CN101701110A - 凹凸棒防晒伞涂料 - Google Patents
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Abstract
本发明公开了一种凹凸棒防晒伞涂料，其技术方案的要点是，凹凸棒防晒伞涂料由膏状凹凸棒石粘土、四氧化三铁粉、三氧化二铁粉、绢云母粉、对甲氧基肉桂酸异戊酯、2-苯基苯并咪唑-5-磺酸、2-羟基-4-正辛氧基二苯甲酮、超细聚乙烯醇、改性羧甲基羟丙基纤维素、金红石型钛白粉和去离子水组成。凹凸棒防晒伞涂料粘度高，附着力强，容易粘附固结在防晒伞的面料纤维内部，在防晒伞面料上形成一层防护薄膜，可以长时间隔离、反射和吸收紫外线，防护人体不受紫外线照射引起的伤害。凹凸棒防晒伞涂料适用于涂刷在防晒伞的内外层面料上，也适用于涂刷在需要有防紫外线辐射功能的运动服、衬衫、长筒袜和帽子等制品上。
Description
技术领域
本发明涉及涂料，具体涉及一种凹凸棒防晒伞涂料。
背景技术
适量的紫外线辐射具有杀菌作用并能促进维生素的合成，有利于人体健康，但在烈日持续照射下，人体皮肤会失去抵御能力，易发生灼伤，出现红斑或水泡。过量的紫外线照射还会诱发皮肤病，甚至皮肤癌。
为了保护人体避免过量紫外线辐射，人们外出会使用太阳伞来阻挡紫外线的直射，太阳伞可以阻挡部分紫外线，但无法隔离、反射和吸收紫外线。
目前市场上有一些普通晴雨伞滥竽充数假冒防紫外线伞，多是在伞面上涂了一层银胶，经过几次阳光照射后就掉了色，只能遮挡部分阳光。
防晒涂料常使用纳米材料，纳米材料表面能高，粒子团聚现象突出，一般常规手段难分散，纳米材料不能均匀分布到涂料中，影响其功能的发挥。
用于防晒产品的涂料不同于一般的防晒霜，防晒霜是一次性使用产品，涂抹在皮肤后，过一段时间就会洗去，而用于防晒产品的涂料则需要有较长使用寿命，即能隔离和反射紫外线，又能有一定的耐热性能和抗氧化性能。
发明内容
本发明的目的是克服现有技术中不足之处，提供一种凹凸棒防晒伞涂料。
凹凸棒防晒伞涂料由膏状凹凸棒石粘土、四氧化三铁粉、三氧化二铁粉、绢云母粉、对甲氧基肉桂酸异戊酯、2-苯基苯并咪唑-5-磺酸、2-羟基-4-正辛氧基二苯甲酮、超细聚乙烯醇、改性羧甲基羟丙基纤维素、金红石型钛白粉和去离子水组成。
凹凸棒防晒伞涂料的生产方法是：配料、搅拌、粉碎、研磨、搅拌、脱气、罐装为凹凸棒防晒伞涂料的成品。
凹凸棒石粘土是一种含水富镁纳米级多孔纤维状硅酸盐粘土矿物，当凹凸棒石粘土中的凹凸棒含量≥80％以上时，其比表面积较大，可达500m2/g以上，大部分的阳离子、水分子和一定大小的有机分子均可直接被吸附进孔道中，其吸水性可达150％以上。
使用凹凸棒矿造浆生产工艺，将凹凸棒石粘土中的水云母、石英、蛋白石和碳酸盐等矿物筛选去除掉，得到一种膏状凹凸棒石粘土，具有超细微粒、摩擦硬度小、无砂粒感和柔软细腻无异味的特点。
膏状凹凸棒石粘土经过高速强力搅拌，成为一种分散性、触变性和胶黏性特好的天然凝胶体，粘度高达10000mPa·s以上，附着力、吸附性能和保湿性能都得到了进一步的提高。
四氧化三铁粉和三氧化二铁粉的颜色有利于将紫外线折射、反射和散射回去，具有隔离紫外线的功能，四氧化三铁粉和三氧化二铁粉都选用纳米级。
绢云母粉能吸收紫外线，高效率屏蔽紫外线，提高凹凸棒防晒伞涂料涂膜层的机械性能和抗透水性，增强涂膜与伞面的附着力，还能进一步延缓凹凸棒防晒伞涂料的老化。
对甲氧基肉桂酸异戊酯对紫外线吸收效果好。
2-苯基苯并咪唑-5-磺酸是一种紫外线吸收剂，其吸收紫外线的能力是普通吸收剂的三倍以上。
2-羟基-4-正辛氧基二苯甲酮是一种性能卓越的高效防老化助剂，能吸收240-340钠米的紫外线，有良好的光稳定效果。
超细聚乙烯醇粉末易溶于水，粘度稳定，不受弱酸、弱碱或有机溶剂的影响，耐油性高，易成膜，形成的薄膜无色透明，具有良好的机械强度，表面光洁而不发粘。
改性羧甲基羟丙基纤维素能迅速溶解于冷水或热水，具有良好的触变性性能，耐盐性和耐酸性性能优越，粘度高，增稠剂效果好。
金红石型钛白粉耐光性非常强，遮盖力好，当阳光照到皮肤上时，能将损害皮肤的紫外线折射、反射和散射回去，有利于减少了紫外线直接接触到人体的皮肤，金红石型钛白粉选用纳米级。
本发明通过下述技术方案予以实现：
1、凹凸棒防晒伞涂料的配料按重量百分比由下列组分组成：膏状凹凸棒石粘土20～55％、四氧化三铁粉5～15％、三氧化二铁粉3～15％、绢云母粉2～15％、对甲氧基肉桂酸异戊酯1～8％、2-苯基苯并咪唑-5-磺酸1～5％、2-羟基-4-正辛氧基二苯甲酮1～5％、超细聚乙烯醇0.5～5％、改性羧甲基羟丙基纤维素0.5～5％、金红石型钛白粉0.5～5％和去离子水5～40％。
2、凹凸棒防晒伞涂料的生产方法是：(1)将凹凸棒防晒伞涂料的配料加入搅拌机内进行低速搅拌混合均匀后，输入粉碎打浆机中进行粉碎打浆为凹凸棒防晒伞涂料的混合物；(2)将步骤(1)获得的混合物输入多功能胶体磨中进行研磨为糊状混合物，颗粒细度小于0.005毫米；(3)将步骤(2)获得的研磨后的糊状混合物，输入超高速搅拌机中进行高速强力搅拌为膏状半成品；(4)将步骤(3)获得的膏状半成品进行真空脱气工艺处理，罐装为凹凸棒防晒伞涂料的成品。
所述膏状凹凸棒石粘土的生产工艺：将凹凸棒矿输入搅拌机内搅拌，经挤出机挤压成片状后，再次输入搅拌机内搅拌，经挤出机挤压成片状后自然晾晒，晾干的凹凸棒矿输送到原料池中浸泡，用气泵冲翻，沉淀后放出浸泡水，筛去杂质，输入半成品池中，重新加水浸泡，用气泵冲翻，沉淀后放出浸泡水，并将沉淀后的泥浆输送到成品池内，即为膏状凹凸棒石粘土。
本生产工艺是采用由本发明人于2004年1月6日申请的“凹凸棒矿造浆生产工艺”，中国专利授权公告号为：CN1287965C，授权公告日：2006年12月6日。
所述膏状凹凸棒石粘土按重量百分比由下列组分组成：凹凸棒石粘土25～40％，水60～75％。
金红石型钛白粉、四氧化三铁粉和三氧化二铁粉添加在凹凸棒防晒伞涂料中，经过搅拌、分散和研磨后能够长期静置不沉降，有利于提高金红石型钛白粉、四氧化三铁粉和三氧化二铁粉的分散性和稳定性。
凹凸棒防晒伞涂料粘度高，附着力强，容易粘附固结在防晒伞的面料纤维内部，在防晒伞面料上形成一层防护薄膜，可以长时间隔离、反射和吸收紫外线，防护人体不受紫外线照射引起的伤害。
凹凸棒防晒伞涂料具有良好的隔热防晒、防水、抗氧化和装饰功能，使用寿命长。
凹凸棒防晒伞涂料适用于涂刷在防晒伞的内外层面料上，也适用于涂刷在需要有防紫外线辐射功能的运动服、衬衫、长筒袜和帽子等制品上。
具体实施方式
下面结合实施例对本发明作进一步的描述：
1、凹凸棒防晒伞涂料的配料按重量百分比由下列组分组成：膏状凹凸棒石粘土32％、四氧化三铁粉10％、三氧化二铁粉8％、绢云母粉6％、对甲氧基肉桂酸异戊酯5％、2-苯基苯并咪唑-5-磺酸3％、2-羟基-4-正辛氧基二苯甲酮2％、超细聚乙烯醇2％、改性羧甲基羟丙基纤维素1％、金红石型钛白粉1％和去离子水30％。
2、凹凸棒防晒伞涂料的生产方法是：(1)将凹凸棒防晒伞涂料的配料加入搅拌机内进行低速搅拌混合均匀后，输入粉碎打浆机中进行粉碎打浆为凹凸棒防晒伞涂料的混合物；(2)将步骤(1)获得的混合物输入多功能胶体磨中进行研磨为糊状混合物，颗粒细度小于0.005毫米；(3)将步骤(2)获得的研磨后的糊状混合物，输入超高速搅拌机中进行高速强力搅拌为膏状半成品；(4)将步骤(3)获得的膏状半成品进行真空脱气工艺处理，罐装为凹凸棒防晒伞涂料的成品。
所述膏状凹凸棒石粘土按重量百分比由下列组分组成：凹凸棒石粘土35％，水65％。
Claims (1)
1.一种凹凸棒防晒伞涂料，其特征在于，凹凸棒防晒伞涂料的配料按重量百分比由下列组分组成：膏状凹凸棒石粘土20～55％、四氧化三铁粉5～15％、三氧化二铁粉3～15％、绢云母粉2～15％、对甲氧基肉桂酸异戊酯1～8％、2-苯基苯并咪唑-5-磺酸1～5％、2-羟基-4-正辛氧基二苯甲酮1～5％、超细聚乙烯醇0.5～5％、改性羧甲基羟丙基纤维素0.5～5％、金红石型钛白粉0.5～5％和去离子水5～40％；
所述膏状凹凸棒石粘土按重量百分比由下列组分组成：凹凸棒石粘土25～40％，水60～75％。
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102330343A (zh) * | 2011-07-27 | 2012-01-25 | 吴江市瑞丰织造有限公司 | 织物用紫外线屏蔽涂料 |
| CN103740244A (zh) * | 2013-11-22 | 2014-04-23 | 池州市英派科技有限公司 | 一种水性高紫外阻隔涂料 |
| CN107297806A (zh) * | 2017-07-27 | 2017-10-27 | 安徽美景工艺品有限公司 | 一种竹制花盆的制作方法 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102330343A (zh) * | 2011-07-27 | 2012-01-25 | 吴江市瑞丰织造有限公司 | 织物用紫外线屏蔽涂料 |
| CN103740244A (zh) * | 2013-11-22 | 2014-04-23 | 池州市英派科技有限公司 | 一种水性高紫外阻隔涂料 |
| CN107297806A (zh) * | 2017-07-27 | 2017-10-27 | 安徽美景工艺品有限公司 | 一种竹制花盆的制作方法 |
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| CN101701110B (zh) | 2011-06-15 |
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