CN101658980A - Open arc overlaying wire material with strong abrasive resistance for grinding roller and grinding disk - Google Patents

Open arc overlaying wire material with strong abrasive resistance for grinding roller and grinding disk Download PDF

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Publication number
CN101658980A
CN101658980A CN200810146876A CN200810146876A CN101658980A CN 101658980 A CN101658980 A CN 101658980A CN 200810146876 A CN200810146876 A CN 200810146876A CN 200810146876 A CN200810146876 A CN 200810146876A CN 101658980 A CN101658980 A CN 101658980A
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China
Prior art keywords
grinding
open arc
nano
grinding roller
wire material
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Granted
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CN200810146876A
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Chinese (zh)
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CN101658980B (en
Inventor
周华荣
胡小海
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JIANGXI HENGDA HI-TECH CO LTD
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Beijing Dongfang Jingge Technology Development Co Ltd
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Abstract

The present invention provides an open arc overlaying wire material with strong abrasive resistance for a grinding roller and a grinding disk, which consists of a steel sheet and powder arranged in the steel sheet. A nano additive (A) is added into the powder, wherein the nano additive (A) can be one or any combination of three of nano TiN (titanium nitride), nano SiN (silicon nitride) and nano SiC (silicon carbide). The powder contains 3 to 5 weight percent of the nano additive (A). The nano additive (A) has the functions of strengthening dispersion of nano ceramic phases, improves cohesion strength, rupture strength and combination strength of a cladding layer material and has good high-temperature stability; and the nano additive (A) improves self lubricity of the material, improves theabrasive resistance of cladding layer metals and prolongs service life of the grinding roller and the grinding disk processed by overlaying. The service life of the grinding roller and the grinding disk processed by the overlaying is improved by 1.5 to 2 times than that processed by open arc overlaying; and the cladding efficiency is improved by 10 to 20 percent so as to save the overlaying wirematerial. The open arc overlaying wire material has light fume and less molten metal spatter in the process of overlaying, and a weld pass is smooth after the material is molded.

Description

Open arc overlaying wire material with strong abrasive resistance for grinding roller and grinding disk
[affiliated technical field]
The present invention belongs to the Surface Engineering built-up welding to repair manufacture field, relate to a kind of open arc overlaying wire material with strong abrasive resistance for grinding roller and grinding disk, can be widely used on the wearing piece of various wear-resisting machineries of industries such as coal, electric power, metallurgy, machinery, chemical industry, can be used for the built-up welding reparation and make new wearing piece.
[background technology]
Because the national economy high speed development is urgent to the electric power energy demand, has promoted the manufacturing fast development of China's station boiler.In recent years, station boiler is compared the thermal efficiency height of ultra supercritical unit, capable of saving fuel at least 4~5% to overcritical and ultra supercritical development with the supercritical unit of routine.The coal-fired unit of a new generation's large-capacity ultra-supercritical has possessed good economy, environmental protection and startup peaking operation performance, and still keeps higher efficient when underload.Proceeding from our national conditions, development ultra supercritical unit helps reducing the average net coal consumption rate of China, helps the stability and the economy of peak load regulation network, helps keeping ecological environment, improves Environmental Protection Level, helps realizing technological leapfrogging.
Follow overcritical and extensive use ultra-supercritical boiler, a large amount of unit pulverized-coal systems of using the band medium-speed pulverizers in coal-burning power plant's Generator Set.Advantages such as medium-speed pulverizer is low with power consumption, noise is little, facility compact, airborne dust are few are used widely in China in recent years.
Therefore the operating period of the coal-grinding member of medium-speed pulverizer, prolongs the service life of medium-speed pulverizer generally about 5000 hours, and the maintenance cost that reduces equipment is that enterprise such as coal-burning power plant needs the problem of solution badly in recent years.Adopt bead-welding technology reparation or new system medium-speed pulverizer grinding roller and grinding disk, can on the basis of improving stock utilization, prolong the service life of equipment, represented the technical advantage of built-up welding.When adopting submerged arc overlay welding to repair medium-speed pulverizer, need equipment such as dismounting grinding roller and mill to carry out the off-line reparation, increased repair time and cost; And the open arc built-up welding can well realize online built-up welding, can finish repair under the state that equipment is not taken out stitches, and has reduced time cost and workman's operation intensity, and promotion potential is huge.
Grinding roller and grinding disk service life of common open arc built-up welding reparation or new system is at 5000~10000 hours, and in addition, flue dust is bigger during existing open arc welding wire welding, is all possessing sizable rising space aspect service life and the effect.
[summary of the invention]
The objective of the invention is to overcome the weak point of prior art, in the medicinal powder of open arc flux-cored wire, added nanoscale nanometer additive (A), play the dispersion-strengthened action of nano ceramics phase, strengthen the cohesive strength of cladding layer material, fracture strength and bond strength, and possess the good high-temperature stability; Improve the self lubricity of material, improve the wearability that the cladding layer metal possesses, prolong the service life of the grinding roller and grinding disk after built-up welding is handled, handle raising 1.5-2 times than existing open arc built-up welding the service life of the grinding roller and grinding disk of handling through built-up welding provided by the invention.
The invention provides a kind of open arc overlaying wire material with strong abrasive resistance for grinding roller and grinding disk is made up of sheetmetal and the medicinal powder that is arranged in the sheetmetal, in medicinal powder, added nanometer additive (A), nanometer additive (A) can be nano TiN (titanium nitride), nanometer SiN (silicon nitride), any combination of a kind of or three in the nano SiC (carborundum).
The content (weight %) of the nanometer additive that described medicinal powder contains (A) is 3~5%.
The chemical composition of described medicinal powder (weight %) is:
Chromium carbide (Cr 3C 2) 10~20%; High carbon ferro-chrome 30~40%; Ferromanganese (MnFe) 2~5%; Ferrosilicon (SiFe) 5~10%; Molybdenum-iron (MoFe) 0~5% or ferro-niobium (NbFe) 0~8%; Nanometer additive (A) 3~5%; Chromium powder (Cr) 5~10%; Graphite (C) 3~5%; Titanium oxide (TiO 2) 5~10%; Calcirm-fluoride (CaF 2) 10~15%; Silica (SiO 2) 2~5%.
The filling rate 45~60% of described medicinal powder.
Described silk material diameter is Φ 2.4mm, Φ 2.8mm, one of three kinds of specifications of Φ 3.2mm.
The chemical composition of described medicinal powder (weight %) is: chromium carbide (Cr 3C 2) 16%; High carbon ferro-chrome 38%; Ferromanganese (MnEe) 2.8%; Ferrosilicon (SiFe) 5.5%; Molybdenum-iron (MoFe) 3%; Nanometer additive (A) 3.2%; Chromium powder (Cr) 7.5%; Graphite (C) 4%; Titanium oxide (TiO 2) 6%; Calcirm-fluoride (CaF 2) 10%; Silica (SiO 2) 4%.
The chemical composition of described medicinal powder (weight %) is: chromium carbide (Cr 3C 2) 18%; High carbon ferro-chrome 35%; Ferromanganese (MnFe) 2.5%; Ferrosilicon (SiFe) 5.5%; Ferro-niobium (NbFe) 4%; Nanometer additive (A) 5%; Chromium powder (Cr) 7%; Graphite (C) 4%; Titanium oxide (TiO 2) 5%; Calcirm-fluoride (CaF 2) 10%; Silica (SiO 2) 4%.
By technique scheme, the present invention has following advantage at least:
1, the existing open arc flux-cored wire of contrast, control the amount ranges of mineral materials such as slag making, gas making in the open arc overlaying wire material with strong abrasive resistance for grinding roller and grinding disk medicinal powder prescription provided by the invention, soot dust granule is thinner in the weld deposit process, and flue dust is light, motlten metal splashes few, and welding bead is smooth after the moulding.
2, the existing open arc flux-cored wire of contrast, the metallics percentage composition improves in the open arc overlaying wire material with strong abrasive resistance for grinding roller and grinding disk medicinal powder provided by the invention, make cladding layer metal effective rate of utilization promote, the reduction of iron loss rate simultaneously also helps improving deposition efficiency, novel welding wire powder core cladding efficient of the present invention improves 10~20%, can save the surfacing welding wire material use quantity in a large number.
[specific embodiment]
Below, will describe example of the present invention in detail.The invention is not restricted to example.
Open arc overlaying wire material with strong abrasive resistance for grinding roller and grinding disk of the present invention is made up of sheetmetal and the medicinal powder that is arranged in the sheetmetal, and the chemical composition of medicinal powder (weight %) is: chromium carbide (Cr 3C 2) 10~20%; High carbon ferro-chrome 30~40%; Ferromanganese (MnFe) 2~5%; Ferrosilicon (SiFe) 5~10%; Molybdenum-iron (MoFe) 0~5% or ferro-niobium (NbFe) 0~8%; Nanometer additive (A) 3~5%; Chromium powder (Cr) 5~10%; Graphite (C) 3~5%; Titanium oxide (TiO 2) 5~10%; Calcirm-fluoride (CaF 2) 10~15%; Silica (SiO 2) 2~5%.
Embodiment 1
The chemical composition of medicinal powder (weight %) is: chromium carbide (Cr 3C 2) 16%; High carbon ferro-chrome 38%; Ferromanganese (MnFe) 2.8%; Ferrosilicon (SiFe) 5.5%; Molybdenum-iron (MoFe) 3%; Nanometer additive (A) 3.2%; Chromium powder (Cr) 7.5%; Graphite (C) 4%; Titanium oxide (TiO 2) 6%; Calcirm-fluoride (CaF 2) 10%; Silica (SiO 2) 4%.
Embodiment 2
The chemical composition of medicinal powder (weight %) is: chromium carbide (Cr 3C 2) 18%; High carbon ferro-chrome 35%; Ferromanganese (MnFe) 2.5%; Ferrosilicon (SiFe) 5.5%; Ferro-niobium (NbFe) 4%; Nanometer additive (A) 5%; Chromium powder (Cr) 7%; Graphite (C) 4%; Titanium oxide (TiO 2) 5%; Calcirm-fluoride (CaF 2) 10%; Silica (SiO 2) 4%.
The filling rate 45~60% of medicinal powder.Silk material diameter of phi 2.4mm of the present invention, Φ 2.8mm, three kinds of specifications of Φ 3.2mm.
In the chemical composition of medicinal powder, the nanometer additive that contains (A) can be nano TiN (titanium nitride), nanometer SiN (silicon nitride), any combination of a kind of or three in the nano SiC (carborundum).In the medicinal powder of open arc flux-cored wire, add nanoscale nanometer additive (A), played the dispersion-strengthened action of nano ceramics phase, strengthened the cohesive strength of cladding layer material, fracture strength and bond strength, and possess the good high-temperature stability; Improve the self lubricity of material, improve the wearability that the cladding layer metal possesses, prolong the service life of the grinding roller and grinding disk after built-up welding is handled, handle raising 1.5-2 times than existing open arc built-up welding the service life of the grinding roller and grinding disk of handling through built-up welding provided by the invention.
Reduced the consumption of mineral materials such as slag making, gas making in the chemical composition of medicinal powder, as calcirm-fluoride (CaF 2) content range be controlled at 10~15%, soot dust granule is thinner in the weld deposit process, flue dust is light, it is few that motlten metal splashes, welding bead is smooth after the moulding.
The metallics percentage composition improves in the chemical composition of medicinal powder, makes the welding wire deposition efficiency promote, and novel welding wire powder core cladding efficient of the present invention improves 10~20%, can save the surfacing welding wire material use quantity in a large number.
Open arc overlaying wire material with strong abrasive resistance for grinding roller and grinding disk of the present invention is exclusively used in open arc built-up welding operation: the cladding layer metal hardness reaches HRC58~65, the anti-wear performance height; Improved 1.5~2 times in 5000~10000 hours that handle than common open arc built-up welding the service life of the grinding roller and grinding disk after built-up welding is handled; Deposition efficiency improves 10~20%, has therefore saved the surfacing welding wire material use quantity; Flue dust is light in the weld deposit process, and motlten metal splashes few, and welding bead is smooth after the moulding; Add nano level nanometer additive (A) in the medicinal powder, played the dispersion-strengthened action of nano ceramics phase, with the cohesive strength of enhancing cladding layer material, fracture strength and bond strength, and possess the good high-temperature stability, improve the self lubricity of material etc.
Open arc overlaying wire material with strong abrasive resistance for grinding roller and grinding disk of the present invention is not restricted to the described embodiments, any in the claimed scope of claims of the present invention improvement and change all within protection scope of the present invention.

Claims (7)

1, a kind of open arc overlaying wire material with strong abrasive resistance for grinding roller and grinding disk, form by sheetmetal and the medicinal powder that is arranged in the sheetmetal, it is characterized in that, in medicinal powder, added nanometer additive (A), nanometer additive (A) can be nano TiN (titanium nitride), nanometer SiN (silicon nitride), any combination of a kind of or three in the nano SiC (carborundum).
2, a kind of open arc overlaying wire material with strong abrasive resistance for grinding roller and grinding disk as claimed in claim 1 is characterized in that, the content (weight %) of the nanometer additive that described medicinal powder contains (A) is 3~5%.
3, a kind of open arc overlaying wire material with strong abrasive resistance for grinding roller and grinding disk as claimed in claim 2 is characterized in that, the chemical composition of described medicinal powder (weight %) is:
Chromium carbide (Cr 3C 2) 10~20%; High carbon ferro-chrome 30~40%; Ferromanganese (MnFe) 2~5%; Ferrosilicon (SiFe) 5~10%; Molybdenum-iron (MoFe) 0~5% or ferro-niobium (NbFe) 0~8%; Nanometer additive (A) 3~5%; Chromium powder (Cr) 5~10%; Graphite (C) 3~5%; Titanium oxide (TiO 2) 5~10%; Calcirm-fluoride (CaF 2) 10~15%; Silica (SiO 2) 2~5%.
4, a kind of open arc overlaying wire material with strong abrasive resistance for grinding roller and grinding disk as claimed in claim 3 is characterized in that, the filling rate 45~60% of described medicinal powder.
5, a kind of open arc overlaying wire material with strong abrasive resistance for grinding roller and grinding disk as claimed in claim 4 is characterized in that, described silk material diameter is Φ 2.4mm, Φ 2.8mm, one of three kinds of specifications of Φ 3.2mm.
6, a kind of open arc overlaying wire material with strong abrasive resistance for grinding roller and grinding disk as claimed in claim 5 is characterized in that, the chemical composition of described medicinal powder (weight %) is: chromium carbide (Cr 3C 2) 16%; High carbon ferro-chrome 38%; Ferromanganese (MnFe) 2.8%; Ferrosilicon (SiFe) 5.5%; Molybdenum-iron (MoFe) 3%; Nanometer additive (A) 3.2%; Chromium powder (Cr) 7.5%; Graphite (C) 4%; Titanium oxide (TiO 2) 6%; Calcirm-fluoride (CaF 2) 10%; Silica (SiO 2) 4%.
7, a kind of open arc overlaying wire material with strong abrasive resistance for grinding roller and grinding disk as claimed in claim 5 is characterized in that, the chemical composition of described medicinal powder (weight %) is: chromium carbide (Cr 3C 2) 18%; High carbon ferro-chrome 35%; Ferromanganese (MnFe) 2.5%; Ferrosilicon (SiFe) 5.5%; Ferro-niobium (NbFe) 4%; Nanometer additive (A) 5%; Chromium powder (Cr) 7%; Graphite (C) 4%; Titanium oxide (TiO 2) 5%; Calcirm-fluoride (CaF 2) 10%; Silica (SiO 2) 4%.
CN2008101468761A 2008-08-27 2008-08-27 Open arc overlaying wire material with strong abrasive resistance for grinding roller and grinding disk Expired - Fee Related CN101658980B (en)

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CN101780536A (en) * 2010-03-17 2010-07-21 任昊 Composite wear-resistant alloy material for cast steel surface
CN101934443A (en) * 2010-09-17 2011-01-05 江西恒大高新技术股份有限公司 Self-protective flux-cored soldering wire for surfacing of abrasion-resistant plate
CN102107341A (en) * 2011-01-26 2011-06-29 江西恒大高新技术股份有限公司 Flux cored wire for corrosion resistant repair of bucket teeth of engineering machinery
CN102416531A (en) * 2011-04-27 2012-04-18 杜荣臻 Slag-free surfacing welding rod
CN102554503A (en) * 2011-12-22 2012-07-11 中国船舶重工集团公司第七二五研究所 Abrasion-resisting surfacing flux-cored wire for coal milling roller
CN106001995A (en) * 2016-07-28 2016-10-12 江苏科技大学 Complex nitride and boride synergetic enhancement self-protection bead weld flux-cored wire
CN106001994A (en) * 2016-07-28 2016-10-12 江苏科技大学 Flux-cored wire capable of enhancing welding partition continuous self-protection effect and preparation method thereof
CN106112303A (en) * 2016-07-28 2016-11-16 江苏科技大学 A kind of multicomponent nitride Strengthening and Toughening self protection pile-up welding flux core welding wire and preparation method thereof
CN106112305A (en) * 2016-07-28 2016-11-16 江苏科技大学 A kind of low cost self-protection flux-cored wire containing different grain size deoxidizer and preparation method thereof
CN106392361A (en) * 2016-07-28 2017-02-15 江苏科技大学 Silicon annealed high-chromium cast iron type self-protection flux-cored wire and preparation method thereof
CN108296666A (en) * 2018-01-24 2018-07-20 江苏孚尔姆焊业股份有限公司 Abrasion-proof overlaying welding flux-cored wire
CN108531845A (en) * 2018-05-29 2018-09-14 苏州乔纳森新材料科技有限公司 A kind of Nano-composite powder core wire and preparation method thereof preparing oil pipeline coating
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CN108570639A (en) * 2018-05-29 2018-09-25 苏州乔纳森新材料科技有限公司 A kind of Nano-composite powder core wire and preparation method thereof preparing refractory coating
CN108754392A (en) * 2018-05-29 2018-11-06 苏州乔纳森新材料科技有限公司 A kind of powder cored filament material and preparation method thereof preparing antiseptic wearable coat
CN108747082A (en) * 2018-06-15 2018-11-06 武汉科技大学 A kind of wear-resisting welding wire with flux core and its preparation method and application
CN109175773A (en) * 2018-10-23 2019-01-11 郑州大学 A kind of mating flux-cored wire of bridge steel Q620qE
CN109926166A (en) * 2019-04-28 2019-06-25 四川省星船城水泥股份有限公司 A kind of ball mill compartment component and ball mill

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US6674047B1 (en) * 2000-11-13 2004-01-06 Concept Alloys, L.L.C. Wire electrode with core of multiplex composite powder, its method of manufacture and use
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CN1263579C (en) * 2003-03-17 2006-07-12 攀钢集团钢城企业总公司溶解乙炔厂 Fluxless heat-and wear-resistant cast iron alloy surfacing welding electrodes and manufacture thereof
CN1186167C (en) * 2003-08-08 2005-01-26 北京工业大学 High hardness high abrasive self protecting pile up welding flux core welding wire
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CN101780536A (en) * 2010-03-17 2010-07-21 任昊 Composite wear-resistant alloy material for cast steel surface
CN101934443A (en) * 2010-09-17 2011-01-05 江西恒大高新技术股份有限公司 Self-protective flux-cored soldering wire for surfacing of abrasion-resistant plate
CN101934443B (en) * 2010-09-17 2016-07-06 江西恒大高新技术股份有限公司 A kind of self-protective flux-cored soldering wire for surfacing of abrasion-resistant plate
CN102107341A (en) * 2011-01-26 2011-06-29 江西恒大高新技术股份有限公司 Flux cored wire for corrosion resistant repair of bucket teeth of engineering machinery
CN102107341B (en) * 2011-01-26 2012-12-26 江西恒大高新技术股份有限公司 Flux cored wire for corrosion resistant repair of bucket teeth of engineering machinery
CN102416531A (en) * 2011-04-27 2012-04-18 杜荣臻 Slag-free surfacing welding rod
CN102554503A (en) * 2011-12-22 2012-07-11 中国船舶重工集团公司第七二五研究所 Abrasion-resisting surfacing flux-cored wire for coal milling roller
CN102554503B (en) * 2011-12-22 2014-10-15 洛阳双瑞特种合金材料有限公司 Abrasion-resisting surfacing flux-cored wire for coal milling roller
CN106112305B (en) * 2016-07-28 2018-05-22 江苏科技大学 A kind of inexpensive self-protection flux-cored wire containing different grain size deoxidier and preparation method thereof
CN106392361B (en) * 2016-07-28 2018-07-27 江苏科技大学 A kind of silicon toughening High-chromium Cast Iron Flux Cored Wire For Self-shielded and preparation method thereof
CN106112303A (en) * 2016-07-28 2016-11-16 江苏科技大学 A kind of multicomponent nitride Strengthening and Toughening self protection pile-up welding flux core welding wire and preparation method thereof
CN106112305A (en) * 2016-07-28 2016-11-16 江苏科技大学 A kind of low cost self-protection flux-cored wire containing different grain size deoxidizer and preparation method thereof
CN106392361A (en) * 2016-07-28 2017-02-15 江苏科技大学 Silicon annealed high-chromium cast iron type self-protection flux-cored wire and preparation method thereof
CN106112303B (en) * 2016-07-28 2018-04-06 江苏科技大学 A kind of multicomponent nitride Strengthening and Toughening self protection pile-up welding flux core welding wire and preparation method thereof
CN106001995A (en) * 2016-07-28 2016-10-12 江苏科技大学 Complex nitride and boride synergetic enhancement self-protection bead weld flux-cored wire
CN106001994B (en) * 2016-07-28 2018-05-22 江苏科技大学 A kind of flux-cored wire for enhancing the welding continuous self-shield effect of subregion and preparation method thereof
CN106001995B (en) * 2016-07-28 2018-07-31 江苏科技大学 A kind of multicomponent nitride and boride collaboration enhancing self protection pile-up welding flux core welding wire
CN106001994A (en) * 2016-07-28 2016-10-12 江苏科技大学 Flux-cored wire capable of enhancing welding partition continuous self-protection effect and preparation method thereof
CN108296666A (en) * 2018-01-24 2018-07-20 江苏孚尔姆焊业股份有限公司 Abrasion-proof overlaying welding flux-cored wire
CN108531845A (en) * 2018-05-29 2018-09-14 苏州乔纳森新材料科技有限公司 A kind of Nano-composite powder core wire and preparation method thereof preparing oil pipeline coating
CN108531846A (en) * 2018-05-29 2018-09-14 苏州乔纳森新材料科技有限公司 A kind of Nano-composite powder core wire and preparation method thereof being used to prepare toughening coating
CN108570639A (en) * 2018-05-29 2018-09-25 苏州乔纳森新材料科技有限公司 A kind of Nano-composite powder core wire and preparation method thereof preparing refractory coating
CN108754392A (en) * 2018-05-29 2018-11-06 苏州乔纳森新材料科技有限公司 A kind of powder cored filament material and preparation method thereof preparing antiseptic wearable coat
CN108747082A (en) * 2018-06-15 2018-11-06 武汉科技大学 A kind of wear-resisting welding wire with flux core and its preparation method and application
CN108747082B (en) * 2018-06-15 2020-07-10 武汉科技大学 Wear-resistant flux-cored wire and preparation method and application thereof
CN109175773A (en) * 2018-10-23 2019-01-11 郑州大学 A kind of mating flux-cored wire of bridge steel Q620qE
CN109175773B (en) * 2018-10-23 2020-07-17 郑州大学 Flux-cored wire matched with bridge steel Q620qE
CN109926166A (en) * 2019-04-28 2019-06-25 四川省星船城水泥股份有限公司 A kind of ball mill compartment component and ball mill

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