CN101600823A - 可湿性的聚酯纤维和织物 - Google Patents
可湿性的聚酯纤维和织物 Download PDFInfo
- Publication number
- CN101600823A CN101600823A CNA2008800014492A CN200880001449A CN101600823A CN 101600823 A CN101600823 A CN 101600823A CN A2008800014492 A CNA2008800014492 A CN A2008800014492A CN 200880001449 A CN200880001449 A CN 200880001449A CN 101600823 A CN101600823 A CN 101600823A
- Authority
- CN
- China
- Prior art keywords
- long filament
- butyl
- polyester
- phenyl
- tert
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 229920000728 polyester Polymers 0.000 title claims abstract description 63
- 239000000835 fiber Substances 0.000 title claims abstract description 59
- 239000004744 fabric Substances 0.000 title claims abstract description 32
- 239000000203 mixture Substances 0.000 claims abstract description 61
- 229910052751 metal Inorganic materials 0.000 claims abstract description 36
- 239000002184 metal Substances 0.000 claims abstract description 36
- 150000008052 alkyl sulfonates Chemical class 0.000 claims abstract description 26
- 238000000034 method Methods 0.000 claims abstract description 21
- 239000002253 acid Substances 0.000 claims abstract description 15
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims abstract description 11
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 claims abstract description 5
- 150000001875 compounds Chemical class 0.000 claims description 37
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 30
- 239000001301 oxygen Substances 0.000 claims description 16
- 229910052760 oxygen Inorganic materials 0.000 claims description 16
- 238000002360 preparation method Methods 0.000 claims description 15
- 239000000463 material Substances 0.000 claims description 13
- 229920000642 polymer Polymers 0.000 claims description 12
- 238000004519 manufacturing process Methods 0.000 claims description 10
- 239000004594 Masterbatch (MB) Substances 0.000 claims description 9
- 229910052708 sodium Inorganic materials 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 7
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 238000009940 knitting Methods 0.000 claims description 6
- 229910052744 lithium Inorganic materials 0.000 claims description 4
- 239000000155 melt Substances 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- 229910052700 potassium Inorganic materials 0.000 claims description 4
- 206010021639 Incontinence Diseases 0.000 claims description 3
- 229920000747 poly(lactic acid) Polymers 0.000 claims description 3
- 238000012549 training Methods 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 239000000654 additive Substances 0.000 abstract description 20
- 230000000996 additive effect Effects 0.000 abstract description 19
- -1 polyethylene terephthalate Polymers 0.000 description 93
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 48
- 229910052757 nitrogen Inorganic materials 0.000 description 35
- 238000003756 stirring Methods 0.000 description 30
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 30
- 239000000243 solution Substances 0.000 description 28
- 238000005481 NMR spectroscopy Methods 0.000 description 26
- 239000000376 reactant Substances 0.000 description 22
- 239000002585 base Substances 0.000 description 19
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 18
- 239000012535 impurity Substances 0.000 description 18
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 17
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 15
- 239000000047 product Substances 0.000 description 14
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 13
- 150000002148 esters Chemical class 0.000 description 13
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 12
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-Tetramethylpiperidine Substances CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 12
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 11
- 239000007787 solid Substances 0.000 description 11
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 10
- 150000001412 amines Chemical class 0.000 description 10
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 10
- 238000002329 infrared spectrum Methods 0.000 description 10
- 229940079827 sodium hydrogen sulfite Drugs 0.000 description 10
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N propylene glycol Substances CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- JIHQDMXYYFUGFV-UHFFFAOYSA-N 1,3,5-triazine Chemical compound C1=NC=NC=N1 JIHQDMXYYFUGFV-UHFFFAOYSA-N 0.000 description 8
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 8
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 8
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 8
- 230000029936 alkylation Effects 0.000 description 8
- 238000005804 alkylation reaction Methods 0.000 description 8
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 8
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 8
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 7
- 239000007859 condensation product Substances 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 7
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 7
- 239000012299 nitrogen atmosphere Substances 0.000 description 7
- 150000008301 phosphite esters Chemical class 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- 239000012312 sodium hydride Substances 0.000 description 7
- 229910000104 sodium hydride Inorganic materials 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- FIDRAVVQGKNYQK-UHFFFAOYSA-N 1,2,3,4-tetrahydrotriazine Chemical compound C1NNNC=C1 FIDRAVVQGKNYQK-UHFFFAOYSA-N 0.000 description 6
- 239000012153 distilled water Substances 0.000 description 6
- 238000001704 evaporation Methods 0.000 description 6
- 229910052759 nickel Inorganic materials 0.000 description 6
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 6
- 229920000139 polyethylene terephthalate Polymers 0.000 description 6
- 239000005020 polyethylene terephthalate Substances 0.000 description 6
- 238000001291 vacuum drying Methods 0.000 description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
- 239000005864 Sulphur Substances 0.000 description 5
- 238000013019 agitation Methods 0.000 description 5
- 239000001273 butane Substances 0.000 description 5
- 150000001721 carbon Chemical group 0.000 description 5
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexamethylene diamine Natural products NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- FTWUXYZHDFCGSV-UHFFFAOYSA-N n,n'-diphenyloxamide Chemical compound C=1C=CC=CC=1NC(=O)C(=O)NC1=CC=CC=C1 FTWUXYZHDFCGSV-UHFFFAOYSA-N 0.000 description 5
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 5
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 5
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 5
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 5
- 235000019394 potassium persulphate Nutrition 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 239000003381 stabilizer Substances 0.000 description 5
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 5
- ALVZNPYWJMLXKV-UHFFFAOYSA-N 1,9-Nonanediol Chemical compound OCCCCCCCCCO ALVZNPYWJMLXKV-UHFFFAOYSA-N 0.000 description 4
- UUABJBNMBCIBFA-UHFFFAOYSA-N 1-hydroxy-2-(2-hydroxyethoxy)ethanesulfonic acid Chemical compound OCCOCC(O)S(O)(=O)=O UUABJBNMBCIBFA-UHFFFAOYSA-N 0.000 description 4
- GLDQAMYCGOIJDV-UHFFFAOYSA-N 2,3-dihydroxybenzoic acid Chemical compound OC(=O)C1=CC=CC(O)=C1O GLDQAMYCGOIJDV-UHFFFAOYSA-N 0.000 description 4
- ZPIRWAHWDCHWLM-UHFFFAOYSA-N 2-dodecylsulfanylethanol Chemical compound CCCCCCCCCCCCSCCO ZPIRWAHWDCHWLM-UHFFFAOYSA-N 0.000 description 4
- BGQNNKZAJXZSPQ-UHFFFAOYSA-N 5,6-dimethylheptane-1,6-diol Chemical compound CC(O)(C)C(C)CCCCO BGQNNKZAJXZSPQ-UHFFFAOYSA-N 0.000 description 4
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 4
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 4
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 4
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical class C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 4
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 4
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 4
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Natural products OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 4
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- 239000000706 filtrate Substances 0.000 description 3
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- 150000003839 salts Chemical class 0.000 description 3
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- 125000004213 tert-butoxy group Chemical group [H]C([H])([H])C(O*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 3
- GPOGLVDBOFRHDV-UHFFFAOYSA-N (2-nonylphenyl) dihydrogen phosphite Chemical compound CCCCCCCCCC1=CC=CC=C1OP(O)O GPOGLVDBOFRHDV-UHFFFAOYSA-N 0.000 description 2
- JEFSTMHERNSDBC-UHFFFAOYSA-N 1,2-dimethylcyclohexa-2,4-dien-1-ol Chemical compound CC1=CC=CCC1(C)O JEFSTMHERNSDBC-UHFFFAOYSA-N 0.000 description 2
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 description 2
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- SLUKQUGVTITNSY-UHFFFAOYSA-N 2,6-di-tert-butyl-4-methoxyphenol Chemical compound COC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SLUKQUGVTITNSY-UHFFFAOYSA-N 0.000 description 2
- FJGQBLRYBUAASW-UHFFFAOYSA-N 2-(benzotriazol-2-yl)phenol Chemical compound OC1=CC=CC=C1N1N=C2C=CC=CC2=N1 FJGQBLRYBUAASW-UHFFFAOYSA-N 0.000 description 2
- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 description 2
- MSXVEPNJUHWQHW-UHFFFAOYSA-N 2-methylbutan-2-ol Chemical compound CCC(C)(C)O MSXVEPNJUHWQHW-UHFFFAOYSA-N 0.000 description 2
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- BWDBEAQIHAEVLV-UHFFFAOYSA-N 6-methylheptan-1-ol Chemical compound CC(C)CCCCCO BWDBEAQIHAEVLV-UHFFFAOYSA-N 0.000 description 2
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- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
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- 229910019142 PO4 Inorganic materials 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- 125000002723 alicyclic group Chemical group 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 2
- 229910052787 antimony Inorganic materials 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 125000005605 benzo group Chemical group 0.000 description 2
- 239000004305 biphenyl Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 159000000007 calcium salts Chemical class 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
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- MHDVGSVTJDSBDK-UHFFFAOYSA-N dibenzyl ether Chemical compound C=1C=CC=CC=1COCC1=CC=CC=C1 MHDVGSVTJDSBDK-UHFFFAOYSA-N 0.000 description 2
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- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/696—Including strand or fiber material which is stated to have specific attributes [e.g., heat or fire resistance, chemical or solvent resistance, high absorption for aqueous compositions, water solubility, heat shrinkability, etc.]
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- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Artificial Filaments (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Nonwoven Fabrics (AREA)
- Woven Fabrics (AREA)
Abstract
本发明的目的在于一种方法,该方法为聚酯纤维或长丝、由其制备的机织或非织造织物、和由此制造的制品提供润湿性。该方法包括将包含聚酯和一种或多种选自苯基烷基-氧-烷基金属磺酸盐、烷基-氧-烷基金属磺酸盐、聚亚乙基氧-烷基金属磺酸盐、烷基-聚亚乙基-氧-烷基金属磺酸盐以及烷基-1,2-二磺酸金属磺酸盐的添加剂的混合物熔融挤出成多根纤维或长丝并冷却纤维或长丝。
Description
本发明涉及一种提供具有耐久可湿性的聚酯针织、机织、非织造织物的方法,以及由此制备的制品。
US 4,357,390教导了具有抗静电性的中空聚酯纤维。
US 4,351,738教导了高速摩擦假拉伸加捻变形的聚酯长丝纱。
US 4,666,764公开了具有拒水性的抗静电聚酯织物。
已经令人惊讶地发现将聚酯与某种苯基烷基-氧-烷基金属磺酸盐、烷基-氧-烷基金属磺酸盐或聚亚乙基氧-烷基金属磺酸盐熔融共混,并将混合物挤出成纤维,为聚酯纤维或长丝提供耐久可湿性和高湿处理性能。
公开了可湿性聚酯纤维或长丝,该聚酯纤维或长丝包括聚酯和一种或多种选自下面的化合物的熔融共混物:
a)具有下式的苯基烷基-氧-烷基金属磺酸盐
b)具有下式的烷基-氧-烷基金属磺酸盐
c)具有下式的聚亚乙基氧-烷基金属磺酸盐
d)具有下式的烷基-聚亚乙基氧-烷基金属磺酸盐
e)烷基-1,2-二磺酸金属磺酸盐
其中
m是0、1或2,
n是1-6的整数,
p是1-16的整数,
R是具有1-24个碳原子的烷基,以及
M是Na、K或Li。
优选,聚酯纤维或长丝包括一种或多种组分a)的苯基烷基-氧-烷基金属磺酸盐。
引人注意的是包括一种或多种组分b)的烷基-氧-烷基金属磺酸盐的聚酯纤维或长丝。
同样引人注意的是包括一种或多种组分c)的聚亚乙基氧-烷基金属磺酸盐的聚酯纤维或长丝。
特别引人注意的是包括一种或多种组分d)的烷基-聚亚乙基氧-烷基金属磺酸盐的聚酯纤维或长丝。
优选,聚酯纤维或长丝包括一种或多种组分e)的烷基-1,2-二磺酸金属磺酸盐。
还公开了一种赋予聚酯纤维或长丝可湿性的方法,该方法包括将包括聚酯和一种或多种选自组分a)、b)、c)、d)和e)的化合物的混合物熔融挤出成多根纤维或长丝,并冷却纤维或长丝。
本方法生产纤维或长丝,其分别针织、机织或粘合成针织、机织或非织造织物。
因此,本发明涉及由纤维或长丝生产的可湿性针织、机织或非织造织物。
本发明的熔融挤出方法形成纤维或长丝。根据已知技术例如纱线或短纤维的连续长丝纺丝,以及例如纺粘制造或熔喷制造的非织造工艺,纤维或长丝由熔体聚合物通过小喷丝孔挤出形成。通常,这样形成的纤维或长丝之后被拉伸或拉长以诱导分子取向和影响结晶度,使得直径减小以及物理性能改善。在例如纺粘和熔喷的非织造工艺中,纤维或长丝直接沉积在多孔表面上,例如移动的扁平传送带上并至少部分地由多种粘结方式的任意者固结。结合工艺或来自不同工艺的织物以制备具有某种所需特性的复合织物对本领域技术人员来说是已知的。这样的例子为联合纺粘和熔喷生产层压织物。另外这些工艺的任一个或两个可以与短纤维梳理工艺或由非织造短纤维梳理工艺产生的粘结织物以任意排列联合。在这样描述的层压织物中,通常各层是至少部分固结的。
本发明也适用于熔体挤出双组份纤维,根据本发明,其中组分之一是聚酯。
聚酯的非织造织物可以具有梳理纤维结构或包括纤维或长丝以无规排列方式分布的毡子。织物可以由包括水刺缠结(hydroentanglement)或射流喷网技术的多个已知工艺中的任一种或通过气体铺网或熔喷长丝、絮片拉伸(batt drawing)、缝合粘结等形成和粘结,取决于由织物制备的制品的最终用途。
热塑性聚酯纤维典型地在约285-约300℃温度范围挤出。
根据本发明,组分a)、b)、c)、d)和e)中的一种或多种化合物以熔体掺入到热塑性聚酯,例如聚对苯二甲酸乙二醇酯中,并与聚酯挤出形成纤维和长丝,然后在后续或同时进行的加工步骤中骤冷、变细并形成织物。
术语“可湿的”意思是提供亲水性。添加剂a)、b)、c)、d)和e)是亲水性添加剂。
组分a)、b)、c)、d)和e)的化合物可以与熔融挤出的聚合物粒料混合。为了改进加工,所述化合物可以预先配制或混合进入聚酯,聚酯也可以包括添料,例如滑石以及其它普通稳定剂。
组分a)、b)、c)、d)和e)的化合物的混合是用通常使用的技术,例如滚压研磨,将它们混合入熔融的聚合物中,在Banbury型混合器中混合,或者在挤出套筒和类似物中混合。将a)、b)、c)、d)和e)的化合物与未加热聚合物颗粒混合能缩短热历史(在高温持续的时间),以实现试剂在聚合物本体中的基本均匀分布,因此减少熔融温度下强烈混合所需的时间。
方便地,组分a)、b)、c)、d)和e)的化合物也能与某种情况下可能需要的任意其它添加剂基本上同时或顺序添加。a)、b)、c)、d)和e)的化合物也可以与其它添加剂预共混,之后将共混物添加到聚合物中。在一些情况下期望a)、b)、c)、d)和e)的化合物可能具有额外的益处,即有助于其它添加剂更容易或均匀地分散或溶解在聚酯中。为了更容易控制各批的质量,可以优选应用聚合物/添加剂共混物的浓缩母料,随后成份地共混入附加份量的聚合物中以获得最终期望的配方。母料或纯的添加剂,可以注入新鲜制备的依然是熔体且在离开聚合容器或***(train)后的聚合物中,并在熔体聚合物冷却成固体或进行进一步加工之前与之共混。
因此,也公开了一种本发明的方法,其包括制备包含组分a)、b)、c)、d)和e)中的一种或多种的化合物以及聚合物的母料,熔融挤出包含所述母料和聚酯的混合物形成多根纤维或长丝并冷却纤维或长丝。
本发明的母料,或浓缩物包括以例如约1%-75%、2%-50%,或5%-40%的重量浓度掺入到聚合物中的组分a)、b)、c)、d)和e)的化合物。
母料聚合物可以是聚酯或者是某种其它热塑性聚合物。
在本发明的方法中,基于聚酯的总重量,组分a)、b)、c)、d)和e)的添加剂化合物总量为0.05%-5.0%重量。例如烷基金属磺酸盐基于聚酯的总重量以0.1%-3.7%、0.25%-3.2%、0.5%-2.7%、0.4%-2.7%、0.3%-2.7%、0.1%-1.0%的量存在。例如本发明的烷基金属磺酸盐以约0.2%、0.3%、0.5%、0.75%、1.0%、2.0%、2.5%、3.5%或约4.5%的量存在,基于聚酯总重量。
依据本发明,将组分a)、b)、c)、d)和e)的一种或多种添加剂化合物掺入到聚酯纤维或长丝中导致在这些材料中观察到改进的可湿性。该改进也是耐久性的,因此纤维或长丝以及由其制备的织物不随老化或加工而失去它们的可湿性。改进的可湿性耐反复的损害,甚至超过延长的时间周期。
本发明的目的在于非织造织物,例如聚酯织物。目的还在于以常规纺织工艺用于机织或针织的线或纱。
本发明组分a)、b)、c)、d)和e)的化合物无关于其它影响非织造织物性能的因素而起作用,例如单位重量、纤维直径、纤维粘结程度和类型,以及复合结构的协同作用和影响。
本发明不限于单组分纤维。期望聚酯双组份纤维,特别是并列或皮芯纤维展示如单组份纤维一样的实用益处。只在单个聚酯组分中包含熔融添加剂可能是特别有效的。
本方法可以应用于中空聚酯纤维,例如在US 4,357,390、US 4,666,764和US 4,351,738中公开的。本发明不限于圆形或中空横截面,在其它例如三角形、三叶形等的横截面中也有效。
本发明的织物可以通过暴露于约0.5-约10兆拉德的伽马照射来消毒。用伽马照射来消毒应用于医院衣服和类似物中。
根据本发明制备的聚酯机织造和非织造纤维和织物还展示出特别的适印性。
根据本发明的纤维和织物具有优异的柔软性。
聚酯具有选自含8-14个碳原子的芳族二羧酸、含4-12个碳原子的脂族二羧酸、含8-12个碳原子的脂环族二羧酸、以及其混合物的二羧酸重复单元。
例如这样的二酸是对苯二甲酸、间苯二甲酸、邻苯二甲酸、萘二甲酸、环己烷二甲酸、环己烷二乙酸、二苯基-4,4’-二甲酸、琥珀酸、马来酸、戊二酸、己二酸、癸二酸及其混合物。
例如二酸是对苯二甲酸、间苯二甲酸和2,6-萘二甲酸。
聚酯的二醇或二元醇部分是从通式HO-G-OH衍生的,其中G是含2-18个碳原子的脂族、脂环族或芳族部分。
例如这样的二醇或二元醇是乙二醇、二甘醇、三甘醇、1,3-丙二醇、1,2-丙二醇、1,4-丁二醇、1,5-戊二醇、1,6-己二醇、1,4-环己烷二甲醇、3-甲基-2,4-戊二醇、2-甲基-1,4-戊二醇、2,2-二乙基-1,3-丙二醇、1,4-二-(羟基乙氧基)苯、2,2-二(4-羟基环己基)-丙烷、2,4-二羟基-1,1,3,3-四甲基环丁烷、2,2-二-(3-羟基乙氧基苯基)丙烷、2,2-二(4-羟基丙氧基苯基)乙烷以及其混合物。
例如二醇是乙二醇或1,4-环己烷二甲醇。
例如聚酯是聚(对苯二甲酸乙二醇酯)PET或聚(2,6-萘-2,6-二甲酸乙二醇酯)PEN或聚(乳酸)PLA。
也期望聚酯也可以是聚酯或包括前述组分的共聚酯的共混物。
另外期望采用本发明的烷基金属磺酸盐为不同于聚酯的聚合物基材提供突出的可湿性。例如聚烯烃或聚酰胺。例如聚丙烯、聚乙烯或其共聚物或其混合物。例如聚酰胺6,6。例如,也期望用这些基材制备机织或非织造织物。
具有最多24个碳原子的烷基是支化或未支化的基团,例如甲基、乙基、丙基、异丙基、正丁基、仲丁基、异丁基、叔丁基、2-乙基丁基、正戊基、异戊基、1-甲基戊基、1,3-二甲基丁基、正己基、1-甲基己基、正庚基、异庚基、1,1,3,3-四甲基丁基、1-甲基庚基、3-甲基庚基、正辛基、2-乙基己基、1,1,3-三甲基己基、1,1,3,3-四甲基戊基、壬基、癸基、十一烷基、1-甲基十一烷基、十二烷基、1,1,3,3,5,5-六甲基己基、十三烷基、十四烷基、十五烷基、十六烷基、十七烷基、十八烷基、二十烷基或二十二烷基。
也设想,除钠、钾或锂外的其它反离子也适用在烷基金属磺酸盐中。例如铵或单、双、三或四烷基铵离子。例如碱金属阳离子、碱土金属阳离子或铝阳离子,例如镁、钙或铝离子。
由本发明的方法制备的组合物也可以任选地包含0.01-10%,优选0.025-5%,特别是0.1-3%重量的各种常规稳定剂共添加剂(coaddtives),如以下所列的材料或其混合物。
1.抗氧化剂
1.1.烷基化单苯酚,例如2,6-二叔丁基-4-甲基苯酚、2-叔丁基-4,6-二甲基苯酚、2,6-二叔丁基-4-乙基苯酚、2,6-二叔丁基-4-正丁基苯酚、2,6-二叔丁基-4-异丁基苯酚、2,6-二环戊基-4-甲基苯酚、2-(α-甲基环己基)-4,6-二甲基苯酚、2,6-双十八烷基-4-甲基苯酚、2,4,6-三环己基苯酚、2,6-二叔丁基-4-甲氧基甲基苯酚、线性的或支链中有分支的壬基苯酚,例如2,6-二壬基-4-甲基苯酚、2,4-二甲基-6-(1-甲基十一烷-1-基)苯酚、2,4-二甲基-6-(1-甲基十七烷-1-基)苯酚、2,4-二甲基-6-(1-甲基十三烷-1-基)苯酚和它们的混合物。
1.2.烷硫基甲基苯酚,例如2,4-二辛硫基甲基-6-叔丁基苯酚、2,4-二辛硫基甲基-6-甲基苯酚、2,4-二辛硫基甲基-6-乙基苯酚、2,6-二-十二烷硫基甲基-4-壬基苯酚。
1.3.对苯二酚和烷基化对苯二酚,例如2,6-二叔丁基-4-甲氧基苯酚、2,5-二叔丁基对苯二酚、2,5-二叔戊基对苯二酚、2,6-二苯基-4-十八烷环氧基苯酚、2,6-二叔丁基对苯二酚、2,5-二叔丁基-4-羟基苯甲醚、3,5-二叔丁基-4-羟基苯甲醚、3,5-二叔丁基-4-羟基苯基硬脂酸酯、二(3,5-二叔丁基-4-羟基苯基)己二酸酯。
1.4.生育酚,例如α-生育酚、β-生育酚、γ-生育酚、δ-生育酚和它们的混合物(维生素E)。
1.5.羟基化硫二苯醚,例如2,2’-硫二(6-叔丁基-4-甲基苯酚)、2,2’-硫二(4-辛基苯酚)、4,4’-硫二(6-叔丁基-3-甲基苯酚)、4,4’-硫二(6-叔丁基-2-甲基苯酚)、4,4’-硫二-(3,6-二仲戊基苯酚)、4,4’-二(2,6-二甲基-4-羟基苯基)二硫化物。
1.6.亚烷基二苯酚,例如2,2’-亚甲基二(6-叔丁基-4-甲基苯酚)、2,2’-亚甲基二(6-叔丁基-4-乙基苯酚)、2,2’-亚甲基二[4-甲基-6-(α-甲基环己基)-苯酚]、2,2’-亚甲基二(4-甲基-6-环己基苯酚)、2,2’-亚甲基二(6-壬基-4-甲基苯酚)、2,2’-亚甲基二(4,6-二叔丁基苯酚)、2,2’-亚乙基二(4,6-二叔丁基苯酚)、2,2’-亚乙基二(6-叔丁基-4-异丁基苯酚)、2,2’-亚甲基二[6-(α-甲基苄基)-4-壬基苯酚]、2,2’-亚甲基二[6-(α,α-二甲基苄基)-4-壬基苯酚]、4,4’-亚甲基二(2,6-二叔丁基苯酚)、4,4’-亚甲基二(6-叔丁基-2-甲基苯酚)、1,1-二(5-叔丁基-4羟基-2-甲基苯基)丁烷、2,6-二(3-叔丁基-5-甲基-2-羟基苄基)-4-甲基苯酚、1,1,3-三(5-叔丁基-4-羟基-2-甲基苯基)丁烷、1,1-二(5-叔丁基-4-羟基-2-甲基-苯基)-3-正十二烷基巯基丁烷、乙二醇二[3,3-二(3-叔丁基-4-羟基苯基)丁酸酯]、二(3-叔丁基-4-羟基-5-甲基苯基)二环戊二烯、双[2-(3′叔丁酯-2-羟基-5-甲基苄基)-6-叔丁基-4-甲基苯基]对苯二甲酸酯、1,1-二-(3,5-二甲基-2-羟基苯基)丁烷、2,2-二-(3,5-二叔丁基-4-羟基苯基)丙烷、2,2-二(5-叔丁基-4-羟基-2-甲基苯基)-4-正十二烷基巯基丁烷、1,1,5,5-四-(5-二叔丁基-4-羟基-2-甲基苯基)戊烷。
1.7.苄基化合物,例如3,5,3′,5’-四叔丁基-4,4’-二羟基二苄基醚、十八烷基-4-羟基-3,5-二甲基苄基巯基乙酸酯、十三烷基-4-羟基-3,5-二叔丁基苄基巯基乙酸酯、三(3,5-二叔丁基-4-羟基苄基)胺、1,3,5-三(3,5-二叔丁基-4-羟基苄基)-2,4,6-三甲基苯、二(3,5-二叔丁基-4-羟基苄基)硫化物、3,5-二叔丁基-4-羟基苄基-巯基-乙酸异辛基酯、二(4-叔丁基-3-羟基-2,6-二甲基苄基)二硫醇对苯二甲酸酯、1,3,5-三(3,5-二叔丁基-4-羟基苄基)异氰脲酸酯、1,3,5-三(4-叔丁基-3-羟基-2,6-二甲基苄基)异氰脲酸酯、3,5-二叔丁基-4-羟基苄基-磷酸双十八烷基酯和3,5-二叔丁基-4-羟基苄基-磷酸单乙基酯,钙盐。
1.8.羟基苄基化丙二酸酯,例如双十八烷基-2,2-二(3,5-二叔丁基-2-羟基苄基)-丙二酸酯、双-十八烷基-2-(3-叔丁基-4-羟基-5-甲基苄基)-丙二酸酯、双十二烷基巯基乙基-2,2-双-(3,5-二叔丁基-4-羟基苄基)丙二酸酯、二[4-(1,1,3,3-四甲基丁基)苯基]-2,2-双(3,5-二叔丁基-4-羟基苄基)丙二酸酯。
1.9.芳族羟基苄基化合物,例如1,3,5-三-(3,5-二叔丁基-4-羟基苄基)-2,4,6-三甲基苯、1,4-双(3,5-二叔丁基-4-羟基苄基)-2,3,5,6-四甲基苯、2,4,6-三(3,5-二叔丁基-4-羟基苄基)苯酚。
1.10.三嗪化合物,例如2,4-二(辛基巯基)-6-(3,5-二叔丁基-4-羟基苯胺基)-1,3,5-三嗪、2-辛基巯基-4,6-二(3,5-二叔丁基-4-羟基苯胺基)-1,3,5-三嗪、2-辛基巯基-4,6-双(3,5-二叔丁基-4-羟基苯氧基)-1,3,5-三嗪、2,4,6-三(3,5-二叔丁基-4-羟基苯氧基)-1,2,3-三嗪、1,3,5-三(3,5-二叔丁基-4-羟基苄基)异氰脲酸酯、1,3,5-三(4-叔丁基-3-羟基-2,6-二甲基苄基)异氰脲酸酯、2,4,6-三(3,5-二叔丁基-4-羟基苯基乙基)-1,3,5-三嗪,1,3,5-三(3,5-二叔丁基-4-羟基苯基丙酰基)-六氢-1,3,5-三嗪、1,3,5-三(3,5-二环己基-4-羟基苄基)异氰脲酸酯。
1.11.苄基膦酸酯,例如二甲基-2,5-二叔丁基-4-羟基苄基膦酸酯、二乙基-3,5-二叔丁基-4-羟基苄基膦酸酯、双十八烷基3,5-二叔丁基4-羟基苄基膦酸酯,双十八烷基-5-叔丁基-4-羟基-3-甲基苄基膦酸酯、3,5-二叔丁基-4-羟基苄基膦酸的一乙基酯的钙盐。
1.12.酰氨基苯酚(Acylaminophenols),例如4-羟基月桂酸苯胺、4-羟基硬脂酸苯胺、2,4-二-辛基巯基-6-(3,5-叔丁基-4-羟基苯胺基)-s-三嗪和辛基-N-(3,5-二叔丁基-4-羟基苯基)-氨基甲酸酯。
1.13.β-(3,5-二叔丁基-4-羟基苯基)丙酸与一元或多元醇的酯,例如与甲醇、乙醇、正辛醇、异辛醇、十八醇、1,6-己二醇、1,9-壬二醇、乙二醇、1,2-丙二醇、新戊二醇、硫代二甘醇、二甘醇、三甘醇、季戊四醇、三(羟乙基)异氰脲酸酯、N,N’-二(羟乙基)草酰胺、3-硫杂十一烷醇、3-硫杂十五烷醇、三甲基己二醇、三羟甲基丙烷、4-羟基甲基-1-磷杂-2,6,7-三氧杂双环[2,2,2]辛烷。
1.14.β-(5-叔丁基-4-羟基-3-甲基苯基)丙酸与一元或多元醇的酯,例如与甲醇、乙醇、正辛醇、异辛醇、十八烷醇、1,6-己二醇、1,9-壬二醇、乙二醇、1,2-丙二醇、新戊二醇、硫代二甘醇、二甘醇、三甘醇、季戊四醇、三(羟乙基)异氰脲酸酯、N,N’-二(羟乙基)草酰胺、3-硫杂十一烷醇、3-硫杂十五烷醇、三甲基己二醇、三羟甲基丙烷、4-羟基甲基-1-磷杂-2,6,7-三氧杂双环[2,2,2]辛烷。
1.15.β-(3,5-双环己基-4-羟基苯基)丙酸与一元或多元醇的酯,例如与甲醇、乙醇、辛醇、十八烷醇、1,6-己二醇、1,9-壬二醇、乙二醇、1,2-丙二醇、新戊二醇、硫代二甘醇、二甘醇、三甘醇、季戊四醇、三(羟乙基)异氰脲酸酯、N,N’-二(羟乙基)草酰胺、3-硫杂十一烷醇、3-硫杂十五烷醇、三甲基己二醇、三羟甲基丙烷、4-羟基甲基-1-磷杂-2,6,7-三氧杂双环[2,2,2]辛烷。
1.16.3,5-二叔丁基-4-羟基苯基乙酸与一元或多元醇的酯,例如与甲醇、乙醇、辛醇、十八烷醇、1,6-己二醇、1,9-壬二醇、乙二醇、1,2-丙二醇、新戊二醇、硫代二甘醇、二甘醇、三甘醇、季戊四醇、三(羟乙基)异氰脲酸酯、N,N’-二(羟乙基)草酰胺、3-硫杂十一烷醇、3-硫杂十五烷醇、三甲基己二醇、三羟甲基丙烷、4-羟基甲基-1-磷杂-2,6,7-三氧杂双环[2,2,2]辛烷。
1.17.β-(3,5-二叔丁基-4-羟基苯基)丙酸的酰胺,例如N,N’-双(3,5-二叔丁基-4-羟基苯基丙酰基)己二酰胺、N,N’-双(3,5-二叔丁基-4-羟基苯基丙酰基)丙二酰胺、N,N’-二(3,5-二叔丁基-4-羟基苯基丙酰基)酰肼、N,N’-二[2-(3-[3,5-二叔丁基-4-羟基苯基]丙酸基)乙基]草酰胺(由Uniroyal提供的XL-1)。
1.18.抗坏血酸(维生素C)
1.19.胺类抗氧化剂,例如N,N’-二-异丙基对苯二胺、N,N’-二仲丁基对苯二胺、N,N’-二(1,4-二甲基戊基)对苯二胺、N,N’-二(1-乙基-3-甲基戊基)对苯二胺、N,N’-二(1-甲基庚基)对苯二胺、N,N’-二环己基对苯二胺、N,N’-二苯基对苯二胺、N,N’-二(2-萘基)对苯二胺,N-异丙基-N’-苯基对苯二胺、N-(1,3-二甲基丁基)-N’-苯基对苯二胺,N-(1-甲基庚基)-N’-苯基对苯二胺、N-环己基-N’-苯基对苯二胺、4-(对甲苯氨磺酰基)二苯胺、N,N’-二甲基-N,N’-二仲丁基对苯二胺、二苯胺、N-烯丙基二苯胺、4-异丙氧基-二苯胺、N-苯基-1-萘胺、N-(4-叔辛基苯基)-1-萘胺、N-苯基-2-萘胺、辛基化(octylated)二苯胺例如p,p’-二叔辛基二苯胺、4正丁基氨基苯酚、4-丁酰氨基苯酚、4-壬酰氨基苯酚、4-十二酰氨基苯酚、4-十八酰氨基苯酚、二(4-甲氧基苯基)胺、2,6-二叔丁基-4-二甲氨基甲基苯酚、2,4’-二氨基二苯基甲烷、4,4’-二氨基二苯基甲烷、N,N,N’,N’-四甲基-4,4’-二氨基二苯基甲烷、1,2-二[(2-甲基苯基)氨基]乙烷、1,2-二(苯基氨基)丙烷、(邻甲苯基)双胍、二[4-(1′,3’-二甲基丁基)苯基]胺、叔辛基化(octylated)N-苯基-1-萘胺、一烷基化(monoalkylated)和二烷基化(dialkylated)叔丁基/叔辛基二苯胺的混合物、一烷基化和二烷基化壬基二苯胺的混合物、一烷基化和二烷基化十二烷基二苯胺的混合物、一烷基化和二烷基化异丙基/异己基二苯胺的混合物、一烷基化和二烷基化叔丁基二苯胺的混合物、2,3-二氢-3,3-二甲基-4H-1,4-苯并噻嗪、吩噻嗪、一烷基化和二烷基化叔丁基/叔辛基吩噻嗪的混合物、一烷基化和二烷基化叔辛基吩噻嗪的混合物、N-烯丙基吩噻嗪、N,N,N’,N’-四苯基-1,4-二氨基丁-2-烯、N,N-二(2,2,6,6-四甲基-哌啶(piperid)-4-基-环己二胺。
2.紫外线吸收剂和光稳定剂
2.1.2-(2-羟基苯基)-2H-苯并***,例如已知的商业化的羟基苯基-2H-苯并***和苯并***,如在以下专利中公开的:美国专利号3,004,896;3,055,896;3,072,585;3,074,910;3,189,615;3,218,332;3,230,194;4,127,586;4,226,763;4,275,004;4,278,589;4,315,848;4,347,180;4,383,863;4,675,352;4,681,905;4,853,471;5,268,450;5,278,314;5,280,124;5,319,091;5,410,071;5,436,349;5,516,914;5,554,760;5,563,242;5,574,166;5,607,987和5,977,219,例如2-(2-羟基-5-甲基苯基)-2H-苯并***、2-(3,5-二叔丁基-2-羟基苯基)-2H-苯并***、2-(2-羟基-5-叔丁基苯基)-2H-苯并***、2-(2-羟基-5-叔辛基苯基)-2H-苯并***、5-氯-2-(3,5-二叔丁基-2-羟基苯基)-2H-苯并***、5-氯-2-(3-叔丁基-2-羟基-5-甲基苯基)-2H-苯并***、2-(3-仲丁基-5-叔丁基-2-羟基苯基)-2H-苯并***、2-(2-羟基-4-辛氧基苯基)-2H-苯并***、2-(3,5-二叔戊基-2-羟基苯基)-2H-苯并***、2-(3,5-二-α-异丙苯基-2-羟基苯基)-2H-苯并***、2-(3-叔丁基-2-羟基-5-(2-(ω-羟基-八-(亚乙基氧)羰基-乙基)-苯基)-2H-苯并***、2-(3-十二烷基-2-羟基-5-甲基苯基)-2H-苯并***、2-(3-叔丁基-2-羟基-5-(2-辛氧基羰基)乙基苯基)-2H-苯并***、十二烷基化2-(2-羟基-5-甲基苯基)-2H-苯并***、2-(3-叔丁基-2-羟基-5-(2-辛氧基羰基乙基)苯基)-5-氯-2H-苯并***、2-(3-叔丁基-5-(2-(2-乙基己氧基)-羰基乙基)-2-羟基苯基)-5-氯-2H-苯并***、2-(3-叔丁基-2-羟基-5-(2-甲氧基羰基乙基)苯基)-5-氯-2H-苯并***、2-(3-叔丁基-2-羟基-5-(2-甲氧基羰基乙基)苯基)-2H-苯并***、2-(3-叔丁基-5-(2-(2-乙基己氧基)羰基乙基)-2-羟基苯基)-2H-苯并***、2-(3-叔丁基-2-羟基-5-(2-异辛氧基羰基乙基)苯基-2H-苯并***、2,2’-亚甲基-双(4-叔辛基(6-2H-苯并***-2-基)苯酚)、2-(2-羟基-3-α-异丙苯基-5-叔辛基苯基)-2H-苯并***、2-(2-羟基-3-叔辛基-5-α-异丙苯基苯基)-2H-苯并***、5-氟-2-(2-羟基-3,5-二-α-异丙苯基-苯基)-2H-苯并***、5-氯-2-(2-羟基-3,5-二-α-异丙苯基苯基)-2H-苯并***、5-氯-2-(2-羟基-3-α-异丙苯基-5-叔辛基苯基)-2H-苯并***、2-(3-叔丁基-2-羟基-5-(2-异辛氧基羰基乙基)苯基)-5-氯-2H-苯并***、5-三氟甲基-2-(2-羟基-3-α-异丙苯基-5-叔辛基苯基)-2H-苯并***、5-三氟甲基-2-(2-羟基-5-叔辛基苯基)-2H-苯并***,5-三氟甲基-2-(2-羟基-3,5-二叔辛基苯基)-2H-苯并***、3-(5-三氟甲基-2H-苯并***-2-基)-5-叔丁基-4-羟基氢化肉桂酸甲酯、5-丁基磺酰基-2-(2-羟基-3-α-异丙苯基-5-叔辛基苯基)-2H-苯并***、5-三氟甲基-2-(2-羟基-3-α-异丙苯基-5-叔丁基苯基)-2H-苯并***、5-三氟甲基-2-(2-羟基-3,5-二叔丁基苯基)-2H-苯并***、5-三氟甲基-2-(2-羟基-3,5-二-α-异丙苯基苯基)-2H-苯并***、5-丁基磺酰基-2-(2-羟基-3,5-二叔丁基苯基)-2H-苯并***和5-苯磺酰基-2-(2-羟基-3,5-二叔丁基苯基)-2H-苯并***。
2.2.2-羟基二苯甲酮,例如4-羟基、4-甲氧基、4-辛氧基、4-癸氧基、4-十二烷氧基、4-苄氧基、4,2′,4’-三羟基和2’-羟基-4,4’-二甲氧基衍生物。
2.3.取代和未取代的苯甲酸的酯,例如4-叔丁基苯基水杨酸酯、苯基水杨酸酯、辛基苯基水杨酸酯、二苯甲酰基间苯二酚、二(4-叔丁基苯甲酰基)间苯二酚、苯甲酰基间苯二酚、2,4-二叔丁基苯基3,5-二叔丁基-4羟基苯甲酸酸酯、十六烷基3,5-二叔丁基-4-羟基苯甲酸酸酯、十八烷基3,5-二叔丁基-4-羟基苯甲酸酸酯、2-甲基-4,6-二叔丁基苯基3,5-二叔丁基-4-羟基苯甲酸酸酯。
2.4.丙烯酸酯和丙二酸酯,例如α-氰基-β,β-二苯基丙烯酸乙酯或异辛酯、α-甲酯基-肉桂酸甲酯、α-氰基-β-甲基对甲氧基肉桂酸甲酯或丁酯、α-甲酯基-对甲氧基肉桂酸甲酯、N-(β-甲酯基-β-氰基乙烯基)-2-甲基二氢吲哚、PR25、二甲基对甲氧基苯亚甲基丙二酸酯(CAS#7443-25-6)、以及PR31、二(1,2,2,6,6-五甲基哌啶-4-基)对甲氧基苯亚甲基丙二酸酯(CAS#147783-69-5)。
2.5.镍化合物,例如2,2’-硫-二[4-(1,1,3,3-四甲基丁基)苯酚]的镍络合物,例如1∶1或1∶2络合物,带有或没有另外的配体,如正丁胺、三乙醇胺或N-环己基二乙醇胺,镍二丁基二硫代氨基甲酸酯,一元烷基酯的镍盐,例如4-羟基-3,5-二叔丁基苯甲基磷酸的甲基或乙基酯,酮肟的镍络合物,例如2-羟基-4-甲基苯基十一烷基酮肟,1-苯基-4-月桂酰基-5-羟基吡唑的镍络合物,带或不带另外的配体。
2.6.空间位阻胺稳定剂,例如4-羟基-2,2,6,6-四甲基哌啶、1-烯丙基-4-羟基-2,2,6,6-四甲基哌啶、1-苄基-4-羟基-2,2,6,6-四甲基哌啶、二(2,2,6,6-四甲基-4-哌啶基)癸二酸酯、二(2,2,6,6-四甲基-4-哌啶基)琥珀酸酯、二(1,2,2,6,6-五甲基-4-哌啶基)癸二酸酯、二(1-辛氧基-2,2,6,6-四甲基-4-哌啶基)癸二酸酯、二(1,2,2,6,6-五甲基-4-哌啶基)正丁基-3,5-二叔丁基-4-羟基苄基丙二酸酯、1-(2-羟乙基)-2,2,6,6-四甲基-4-羟基哌啶和琥珀酸的缩合物(condensate)、N,N’-二(2,2,6,6-四甲基-4-哌啶基)己二胺和4-叔辛基氨基-2,6-二氯-1,3,5-三嗪的线性或环形缩合物、三(2,2,6,6-四甲基-4-哌啶基)次氮基三乙酸酯、四(2,2,6,6-四甲基-4-哌啶基)-1,2,3,4-丁烷四甲酸酯、1,1’-(1,2-乙二基)-二(3,3,5,5-四甲基哌嗪酮)、4-苯甲酰基-2,2,6,6-四甲基哌啶、4-十八烷氧基-2,2,6,6-四甲基哌啶、二(1,2,2,6,6-五甲基哌啶基)-2-正丁基-2(2-羟基-3,5-二叔丁基苄基)丙二酸酯、3-正辛基-7,7,9,9-四甲基-1,3,8-三氮杂螺[4.5]癸-2,4-二酮、二(1-辛氧基-2,2,6,6-四甲基哌啶基)癸二酸酯、二(1-辛氧基-2,2,6,6-四甲基哌啶基)琥珀酸酯、N,N’-二(2,2,6,6-四甲基-4-哌啶基)己二胺和4-吗啉代-2,6-二氯-1,3,5-三嗪的线性或环形缩合物、2-氯-4,6-二(4-正丁基氨基-2,2,6,6-四甲基哌啶基)-1,3,5-三嗪和1,2-二(3-氨基丙基氨基)乙烷的缩合物、2-氯-4,6-二(4-正丁基氨基-1,2,2,6,6-五甲基哌啶基)-1,3,5-三嗪和1,2-二-(3-氨基丙基氨基)乙烷的缩合物、8-乙酰基-3-十二烷基-7,7,9,9-四甲基-1,3,8-三氮杂螺[4.5]癸-2,4二酮、3-十二烷基-1-(2,2,6,6-四甲基-4-哌啶基)吡咯烷-2,5-二酮、3-十二烷基-1-(1,2,2,6,6-五甲基-4-哌啶基)吡咯烷-2,5-二酮、4-十六烷氧基和4-十八烷氧基-2,2,6,6-四甲基哌啶的混合物、N,N’-二(2,2,6,6-四甲基-4-哌啶基)己二胺和4-环己基氨基-2,6-二氯-1,3,5-三嗪的缩合产物、1,2-二(3-氨基丙基氨基)乙烷和2,4,6-三氯-1,3,5-三嗪以及4-丁基氨基-2,2,6,6-四甲基哌啶的缩合产物(CAS注册号[136504-96-6]);N-(2,2,6,6-四甲基-4-哌啶基)正十二烷基琥珀酰亚胺、N-(1,2,2,6,6-五甲基-4-哌啶基)正十二烷基琥珀酰亚胺、2-十一烷基-7,7,9,9-四甲基-1-氧杂-3,8-二氮杂-4-氧代螺[4,5]癸烷、7,7,9,9-四甲基-2-环十一烷基-1-氧杂-3,8-二氮杂-4-氧代螺[4,5]癸烷和环氧氯丙烷的反应产物、1,1-二(1,2,2,6,6-五甲基-4-哌啶氧基羰基)-2-(4-甲氧基苯基)乙烯、N,N’-二甲酰基-N,N’-二(2,2,6,6-四甲基-4-哌啶基)己二胺、4-甲氧基-亚甲基-丙二酸与1,2,2,6,6-五甲基-4-羟基哌啶的二酯、聚[甲基丙基-3-氧-4-(2,2,6,6-四甲基-4-哌啶基)]硅氧烷、马来酸酐-α-烯烃共聚物与2,2,6,6-四甲基-4-氨基哌啶或1,2,2,6,6-五甲基-4-氨基哌啶的反应产物。
空间位阻胺也可以是美国专利5,980,783中描述的化合物中的一种,也就是组分1-a)、1-b)、1-c)、1-d)、1-e)、1-f)、1-g)、1-h)、1-i)、1-j)、1-k)或1-l)的化合物,特别是列在所述美国专利5,980,783的64-72栏中的光稳定剂1-a-1、1-a-2、1-b-1、1-c-1、1-c-2、1-d-1、1-d-2、1-d-3、1-e-1、1-f-1、1-g-1、1-g-2或1-k-1。
空间位阻胺也可以是美国专利6,046,304和6,297,299中描述的化合物中的一种,例如如其中的权利要求10或38或实施例1-12或D-1至D-5中描述的化合物。
2.7.氮原子被羟基取代的烷氧基所取代的空间位阻胺,例如诸如下列的化合物:1-(2-羟基-2-甲基丙氧基)-4-十八烷酰氧基-2,2,6,6-四甲基哌啶、1-(2-羟基-2-甲基丙氧基)-4-十六烷酰氧基-2,2,6,6-四甲基哌啶、1-氧基-4-羟基-2,2,6,6-四甲基哌啶与叔戊醇的碳自由基的反应产物、1-(2-羟基-2-甲基丙氧基)-4-羟基-2,2,6,6-四甲基哌啶、1-(2-羟基-2-甲基丙氧基)-4-氧代-2,2,6,6-四甲基哌啶、二(1-(2-羟基-2-甲基丙氧基)-2,2,6,6-四甲基哌啶-4-基)癸二酸酯、二(1-(2-羟基-2-甲基丙氧基)-2,2,6,6-四甲基哌啶-4-基)己二酸酯、二(1-(2-羟基-2-甲基丙氧基)-2,2,6,6-四甲基哌啶-4-基)琥珀酸酯、二(1-(2-羟基-2-甲基丙氧基)-2,2,6,6-四甲基哌啶-4-基)戊二酸酯和2,4-二{N-[1-(2-羟基-2-甲基丙氧基)-2,2,6,6-四甲基哌啶-4-基]-N-丁基氨基}-6-(2-羟基乙基氨基)-s-三嗪。
2.8.草酰胺,例如4,4’-二辛氧基草酰替苯胺、2,2’-二乙氧基草酰替苯胺、2,2’-二辛氧基-5,5’-二叔丁氧基草酰替苯胺(di-tert-butoxanilide)、2,2’-双十二烷氧基-5,5’-二叔丁氧基草酰替苯胺、2-乙氧基-2’-乙氧基草酰替苯胺、N,N’-二(3-二甲基氨基丙基)草酰胺、2-乙氧基-5-叔丁基-2’-乙氧基草酰替苯胺及其与2-乙氧基-2’-乙基-5,4’-二叔丁氧基草酰替苯胺的混合物、邻和对-甲氧基-双取代的草酰替苯胺的混合物以及邻和对-乙氧基-双取代的草酰替苯胺的混合物。
2.9.三芳基邻羟基苯-s-三嗪,例如已知的商业化的三芳基邻羟苯基-s-三嗪和三嗪,如在下列专利中公开的:WO 96/28431、EP 434608、EP 941989、GB2,317,893、美国专利号3,843,371;4,619,956;4,740,542;5,096,489;5,106,891;5,298,067;5,300,414;5,354,794;5,461,151;5,476,937;5,489,503;5,543,518;5,556,973;5,597,854;5,681,955;5,726,309;5,942,626;5,959,008;5,998,116和6,013,704,例如4,6-二(2,4-二甲基苯基)-2-(2-羟基-4-辛氧基苯基)-s-三嗪、CytecCorp的1164、4,6-二(2,4-二甲基苯基)-2-(2,4-二羟苯基)-s-三嗪、2,4-双(2,4-二羟基苯基)-6-(4-氯苯基)-s-三嗪、2,4-二[2-羟基-4-(2-羟基乙氧基)苯基]-6-(4-氯苯基)-s-三嗪、2,4-二[2-羟基-4-(2-羟基-4-(2-羟基乙氧基)苯基)-6-(2,4-二甲基苯基)-s-三嗪、2,4-二[2-羟基-4-(2-羟基乙氧基)苯基]-6-(4-溴苯基)-s-三嗪、2,4-二[2-羟基-4-(2-乙酰氧基乙氧基)苯基]-6-(4-氯苯基)-s-三嗪、2,4-双(2,4-二羟基苯基)-6-(2,4-二甲基苯基)-s-三嗪、2,4-二(4-联苯基)-6-(2-羟基-4-辛氧基羰基亚乙氧基苯基)-s-三嗪、2-苯基-4-[2-羟基-4-(3-仲丁氧基-2-羟基丙氧基)苯基]-6-[2-羟基-4-(3-仲戊氧基-2-羟基丙氧基)苯基]-s-三嗪、2,4-双(2,4-二甲基苯基)-6-[2-羟基-4-(3-苄氧基-2-羟基丙氧基)苯基]-s-三嗪、2,4-二(2-羟基-4-正丁氧基苯基)-6-(2,4-二正丁氧基苯基)-s-三嗪、2,4-双(2,4-二甲基苯基)-6-[2-羟基-4-(3-壬氧基*-2-羟基丙氧基)-5-α-异丙苯基苯基]-s-三嗪(*表示辛氧基、壬氧基和癸氧基的混合物)、亚甲基二-{2,4-双(2,4-二甲基苯基)-6-[2-羟基-4-(3-丁氧基-2-羟基丙氧基)苯基]-s-三嗪}、在3∶5’、5∶5’和3∶3’位置上以5∶4∶1的比例桥连的亚甲基桥连的二聚体混合物、2,4,6-三(2-羟基-4-异辛氧羰基异亚丙氧基苯基)-s-三嗪、2,4-双(2,4-二甲基苯基)-6-(2-羟基-4-己氧基-5-α-异丙苯基苯基)-s-三嗪、2-(2,4,6-三甲基苯基)-4,6-二[2-羟基-4-(3-丁氧基-2-羟基丙氧基)苯基]-s-三嗪、2,4,6-三[2-羟基-4-(3-仲丁氧基-2-羟基丙氧基)苯基]-s-三嗪、4,6-二(2,4-二甲基苯基)-2-(2-羟基-4-(3-十二烷氧基-2-羟基丙氧基)苯基)-s-三嗪和4,6-二(2,4-二甲基苯基)-2-(2-羟基-4-(3-十三烷氧基-2-羟基丙氧基)苯基)-s-三嗪的混合物、Ciba Specialty Chemicals Corp.的400、4,6-二(2,4-二甲基苯基)-2-(2-羟基-4-(3-(2-乙基己氧基)-2-羟基丙氧基)-苯基)-s-三嗪和4,6-二苯基-2-(4-己氧基-2-羟基苯基)-s-三嗪。
3.金属减活化剂,例如N,N’-二苯基草酰胺、N-水杨醛-N’-水杨酰肼、N,N’-二(水杨酰)肼、N,N’-双(3,5-二叔丁基-4-羟基苯基丙酰)肼、3-水杨酰氨基-1,2,4-***、二(苯亚甲基)草酰二酰肼、草酰替苯胺、间苯二酰二酰肼、癸二酰二苯基酰肼、N,N’-二乙酰己二酰二酰肼、N,N’-二(水杨酰)草酰二酰肼、N,N’-二(水杨酰)硫代丙酰二酰肼。
4.亚磷酸酯和亚膦酸酯,例如亚磷酸三苯酯、二苯基烷基亚磷酸酯、苯基二烷基亚磷酸酯、三(壬基苯基)亚磷酸酯、三月桂基亚磷酸酯、三-十八烷基亚磷酸酯、二硬脂基季戊四醇二亚磷酸酯、三(2,4-二叔丁基苯基)亚磷酸酯、二异癸基季戊四醇二亚磷酸酯、二(2,4-二叔丁基苯基)季戊四醇二亚磷酸酯、二(2,6-二叔丁基-4-甲基苯基)季戊四醇二亚磷酸酯、二异癸氧基季戊四醇二亚磷酸酯、二(2,4-二叔丁基-6-甲基苯基)季戊四醇二亚磷酸酯、二(2,4,6-三(叔丁基苯基)季戊四醇二亚磷酸酯、三-硬脂基山梨醇三亚磷酸酯、四(2,4-二叔丁基苯基)4,4’-亚联苯基二亚膦酸酯、6-异辛氧基-2,4,8,10-四叔丁基双苯并[d,f][1,3,2]二氧杂磷杂环庚烷(dioxaphosphepin)、6-氟-2,4,8,10-四叔丁基-12-甲基-双苯并[d,g][1,3,2]二氧杂磷杂环辛烷(dioxaphosphocin)、二(2,4-二叔丁基-6-甲基苯基)甲基亚磷酸酯、二(2,4-二叔丁基-6-甲基苯基)乙基亚磷酸酯、2,2’,2”-次氮基[三乙基三(3,3’,5,5’-四叔丁基-1,1’-联苯-2,2’-二基)亚磷酸酯]、2-乙基己基(3,3’,5,5’-四叔丁基-1,1’-联苯-2,2’-二基)亚磷酸酯。
特别优选的是下面的亚磷酸酯:
5.羟基胺,例如N,N-二苄基羟基胺、N,N-二乙基羟基胺、N,N-二辛基羟基胺、N,N-二月桂基羟基胺、N,N-二-十四烷基羟基胺、N,N-二-十六烷基羟基胺、N,N-二-十八烷基羟基胺、N-十六烷基-N-十八烷基羟基胺、N-十七烷基-N-十八烷基羟基胺、N-甲基-N-十八烷基羟基胺和来自氢化牛脂胺的N,N-二烷基羟基胺。
6.硝酮,例如N-苄基-α-苯基硝酮、N-乙基-α-甲基硝酮、N-辛基-α-庚基硝酮、N-十二烷基-α-十一烷基硝酮、N-十四烷基-α-十三烷基硝酮、N-十六烷基-α-十五烷基硝酮、N-十八烷基-α-十七烷基硝酮、N-十六烷基-α-十七烷基硝酮、N-十八烷基-α-十五烷基硝酮、N-十七烷基-α-十七烷基硝酮、N-十八烷基-α-十六烷基硝酮、N-甲基-α-十七烷基硝酮和衍生自来自氢化牛脂胺的N,N-二烷基羟基胺的硝酮。
7.胺氧化物,例如美国专利号5,844,029和5,880,191中公开的胺氧化物的衍生物、二癸基甲基胺氧化物、十三烷基胺氧化物、三月桂胺氧化物和三-十六烷基胺氧化物。
8.苯并呋喃酮和吲哚酮,例如那些在美国专利4,325,863、4,338,244、5,175,312、5,216,052、5,252,643;DE-A-4316611;DE-A-4316622;DE-A-4316876;EP-A-0589839或EP-A-0591102中公开的那些,或3-[4-(2-乙酰氧基乙氧基)苯基]-5,7-二叔丁基苯并呋喃-2-酮、5,7-二叔丁基-3-[4-(2-十八酰氧基乙氧基)苯基]苯并呋喃-2-酮、3,3’-二[5,7-二叔丁基-3-(4-[2-羟基乙氧基]苯基)苯并呋喃-2-酮]、5,7-二叔丁基-3-(4-乙氧苯基)苯并呋喃-2-酮、3-(4-乙酰氧基-3,5-二甲基苯基)-5,7-二叔丁基苯并呋喃-2-酮、3-(3,5-二甲基-4-新戊酰氧基苯基)-5,7-二叔丁基苯并呋喃-2-酮、3-(3,4-二甲基苯基)-5,7-二叔丁基苯并呋喃-2-酮、3-(2-乙酰基-5-异辛基苯基)-5-异辛基苯并呋喃-2-酮以及3-(2,3-二甲基苯基)-5,7-二叔丁基苯并呋喃-2-酮。
9.硫代协合剂,例如二月桂基硫代二丙酸酯或双十八烷基硫代二丙酸酯。
10.过氧化物清除剂,例如β-硫代二丙酸的酯,例如月桂基、十八烷基、十四烷基或十三烷基酯、巯基苯并咪唑或2-巯基-苯并咪唑的锌盐、二丁基双硫代氨基甲酸锌、双十八烷基二硫化物、季戊四醇四(β-十二烷基巯基)丙酸酯。
11.聚酰胺稳定剂,例如与碘化物和/或磷化合物结合的铜盐和二价锰盐。
12.碱性共稳定剂,例如三聚氰胺、聚乙烯吡咯烷酮、双氰胺、三烯丙基氰脲酸酯、脲衍生物、肼衍生物、胺、聚酰胺、聚氨酯、高级脂肪酸的碱金属盐和碱土金属盐,例如硬脂酸钙、硬脂酸锌、山嵛酸镁、硬脂酸镁、蓖麻醇酸钠和棕榈酸钾、焦儿茶酸锑或焦儿茶酸锌。
13.成核剂,例如无机物质,如滑石粉,金属氧化物,如二氧化钛或氧化镁,优选碱土金属的磷酸盐、碳酸盐或硫酸盐;有机化合物,如一元或多元羧酸以及它们的盐,如4-叔丁基苯甲酸、己二酸、二苯基乙酸、琥珀酸钠或苯甲酸钠;聚合化合物,如离子共聚物(离聚物)。
14.填料和增强剂,例如碳酸钙、硅酸盐、玻璃纤维、玻璃球(glass bulbs)、石棉、滑石、高岭土、云母、硫酸钡、金属氧化物和氢氧化物、炭黑、石墨、木粉和面粉或其它天然产品的纤维、合成纤维。
15.分散剂,例如聚氧化乙烯蜡或矿物油。
16.其他添加剂,例如增塑剂、润滑剂、乳化剂、颜料、染料、荧光增白剂、流变添加剂、催化剂、流量控制剂、防滑剂、交联剂、交联促进剂、卤素清除剂、烟雾抑制剂、阻燃剂、抗静电剂、澄清剂如取代和未取代的二苯亚甲基山梨糖醇、苯并噁嗪酮紫外线吸收剂如2,2’-对亚苯基二(3,1-苯并噁嗪-4-酮)、3638(CAS#18600-59-4)和起泡剂。
由本发明的纤维或长丝生产的可湿性织物特别适用于例如生产卫生制品的皮肤接触内衬织物,特别是一次性尿布、训练裤、妇女卫生产品或失禁护理产品。该织物也适用于制造诸如湿和干抹布、伤口敷料、手术斗篷、过滤介质(filtermedial)、电池隔膜等的制品。
例如在美国专利5,149,576;5,961,504;6,031,147和6,110,849中描述了尿布结构。
此外,通常希望赋予熔融挤出的聚烯烃薄膜润湿性。这样的薄膜,以多孔的形式,广泛用作卫生制品的保护层(cover sheets)。
用于卫生制品的面层材料(coverstock),再湿润(wetback)性能的改善可以通过使用两层或多层织物粘结在一起来提高。实例包括两个纺粘层或SMS织物,其中熔喷层没有现有的添加剂。
除了织物,根据本发明也为聚酯薄膜、板材、片材和模型制品提供了极好的润湿性。
所以也公开了由可湿性织物制备选自一次性尿布、训练裤、妇女卫生产品、失禁护理产品、湿或干抹布、伤口敷料、手术斗篷、过滤介质和电池隔膜的制品。
因此,本发明的另外目的是一种可湿性聚酯薄膜、板材、片材或模型制品,该薄膜、板材、片材或模型制品包括熔融共混物,其包括聚酯和一种或多种组分a)、b)、c)、d)和e)的化合物。
另外预期金属M的列表可以扩大,从而包括其它磺酸盐金属盐在内。例如,金属M可以选自Li、Na、K、Cs、Be、Ca、Mg、Sr、Ba、Al、Sb、Cd、Mn、Fe、Co、Ni、Cu和Zn。在每一种情况下,组分a)、b)、c)、d)和e)的化合物都是电中性的。
例如以下e)的络合物包括:
下面的实施例进一步举例说明本发明。除另另外注明,数量以重量百分比报告。
实施例1:制备4-苄氧基-丁烷-1-磺酸钠。
在2升圆底烧瓶中,加入26.63g的氢化钠(60%)和600ml的干二甲基甲酰胺并搅拌。将60.00g苯甲醇添加到反应混合物中,在氮气气氛、室温下搅拌1小时。反应混合物进一步搅拌0.5小时。此后,将90.55g的1,4-丁烷磺内酯缓慢添加到反应混合物中搅拌2小时。然后反应混合物搅拌过夜。在反应结束时,将反应物料倒入2.5升的2-丙醇中并剧烈搅拌。过滤产品,用500ml的2-丙醇和500ml的己烷洗涤。然后产品通过用甲醇重结晶来纯化并真空干燥。产率为45%。
实施例2:制备4-苯乙氧基-丁烷-1-磺酸钠。
在1升3颈圆底烧瓶中,提供400ml的干二甲基甲酰胺并加入13.10g氢化钠(60%)。这种混合物在氮气气氛、室温下搅拌0.5小时。40g 2-苯基乙醇的60ml干二甲基甲酰胺溶液在2小时内、室温下滴加到搅拌的反应混合物中。然后,44.58g 1,4-丁烷磺内酯的60ml干二甲基甲酰胺溶液在3个小时内逐滴加入到搅拌的反应混合物中。在室温下,反应混合物保持搅拌过夜。在反应结束时,真空下蒸发溶剂并用1.5升2-丙醇处理残余物,搅拌15分钟并过滤。再次用2-丙醇处理湿饼以除去未反应的原料。真空下干燥湿饼以生产灰白色(off-white)的固体,用核磁共振(NMR)表征。核磁共振显示存在9.65%的烯丙基杂质。
为了消除烯丙基杂质,将36.70g的化合物溶解在150ml的蒸馏水中,并且该溶液保持在50℃加热搅拌。将1.36g亚硫酸氢钠和10mg的过硫酸钾加入该溶液中,在50℃连续搅拌过夜。真空除去溶剂并在真空下干燥固体,通过红外光谱(IR)和核磁共振(NMR)表征。NMR谱表明,亚硫酸氢钠处理后烯丙基杂质减少到3.06%。产率为42.9%。
实施例3:制备4-(3-苯基-丙氧基)-丁烷-1-磺酸钠。
在1升3颈圆底烧瓶中,放入300ml的干二甲基甲酰胺和10.14g氢化钠(60%),并在氮气气氛、室温下搅拌0.5小时。将40.00g 3-苯基丙醇在0.5小时内、室温下随搅拌逐滴加入到反应混合物中。反应混合物再持续搅拌另外0.5小时。此后,将44.58g 1,4-丁烷磺内酯在0.75小时内边搅拌边逐滴地加入到反应混合物中。反应混合物在室温下保持搅拌3小时。在反应结束时,真空下蒸发溶剂并用3.5升2-丙醇处理残余物,搅拌20分钟并过滤。再次用2-丙醇处理湿饼以除去未反应的原料。真空下干燥湿饼以生产灰白色(off-white)的固体,用核磁共振表征。核磁共振显示存在15%的烯丙基杂质。
为了消除烯丙基杂质,将30.20g化合物溶解在150ml的蒸馏水中,并且该溶液保持在50℃加热搅拌。将1.76g亚硫酸氢钠和50mg的过硫酸钾加入到该溶液中,并连续搅拌过夜。真空下除去溶剂并在真空下干燥固体,通过红外光谱(IR)和核磁共振(NMR)表征。NMR谱表明亚硫酸氢钠处理后烯丙基杂质减少到3.10%。产率为64.6%。
实施例4:制备4-(4-苯基丁氧基)-丁烷-1-磺酸钠。
在1升3颈圆底烧瓶中,放入500ml的干二甲基甲酰胺和14.53g氢化钠(60%),并在氮气气氛下搅拌0.5小时。54.60g 4-苯基-1-丁醇的100ml干二甲基甲酰胺溶液在2小时内、室温下随搅拌逐滴加入到反应混合物中。之后,49.49g 1,4-丁烷磺内酯的100ml干二甲基甲酰胺溶液在3小时内边搅拌边逐滴地加入到反应混合物中。反应混合物保持搅拌过夜。然后真空下蒸发溶剂并用2.0升2-丙醇处理残余物,搅拌15分钟并过滤。再次用2-丙醇处理湿饼以除去未反应的原料。在真空下干燥湿饼以生产灰白色(off-white)的固体,用核磁共振表征。核磁共振显示存在18.70%的烯丙基杂质和一些1,4-二磺酸化丁烷杂质。
为了去除烯丙基杂质,将89.30g化合物溶解在250ml的蒸馏水中,并且该溶液保持在50℃加热搅拌。将7.72g亚硫酸氢钠和50mg的过硫酸钾加入到该溶液中,并连续搅拌过夜。真空下除去溶剂并在真空下干燥固体,通过红外光谱(IR)和核磁共振(NMR)表征。NMR谱表明烯丙基杂质减少到2.00%。还发现在该产物中存在其它杂质。该1,4-二磺酸化丁烷杂质通过将91.00g上述化合物溶解在过量的甲醇中,然后在上述溶液中慢慢加入1,2-二氯乙烷直到溶液变得混浊来除去。过滤溶液并真空下浓缩滤出液以回收所需的产品。真空下干燥固体并用核磁共振表征。产率为79.6%。
实施例5:制备带有丁氧基磺酸钠端基的聚乙二醇甲醚(Mn=550)。
在1升3颈圆底烧瓶中,放入400ml的干二甲基甲酰胺和3.64g氢化钠(60%),并在氮气气氛、室温下搅拌0.5小时。50.00g聚乙二醇甲醚(Mn=550)的100ml干二甲基甲酰胺溶液在2小时内、室温下随搅拌逐滴加入到上述溶液中。之后,12.38g 1,4-丁烷磺内酯的50ml干二甲基甲酰胺溶液在3小时内随搅拌逐滴地加入到反应混合物中。反应混合物在室温下保持搅拌过夜。之后,真空下蒸发溶剂并用2.0升乙酸乙酯溶解残余物。此后,慢慢加入正己烷直至产物从溶液中沉淀出来。然后,过滤产品并在真空下干燥得到浅黄的半固体,用核磁共振表征。核磁共振显示存在10.00%的烯丙基杂质。
为了除去烯丙基杂质,将37.40g化合物溶解在150ml的蒸馏水中,并且该溶液保持在50℃加热搅拌。将0.55g的亚硫酸氢钠和10mg的过硫酸钾加入到该溶液并连续搅拌过夜。真空下除去溶剂并在真空下干燥固体,通过红外光谱(IR)和核磁共振(NMR)表征。NMR谱显示亚硫酸氢钠处理后烯丙基杂质减少到3.50%。产率为58.1%。
实施例6:由1-辛醇和1,4-丁烷砜制备磺酸盐。
在1升3颈圆底烧瓶中,放入300ml的干二甲基甲酰按和7.68g氢化钠(60%),并在氮气气氛、室温下搅拌0.5小时。将25.00g 1-辛醇的50ml干二甲基甲酰胺溶液在2小时内、室温下随搅拌逐滴加入到上述溶液中。之后,将23.53g 1,4-丁烷磺内酯的50ml干二甲基甲酰胺溶液在3小时内随搅拌逐滴地加入到反应混合物中。反应混合物在室温下保持搅拌过夜。之后,真空下蒸发溶剂并用1.5升2-丙醇处理残余物。过滤产物并在真空下干燥得到白色固体,用核磁共振表征。核磁共振显示存在13.36%的烯丙基杂质。为了除去烯丙基杂质,将43.3g化合物溶解在150ml的蒸馏水中,并且该溶液在50℃保持加热搅拌。将2.19g的亚硫酸氢钠和20mg的过硫酸钾加入到该溶液中并连续搅拌过夜。真空下除去溶剂并在真空下干燥固体,通过红外光谱(IR)和核磁共振(NMR)表征。NMR谱显示亚硫酸氢钠处理后烯丙基杂质减少到2.48%。产率为75.2%。
实施例7:制备十八烷-1,2-二磺酸二钠盐。
在1升单颈圆底烧瓶中,装入25g的十八-1-烯、25.8g的亚硫酸氢钠和0.25g的2,6-二叔丁基-4-甲基-苯酚。将250ml的2-丙醇和250ml的蒸馏水加入到该混合物中,将反应混合物搅拌加热到50℃。此后,向该反应混合物中加入1.5ml的过苯甲酸叔丁酯,并保持在50℃搅拌24小时。真空下除去溶剂,化合物在60℃真空下干燥12小时。该产物(十八烷-1,2-二磺酸二钠盐)最后通过柱色谱纯化。产率为25.26%。
实施例8:制备磺烷基化的乙氧基化醇。
在5升3颈圆底烧瓶中,放入500ml的干二甲基甲酰胺和42.3g氢化钠(60%),并在氮气气氛、室温下搅拌0.5小时。350.00g乙氧基化醇(ImbentinAG/200/025)的2000ml干二甲基甲酰胺溶液在1小时内、50℃随搅拌逐滴加入到上述溶液中,该溶液保持在50℃另搅拌3小时。然后将121.72g 1,4-丁烷磺内酯的500ml干二甲基甲酰胺溶液在3小时内边搅拌边逐滴添加到反应混合物中。反应混合物在50℃保持搅拌过夜。之后,真空下蒸发溶剂并用4升2-丙醇处理残余物并过滤。残余物进一步用2升2-丙醇洗涤。之后,真空下干燥产品以得到白色粉体,用核磁共振表征。产率为65.86%。
实施例9:润湿性测量。
在双螺杆挤出机中混合之前,将添加剂化合物与商业纤维级(约0.65iv)PET树脂干混,总批量为1000g。作为可选的方案,制备浓缩物并以适当的比例与PET树脂共混以获取目标浓度。浓度是添加剂占PET重量的重量百分比。共混的树脂被结晶、干燥、并在氩气吹扫下在具有6”模头的研究规模的熔喷线上生产非织造织物。熔体和空气温度设定为约305℃。当PET在没有添加剂下运行时,调整气流以不形成飞毛(fly)。非织造网的目标单位重量为80gsm。
下表包括亲水性添加剂是合成实施例1-6之一的结果。测量的是0.9%氯化钠/水溶液通过样品织物花费的时间(液体撞击通过时间,EDANA 150.5-02)。大于50秒的时间被认为是不可行的,10至50秒被认为是适度有效的,小于10秒钟被认为是高度有效的。
Claims (13)
2.根据权利要求1的聚酯纤维或长丝,包括一种或多种组分a)的苯基烷基-氧-烷基金属磺酸盐。
3.根据权利要求1的聚酯纤维或长丝,包括一种或多种组分b)的烷基-氧-烷基金属磺酸盐。
4.根据权利要求1的聚酯纤维或长丝,包括一种或多种组分c)的聚亚乙基-氧-烷基金属磺酸盐。
5.根据权利要求1的聚酯纤维或长丝,包括一种或多种组分d)的烷基-聚亚乙基氧-烷基金属磺酸盐。
6.根据权利要求1的聚酯纤维或长丝,包括一种或多种组分e)的烷基-1,2-二磺酸金属磺酸盐。
7.根据权利要求1的聚酯纤维或长丝,其中聚酯是聚(对苯二甲酸乙二醇酯)、聚(2,6-萘-2,6-二甲酸乙二醇酯)或聚(乳酸)。
8.根据权利要求1的聚酯纤维或长丝,其中聚酯是聚(对苯二甲酸乙二醇酯)。
9.根据权利要求1的聚酯纤维或长丝,其中化合物a)、b)、c)、d)和e)以0.05%到5.0%重量存在,基于聚酯的重量。
10.由权利要求1的聚酯纤维或长丝制造的可湿性针织、机织或非织造织物。
11.一种制品,其由根据权利要求10的可湿性织物生产制备,该制品选自一次性尿布、训练裤、女性卫生产品、失禁护理产品、湿或干抹布、创伤敷料、手术斗篷、过滤介质和电池隔膜。
12.一种赋予聚酯纤维或长丝可润湿性的方法,该方法包括熔融挤出含有聚酯和一种或多种选自根据权利要求1的a)、b)、c)、d)和e)的化合物的混合物,形成多根纤维或长丝并冷却纤维或长丝。
13.根据权利要求12的方法,其包括制备母料,该母料包括a)、b)、c)、d)和e)中的一种或多种化合物和第一聚合物,熔融挤出包括所述母料和聚酯的混合物,形成多根纤维或长丝并冷却纤维或长丝。
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