CN101717296A - Green nutritional compound fertilizer and method for preparing same - Google Patents

Green nutritional compound fertilizer and method for preparing same Download PDF

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Publication number
CN101717296A
CN101717296A CN200910227440A CN200910227440A CN101717296A CN 101717296 A CN101717296 A CN 101717296A CN 200910227440 A CN200910227440 A CN 200910227440A CN 200910227440 A CN200910227440 A CN 200910227440A CN 101717296 A CN101717296 A CN 101717296A
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fertilizer
parts
compound fertilizer
plant
crops
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CN101717296B (en
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闫虎成
闫森元
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Xichuan Yuanke Biological Technology Co., Ltd.
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闫虎成
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Abstract

The invention relates to green nutritional compound fertilizer and a method for preparing same. The green nutritional compound fertilizer is prepared from plant material, urea or ammonium nitrate, superphosphate, potassium silicate, sodium borate, hydrated magnesium sulphate, zinc sulphate, chelated iron, sodium molybdenum, manganese sulfate, copper sulfate, cobalt nitrate and bio-fertilizer. 60 percent of the green nutritional compound fertilizer can be more easily absorbed by the crops, and the residue of the green nutritional compound fertilizer can be reduced. The green nutritional compound fertilizer can promote the growth of the crops, improve the quality of the crops, make the crops sprout and ripe earlier and have the developed root system and the luxuriant foliage and increase the yield of the crops by 50-80 percent. The green nutritional compound fertilizer can inhibit the breeding and the propagation of pathogens in the soil, reduce the crop diseases, enhance the disease resistance ability of the crops, improve the soil structure, activate the soil nutrient and realize the ecological planting of the crops.

Description

Green nutritional compound fertilizer and preparation method thereof
Technical field
The invention belongs to the agricultural fertilizer technical field, is a kind of green nutritional compound fertilizer and preparation method thereof.
Background technology
For many years, the application of chemical fertilizer on farm crop played enormous function to the volume increase of crop, but because of a large amount of unreasonable use chemical fertilizer cause soil compaction, soil fertility decline, environmental pollution, ecological damage, especially the agricultural byproducts quality descends.In the last few years, though various mixing ecological fertilizers occurred, improve the agricultural byproducts quality and keep soil from packing together aspect receive certain effect, but its employed organic raw material, mainly be industrial organic waste, agricultural crop straw and feces of livestock and poultry etc. by the microorganism decomposition, its major defect: the nutritive element many places in the mineral manure that is to use are in locking states, lack the degraded activation, crop is difficult to absorb, not only cause the fertilizer waste, and cause Soil structure to be degenerated, and hardening, liquid manure keeps and the decline of fighting drought ability and the destruction of ecotope.The 2nd, a large amount of inorganic substance and synthetic pesticide be residual to carry many hazardous and noxious substances, in the sick parasitosis bacterium of kill harmful, also make beneficial organism, microorganism extinction in the soil, and these biologies are to suppress sick parasitosis bacterium to grow, activate the effective strength that improves Soil structure, and the shortage of various beneficial organisms is the major causes that cause crop disease-resistant immunity degradation and Soil structure to be degenerated.The 3rd, the supplies of paying attention to a large amount of, middle amount and micronutrient element more, and it is foster to lack moistening of degraded activation and organic composition, and objectionable impurities and farm chemical ingredients are carried in the product in addition, causes quality of agricultural product to descend, be of low nutritive value, lack the due fragrant and sweet savoriness taste of ecological crop.
Summary of the invention
The purpose of this invention is to provide complete, the easy absorption of a kind of nutrition, good, the crop specific absorption height of sustained release performance, can improve crop yield and quality, and can promote beneficial organism growth, improve the crop disease-resistant immunological competence, activating soil, the green nutritional compound fertilizer of fundamentally improving the ecological environment and preparation method thereof.
Realize that the technical scheme that purpose of the present invention is taked is: this compound fertilizer is formed by the preparation of raw material of following mass parts: 20~30 parts of plant materials, urea or 20~30 parts in ammonium nitrate, 5~7 parts of calcium superphosphate, 5~7 parts of potassium silicates, 3~7 parts of boraxs, 2~4 parts of Magnesium sulfate heptahydrates, 0.3~0.7 part in zinc sulfate, 0.3~0.7 part of chelated iron, 0.3~0.7 part of Sodium orthomolybdate, 3~6 parts of manganous sulfates, 0.01~0.03 part in copper sulfate, 0.01~0.03 part of Xiao Suangu, 1~5 part of bio-fertilizer.
What described plant material was selected for use is root, stem, the leaf of plant Pueraria lobota, or selects the processing clout of root, skin, branch, leaf or its timber of Ailanthus altissima or chinaberry or acacia tree for use, perhaps get in 4 kind of plant any more than 2 kinds with the compound of any proportioning.
The preparation method of green nutritional compound fertilizer of the present invention comprises the following steps:
(1) preparation of plant material: the plant material of selecting for use is dried, and pulverizing 80 mesh sieves, to make pure plant powder standby;
(2) preparation of trace element materials: get borax, Magnesium sulfate heptahydrate, zinc sulfate, chelated iron, Sodium orthomolybdate, manganous sulfate, copper sulfate, Xiao Suangu separated pulverizing and cross 80 mesh sieves to make various micro-powders standby:
(3) fermentation: take by weighing pure plant powder and bio-fertilizer and mix by described proportioning, the aqueous sulfuric acid with 5% is adjusted pH value to 5~8, stacks under normal temperature condition and ferments 5~15 days, and it is standby to make active organic fertilizer;
(4) combination drying: take by weighing active organic fertilizer, various micro-powder and urea or ammonium nitrate, calcium superphosphate, potassium silicate mixing and stirring by described proportioning, insert oven dry in the drying plant, bake out temperature is 30~60 ℃, drying time 0.5~1.5 hour, it is standby to make the compound dry mash;
(5) granulation: the compound dry mash that makes is made the composite particles material of particle diameter at 4~6mm with granulating equipment;
(6) batch mixing:, promptly make green nourishing composite fertilizer finished product with composite particles material and compound dry mash ratio uniform mixing in 7: 3.
Green nutritional compound fertilizer according to the such scheme preparation, not only nutrition arrangement is complete rationally, and utilize profitable strain in the bio-fertilizer, make the nutritive element activation in plant and the inorganic fertilizer, become fully and be easy to effective nutrition of being absorbed by crop, prolong its reactivation process thus, played the good slow release effect.Thereby, can promote crop to absorb, the fertilizer specific absorption is brought up to more than 60% by 34%, and can promote plant growth, crop is sent out ahead of time sprout, well developed root system, branches and leaves are luxuriant, premature ripening, on the basis that increases crop yield 15~30%, make crop keep pure ecological quality, there are not any murder by poisoning or pollution, its fruit is edible fragrant and sweet good to eat, useful HUMAN HEALTH.And the profitable strain in the bio-fertilizer is in the preparation journey and be applied in the soil and can both breed growth with keeping, reach the development of growing that suppresses pathogenic bacteria in the soil, reduce crop pest, strengthen the crop disease-resistant ability and the structure of constantly improving the soil, the activating soil nutrient is realized the best effect that crop ecological is planted.
Embodiment
Green nutritional compound fertilizer of the present invention is in conjunction with long-term practical experience by the contriver, by the great deal of experimental gained, this compound fertilizer is according to the rule of plant growth to fertilizer demand, and the basic principle of optimizing soil mechanism, its raw material adopts plant, inorganic fertilizer, bio-fertilizer three fertile combinations, and adds various trace elements, prepares by compound, thereby the slow Ji mutually of the urgency that makes fertilizer efficiency, balanced, lasting, nutrient is comprehensive.Simultaneously, can be soil nutrient with plant material, chemical fertilizer Degradation and Transformation, reach long-acting, quick-acting, synergy " triple effect combination ", have " surely ", " soon ", the characteristics such as " urging " of bio-feritlizer of chemical fertilizer in the organic fertilizer, fertilizer efficiency and utilization ratio thereof are improved greatly.The plant material of selecting for use in the compound fertilizer contains Mierocrystalline cellulose, hemicellulose, starch, various sugar, protein, amino acid, aminohexose, nucleic acid, Nucleotide etc., function with Pesticidal and sterilizing, using of agricultural chemicals be can reduce or exempt, residue chemical fertilizer and pesticide residue in the soil avoided; Main component is profitable strains such as photosynthetic bacteria, vinelandii, phosphate solubilizing bacteria, potassium solubilizing bacteria and the bacterium of becoming thoroughly decomposed in the used bio-fertilizer, plant is decomposed through enzymatic reaction, the mineralising of bio-fertilizer, the simple compounds that produces can directly be absorbed by plant, suppress soil disease, promote crop rhizosphere beneficial microorganism propagation, improve the crop rhizosphere ecotope.The increase of beneficial microorganism and disease-resistant factor also can reduce infecting of soil disease significantly, reduces continuous cropping crop disease index, uses year after year and can alleviate continuous cropping obstacle greatly.
This compound fertilizer is by the fermentation culture of biological bacteria in organic fertilizer, promote the activation of biological bacteria on the one hand, effect by contained vinelandii in the bio-fertilizer and photosynthetic bacteria on the other hand, make that residual fixed nitrogen is decomposed into quick-acting nitrogen gradually in the inorganic nitrogen that decomposites in the chemical fertilizer and the native soil, and promote its photosynthetic conversion.Equally, contained phosphate solubilizing bacteria, potassium solubilizing bacteria are decomposed into the phosphorus, the potassium that are fixed in inorganic phosphorus, potassium and the soil that decomposites in the chemical fertilizer to be easy to rapid available phosphorus and the available potassium that is absorbed by crop gradually in the bio-fertilizer.The utilization ratio of each nutritive element can be brought up to more than 60% thus, be reached the raising crop quality, produce the effect of the ecological crop product of nontoxic, look delicate flavour U.S..In addition, the biological flora in the bio-fertilizer can also be grown in soil in continual breeding, thereby makes soil activating, generally uses 3~5 years, and it is very soft that agricultural land soil becomes, and it is time saving and energy saving to cultivate, and labour intensity reduces greatly.Plant material in this compound fertilizer can produce a large amount of humic acidss in preparation process, it is good nitrification inhibitor, can prolong the retention time of blood urea nitrogen in soil, the environmental pollution that the nitrate that the elimination urea decomposition becomes, nitrite, oxynitride form.
Each component of green nutritional compound fertilizer of the present invention all can be received good application effect in following proportion by weight scope: 20~30 parts of plant materials, urea or 20~30 parts in ammonium nitrate, 5~7 parts of calcium superphosphate, 5~7 parts of potassium silicates, 3~7 parts of boraxs, 2~4 parts of Magnesium sulfate heptahydrates, 0.3~0.7 part in zinc sulfate, 0.3~0.7 part of chelated iron, 0.3~0.7 part of Sodium orthomolybdate, 3~6 parts of manganous sulfates, 0.01~0.03 part in copper sulfate, 0.01~0.03 part of Xiao Suangu, 1~5 part of bio-fertilizer.Wherein plant material be the root, stem, leaf of any one or various plants in chinaberry, acacia tree, Ailanthus altissima and the Pueraria lobota, really, wood, skin is with any proportioning matched combined; Also can adopt produce in the timber or the fruit course of processing waste material so that select the comprehensive utilization of plant material for use, reduce the production cost of compound fertilizer of the present invention.Trace elements such as described borax, Magnesium sulfate heptahydrate, zinc sulfate, chelated iron, Sodium orthomolybdate, manganous sulfate, copper sulfate, Xiao Suangu can adopt mineral substance such as crude boron stone, magnesium ore, zinc ore, iron ore, molybdenum ore, manganese ore, copper mine stone, cobalt ore respectively, bio-fertilizer can directly be bought on market, numb doctor's board bio-fertilizer of preferably selecting for use the Beijing Xinxin Shengda Bioengineering Technology Co., Ltd to produce, the main component of this bio-fertilizer is profitable strains such as photosynthetic bacteria, vinelandii, phosphate solubilizing bacteria, potassium solubilizing bacteria and the bacterium of becoming thoroughly decomposed.Below in conjunction with embodiment the preparation method of this compound fertilizer is described further.
Embodiment 1
The mass parts of each component raw material can be in the green nutritional compound fertilizer of the present invention: 20 parts of plant materials, urea or 20 parts in ammonium nitrate, 5 parts of calcium superphosphate, 5 parts of potassium silicates, 3 parts of boraxs, 2 parts of Magnesium sulfate heptahydrates, 0.3 part in zinc sulfate, 0.3 part of chelated iron, 0.3 part of Sodium orthomolybdate, 3 parts of manganous sulfates, 0.01 part in copper sulfate, 0.01 part of Xiao Suangu, 1 part of bio-fertilizer.
The preparation method of green nutritional compound fertilizer of the present invention is as follows:
To choose the chinaberry in the plant material earlier, the acacia tree, the root of any two kinds or various plants in Ailanthus altissima and the Pueraria lobota, stem, leaf, really, wood, the tailing that is produced in skin or its materials processing, slag charge, dry with any proportioning matched combined, pulverize 80 mesh sieves and made pure plant powder, take by weighing pure plant powder and bio-fertilizer by described proportioning then, after it is mixed, aqueous sulfuric acid with 5% is adjusted in pH value to 5~8 scopes, under normal temperature condition, stack fermentation 5~15 days, make the activation of fully becoming thoroughly decomposed under the effect of pure plant powder profitable strain in bio-fertilizer, make active organic fertilizer; Getting borax, Magnesium sulfate heptahydrate, zinc sulfate, chelated iron, Sodium orthomolybdate, manganous sulfate, copper sulfate, Xiao Suangu separated pulverizing again crosses 80 mesh sieves and makes various micro-powders: take by weighing active organic fertilizer, various micro-powder and urea or ammonium nitrate, calcium superphosphate, potassium silicate respectively by described proportioning raw materials at last, insert mixing and stirring in the stirrer, insert oven dry in the drying plant after the taking-up, bake out temperature is controlled in 30~60 ℃ of scopes, drying time 0.5~1.5 hour is made the compound dry mash; Again the compound dry mash is sent into and made the composite particles material of particle diameter in the tablets press, promptly make green nourishing composite fertilizer finished product at 4~6mm.In order to make the combination of long drives and drop shots of fertilizer efficiency release period, also compound granulated fertilizer and compound dry mash can be used after in 7: 3 ratio uniform mixing.
Embodiment 2
The mass parts of each component raw material can be in the green nutritional compound fertilizer of the present invention: 20~30 parts of plant materials, urea or 25 parts in ammonium nitrate, 6 parts of calcium superphosphate, 6 parts of potassium silicates, 5 parts of boraxs, 3 parts of Magnesium sulfate heptahydrates, 0.5 part in zinc sulfate, 0.5 part of chelated iron, 0.5 part of Sodium orthomolybdate, 4 parts of manganous sulfates, 0.02 part in copper sulfate, 0.02 part of Xiao Suangu, 3 parts of bio-fertilizers.Its preparation method is identical with embodiment 1, is that selected plant material and nitrogenous fertilizer raw material can change in conjunction with the particular case adjustment.
Embodiment 3
The mass parts of each component raw material can be in the green nutritional compound fertilizer of the present invention: 30 parts of plant materials, urea or 30 parts in ammonium nitrate, 7 parts of calcium superphosphate, 7 parts of potassium silicates, 7 parts of boraxs, 4 parts of Magnesium sulfate heptahydrates, 0.7 part in zinc sulfate, 0.7 part of chelated iron, 0.7 part of Sodium orthomolybdate, 6 parts of manganous sulfates, 0.03 part in copper sulfate, 0.03 part of Xiao Suangu, 5 parts of bio-fertilizers.Its preparation method is identical with embodiment 1, is that selected plant material and nitrogenous fertilizer raw material can change in conjunction with the particular case adjustment.

Claims (3)

1. one kind has green nutritional compound fertilizer, it is characterized in that: it is that preparation of raw material by following mass parts forms: 20~30 parts of plant materials, urea or 20~30 parts in ammonium nitrate, 5~7 parts of calcium superphosphate, 5~7 parts of potassium silicates, 3~7 parts of boraxs, 2~4 parts of Magnesium sulfate heptahydrates, 0.3~0.7 part in zinc sulfate, 0.3~0.7 part of chelated iron, 0.3~0.7 part of Sodium orthomolybdate, 3~6 parts of manganous sulfates, 0.01~0.03 part in copper sulfate, 0.01~0.03 part of Xiao Suangu, 1~5 part of bio-fertilizer.
2. green nutritional compound fertilizer according to claim 1, it is characterized in that: what described plant material was selected for use is root, stem, the leaf of plant Pueraria lobota, or select the processing clout of root, skin, branch, leaf or its timber of Ailanthus altissima or chinaberry or acacia tree for use, perhaps get in 4 kind of plant any more than 2 kinds with the compound of any proportioning.
3. preparation method who is used for the described green nutritional compound fertilizer of production claim 1, it is characterized in that: it comprises the following steps:
(1) preparation of plant material: the plant material of selecting for use is dried, and pulverizing 80 mesh sieves, to make pure plant powder standby;
(2) preparation of trace element materials: get borax, Magnesium sulfate heptahydrate, zinc sulfate, chelated iron, Sodium orthomolybdate, manganous sulfate, copper sulfate, Xiao Suangu separated pulverizing and cross 80 mesh sieves to make various micro-powders standby:
(3) fermentation: take by weighing pure plant powder and bio-fertilizer and mix by described proportioning, the aqueous sulfuric acid with 5% is adjusted pH value to 5~8, stacks under normal temperature condition and ferments 5~15 days, and it is standby to make active organic fertilizer;
(4) combination drying: take by weighing active organic fertilizer, various micro-powder and urea or ammonium nitrate, calcium superphosphate, potassium silicate mixing and stirring by described proportioning, insert oven dry in the drying plant, bake out temperature is 30~60 ℃, drying time 0.5~1.5 hour, it is standby to make the compound dry mash;
(5) granulation: the compound dry mash that makes is made the composite particles material of particle diameter at 4~6mm with granulating equipment;
(6) batch mixing:, promptly make the green nutritional compound fertilizer finished product with composite particles material and compound dry mash ratio uniform mixing in 7: 3.
CN200910227440A 2009-12-11 2009-12-11 Green nutritional compound fertilizer and method for preparing same Active CN101717296B (en)

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CN102249813A (en) * 2011-06-28 2011-11-23 顾智奇 Special chinaberry tree compound fertilizer for preventing and treating diseases and pests of Chinese herbal medicines, and preparation and application methods thereof
CN103320140A (en) * 2013-07-03 2013-09-25 山东浩成化工有限公司 Soil conditioner
CN103524199A (en) * 2013-02-22 2014-01-22 杨栓明 Compound fertilizer for green food production
CN103724123A (en) * 2013-12-20 2014-04-16 当涂县科辉商贸有限公司 Fertilizer prepared from plants and preparation method thereof
WO2014084714A1 (en) * 2012-11-30 2014-06-05 Universiti Putra Malaysia A composition for treating ganoderma disease in plants comprising silicium dioxide
CN104788251A (en) * 2015-01-30 2015-07-22 姜明光 Silicon-based biological type acid soil modifier and preparation method thereof
CN104845639A (en) * 2015-04-22 2015-08-19 吴迪 Soil conditioner preparation method
CN105330371A (en) * 2014-11-15 2016-02-17 深圳市芭田生态工程股份有限公司 Nutrition conditioning ecological fertilizer
CN107162852A (en) * 2017-06-10 2017-09-15 吉林省农业科学院 A kind of activator for phosphor element of soil and its preparation method and application
CN107814622A (en) * 2017-10-31 2018-03-20 蚌埠标优美生态工程有限公司 A kind of slow release fertilizer preparation method for promoting straw-returning
CN108147894A (en) * 2018-01-08 2018-06-12 淅川县源科生物科技有限公司 The production method of high activity SOD rice
CN108178683A (en) * 2018-01-08 2018-06-19 淅川县源科生物科技有限公司 The production method of high activity SOD pears
CN108260483A (en) * 2018-01-08 2018-07-10 淅川县源科生物科技有限公司 The production method of high activity SOD vegetables
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CN108260455A (en) * 2018-01-08 2018-07-10 淅川县源科生物科技有限公司 The production method of high activity SOD pomegranates
CN108260454A (en) * 2018-01-08 2018-07-10 淅川县源科生物科技有限公司 The production method of high activity SOD citruses
CN108260456A (en) * 2018-01-08 2018-07-10 淅川县源科生物科技有限公司 The production method of high activity SOD cherries
CN108260465A (en) * 2018-01-08 2018-07-10 淅川县源科生物科技有限公司 The production method of high activity SOD grapes
CN108283110A (en) * 2018-01-08 2018-07-17 淅川县源科生物科技有限公司 The production method of high activity SOD peanuts
CN108283109A (en) * 2018-01-08 2018-07-17 淅川县源科生物科技有限公司 The production method of high activity SOD Kiwi berrys
CN108283119A (en) * 2018-01-08 2018-07-17 淅川县源科生物科技有限公司 The production method of high activity SOD potato agricultural product
CN108456048A (en) * 2018-01-08 2018-08-28 淅川县源科生物科技有限公司 Application of the green nutritional compound fertilizer in producing high activity SOD apples
CN108450260A (en) * 2018-01-08 2018-08-28 淅川县源科生物科技有限公司 The production method of high activity SOD wheats
CN108456049A (en) * 2018-01-08 2018-08-28 淅川县源科生物科技有限公司 The production method of high activity SOD peaches
CN115010547A (en) * 2021-03-05 2022-09-06 张玉昌 Preparation method of special magnetic compound fertilizer for breeding
CN117534528A (en) * 2023-11-21 2024-02-09 宁夏大彩生物科技有限公司 Environment-friendly compound fertilizer

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CN102249813A (en) * 2011-06-28 2011-11-23 顾智奇 Special chinaberry tree compound fertilizer for preventing and treating diseases and pests of Chinese herbal medicines, and preparation and application methods thereof
WO2014084714A1 (en) * 2012-11-30 2014-06-05 Universiti Putra Malaysia A composition for treating ganoderma disease in plants comprising silicium dioxide
CN103524199A (en) * 2013-02-22 2014-01-22 杨栓明 Compound fertilizer for green food production
CN103320140A (en) * 2013-07-03 2013-09-25 山东浩成化工有限公司 Soil conditioner
CN103724123A (en) * 2013-12-20 2014-04-16 当涂县科辉商贸有限公司 Fertilizer prepared from plants and preparation method thereof
CN105330371A (en) * 2014-11-15 2016-02-17 深圳市芭田生态工程股份有限公司 Nutrition conditioning ecological fertilizer
CN104788251A (en) * 2015-01-30 2015-07-22 姜明光 Silicon-based biological type acid soil modifier and preparation method thereof
CN104845639A (en) * 2015-04-22 2015-08-19 吴迪 Soil conditioner preparation method
CN107162852A (en) * 2017-06-10 2017-09-15 吉林省农业科学院 A kind of activator for phosphor element of soil and its preparation method and application
CN107814622A (en) * 2017-10-31 2018-03-20 蚌埠标优美生态工程有限公司 A kind of slow release fertilizer preparation method for promoting straw-returning
CN108260483A (en) * 2018-01-08 2018-07-10 淅川县源科生物科技有限公司 The production method of high activity SOD vegetables
CN108260465A (en) * 2018-01-08 2018-07-10 淅川县源科生物科技有限公司 The production method of high activity SOD grapes
CN108147894A (en) * 2018-01-08 2018-06-12 淅川县源科生物科技有限公司 The production method of high activity SOD rice
CN108260457A (en) * 2018-01-08 2018-07-10 淅川县源科生物科技有限公司 The production method of high activity SOD tealeaves
CN108260455A (en) * 2018-01-08 2018-07-10 淅川县源科生物科技有限公司 The production method of high activity SOD pomegranates
CN108260454A (en) * 2018-01-08 2018-07-10 淅川县源科生物科技有限公司 The production method of high activity SOD citruses
CN108260456A (en) * 2018-01-08 2018-07-10 淅川县源科生物科技有限公司 The production method of high activity SOD cherries
CN108178683A (en) * 2018-01-08 2018-06-19 淅川县源科生物科技有限公司 The production method of high activity SOD pears
CN108283110A (en) * 2018-01-08 2018-07-17 淅川县源科生物科技有限公司 The production method of high activity SOD peanuts
CN108283109A (en) * 2018-01-08 2018-07-17 淅川县源科生物科技有限公司 The production method of high activity SOD Kiwi berrys
CN108283119A (en) * 2018-01-08 2018-07-17 淅川县源科生物科技有限公司 The production method of high activity SOD potato agricultural product
CN108456048A (en) * 2018-01-08 2018-08-28 淅川县源科生物科技有限公司 Application of the green nutritional compound fertilizer in producing high activity SOD apples
CN108450260A (en) * 2018-01-08 2018-08-28 淅川县源科生物科技有限公司 The production method of high activity SOD wheats
CN108456049A (en) * 2018-01-08 2018-08-28 淅川县源科生物科技有限公司 The production method of high activity SOD peaches
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CN117534528A (en) * 2023-11-21 2024-02-09 宁夏大彩生物科技有限公司 Environment-friendly compound fertilizer

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