CN101781416A - Negative ion high-pressure hose and preparation method thereof - Google Patents
Negative ion high-pressure hose and preparation method thereof Download PDFInfo
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- CN101781416A CN101781416A CN 201010130550 CN201010130550A CN101781416A CN 101781416 A CN101781416 A CN 101781416A CN 201010130550 CN201010130550 CN 201010130550 CN 201010130550 A CN201010130550 A CN 201010130550A CN 101781416 A CN101781416 A CN 101781416A
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Abstract
The invention relates to a negative ion high-pressure hose and a preparation method thereof, and the preparation method is characterized by comprising the following steps: mixing 100 parts by weight of crude rubber, 2-4 parts by weight of zinc oxide, 0.5-1.5 parts by weight of stearic acid, 55-65 parts by weight of carbon black N770, 55-60 parts by weight of stearic pot clay, 18-22 parts by weight of plasticizer POP, 4-6 parts by weight of tackifying resin, 1-2 parts by weight of accelerator CZ, 0.2-0.4 part by weight of accelerator D, 1-2 parts by weight of sulphur, 0.8-1.2 part by weight of chalked cross-linking agent TAIC, 0.3-0.6 part by weight of antiager BLE and 1-3 parts by weight of negative ion powder, mixedly compressing, extruding with skeletons, moulding, and vulcanizing to obtain the product. The obtained product has the advantages and effects of possessing anti-static function, preventing feed liquor from corrosion, removing odor from odorous feed liquor, purifying air and resisting electromagnetic radiation, and having high temperature resistance and high pressure resistance.
Description
Technical field
The present invention relates to a kind of negative ion high-pressure hose, be mainly used in oil, water or the liquid of mining industry, machinery, chemical industry, oil, automobile and other industries output high pressure-temperature, belong to rubber item.
The invention still further relates to the preparation method of this negative ion high-pressure hose.
Background technology
Present high-pressure rubber pipe can be withstand voltage high temperature resistant, but do not possess electrostatic-proof function, can not prevent that feed liquid from getting rusty, more can not eliminate the peculiar smell of taste substance liquid and can not purify air etc., so function singleness, and kind is few.
Summary of the invention
Thereby purpose of the present invention just for the shortcoming that overcomes above-mentioned prior art with not enough and provide a kind of function negative ion high-pressure hose how wide in variety can have electrostatic-proof function, prevent that feed liquid from getting rusty, eliminating the peculiar smell of taste substance liquid, purifying air and the multi-functional product of anti-electromagnetic radiation.
The present invention also provides the preparation method of this negative ion high-pressure hose.
The objective of the invention is to realize by following technical proposal:
A kind of negative ion high-pressure hose, it adopts the following weight proportion raw material to make:
100 parts of rubbers
2～4 parts in zinc oxide
0.5～1.5 part of stearic acid
55～65 parts of carbon black N770
55～60 parts in stearic potter's clay
18～22 parts of plasticizer P OP
4～6 parts of tackifying resins
1～2 part of accelerant CZ
0.2～0.4 part of vulkacit D
1～2 part in sulphur
0.8～1.2 part of efflorescence linking agent TAIC
0.3～0.6 part of protective agent BLE
1～3 part of negative ion powder.
Described raw material also can be the negative ion powder that adds above-mentioned various rubber weight 1～3% in natural rubber, reclaimed rubber, isoprene-isobutylene rubber, ethylene-propylene rubber(EPR) or the silicon rubber.
The manufacture method of described negative ion high-pressure hose, with rubber 100 weight parts, zinc oxide 2～4 weight parts, stearic acid 0.5～1.5 weight part, carbon black N770 55～65 weight parts, stearic potter's clay 55～60 weight parts, plasticizer P OP 18～22 weight parts, tackifying resin 3～6 weight parts, accelerant CZ 1～2 weight part, vulkacit D 0.2～0.4 weight part, sulphur 1～2 weight part, efflorescence linking agent TAIC 0.8～1.2 weight part, protective agent BLE 0.3～0.6 weight part and negative ion powder 1～3 weight part carry out mixed pressure after mixing, extrude with skeleton, moulding, sulfuration obtains product.
Described negative ion high-pressure hose manufacture method, the blank that is pressed into natural rubber, reclaimed rubber, isoprene-isobutylene rubber, ethylene-propylene rubber(EPR) or silicon rubber, behind two-sided 1～3% negative ion powder that all practise to apply above-mentioned various rubber weight of stock, carry out mixed pressure again, extrude with skeleton, moulding, sulfuration, obtain product.。
When negative ion high-pressure hose of the present invention adopts rubber, can add 1～3 part of zinc oxide 2～4 weight parts, stearic acid 0.5～1.5 weight part, carbon black N770 55～65 weight parts, stearic potter's clay 55-60 weight part, plasticizer P OP 18～22 weight parts, tackifying resin 3-6 weight part, accelerant CZ 1～2 weight part, vulkacit D 0.2～0.4 weight part, sulphur 1～2 weight part, efflorescence linking agent TAIC 0.8～1.2 weight part, protective agent BLE 0.3-0.6 weight part and negative ion powder, wherein zinc oxide English name Zineoxide; Zine white, another name zinc white; Zinc white molecular formula ZnO outward appearance and proterties white hex crystal or powder, the stopping composition of odorlessness, rubber; The stearic acid chemical name: octadecanoic acid claims again: stearic acid; Octadecanoic acid; English name: Stearic acid; Octadecanoic acid, Triple Pressed Stearic Acid molecular formula: C18H36O2; CH3 (CH2) 16COOH, molecular weight: 284.48, be thiofide; Carbon black is a strengthening agent, has medium reinforcing property; Hard (china) clay has half strengthening action in rubber, can improve mechanical properties of vulcanizate, and plasticizer P OP is a softening agent; Tackifying resin has good polymer phase capacitive.Be used as tackifier, accelerant CZ molecular formula C13H16N2S2, chemical name N-cyclohexyl-2-benzothiazole sulfonamide in the rubber item industry, be the active aftereffect industrial rubber articles of a kind of height promotor, scorching quality is good, process safety, and curing time is short.Promoter action is very strong when curing temperature is more than 138 ℃; But vulkacit D is rubber accelerator, sulphur accelerated cure speed, the crosslinked linking agent TAIC of efflorescence, and molecular weight: 249.27, room temperature (25 ℃) is colourless liquid or hexagonal flake xln, is the cocuring agent of multiple specialty elastomer.Antioxidant BLE is a kind of general purpose rubber anti-aging agent.To heat, oxygen, deflect, fatigue aging has good protective benefits, is used for industrial rubber articles, to improving adhesion of rubber to metal power effect unique arranged.Negative ion powder is the principle that human use's nature produces negative ion, and a kind of composite minerals of synthetic or proportioning generally all is tourmaline powder+lanthanon or rare earth element, passes through the nanotechnology elaborate by natural materials.Scientific research shows, negative ion powder keeps energetic to human body and human residential environment's improvement is had great help.The characteristics of these series product be natural, tasteless, nontoxic, safety performance is good.Composition is to be the aluminium of feature with the boracic, sodium, iron, the silicate material of lithium ring texture, isomorph is grown, because of its pyroelectricity and piezoelectricity, make its polarity ion cause that in the equilibrium theory of tide vibration moment of dipole changes the electromagnetic radiation that produces far infrared band, if add to by a certain percentage by (for example fiber) in the product, make its free ion by self, impurity ion and ionic substance, impurity and two, three phonon sympathetic responses produce radiation, affect ionic linkage polarity vibration organic and the inorganic molecule interlinkage, having formed stronger radiation broadband, is more than 90% according to the test anion powder to far emittance.The far infrared performance of anion powder has the effect that purifies air, eliminates human-body fatigue, promotes health to the health care of human body.In addition, these series product also have antibacterial, degermation, and have tangible deodorization functions.This product can be used for fiber, when weaving clothing and be worn in the person with this, can excite negative ion to human body continuously, makes human body keep energetic; Can constantly be human body again on the other hand, negative ion powder can absorb the peculiar smell that product sent such as paint, colloid.
Add 1～3% negative ion powder of above-mentioned various glue weight at natural rubber, reclaimed rubber, isoprene-isobutylene rubber, ethylene-propylene rubber(EPR) or silicon rubber, can reach effect same.
Because taking technique scheme to make the present invention and technology compare product to have electrostatic-proof function, prevent feed liquid gets rusty, eliminates the peculiar smell of taste substance liquid, purifies air and the advantage and the effect of the multiple efficacies of anti-electromagnetic radiation, high temperature high voltage resistant.
Embodiment
Embodiment 1
With rubber 100kg, zinc oxide 2kg, stearic acid 1.5kg, carbon black N770 55kg, stearic potter's clay 60kg, plasticizer P OP 18kg, tackifying resin 6kg, accelerant CZ 2kg, vulkacit D 0.2kg, sulphur 2kg, efflorescence linking agent TAIC 0.8kg, protective agent BLE 0.6kg and negative ion powder 1kg, carry out mixed pressure after the mixing, extrude with skeleton, moulding, sulfuration, obtain product.
Embodiment 2
With rubber 100kg, zinc oxide 3kg, stearic acid 1.0kg, carbon black N770 60kg, stearic potter's clay 58kg, plasticizer P OP 20kg, tackifying resin 5kg, accelerant CZ 1.5kg, vulkacit D 0.3kg, sulphur 1.5kg, efflorescence linking agent TAIC 1.0kg, protective agent BLE 0.4kg and negative ion powder 2kg, carry out mixed pressure after the mixing, extrude with skeleton, moulding, sulfuration, obtain product.
Embodiment 3
With rubber 100kg, zinc oxide 4kg, stearic acid 0.5kg, carbon black N770 65kg, stearic potter's clay 55kg, plasticizer P OP 22kg, tackifying resin 4kg, accelerant CZ 1kg, vulkacit D 0.4kg, sulphur 1kg, efflorescence linking agent TAIC 1.2kg, protective agent BLE 0.3kg and negative ion powder 3kg, carry out mixed pressure after the mixing, extrude with skeleton, moulding, sulfuration, obtain product.
Embodiment 4
Get natural rubber 100kg and be pressed into blank, in that stock is two-sided carries out mixed pressure after all practise applying the 1kg negative ion powder, extrude with skeleton, moulding, sulfuration, obtain product again.
Embodiment 5
Get reclaimed rubber 100kg and be pressed into blank, in that stock is two-sided carries out mixed pressure after all practise applying the 2kg negative ion powder, extrude with skeleton, moulding, sulfuration, obtain product again.
Embodiment 6
Get ethylene-propylene rubber(EPR) 100kg and be pressed into blank, in that stock is two-sided carries out mixed pressure after all practise applying the 3kg negative ion powder, extrude with skeleton, moulding, sulfuration, obtain product again.
Claims (4)
1. negative ion high-pressure hose is characterized in that its adopts following weight proportion raw material to make:
100 parts of rubbers
2～4 parts in zinc oxide
0.5～1.5 part of stearic acid
55～65 parts of carbon black N770
55～60 parts in stearic potter's clay
18～22 parts of plasticizer P OP
4～6 parts of tackifying resins
1～2 part of accelerant CZ
0.2～0.4 part of vulkacit D
1～2 part in sulphur
0.8～1.2 part of efflorescence linking agent TAIC
0.3～0.6 part of protective agent BLE
1～3 part of negative ion powder.
2. negative ion high-pressure hose according to claim 1 is characterized in that raw material also can be the negative ion powder that adds above-mentioned various rubber weight 1～3% in natural rubber, reclaimed rubber, isoprene-isobutylene rubber, ethylene-propylene rubber(EPR) or the silicon rubber.
3. the manufacture method of the described negative ion high-pressure hose of root a tree name claim 1, it is characterized in that rubber 100 weight parts, zinc oxide 2～4 weight parts, stearic acid 0.5～1.5 weight part, carbon black N77055～65 weight parts, stearic potter's clay 55～60 weight parts, plasticizer P OP 18～22 weight parts, tackifying resin 3～6 weight parts, accelerant CZ 1～2 weight part, vulkacit D 0.2～0.4 weight part, sulphur 1～2 weight part, efflorescence linking agent TAIC 0.8～1.2 weight part, protective agent BLE 0.3～0.6 weight part and negative ion powder 1～3 weight part carry out mixed pressure after mixing, extrude with skeleton, moulding, sulfuration obtains product.
4. as negative ion high-pressure hose manufacture method as described in the claim 2, it is characterized in that the blank that is pressed into natural rubber, reclaimed rubber, isoprene-isobutylene rubber, ethylene-propylene rubber(EPR) or silicon rubber, behind two-sided 1～3% negative ion powder that all practise to apply above-mentioned various rubber weight of stock, carry out mixed pressure again, extrude with skeleton, moulding, sulfuration, obtain product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101305507A CN101781416B (en) | 2010-03-24 | 2010-03-24 | Negative ion high-pressure hose and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010101305507A CN101781416B (en) | 2010-03-24 | 2010-03-24 | Negative ion high-pressure hose and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN101781416A true CN101781416A (en) | 2010-07-21 |
| CN101781416B CN101781416B (en) | 2011-09-07 |
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| CN2010101305507A Expired - Fee Related CN101781416B (en) | 2010-03-24 | 2010-03-24 | Negative ion high-pressure hose and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103059423A (en) * | 2012-11-14 | 2013-04-24 | 安徽江威精密制造有限公司 | Tension-resistant rubber wrapping material for capacitor housing |
| CN103102601A (en) * | 2012-11-13 | 2013-05-15 | 铜陵亿亨达电子有限责任公司 | Alkali-resistant capacitor case rubber wrapping material |
| CN104277460A (en) * | 2014-10-22 | 2015-01-14 | 柳州市颖航汽配有限公司 | Antibacterial rubber pad |
| CN104804232A (en) * | 2015-04-23 | 2015-07-29 | 苏州劲元油压机械有限公司 | Corrosion resistant rubber oil-conveying pipe and preparation technology thereof |
| CN107936391A (en) * | 2017-12-05 | 2018-04-20 | 玉环县鑫庄电子有限公司 | A kind of modified butyl rubber |
| CN105885245B (en) * | 2016-04-18 | 2020-08-28 | 易宝（福建）高分子材料股份公司 | Halogen-free environment-friendly ethylene propylene diene monomer/negative oxygen ion powder blended closed-cell secondary foaming material and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1498915A (en) * | 2002-11-06 | 2004-05-26 | 李青山 | Composite material of polyolefine/lightweight shale of opal in Nenjiang River |
| CN1635020A (en) * | 2004-12-06 | 2005-07-06 | 东华大学 | Anion rubber composite material and method for preparation |
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2010
- 2010-03-24 CN CN2010101305507A patent/CN101781416B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1498915A (en) * | 2002-11-06 | 2004-05-26 | 李青山 | Composite material of polyolefine/lightweight shale of opal in Nenjiang River |
| CN1635020A (en) * | 2004-12-06 | 2005-07-06 | 东华大学 | Anion rubber composite material and method for preparation |
Non-Patent Citations (1)
| Title |
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| 《橡胶科技市场》 20080501 谢磊等 负离子橡胶弹性材料的设计与开发 21-23 1-4 , 第9期 2 * |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103102601A (en) * | 2012-11-13 | 2013-05-15 | 铜陵亿亨达电子有限责任公司 | Alkali-resistant capacitor case rubber wrapping material |
| CN103102601B (en) * | 2012-11-13 | 2015-05-13 | 铜陵亿亨达电子有限责任公司 | Alkali-resistant capacitor case rubber wrapping material |
| CN103059423A (en) * | 2012-11-14 | 2013-04-24 | 安徽江威精密制造有限公司 | Tension-resistant rubber wrapping material for capacitor housing |
| CN103059423B (en) * | 2012-11-14 | 2015-04-22 | 安徽江威精密制造有限公司 | Tension-resistant rubber wrapping material for capacitor housing |
| CN104277460A (en) * | 2014-10-22 | 2015-01-14 | 柳州市颖航汽配有限公司 | Antibacterial rubber pad |
| CN104804232A (en) * | 2015-04-23 | 2015-07-29 | 苏州劲元油压机械有限公司 | Corrosion resistant rubber oil-conveying pipe and preparation technology thereof |
| CN105885245B (en) * | 2016-04-18 | 2020-08-28 | 易宝（福建）高分子材料股份公司 | Halogen-free environment-friendly ethylene propylene diene monomer/negative oxygen ion powder blended closed-cell secondary foaming material and preparation method thereof |
| CN107936391A (en) * | 2017-12-05 | 2018-04-20 | 玉环县鑫庄电子有限公司 | A kind of modified butyl rubber |
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| Publication number | Publication date |
|---|---|
| CN101781416B (en) | 2011-09-07 |
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| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: HEBEI YONGZHENG ENVIRONMENTAL PROTECTION EQUIPMENT CO., LTD. Assignor: Zhang Yongzheng Contract record no.: 2012130000017 Denomination of invention: Negative ion high-pressure hose and preparation method thereof Granted publication date: 20110907 License type: Exclusive License Open date: 20100721 Record date: 20120305 |
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20110907 Termination date: 20120324 |