A kind of non-toxic and fireproof rubber sealing strip for doors and windows of vehicles running on rails and preparation method thereof
Technical field
The present invention relates to a kind of rubber material, especially a kind of nontoxic flameproof doors and windows of vehicles sealing band belongs to the environment-friendly rubber manufacture technology field with rubber and preparation method thereof.
Background technology
In recent years, sealed doors and windows on the guideway vehicle is more and more used on guideway vehicle, as light rail, high ferros etc. all adopt aggregated(particle) structure, continuous prosperity along with guideway vehicle, the sealing band of the sealed doors and windows on the guideway vehicle is also in fast rise, but there is serious toxicity problem in the sealing band rubber assembly of guideway vehicle both domestic and external to human body, as rubber toxicity, fire resistance, hardness, pulling strengrth, elongation at failure, compressive permanent set, peel strength, all out of reach requirements of oxygen index (OI) or the like, therefore, the existing doors and windows of vehicles sealing band rubber overwhelming majority adopts import parts.
Summary of the invention
In order to overcome above defective, the technical problem to be solved in the present invention is: propose a kind of non-toxic and fireproof rubber sealing strip for doors and windows of vehicles running on rails and preparation method thereof, thereby can adapt to external, domestic doors and windows of vehicles to the nontoxic flameproof demand of rubber.
The technical solution adopted in the present invention is: a kind of non-toxic and fireproof rubber sealing strip for doors and windows of vehicles running on rails, it is mixed and made into by ethylene propylene diene rubber, carbon black, fire retardant, vulcanizator, accelerator, paraffinic based oil and extending agent, each raw material component by weight is: ethylene propylene diene rubber: 35-40 part, carbon black: 10-15 part, fire retardant: 20-30 part, vulcanizator: 2-4 part, accelerator: 5-15 part, paraffinic based oil: 10-15 part, extending agent: 5-7 part.
According to another preferred embodiment, non-toxic and fireproof rubber sealing strip for doors and windows of vehicles running on rails comprises that further each raw material component by weight is: ethylene propylene diene rubber: 40 parts, carbon black: 10 parts, fire retardant: 25 parts, vulcanizator: 3 parts, accelerator: 10 parts, paraffinic based oil: 15 parts, extending agent: 6 parts.
The preparation method that the present invention has non-toxic and fireproof rubber sealing strip for doors and windows of vehicles running on rails is as follows: by weight with ethylene propylene diene rubber 35-40 part, carbon black 10-15 part, fire retardant 20-30 part, paraffinic based oil 10-15 part, after extending agent 5-7 part is mixed again 130 ℃-150 ℃ temperature blanking stir cooling 60-120 minute, material after mixing is being added vulcanizator 2-4 part more by weight through under 50-70 ℃ the temperature, accelerator: mixing more even after 5-15 part, promptly obtain nontoxic flameproof elastomeric material, through being up to the standards, entering the extruder microwave vulcanization with this elastomeric material and just obtain having nontoxic flameproof rubber.
The present invention is main material with the ethylene propylene diene rubber, have nontoxic and rubber fire resistance through modification and being prepared into, this elastomeric material compatible with environment is strong, the present invention is by France, Germany, the authentication of Britain international standard standard detection, has nontoxic fire-proof function, this elastomeric material can be used for producing various nontoxic and rubbers that fire resistance is high, but widespread use and guideway vehicle, automotive field, skyscraper, and the present invention has good social benefit and economic benefit.
The specific embodiment
Embodiment 1, by weight with ethylene propylene diene rubber: 35 parts, carbon black: 10 parts, fire retardant: 20 parts (fire retardant can adopt commercially available aluminium hydroxide or magnesium hydroxide etc.), paraffinic based oil: 10 parts, extending agent: after 5 parts (extending agent generally adopts potter's clay) mixes again 130 ℃-150 ℃ temperature blanking stir cooling 60-120 minute, material after mixing is added vulcanizator under through 50 ℃ of-70 ℃ of temperature more by weight: 3 parts, accelerator: mixing more even after 10 parts, promptly obtain nontoxic flameproof elastomeric material, enter the extrusion press extruding with this elastomeric material and just obtain having nontoxic flameproof rubber.
Rubber of the present invention is through detecting, and its performance is:
Your hardness that continues of rubber: 68 ± 2 degree;
Pulling strengrth is: 9MPa;
Elongation at failure: 336%;
Compressive permanent set: 16%;
Peel strength: 17KN/m;
Oxygen index (OI): 31%;
Ozone resistants: at 50PPhm, 20%, the 40 ℃ * 72h that stretches, sample does not have be full of cracks or strange phenomena;
Toxicity: do not detect.
In addition, detect authentication through international standard testing agencies such as France, Germany, Britain:
Ozone resistants: at 50PPhm, 20%, the 40 ℃ of * 72h that stretches, sample do not have be full of cracks or strange phenomena;
Toxicity: do not detect.
Embodiment 2, by weight with ethylene propylene diene rubber: 40 parts, carbon black: 10 parts, fire retardant: 20 parts (fire retardant can adopt commercially available aluminium hydroxide or magnesium hydroxide etc.), paraffinic based oil: 15 parts, extending agent: after 5 parts (extending agent generally adopts potter's clay) mixes again 130 ℃-150 ℃ temperature blanking stir cooling 60-120 minute, material after mixing is added vulcanizator under through 50 ℃-70 ℃ temperature more by weight: 3 parts, accelerator: mixing more even after 10 parts, promptly obtain nontoxic flameproof elastomeric material, enter extruder with this elastomeric material and just obtain having nontoxic flameproof rubber through microwave vulcanization.
Rubber of the present invention is through detecting, and its performance is:
Your hardness that continues of rubber: 70 ± 2 degree;
Pulling strengrth is: 9MPa;
Elongation at failure: 355%;
Compressive permanent set: 17%;
Peel strength: 17KN/m;
Oxygen index (OI): 31.6%;
Ozone resistants: at 50PPhm, 20%, the 40 ℃ * 72h that stretches, sample does not have be full of cracks or strange phenomena;
Toxicity: do not detect.
In addition, detect authentication through international standard testing agencies such as France, Germany, Britain:
Ozone resistants: at 50PPhm, 20%, the 40 ℃ of * 72h that stretches, sample do not have be full of cracks or strange phenomena;
Toxicity: do not detect.