200910105327A CN101787188A CN 101787188 A CN101787188 A CN 101787188A CN 200910105327 A CN200910105327 A CN 200910105327A CN 200910105327 A CN200910105327 A CN 200910105327A CN 101787188 A CN101787188 A CN 101787188A
- Authority
- CN
- China
- Prior art keywords
- parts
- matrix material
- polystyrene
- polycarbonate
- hips
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920005669 high impact polystyrene Polymers 0.000 title claims abstract description 73
- 239000004797 high-impact polystyrene Substances 0.000 title claims abstract description 73
- 238000002360 preparation method Methods 0.000 title claims abstract description 26
- 239000003063 flame retardant Substances 0.000 title claims abstract description 20
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title abstract description 7
- 239000002131 composite material Substances 0.000 title abstract description 5
- 239000004417 polycarbonate Substances 0.000 claims abstract description 68
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 57
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000002994 raw material Substances 0.000 claims abstract description 26
- 239000004793 Polystyrene Substances 0.000 claims abstract description 25
- 229920002223 polystyrene Polymers 0.000 claims abstract description 25
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 7
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 7
- 238000007605 air drying Methods 0.000 claims abstract description 6
- 238000005303 weighing Methods 0.000 claims abstract description 6
- 239000011159 matrix material Substances 0.000 claims description 37
- 239000004609 Impact Modifier Substances 0.000 claims description 14
- 239000003112 inhibitor Substances 0.000 claims description 11
- 239000000314 lubricant Substances 0.000 claims description 11
- 230000003647 oxidation Effects 0.000 claims description 11
- 238000007254 oxidation reaction Methods 0.000 claims description 11
- 239000011258 core-shell material Substances 0.000 claims description 10
- -1 metaborate Chemical compound 0.000 claims description 10
- 239000012752 auxiliary agent Substances 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 9
- 238000012545 processing Methods 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 6
- 239000007822 coupling agent Substances 0.000 claims description 5
- 238000005469 granulation Methods 0.000 claims description 5
- 230000003179 granulation Effects 0.000 claims description 5
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 4
- CMQUQOHNANGDOR-UHFFFAOYSA-N 2,3-dibromo-4-(2,4-dibromo-5-hydroxyphenyl)phenol Chemical compound BrC1=C(Br)C(O)=CC=C1C1=CC(O)=C(Br)C=C1Br CMQUQOHNANGDOR-UHFFFAOYSA-N 0.000 claims description 3
- 150000007970 thio esters Chemical class 0.000 claims description 3
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 2
- 229920000402 bisphenol A polycarbonate polymer Polymers 0.000 claims description 2
- 238000000354 decomposition reaction Methods 0.000 claims description 2
- 239000003822 epoxy resin Substances 0.000 claims description 2
- 239000002530 phenolic antioxidant Substances 0.000 claims description 2
- 150000008301 phosphite esters Chemical group 0.000 claims description 2
- 229920000647 polyepoxide Polymers 0.000 claims description 2
- 239000002671 adjuvant Substances 0.000 abstract 2
- 238000007580 dry-mixing Methods 0.000 abstract 1
- 229920009204 Methacrylate-butadiene-styrene Polymers 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 8
- ZJOLCKGSXLIVAA-UHFFFAOYSA-N ethene;octadecanamide Chemical compound C=C.CCCCCCCCCCCCCCCCCC(N)=O.CCCCCCCCCCCCCCCCCC(N)=O ZJOLCKGSXLIVAA-UHFFFAOYSA-N 0.000 description 8
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical class C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 5
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 4
- 229910052794 bromium Inorganic materials 0.000 description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 4
- 239000003999 initiator Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical class OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 229920006351 engineering plastic Polymers 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 235000019260 propionic acid Nutrition 0.000 description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- VEORPZCZECFIRK-UHFFFAOYSA-N 3,3',5,5'-tetrabromobisphenol A Chemical compound C=1C(Br)=C(O)C(Br)=CC=1C(C)(C)C1=CC(Br)=C(O)C(Br)=C1 VEORPZCZECFIRK-UHFFFAOYSA-N 0.000 description 1
- 241000024287 Areas Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920007019 PC/ABS Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 1
- GHPGOEFPKIHBNM-UHFFFAOYSA-N antimony(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Sb+3].[Sb+3] GHPGOEFPKIHBNM-UHFFFAOYSA-N 0.000 description 1
- 230000031709 bromination Effects 0.000 description 1
- 238000005893 bromination reaction Methods 0.000 description 1
- WWNGFHNQODFIEX-UHFFFAOYSA-N buta-1,3-diene;methyl 2-methylprop-2-enoate;styrene Chemical compound C=CC=C.COC(=O)C(C)=C.C=CC1=CC=CC=C1 WWNGFHNQODFIEX-UHFFFAOYSA-N 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical group C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- PWWSSIYVTQUJQQ-UHFFFAOYSA-N distearyl thiodipropionate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCCCCCC PWWSSIYVTQUJQQ-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- GLDOVTGHNKAZLK-UHFFFAOYSA-N n-octadecyl alcohol Natural products CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- WUUHFRRPHJEEKV-UHFFFAOYSA-N tripotassium borate Chemical class [K+].[K+].[K+].[O-]B([O-])[O-] WUUHFRRPHJEEKV-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
物理性能 | 单位 | 测试方法 |
熔融指数 | g/10min | ASTM D1238 |
拉伸强度 | MPa | ASTM D638 |
断裂伸长率 | % | ASTM D638 |
弯曲强度 | MPa | ASTM D790 |
弯曲模量 | MPa | ASTM D790 |
Izod缺口冲击强度 | J/m | ASTM D256 |
燃烧性 | UL94 |
组成 | 实施例1 | 实施例2 | 实施例3 | 实施例4 | 实施例5 | 实施例6 |
PC | 77 | 75 | 70 | 69.5 | 66.5 | 68 |
HIPS | 5 | 5 | 10 | 12 | 15 | 12 |
增韧剂(C223A) | 4 | 4 | 4 | 4 | 4 | 4 |
阻燃剂(BEO) | 9 | 9 | 9 | 9 | 9 | 9 |
组成 | 实施例1 | 实施例2 | 实施例3 | 实施例4 | 实施例5 | 实施例6 |
阻燃增效剂(Sb2O3) | 3 | 3 | 3 | 3 | 3 | 3 |
相容剂 | 1 | 3 | 3 | 1.5 | 3 | 3 |
1010 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 |
168 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 | 0.2 |
加工助剂(润滑剂、偶联剂) | 0.6 | 0.6 | 0.6 | 0.6 | 0.6 | 0.6 |
缺口冲击强度(J/m) | 369 | 390 | 351 | 324 | 309 | 335 |
熔融指数(g/10min) | 27 | 31 | 33.4 | 35 | 39 | 37 |
拉伸强度(MPa) | 59 | 56.4 | 53.31 | 54.72 | 56.3 | 55.1 |
断裂伸长率(%) | 64 | 67 | 58 | 55.3 | 48.7 | 53 |
弯曲强度(MPa) | 59 | 60.4 | 57.1 | 55.4 | 51.8 | 56.9 |
弯曲模量(MPa) | 2370 | 2394 | 2310 | 2285 | 2217 | 2307 |
燃烧性UL94(1.6mm) | V0 | V0 | V0 | V0 | V0 | V0 |
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2009101053274A CN101787188B (zh) | 2009-02-06 | 2009-02-06 | 阻燃pc/hips复合材料及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2009101053274A CN101787188B (zh) | 2009-02-06 | 2009-02-06 | 阻燃pc/hips复合材料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101787188A true CN101787188A (zh) | 2010-07-28 |
CN101787188B CN101787188B (zh) | 2012-05-23 |
Family
ID=42530572
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2009101053274A Expired - Fee Related CN101787188B (zh) | 2009-02-06 | 2009-02-06 | 阻燃pc/hips复合材料及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN101787188B (zh) |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102532855A (zh) * | 2012-02-15 | 2012-07-04 | 沈阳科通塑胶有限公司 | 一种聚碳酸酯注塑级增韧剂、增韧聚碳酸酯及聚碳酸酯注塑级增韧剂的制备方法 |
CN103554875A (zh) * | 2013-10-25 | 2014-02-05 | 安徽省富光实业股份有限公司 | 一种水杯壳体用耐刮伤耐磨损聚碳酸酯材料及其制备方法 |
CN104086971A (zh) * | 2014-07-15 | 2014-10-08 | 宁波浙铁大风化工有限公司 | 一种高流动性阻燃聚碳酸酯-聚苯乙烯组合物及其制备方法 |
CN104672878A (zh) * | 2015-02-12 | 2015-06-03 | 四川长虹电器股份有限公司 | 聚碳酸酯树脂/聚苯乙烯树脂合金材料及制备方法 |
EP2957595A1 (de) * | 2014-06-18 | 2015-12-23 | Basf Se | Flammschutzmittelzusammensetzung zur Verwendung in Styrolpolymerschaumstoffen |
CN105820529A (zh) * | 2015-12-31 | 2016-08-03 | 宁波能之光新材料科技有限公司 | 一种聚碳酸酯与聚苯乙烯合金材料及其制备方法 |
CN106279770A (zh) * | 2016-08-26 | 2017-01-04 | 大连盖特科技发展有限公司 | 含复合高分子偶联剂的活性镁系阻燃剂 |
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CN108129821A (zh) * | 2017-12-07 | 2018-06-08 | 东莞市高能高分子材料有限公司 | 一种耐腐蚀高刚性的聚碳酸酯改性塑料及其制备方法 |
CN108752775A (zh) * | 2018-06-20 | 2018-11-06 | 安徽江淮汽车集团股份有限公司 | 一种阻燃导热回收ps复合材料及其制备方法 |
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-
2009
- 2009-02-06 CN CN2009101053274A patent/CN101787188B/zh not_active Expired - Fee Related
Cited By (25)
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CN102532855A (zh) * | 2012-02-15 | 2012-07-04 | 沈阳科通塑胶有限公司 | 一种聚碳酸酯注塑级增韧剂、增韧聚碳酸酯及聚碳酸酯注塑级增韧剂的制备方法 |
CN102532855B (zh) * | 2012-02-15 | 2013-06-19 | 沈阳科通塑胶有限公司 | 一种聚碳酸酯注塑级增韧剂、增韧聚碳酸酯及聚碳酸酯注塑级增韧剂的制备方法 |
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