CN101757966B - Nanoscale high-flow pin-type sand mill - Google Patents

Nanoscale high-flow pin-type sand mill Download PDF

Info

Publication number
CN101757966B
CN101757966B CN201010000456XA CN201010000456A CN101757966B CN 101757966 B CN101757966 B CN 101757966B CN 201010000456X A CN201010000456X A CN 201010000456XA CN 201010000456 A CN201010000456 A CN 201010000456A CN 101757966 B CN101757966 B CN 101757966B
Authority
CN
China
Prior art keywords
rotor
sand cylinder
separator
rotating shaft
sand mill
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201010000456XA
Other languages
Chinese (zh)
Other versions
CN101757966A (en
Inventor
雷立猛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Puhler Guangdong Smart Nano Technology Co ltd
Original Assignee
PUHLER GUANGZHOU MACHINERY AND EQUIPMENT CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by PUHLER GUANGZHOU MACHINERY AND EQUIPMENT CO Ltd filed Critical PUHLER GUANGZHOU MACHINERY AND EQUIPMENT CO Ltd
Priority to CN201010000456XA priority Critical patent/CN101757966B/en
Publication of CN101757966A publication Critical patent/CN101757966A/en
Application granted granted Critical
Publication of CN101757966B publication Critical patent/CN101757966B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Landscapes

  • Crushing And Grinding (AREA)

Abstract

The invention relates to a nanoscale high-flow pin-type sand mill comprising a rack and a sand cylinder which is arranged on the rack and is sealed by a left cover and a right cover, wherein a feed pipe and a discharging pipe are respectively arranged on the two sides of the sand cylinder; a spindle passes through the left end cover to extend into the sand cylinder and is fixedly provided with a rotor; the surrounding wall of the rotor is axially provided with a plurality of rows of pins; a separator is installed on the sand cylinder and is communicated with the discharging pipe; one end of the rotor is installed on the spindle, and the other end of the rotor is axially provided with a groove; one end of the separator is fixed on the right end cover; and the other end of the separator passes through the right end cover to extend into the groove. In this way, the length of the sand cylinder can be effectively shortened to increase the diameter thereof, thus the spindle can be designed to be short and thick so as to improve the rotational speed of the spindle and increase the linear speed of the material and grinding medium in the sand cylinder; and the material is fully dispersed and ground to ensure grinding precision and improve grinding efficiency.

Description

Nanoscale high-flow pin-type sand mill
Technical field
The present invention relates to a kind of horizontal sand mill, is nanoscale high-flow pin-type sand mill specifically.
Background technology
On the basis that guarantees grinding precision, improving grinding efficiency is the research direction of sand mill.Existing excellent pin-type sand mill comprises frame and the sand cylinder that is arranged on the frame by left and right end cap seal; Be provided with rotating shaft in the sand cylinder; Direct mounting bar pin in rotating shaft is perhaps installed rotor in rotating shaft, then mounting bar pin again on rotor; Separator generally is installed in the end of rotating shaft or is installed in a side of rotor, like Chinese patent (200520032444.X).This structures shape the Design of length of sand mill sand cylinder should be longer; Therefore the length of rotating shaft need be very long, thereby limited the raising of grinder rotating shaft rotary speed, causes abrasive media and the material linear velocity in grinding chamber slower; The shearing force of its formation is less; Grind fully inadequately,, then must prolong milling time as reaching predetermined grinding precision; Sand cylinder length is long simultaneously, and the material percent of pass is also lower, has hindered the raising of grinding efficiency.And, owing to sand mill is to utilize the high speed rotary drive material of rod pin and abrasive media rotation to produce very strong centrifugal force, make the uniform dispersion grinding of material, form shearing force again between material and the abrasive media simultaneously.Therefore, material has very big energy to be converted into heat energy in dispersion grinding, and these heat energy raise the temperature of polished material and entire machine rapidly.At present, the way of use normally is provided with cooling jacket in sand cylinder, but effect is not ideal enough, and it is not obvious to lower the temperature, and the centre of sand cylinder can not get effective cooling, has further limited the raising of the rotary speed of rotating shaft.
Summary of the invention
Technical problem to be solved by this invention is to overcome the deficiency of above-mentioned prior art, provides a kind of grinding efficiency high nanoscale high-flow pin-type sand mill.
The present invention is achieved in that nanoscale high-flow pin-type sand mill, comprises frame and is arranged on the frame by the sand cylinder of left and right end cap seal, and feed pipe and discharge nozzle lay respectively at the sand cylinder both sides; One rotating shaft is passed said left end cap and is stretched in the sand cylinder; Be installed with a rotor in the said rotating shaft, the rotor perisporium is equipped with number row rod pin vertically, and a separator is installed on the sand cylinder and with discharge nozzle and is connected; One end of said rotor is installed in the rotating shaft; The other end of said rotor is provided with groove vertically, and an end of said separator is fixed on the right end cap, and the other end of said separator passes right end cap and extend in the said groove.
The present invention also has following additional technical feature:
A said end of said rotor is formed with inserting groove, and said rotating shaft one is end formed to have the Plug Division that cooperates with inserting groove, and said Plug Division is passed left end cap and inserted in the inserting groove.
Said inserting groove is an annular groove, and said Plug Division is an annular protrusion.
Be provided with the cooling duct that is interconnected between said rotating shaft and the rotor.
Be provided with the cooling duct that is interconnected between said sand cylinder and the right end cap.
Said separator length is 1/2 of sand cylinder length.
Said separator diameter is 1/3 of a sand cylinder internal diameter.
Open the strip through-hole that communicates with said groove between adjacent two row's rod pins of said rotor.
Nanoscale high-flow pin-type sand mill provided by the invention compared with prior art has following advantage: an end of said rotor is installed in the rotating shaft; The other end of said rotor is provided with groove vertically; One end of said separator is fixed on the right end cap, and the other end of said separator passes right end cap and extend in the said groove.So just, can shorten the length of sand cylinder effectively and increase diameter, thus rotating shaft can design very short very thick, thereby improve the rotary speed of rotating shaft, increase material and the linear velocity of abrasive media in sand cylinder, to the abundant dispersion grinding of material, the assurance grinding precision; And the diameter of increase sand cylinder, can make the percent of pass of material higher, charging and discharging speed is faster, improves grinding efficiency.Be provided with the cooling duct that is interconnected between said rotating shaft and the rotor; Be provided with the cooling duct that is interconnected between said sand cylinder and the right end cap.Can design two cooling recirculation systems through above-mentioned cooling duct, it not only can be lowered the temperature to sand cylinder, also can cool off rotating shaft and rotor, makes the mechanical temperature of entire machine reduce, and also can improve the rotary speed of rotating shaft, further improves grinding efficiency.
Description of drawings
Fig. 1 is the structural representation of a kind of optimal way of the present invention.
Fig. 2 is an A-A cutaway view among Fig. 1.
Fig. 3 is the schematic perspective view of rotor of the present invention.
The specific embodiment
Referring to Fig. 1 to Fig. 3; A kind of optimal way of nanoscale high-flow pin-type sand mill of the present invention is shown; Comprise frame 1 and be arranged on the sand cylinder 2 that seals by left and right end cap 21,22 on the frame; Rotating shaft 5 is passed said left end cap 21 and is stretched in the sand cylinder, is installed with a rotor 6 in the rotating shaft 5, and the rotor perisporium is equipped with number row rod pin 61 vertically.Material gets in the sand cylinder 2 from the feed pipe 3 of sand cylinder left end; Material in sand cylinder and abrasive media are under the effect of epitrochanterian rod pin 61 rotations; Constantly bump and produce centrifugal force; Make the abundant dispersion grinding of material, utilize dynamic centrifugation principle that the material after the grinding is flowed out from discharge nozzle 4 through separator 7 then.One end of said rotor 6 is installed in the rotating shaft 5, and the other end of said rotor is provided with groove 62 vertically, and an end of said separator 7 is fixed on the right end cap 22, and the other end of said separator passes right end cap and extend in the said groove 62.So just, can shorten the length of sand cylinder effectively and increase diameter, thus rotating shaft can design very short very thick, thereby improve the rotary speed of rotating shaft, increase material and the linear velocity of abrasive media in sand cylinder, to the abundant dispersion grinding of material, the assurance grinding precision; And the diameter of increase sand cylinder, can make the percent of pass of material higher, charging and discharging speed is faster, improves grinding efficiency.Separator described in the present invention is dynamically big flow cyclone, and its gap minimum can reach 30 microns, and the abrasive media filling rate in the sand cylinder can reach more than 96.5%, and rotor also can increase with the diameter of rod pin, and this all helps to improve grinding effect.
In the course of the work, like the sand mill of a 20L, its root diameter is 312mm, and the rotary speed of rotating shaft is 757rpm, is about 12.5m/s through calculating the linear velocity that can obtain rotor.Rotary speed as with rotating shaft increases to 1600rpm, and then the linear velocity of rotor can reach more than the 25m/s, the energy that this is produced in the time of can improving the sand mill dispersion grinding greatly, thus reach dispersion grinding effect rapidly and efficiently.
In the present embodiment, a said end of said rotor 6 is formed with inserting groove 63, and said rotating shaft 5 one is end formed to have the Plug Division 51 that cooperates with inserting groove, and said Plug Division 51 is passed left end cap 21 and inserted in the inserting grooves 63.Said inserting groove is an annular groove, and said Plug Division is an annular protrusion.In implementation process, interference fit that can be through annular protrusion and annular groove is installed in an end of rotor in the rotating shaft, also can connect the end that rotor one end is installed in rotating shaft with screw vertically, and other connected mode can also be arranged.
Be provided with the cooling duct 8 that is interconnected between said rotating shaft 5 and the rotor 6; Be provided with the cooling duct 8 that is interconnected between said sand cylinder 2 and the right end cap 22.Can design two cooling recirculation systems through above-mentioned cooling duct; One of them cooling recirculation system is: cooling water or other cooling fluid get into the cooling duct of rotor from the cooling duct 8 of rotating shaft; Flow out from rotor then, like this can be simultaneously to rotor and rotating shaft cooling.Its implementation has multiple, such as: bearing can be set on rotor, the cooling duct that is interconnected with rotor is set in the bearing, thereby water or other cooling fluid after the circulation are flowed out from bearing; Another cooling recirculation system is: cooling water or other cooling fluid get into the cooling duct 8 in the sand cylinder through coolant pump from the sand cylinder downside; Flow out from the sand cylinder upside cooling duct through right end cap again; Can guarantee like this to be full of cooling water in the cooling duct of whole sand cylinder; Simultaneously, can increase chilled water unit at the right end cap place, and below the right end cap discharging opening, set up relief valve 23 and discharge gate for better temperature control when satisfying discharging; The inconvenience that is brought when avoiding equipment to shut down in the running or suddenly, also available certainly have other mode to realize this cooling recirculation system.The realization of these two cooling recirculation systems not only can be lowered the temperature to sand cylinder; Also can cool off rotating shaft and rotor, make the mechanical temperature of entire machine reduce the heat energy that is produced in the time of also can controlling the rotary speed that improves rotating shaft; Further improve grinding efficiency, guarantee product with stable quality.
In implementation process; Can sand cylinder be designed to very short very thick; Rotor is designed to hollow shape and opens the strip through-hole 64 that groove communicates last, makes the time of staying of material in sand cylinder short, and the material circular flow is big; Perfect heat-dissipating can be used the dynamically big flow cyclone that length is long, diameter is thick, the gap is little, precision is high simultaneously.The length of ordinary circumstance separator is about 1/2 of sand cylinder length; Diameter is about 1/3 of sand cylinder internal diameter; Can guarantee better grinding effect like this, also can select thinner abrasive media, improve the filling rate of abrasive media in sand cylinder; Can make the precision of abrasive product reach nanoscale in this way, and product the particle diameter detecting instrument following show that the particle diameter distributions is narrow.In implementation process; It is better to be used the automatic control system effect, as the product energy consumption value parameter can be imported setting in advance, when guaranteeing that the sand mill energy consumption reaches setting value; The expression product has reached estimates to grind the fineness that requires; This moment, the sand mill autostop both guaranteed the stability of product quality, had practiced thrift energy consumption again.
In the present invention, open the strip through-hole 64 that communicates with said groove between adjacent two row's rod pins 61 of said rotor 6.Not only alleviated the weight of whole rotor, cut down the consumption of energy, and can let material and abrasive media accumulate in around the separator fast; Under action of centrifugal force, abrasive media is by dynamic separator separates, and material is got rid of into and flows out from discharge nozzle in the separator simultaneously; So just, separation and circulation rate have been improved; Thereby make that charging and discharging speed is quicker, further improve grinding efficiency, guarantee product quality.
The foregoing description only supplies to explain the present invention's usefulness; And be not to be limitation of the present invention; The those of ordinary skill in relevant technologies field under the situation that does not break away from the spirit and scope of the present invention, can also be made various variations and modification; Therefore all technical schemes that are equal to also should belong to category of the present invention, and scope of patent protection of the present invention should be limited each claim.

Claims (7)

1. nanoscale high-flow pin-type sand mill; Comprise frame (1) and be arranged on the sand cylinder (2) that seals by left and right end cap (21,22) on the frame; Feed pipe (3) lays respectively at the sand cylinder both sides with discharge nozzle (4), and a rotating shaft (5) is passed said left end cap and stretched in the sand cylinder, is installed with a rotor (6) in the said rotating shaft; The rotor perisporium is equipped with number row's rod pin (61) vertically; One separator (7) is installed on the sand cylinder and with discharge nozzle and is connected, and it is characterized in that: an end of said rotor (6) is installed in the rotating shaft, and the other end of said rotor is provided with groove (62) vertically; One end of said separator (7) is fixed on the right end cap, and the other end of said separator passes right end cap and extend in the said groove; A said end of said rotor (6) is formed with inserting groove (63), and said rotating shaft one is end formed to have the Plug Division (51) that cooperates with inserting groove, and said Plug Division is passed left end cap and inserted in the inserting groove.
2. nanoscale high-flow pin-type sand mill according to claim 1 is characterized in that: said inserting groove (63) is an annular groove, and said Plug Division (51) are annular protrusion.
3. nanoscale high-flow pin-type sand mill according to claim 1 is characterized in that: be provided with the cooling duct (8) that is interconnected between said rotating shaft (5) and the rotor (6).
4. nanoscale high-flow pin-type sand mill according to claim 1 is characterized in that: be provided with the cooling duct (8) that is interconnected between said sand cylinder (2) and the right end cap (22).
5. nanoscale high-flow pin-type sand mill according to claim 1 is characterized in that: said separator (7) length is 1/2 of sand cylinder (2) length.
6. nanoscale high-flow pin-type sand mill according to claim 1 is characterized in that: said separator (7) diameter is 1/3 of sand cylinder (a 2) internal diameter.
7. according to any described nanoscale high-flow pin-type sand mill in the claim 1 to 6, it is characterized in that: open the strip through-hole (64) that communicates with said groove (62) between adjacent two row's rod pins (61) of said rotor (6).
CN201010000456XA 2010-01-11 2010-01-11 Nanoscale high-flow pin-type sand mill Active CN101757966B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201010000456XA CN101757966B (en) 2010-01-11 2010-01-11 Nanoscale high-flow pin-type sand mill

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201010000456XA CN101757966B (en) 2010-01-11 2010-01-11 Nanoscale high-flow pin-type sand mill

Publications (2)

Publication Number Publication Date
CN101757966A CN101757966A (en) 2010-06-30
CN101757966B true CN101757966B (en) 2012-05-23

Family

ID=42489441

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201010000456XA Active CN101757966B (en) 2010-01-11 2010-01-11 Nanoscale high-flow pin-type sand mill

Country Status (1)

Country Link
CN (1) CN101757966B (en)

Families Citing this family (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102794215B (en) * 2012-08-21 2016-05-11 向小月 A kind of many circulation grinding system
CN103178633B (en) * 2013-04-19 2015-04-22 昆山聚贝机械设计有限公司 Rotor external body cooling structure of ball mill
CN103170396A (en) * 2013-04-19 2013-06-26 昆山聚贝机械设计有限公司 Cooling type end cover of bead mill
CN104971799A (en) * 2014-04-03 2015-10-14 无锡赫达科技有限公司 Annulus space type nano sand mill
CN104190504A (en) * 2014-08-15 2014-12-10 广州派勒机械设备有限公司 High-performance super-flow nanometer sand mill
CN104741176B (en) * 2015-03-03 2018-04-27 广东派勒智能纳米科技股份有限公司 Rod pin type nanometer sand mill
CN104959196A (en) * 2015-06-29 2015-10-07 广州派勒机械设备有限公司 Super sand mill with double-separation system
CN105396650A (en) * 2015-09-22 2016-03-16 广州派勒机械设备有限公司 Screen-free type intelligent nanometer grinding system
CN105170293B (en) * 2015-09-29 2023-11-24 深圳市科力纳米工程设备有限公司 Forced dispersing device
CN106345577A (en) * 2016-09-20 2017-01-25 派勒(天津)纳米技术有限公司 Smart online-discharging dry ball mill
CN107570278A (en) * 2017-09-26 2018-01-12 广州大学 A kind of nano-milled component cooling water circulatory system
CN107626395B (en) * 2017-11-09 2019-07-30 江南大学 A kind of double taper type sander apparatus of stick pin type
CN109622363A (en) * 2018-12-24 2019-04-16 深圳市科力纳米工程设备有限公司 A kind of wet grinding separator and system
CN111060371B (en) * 2019-12-30 2022-09-23 甘肃农业大学 Stirring type seed grinding device and working method thereof
DE102020103848A1 (en) * 2020-02-14 2021-08-19 Netzsch-Feinmahltechnik Gmbh Temperature-controlled component and method for manufacturing a temperature-controlled component
CN112892793B (en) * 2021-01-15 2022-07-22 宜春职业技术学院(宜春市技术工人学校) Fine arts pigment grinder
CN113289731B (en) * 2021-05-20 2023-07-18 博亿(深圳)工业科技有限公司 Grinding system and method with multiple dispersion speeds
CN113289733B (en) * 2021-05-20 2023-08-15 博亿(深圳)工业科技有限公司 Grinding and dispersing device and dispersing method capable of outputting various dispersing speeds
CN114130485B (en) * 2021-11-25 2022-06-14 东莞市华汇精密机械有限公司 Double-convex-pin-type nano sand mill
CN115770650B (en) * 2022-12-30 2023-07-14 河北益诺森水墨有限公司 Environment-friendly water-based ink grinding processing equipment for transfer printing and grinding process

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1307934A (en) * 2001-02-12 2001-08-15 宜兴市洪流集团公司 Improved sand mill
CN2836917Y (en) * 2005-10-28 2006-11-15 冯立明 A novel sand mill
CN201329300Y (en) * 2008-09-09 2009-10-21 耐驰(上海)机械仪器有限公司 Stirrer
CN201596544U (en) * 2010-01-11 2010-10-06 雷立猛 Nano-grade large-capacity pin-type sand mill

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1307934A (en) * 2001-02-12 2001-08-15 宜兴市洪流集团公司 Improved sand mill
CN2836917Y (en) * 2005-10-28 2006-11-15 冯立明 A novel sand mill
CN201329300Y (en) * 2008-09-09 2009-10-21 耐驰(上海)机械仪器有限公司 Stirrer
CN201596544U (en) * 2010-01-11 2010-10-06 雷立猛 Nano-grade large-capacity pin-type sand mill

Also Published As

Publication number Publication date
CN101757966A (en) 2010-06-30

Similar Documents

Publication Publication Date Title
CN101757966B (en) Nanoscale high-flow pin-type sand mill
CN201596544U (en) Nano-grade large-capacity pin-type sand mill
CN201596542U (en) Dynamic centrifugal discharge system of disc type sand grinder
CN102935397B (en) Dual-rotation conical-drum-type horizontal sand mill
CN103357489B (en) Centrifugal type partition-net-free material bead separator for media stirring mill
KR101310130B1 (en) Grinding and dispersing apparatus for processing of minute particle of materials
CN103657798B (en) Stirring-type grinding cylinder and lapping device
CN104971799A (en) Annulus space type nano sand mill
CN110898944A (en) Annular gap grinding device
CN207187872U (en) A kind of grinder of new structure
CN106428580B (en) A kind of unmanned helicopter
CN110947471A (en) Sand mill with high efficiency and stable performance
CN209885912U (en) Improved sand mill
CN201848763U (en) Turbine type nanometer beads mill
CN204724256U (en) Rod pin nanometer sand mill
CN201783351U (en) Improved centrifugal type nano bead mill
CN207187885U (en) A kind of high efficiency grinder
CN203264780U (en) Horizontal disc-type sand mill
CN203830077U (en) Annular space type nanometer sanding machine
CN211660186U (en) Annular gap grinding device
CN104226426A (en) Full-sized dynamic separation nano sand mill
CN104226428B (en) Novel high-performance ball mill
CN205084781U (en) Single driving high pressure grinding roller
CN201275490Y (en) Bead grinder
CN212596098U (en) Shaft core discharging ceramic rod pin sand mill for laboratory

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
ASS Succession or assignment of patent right

Owner name: GUANGZHOU PUHLER MACHINERY AND EQUIPMENT CO., LTD.

Free format text: FORMER OWNER: LEI LIMENG

Effective date: 20120307

C41 Transfer of patent application or patent right or utility model
COR Change of bibliographic data

Free format text: CORRECT: ADDRESS; FROM: 510700 GUANGZHOU, GUANGDONG PROVINCE TO: 511498 GUANGZHOU, GUANGDONG PROVINCE

TA01 Transfer of patent application right

Effective date of registration: 20120307

Address after: 511498, 88, Xie Shi Road, four village, Shek Pik, Panyu District, Guangdong, Guangzhou

Applicant after: PUHLER (GUANGZHOU) MACHINERY AND EQUIPMENT Co.,Ltd.

Address before: Whampoa fengle North District of Guangzhou City, Guangdong Province, No. 84-88 510700 building 301 Room Nineteen

Applicant before: Lei Limeng

C14 Grant of patent or utility model
GR01 Patent grant
C56 Change in the name or address of the patentee
CP03 Change of name, title or address

Address after: 511495 Guangzhou, Panyu District, Zhong Cun street, the source of the road on the 1st

Patentee after: PUHLER (GUANGDONG) SMART NANO TECHNOLOGY Co.,Ltd.

Address before: 511498, 88, Xie Shi Road, four village, Shek Pik, Panyu District, Guangdong, Guangzhou

Patentee before: PUHLER (GUANGZHOU) MACHINERY AND EQUIPMENT Co.,Ltd.

PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: Nanoscale high-flow pin-type sand mill

Effective date of registration: 20161026

Granted publication date: 20120523

Pledgee: Bank of China Limited by Share Ltd. Guangzhou Panyu branch

Pledgor: PUHLER (GUANGDONG) SMART NANO TECHNOLOGY Co.,Ltd.

Registration number: 2016440000025

PLDC Enforcement, change and cancellation of contracts on pledge of patent right or utility model
PC01 Cancellation of the registration of the contract for pledge of patent right
PC01 Cancellation of the registration of the contract for pledge of patent right

Date of cancellation: 20221014

Granted publication date: 20120523

Pledgee: Bank of China Limited by Share Ltd. Guangzhou Panyu branch

Pledgor: PUHLER (GUANGDONG) SMART NANO TECHNOLOGY Co.,Ltd.

Registration number: 2016440000025

PE01 Entry into force of the registration of the contract for pledge of patent right
PE01 Entry into force of the registration of the contract for pledge of patent right

Denomination of invention: Nanometer high flow rod pin sander

Effective date of registration: 20221020

Granted publication date: 20120523

Pledgee: Bank of China Limited by Share Ltd. Guangzhou Panyu branch

Pledgor: PUHLER (GUANGDONG) SMART NANO TECHNOLOGY Co.,Ltd.

Registration number: Y2022980018953