CN101554170A - Chlorantraniliprole and emamectin benzoate insecticidal composition - Google Patents
Chlorantraniliprole and emamectin benzoate insecticidal composition Download PDFInfo
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- CN101554170A CN101554170A CNA2009100225428A CN200910022542A CN101554170A CN 101554170 A CN101554170 A CN 101554170A CN A2009100225428 A CNA2009100225428 A CN A2009100225428A CN 200910022542 A CN200910022542 A CN 200910022542A CN 101554170 A CN101554170 A CN 101554170A
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- rynaxypyr
- active component
- active ingredient
- emamectin benzoate
- chlorantraniliprole
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Abstract
The invention relates to a chlorantraniliprole and emamectin benzoate synergistic insecticidal composition, comprising first active ingredient chlorantraniliprole, second active ingredient emamectin benzoate and diluting agent or carrier which can be acceptable on pesticide, wherein, the weight ratio between the first active ingredient and the second active ingredient is 30:1-1:1. The insecticidal composition can be prepared into suspending agent, water dispersible granules and microemulsion according to the known method in the technical field. The mixed composition has remarkable synergy, so as to improve the control efficiency and expand the control spectrum; the two active ingredients are mixed together, so that the dosage is reduced, the cost is lowered, and the environmental pollution can be alleviated.
Description
Technical field
The present invention relates to a kind of Pesticidal combination, particularly a kind of Synergistic fertilizer Pesticidal combination that contains Rynaxypyr and emamectin-benzoate.
Background technology
Rynaxypyr (Chlorantraniliprole) is first broad spectrum pesticide with novel mebenil yl-benzamide class chemical constitution, and this insecticide has unique chemical structure, the novel mode of action, the biological property and the environmental ecology safety of high-efficiency broad spectrum.Rynaxypyr can effectively be prevented and treated nearly all important lepidoptera pest and other insect of part; larvicidal activity and lasting effect provide outstanding crop protection effect efficiently for they; rice-stem borer, paddy stem borer and rice leaf roller there is special efficacy; all effective to rice thrips, rice silk worm first, rice plant skipper and pink rice borer, the lasting period is more than 20 days.Rynaxypyr has rapid prevention insect feed, efficient activity and the good resistance of rainwater washing against performance of being detained, and has realized the quick-acting of plant protection and good lasting effect.The unique novel mode of action of Rynaxypyr is by activating the ryania acceptor in the insect muscle, cause the internal calcium ion unrestrictedly to discharge, stop contraction of muscle, thereby make insect stop to get food rapidly, muscular paralysis, vigor disappearance, paralysis appear, until thorough death, insect stops harm from getting to eat, and only needs about 7 minutes time.Especially the insect to conventional pesticide generation resistance has special efficacy and natural parasitic wasp, natural enemy and insect pollinator is had good selectivity, toxicity to mammal, fish and birds is extremely low, this makes Rynaxypyr be particularly suitable for the insect comprehensive regulation (IPM), helps the good quality and high output of grain.Rynaxypyr is high because of insecticidal activity, sets up the new mark post of insecticide, but its mu is higher with cost, has limitation in actual applications.Its chemical name is: 3-bromo-N--1-(3-chloropyridine-2-yl)-1-hydrogen-pyridine-5-formamide, and its chemical structural formula is as follows:
Emamectin-benzoate (Emamectin benzoate) is called for short first dimension salt, is a kind of antibiotic insecticide, is that the Avermectin hydroxyl is derived and formed.Have efficient, wide spectrum, a drug can be prevented and treated various pests, and the speed of desinsection is slower, and the lasting period is long.Its mechanism of action is to hinder pest movements nerve information transmission and make the health paralysis, and the mode of action is based on stomach toxicity and tag, and can effectively infiltrate the leaf tissue of target crop, to natural enemies security, easily degraded, noresidue, to the person poultry safety, can with most of combined use of pesticides.The existing many at home enterprises of first dimension salt produce, application area on crop is also increasing year by year, but because of to fishes and shrimps, honeybee toxicity height, the use in places such as water sources is subjected to certain limitation, and nearly 2 years continuous use, the insect of some crops has also produced certain resistance.Its chemical structural formula is as follows:
The synergistic complex of agricultural chemicals is expanding prevention spectrum, raising preventive effect and the effective measures that reduce peasant's drug cost, the inventor furthers investigate the mixture preparation of Rynaxypyr and first dimension salt, found that the mixture preparation of Rynaxypyr and first dimension salt has strong synergy.Especially the most obvious with the synergy that is mixed of the ratio of Rynaxypyr and emamectin benzoate-chlorfenapyr active ingredient (10: 1～1: 1), co-toxicity coefficient reaches more than 200.Finished the present invention based on above research and discovery.
Summary of the invention
The object of the present invention is to provide a kind of component reasonable, good to pest controling effect, drug cost is low, and stop and delay pest resistance to insecticide development, to environment, person poultry safety, Synergistic insecticidal composition that can large scale application.
Implementation procedure of the present invention is as follows:
A kind of insecticides comprises:
A) the first active component Rynaxypyr;
B) the second active component emamectin-benzoate;
And acceptable diluent or carrier on the agricultural chemicals, wherein the weight ratio of first active component and second active component is 30: 1～1: 1, preferred weight ratio is 10: 1～1: 1.
First active component and the second active component summation account for 0.5%～90% of composition total weight.
Composition pesticide of the present invention can be mixed with suspending agent, water dispersible granules and microemulsion according to method well-known in the art.
Auxiliary agent used when the preparation suspending agent is as follows:
Suspending agent is each active component to be added with auxiliary agent sand milling obtains in the sand milling still, optionally adds suitable stabilizing agent, antifreezing agent, thickener, bleeding agent etc. simultaneously.
Adjuvant used as follows when the preparation water dispersible granules:
Wetting agent can be sodium alkyl benzene sulfonate, sodium lignin sulfonate, fatty alcohol, alkyl sulfate, alkylphenol polyoxyethylene etc., and general consumption accounts for 5-25wt%.
Dispersant can be naphthalenesulfonic acid-formaldehyde condensate, ethoxylated dodecyl alcohol etc., and general consumption accounts for 5-10wt%.
Carrier adularescent kaolin, precipitated calcium carbonate, white carbon, diatomite etc., general consumption accounts for 20-60wt%.
Binding agent has lecithin, polyethylene glycol, starch etc., and general consumption accounts for 2-8wt%.
Disintegrant has bentonite, ammonium sulfate etc., and general consumption accounts for 5-15wt%.
Adjuvant used when the preparation microemulsion:
Emulsifier has alkylbenzenesulfonate series, diphenyl phenolic group polyoxyethylene poly-oxygen propylene aether, diphenyl phenolic group APEO formaldehyde condensation products, castor oil ethylene oxide adduct and derivative thereof etc., for example dense newborn 2201, NP series etc.Emulsifier can be one or more mixing, and general consumption accounts for 10-30wt%.
Solvent and cosolvent have arene, alcohols, ester class, ketone, amide-type, and for example: methyl alcohol, ethanol, butanols, cyclohexanone etc. can be the mixtures of one or more solvents or auxiliary agent, and general consumption accounts for 20-50wt%.
Antifreezing agent has glycerine, propane diols, ethylene glycol, urea, sodium chloride etc., and general consumption accounts for 2-7wt%.
Stabilizing agent has urea, methyl alcohol, wettable starch etc., and general consumption accounts for 0.5-8wt%.
Defoamer has organic silicone oil, methyl alcohol, ethanol etc., and general consumption accounts for 0.5-8wt%.
Compared with prior art, beneficial effect of the present invention is: 1, being mixed has obvious synergistic effect, has improved control efficiency; 2, enlarged the control spectrum; 3, two kinds of active ingredients are mixed, and have reduced dosage, thereby have reduced cost and the pollution that has alleviated environment; 4, be mixed and delayed the resistance of single active ingredient.
Embodiment
Biological control example 1: Rynaxypyr and the composite synergy of first dimension salt to rice leaf roller
Test medicine is mixed with former medicine the test medicine that needs by research department of Shanxi Biaozheng Crop Science Co., Ltd.Test method is with reference to " the agricultural industry criteria NY/T1154.7-2006 of the People's Republic of China (PRC) ".The examination worm is the rice leaf roller adult of picking up from the field, and indoor rice seedling is raised, and adopts the larva of first generation hatching.Select the larva of growth uniformity, the culture dish that the diameter of the fresh rice leaf of access storing is 12 centimetres.Every ware is put into 10 rice leaf roller.Whenever be treated to 5 wares.Spray under 50PSI pressure with the Potter spray tower.Culture dish of each spray, 3 milliliters of every ware spraying liquids.Sprayed the back and fast put into 25 ℃ behind the airing rice leaf, cultivated in the 12H/12H illumination box, checked in 48 hours and to calculate lethality by dead borer population.Blank spray equivalent clear water.General each processing is provided with 6 concentration gradients.Carry out statistical analysis with the DPS statistical analysis software, calculate the LC of each medicament
50, estimate the activity of reagent agent according to this to the examination worm.Calculate co-toxicity coefficient (CTC) according to the abundant method of Sun Yun.
When CTC≤80, then the composition performance is for antagonism, and when 80＜CTC＜120, then the composition performance is for summation action, and when CTC 〉=120, then the composition performance is synergistic effect.
Actual measurement toxicity index (ATI)=(standard medicament LC
50/ reagent agent LC
50) * 100
The percentage composition of B in percentage composition+B medicament toxicity index * mixture of A in theoretical toxicity index (TTI)=A medicament toxicity index * mixture
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (the ATI)/theoretical toxicity index (TTI) of mixture] * 100
The joint toxicity measuring of table 1 Rynaxypyr and first dimension salt pair rice leaf roller
| Reagent agent (active ingredient weight ratio) | LC 50 (mg/l) | ATI | TTI | Co-toxicity coefficient CTC |
| Rynaxypyr | 1.11 | 100 | ||
| First dimension salt | 0.58 | 191.4 | ||
| Rynaxypyr, first dimension salt 30: 1 | 0.89 | 124.7 | 102.9 | 121.1 |
| Rynaxypyr, first dimension salt 20: 1 | 0.82 | 135.4 | 104.4 | 129.7 |
| Rynaxypyr, first dimension salt 15: 1 | 0.66 | 168.2 | 105.7 | 159.1 |
| Rynaxypyr, first dimension salt 10: 1 | 0.48 | 231.3 | 108.3 | 213.5 |
| Rynaxypyr, first dimension salt 5: 1 | 0.32 | 346.9 | 115.2 | 301.0 |
| Rynaxypyr, first dimension salt 1: 1 | 0.35 | 317.1 | 145.7 | 217.7 |
Measurement result to rice leaf roller is as shown in table 1, and salt is composite that rice leaf roller is had very high synergistic effect for Rynaxypyr and first dimension.Rynaxypyr and first dimension salt proportioning are that 15: 1～1: 1 o'clock co-toxicity coefficient can reach more than 150.
Biological control example 2: Rynaxypyr and the composite synergy of first dimension salt to diamond-back moth
Test medicine is mixed with former medicine the test medicine that needs by research department of Shanxi Biaozheng Crop Science Co., Ltd.Test method is with reference to " the agricultural industry criteria NY/T1154.7-2006 of the People's Republic of China (PRC) ".The examination worm is the pupa that picks up from the diamond-back moth in field, and that Turnip Sprouts examination of indoor idol is supported, and adopts the larva of first generation hatching.Select the third-instar larvae of growth uniformity, the culture dish that the diameter of the fresh a variety of Chinese cabbage of access storing is 12 centimetres.Every ware is put into 30 diamondback moth larvaes.5 wares of every processing.Spray under 50PSI pressure with the Porrer spray tower.Culture dish of each spray, 3 milliliters of every ware spraying liquids.Sprayed the back and fast put into 25 ℃ behind the airing Chinese cabbage leaf, cultivated in the 12H/12H illumination box, checked in 48 hours and to calculate lethality by dead borer population.Blank spray equivalent clear water.General each processing is provided with 6 concentration gradients.Statistical method is the same.
The joint toxicity measuring of table 2 Rynaxypyr and first dimension salt pair diamond-back moth
| Reagent agent (active ingredient weight ratio) | LC 50 (mg/l) | ATI | TTI | Co-toxicity coefficient CTC |
| Rynaxypyr | 0.89 | 100.0 | ||
| First dimension salt | 0.21 | 423.8 | ||
| Rynaxypyr, first dimension salt 30: 1 | 0.52 | 171.2 | 110.4 | 155.0 |
| Rynaxypyr, first dimension salt 20: 1 | 0.44 | 202.3 | 115.4 | 175.3 |
| Rynaxypyr, first dimension salt 15: 1 | 0.35 | 254.3 | 120.2 | 211.5 |
| Rynaxypyr, first dimension salt 10: 1 | 0.25 | 356.0 | 129.4 | 275.0 |
| Rynaxypyr, first dimension salt 5: 1 | 0.18 | 494.4 | 154.0 | 321.1 |
| Rynaxypyr, first dimension salt 1: 1 | 0.14 | 635.7 | 261.9 | 242.7 |
Measurement result to diamond-back moth is as shown in table 2, and salt is composite that diamond-back moth is had very high synergistic effect for Rynaxypyr and first dimension.Rynaxypyr and first dimension salt proportioning are that 30: 1～1: 1 o'clock co-toxicity coefficient can reach more than 150.
Bactericidal composition of the present invention can be prepared into known method and be fit to any one formulation that agricultural is used, and reasonable formulation is water dispersible granules, suspending agent.Below describe with specific embodiment, all the prescription in percentage all be weight percentage.The processing technology of the various preparations of the present composition is prior art, can change to some extent according to different situations.
Formulation examples 1 (20% suspending agent)
Rynaxypyr 17.5%, first dimension salt 2.5%, ethanol 5%, naphthalenesulfonic acid-formaldehyde condensate 7%, 2201 accounts for 115%, filler white carbon 17%, other complements to 100% with deionized water.
This prescription is by the doubly dilution spraying of 10 gram/mus, 72 hours control efficiency are 93.1% behind the medicine, 10% Rynaxypyr suspending agent and 2.5% emamectin benzoate microemulsion use after the same method, and 72 hours preventive effects are respectively 72.4% and 81.3% behind the medicine.
Formulation examples 2 (65% water dispersible granules)
Rynaxypyr 60%, first dimension salt 5%, polyethylene glycol 3%, neopelex 6%, bentonite 14%, naphthalenesulfonic acid-formaldehyde condensate 6%, white carbon complements to 100%.
This prescription is by the doubly dilution spraying of 3 gram/mus, 72 hours control efficiency are 96.1% behind the medicine, 10% Rynaxypyr suspending agent and 2.5% emamectin benzoate microemulsion use after the same method, and 72 hours preventive effects are respectively 63.5% and 74.3% behind the medicine.
Formulation examples 3 (45% microemulsion)
Rynaxypyr 40%, first dimension salt 5%, methyl alcohol 6%, glycerine 7%, sodium lignin sulfonate 26%, dense newborn 2,201 19%, deionized water complements to 100%.
This prescription is by the doubly dilution spraying of 5 gram/mus, 72 hours control efficiency are 94.3% behind the medicine, 10% Rynaxypyr suspending agent and 2.5% emamectin benzoate microemulsion use after the same method, and 72 hours preventive effects are respectively 61.5% and 75.2% behind the medicine.
Formulation examples 4 (21% microemulsion)
Rynaxypyr 18%, first dimension salt 3%, methyl alcohol 3%, glycerine 5%, sodium alkyl benzene sulfonate 22%, dense newborn 2,201 18%, deionized water complements to 100%.
This prescription is by the doubly dilution spraying of 10 gram/mus, 72 hours control efficiency are 92.7% behind the medicine, 10% Rynaxypyr suspending agent and 2.5% emamectin benzoate microemulsion use after the same method, and 72 hours preventive effects are respectively 71.2% and 81.8% behind the medicine.
Claims (5)
1, a kind of insecticides is characterized in that comprising:
A) the first active component Rynaxypyr;
B) the second active component emamectin-benzoate;
And acceptable diluent or carrier on the agricultural chemicals, wherein the weight ratio of first active component and second active component is 30: 1～1: 1.
2, insecticides according to claim 1 is characterized in that: the weight ratio of first active component and second active component is 10: 1～1: 1.
3, insecticides according to claim 1 is characterized in that: active component accounts for 0.5%～90% of composition total weight.
4, insecticides according to claim 1 is characterized in that: composition is suspending agent, water dispersible granules or microemulsion.
5, one of any application of described insecticides aspect controlling crop diseases and insect pests of claim 1 to 4.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2009100225428A CN101554170A (en) | 2009-05-15 | 2009-05-15 | Chlorantraniliprole and emamectin benzoate insecticidal composition |
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|---|---|---|---|
| CNA2009100225428A CN101554170A (en) | 2009-05-15 | 2009-05-15 | Chlorantraniliprole and emamectin benzoate insecticidal composition |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101755774A (en) * | 2010-01-26 | 2010-06-30 | 中国水稻研究所 | Compound pesticide of chlorantraniliprole and avermectins |
| CN101779643A (en) * | 2010-02-12 | 2010-07-21 | 浙江升华拜克生物股份有限公司 | Compound pesticide |
| CN102524276A (en) * | 2012-01-30 | 2012-07-04 | 华南理工大学 | Chlorantraniliprole and emamectin benzoate compounded suspending agent and preparation method thereof |
| CN102657191A (en) * | 2012-05-14 | 2012-09-12 | 江苏省农业科学院 | Field drum mixed pesticide synergist formula for rice plant hopper and stem borer |
| CN104472495A (en) * | 2014-12-15 | 2015-04-01 | 广西颐生园生态农业有限公司 | Insecticidal composition containing benzenecarbothioamide |
| CN105685067A (en) * | 2016-03-31 | 2016-06-22 | 杭州宇龙化工有限公司 | Agricultural insecticidal composition and application thereof |
| CN105724389A (en) * | 2016-04-19 | 2016-07-06 | 陕西上格之路生物科学有限公司 | Dispersible oil suspension containing chlorantraniliprole |
| CN106577730A (en) * | 2017-01-11 | 2017-04-26 | 陕西上格之路生物科学有限公司 | Insecticide composition containing chlorantraniliprole |
| CN110754475A (en) * | 2019-11-12 | 2020-02-07 | 安徽省农业科学院植物保护与农产品质量安全研究所 | Medicament composition for preventing and treating spodoptera frugiperda and use method thereof |
| CN110896955A (en) * | 2019-10-25 | 2020-03-24 | 河北威远生物化工有限公司 | Insecticidal composition for preventing and treating lepidoptera pests |
| CN114052036A (en) * | 2021-12-31 | 2022-02-18 | 山东耘歌生物科技有限公司 | Insecticide containing chlorantraniliprole and emamectin benzoate as well as preparation method and application thereof |
| CN116746583A (en) * | 2023-08-11 | 2023-09-15 | 山东科赛基农生物工程有限公司 | Water dispersible granule containing emamectin benzoate and chlorantraniliprole |
-
2009
- 2009-05-15 CN CNA2009100225428A patent/CN101554170A/en active Pending
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101755774A (en) * | 2010-01-26 | 2010-06-30 | 中国水稻研究所 | Compound pesticide of chlorantraniliprole and avermectins |
| CN101779643A (en) * | 2010-02-12 | 2010-07-21 | 浙江升华拜克生物股份有限公司 | Compound pesticide |
| CN101779643B (en) * | 2010-02-12 | 2014-03-19 | 浙江升华拜克生物股份有限公司 | Compound pesticide |
| CN102524276A (en) * | 2012-01-30 | 2012-07-04 | 华南理工大学 | Chlorantraniliprole and emamectin benzoate compounded suspending agent and preparation method thereof |
| CN102657191A (en) * | 2012-05-14 | 2012-09-12 | 江苏省农业科学院 | Field drum mixed pesticide synergist formula for rice plant hopper and stem borer |
| CN102657191B (en) * | 2012-05-14 | 2013-10-16 | 江苏省农业科学院 | Field drum mixed pesticide synergist formula for rice plant hopper and stem borer |
| CN104472495A (en) * | 2014-12-15 | 2015-04-01 | 广西颐生园生态农业有限公司 | Insecticidal composition containing benzenecarbothioamide |
| CN105685067A (en) * | 2016-03-31 | 2016-06-22 | 杭州宇龙化工有限公司 | Agricultural insecticidal composition and application thereof |
| CN105724389A (en) * | 2016-04-19 | 2016-07-06 | 陕西上格之路生物科学有限公司 | Dispersible oil suspension containing chlorantraniliprole |
| CN106577730A (en) * | 2017-01-11 | 2017-04-26 | 陕西上格之路生物科学有限公司 | Insecticide composition containing chlorantraniliprole |
| CN110896955A (en) * | 2019-10-25 | 2020-03-24 | 河北威远生物化工有限公司 | Insecticidal composition for preventing and treating lepidoptera pests |
| CN110896955B (en) * | 2019-10-25 | 2021-08-03 | 河北威远生物化工有限公司 | Insecticidal composition for preventing and treating lepidoptera pests |
| CN110754475A (en) * | 2019-11-12 | 2020-02-07 | 安徽省农业科学院植物保护与农产品质量安全研究所 | Medicament composition for preventing and treating spodoptera frugiperda and use method thereof |
| CN114052036A (en) * | 2021-12-31 | 2022-02-18 | 山东耘歌生物科技有限公司 | Insecticide containing chlorantraniliprole and emamectin benzoate as well as preparation method and application thereof |
| CN116746583A (en) * | 2023-08-11 | 2023-09-15 | 山东科赛基农生物工程有限公司 | Water dispersible granule containing emamectin benzoate and chlorantraniliprole |
| CN116746583B (en) * | 2023-08-11 | 2023-11-03 | 山东科赛基农生物工程有限公司 | Water dispersible granule containing emamectin benzoate and chlorantraniliprole |
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Application publication date: 20091014 |