CN101610683A - 制造含有类胡萝卜素的粉末的工艺 - Google Patents
制造含有类胡萝卜素的粉末的工艺 Download PDFInfo
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- CN101610683A CN101610683A CNA2008800051839A CN200880005183A CN101610683A CN 101610683 A CN101610683 A CN 101610683A CN A2008800051839 A CNA2008800051839 A CN A2008800051839A CN 200880005183 A CN200880005183 A CN 200880005183A CN 101610683 A CN101610683 A CN 101610683A
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Abstract
本发明提供了含有一种或多种类胡萝卜素的粉末的制造工艺，可通过所述工艺获得的粉末和含有所述粉末的食物组合物。
Description
本发明涉及制造含有一种或多种类胡萝卜素的粉末的工艺，另外，本发明涉及可通过所述工艺获得的粉末，还涉及含有所述粉末的食物组合物，特别是速溶饮料。
类胡萝卜素对多种食物和饮料而言是尤其有用的着色剂来源。类胡萝卜素包括胡萝卜素、番茄红素、胭脂树橙、玉米黄素、隐黄素、角黄素、叶黄素、β-阿朴-8′-胡萝卜醛、β-阿朴-12′-胡萝卜醛，并能够提供范围从黄到红的色素。类胡萝卜素类的一个特别重要的成员是β-胡萝卜素，因为β-胡萝卜素不仅可用作着色剂(通常颜色为黄色、橙色和特别是红色)，而且还提供有价值的维生素A来源。除了着色能力外，大部分其它类胡萝卜素还具有其它有益特性。为此，类胡萝卜素通常被包含在食物和饮料中作为着色剂，特别是需要或期望它们的其它有益特性(例如维生素A强化)时。
尽管在大部分应用中，着色作用和其它有益特性都是人们想要的，但是也存在其它一些应用，其中就终产物的期望颜色而言，类胡萝卜素的强烈色彩是一个问题，特别是当类胡萝卜素的其它特性是应用焦点时。
因此，提供含有一种或多种类胡萝卜素的下述粉末是以下发明的一个目标，其中在一种优选的情况下的粉末应当对终产物不具有任何显著的着色作用。另外，粉末应当满足食物组合物的通常需求，例如对氧化而言是稳定的、随着时间的进展在产物中均匀分布并保持均匀分布等等。
惊人地发现通过下述制造含有一种或多种类胡萝卜素的粉末的工艺达成了本发明的目的，所述工艺包括步骤：
a)提供多糖的水溶液；
b)在步骤a)的溶液中形成类胡萝卜素悬浮液；
c)研磨步骤b)的悬浮液，直至类胡萝卜素颗粒的平均粒径在从约0.6μm到约1.4μm的范围内；
d)干燥步骤c)的悬浮液。
本领域技术人员没有预见到，可通过根据本发明的工艺获得的粉末能够解决上述问题。
根据本发明的工艺的步骤a)可在任何合理的温度下进行，以确保多糖在水中的快速溶解。为了确保多糖在合理的时间量内完全溶解，加热至约40到80℃是优选的。
本文使用术语“多糖”包括金合欢胶、果胶、纤维素、纤维素衍生物和/或改性的多糖。
本文使用术语“改性的多糖”是指在直链中含有亲脂片段如烃片段的多糖，所述烃片段优选地具有5到18个碳原子的链长度。优选地，改性的多糖应是人消耗可接受的，即优选的改性的多糖应当符合GRAS(Generally Recognized As Safe)标准或由全世界的各个管理机构批准用于食物消耗的。一种优选的改性的多糖是改性的食物淀粉。
本文使用术语“改性的食物淀粉”是指由通过已知的化学方法用疏水片段取代的淀粉制成的改性淀粉。例如，可用环状二羧酸酐如琥珀酸酐和/或戊二酸酐处理淀粉，所述酸酐用烷基或烯基烃基取代。
本发明的一种尤其优选的改性淀粉具有下式(I)：
其中St是淀粉，R是亚烷基，R′是疏水基团。优选地R为低级亚烷基，例如二亚甲基或三亚甲基。R′可以是烷基或链烯基，优选地具有5到18个碳原子。式(I)的一种优选的改性淀粉为辛烯基琥珀酸淀粉钠(StarchSodium Octenyl Succinate，也称“OSA-淀粉”)。本文使用术语OSA-淀粉表示用辛烯基琥珀酸酐(0SA)处理过的任何淀粉(来自天然来源例如玉米、小麦、木薯、马铃薯或是合成的)。取代程度，即相对于羟基总数的酯化羟基数量，通常在从0.1％到10％的范围内，优选地在从0.5％到5％的范围内，更优选地在从2％到4％的范围内变化。
OSA-淀粉可含有其它水胶体，如淀粉、麦芽糖糊精、碳水化合物、胶质(gum)、玉米糖浆等，并可选地含有任何典型的乳化剂(作为共乳化剂)，如脂肪酸单甘油酯和二甘油酯、脂肪酸的多甘油酯、卵磷脂、脱水山梨醇单硬脂酸酯和植物纤维或糖。
OSA-淀粉可以商品名HiCap 100、Capsul、Capsul HS、Purity Gum2000、UNI-PURE、HYLON VII等从例如National Starch商业获得；或从Roquette Frères商业获得；或以商品名C*EmCap从CereStar商业获得；或从Tate&Lyle商业获得。
如果以下述方式选择步骤a)的水溶液中水和多糖(一种或多种化合物)的量则是有利的，所述方式使得根据本发明的步骤b)的悬浮液中多糖的量在按重量计10％到25％的范围内，并且所述悬浮液中水的量在按重量计50％到70％的范围内，优选地在按重量计55％到65％的范围内，所述范围均以悬浮液的总重为基础。
根据本发明，如果在步骤b)中添加的类胡萝卜素(一种或多种化合物)的量在按重量计从2％到11％的范围内，优选地在按重量计从5％到10％的范围内，则是有利的，所述范围均以悬浮液的总重为基础。
在本发明的工艺的一个优选的实施方案中，在步骤b)中还向步骤a)的溶液中添加其它佐剂。所述其它佐剂优选地选自下述组中的一种或多种：
·稀释剂；
·抗氧化剂(脂溶性或水溶性)；
·甘油三酯(油和/或脂肪)；
优选的稀释剂可选自甘油、单糖、二糖和寡糖。根据本发明，蔗糖、转化糖、葡萄糖、果糖、乳糖、麦芽糖、蔗糖、糖醇和淀粉水解产物例如糊精和麦芽糖糊精是优选的。麦芽糖糊精是特别优选的。
根据本发明，如果悬浮液中稀释剂(一种或多种化合物)的量在按重量计从5％到20％的范围内，优选地在按重量计从10％到15％的范围内则是优选的，所述范围均以悬浮液的总重为基础。
优选的水溶性抗氧化剂是例如抗坏血酸或其盐，优选地为抗坏血酸钠。优选的脂溶性抗氧化剂是例如生育酚(合成的或天然的)；丁基化的羟基甲苯(BHT)；丁基化的羟基茴香醚(BHA)；没食子酸丙酯；叔丁基羟基喹啉和/或脂肪酸的抗坏血酸酯，优选地为棕榈酸抗坏血酸酯和/或硬脂酸抗坏血酸酯。dl-生育酚是特别优选的。
根据本发明，如果悬浮液中抗氧化剂(一种或多种化合物)的量在按重量计从0.1％到2％的范围内，优选地在按重量计从0.5％到1.5％的范围内则是有利的，所述范围均以悬浮液的总重为基础。
甘油三酯优选地选自植物油和/或脂肪，优选地为玉米油、向日葵油、大豆油、红花油、油菜籽油、花生油、棕榈油、棕榈仁油、棉籽油和/或椰子油，包括其分级的品质。甘油三酯可优选地是所谓的MCT(中链甘油三酯)，即中链脂肪酸(优选地为具有6到12个C原子链长度的饱和脂肪酸)和甘油的酯。
根据本发明，如果悬浮液中甘油三酯(一种或多种化合物)的量在按重量计0％到5％的范围内，优选地在按重量计从0.2％到2％的范围内则是有利的，所述范围均以悬浮液的总重为基础。
研磨步骤优选地用可商业获得的球磨机完成。通过相互调节以下的参数达成类胡萝卜素颗粒的期望的平均粒径：转速(圆周速度)、研磨机中的平均停留时间、研磨珠的材料和大小，和研磨机的负荷。优选低转速(例如从1到5m/s、优选地从2到4m/s的圆周速度)、在研磨机中的短平均滞留时间(例如1到10分钟)、玻璃珠(例如平均直径为0.5到1.5mm)和70％到90％的平均负荷。
优选的研磨参数可根据研磨步骤中使用的球磨机而有所不同，但是这可由本领域技术人员容易地调节，而无需其自身付出创造性劳动。
根据本发明的工艺的步骤c)可在任何合理的温度下进行。加热至约40到60℃是优选的。
干燥步骤可用本领域技术人员已知的任何常规干燥工艺完成，优选的是喷雾干燥和/或粉末捕获工艺，所述粉末捕获工艺中喷出的悬浮液微滴被捕获在吸附剂床中并随后被干燥，所述吸附剂例为如淀粉或硅酸钙或癸酸或碳酸钙或其混合物。
根据本发明，如果通过干燥步骤获得的粉末中残余的水分含量在以粉末总重为基础4wt-％到6wt-％的范围内则是有利的。
在本发明的一个优选的实施方案中，步骤c)的悬浮液被喷雾干燥。在该情况下，优选如下选择喷雾干燥参数：
·进气口：约220-180℃，特别是约200℃；
·出气口：约100-70℃，特别是约80℃。
在本发明工艺的一个优选的实施方案中，向粉末中(即在干燥步骤期间)添加或向在步骤d)中获得的产物中添加一种或多种流动调节剂(也称作抗结块剂，流动增强剂)。
优选的流动调节剂是例如(亲水的)烟雾硅胶(fumed silica)，例如可以商品名
从Degussa商业获得的烟雾硅胶。
根据本发明，如果粉末中流动调节剂(一种或多种化合物)的量在以粉末总重为基础按重量计0.1％到0.5％的范围内则是有利的。
本发明还涉及通过上文所公开的本发明的工艺获得的粉末(干燥粉末、微珠或颗粒)。另外，本发明还涉及具有相同特性但是通过不同工艺获得的粉末，即可根据本发明的工艺获得的粉末。
本发明还涉及食物组合物，特别是含有通过所述工艺获得/可通过所述工艺获得的粉末的饮料。本发明的饮料可以是基本组合物，其使用时可以或必须向其中添加水或另一液体饮料组合物(例如乳、果汁等等)。基本组合物可以被制成在消耗前要与水或另一液体饮料组合物混合的干燥的粉末产物(速溶饮料)，被制成必须向其中添加水或另一液体饮料组合物的浓缩物，或被制成不需要向其中添加液体的饮料。
要被添加进食物组合物的根据本发明的粉末的量取决于所述粉末的效能，即粉末中类胡萝卜素的量，所述量根据本发明可在按重量计从约10％到约20％的范围内，优选地在按重量计从约15％到约20％的范围内，所述范围均以粉末的总重为基础。
在澄清饮料的情况下，优选的饮料应当具有与添加粉末前的光学透明度无显著差异的光学透明度，例如通过视检不显示显著更混浊的饮料。
本领域技术人员未曾预见到，向水或另一液体饮料组合物(例如乳、果汁等)添加根据本发明的粉末不会改变液体的颜色，即不会对饮料具有肉眼可见的着色作用。
包含本发明粉末的泡腾片剂也是本发明的部分。本发明的片剂也可溶于液体中，相对于不含本发明粉末的相似泡腾片剂而言不改变颜色。
通过以下的实施例进一步阐述本发明。
实施例
实施例1
将300.0g水加热至80℃。添加100.0g Capsul(OSA-淀粉)并搅拌90分钟。然后添加50.0g Maltodextrin、2.0g玉米油、4.0g dl-α-生育酚和36.0gβ-胡萝卜素晶体，并搅拌30分钟。
将低粘度粗制悬浮液转移至商业搅动球磨机中。将温度调节至50℃并进行研磨过程，直至达成0.9μm的平均粒径。最后在Niro雾化器中干燥经研磨的悬浮液。进气口：200℃，出气口：80℃。
获得含有17.2％(w/w)β-胡萝卜素的红色粉末。色彩强度(E1％1cm)为0。
实施例2
将300.0g水加热至80℃。添加100.0g Capsul(OSA-淀粉)并搅拌90分钟。然后添加52.0g Maltodextrin、4.0g dl-α-生育酚和36.0g β-胡萝卜素晶体，并搅拌30分钟。
将低粘度粗制悬浮液转移至商业搅动球磨机中。将温度调节至50℃并进行研磨过程，直至达成0.6μm的平均粒径。最后在Niro雾化器中干燥经研磨的悬浮液。进气口：200℃，出气口：80℃。
获得含有17.8％(w/w)β-胡萝卜素的红色粉末。色彩强度(E1％1cm)为22。
Claims (13)
1.制造含有一种或多种类胡萝卜素的粉末的工艺，所述工艺包括下述步骤：
a)提供多糖的水溶液；
b)在步骤a)的所述溶液中形成类胡萝卜素悬浮液；
c)研磨步骤b)的所述悬浮液，直至类胡萝卜素颗粒的平均粒径在从约0.6μm到约1.4μm的范围内；
d)干燥步骤c)的所述悬浮液。
2.根据权利要求1的工艺，特征是所述多糖选自金合欢胶、果胶、纤维素、纤维素衍生物和/或改性的多糖。
3.根据前述权利要求任一项的工艺，特征是所述多糖选自改性的多糖。
4.根据前述权利要求任一项的工艺，特征是以下述方式选择步骤a)的所述水溶液中水和多糖(一种或多种化合物)的量，所述方式使得根据本发明步骤b)的所述悬浮液中多糖的量在按重量计从15％到25％的范围内，并且所述悬浮液中水的量在按重量计从50％到70％的范围内，所述范围均以所述悬浮液的总重为基础。
5.根据前述权利要求任一项的工艺，特征是在步骤b)中添加的类胡萝卜素(一种或多种化合物)的量以所述悬浮液的总重为基础在按重量计从2％到11％的范围内。
6.根据前述权利要求任一项的工艺，特征是在步骤b)中向步骤a)的所述溶液中添加其它佐剂，所述佐剂选自以下组中的一个或多个：稀释剂；抗氧化剂(脂溶性或水溶性)；甘油三酯(油和/或脂肪)。
7.根据前述权利要求任一项的工艺，特征是用球磨机完成所述研磨步骤。
8.根据前述权利要求任一项的工艺，特征是所述干燥步骤是喷雾干燥步骤。
9.能够通过根据前述权利要求任一项的工艺获得的粉末。
10.含有根据权利要求9的粉末的食物、饮料或药物制剂。
11.含有根据权利要求9的粉末的饮料。
12.在消耗前要与水或另一液体饮料组合物混合的干燥粉末产品(速溶饮料)，所述速溶饮料含有根据权利要求9的粉末。
13.根据权利要求1到8中任一项的粉末用于制造食物、饮料或药物制剂的用途，所述食物、饮料或药物制剂包括任何种类的即食食物和速溶饮料。
Applications Claiming Priority (3)
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|---|---|---|---|
| EP07003110.9 | 2007-02-14 | ||
| EP07003110.9A EP1964479B1 (en) | 2007-02-14 | 2007-02-14 | Process for the manufacture of a powder containing carotenoids |
| US60/907,585 | 2007-04-10 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101610683A true CN101610683A (zh) | 2009-12-23 |
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| CNA2008800051839A Pending CN101610683A (zh) | 2007-02-14 | 2008-02-04 | 制造含有类胡萝卜素的粉末的工艺 |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20100136177A1 (zh) |
| EP (1) | EP1964479B1 (zh) |
| CN (1) | CN101610683A (zh) |
| ES (1) | ES2422458T3 (zh) |
| PL (1) | PL1964479T3 (zh) |
| WO (1) | WO2008098694A1 (zh) |
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| US4389419A (en) * | 1980-11-10 | 1983-06-21 | Damon Corporation | Vitamin encapsulation |
| US4992282A (en) * | 1989-05-08 | 1991-02-12 | The Procter & Gamble Company | Stable nutritional vitamin and mineral supplemented beverage |
| DK546289D0 (da) * | 1989-11-02 | 1989-11-02 | Danochemo As | Carotenoidpulvere |
| DK19393D0 (da) * | 1993-02-19 | 1993-02-19 | Danochemo As | Fremgangsmaade til fremstilling af et i vand dispergerbart pulverformigt carotenoidpraeparat |
| EP1178738B2 (en) * | 1999-05-21 | 2010-10-20 | Chr. Hansen A/S | A colouring substance composition and a method of manufacturing same |
| US20060110517A1 (en) * | 2003-01-31 | 2006-05-25 | Reinhold Carle | Novel compositions comprising carotenoids |
| DE102004046026A1 (de) * | 2004-09-21 | 2006-03-23 | Basf Ag | Verfahren zur Herstellung von Trockenpulvern eines oder mehrerer Carotinoide |
| DE102005030952A1 (de) * | 2005-06-30 | 2007-01-18 | Basf Ag | Verfahren zur Herstellung einer wässrigen Suspension und einer pulverförmigen Zubereitung eines oder mehrerer Carotinoide |
| EP1903887A1 (en) * | 2005-07-20 | 2008-04-02 | DSMIP Assets B.V. | Novel stabilized carotenoid compositions |
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2007
- 2007-02-14 EP EP07003110.9A patent/EP1964479B1/en not_active Revoked
- 2007-02-14 PL PL07003110T patent/PL1964479T3/pl unknown
- 2007-02-14 ES ES07003110T patent/ES2422458T3/es active Active
-
2008
- 2008-02-04 US US12/526,148 patent/US20100136177A1/en not_active Abandoned
- 2008-02-04 WO PCT/EP2008/000848 patent/WO2008098694A1/en active Application Filing
- 2008-02-04 CN CNA2008800051839A patent/CN101610683A/zh active Pending
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| CN108697149A (zh) * | 2016-03-02 | 2018-10-23 | 巴斯夫欧洲公司 | 振动液滴形成 |
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| US11744266B2 (en) | 2016-03-15 | 2023-09-05 | Dsm Ip Assets B.V. | Coated particles |
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| CN109069433B (zh) * | 2016-04-01 | 2021-10-26 | 帝斯曼知识产权资产管理有限公司 | 新颖的叶黄素和/或玉米黄质的可片剂化制剂 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1964479B1 (en) | 2013-05-15 |
| ES2422458T3 (es) | 2013-09-11 |
| PL1964479T3 (pl) | 2013-09-30 |
| WO2008098694A1 (en) | 2008-08-21 |
| US20100136177A1 (en) | 2010-06-03 |
| EP1964479A1 (en) | 2008-09-03 |
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