CN101669520A - Air conditioning filter screen bacteriostatic agent and preparation method thereof as well as preparation method of air conditioning filter screen - Google Patents
Air conditioning filter screen bacteriostatic agent and preparation method thereof as well as preparation method of air conditioning filter screen Download PDFInfo
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- CN101669520A CN101669520A CN200910131517A CN200910131517A CN101669520A CN 101669520 A CN101669520 A CN 101669520A CN 200910131517 A CN200910131517 A CN 200910131517A CN 200910131517 A CN200910131517 A CN 200910131517A CN 101669520 A CN101669520 A CN 101669520A
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Abstract
The invention relates to an air conditioning filter screen bacteriostatic agent and a preparation method thereof as well as a preparation method of an air conditioning filter screen. The air conditioning filter screen bacteriostatic agent comprises a surfactant and nano silver sol solution with the particle size of 10-100nm. The preparation method of the air conditioning filter screen bacteriostatic agent comprises the following steps: an oxidant containing silver and a reducing agent are reacted in environment with the existence of a protective agent so as to form nano silver colloid; and thesurfactant is used for treating the nano silver colloid, and the nano silver air conditioning filter screen bacteriostatic agent is prepared. The method for preparing the air conditioning filter screen by utilizing the bacteriostatic agent comprises the following steps: the air conditioning filter screen bacteriostatic agent is diluted and sprayed on the air conditioning filter screen; and the air conditioning filter screen is dried so as to obtain the air conditioning filter screen with an antibacterial function. The air conditioning filter screen bacteriostatic agent has favorable permeability, wettability and rewettability to fibers, can enable the air conditioning filter screen to have lasting bacteriostasis property with high efficiency, and has simple preparation process and low cost. The invention can efficiently improve the quality of air filtered by an air conditioning and prevent secondary pollution.
Description
Technical field
The present invention relates to a kind ofly be used for the bacteriostatic agent of air-conditioning filter net and have the preparation method of the air-conditioning filter net of bacteria resistance function, be specifically related to the preparation method of a kind of Nano Silver air-conditioning filter net bacteriostatic agent and Nano Silver air-conditioning filter net.
Background technology
Along with the raising day by day of people's living standard, can be the central air-conditioning that the air-conditioning that people bring a home from home, particularly public place generally use and generally be used for daily life and work.But, because the filter screen of air-conditioning inside creates suitable condition can for growth of bacterium and breeding, therefore, when air-conditioning work, bacterium on its filter screen (as Legionella etc.) very easily pollute room air through air exchange, thus people's health is constituted huge threat.
Present treatment measures to air-conditioning filter net mainly contain in chemical bactericide sterilization, ultra violet lamp or the filter screen adds activated carbon, but chemical bactericide disposable sterilization and bacterium often is easy to generate drug resistance and makes a variation, and the toxic composition that volatilizees easily; Symptoms such as the ultra violet lamp method is by air is produced ozone by ultraviolet irradiation, thereby plays bactericidal action, produces headache but the long-term existence of ozone can cause human body, and is uncomfortable in chest; Though and the bacterium of the adsorbable some of activated carbon, and contaminated air does not just have ability to stop breeding and the growth of bacterium when its absorption reaches after full.
For overcoming the defective of conventional method, people are developed the air-conditioning filter net bacteriostatic agent that multiple other form, for example, the invention in Chinese patent publication number CN1580219, open day on February 16th, 2005 proposes a kind of long-acting air conditioning purge agent, it is by adding surfactant in water, film forming agent, bactericide etc. and make.But the bactericide that adopts in this clarificant is bactericide such as quaternary ammonium salt, imidazoline, and its sterilization mechanism is a chemism, so the air conditioner filter screen of wherethrough reason causes secondary pollution easily.Again for example; the invention in China Patent No. ZL200510062319.8, open day on July 19th, 2006 proposes a kind of preparation method of inorganic material carried nanometer silver sol; it is by after dissolving silver nitrate; add inorganic nano material colloidal sol, protectant, stabilizing agent and reductant successively, thereby make inorganic carrier nano silver colloidal sol.It is online that this colloidal sol can be applied to air conditioning filter, but this colloidal sol is difficult to evenly spray to the air conditioner filter screen surface, thereby make its antibacterial bacteriostatic effect relatively poor, and if the method by improving quantity for spray to increase the cover degree of this colloidal sol on the screen pack surface, then often causes increasing substantially of cost.
Summary of the invention
The objective of the invention is to propose a kind of fiber to be had excellent permeability, wetability and wetability again, and preparation method with air-conditioning filter net bacteriostatic agent He this bacteriostatic agent of persistent high efficiency fungistatic effect, and a kind of technology is succinct, with low cost, and can make air-conditioning filter net have the preparation method of the air-conditioning filter net of persistent high efficiency bacteriostasis property, to overcome deficiency of the prior art.
For achieving the above object, the present invention has adopted following technical scheme:
A kind of air-conditioning filter net bacteriostatic agent, it is characterized in that composition and mass percentage content thereof that this bacteriostatic agent comprises are: the nano silver colloidal sol liquid of surfactant 0.01~1% and surplus, the particle diameter of Nano Silver is 10~100nm in this nano silver colloidal sol.
Described surfactant is the non-ionic surfactant polyoxyethylene ether compound.
A kind of preparation method of air-conditioning filter net bacteriostatic agent; it is characterized in that; this method is: at first the argentiferous Oxidizing and Reducing Agents is reacted in the environment that has protectant to exist; form nano silver colloid; then with surfactant this nano silver colloid is handled again, made Nano Silver air-conditioning filter net bacteriostatic agent.
This method is specially:
At first that argentiferous oxidant, reductant and protectant is water-soluble, form oxidizing agent solution, reductant solution and protectant solution respectively;
Then, oxidizing agent solution and reductant solution are slowly dropped in the protectant solution, accompany by stirring simultaneously, after dropwising to oxidizing agent solution and reductant solution, fully mix reaction solution, obtain the nano silver colloidal sol liquid of particle diameter at 10~100nm;
Thereafter, add surfactant in nano silver colloidal sol liquid, and stir, form the air-conditioning filter net bacteriostatic agent, the mass percentage content of surfactant is 0.01~1% in this air-conditioning filter net bacteriostatic agent.
In the described oxidizing agent solution, the mol ratio of argentiferous oxidant and water is 0.1~50: 1000, and in the described reductant liquid, the mol ratio of reductant and water is 0.01~50: 1000, and in the described protectant solution, the mol ratio of protectant and water is 0.01~50: 1000.
Described oxidizing agent solution and reductant solution are that the speed with 30~3000/min drops in the protectant solution; and also the speed with 100~500rpm stirs protectant solution when dripping; after treating that oxidizing agent solution and reductant solution dropwise, continue to mix reaction solution 0.5~3h.
Described argentiferous oxidant comprises silver nitrate, and described reductant is one or several the combination in hydrazine hydrate, ascorbic acid, the potassium borohydride, and described protectant is one or several the combination in amino acid, polyvinyl alcohol or the dodecyl sodium sulfonate.
Described surfactant is the non-ionic surfactant polyoxyethylene ether compound.
A kind of preparation method of air-conditioning filter net, it is characterized in that, this method is: with surfactant particle diameter is handled at the nano silver colloid liquid of 10~100nm, make the air-conditioning filter net bacteriostatic agent, should silver air-conditioning filter net bacteriostatic agent dilute thereafter, it is online to spray to air conditioning filter again, at last this air-conditioning filter net is carried out drying and handles, and makes the air-conditioning filter net with antibacterial functions.
This method is specially:
Argentiferous oxidant, reductant and protectant is water-soluble respectively, form oxidizing agent solution, reductant solution and protectant solution, wherein, the argentiferous oxidant in the oxidizing agent solution and the mol ratio of water are 0.1~50: 1000, the reductant in the reductant liquid and the mol ratio of water are 0.01~50: 1000, and the protectant in the protectant solution and the mol ratio of water are 0.01~50: 1000;
Oxidizing agent solution and the reductant solution speed with 30~3000/min is dropped in the protectant solution, and also the speed with 100~500rpm stirs protectant solution when dripping, after treating that oxidizing agent solution and reductant solution dropwise, continue to mix reaction solution 0.5~3h, obtain the nano silver colloidal sol liquid of particle diameter at 10~100nm;
In nano silver colloidal sol liquid, add the non-ionic surfactant polyoxyethylene ether compound, and stir, form the air-conditioning filter net bacteriostatic agent, wherein, the non-ionic surfactant polyoxyethylene ether compound is 0.01~1% in the mass percentage content of air-conditioning filter net bacteriostatic agent;
The air-conditioning filter net bacteriostatic agent is diluted with water, and silver content is at 200~300mg/kg in the air-conditioning filter net bacteriostatic agent to the dilution, and it is online it to be sprayed to air conditioning filter again;
Be to dry under 50~80 ℃ the condition with the air-conditioning filter net natural air drying or in temperature, make air-conditioning filter net with antibacterial functions.
Among the present invention by in the nano silver antibacterial agent, add can with the compatible non-ionic surfactant polyoxyethylene ether compound of nano silver colloid, thereby make this bacteriostatic agent have good penetration, wetability, wetability again to fiber.These bacteriostatic agents can be loaded into air-conditioning filter net rapidly and uniformly by conventional spraying method, particularly on the air conditioning for automobiles screen pack, thereby make it have the bacteriostasis antibiosis function of persistent high efficiency, effectively improve the air quality in the enclosure spaces such as room or automobile, prevented the secondary pollution that produces because of air-conditioning filter net.With the be treated to example of this air-conditioning filter net bacteriostatic agent to the air conditioning for automobiles screen pack, the air-conditioning filter net bacteriostatic agent that each air conditioning for automobiles screen pack only need spray about 50ml gets final product, cost is very cheap, and this filter screen still reaches more than 99.9% to the bacteriostasis rate of bacterium after running car reaches 10000km, thereby effectively improved the quality of automobile air, brought Gospel for driver and passenger.
The main component of air-conditioning filter net bacteriostatic agent is a nano silver colloidal sol among the present invention, it has long-acting, broad-spectrum restraining and sterilizing bacteria performance, 650 various bacteria had extremely strong inhibition ability, antibiotic lastingly potent and do not develop immunity to drugs, to the effect of skin nonirritant, to had no corrosive effect on metals, do not contain poisonous harmful components.In addition, the preferred APEO compounds that adopts is as surfactant among the present invention, and its addition had better effect at 1% o'clock.
Compared with prior art, beneficial effect of the present invention is: this air-conditioning filter net bacteriostatic agent has excellent permeability, wetability and wetability again to fiber, and has a persistent high efficiency fungistatic effect, and preparation technology is simple, preparation method's technology of this air-conditioning filter net is succinct, with low cost, and can make air-conditioning filter net have the persistent high efficiency bacteriostasis property.The present invention can be cheap cost suppress the growth of the online bacterium of air conditioning filter for a long time efficiently, improve the quality of air conditioning filter air, effectively prevent secondary pollution.
Embodiment
Below in conjunction with specific embodiment content of the present invention is described in further detail.
The preparation method of embodiment 1 this air-conditioning filter net bacteriostatic agent is:
The 10g polyvinyl alcohol is dissolved in the 2L deionized water, is mixed with protectant solution;
The 3g ascorbic acid is dissolved in the 2L deionized water preparation reductant solution;
The 9g silver nitrate is dissolved in the 1L deionized water, is prepared into the argentiferous oxidizing agent solution;
Reductant liquid and the argentiferous oxidizing agent solution speed with 30~100/min slowly is added drop-wise in the reductant solution, accompanies by the stirring of speed simultaneously, wait to dropwise the back and continue to stir 1h, obtain the nano silver colloidal sol liquid of average grain diameter at 80nm at 100~200rpm;
Stir behind the interpolation JFC in nano silver colloidal sol liquid and obtain the air-conditioning filter net bacteriostatic agent, wherein the mass percentage content of JFC is 0.1%, and the silver content that adopts chemical analysis method Fo Erhadefa to measure in this air-conditioning filter net bacteriostatic agent is 1144mg/kg;
Adopt the mode of spraying to be sprayed onto on the air conditioning for automobiles screen pack with after 5 times of the deionized water dilutions air-conditioning filter net bacteriostatic agent, then this screen pack is dried naturally, obtain having the air conditioning for automobiles screen pack of antibacterial functions.
This air conditioning for automobiles screen pack is tested its anti-microbial property according to JIS-L1902:1998, and the result shows, this air conditioning for automobiles screen pack all reaches 2.5 to Escherichia coli and staphylococcus aureus bacteriostatic activity value and bactericidal activity value, is converted into bacteriostasis rate and reaches 99.9%.Test result is as follows:
This air conditioning for automobiles screen pack is installed on the automobile, behind running car 5000km and 10000km, test its anti-microbial property according to IS-L1902:1998 respectively, the result shows, it all reaches 2.5 to Escherichia coli and staphylococcus aureus bacteriostatic activity value and bactericidal activity value, is converted into bacteriostasis rate and reaches 99.9%.Test result is as follows.
The preparation method of embodiment 2 these air-conditioning filter net bacteriostatic agents is:
45g neopelex and 55g amino acid are dissolved in 21 deionized waters, are mixed with protectant solution;
100g ascorbic acid and 50g hydrazine hydrate are dissolved in the 2L deionized water, are mixed with reductant solution;
The 25.5g silver nitrate is dissolved in the 1L deionized water, is prepared into the argentiferous oxidizing agent solution;
Reductant solution and oxidizing agent solution be added drop-wise in the protectant solution with the speed of 500~1000/min react; accompany by the stirring of speed simultaneously at 200~300rpm; continue to mix reaction solution 2h after waiting to dropwise, obtain the nano silver colloidal sol liquid of average grain diameter at 20~40nm.
Stir behind the interpolation JFC in nano silver colloidal sol liquid and obtain the air-conditioning filter net bacteriostatic agent, wherein the mass percentage content of JFC is 0.05%, and the silver content that adopts chemical analysis method Fo Erhadefa to measure in this air-conditioning filter net bacteriostatic agent is 250mg/kg;
Adopt the mode of spraying to be sprayed onto on the air conditioning for automobiles screen pack with after 5 times of the deionized water dilutions air-conditioning filter net bacteriostatic agent, then with this screen pack 50~60 ℃ of oven dry, obtain having the air conditioning for automobiles screen pack of antibacterial functions.
This air conditioning for automobiles screen pack is tested anti-microbial property according to JIS-L1902:1998, and the result shows that it all reaches 2.5 to Escherichia coli and staphylococcus aureus bacteriostatic activity value and bactericidal activity value, is converted into bacteriostasis rate and reaches 99.9%.Behind running car 5000km and 10000km, this air conditioning for automobiles filter screen still remains on more than 99.9% the bacteriostasis rate of Escherichia coli and staphylococcus aureus.
The preparation method of embodiment 3 these air-conditioning filter net bacteriostatic agents is:
300g polyvinyl alcohol and 50g amino acid are dissolved in the 10L deionized water, are mixed with protectant solution;
The 200g potassium borohydride is dissolved in the 2L deionized water, is mixed with reductant solution;
The 90g silver nitrate is dissolved in the 2L deionized water, is prepared into the argentiferous oxidizing agent solution;
Reductant solution and oxidizing agent solution be added drop-wise in the protectant solution with the speed of 1000~3000/min react, accompany by the stirring of speed simultaneously at 300~500rpm, continue to mix reaction solution 0.5h after waiting to dropwise, obtain the nano silver colloidal sol liquid of average grain diameter at 60nm;
Stir behind the interpolation JFC in nano silver colloidal sol liquid and obtain the air-conditioning filter net bacteriostatic agent, wherein the mass percentage content of JFC is 0.01%, and the silver content that adopts chemical analysis method Fo Erhadefa to measure in this air-conditioning filter net bacteriostatic agent is 4084mg/kg;
Adopt the mode of spraying to be sprayed onto on the air conditioning for automobiles screen pack with after 12 times of the deionized water dilutions air-conditioning filter net bacteriostatic agent, then with this screen pack 60~80 ℃ of oven dry, obtain having the air conditioning for automobiles screen pack of antibacterial functions.
This air conditioning for automobiles screen pack is tested anti-microbial property according to JIS-L1902:1998, and the result shows that it all reaches 2.5 to Escherichia coli and staphylococcus aureus bacteriostatic activity value and bactericidal activity value, is converted into bacteriostasis rate and reaches 99.9%.Behind running car 5000km and 10000km, after tested, the air conditioning for automobiles filter screen to the bacteriostasis rate of Escherichia coli and staphylococcus aureus still more than 99.9%.
The foregoing description only is explanation technical conceive of the present invention and characteristics, and its purpose is to allow the personage who is familiar with this technology can understand content of the present invention and enforcement according to this, can not limit protection scope of the present invention with this.All equivalences that spirit essence is done according to the present invention change or modify, and all should be encompassed within protection scope of the present invention.
Claims (10)
1. air-conditioning filter net bacteriostatic agent, it is characterized in that composition and mass percentage content thereof that this bacteriostatic agent comprises are: the nano silver colloidal sol liquid of surfactant 0.01~1% and surplus, the particle diameter of Nano Silver is 10~100nm in this nano silver colloidal sol.
2. air-conditioning filter net bacteriostatic agent according to claim 1 is characterized in that described surfactant is the non-ionic surfactant polyoxyethylene ether compound.
3. preparation method of air-conditioning filter net bacteriostatic agent according to claim 1; it is characterized in that; this method is: at first the argentiferous Oxidizing and Reducing Agents is reacted in the environment that has protectant to exist; form nano silver colloid; then with surfactant this nano silver colloid is handled again, made Nano Silver air-conditioning filter net bacteriostatic agent.
4. the preparation method of the bacteriostatic agent of air-conditioning filter net according to claim 1 according to claim 3 is characterized in that, this method is specially:
At first that argentiferous oxidant, reductant and protectant is water-soluble, form oxidizing agent solution, reductant solution and protectant solution respectively;
Then, oxidizing agent solution and reductant solution are slowly dropped in the protectant solution, accompany by stirring simultaneously, after dropwising to oxidizing agent solution and reductant solution, fully mix reaction solution, obtain the nano silver colloidal sol liquid of particle diameter at 10~100nm;
Thereafter, add surfactant in nano silver colloidal sol liquid, and stir, form the air-conditioning filter net bacteriostatic agent, the mass percentage content of surfactant is 0.01~1% in this air-conditioning filter net bacteriostatic agent.
5. the preparation method of the bacteriostatic agent of air-conditioning filter net according to claim 1 according to claim 4; it is characterized in that in the described oxidizing agent solution; the mol ratio of argentiferous oxidant and water is 0.1~50: 1000; in the described reductant liquid; the mol ratio of reductant and water is 0.01~50: 1000; in the described protectant solution, the mol ratio of protectant and water is 0.01~50: 1000.
6. the preparation method of the bacteriostatic agent of air-conditioning filter net according to claim 1 according to claim 4; it is characterized in that described oxidizing agent solution and reductant solution are that speed with 30~3000/min drops in the protectant solution; and also the speed with 100~500rpm stirs protectant solution when dripping; after treating that oxidizing agent solution and reductant solution dropwise, continue to mix reaction solution 0.5~3h.
7. according to the preparation method of claim 3 or the 4 or 5 described bacteriostatic agents of air-conditioning filter net according to claim 1; it is characterized in that described argentiferous oxidant comprises silver nitrate; described reductant is one or several the combination in hydrazine hydrate, ascorbic acid, the potassium borohydride, and described protectant is one or several the combination in amino acid, polyvinyl alcohol or the dodecyl sodium sulfonate.
8. according to the preparation method of claim 3 or the 4 described bacteriostatic agents of air-conditioning filter net according to claim 1, it is characterized in that described surfactant is the non-ionic surfactant polyoxyethylene ether compound.
9. the preparation method of an air-conditioning filter net, it is characterized in that, this method is: with surfactant particle diameter is handled at the nano silver colloid liquid of 10~100nm, make the air-conditioning filter net bacteriostatic agent, should silver air-conditioning filter net bacteriostatic agent dilute thereafter, it is online to spray to air conditioning filter again, at last this air-conditioning filter net is carried out drying and handles, and makes the air-conditioning filter net with antibacterial functions.
10. the preparation method of air-conditioning filter net according to claim 9 is characterized in that, this method is specially:
Argentiferous oxidant, reductant and protectant is water-soluble respectively, form oxidizing agent solution, reductant solution and protectant solution, wherein, the argentiferous oxidant in the oxidizing agent solution and the mol ratio of water are 0.1~50: 1000, the reductant in the reductant liquid and the mol ratio of water are 0.01~50: 1000, and the protectant in the protectant solution and the mol ratio of water are 0.01~50: 1000;
Oxidizing agent solution and the reductant solution speed with 30~3000/min is dropped in the protectant solution, and also the speed with 100~500rpm stirs protectant solution when dripping, after treating that oxidizing agent solution and reductant solution dropwise, continue to mix reaction solution 0.5~3h, obtain the nano silver colloidal sol liquid of particle diameter at 10~100nm;
In nano silver colloidal sol liquid, add the non-ionic surfactant polyoxyethylene ether compound, and stir, form the air-conditioning filter net bacteriostatic agent, wherein, the non-ionic surfactant polyoxyethylene ether compound is 0.01~1% in the mass percentage content of air-conditioning filter net bacteriostatic agent;
The air-conditioning filter net bacteriostatic agent is diluted with water, and silver content is at 200~300mg/kg in the air-conditioning filter net bacteriostatic agent to the dilution, and it is online it to be sprayed to air conditioning filter again;
Be to dry under 50~80 ℃ the condition with the air-conditioning filter net natural air drying or in temperature, make air-conditioning filter net with antibacterial functions.
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Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2010143075A2 (en) * | 2009-06-10 | 2010-12-16 | Willoughby Andrew J M | Dental uses of silver hydrosol |
CN104841202A (en) * | 2015-04-21 | 2015-08-19 | 漳州康创净化材料有限公司 | Preparation technology of filter screen |
CN105113216A (en) * | 2015-09-15 | 2015-12-02 | 浙江金海环境技术股份有限公司 | Antiviral air filtering net and manufacturing method and application thereof |
CN107213789A (en) * | 2017-07-12 | 2017-09-29 | 合肥轻风飏电气科技有限责任公司 | A kind of air purifier antibiotic filter screen |
CN107646895A (en) * | 2017-08-09 | 2018-02-02 | 深圳沃海森科技有限公司 | Bacteriostatic agent of air-conditioning air inlet and preparation method thereof |
CN107668093A (en) * | 2017-08-08 | 2018-02-09 | 深圳沃海森科技有限公司 | Environment-friendly long-life type air conditioner filter element bacteriostatic agent and preparation method thereof |
CN108018744A (en) * | 2017-11-08 | 2018-05-11 | 天津科技大学 | A kind of preparation method of multifunctional modification filter paper |
CN109925789A (en) * | 2019-02-14 | 2019-06-25 | 安徽宏凤空调滤网有限公司 | A kind of long acting antibiotic anti-mite air-conditioning filter net and preparation method thereof |
CN112774314A (en) * | 2020-12-16 | 2021-05-11 | 哈尔滨工业大学(深圳) | Nano metal particle coating method for improving bacteriostatic activity of filter layer and mask |
CN113144752A (en) * | 2021-04-30 | 2021-07-23 | 安阳振动器有限责任公司 | Preparation method of special composite filter screen for air purification of train carriage |
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Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2010143075A2 (en) * | 2009-06-10 | 2010-12-16 | Willoughby Andrew J M | Dental uses of silver hydrosol |
WO2010143075A3 (en) * | 2009-06-10 | 2011-04-21 | Willoughby Andrew J M | Silver hydrosol, dental applications and other uses thereof |
CN104841202A (en) * | 2015-04-21 | 2015-08-19 | 漳州康创净化材料有限公司 | Preparation technology of filter screen |
CN105113216A (en) * | 2015-09-15 | 2015-12-02 | 浙江金海环境技术股份有限公司 | Antiviral air filtering net and manufacturing method and application thereof |
CN107213789A (en) * | 2017-07-12 | 2017-09-29 | 合肥轻风飏电气科技有限责任公司 | A kind of air purifier antibiotic filter screen |
CN107668093A (en) * | 2017-08-08 | 2018-02-09 | 深圳沃海森科技有限公司 | Environment-friendly long-life type air conditioner filter element bacteriostatic agent and preparation method thereof |
CN107646895A (en) * | 2017-08-09 | 2018-02-02 | 深圳沃海森科技有限公司 | Bacteriostatic agent of air-conditioning air inlet and preparation method thereof |
CN108018744A (en) * | 2017-11-08 | 2018-05-11 | 天津科技大学 | A kind of preparation method of multifunctional modification filter paper |
CN109925789A (en) * | 2019-02-14 | 2019-06-25 | 安徽宏凤空调滤网有限公司 | A kind of long acting antibiotic anti-mite air-conditioning filter net and preparation method thereof |
CN113959039A (en) * | 2020-03-23 | 2022-01-21 | 艾感科技(广东)有限公司 | Evaluation device and method for loss state of nanofiber membrane |
CN112774314A (en) * | 2020-12-16 | 2021-05-11 | 哈尔滨工业大学(深圳) | Nano metal particle coating method for improving bacteriostatic activity of filter layer and mask |
CN112774314B (en) * | 2020-12-16 | 2022-10-21 | 哈尔滨工业大学(深圳) | Nano metal particle coating method for improving bacteriostatic activity of filter layer and mask |
CN113144752A (en) * | 2021-04-30 | 2021-07-23 | 安阳振动器有限责任公司 | Preparation method of special composite filter screen for air purification of train carriage |
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