CN101778617A - Conditioning composition comprising dual cationic surfactant system, aminosilicone and silicone resin - Google Patents

Conditioning composition comprising dual cationic surfactant system, aminosilicone and silicone resin Download PDF

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CN101778617A
CN101778617A CN200880100546A CN200880100546A CN101778617A CN 101778617 A CN101778617 A CN 101778617A CN 200880100546 A CN200880100546 A CN 200880100546A CN 200880100546 A CN200880100546 A CN 200880100546A CN 101778617 A CN101778617 A CN 101778617A
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李宇俊
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Procter and Gamble Ltd
Procter and Gamble Co
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A61K8/342—Alcohols having more than seven atoms in an unbroken chain
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41—Amines
    • A61K8/416—Quaternary ammonium compounds
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
    • A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners

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Abstract

Disclosed is a conditioning composition comprising: (a) from about 0.1% to about 10% of a surfactant system comprising: di- and mono-alkyl quaternized ammonium salt cationic surfactants; (b) from about 1% to about 15% of a high melting point fatty compound; (c) from about 0.1 % to about 20% of an aminosilicone; (d) from about 0.0001% to about 10% of a silicone resin; and (e) an aqueous carrier. The composition of the present invention can provide improved wet and dry conditioning benefits while providing chronic/long lasting color protection benefits.

Description

The care composition that comprises binary cationic surfactant system, amino silicone and organic siliconresin
Invention field
The present invention relates to a kind of care composition, this care composition comprises: the surfactant system that (a) comprises dialkyl group and monoalkyl quaternary ammonium ammonium salt cationic surfactant; (b) hard fat compounds of group; (c) amino silicone (aminosilicone); (d) organic siliconresin; (e) aqueous carrier.Compositions of the present invention can provide the wet conditioning beneficial effect of improvement and do the conditioning beneficial effect, and lasting conditioning and long-term/persistent color protection beneficial effect can be provided simultaneously.
Background of invention
Develop several different methods and come conditioning hair.A kind of common method of conditioning beneficial effect that provides is to use conditioner, as cationic surfactant and polymer, hard fat compounds of group, low melting point oil, silicone compounds and their mixture.These conditioners of known great majority provide various conditioning beneficial effects.For example, when using, it is believed that some cationic surfactant can provide gel-type vehicle with some hard fat compounds of group.Described gel-type vehicle is suitable for providing multiple conditioning beneficial effect, as is applied to the smooth feeling during wet the sending out, and does flexibility and moist feeling on sending out.
Need to provide lasting conditioning and long-term/persistent color protection beneficial effect, and the wet conditioning beneficial effect of improvement and the hair care composition of dried conditioning beneficial effect can be provided simultaneously.This type of lasting conditioning and long-term/persistent color protection beneficial effect be at least a in for example following beneficial effect: long-term maintenance good feel after chromotrichia; prevent painted Achromotrichia or make Achromotrichia minimize/slow down, until chromotrichia next time.
WO 2005/107682 discloses and has handled the hair-conditioning after the hair oxidation via painted, bleaching or hair-waving, and described conditioning comprises with the care composition that comprises functionalized silicone such as amino silicone nurses one's health processing.WO 2005/107682 also discloses hair conditioner in embodiment 3, described conditioner comprises: the amino propyl group dimethylamine of stearoyl; Varisoft 432PPG; Spermol; Stearyl alcohol; The MQ resin of the amino silicone of commodity TSF4707 by name and commodity SR1000 by name.
Yet find, still be difficult for obtaining a kind of wet conditioning beneficial effect of improvement that provides and nurse one's health beneficial effect and can provide lasting conditioning and long-term/persistent color to protect the hair care composition of beneficial effect simultaneously with doing.
Described based on preamble, still need a kind of wet conditioning beneficial effect of improvement that provides to nurse one's health beneficial effect and can provide lasting conditioning and long-term/persistent color to protect the care composition of beneficial effect simultaneously with doing.
Can provide whole advantage of the present invention and beneficial effect without any prior art.
Summary of the invention
The present invention relates to a kind of care composition, described care composition comprises by weight:
(a) about 0.1% to about 10% surfactant system, described system comprises:
Dialkyl quats salt cation surfactant; With
The monoalkyl quaternary cationics;
(b) about 1% to about 15% hard fat compounds of group;
(c) about 0.1% to about 20% amino silicone;
(d) about 0.0001% to about 10% organic siliconresin; With
(e) aqueous carrier.
Care composition of the present invention can provide the wet conditioning beneficial effect of improvement and do the conditioning beneficial effect, and lasting conditioning and long-term/persistent color protection beneficial effect can be provided simultaneously.
By reading following description and appending claims, can understand these and other feature, aspect and advantage of the present invention better.
Detailed Description Of The Invention
Though this description it is believed that by following explanation to understand the present invention better by particularly pointing out and clearly claimed claims of the present invention are drawn a conclusion.
In this article, " comprise/comprise " and be meant and add other step of not influencing final result and other composition.This term comprise term " by ... form " and " basically by ... composition ".
Except as otherwise noted, all percentage ratio, umber and ratio are all in the gross weight of the present composition.All relate to the weight of listed composition all in its activity substance content, and therefore do not comprise the carrier or the by-product that may be included in the commercially available material.
Term used herein " mixture " will comprise the simple combination of material and make up issuable any chemical compound by them.
Compositions
It is believed that (i) comprises the cationic surfactant system of dialkyl group and monoalkyl quaternary cationics and (ii) comprise the siloxane systems of amino silicone and organic siliconresin and the combination of other required composition of the present invention can provide the wet conditioning beneficial effect of improvement and do the conditioning beneficial effect, and lasting conditioning and long-term/persistent color protection beneficial effect can be provided simultaneously.
Preferably, when the gel-type vehicle that comprises cationic surfactant and/or form by cationic surfactant and hard fat compounds of group, for fear of with cationic surfactant worthless reciprocal action taking place and/or for stable gel substrate, compositions of the present invention is substantially free of anion surfactant and anionic polymer.In the present invention, " being substantially free of anion surfactant and anionic polymer " is meant that described compositions comprises 1% or still less, preferred 0.5% or still less altogether, more preferably totally 0% anion surfactant and anionic polymer.
Cationic surfactant system
Compositions of the present invention comprises cationic surfactant system, and described cationic surfactant system comprises dialkyl quats salt cation surfactant and monoalkyl quaternary cationics.The content of described cationic surfactant system in described compositions is about 0.1% to about 10% by weight, and preferred about 0.3% to about 5%, more preferably from about 0.5% to about 3%.
It is believed that with other cationic surfactant and compare that the combination of dialkyl group and monoalkyl quaternary cationics can improve the deposition of siloxanes of the present invention and aliphatic alcohol.This type of other cationic surfactant is for example other combination of cationic surfactant, or use single cationic surfactant, this type of other combination comprise dialkyl quats salt cation surfactant with by the combination of the amino propyl group dimethylamine of the quaternised amidoamines cationic surfactant of glutamic acid such as stearoyl, mountain Yu amido propyl dimethylamine.
Because the improvement of this type of silicone deposition, preferably comprise cationic surfactant system, make the weight rate of dialkyl quats salt cation surfactant and monoalkyl quaternary cationics at about 1: 1 to about 1: 20, more preferably from about 1: 1 to about 1: 15, also more preferably from about 1: 1 to about 1: 10 scope.
(i) dialkyl quats salt cation surfactant
The dialkyl quats salt cation surfactant that can be used for this paper is to have those of following formula structure:
Figure GPA00001009396200041
R wherein 75, R 76, R 77And R 78In two be selected from alkyl with 12 to 30 carbon atoms, or have maximum about 30 carbon atoms and have or do not have aryl, alkoxyl, polyoxyalkylenes, alkyl amido, hydroxyalkyl, aryl or the alkylaryl of ester group; R 75, R 76, R 77And R 78In all the other groups be independently selected from and have 1 alkyl to about 4 carbon atoms, or have alkoxyl, polyoxyalkylenes, alkyl amido, hydroxyalkyl, aryl or the alkylaryl of about 4 carbon atoms at most; And X -Be salt anionic, such as being selected from those of halogen (for example chloride ion, bromide ion), acetate, citrate, lactate, glycolate, phosphate radical, nitrate anion, sulfonate radical, sulfate radical, alkyl sulfate and alkyl sulfonic acid foundation.Except carbon atom and hydrogen atom, alkyl group also can comprise ether and/or ester bond and other group such as amino.Than the alkyl of long-chain, as have about 12 carbon atoms or more those), can be for saturated or unsaturated or be side chain.R 75, R 76, R 77And R 78In two be preferably selected from and have 12 to 30 carbon atoms, more preferably have 16 to 22 carbon atoms, also more preferably have the alkyl of 16 to 20 carbon atoms; R 75, R 76, R 77And R 78In all the other groups be independently selected from CH 3, C 2H 5, C 2H 4OH and their mixture; And X is selected from the group of being made up of following: Cl, Br, CH 3OSO 3, C 2H 5OSO 3, and their mixture.
The limiting examples of preferred dialkyl quats salt cation surfactant comprises: two cocoyl alkyl dimethyl ammonium chlorides; Two cocoyl dimethyl ammonium bromide; The myristyl alkyl dimethyl ammonium chloride; Myristyl dimethyl ammonium bromide; Varisoft 432PPG; Double hexadecyl dimethyl ammonium bromide; Double hexadecyl methyl-benzyl ammonium chloride; VARISOFT TA100; Distearyl dimethyl ammonium bromide; Dimethyl two (h-tallow base) ammonium chloride; Hydroxypropyl distearyl ammonium chloride; Distearyl methyl-benzyl ammonium chloride; Two mountain Yu bases/two Semen arachidis hypogaeae base alkyl dimethyl ammonium chlorides; Two mountain Yu bases/two Semen arachidis hypogaeae base dimethyl ammonium bromide; Two mountain Yu base alkyl dimethyl ammonium chloride; Two mountain Yu base dimethyl ammonium bromide; Two mountain Yu base dimethyl methyl ester ammonium sulfate; Two mountain Yu ylmethyl benzyl ammonium chlorides; Dihydro tallow benzyl ammonium chloride; Dihydro tallow ethyl-hydroxyethyl methyl ester ammonium sulfate; Dihydro tallow ethoxy methyl ester ammonium sulfate; Two-C12-15 alkyl-dimethyl ammonium chloride; Two-C12-18 alkyl-dimethyl ammonium chloride; Two-C14-18 alkyl-dimethyl ammonium chloride; Two cocoyl ethyl-hydroxyethyl methyl ester ammonium sulfate; Two Semen sojae atricolor acyl group ethyl-hydroxyethyl methyl ester ammonium sulfate; Two palmityl ethyl alkyl dimethyl ammonium chlorides; Dihydro palmityl ethyl-hydroxyethyl methyl ester ammonium sulfate; Dihydro Adeps Bovis seu Bubali acylamino-ethyl-hydroxyethyl ammonium chloride; Dihydro Adeps Bovis seu Bubali acylamino-ethyl-hydroxyethyl methyl ester ammonium sulfate; Dihydro Adeps Bovis seu Bubali acyl group ethyl-hydroxyethyl methyl ester ammonium sulfate; Distearyl acyl group ethyl-hydroxyethyl methyl ester ammonium sulfate; Quaternary ammonium-82.
The another kind of dialkyl quats salt cation surfactant that can be used for this paper is asymmetric dialkyl quats salt cation surfactant.It is believed that with symmetric dialkyl quats salt cation surfactant and compare that asymmetric dialkyl quats salt cation surfactant can provide and be easy to the rinsing sense.The asymmetric dialkyl quats salt cation surfactant that can be used for this paper is to have those of following formula structure:
Figure GPA00001009396200051
R wherein 71Be selected from the alkyl of 12 to 30 carbon atoms or have aromatics, alkoxyl, polyoxyalkylene, alkyl amido, hydroxyalkyl, aryl or the alkylaryl of about 30 carbon atoms at most; R 72Be selected from the alkyl of 5 to 12 carbon atoms or have aromatics, alkoxyl, polyoxyalkylene, alkyl amido, hydroxyalkyl, aryl or the alkylaryl of about 12 carbon atoms at most; R 73And R 74Be independently selected from 1 to the alkyl of about 4 carbon atoms or have aromatics, alkoxyl, polyoxyalkylene, alkyl amido, hydroxyalkyl, aryl or the alkylaryl of about 4 carbon atoms at most; And X -Be the one-tenth salt anionic, as be selected from halogen (as chloride ion, bromide ion), acetate, citrate, lactate, glycolate, phosphate radical, nitrate anion, sulfonate radical, sulfate radical, alkyl sulfate and alkyl sulfonic acid foundation those.Except carbon atom and hydrogen atom, alkyl group also can comprise ehter bond, ester bond and other group such as amino.Than the alkyl of long-chain, as, about 12 or those of more a plurality of carbon atoms, can be for saturated or unsaturated and/or straight chain or side chain.R 71Be preferably selected from and have 12 to 30 carbon atoms, preferably have the non-functionalised alkyl of 16 to 22 carbon atoms; R 72Be selected from and have 5 to 12 carbon atoms, more preferably have 6 to 10 carbon atoms, also more preferably have the non-functionalised alkyl of 8 carbon atoms; R 73And R 74Be independently selected from CH 3, C 2H 5, C 2H 4OH and their mixture; And X is selected from the group of being made up of following: Cl, Br, CH 3OSO 3, C 2H 5OSO 3, and their mixture.More preferably, R 71Be the saturated non-functionalized alkyl of straight chain, and R 72It is the saturated non-functionalized alkyl of side chain.Also more preferably, R 72Branched group be 1 to 4 carbon atom, even the more preferably saturated alkyl of straight chain of 2 carbon atoms.
The limiting examples of preferred asymmetric dialkyl quats salt cation surfactant comprises: stearyl ethylhexyl ammonium chloride, stearyl ethylhexyl ammonium bromide; Stearyl ethylhexyl dimethyl methyl ester ammonium sulfate; Derive from the cetearyl ethylhexyl dimethyl methyl ester ammonium sulfate of Evonik with for example trade name Varisoft ASQ.
(ii) monoalkyl quaternary cationics
The monoalkyl quaternary cationics that can be used for this paper is to have those of following formula structure:
Figure GPA00001009396200061
R wherein 75, R 76, R 77And R 78In one be selected from alkyl or have at most aryl, alkoxyl, polyoxyalkylenes, alkyl amido, hydroxyalkyl, aryl or the alkylaryl of about 30 carbon atoms with 12 to 30 carbon atoms; R 75, R 76, R 77And R 78In all the other groups be independently selected from and have 1 to the alkyl of about 4 carbon atoms or have alkoxyl, polyoxyalkylenes, alkyl amido, hydroxyalkyl, aryl or the alkylaryl of about 4 carbon atoms at most; And X -Be into salt anionic, as be selected from halogen (as chloride ion, bromide ion), acetate, citrate, lactate, glycolate, phosphate radical, nitrate anion, sulfonate radical, sulfate radical, alkyl sulfate and alkyl sulfonic acid foundation those.Except carbon atom and hydrogen atom, alkyl group also can comprise ether and/or ester bond and other group such as amino.Than the alkyl of long-chain, as having those of about 12 or more a plurality of carbon atoms, can be saturated or unsaturated.Preferably, R 75, R 76, R 77And R 78In one be selected from and have 12 to 30 carbon atoms, more preferably 16 to 22 carbon atoms, more preferably 18 to 22 carbon atoms also, even the more preferably alkyl of 22 carbon atoms; R 75, R 76, R 77And R 78In all the other groups be independently selected from CH 3, C 2H 5, C 2H 4OH and their mixture; And X is selected from the group of being made up of following groups: Cl, Br, CH 3OSO 3, C 2H 5OSO 3, and their mixture.Also it is believed that, become salt anionic to compare with other, anionic use can provide better conditioning beneficial effect as salify for alkyl sulfate such as methyl ester sulfate radical (methosulfate) and ethyl ester sulfate radical (ethosulfate), especially wet conditioning beneficial effect.
The limiting examples of this type of monoalkyl quaternary cationics comprises: mountain Yu base leptodactyline such as mountain Yu base trimethyl methyl ester ammonium sulfate and mountain Yu base trimethyl ammonium chloride; The stearyl leptodactyline; The cetyl leptodactyline; With the hydrogenated tallow alkyl leptodactyline.
The hard fat chemical compound
Compositions of the present invention comprises the hard fat compounds of group.For the conditioning beneficial effect of improvement is provided, as the wetness sensation on wet smooth feeling, flexibility and dried the sending out of sending out during using, described hard fat compounds of group is in by the weight of described compositions about 1% to about 15%, preferred about 2% to about 10%, and more preferably from about 3% to about 8% content is included in the described compositions.
Can be used for hard fat compounds of group of the present invention has 25 ℃ or higher fusing point and is selected from the group of being made up of following: aliphatic alcohol, fatty acid, fatty alcohol derivative, derivative of fatty acid and their mixture.It will be appreciated by those skilled in the art that the chemical compound in this part that is disclosed in this description belongs to more than one classification sometimes, for example some fatty alcohol derivative also can be classified as derivative of fatty acid.But specified class is not intended to specific compound is limited, but for the ease of classification and name.In addition, it will be understood by those skilled in the art that to have required certain some chemical compound of carbon number purpose and may have and be lower than 25 ℃ fusing point according to the number of two keys and the length and the position of position and side chain.This low-melting compound will be not included in this part.The limiting examples of high melting compound is found in " International Cosmetic Ingredient Dictionary ", the 5th edition, 1993; " CTFA Cosmetic Ingredient Handbook ", second edition, 1992.
In multiple hard fat compounds of group, preferred fat alcohol is used for compositions of the present invention.The aliphatic alcohol that can be used for this paper is to have about 14 to about 30 carbon atoms, and preferred about 16 to those of about 22 carbon atoms.These aliphatic alcohol are saturated and can are straight chain alcohol or branched-chain alcoho.Preferred aliphatic alcohol comprises for example spermol, stearyl alcohol, docosanol and their mixture.
Be preferably the hard fat compounds of group of highly purified unification compound.Highly be preferably the unification compound of the pure fat alcohol that is selected from the group of forming by pure spermol, stearyl alcohol and docosanol." pure " herein is meant that the purity of chemical compound is at least about 90%, is preferably at least about 95%.When consumer's rinsing compositions of the present invention, these high-purity unification compounds provide good eccysis from hair.
Aqueous carrier
Care composition of the present invention comprises aqueous carrier.According to selecting the content and the kind of described carrier with required other characteristic of the compatibility of other component and product.Compositions of the present invention contains about 20% usually to about 99%, and preferred about 30% to about 95%, more preferably from about 80% to about 95% water.
Can be used for the aqueous solution that carrier of the present invention comprises water and the pure and mild polyhydric alcohol of low alkyl group.Be applicable to that lower alkyl alcohol of the present invention is the monohydric alcohol with 1 to 6 carbon atom, more preferably ethanol and isopropyl alcohol.Can be used for polyhydric alcohol of the present invention and comprise propylene glycol, hexanediol, glycerol and propylene glycol.
Preferably, this aqueous carrier is water basically.The preferred deionized water that uses.The characteristic required according to product also can be used the water of the natural origin that comprises mineral cation.
Gel-type vehicle
Preferably, above-mentioned cationic surfactant forms gel-type vehicle with hard fat compounds of group and aqueous carrier in compositions of the present invention.
Described gel-type vehicle is suitable for providing multiple conditioning beneficial effect, provides flexibility and moist feeling as smooth feeling being provided during being administered to wet sending out and doing to send out.For above-mentioned gel-type vehicle is provided, the cationic surfactant and the hard fat compounds of group that comprise certain content, so that the weight rate of cationic surfactant and hard fat compounds of group is at preferred about 1: 1 to about 1: 10, more preferably from about 1: 1 to about 1: 6 scope.
In order to form gel-type vehicle, preferably prepare described compositions by the following method:
Usually water is heated at least about 70 ℃ preferred about 80 ℃ to about 90 ℃.Cationic surfactant and hard fat compounds of group are mixed with water to form mixture.Preferably the temperature of described mixture is remained on than under all high temperature of the melt temperature of the melt temperature of cationic surfactant and hard fat compounds of group, and with whole mixture homogenize.Stirring after not observing solid, making described mixture gradually (for example with about
Figure GPA00001009396200081
Minute to approximately
Figure GPA00001009396200082
Minute speed) be cooled to and be lower than 60 ℃, preferably be lower than approximately
Figure GPA00001009396200083
Temperature.At this gradually in the cooling procedure, about 50 ℃ to approximately
Figure GPA00001009396200084
Between, can be observed the remarkable increase of viscosity.This shows and has formed gel-type vehicle.Then, annexing ingredient is mixed with gel-type vehicle, and be cooled to room temperature.
Preferably, the present invention comprises by the weight of described compositions about 60% to about 99%, and preferred about 70% to about 95%, more preferably from about 80% to about 95% gel-type vehicle.Can in described gel-type vehicle, add optional member, as siloxanes.The feature of compositions that comprises the gel-type vehicle of above-mentioned amount is usually at 950s -1Under have about 40Pa to about 600Pa, preferably about 50Pa is to about 500Pa, and more preferably from about 70Pa extremely the rheology of about 400Pa (when employing TA AR1000 flow graph under 26.7 ℃ with 0.1s -1To 1100s -1Shear rate when measuring with persistent period of 1 minute).Though compositions of the present invention can comprise thickening polymer, compositions of the present invention can have above-mentioned rheology in the presence of any thickening polymer.Though compositions of the present invention can comprise thickening polymer, compositions of the present invention can have above-mentioned viscosity under the situation that does not contain any thickening polymer.
Amino silicone
Compositions of the present invention comprises amino silicone.The content of described amino silicone in described compositions counts about 0.1% to about 20% by the weight of described compositions, and preferred about 0.25% to about 15%, and more preferably from about 0.5% to about 10%, and also more preferably from about 1% to about 7%.
The amino silicone that can be used for this paper includes but not limited to have the siloxanes of following array structure:
Figure GPA00001009396200091
Wherein:
(n+m) sum is about 2 to about 2000, and preferred about 150 to about 2000, and more preferably from about 250 to about 1200, also more preferably from about 300 to about 800 scopes;
N is at about 1 number to about 1999 scopes, and m is at about 1 number to about 1999 scopes; And select n and m, make that the ratio of m: n is about 1: 1000 to about 1: 10, preferred about 1: 1000 to about 1: 25, more preferably from about 1: 800 to about 1: 50, also more preferably from about 1: 500 to about 1: 50, even more preferably from about 1: 400 to about 1: 100;
R 14, R 15, R 16Can be identical or different, and be selected from hydroxyl, C1-C4 alkoxyl and methyl, R 14And R 15Be preferably hydroxyl and/or C1-C4 alkoxyl, and R 16Be methyl;
A is selected from the C3-C8 alkenyl of straight chain and side chain;
R 17Be selected from (C2-C8) NH of H, phenyl, straight or branched C1-C4 alkyl, benzyl or preferred straight or branched 2And
G is selected from H, phenyl, hydroxyl, C1-C8 alkyl, preferable methyl.
These amino silicones can be random or block type.
Suitable amino silicone of the present invention includes but not limited to contain the organically-modified siloxanes of amido functional group, its can trade name such as ADM1100 and ADM1600 derive from Wacker Silicones, with trade name AP6087, DC2-8211, DC8822, DC8822A, DC8803, DC2-8040, DC2-8813, DC2-8630 and DC8566 derive from Dow Corning Corporation, with trade name KF-862, KF-861, KF-862S, KF-8005, KF-8004, KF-867S, KF-873 and X-52-2328 derive from Shin-Etsu Corporation, and with trade name TSF 4702, TSF 4703, TSF 4704, TSF 4705, TSF 4707, TSF 4708, TSF 4709, F42-B3115, SF 1708, SF 1923, SF 1921, SF 1925, OF TPAC3309, OF 7747, OF-NH TP AI3631, OF-NH TPAI3683 derives from GE Bayer Silicones.
The highly preferred amino silicone of the present invention is to have the viscosity of amido functional group greater than about 4, (000mPa.s in view of the conditioning effect) and maximum about 100, the organically-modified siloxanes of (000mPa.s in view of the close friend mixes property handled and spreadability), it includes but not limited to and can derive from WackerSilicones by trade name ADM1100, derive from Dow Corning Corporation and derive from the fluid of the commercially available acquisition of GE Bayer Silicones with trade name TSF 4707 with trade name AP6087, DC8803.
Organic siliconresin
Compositions of the present invention comprises organic siliconresin.Not bound by theory, it is believed that organic siliconresin set up three-dimensional network producing viscoelasticity in the amino silicone fluid, thereby improve fluidic bond properties, and therefore improved in the suprabasil persistency of cellulosic.Described organic siliconresin is preferably water insoluble.At fiber treatment composition is under the situation of emulsion, and the form that the mixture of amino silicone and organic siliconresin can emulsion droplet is scattered in wherein.
The organopolysiloxane resin is a solid at about 25 ℃ preferably as described in the present invention.Not bound by theory, it is believed that the SOLID ORGANIC silicones can form ultra-fine dispersion in amino silicone.When using the fluid organic siliconresin, its behavior is different from any organic siliconresin self, amino silicone self, and with the blend fluid of amino silicone.
Organopolysiloxane preferably has about 500g/mol to about 50 as described in the present invention, 000g/mol, and more preferably from about 750g/mol is to about 25,000g/mol, also more preferably from about 1,000 to about 10, the molecular weight ranges of 000g/mol.Not bound by theory, it is believed that the organic siliconresin with less or larger molecular weight is tending towards providing the synergism that weakens with amino silicone.
The content of described organic siliconresin in described compositions counts about 0.0001% to about 10% by the weight of described compositions, and preferred about 0.001% to about 5%, and more preferably from about 0.002% to about 3%, and also more preferably from about 0.003% to about 1%.Preferably comprise organic siliconresin, make the weight rate of organic siliconresin and amino silicone at about 1: 500 to about 1: 3000, more preferably from about 1: 800 to about 1: 2000, also more preferably from about in 1: 800 to about 1: 1500 scope.The organic siliconresin that it is believed that low content provides the collaborative beneficial effect that weakens with amino silicone, and high-load organic siliconresin is tending towards the sensation that provides relatively poor.
The organopolysiloxane that can be used for this paper is R 3SiO 1/2" M " unit, R 2SiO " D " unit, RsiO 3/2" T " unit, SiO 2" Q " unitary combination, the satisfied R that concerns of described unit ratio each other nSiO (4-n)/2, wherein n is the value between 1.0 to 1.50, and R is a methyl.Silanol or alkoxy-functional also can be present in the resin structure.
More preferably, 1170-002 comprises multiple simple function group R 3SiO 1/2" M " unit and four-functional group SiO 2" Q " unit also is called as " MQ " resin.In the case, " M " advantageously is 0.7 with " Q " functional unit's ratio, and the value of n is 1.2. such as these organopolysiloxane resin is the SR1000 that is purchased from GE Bayer Silicones, and the Wacker 803 that derives from Wacker Silicones.
Annexing ingredient
Compositions of the present invention can comprise other annexing ingredient, described other annexing ingredient can be selected by those skilled in the art and is suitable for making described compositions attractive in appearance or aestheticly more can accept according to the required characteristic of end product, perhaps provides additional use beneficial effect for them.The independent consumption of above-mentioned other annexing ingredient is generally about 0.001% to about 10% by described composition weight meter, is preferably at most about 5%.
Various other annexing ingredients can be formulated in the compositions of the present invention.These components comprise: fusing point is less than 25 ℃ low melting point oil, for example comprises such as the unsaturated fatty alcohol of oleyl alcohol with such as the ester oil of pentaerythritol ester oil; Other oil is such as safflower oil, Oleum Cocois; Cationic conditioning polymer comprises for example cationic cellulose and cationic guar gum; Polyethylene Glycol; Other conditioner, as has a trade name Peptein 2000, derive from the hydrolytic collagen of Hormel, has trade name Emix-d, derive from the vitamin E of Eisai, derive from the pantothenylol of Roche, derive from the general benzyl ethyl ether of Roche, hydrolysis of keratin, protein, hydrolysis Semen pruni armeniacae albumen, plant extract and nutrient substance; Antiseptic is as benzylalcohol, methyl parahydroxybenzoate, propyl p-hydroxybenzoate and imidazolidinyl urea; The pH regulator agent is as citric acid, sodium citrate, succinic acid, phosphoric acid, sodium hydroxide, sodium carbonate; Salt is usually as potassium acetate and sodium chloride; Coloring agent is as any FD﹠amp; C or D﹠amp; The C dyestuff; Spice; And sequestering agent, as disodiumedetate; Ultraviolet and infrared shielding and absorbent are as ethylhexyl salicylate, octyl methoxycinnamate, benzophenone-3 and benzophenone-4; With the dandruff agent, as Zinc Pyrithione and salicylic acid.
Product form
Care composition of the present invention can be rinse-off products or leave product form, and can be formulated as the multiple product form, and described multiple product form includes but not limited to cream, gel, emulsion, mousse and spray.
Care composition of the present invention is particularly useful for the agent of washing-off type hair care.This based composition uses with dye compositions preferably according to the following step:
(i) dye compositions is used on hair 5 to 60 minutes;
(ii) randomly and preferably use the water rinse hair;
(iii) then the care composition of effective dose is administered on the hair; And
(iv) preferably use the water rinse hair.
This type of care composition also can follow these steps to use:
(i) after shampoo was sent out, the care composition of coating effective dose was with conditioning hair on hair; With
(ii) clean described hair then.
Embodiment
Following examples have further described and have proved the embodiment in the scope of the invention.These embodiment that given only are illustrative, and are unintelligible for being limitation of the present invention, because can carry out many changes in the case of without departing from the spirit and scope of protection of the present invention.Unless hereinafter explanation in addition, the composition of Shi Yonging is all discerned with chemical name or CTFA name herein.
[compositions]
Figure GPA00001009396200121
Figure GPA00001009396200131
The definition of component
*1 distearyl acyl group ethyl-hydroxyethyl methyl ester ammonium sulfate: Dehyquart F-75 derives from Cognis.
*2 asymmetric dialkyl quats salt cation surfactants-1: cetearyl ethylhexyl dimethyl methyl ester ammonium sulfate derives from Evonik with trade name Varisoft ASQ
*3 amino silicones-1: have following array structure:
Figure GPA00001009396200132
Wherein: m and n make the number of (n+m) sum in 300 to 800 scopes, and select m and n, make that the ratio of m: n is 1: 400 to 1: 100; R 14And R 15Be hydroxyl and/or C1-C4 alkoxyl, and R 16Be methyl; A is selected from straight chain and side chain C3-C8 alkenyl; R 17Be selected from straight or branched (C2-C8) NH 2And G is a methyl.
*4 amino silicones-2:ADM1100 derive from Wacker Silicones
*5MQ resin: SR1000 (poly-trimethyl hydrogen silicon on silicon hydrochlorate) derives from GE Silicones
Preparation method
They can followingly suitably prepare can to prepare " embodiment 1 " as implied above to " embodiment 8 " by any conventional method well known in the art:
Under agitation, cationic surfactant and hard fat compounds of group are added to the water, and are heated to about 80 ℃.Described mixture is cooled to about 50 ℃.If comprise silicone compounds, spice, antiseptic, then under agitation they are joined in the described mixture.Make described mixture cooling room temperature then.
Embodiment 1 to 8 is the present invention of being particularly useful for rinsing purposes care compositions of taking care of hair.Embodiment open by aforementioned " embodiment 1 " to " embodiment 8 " and representative has many advantages.For example, they can provide the wet conditioning beneficial effect of improvement and do the conditioning beneficial effect, and lasting conditioning and long-term/persistent color protection beneficial effect can be provided simultaneously.
Dimension disclosed herein and value should be interpreted as it is that strictness to quoting exact value limits.On the contrary, except as otherwise noted, each such dimension is intended to represent the value of being quoted and centers on the scope that is equal on this value function.For example, disclosed size " 40mm " is intended to expression " about 40mm ".
Unless be not included in interior clearly or in other words restriction, every piece of document that this paper quoted comprises any cross reference or relevant patent or patent application, all incorporates this paper in full into way of reference hereby.The quoting of any document is not it as disclosed herein or be subjected to the approval of prior art of any invention of claims protection; perhaps to himself; perhaps with any other combination in any of list of references, perhaps with reference to, propose, suggestion or disclose the approval of any this type of invention.In addition, when any implication of same term in any implication of term in the presents or definition and the file of incorporating into way of reference or when defining contradiction, should obey the implication or the definition of giving this term in the present invention.
Though illustrated and described specific embodiments of the present invention, it will be apparent to one skilled in the art that and under the situation that does not deviate from essence of the present invention and scope, can make a plurality of other changes and modification.Therefore, claims all such changes and modification of being intended to be included in the scope of the present invention.

Claims (7)

1. care composition, described care composition comprises by weight:
(a) about 0.1% to about 10% surfactant system, described surfactant system comprises:
Dialkyl quats salt cation surfactant; With
The monoalkyl quaternary cationics;
(b) about 1% to about 15% hard fat compounds of group;
(c) about 0.1% to about 20% amino silicone;
(d) about 0.0001% to about 10% organic siliconresin; With
(e) aqueous carrier.
2. care composition as claimed in claim 1, the weight rate of wherein said dialkyl quats salt cation surfactant and described monoalkyl quaternary cationics at about 1: 1 to about 1: 20 scope.
3. care composition as claimed in claim 1, wherein said monoalkyl quaternary cationics comprises the alkyl sulfate anion, and described alkyl sulfate anion is selected from methyl ester sulfate radical or ethyl ester sulfate radical.
4. care composition as claimed in claim 1, wherein said organic siliconresin about 25 ℃ for solid and have about 1,000 to about 10,000 the gram molecular weight ranges.
5. care composition as claimed in claim 1, the weight rate of wherein said organic siliconresin and described amino silicone at about 1: 500 to about 1: 3000 scope.
6. care composition as claimed in claim 1, wherein said compositions is substantially free of anion surfactant and anionic polymer.
7. care composition as claimed in claim 1, described compositions are the washing-off type hair care composition.
CN200880100546A 2007-07-27 2008-07-24 Conditioning composition comprising dual cationic surfactant system, aminosilicone and silicone resin Pending CN101778617A (en)

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