CN101560656B - 一种无铅印制电路板铜面保护剂及其制备方法 - Google Patents
一种无铅印制电路板铜面保护剂及其制备方法 Download PDFInfo
- Publication number
- CN101560656B CN101560656B CN2009101313110A CN200910131311A CN101560656B CN 101560656 B CN101560656 B CN 101560656B CN 2009101313110 A CN2009101313110 A CN 2009101313110A CN 200910131311 A CN200910131311 A CN 200910131311A CN 101560656 B CN101560656 B CN 101560656B
- Authority
- CN
- China
- Prior art keywords
- protecting agent
- printed circuit
- circuit board
- copper surface
- lead
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000010949 copper Substances 0.000 title claims abstract description 40
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 39
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 39
- 239000003223 protective agent Substances 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 230000001681 protective effect Effects 0.000 claims abstract description 36
- 239000000463 material Substances 0.000 claims abstract description 29
- -1 imidazoles compound Chemical class 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000008367 deionised water Substances 0.000 claims abstract description 17
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 17
- 150000007524 organic acids Chemical class 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 claims abstract description 6
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims description 22
- 239000002994 raw material Substances 0.000 claims description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 10
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 claims description 10
- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 150000002170 ethers Chemical class 0.000 claims description 7
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical group Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 6
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 6
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 claims description 6
- YMHOBZXQZVXHBM-UHFFFAOYSA-N 2,5-dimethoxy-4-bromophenethylamine Chemical compound COC1=CC(CCN)=C(OC)C=C1Br YMHOBZXQZVXHBM-UHFFFAOYSA-N 0.000 claims description 5
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 claims description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 5
- 241000545067 Venus Species 0.000 claims description 5
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- 239000013078 crystal Substances 0.000 claims description 5
- 235000019253 formic acid Nutrition 0.000 claims description 5
- 235000019260 propionic acid Nutrition 0.000 claims description 5
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 5
- 239000004246 zinc acetate Substances 0.000 claims description 5
- 125000003785 benzimidazolyl group Chemical group N1=C(NC2=C1C=CC=C2)* 0.000 claims description 4
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 3
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 3
- 229960003280 cupric chloride Drugs 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- 239000011592 zinc chloride Substances 0.000 claims description 3
- 235000005074 zinc chloride Nutrition 0.000 claims description 3
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 3
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 3
- 229960001763 zinc sulfate Drugs 0.000 claims description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 2
- 238000007598 dipping method Methods 0.000 abstract description 14
- 238000005516 engineering process Methods 0.000 abstract description 14
- 230000003064 anti-oxidating effect Effects 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002736 nonionic surfactant Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 230000035939 shock Effects 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 14
- 238000005476 soldering Methods 0.000 description 13
- 238000000034 method Methods 0.000 description 11
- 230000004907 flux Effects 0.000 description 10
- 230000008569 process Effects 0.000 description 10
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 5
- 239000012528 membrane Substances 0.000 description 5
- 238000007747 plating Methods 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 229910000679 solder Inorganic materials 0.000 description 4
- 238000003466 welding Methods 0.000 description 4
- 239000010410 layer Substances 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 229910001128 Sn alloy Inorganic materials 0.000 description 1
- 229910007637 SnAg Inorganic materials 0.000 description 1
- 229910008433 SnCU Inorganic materials 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- UWKMXQVGHDYFTN-UHFFFAOYSA-N copper imidazol-3-ide Chemical compound [Cu++].c1c[n-]cn1.c1c[n-]cn1 UWKMXQVGHDYFTN-UHFFFAOYSA-N 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000009713 electroplating Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Images
Landscapes
- Electric Connection Of Electric Components To Printed Circuits (AREA)
- Non-Metallic Protective Coatings For Printed Circuits (AREA)
Abstract
Description
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2009101313110A CN101560656B (zh) | 2009-04-14 | 2009-04-14 | 一种无铅印制电路板铜面保护剂及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2009101313110A CN101560656B (zh) | 2009-04-14 | 2009-04-14 | 一种无铅印制电路板铜面保护剂及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101560656A CN101560656A (zh) | 2009-10-21 |
CN101560656B true CN101560656B (zh) | 2011-05-18 |
Family
ID=41219622
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2009101313110A Expired - Fee Related CN101560656B (zh) | 2009-04-14 | 2009-04-14 | 一种无铅印制电路板铜面保护剂及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN101560656B (zh) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102766874A (zh) * | 2012-08-20 | 2012-11-07 | 合肥奥福表面处理科技有限公司 | Osp铜面保护剂 |
CN104525959B (zh) * | 2014-12-25 | 2016-09-07 | 安徽旭晶粉体新材料科技有限公司 | 一种水雾法生产铜粉用的复合抗氧化剂 |
CN104470202B (zh) * | 2014-12-31 | 2017-10-24 | 上海创功通讯技术有限公司 | 用于移动终端的印刷电路板及其焊盘表面处理方法 |
CN105671538A (zh) * | 2016-01-08 | 2016-06-15 | 滁州嘉泰科技有限公司 | 一种无铅印制电路板用复配osp处理剂 |
CN106191831A (zh) * | 2016-08-16 | 2016-12-07 | 安徽天祥空调科技有限公司 | 一种用于空调散热片的成膜剂及其制备方法 |
CN109570825B (zh) * | 2018-11-22 | 2021-07-13 | 东莞市绿志岛金属有限公司 | 一种低温无卤无铅焊锡膏及其制备方法 |
CN110965064B (zh) * | 2019-11-28 | 2022-04-29 | 深圳市贝加电子材料有限公司 | 烷基酰胺苯并咪唑类化合物的应用和有机可焊保护剂及其制备、使用方法和应用 |
CN111472002A (zh) * | 2020-04-30 | 2020-07-31 | 国网河南省电力公司社旗县供电公司 | 一种用于印刷电路板的缓蚀剂 |
CN111636083B (zh) * | 2020-06-05 | 2022-08-12 | 江苏艾森半导体材料股份有限公司 | 一种防止高温回流焊聚锡的保护剂及制备方法和使用方法 |
CN111922553A (zh) * | 2020-08-08 | 2020-11-13 | 深圳市创智成功科技有限公司 | 用于晶圆先进封装领域的铜面保护剂及其制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1422924A (zh) * | 1994-12-12 | 2003-06-11 | 阿尔菲弗赖伊有限公司 | 助粘组合物、多层印刷电路板的制法和转涂的铜表面 |
CN1955341A (zh) * | 2005-10-25 | 2007-05-02 | 李碧洁 | 适用于多次高温无铅焊接的铜面防氧化剂 |
-
2009
- 2009-04-14 CN CN2009101313110A patent/CN101560656B/zh not_active Expired - Fee Related
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1422924A (zh) * | 1994-12-12 | 2003-06-11 | 阿尔菲弗赖伊有限公司 | 助粘组合物、多层印刷电路板的制法和转涂的铜表面 |
CN1955341A (zh) * | 2005-10-25 | 2007-05-02 | 李碧洁 | 适用于多次高温无铅焊接的铜面防氧化剂 |
Also Published As
Publication number | Publication date |
---|---|
CN101560656A (zh) | 2009-10-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101560656B (zh) | 一种无铅印制电路板铜面保护剂及其制备方法 | |
CN104602862B (zh) | 无铅焊料球 | |
EP3062956B1 (en) | Lead-free, silver-free solder alloys | |
CN101717929B (zh) | 一种半光亮无铅化学镀锡液及其使用方法 | |
CN101189362B (zh) | 无电解镀镍液 | |
CN101780607B (zh) | 一种用于电子封装组装钎焊的无铅钎料及其制备方法 | |
CN103132113B (zh) | 一种弱碱性锡基无铅钎料复合镀液及其应用 | |
JP2007203373A (ja) | 無鉛はんだ合金 | |
US6428911B2 (en) | Soldering method and soldered joint | |
CN101705482A (zh) | 一种烷基磺酸化学镀锡液及基于该化学镀锡液的镀锡工艺 | |
CN101234460B (zh) | 水溶性热浸镀锡助焊剂及其制备方法 | |
JP2012241251A (ja) | 銅または銅合金の表面処理剤及びその利用 | |
CN101003111A (zh) | 一种SnZn系无铅钎料用助焊剂及其制备方法 | |
CN102059477B (zh) | 一种适用于无银无铅焊料的无卤素助焊剂 | |
KR102376716B1 (ko) | 납땜 합금, 납땜 분말, 및 납땜 조인트 | |
CN102085604A (zh) | Sn-Ag-Cu-Bi-Cr低银无铅焊料 | |
CN102212805A (zh) | 无氰浸金液及无氰浸金工艺 | |
KR20130111081A (ko) | 무전해 도금을 이용하여 금속표면에 주석이 코팅된 전도성 금속분말을 얻는 제조방법 | |
CN101920406B (zh) | Sn-Ag-Zn-Cr共晶无铅焊料 | |
Hua et al. | Electrochemical migration and rapid whisker growth of Zn and Bi dopings in Sn-3.0 Ag-0.5 Cu solder in 3wt.% NaCl solution | |
CN108788511A (zh) | 一种具有高抗氧化能力的有铅焊料及其制备方法 | |
JPS59500475A (ja) | キレ−ト化金属 | |
CN103978320B (zh) | 一种颗粒添加的低银系无铅焊料 | |
KR20160080014A (ko) | Bi-코팅된 무연 솔더 볼 및 이의 제조방법 | |
CN102198566B (zh) | 铁粉锡基复合焊锡合金球及其覆晶植球的方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C56 | Change in the name or address of the patentee |
Owner name: GUANGDONG ZHONGSHI METALS CO., LTD. Free format text: FORMER NAME: DONGGUAN ZHONGSHI SOLDER CO., LTD. |
|
CP01 | Change in the name or title of a patent holder |
Address after: 523920 longan industrial zone, Humen Town, Guangdong, Dongguan Patentee after: GUANGDONG ZHONGSHI METAL CO.,LTD. Address before: 523920 longan industrial zone, Humen Town, Guangdong, Dongguan Patentee before: Dongguan Zhongshi Solder Manufacturers Co.,Ltd. |
|
DD01 | Delivery of document by public notice |
Addressee: GUANGDONG ZHONGSHI METAL CO.,LTD. Document name: Notification of Passing Examination on Formalities Addressee: GUANGDONG ZHONGSHI METAL CO.,LTD. Document name: Notification of Decision on Request for Restoration of Right |
|
CP02 | Change in the address of a patent holder |
Address after: 523000, No. 2, No. 1, industrial North Road, Songshan hi tech Industrial Development Zone, Guangdong, Dongguan Patentee after: GUANGDONG ZHONGSHI METAL Co.,Ltd. Address before: 523920 longan industrial zone, Humen Town, Guangdong, Dongguan Patentee before: GUANGDONG ZHONGSHI METAL Co.,Ltd. |
|
CP02 | Change in the address of a patent holder | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A copper protective agent for lead-free printed circuit board and its preparation method Effective date of registration: 20200921 Granted publication date: 20110518 Pledgee: China Everbright Bank Limited by Share Ltd. Dongguan branch Pledgor: GUANGDONG ZHONGSHI METAL Co.,Ltd. Registration number: Y2020980006258 |
|
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
DD01 | Delivery of document by public notice |
Addressee: Peng Xiaoyun Document name: Notice of conformity |
|
DD01 | Delivery of document by public notice | ||
CF01 | Termination of patent right due to non-payment of annual fee | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20110518 |