CN101658933B - Preparation method of magnetic nano-materials and application thereof - Google Patents
Preparation method of magnetic nano-materials and application thereof Download PDFInfo
- Publication number
- CN101658933B CN101658933B CN2009101450264A CN200910145026A CN101658933B CN 101658933 B CN101658933 B CN 101658933B CN 2009101450264 A CN2009101450264 A CN 2009101450264A CN 200910145026 A CN200910145026 A CN 200910145026A CN 101658933 B CN101658933 B CN 101658933B
- Authority
- CN
- China
- Prior art keywords
- magnetic
- preparation
- nano
- application
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000002086 nanomaterial Substances 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 24
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000006243 chemical reaction Methods 0.000 claims abstract description 14
- 150000002500 ions Chemical class 0.000 claims abstract description 12
- 239000008367 deionised water Substances 0.000 claims abstract description 9
- 238000001291 vacuum drying Methods 0.000 claims abstract description 9
- 229910001385 heavy metal Inorganic materials 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 150000002815 nickel Chemical class 0.000 claims abstract description 7
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 5
- 239000012153 distilled water Substances 0.000 claims abstract description 5
- 238000000576 coating method Methods 0.000 claims abstract description 4
- 238000002156 mixing Methods 0.000 claims abstract description 3
- 238000010521 absorption reaction Methods 0.000 claims description 16
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 11
- 239000003945 anionic surfactant Substances 0.000 claims description 8
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 7
- 239000008103 glucose Substances 0.000 claims description 7
- 239000008187 granular material Substances 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 5
- 239000002122 magnetic nanoparticle Substances 0.000 claims description 5
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 claims description 4
- 238000013019 agitation Methods 0.000 claims description 4
- 229910001379 sodium hypophosphite Inorganic materials 0.000 claims description 4
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 claims description 3
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 3
- MQRWBMAEBQOWAF-UHFFFAOYSA-N acetic acid;nickel Chemical compound [Ni].CC(O)=O.CC(O)=O MQRWBMAEBQOWAF-UHFFFAOYSA-N 0.000 claims description 3
- 239000010842 industrial wastewater Substances 0.000 claims description 3
- 229940078494 nickel acetate Drugs 0.000 claims description 3
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical group Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims description 3
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical group OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 claims description 2
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 claims description 2
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 claims description 2
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 claims description 2
- 239000012279 sodium borohydride Substances 0.000 claims description 2
- 229910000033 sodium borohydride Inorganic materials 0.000 claims description 2
- 239000003463 adsorbent Substances 0.000 abstract description 7
- 238000001179 sorption measurement Methods 0.000 abstract description 7
- 238000001035 drying Methods 0.000 abstract description 5
- 239000004094 surface-active agent Substances 0.000 abstract description 2
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 abstract 4
- 239000002082 metal nanoparticle Substances 0.000 abstract 3
- 239000003513 alkali Substances 0.000 abstract 1
- 125000000129 anionic group Chemical group 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 229910021641 deionized water Inorganic materials 0.000 abstract 1
- 238000003760 magnetic stirring Methods 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 description 20
- 239000000243 solution Substances 0.000 description 12
- 239000010949 copper Substances 0.000 description 11
- 238000000034 method Methods 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 239000002077 nanosphere Substances 0.000 description 5
- 206010013786 Dry skin Diseases 0.000 description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- 238000002835 absorbance Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 150000002303 glucose derivatives Chemical class 0.000 description 2
- 239000011259 mixed solution Substances 0.000 description 2
- 239000011807 nanoball Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- -1 polytetrafluoroethylene Polymers 0.000 description 2
- 238000000634 powder X-ray diffraction Methods 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241000080590 Niso Species 0.000 description 1
- 238000001069 Raman spectroscopy Methods 0.000 description 1
- 230000005260 alpha ray Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 238000003763 carbonization Methods 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010891 electric arc Methods 0.000 description 1
- 238000010894 electron beam technology Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000001659 ion-beam spectroscopy Methods 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 230000005415 magnetization Effects 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 238000012876 topography Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Images
Landscapes
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
Abstract
The invention discloses a preparation method of magnetic nano-materials and application thereof, wherein the preparation method comprises a preparation process of magnetic metal nano-particles and a carbon coating process. The preparation process of the magnetic metal nano-particles comprises the steps of: dissolving an anionic type surfactant, a soluble nickel salt and a strong reducing agent in distilled water; slowly adding N, N-dimethylformamide (DMF) and strong alkali to the solution in sequence on the condition of magnetic stirring; mixing evenly; raising the temperature to be between 140 DEG C and 180 DEG C; reacting for 10 hours to 12 hours; cooling the solution to room temperature; using deionized water to wash for a plurality of times and then drying in a vacuum drying box at the temperature of 50 DEG C to 60 DEG C till constant weight; and finally obtaining the magnetic metal nano-particles. Compared with the prior art, the preparation method of magnetic nano-materials and the application thereof have mild reaction conditions; and the mesh-shaped carbon-coated magnetic adsorbent is characterized by selective adsorption of heavy metal ions, larger specific surface area, strong adsorption capability, and easy separation from the absorbed solution.
Description
Technical field
The present invention relates to preparation of nanomaterials and application thereof, particularly the preparation method of carbon-cladded magnetic metal nanometer material and application thereof.
Background technology
Traditional preparation carbon-cladded magnetic metal nanometer material is to utilize physical means as vapour deposition process, arc-discharge technique, pyrolysismethod, ion beam sputtering, electron beam irradiation method, metallic charcoal gel explosion method, laser evaporation method, plasma evaporation method etc., the equipment complexity that these methods are used, complex operation, cost height, preparation temperature height, energy consumption are greatly, reaction is violent and accessory substance is many, thereby are difficult to realize large-scale production.Chinese patent CN1951608A has introduced a kind of preparation method of carbon-cladded magnetic metal nanometer material, and this method is the reduction route under inert gas shielding and highly basic condition, therefore, and severe reaction conditions; Simultaneously, this method is not used the auxiliary of any surfactant, and the nano material of gained magnetic does not have the surface topography of rule.
Summary of the invention
The 1st technical problem to be solved by this invention provide a kind of simple magnetic Nano material the preparation method.
The 2nd technical problem to be solved by this invention is the application of above-mentioned magnetic Nano material.
The technical scheme of the technical problem that the present invention solves is: a kind of preparation of nanomaterials of magnetic, comprise that nano metallic nickel granular material preparation process, carbon coat process,
Described nano metallic nickel granular material preparation process is:
With anionic surfactant, soluble nickel salt and strong reductant are dissolved in the distilled water, successively with N, dinethylformamide (DMF) and highly basic slowly add in the above-mentioned solution, after mixing under the situation of magnetic agitation, heat up 140～180 ℃, reacted 10-12 hour, and be cooled to room temperature, spend deionised water for several times, 50-60 ℃ is dried to constant weight in vacuum drying chamber, and products therefrom is a magnetic nano-balls.
The mol ratio 1 of soluble nickel salt and anion surfactant: 0.15-0.3.
Described anion surfactant is neopelex (SDBS), lauryl sodium sulfate (SDS).
Described soluble nickel salt is a nickel chloride, nickelous sulfate, and nickel acetate, its chemical formula is respectively NiCl
2, NiSO
4, Ni (CH
3COO)
2
Described strong reductant is hydrazine hydrate, sodium hypophosphite, sodium borohydride.
Described carbon coating process is:
With the ultrasonic weight concentration that is scattered in of made magnetic nano-particle is in the 10-15% glucose solution, and reaction was cooled to room temperature after 3-4 hour under 160-170 ℃, spent deionised water, was dried to constant weight in vacuum drying chamber under 50-60 ℃, got final product.
The application of the nano material of the magnetic that the present invention is made heavy metal ions in the absorption industrial wastewater.
Can selective absorption contain Pb especially
2+, Cu
2+, Cd
2+The heavy metal solution of ion.
The present invention controls the magnetic nanoparticle pattern by anion surfactant, obtains the nanosphere of size homogeneous; Anion surfactant attaches to the surface of nanosphere, makes the webbed structure of glucose carbonization in the solution; Because adsorbent is the magnetic nano-balls nucleocapsid structure that reticulated carbon coats, and has very big specific area; In use, owing to contain nickel in the nano material, therefore after having adsorbed heavy metal,, nano material is separated with waste water by externally-applied magnetic field.
The present invention compared with prior art, the reaction condition gentleness, the magnetic adsorbent that made reticulated carbon coats has the selective absorption heavy metal ion, specific area is bigger, high adsorption capacity; The characteristics that are easy to from adsorbed solution, separate.
Description of drawings
Fig. 1 is the X-ray powder diffraction pattern of embodiment 1 gained nano material.
Fig. 2 is the energy spectrogram (EDS) of embodiment 1 gained nano material
Fig. 3 is SEM (SEM) photo of embodiment 1 gained magnetic metal nanosphere
Fig. 4 is SEM (SEM) photo of embodiment 1 gained nano material
Fig. 5 is transmission electron microscope (TEM) photo of embodiment 1 gained nano material.
Fig. 6 is the room temperature hysteresis curve of embodiment 1, and 51 is room temperature hysteresis curve, the 52 room temperature hysteresis curves for the nano material of embodiment 1 gained of embodiment 1 gained magnetic metal Nano microsphere.
Fig. 7 is the Raman spectrogram of embodiment 1 gained nano material.
Fig. 8 is the Pb that contains of embodiment 1 gained nano material
2+The adsorption curve of solution:
Fig. 9 is the Cu that contains of embodiment 1 gained nano material
2+The adsorption curve of solution:
Figure 10 is the Cd that contains of embodiment 1 gained nano material
2+The adsorption curve of solution:
The specific embodiment
Embodiment 1:
1, nano metallic nickel granular material preparation process:
Lauryl sodium sulfate (SDS) with 0.3mmol, the sodium hypophosphite of 2mmol nickel chloride and 8mmol, be dissolved in the 15mL distilled water, under the situation of magnetic agitation successively with 5mL N, dinethylformamide (DMF) and 25mmol KOH slowly add in the above-mentioned solution, the gained mixed solution is poured in the stainless steel autoclave of polytetrafluoroethylene (PTFE) as liner, be heated to 160 ℃ of reactions 10 hours.Reaction is cooled to room temperature with autoclave after finishing, and spends deionised water gained black product for several times, 50 ℃ of dryings in vacuum drying chamber, and products therefrom is the metal magnetic nanosphere.
2, carbon coats process:
2g glucose is dissolved in the 20mL water, adds the above-mentioned product of 20mg in this glucose solution ultrasonic 20 minutes, it is changed in the stainless steel autoclave, be heated to 160 ℃ of reactions 4 hours.Reaction is cooled to room temperature with autoclave after finishing, and spends deionised water gained black product for several times, and 50 ℃ of dryings get final product in vacuum drying chamber.
With day island proper Tianjin XRD-6000 type x-ray powder diffraction instrument to the product of implementing experiment 1 (Cu K alpha ray, λ=0.154060nm, 0.02 ° of sweep speed/s) carry out the thing identification of phases, as shown in fig. 1.Contrast JCPDS standard card (04-0850), all diffraction maximums fit like a glove with face-centered cubic magnetic nano-particle Ni mutually.Because diffraction maximum is very strong, illustrates that product has degree of crystallinity preferably.In addition, angle is the carbon that 20 °-30 ° baseline projection results from the crystallinity difference among Fig. 1.Fig. 2 elementary analysis shows that make and contain C, Ni, Cu and O element in the product, wherein element Cu comes from the copper sheet that supports sample.Fig. 3 and Fig. 4 show that respectively products therefrom has the nucleocapsid structure of reticulated carbon coated magnetic nano particle.Fig. 5 confirms that this product has magnetic, and saturation magnetization changes before and after the bag carbon.Fig. 6 shows, at 1387cm
-1(D band) and 1587cm
-1(G band) locates two big peaks, corresponding carbon atom sp
2The characteristic peak of hydridization has further proved the existence of carbon in the product.
Embodiment 2:
1, nano metallic nickel granular material preparation process:
Neopelex (SDBS) with 0.3mmol, the sodium hypophosphite of 2mmol nickel acetate and 8mmol, be dissolved in the 15mL distilled water, under the situation of magnetic agitation successively with 5mLN, dinethylformamide (DMF) and 25mmol KOH slowly add in the above-mentioned solution, the gained mixed solution is poured in the stainless steel autoclave of polytetrafluoroethylene (PTFE) as liner, be heated to 160 ℃ of reactions 10 hours.Reaction is cooled to room temperature with autoclave after finishing, and spends deionised water gained black product for several times, 50 ℃ of dryings in vacuum drying chamber, and products therefrom is the metal magnetic nanosphere.
2, carbon coats process:
2g glucose is dissolved in the 20mL water, adds the above-mentioned product of 20mg in this glucose solution ultrasonic 20 minutes, it is changed in the stainless steel autoclave, be heated to 160 ℃ of reactions 4 hours.Reaction is cooled to room temperature with autoclave after finishing, and spends deionised water gained black product for several times, and 50 ℃ of dryings get final product in vacuum drying chamber.
Embodiment 3:
The Pb that 20mg embodiment 1 products therefrom is added 50 milliliters of 10mg/L
2+In the solion, ultrasonic absorption 30 minutes, the atom absorptiometry shows Pb
2+The absorbance of solion 0.039 drops to 0.005 before adsorb, i.e. Pb
2+Ion concentration drops to 1.42mg/L (shown in Figure 8) by the preceding 10mg/L of absorption.As calculated, adsorbent is at the Pb of 10mg/L
2+Absorption Pb in the solion
2+Ability be 21.38mg/g.
Embodiment 4:
The Cd that 20mg embodiment 1 products therefrom is added 50 milliliters of 10mg/L
2+In the solion, ultrasonic absorption 30 minutes, the atom absorptiometry shows Cd
2+The absorbance of solion 0.413 drops to 0.195 before adsorb, i.e. Cd
2+Ion concentration drops to 2.43mg/L (as shown in Figure 9) by the preceding 5mg/L of absorption, and as calculated, adsorbent is at the Cd of 5mg/L
2+Adsorb Cd in the solion
2+Ability be 6.425mg/g;
Embodiment 5:
The Cu that 20mg embodiment 2 products therefroms is added 50 milliliters of 10mg/L
2In the solion, ultrasonic absorption 30 minutes, Cu
2+The absorbance of solion 0.330 drops to 0.139 before adsorb, i.e. Cu
2+Ion concentration drops to 4.28mg/L (as shown in figure 10) by the preceding 10mg/L of absorption, and as calculated, adsorbent is at the Cu of 10mg/L
2+Adsorption of Cu in the solion
2+Ability be 14.3mg/g.
Embodiment 6:
Embodiment 7:
Above presentation of results, Ci Xingnamilizi @C core-shell nano structure adsorbent for heavy metal has the selection absorption property, to Pb
2+, Cu
2+, Cd
2+Can effectively adsorb, and to the absorption of heavy metal ion As (V) and Cr (VI) to no effect.
Claims (6)
1. the preparation of nanomaterials of a magnetic comprises nano metallic nickel granular material preparation process, carbon coating process, it is characterized in that:
Described nano metallic nickel granular material preparation process is:
With anionic surfactant, soluble nickel salt and strong reductant are dissolved in the distilled water, successively with N, dinethylformamide (DMF) and highly basic slowly add in the above-mentioned solution, after mixing under the situation of magnetic agitation, heat up 140～180 ℃, reacted 10-12 hour, and be cooled to room temperature, spend deionised water for several times, 50-60 ℃ is dried to constant weight in vacuum drying chamber, gets final product; The mol ratio 1 of soluble nickel salt and anion surfactant: 0.15-0.3;
Described carbon coating process is:
With the ultrasonic weight concentration that is scattered in of made magnetic nano-particle is in the 10-15% glucose solution, and is cooled to room temperature in reaction under 160-170 ℃ after 3-4 hour, spends deionised water, is dried to constant weight in vacuum drying chamber under 50-60 ℃, gets final product.
2. the preparation of nanomaterials of a kind of magnetic according to claim 1, it is characterized in that: described anion surfactant is a neopelex, lauryl sodium sulfate.
3. the preparation of nanomaterials of a kind of magnetic according to claim 1, it is characterized in that: described soluble nickel salt is a nickel chloride, nickelous sulfate, nickel acetate.
4. the preparation of nanomaterials of a kind of magnetic according to claim 1, it is characterized in that: described strong reductant is hydrazine hydrate, sodium hypophosphite, sodium borohydride.
5. the application of the nano material of the described magnetic of claim 1 heavy metal ions in the absorption industrial wastewater.
The nano material of the described magnetic of claim 1 absorption industrial wastewater in Pb
2+, Cu
2+, Cd
2+The application of ions.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009101450264A CN101658933B (en) | 2009-09-21 | 2009-09-21 | Preparation method of magnetic nano-materials and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009101450264A CN101658933B (en) | 2009-09-21 | 2009-09-21 | Preparation method of magnetic nano-materials and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101658933A CN101658933A (en) | 2010-03-03 |
| CN101658933B true CN101658933B (en) | 2011-05-04 |
Family
ID=41787304
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2009101450264A Expired - Fee Related CN101658933B (en) | 2009-09-21 | 2009-09-21 | Preparation method of magnetic nano-materials and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101658933B (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8652386B2 (en) | 2010-09-16 | 2014-02-18 | Georgia Tech Research Corporation | Alignment of carbon nanotubes comprising magnetically sensitive metal oxides in nanofluids |
| CN102600794A (en) * | 2012-04-10 | 2012-07-25 | 东北大学 | Two preparation methods of nanometer magnetic adsorbent |
| CN102814158B (en) * | 2012-07-20 | 2015-01-28 | 安徽师范大学 | Preparation method and application of porous magnetic superstructure nanocomposite |
| CN103406100A (en) * | 2013-07-08 | 2013-11-27 | 武汉金益肽生物有限公司 | Magnetic chelate, and preparation method and application thereof |
| US9312046B2 (en) | 2014-02-12 | 2016-04-12 | South Dakota Board Of Regents | Composite materials with magnetically aligned carbon nanoparticles having enhanced electrical properties and methods of preparation |
| EP3134932B1 (en) | 2014-04-25 | 2021-08-25 | South Dakota Board of Regents | High capacity electrodes |
| CN104096836B (en) * | 2014-06-05 | 2016-06-29 | 深圳市本征方程石墨烯技术股份有限公司 | A kind of graphene coated magnetic Nano nickel particles and preparation method thereof |
| US10468674B2 (en) | 2018-01-09 | 2019-11-05 | South Dakota Board Of Regents | Layered high capacity electrodes |
| CN109909493A (en) * | 2019-02-25 | 2019-06-21 | 华中科技大学 | A kind of method that electron beam irradiation improves metal material stability |
| CN111792697B (en) * | 2020-06-10 | 2021-11-09 | 山东大学 | Application of magnetic caramelized carbon nano material in removing heavy metals in water body |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1951608A (en) * | 2005-10-21 | 2007-04-25 | 安徽师范大学 | Preparation method of carbon-cladded magnetic metal nanometer material |
| CN1966466A (en) * | 2006-09-15 | 2007-05-23 | 东南大学 | Water-heating synthesis method for preparing carbon-embedded magnetic nano composite granula |
| CN101176915A (en) * | 2006-11-09 | 2008-05-14 | 南京大学 | Method for preparing nano metallic nickel granular material coating with carbon |
| CN101502789A (en) * | 2009-01-22 | 2009-08-12 | 上海交通大学 | Method for preparing magnetic active carbon composite material for water processing |
-
2009
- 2009-09-21 CN CN2009101450264A patent/CN101658933B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1951608A (en) * | 2005-10-21 | 2007-04-25 | 安徽师范大学 | Preparation method of carbon-cladded magnetic metal nanometer material |
| CN1966466A (en) * | 2006-09-15 | 2007-05-23 | 东南大学 | Water-heating synthesis method for preparing carbon-embedded magnetic nano composite granula |
| CN101176915A (en) * | 2006-11-09 | 2008-05-14 | 南京大学 | Method for preparing nano metallic nickel granular material coating with carbon |
| CN101502789A (en) * | 2009-01-22 | 2009-08-12 | 上海交通大学 | Method for preparing magnetic active carbon composite material for water processing |
Non-Patent Citations (1)
| Title |
|---|
| zhaoping liu et al.complex-surfactant-assisted hydrothermal route to ferromagnetic nickel nanobelts.《Advanced Meterials》.2003,第15卷(第22期),1946-1948. * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101658933A (en) | 2010-03-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101658933B (en) | Preparation method of magnetic nano-materials and application thereof | |
| Singh et al. | Ternary transition metal alloy FeCoNi nanoparticles on graphene as new catalyst for hydrogen sorption in MgH2 | |
| Feng et al. | Highly efficient and selective recovery of Au (III) from a complex system by molybdenum disulfide nanoflakes | |
| Yang et al. | Fabrication of core-shell Fe3O4@ MIL-100 (Fe) magnetic microspheres for the removal of Cr (VI) in aqueous solution | |
| Ge et al. | Microwave preparation of triethylenetetramine modified graphene oxide/chitosan composite for adsorption of Cr (VI) | |
| Feng et al. | In situ facile synthesis of bimetallic CoNi catalyst supported on graphene for hydrolytic dehydrogenation of amine borane | |
| Li et al. | Adsorbent for chromium removal based on graphene oxide functionalized with magnetic cyclodextrin–chitosan | |
| Liu et al. | Facile and straightforward synthesis of superparamagnetic reduced graphene oxide–Fe3O4 hybrid composite by a solvothermal reaction | |
| Rojas et al. | Production of palladium nanoparticles supported on multiwalled carbon nanotubes by gamma irradiation | |
| Chandra et al. | Fabrication of magnetically separable palladium–graphene nanocomposite with unique catalytic property of hydrogenation | |
| CN104722276B (en) | A kind of melon ring/graphene oxide magnetic composite and preparation method thereof | |
| Cui et al. | One step solvothermal synthesis of functional hybrid γ-Fe2O3/carbon hollow spheres with superior capacities for heavy metal removal | |
| Ni et al. | Ionic liquid modified molybdenum disulfide and reduced graphene oxide magnetic nanocomposite for the magnetic separation of dye from aqueous solution | |
| Venkateswarlu et al. | An environmentally benign synthesis of Fe3O4 nanoparticles to Fe3O4 nanoclusters: Rapid separation and removal of Hg (II) from an aqueous medium | |
| CN106563484B (en) | A kind of preparation method of the hollow nitrating carbon copper-clad nanocatalyst of mesoporous type | |
| Kobyliukh et al. | Effect of graphene material structure and iron oxides deposition method on morphology and properties of graphene/iron oxide hybrids | |
| Wang et al. | Magnetic nanoparticles/graphitic carbon nanostructures composites: Excellent magnetic separable adsorbents for precious metals from aqueous solutions | |
| Jiang et al. | Preparation of monodisperse Ni/PS spheres and hollow nickel spheres by ultrasonic electroless plating | |
| Yue et al. | Deposition of gold nanoparticles on β-FeOOH nanorods for detecting melamine in aqueous solution | |
| Chen et al. | One-pot preparation of Ni-graphene hybrids with enhanced catalytic performance | |
| Kong et al. | One-step synthesis of Fe 2 O 3 nano-rod modified reduced graphene oxide composites for effective Cr (vi) removal: Removal capability and mechanism | |
| Mohammadi et al. | A general approach to multicomponent metal-decorated crumpled reduced graphene oxide nanocomposites using a flame-based process | |
| Lin et al. | Co3O4 nanocube-decorated nitrogen-doped carbon foam as an enhanced 3-dimensional hierarchical catalyst for activating Oxone to degrade sulfosalicylic acid | |
| Ren et al. | Facile synthesis of CoFe2O4-graphene oxide nanocomposite by high-gravity reactor for removal of Pb (II) | |
| CN103028738B (en) | Method for controllably preparing FeNi3 micro-nano materials in various shapes |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Anhui bangrui Industry & Trade Co., Ltd. Assignor: Anhui Normal University Contract record no.: 2012340000143 Denomination of invention: Preparation method of magnetic nano-materials and application thereof Granted publication date: 20110504 License type: Exclusive License Open date: 20100303 Record date: 20120428 |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20110504 Termination date: 20200921 |