CN101760110A - Ultraviolet curing nano transparent heat-insulation composite coating - Google Patents
Ultraviolet curing nano transparent heat-insulation composite coating Download PDFInfo
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Abstract
The invention discloses an ultraviolet curing nano transparent heat-insulation composite coating belonging to the field of ultraviolet curing coatings and containing the following substances in percentage by weight: 30-75 percent of oilopolymer, 0.01-15 percent of photosensitive curing agent and 10-55 percent of activated monomer, as well as 0.1-15 percent of stannic oxide. The transparent heat-insulation coating can be prepared in 1 minute under ultraviolet irradiation at room temperature, and the curing speed is high and the cost is low. The coating has selectivity to a solar spectrum, and a coating film which is about 5-70 micrometers is formed on the material surface. When the coating is used for glass, the visible light transmissivity of the glass is still higher than 75 percent, and the infrared thermal screening factor is higher than 70 percent, thereby not only keeping the transparency of the original glass, but also effectively isolating the infrared thermal radiation of sunlight. The coating has good ageing resistance, contamination resistance, anti-static performance, anti-dazzle performance, radiation protection, quick curing, environmental protection and the like.
Description
Technical field
The present invention relates to a kind of ultraviolet-curing paint, specifically, is a kind of nano transparent heat-insulation composite coating of ultraviolet light polymerization.
Background technology
Nano transparent heat-insulation composite coating is the high-tech energy-saving coatings that development in recent years is got up.This coating is to utilize the shielding properties of nano material to the infrared rays excellence, selects good coating system for use, makes the nano transparent heat-insulation composite coating of making have strong adhesion, transparent, shielding infrared rays, heat insulation, characteristics such as environmental protection.According to surveying and determination, the coating that scribbles this coating can make the testee tow sides temperature difference reach 9 degrees centigrade, and energy-efficient performance is very superior.This coating is used for glass to prevent ultrared transmission, effectively cuts down the consumption of energy, have crucial meaning.
At present, the domestic research that has many people to carry out this respect.CN101029206 invents a kind of thermal-insulating external-wall coating of nano-composite water and preparation method thereof, the CN1903958 disclosure of the Invention a kind of synthesized polyurethane glass heat insulating paint and preparation method thereof, the CN1357590 disclosure of the Invention a kind of preparation method of inorganic antistatic water suspensoid, the CN1446862 disclosure of the Invention a kind of nano antimony-doped tindioxide water paste and preparation method thereof, the CN101164946 invention relates to a kind of preparation method of thermal insulation spraying agent for glass, the CN101205419 disclosure of the Invention a kind of Yb-doped nano aqueous ATO heat-proof slurry and preparation method thereof, the CN101219859 disclosure of the Invention nano-oiliness ATO heat-insulating slurry and preparation method and application thereof, the CN1542062 disclosure of the Invention a kind of nano antimony-doped tindioxide (ATO) polar organic slurry, the CN1864834 disclosure of the Invention a kind of brilliant aqueous dispersions of transparent conductive nano and preparation method thereof of high-solid level of non-additive long-term stability, the CN1884409 disclosure of the Invention a kind of nanometer antimony-doped stannic oxide antistatic coating and preparation method thereof, the CN101186781 disclosure of the Invention a kind of water transparent heat insulation paint and preparation method thereof.CN1249321 invents a kind of radioresistant insulating water paint that is applied to skin or metallic surface.CN101289281 invents a kind of high transparent organic silicon resin glass thermal insulating coating.CN101362630 invents a kind of insulating mold coating of transparent glass of acrylic resin modified preparation.The CN101550312 disclosure of the Invention a kind of synthetic alkyd resin glass transparent insulating coating and preparation method thereof.More than these coating all have the characteristics that visible light transmissivity is very high, the infrared light transmitance is very low.But, they or water-borne coatings or do not adopt the oil paint of ultraviolet light polymerization technology, set time is long, the contaminate environment if oiliness system (paint) also needs to expend than multi-solvent.
UV-light (UV) is coating material solidified to be to obtain flourish new high-tech industry over past ten years at home, and nanotechnology is the 21st century focus competitively studied of countries in the world.Come the nano transparent heat-insulation composite coating of modified ultraviolet curing with nanotechnology, not only can make the upgrading of UV coating products, and can impel UV coating to expand to high-tech sector fields such as (as aerospace, electronic materials).
UV solidifies the rapid polymerization reaction that is often referred to the solvent-free aqueous chemical material of UV-light (UV) radiation and takes place, zero release in production and environment for use and zero waste treatment, adopt this technology to significantly reduce volatile organic matter (VOC) and enter environment, avoid producing the Greenhouse effect even more serious thus, and under irradiation of sunlight, form oxide compound and photo-chemical smog than carbonic acid gas.This promotes the whole ecological system to keep circulation to have very important significance for the protection environment.
At present, the domestic report that a lot of nano composite dopes are arranged relates to multiple products such as car paint, building coating, antibiotic paint, UV be coating material solidified.In paint field, nanometer grade silica, titanium dioxide, zinc oxide, alchlor particle are often used as the auxiliary agent of coating, in order to the rheological of improving coating, improve adhesive force of coatings, hardness of film, smooth finish and do aging resistance.According to the literature, nano titanium oxide and nano silicon also have antibiotic, antirust, decompose foreign odor and multiple function such as antifouling.With containing the 0.5%--4.0% nano titanium oxide, can be used for preparing permanent seal cooling external application Clear paint as a kind of good ultraviolet money absorption agent.The adding of nano silicon can improve curing speed, hardness of film, sticking power and cryogenic thermostability that the nano transparent heat-insulation composite coating of ultraviolet light polymerization is filmed.
Summary of the invention
1. invent the technical problem that will solve
At the existing problem of existing nano transparent heat-insulation composite coating performance, the invention provides a kind of nano transparent heat-insulation composite coating of ultraviolet light polymerization, wherein comprise ATO powder body material (stannic oxide and weisspiessglanz), make its cost far below being the coating that material is developed with the tin indium oxide, also be lower than the thermal isolation film that adopts usually now.Can have functions such as excellent ageing-resistant, anti-contamination is self-cleaning, anti-electrostatic, anti-dazzle, radioprotective, quick solidifying.
2. technical scheme
A kind of nano transparent heat-insulation composite coating of ultraviolet light polymerization, comprise the following material of weight percent content: oligomer 30～75%, photo-curing agent 0.01～15% and reactive monomer 10～55%, it also contains weight percent is 0.1～15% tin-antiomony oxide (ATO).
Above-mentioned reactive monomer (photosensitive diluent) is pentaerythritol triacrylate (PETA), Viscoat 295 (TMPTA), ethoxylated trimethylolpropane triacrylate (EO-TMPTA), propoxylation Viscoat 295 (PO-TMPTA), hexanediyl ester (HDDA), tripropylene glycol diacrylate (TPGDA), propylene glycol diacrylate (DPGDA), neopentylglycol diacrylate (NPGDA), butyl acrylate, a kind of or several materials in Isooctyl acrylate monomer and the vinylformic acid norbornene ester, they account for, and the composition by weight number is 10-55% in the coating.Photo-curing agent (photoinitiator) is a benzophenone, 1173 and the Irgacure819,651,907,2959 of Belgian UCB. S.A. (BE) Bruxelles Belgium.The photo-curing synergistic agent is the vinylformic acid tertiary ammonium salt, and it accounts for, and composition by weight is 0-15% in the coating.Flow agent and defoamer respectively account in the coating composition by weight and are 0.01-5%.Dispersion moisture agent accounts for that composition by weight is 0.01-5% in the coating.Nano material comprises that described nano material is nano silicon, zirconium dioxide, titanium dioxide, aluminum oxide, and weight percent is in 10%.Described tin-antiomony oxide (ATO) is a nano material.
Oligomer is the main component of decision coating physicals, to the many important performance of material, has a significant impact as rigidity, viscosity, curing speed, sticking power, anti-old power performance.Contain epoxy group(ing), hydroxyl isopolarity group in the acrylic acid epoxy resin molecule to by sticking material very strong sticking power being arranged, film forming matter rigidity is big, and is ageing-resistant, hardness big but weathering resistance is bad.N and urethano are arranged in the acroleic acid polyurethane molecule, unoccupied orbital is arranged on the N, snappiness is good, and is helpful to improving the coating snappiness.Acrylic-amino resin, cost is low, and viscosity is low, and curing speed is fast.Polyester acrylate and organosilicon-modified acrylate then sticking power are good.
Use because the viscosity of oligomer, is difficult to normal construction generally all than higher, so must add thinner, and this thinner is a kind of photosensitive diluent, promptly has in dilution function before solidifying and the solidification process to participate in the solidified function.The UV paint thinner mainly comprises pentaerythritol triacrylate (PETA), Viscoat 295 (TMPTA), ethoxylated trimethylolpropane triacrylate (EO-TMPTA), propoxylation Viscoat 295 (PO-TMPTA), hexanediyl ester (HDDA), tripropylene glycol diacrylate (TPGDA), propylene glycol diacrylate (DPGDA), neopentylglycol diacrylate (NPGDA), butyl acrylate, Isooctyl acrylate monomer and vinylformic acid norbornene ester.Thinner contains one～three activated double bonds, under photosensitizers and uviolizing crosslinking reaction takes place, and forms the build network structure.The used photosensitive diluent of the present invention is water white transparency, odorlessness liquid.
The photo-curing agent in prescription consumption seldom, adopt among the present invention benzophenone, 1173 and the Irgacure819,651,907 of Belgian UCB. S.A. (BE) Bruxelles Belgium, 2959 etc. be the photo-curing agent.It is fast to have curing speed, and stability is high, is difficult for advantages such as yellowing during curing.
The present invention adopts the photo-curing synergistic agent, and contained tertiary amine groups has the effect of free epoxy group(ing) in the curing system, accelerates curing speed under ultraviolet ray.
Flow agent and photosensitive resin consistency are good, and the coating levelling is effective after adding.
The foam of coating system is eliminated or suppressed to defoamer.
Dispersion moisture agent accounts for that composition by weight is 0.01-5% in the coating, plays the dispersion moistening nano-powder.
3. beneficial effect
The invention discloses a kind of nano transparent heat-insulation composite coating of ultraviolet light polymerization, select nano inorganic material for use, can have functions such as excellent ageing-resistant, anti-contamination is self-cleaning, anti-electrostatic, anti-dazzle, radioprotective, quick solidifying, the good prospect of marketing is arranged.This material has selectivity to solar spectrum, form about 5～70 microns filming at glass surface, the visible light transmissivity of glass still is higher than 75%, and the infra-red heat shielding rate is higher than 70%, this has not only kept the transparency of original glass, and can effectively completely cut off the infrared emanation of sunlight.The glass made from this coating has higher visible light transmissivity, and the reflectivity to infrared rays (thermal radiation) is very high simultaneously, has the effect that blocking radiant heat directly sees through.Coating of the present invention at normal temperatures can be made transparent heat insulating dope through UV-irradiation in 1 minute, curing speed is exceedingly fast, and cost is low, environmental protection.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
The main production process of preparation of the present invention is: 55-65 ℃ of control stirring tank, (after 1000～2000rpm), adding residue is again prepared burden, and continues to stir after 1～4 hour to get final product earlier nano material and reactive monomer to be carried out high speed dispersion 1 hour.Following examples are all by this preparation.Following degree is weight percent content.
Embodiment 1
Preparation as stated above, the each component parts by weight are respectively:
Acrylic-amino resin: 20%
Acroleic acid polyurethane: 10%
Acrylic acid epoxy resin: 10%
Dispersion moisture agent: 2%
Nano silicon: 1%
ATO：2％
HDDA：20％
TPGDA：8％
TMPTA：2％
Butyl acrylate: 15%
Benzophenone: 5%
Irgacure819：5％
1173：4％
Photo-curing synergistic agent: 6%
With the coating that this prescription is produced, adopt spraying method after construction on glass, the gained hardness of film reaches 2H, the visible light transmissivity 85% of glass, the infra-red heat shielding rate is higher than 71%.
Embodiment 2
Adjust nano material kind and oligomer, various material contents are as follows:.
Polyester acrylic resin: 10%
Acroleic acid polyurethane: 5%
Organosilicon modified crylic acid resin: 25%
Dispersion moisture agent: 2%
Nano silicon: 0.5%
Nano aluminium oxide: 0.5%
ATO：7％
HDDA：10％
TPGDA：8％
TMPTA：2％
Isooctyl acrylate monomer: 10%
Irgacure970：10％
1173：4％
Photo-curing synergistic agent: 6%
With the coating that this prescription is produced, adopt roll coating model after construction on glass, the gained hardness of film reaches 2H, the visible light transmissivity 80% of glass, infra-red heat shielding rate 87%.
Embodiment 3
Adjust nano material kind and oligomer, various material contents are as follows.
Acroleic acid polyurethane: 25%
Organosilicon modified crylic acid resin: 20%
Dispersion moisture agent: 1.5%
Nano silicon: 0.5%
ATO：5％
PETA：4％
HDDA：8％
TPGDA：8％
E0-TMPTA：5％
Butyl acrylate: 7%
Irgacure970：10％
1173：6％
With the coating that this prescription is produced, adopt roll coating model after construction on glass, the gained hardness of film reaches 2H, the visible light transmissivity 83% of glass, infra-red heat shielding rate 87%.
Embodiment 4
On the basis of embodiment 1 prescription, adjust, only keep following material:
Acrylic-amino resin: 20%
Acroleic acid polyurethane: 10%
Acrylic acid epoxy resin: 10%
ATO：15％
HDDA：30％
1173：15％
With the coating that this prescription is produced, adopt spraying method after construction on glass, gained hardness of film, visible light transmissivity and infra-red heat shielding rate all are lower than embodiment 1.The visible light transmissivity 78%. of glass
Embodiment 5
On the basis of embodiment 4 prescriptions, adjust, increase nano material:
Acrylic-amino resin: 20%
Acroleic acid polyurethane: 10%
Acrylic acid epoxy resin: 10%
Nano silicon: 5%
ATO：10％
HDDA：30％
1173：15％
With the coating that this prescription is produced, adopt spraying method after construction on glass, gained hardness of film, visible light transmissivity and infra-red heat shielding rate all are better than embodiment 4.
Embodiment 6
On the basis of embodiment 4 prescriptions, adjust:
Acrylic-amino resin: 35%
Acroleic acid polyurethane: 20%
Acrylic acid epoxy resin: 20%
Nano silicon: 5%
ATO：5％
HDDA：10％
1173：5％
With the coating that this prescription is produced, adopt spraying method after construction on glass, gained hardness of film, visible light transmissivity and infra-red heat shielding rate all are better than embodiment 4.
Embodiment 7
On the basis of embodiment 4 prescriptions, adjust:
Acrylic-amino resin: 24%
Acroleic acid polyurethane: 10%
Acrylic acid epoxy resin: 10%
Nano silicon: 0.89%
ATO：0.1％
HDDA：55％
1173：0.01％
With the coating that this prescription is produced, adopt spraying method after construction on glass, gained hardness of film, visible light transmissivity and infra-red heat shielding rate are not better than embodiment 4.
The content constraints that protection scope of the present invention is not enumerated by the foregoing description.
Claims (9)
1. the nano transparent heat-insulation composite coating of a ultraviolet light polymerization, comprise the following material of weight percent content: oligomer 30～75%, photo-curing agent 0.01～15% and reactive monomer 10～55% is characterized in that: also contain weight percent and be 0.1～15% tin-antiomony oxide.
2. the nano transparent heat-insulation composite coating of ultraviolet light polymerization according to claim 1 is characterized in that also comprising nano material, wherein nano material is a kind of in nano silicon, nano zirconium dioxide, nano titanium oxide, the nano aluminium oxide or several, and weight percent is in 10%.
3. the nano transparent heat-insulation composite coating of any one ultraviolet light polymerization according to claim 2, it is characterized in that oligomer be contain that two keys can ultraviolet light polymerization resin, mix by a kind of or several materials in acrylic acid epoxy resin, acroleic acid polyurethane, polyester acrylate, organosilicon-modified acrylate and the aminoacrylic acid resin and to form.
4. the nano transparent heat-insulation composite coating of any one ultraviolet light polymerization according to claim 3 is characterized in that reactive monomer is a kind of in pentaerythritol triacrylate, Viscoat 295, ethoxylated trimethylolpropane triacrylate, propoxylation Viscoat 295, hexanediyl ester, tripropylene glycol diacrylate, propylene glycol diacrylate, neopentylglycol diacrylate, butyl acrylate, Isooctyl acrylate monomer and the vinylformic acid norbornene ester or several.
5. the nano transparent heat-insulation composite coating of any one ultraviolet light polymerization according to claim 4 is characterized in that the photo-curing agent is a benzophenone, 1173 or the Irgacure819,651,907 of Belgian UCB. S.A. (BE) Bruxelles Belgium, 2959 a kind of or several.
6. according to the nano transparent heat-insulation composite coating of each described ultraviolet light polymerization in the claim 1～5, it is characterized in that also containing weight percent content 5% with interior defoamer, defoamer is a kind of in silicone antifoam agent, vinyl polymer and the acrylic acid copolymer defoamer or several.
7. according to the nano transparent heat-insulation composite coating of each described ultraviolet light polymerization in the claim 1～5, it is characterized in that also containing weight percent content 5% with interior flow agent, flow agent is a kind of in polysiloxane, vinyl polymer and the acrylate copolymer or several.
8. according to the nano transparent heat-insulation composite coating of each described ultraviolet light polymerization in the claim 1～5, it is characterized in that also containing weight percent content 5% with interior dispersion moisture agent, dispersion moisture agent is a kind of in carboxylic acid, the amide polymer or several.
9. according to the nano transparent heat-insulation composite coating of each described ultraviolet light polymerization in the claim 1～5, it is characterized in that also containing weight percent content 15% with interior vinylformic acid tertiary ammonium salt photo-curing synergistic agent.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1554717A (en) * | 2003-12-26 | 2004-12-15 | �Ͼ���̩���ײ�������˾ | Nano technology modified ultraviolet solidified woodware paint |
| CN1800068A (en) * | 2005-12-15 | 2006-07-12 | 南京工业大学 | Transparent heat insulating glass |
| CN101186781A (en) * | 2007-12-14 | 2008-05-28 | 华南理工大学 | Transparent heat insulating dope and preparation method thereof |
| CN101423634A (en) * | 2008-12-18 | 2009-05-06 | 江南大学 | Method for preparing multifunctional nano composite material |
| CN101538443A (en) * | 2008-03-19 | 2009-09-23 | 汤汉良 | Method for preparing automobile finish made of nanometer heat insulation material |
-
2010
- 2010-02-11 CN CN 201010110050 patent/CN101760110A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1554717A (en) * | 2003-12-26 | 2004-12-15 | �Ͼ���̩���ײ�������˾ | Nano technology modified ultraviolet solidified woodware paint |
| CN1800068A (en) * | 2005-12-15 | 2006-07-12 | 南京工业大学 | Transparent heat insulating glass |
| CN101186781A (en) * | 2007-12-14 | 2008-05-28 | 华南理工大学 | Transparent heat insulating dope and preparation method thereof |
| CN101538443A (en) * | 2008-03-19 | 2009-09-23 | 汤汉良 | Method for preparing automobile finish made of nanometer heat insulation material |
| CN101423634A (en) * | 2008-12-18 | 2009-05-06 | 江南大学 | Method for preparing multifunctional nano composite material |
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