CN101643218A - 一种微波加热合成取向性mfi型分子筛膜的方法 - Google Patents
一种微波加热合成取向性mfi型分子筛膜的方法 Download PDFInfo
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- CN101643218A CN101643218A CN200910101819A CN200910101819A CN101643218A CN 101643218 A CN101643218 A CN 101643218A CN 200910101819 A CN200910101819 A CN 200910101819A CN 200910101819 A CN200910101819 A CN 200910101819A CN 101643218 A CN101643218 A CN 101643218A
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- molecular sieve
- microwave heating
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- room temperature
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- 239000012528 membrane Substances 0.000 title claims abstract description 88
- 238000010438 heat treatment Methods 0.000 title claims abstract description 74
- 239000002808 molecular sieve Substances 0.000 title claims abstract description 49
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 title claims abstract description 49
- 230000002194 synthesizing effect Effects 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title claims abstract description 26
- 230000032683 aging Effects 0.000 claims abstract description 26
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 26
- 238000003786 synthesis reaction Methods 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- LPSKDVINWQNWFE-UHFFFAOYSA-M tetrapropylazanium;hydroxide Chemical compound [OH-].CCC[N+](CCC)(CCC)CCC LPSKDVINWQNWFE-UHFFFAOYSA-M 0.000 claims abstract description 12
- 238000002360 preparation method Methods 0.000 claims abstract description 5
- 238000001035 drying Methods 0.000 claims abstract description 3
- 238000005406 washing Methods 0.000 claims abstract description 3
- 239000007788 liquid Substances 0.000 claims description 21
- 238000003878 thermal aging Methods 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 230000029087 digestion Effects 0.000 claims description 2
- 239000011521 glass Substances 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 238000003756 stirring Methods 0.000 abstract description 3
- 239000012530 fluid Substances 0.000 abstract 3
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 abstract 1
- 238000005265 energy consumption Methods 0.000 abstract 1
- 230000006911 nucleation Effects 0.000 abstract 1
- 238000010899 nucleation Methods 0.000 abstract 1
- 238000003483 aging Methods 0.000 description 22
- 238000002425 crystallisation Methods 0.000 description 19
- 230000008025 crystallization Effects 0.000 description 19
- 238000010586 diagram Methods 0.000 description 19
- 239000013078 crystal Substances 0.000 description 8
- 229910001220 stainless steel Inorganic materials 0.000 description 8
- 239000010935 stainless steel Substances 0.000 description 8
- 239000000758 substrate Substances 0.000 description 8
- 239000008367 deionised water Substances 0.000 description 7
- 229910021641 deionized water Inorganic materials 0.000 description 7
- 238000007789 sealing Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 238000001027 hydrothermal synthesis Methods 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005672 electromagnetic field Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000013335 mesoporous material Substances 0.000 description 1
- 239000012229 microporous material Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 238000012876 topography Methods 0.000 description 1
- 238000005829 trimerization reaction Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 150000003738 xylenes Chemical class 0.000 description 1
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CN101643218A true CN101643218A (zh) | 2010-02-10 |
CN101643218B CN101643218B (zh) | 2011-02-09 |
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Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103132056A (zh) * | 2013-03-15 | 2013-06-05 | 沈阳化工大学 | 一种将铝或铝合金表面进行耐腐蚀处理的方法 |
CN103274430A (zh) * | 2013-07-01 | 2013-09-04 | 中国海洋石油总公司 | 一种回收利用晶化母液合成纯相sapo-31分子筛的方法 |
CN103818089A (zh) * | 2014-03-03 | 2014-05-28 | 河南中烟工业有限责任公司 | 一种金属防腐涂层的制备方法 |
CN104817095A (zh) * | 2015-04-15 | 2015-08-05 | 黑龙江大学 | 两步微波辐射加热的晶种引导法合成Zn/Al-MFI分子筛的方法 |
CN108579465A (zh) * | 2018-07-17 | 2018-09-28 | 深圳市晶特智造科技有限公司 | 一种高度取向沸石膜的制备方法 |
CN108636128A (zh) * | 2018-05-14 | 2018-10-12 | 南京工业大学 | 一种微波加热法快速制备h0h取向MFI型分子筛膜的方法 |
CN111099622A (zh) * | 2018-10-25 | 2020-05-05 | 中国石油化工股份有限公司 | b取向MFI分子筛的制备方法 |
CN112619685A (zh) * | 2020-12-18 | 2021-04-09 | 复旦大学 | 具有mfi结构的纳米雏晶催化剂及其制备方法和应用 |
CN113371728A (zh) * | 2021-07-09 | 2021-09-10 | 景德镇陶瓷大学 | 一种快速合成具有分级孔结构的分子筛的制备方法及其制得的产品 |
WO2021196539A1 (zh) * | 2020-03-30 | 2021-10-07 | 黄山学院 | 一种微波加热合成高质量无机膜的方法 |
US20220024774A1 (en) * | 2018-12-16 | 2022-01-27 | Hymater Co., Ltd. | Method for synthesizing supported molecular sieve membrane by microwaves |
CN115212732A (zh) * | 2021-04-20 | 2022-10-21 | 大连理工大学 | 一种具有优异气体分离性能mfi分子筛膜的制备方法及应用 |
-
2009
- 2009-08-27 CN CN2009101018196A patent/CN101643218B/zh not_active Expired - Fee Related
Cited By (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103132056A (zh) * | 2013-03-15 | 2013-06-05 | 沈阳化工大学 | 一种将铝或铝合金表面进行耐腐蚀处理的方法 |
CN103274430A (zh) * | 2013-07-01 | 2013-09-04 | 中国海洋石油总公司 | 一种回收利用晶化母液合成纯相sapo-31分子筛的方法 |
CN103818089A (zh) * | 2014-03-03 | 2014-05-28 | 河南中烟工业有限责任公司 | 一种金属防腐涂层的制备方法 |
CN103818089B (zh) * | 2014-03-03 | 2017-02-15 | 河南中烟工业有限责任公司 | 一种金属防腐涂层的制备方法 |
CN104817095A (zh) * | 2015-04-15 | 2015-08-05 | 黑龙江大学 | 两步微波辐射加热的晶种引导法合成Zn/Al-MFI分子筛的方法 |
CN108636128A (zh) * | 2018-05-14 | 2018-10-12 | 南京工业大学 | 一种微波加热法快速制备h0h取向MFI型分子筛膜的方法 |
CN108636128B (zh) * | 2018-05-14 | 2020-02-21 | 南京工业大学 | 一种微波加热法快速制备h0h取向MFI型分子筛膜的方法 |
CN108579465B (zh) * | 2018-07-17 | 2021-10-26 | 深圳市晶特智造科技有限公司 | 一种高度取向沸石膜的制备方法 |
CN108579465A (zh) * | 2018-07-17 | 2018-09-28 | 深圳市晶特智造科技有限公司 | 一种高度取向沸石膜的制备方法 |
CN111099622A (zh) * | 2018-10-25 | 2020-05-05 | 中国石油化工股份有限公司 | b取向MFI分子筛的制备方法 |
CN111099622B (zh) * | 2018-10-25 | 2021-10-01 | 中国石油化工股份有限公司 | b取向MFI分子筛的制备方法 |
US20220024774A1 (en) * | 2018-12-16 | 2022-01-27 | Hymater Co., Ltd. | Method for synthesizing supported molecular sieve membrane by microwaves |
US11926530B2 (en) * | 2018-12-16 | 2024-03-12 | Zhejiang Hymater New Materials Co., Ltd | Method for synthesizing supported molecular sieve membrane by microwaves |
WO2021196539A1 (zh) * | 2020-03-30 | 2021-10-07 | 黄山学院 | 一种微波加热合成高质量无机膜的方法 |
CN112619685A (zh) * | 2020-12-18 | 2021-04-09 | 复旦大学 | 具有mfi结构的纳米雏晶催化剂及其制备方法和应用 |
CN115212732A (zh) * | 2021-04-20 | 2022-10-21 | 大连理工大学 | 一种具有优异气体分离性能mfi分子筛膜的制备方法及应用 |
CN115212732B (zh) * | 2021-04-20 | 2024-02-06 | 大连理工大学 | 一种具有优异气体分离性能mfi分子筛膜的制备方法及应用 |
CN113371728A (zh) * | 2021-07-09 | 2021-09-10 | 景德镇陶瓷大学 | 一种快速合成具有分级孔结构的分子筛的制备方法及其制得的产品 |
CN113371728B (zh) * | 2021-07-09 | 2023-03-24 | 景德镇陶瓷大学 | 一种快速合成具有分级孔结构的分子筛的制备方法及其制得的产品 |
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Inventor after: Wang Zhengbao Inventor after: Li Xianming Inventor after: Lai Lulu Inventor after: Li Jiangang Inventor after: Dong Yanjuan Inventor before: Wang Zhengbao Inventor before: Li Xianming |
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Free format text: CORRECT: INVENTOR; FROM: WANG ZHENGBAO LI XIANMING TO: WANG ZHENGBAO LI XIANMING LAI LULU LI JIANGANG DONG YANJUAN |
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Granted publication date: 20110209 Termination date: 20130827 |