CN101623005A - Multifunctional ecological agricultural environment-friendly composition and production method thereof - Google Patents
Multifunctional ecological agricultural environment-friendly composition and production method thereof Download PDFInfo
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Abstract
The invention relates to a multifunctional ecological agricultural environment-friendly composition and a production method thereof. The composition is prepared by mixing natural waste animal and plant shells, fruit and vegetable garbage, natural minerals, bacteriophage and traditional Chinese medicinal extracts, wherein the effective content of mixture liquid of chitosan and collagen is 0.5-0.99% or 1-5%; the bacteriophage accounts for 0.01-0.1% in the total solution; the traditional Chinese medicinal extracts account for 0.02-0.1% in the total solution, carriers of 80 mu are adopted; and the mass ratio of natural zeolite power and acetate solution is 1: 1-2. The composition has no poison or side effects, can be diluted (use internally as well) with water by 500 folds and sprayed into the natural environment to form a continuous network film to prevent bacteria, influenza virus and plant diseases and insect pests. The invention may fully replace chemical pesticides, chemical fertilizer hormones and antibiotics. Further, the invention is a good soil modifier, a wastewater treatment agent, a growth conditioner, can be degraded stably to release a plurality of nutrients available for three growing periods, has low cost which is only 1/6 of the others and has six functions.
Description
One technical field
The present invention relates to virus and modern agriculture (agricultural chemicals, chemical fertilizer, hormone, antibiotic) residual hazards such as the various influenzas of a kind of control, the composition that a medicine six is controlled; Be specifically related to a kind of multi-functional " ecological agricultural environment-friendly composition " and production method thereof.
Two background technologies
Mankind nowadays is being born the savage modern serious illness, and the injury of people and bird flu, H1N1 combination influenza is much to seek cause a disease malicious source and radical cure way so far both at home and abroad.Germ, poison like best " pollution ", and its unrestricted tourism is lived, and especially air pollution is difficult to stop: Given this, green organic food is difficult to produce, and human health is just more unsecured.The expert has invented various methods and product both at home and abroad, but none energy comprehensive regulation environmental pollution and modern agriculture virus.Whom excuse me, has can produce " green, environmental protection, organic food " in serious germ virus environment? according to newspaper: Taiwan more than 2,000 ten thousand populations just had a people to die from cancer in average per 10 minutes.Doctor trained in Western medicine that Here it is, " take stopgap measures " causes disastrous effect " syndrome " to be difficult to treatment! This is the injury that the chemical fertilizer, agricultural chemicals, hormone etc. of modern agriculture causes to the mankind; Be that the Western medicine antibiotic has served as the killer, aggravated the human diseases deterioration.At present, do not have the correlation combiner agent both at home and abroad and can prevent and treat bacterial virus, can eliminate the report that residual hazards such as air, water, soil, chemical fertilizer, agricultural chemicals hormone are polluted again.
I am grown in the rural area, and the ecotope and the ecological agriculture are liked ardently.My mother is biological, traditional Chinese medicine development master-hand, is again plant husbandry and aquaculture expert, and the people of my family and livestock and poultry etc. are ill all to be folk prescription treatment among the people; Never go up chemical fertilizer, aquaculture is never used grain with planting, and the meat egg price of livestock and poultry is all expensive a lot of than others' family These have all entailed me.
1, shitosan 1-6 version Jiang Ting writes greatly, and chemical industry publishing house publishes, No. the 144481st, Chinese depository library CIP data core word 2006.
2, effect (U.S.) the MK Wal moral DJ of phage-in bacterium pathogenesis and biotechnology, Fried SL Adia chief editor; Ai Yuncan, Meng Fanmei master translate, the ISBN978-7-03-019409-1 of Beijing Science Press 2007 (modern biotechnology forward position); No. the 109266th, China depository library CIP data core word (2007).Other effect of the 428th page of phage treatment of this book; Phage not only can be treated the infectious diseases that is caused by germ virus, and has extended to infectious diseases field in addition.
3, my the huge hair tonic of the friendly Qin bright " bactericide prepared from biology " patent No. ZL94111370.1 international monopoly Main classification A61K35/74 obtains the national science and technology achievement, numbering 014684, national registration number 970577; Obtain State Torch Program bullets: 96D231D6910239; Lot number: No. (1996) 049, meter word are sent out by state section; No. the 01st, Ministry of Agriculture's product batch number (1996) agriculture and animal husbandry (medicine literary composition) word.
Three summary of the invention
The technical problem to be solved in the present invention provides a kind of multi-functional " ecological agricultural environment-friendly composition " and production method thereof.For solving the problems of the technologies described above, the technical solution used in the present invention is:
The main auxiliary agent of said composition is shitosan, collagen, phage; Carrier is the natural zeolite powder of multi-function and multi-element; Tonic is a Chinese herbal medicine extract.The employing physical method mixes, safe without toxic side effect.One medicine six is controlled, and has has both prevented and treated residual hazards such as air, water, soil, seedling, agricultural chemicals, chemical fertilizer, hormone and has polluted; Prevent and treat of the injury of various influenza viruses again to people and animals; Water saving joint is fertile, save labor, province's expense and cost only are 1/6 of other series products.
A, preparation method and technological process
1. chemical method chitin extraction (shitosan) generally adopts both at home and abroad the shell extraction chitin of discarded clam, freshwater mussel, shrimp, crab: shell is handled through soda acid is sloughed calcium salt and protein, then with highly basic under heating condition, slough acetyl just obtain using ten minutes widely chitin (shitosan) molecular weight do not wait to hundreds of thousands by tens0000.
2. adopting the physics method is raw material production " shitosan " with the fly maggot
30 kilograms of fly maggots are separated with culture matrix, it is washed, put into 80 ℃ of hot water 3 minutes, pull out then and drain, with filtering after the high-speed grinder fragmentation; Putting into reaction ax after the maggot skin cleaned adds 20-80 and rises the 2-9% sodium hydroxide solution; 100 ℃ of insulations 8 hours, emit the back slowly reaction stirred to fly maggot mouthpart and viscera tissue because of till the different maggot skins of proportion separate; The maggot skin is put in 0.2% liquor potassic permanganate decolouring 4 hours, put into 0.7% oxalic acid solution demanganize 2 hours after cleaning again, this product is cleaned to immerse to take out after 1-6 hour in the 1-3 equivalent hydrochloric acid clean the back oven dry and be the shitosan finished product.
3. develop common " ecological agricultural environment-friendly composition ": the 4g shitosan is dispersed in the 500ml water, adds the stirring of 5.6ml hydrochloric acid and make it dissolving; Simultaneously the commercially available collagen of 10g is dispersed in the 600ml water, the potassium hydroxide 34ml of adding 10% stirs and makes it dissolving; With two kinds of solution mixing and stirring, be the environment-friendly liquid material then.Chitosan-containing 0.5-0.9%, collagen 1-5%; PH5.5-6.0; With 80 order natural zeolites and 0.5% shitosan, acetic acid solution is by 1: the 1-2 mass ratio mixes to be made chitosan loadedly on natural zeolite, and shitosan and zeolite press solution than 0.01-0.1% interpolation phagocytosis liquid again than 0.04-0.1%; Add Chinese herbal medicine extract 0.02-1% solution than pressing the crop demand; Fully stir evenly and promptly become multifunctional ecological agricultural environment-friendly composition.Technological process is as follows:
4. fly maggot separation-cleaning-blanching-fragmentation-digestion-separation-decolouring-demanganize-acidleach-oven dry-shitosan+collagen+zeolite powder+phagocytosis+Chinese medical extract-puddle stirs evenly-checks-packs-finished product.
5. annotate: pharmaceutical, extraction shitosan technological process: shitosan-batching-enzymolysis-ultrafiltration-nanofiltration-concentrate-spraying-drying-check-packing is the chitosan oligosaccharide pulvis.
The chitosan oligosaccharide quality requirement: the Q/DZG001-2006 standard, product is average
＜3000, take off acetate degree＞90%, 1% aqueous solubilities greater than 99%, ash content≤1%, moisture≤10%; Raw material sources are wide: marine animal give up shell, sea-plant red algae, all available biotechnology of fruits and vegetables agricultural products offcuts is obtained.Country such as complete alternative antibiotic, hormone, chemical pesticide forbidding product.
The test of B compound is to this
With shitosan, active carbon or convex-concave rod stone, zeolite is pressed certain mass than mixing, and its effect is better than shitosan in natural environmental protection, the animals and plants extermination of disease and insect pest, water treatment effect.According to the exchangeability of natural zeolite to metal cation, utilize shitosan in acid solution, to have the characteristic of positive charge, 80 order natural zeolites and 90% are taken off 0.5% of acetate degree shitosan; Acetic acid solution is by 1: the 1-2 mass ratio mixes, and makes chitosan loadedly on natural zeolite, and shitosan and zeolite mass ratio are 0.04-0.1%, and the adsorbent consumption is 8.0g/L, Cu in the waste water
6+Mass concentration is not more than 10ml/L; PH=4-6, adsorption time are 40 minutes, Cu
6+Clearance is that 80% compare the adsorption equilibrium time with active carbon adsorption short, cost is low only be its 1/6; Common absorption is accelerated.Given this, carry out the sewage water treatment, soil melioration, the raising that achieves noticeable achievement of control crop fertilizer efficiency, prevention and elimination of disease and pests result with multiple combined method; 500 times of environmental protection liquid sterilization effects are suitable with 600 times of sterilization lings; Regulate each growth period fertilizer efficiency nutrient of crop and reach 2 more than vegetative period, be better than chemical fertilizer more than one times.Because this product is slant acidity or neutrality, so and phage, Chinese herbal medicine extract is used and has no adverse effects and increased curative effect and multinomial function.Verify by theory and practice: the present invention's multi-functional " ecological agricultural environment-friendly composition " specific function is feasible.
The C effect
This product is not that agricultural chemicals can Pesticidal and sterilizing, is not that chemical fertilizer can increase production and creates efficiently, and fertilizer efficiency reaches 3 vegetative period of crop; Not that bagging can be economized on water fertilizer more than 50%; Not that hormone can be regulated each growth period of crop, promote photosynthesis; Not that antibiotic can be prevented and cured diseases; Not that the water machine can be administered water pollution; This agent can be administered the soil compaction necrosis comprehensively for a long time, strengthens crop drought resistance, cold resistance, and can reduce phenomenons such as dehiscent fruit, decayed fruit, shedding, rust fruit, tertia fruit; Improve the product grade, keep ecological local flavor, short precocity is gone on the market more than 10 days in advance; Spray and dip before fruit and vegetables, flowers are gathered and to prolong fresh keeping time and storage life, be used to prevent and treat infecting of bacterium, germ, combination influenza; Can replace fully: the additive product of chemical pesticide, chemical fertilizer, antibiotic, hormone and country's forbidding.Can be used for various Animal diseases treatments, the export processing that can be used for varieties of food items is earned foreign exchange: must protect export inspection and reach international standard.
The D function
Use the deserted mountain abandoned land, utilize the animals and plants waste material, house refuse " turning waste into wealth ", curbing environmental pollution etc. all is that country supports allowance.Agriculture, rural areas and farmers are brand strategies of Chinese development: the exploitation pollution-free food, organic food is the needs of agricultural restructuring, develops the needs that pollution-free agricultural product are human healths.
1. utilize deserted mountain abandoned land kind of the grass of planting trees, and development insect and aquatic animal, utilize offcuts to produce collagen.
2. utilize residual body of animal and plant and useless shell to produce chitin, shitosan, chitosan oligosaccharide.
3. utilize Chinese herbal medicine extract to do insecticide, veterinary drug, plant growth regulator; Waste residue extracts feed high protein.
4. utilize high nutrient source zeolite; According to investigating known zeolites kind more than 40, but clinoptilolite wherein, modenite contains constant and trace and rare element and reaches kind more than 60; Can be rated as inorganic nature mineral matter nutritional source; It is good soil conditioner; Sewage-treating agent; Fertilizer synergist; Plant growth regulator: contain N1.38%, P
2O
53.3% and K
2O
42.13%; Extremely strong and the stable in properties of adsorption capacity can reduce element and nutritive loss, and fertilizer efficiency reaches 3 vegetative period, can change soil structure, increases oxygen content and gas permeability; Can adsorb bacterial virus, toxic metals and toxic gas prevent that the soil-borne disease insect pest from taking place.Possess ion exchanging function, the bidirectional modulation pH value reduces the generation of disease, and can improve enzymic activity and improve nutritional utilization, reduces the crops cost; Regeneration slowly-releasing ion exchange fertilizer can be stablized and discharges squama potassium and be made for thing and grow fast.Prematurity is beared fruit, early ripe more; Take place but be used for the livestock and poultry disease preventing and treating, promote growth, many raw eggs fast.Therefore be mated each apparent magical effect.
5. utilize phagocytosis positively charged function poisonous flora (negative electricity) to be attracted to cement and extremely death of cracking.
6. adopt " curing agricultural homology " base reason that the method for drug matching is added in this agent and can prevent and treat animal and plant all kinds of diseases and ailments.
E base reason of the present invention:
Theory and practice experience with the elite " all things on earth counteracts each other " of curing sage, medicine sage, Li Shizhen (1518-1593 A.D.) has found point of penetration: the own hundred medicines doctor of all kinds of diseases and ailments, and all things on earth all has natural enemy; The reason of " farming doctor homology " just.Doctor trained in Western medicine is that the reaction of " pin for the treatment of the head when the head aches is cured pin bitterly " antibiotic is fast, becomes more refractory treatment of syndrome but stay malicious root.Traditional Chinese medical science research Chinese herbal medicine (comprising dietotherapy) is kept eighteen incompatibilities firmly in mind, and compatibility error life be cannot say for sure; Single medicine does not have that two medicines are good, multiple medicines is stronger than two medicines, and the power-power cooperation potion pushes up hundred doses, and diagnosis and treatment based on an overall analysis of the illness and the patient's condition is ingenious reasonably combined effective.Ancients say: beat snake and will make a call to seven cun (the heel of Achilles) earlier; The maximum enemy of mankind nowadays is " pollution " (water, air, soil, agricultural chemicals, chemical fertilizer, hormone ...) inventive method has three:
, with the liquid protective film of this invention it is protected pathogenic bacteria, virus, damage by disease and insect and can't infect;
Four embodiments
The soluble powder that 1. 1 kinds of following compositions of embodiment and content constitute: molecular weight 0.1 ten thousand-200,000 shitosan; The 50-100% collagen.
The aqueous solvent that 2. 1 kinds of following composition percentage compositions of embodiment constitute: chitosan-containing 0.5-0.9%; Contain collagen 1-5%;
3. 1 kinds of following composition solubility microbial inoculum: phage＞4.7*10 of embodiment
10PFU/ml, the water purification factor＞5mg/L; Chi thalline active extract＞2mg/L; Immunomodulator＞7mg/L, amino acid/11 2mg/L, micro-8mg/L, specific proteins 3mg/L; Algae-lysin factor＞5mg/L.
4. 1 kinds of following composition soluble powders of embodiment; 80 order natural zeolite powders; Require modenite and clinoptilolite.
5. 1 kinds of following composition solubility solution of embodiment, acetic acid solution is by 1: the 1-2 mass ratio.
6. 1 kinds of following compositions of embodiment constitute mixed solution; Content is than being 0.04-0.1% shitosan and zeolite powder.
7. 1 kinds of following composition soluble liquids of embodiment; Constitute by 1-3 equivalent hydrochloric acid.
8. 1 kinds of following composition soluble liquids of embodiment, solution amount 30-80 liter contains potassium hydroxide 2-9%.
9. 1 kinds of following composition soluble liquids of embodiment, liquid zeolite slowly-releasing ion fertilizer contains N1.389%; P
2O
53.3%, K
2O
42.13%.
Embodiment 10. Hunan Province western Hunan market test demonstration proof, multi-functional " ecological agricultural environment-friendly composition " brought distinct economic to farmer specialized cooperative society, and chief Zhao says: it is sick with 1% multi-functional " ecological agricultural environment-friendly composition " whole pig farms of sprinkling and pig farm environment (2 sick pigs add forage volume 6% administration for oral administration) that swine flu is suffered from 2 on pig farm; Control, prevent swine flu effect 100%;
Embodiment 11. senior agronomist Zhang Jiaohua are to the fruit tree garden: canker, anthracnose, two spotted spider mite carry out spray test to this; Use multi-functional " ecological agricultural environment-friendly composition " incidence of disease only to be 0.05-0.1%; And use the agricultural chemicals incidence of disease is 4.8%;
Embodiment 12. agronomist Zhang Chaobiao have carried out experiment to paddy rice and have sprayed; Leaf mining pretty young woman and canker obtain radical cure, and the strong blade of bar is thick green, and leaflet is many, the fringe line length, and the grains are plump.Output obviously increases; And show that drought resisting, cold tolerance are very strong.
Multi-functional " ecological agricultural environment-friendly composition " preserve moisture and fertility effect obvious (there be not the not withered early of spray) is sprayed in the muskmelon garden to embodiment 13. agronomist Duan Shaojin and downy mildew has reduced 90%; Many knots fruit and fruity several times are pure, crisp sweet, and the pericarp light is fine and smooth.
Embodiment 14. Hongjiang town He Bing uses multi-functional " ecological agricultural environment-friendly composition " to spray in the vineyard and to irrigate the strong leaf of back strain green, and the neat size of fruit growth is well-balanced, and painted morning, dehiscent fruit, damage by disease and insect are not few, and the ripe fruit of regrowth hair is arranged, and obviously increases production extra earning.
Embodiment 15. demonstration gardens make wheat sharp eyespot reduce by 80% with 0.1% multi-functional " ecological agricultural environment-friendly composition " seed soaking; Root rot reduces by 62%; The paddy rice flax is sick to reduce more than 80%.
Embodiment 16. demonstration farms dispose of sewage with multi-functional " ecological agricultural environment-friendly composition ", and heavy metal is superfluous to be closed because of this agent possesses, activated sludge flocculation, sterilizing; Be adsorbed with effects such as poisonous gas, heavy metal, because this agent constituent acts on simultaneously.The time of purifying waste water is only used 30 minutes, and cost only is about 1/10 of other water treatment expenses, and this agent degraded has no side effect to health safety.
It is obvious that embodiment 17. demonstration farms carry out reclamation result with multi-functional " ecological agricultural environment-friendly composition ": increased granular structure and gas permeability, not only protected fertilizer but also water conservation, made this fertilizer degraded back fertilizer efficiency can be made for 2 of things more than vegetative period; And controlled native pathogen.
Embodiment 18. demonstration farms spray and experimental results show that: can make tobacco reduce mosaic virus in ten days, make Kidney bean avoid lucerne flowers and leaves cause of disease bacterium and contaminate; Mu is executed the wilt disease that this agent of 25-50 microgram causes the celery Fusarium oxysporum and is obtained radical cure; Soak root with 1-3% solution and can treat tomato, cucumber root rot, fusarium wilt, damping off.
Embodiment 19. demonstration farms are protected fruits and vegetables
Experimental results show that: fruits and vegetables prolong fresh-keeping 15 days, and lichee (low temperature) is fresh-keeping to reach 25 days, and kiwi fruit is fresh-keeping to reach 80 days, and fresh flower can prolong 7-10 days.
Embodiment 20. demonstration farms experimental results show that aquatic livestock with this agent: bacteriosis, colibacillosis, septicemia, gastrointestinal disease, ascites disease, ulcer disease, red skin disease, red plum pinta, oral ulcer, appendicopathia, purulence born of the same parents disease, muscular dystrophy, fin rot, oedema, mashed limb, furuncle, saprolegniasis etc. are all had obvious curative effects.Especially edible multi-functional " ecological agricultural environment-friendly composition " export quarantine in preceding 40 days reaches international standard to various food exports.
Carried out marketing plan: set up " international agricultural development center ", " the agriculture hospital " that look " has a distinctive style " held in establishment, according to " curing agricultural homology " is aim, with the famous experience ingenious physical engagement radical cure of the modern high technology natural environment pollution in addition that hundred grass holy, the holy Li Shizhen (1518-1593 A.D.) of medicine are controlled all kinds of diseases and ailments, the viral radical cure of radical cure modern agriculture plant, animal and the human various diseases of curing.In order to benefit the Chinese nation as early as possible, to benefit the whole mankind; The domestic and international farmer specialized cooperative society associating of my development " link-relative method ", urban community associating both at home and abroad; Be responsible for all-around service (made-to-order farming of town and country associating just) by " agriculture hospital "; We multi-functional " ecological agricultural environment-friendly composition " freely supplied with farmer specialized cooperative society use, regain the farmer specialized cooperative society organic products again, to each community, have the special messenger to be responsible for getting in touch order and deliver goods with the owner of community through processing sell.Edible rubbish with the city, the discarded object in rural area, residue after the processing all reclaims and makes the raw material of various fertilizer, feed and the agent of production agricultural environmental protection, then this product and the means of production is delivered in peasant's hand, forms the benign cycle comprehensively of cities and towns, rural area-industry and agricultural; Thoroughly administer and pollute, realize the target of ecological agriculture organic food.
With Beijing is axle, eight agriculture suburbs totally 2600 farmer specialized cooperative societies in communication; The urban community service station is sold the website and is begun to form in improving; " agriculture hospital " Technician Training is about to begin the food garbage in (being borrow-hen-lay now) deserted mountain both domestic and external abandoned land, city, and waste material after the food processing, agricultural residue all are " agriculture hospital " sources; Does this invention have much to contribution to society? soon be covered with the whole world in the future; Create harmonious society.A state-owned such able person during the Party Central Committee and government also do not know now! State-owned so good product in not knowing.Given this, hope Patent Office open early, inform that the state leader wins honour for for the Chinese nation early! For the whole mankind benefits.
Claims (9)
1. multi-functional " ecological agricultural environment-friendly composition " is comprehensive regulation environmental pollution, prevents and treats the composition of various germs, virus (comprising: fowl, pig, people make up influenza and agricultural chemicals, chemical fertilizer, hormone, antibiotic residual hazard) ecological, environmental protective.Wherein phagocytosis solution compares 0.01%-0.10%;
2. according to claim 1, multi-functional " ecological agricultural environment-friendly composition " composition is characterized in that chitosan-containing 0.5%-0.9% in the mixed solution; Contain collagen 1%-5%;
3. according to claims 1 or 2, multi-functional " ecological agricultural environment-friendly composition " composition is characterized in that Chinese herbal medicine extract accounts for the 0.01%-0.05% of total solution;
4. according to claim 1 or 2, multi-functional " ecological agricultural environment-friendly composition " composition is characterized in that adding 80 order natural zeolites and 0.5% chitosan solution, and acetic acid solution is by 1: the 1-2 mass ratio;
5. according to claim 2, multi-functional " ecological agricultural environment-friendly composition " composition is characterized in that shitosan and zeolite ratio are 0.04-0.10%;
6. according to claim 2, multi-functional " ecological agricultural environment-friendly composition " composition is characterized in that 1-3 equivalent hydrochloric acid;
7. according to claim 6, multi-functional " ecological agricultural environment-friendly composition " composition is characterized in that being advisable in acidleach 1-8 hour;
8. according to claim 2 or 6, multi-functional " ecological agricultural environment-friendly composition " composition is characterized in that the 30-80 liter, the 2%-9% potassium hydroxide solution;
9. according to claim 1 or 4, multi-functional " ecological agricultural environment-friendly composition " composition is characterized in that multi-functional zeolite slowly-releasing ion exchange compoiste fertilizer contains N1.38%; P2O53.3%; K2O42.13%.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102365945A (en) * | 2011-10-28 | 2012-03-07 | 海南正业中农高科股份有限公司 | Chitosan oligosaccharide composition for resisting citrus canker disease as well as application and method thereof |
| CN104071861A (en) * | 2014-07-09 | 2014-10-01 | 周振坤 | Sewage purifying agent and preparation method thereof |
| CN107535265A (en) * | 2017-09-13 | 2018-01-05 | 安徽有余跨越瓜蒌食品开发有限公司 | A kind of implantation methods of mulberries |
-
2009
- 2009-06-02 CN CN200910143893A patent/CN101623005A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102365945A (en) * | 2011-10-28 | 2012-03-07 | 海南正业中农高科股份有限公司 | Chitosan oligosaccharide composition for resisting citrus canker disease as well as application and method thereof |
| CN102365945B (en) * | 2011-10-28 | 2013-10-23 | 海南正业中农高科股份有限公司 | Chitosan oligosaccharide composition for resisting citrus canker disease as well as application and method thereof |
| CN104071861A (en) * | 2014-07-09 | 2014-10-01 | 周振坤 | Sewage purifying agent and preparation method thereof |
| CN104071861B (en) * | 2014-07-09 | 2015-12-02 | 周振坤 | A kind of purifying agent for polluted water and preparation method thereof |
| CN107535265A (en) * | 2017-09-13 | 2018-01-05 | 安徽有余跨越瓜蒌食品开发有限公司 | A kind of implantation methods of mulberries |
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Open date: 20100113 |