CN101553537B - Polyphenylene sulfide resin molded article - Google Patents
Polyphenylene sulfide resin molded article Download PDFInfo
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- CN101553537B CN101553537B CN2007800354856A CN200780035485A CN101553537B CN 101553537 B CN101553537 B CN 101553537B CN 2007800354856 A CN2007800354856 A CN 2007800354856A CN 200780035485 A CN200780035485 A CN 200780035485A CN 101553537 B CN101553537 B CN 101553537B
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- CN
- China
- Prior art keywords
- polyphenylene sulfide
- resin molded
- mass parts
- molded article
- sulfide resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Links
- 239000004734 Polyphenylene sulfide Substances 0.000 title claims abstract description 52
- 229920000069 polyphenylene sulfide Polymers 0.000 title claims abstract description 52
- 229920005989 resin Polymers 0.000 title claims abstract description 39
- 239000011347 resin Substances 0.000 title claims abstract description 39
- 239000003365 glass fiber Substances 0.000 claims abstract description 23
- 239000011342 resin composition Substances 0.000 claims abstract description 12
- 230000003287 optical effect Effects 0.000 claims description 29
- 238000000465 moulding Methods 0.000 claims description 23
- 239000000463 material Substances 0.000 claims description 16
- 238000011049 filling Methods 0.000 claims description 14
- 229920006389 polyphenyl polymer Polymers 0.000 claims description 10
- 150000003568 thioethers Chemical class 0.000 claims description 10
- 239000000203 mixture Substances 0.000 description 9
- -1 p-phenylene, m-phenylene, o-phenylene Chemical group 0.000 description 9
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 description 6
- 150000001491 aromatic compounds Chemical class 0.000 description 5
- 238000005452 bending Methods 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 229910052736 halogen Inorganic materials 0.000 description 5
- 125000005843 halogen group Chemical group 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 239000000835 fiber Substances 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- ODPYDILFQYARBK-UHFFFAOYSA-N 7-thiabicyclo[4.1.0]hepta-1,3,5-triene Chemical group C1=CC=C2SC2=C1 ODPYDILFQYARBK-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 229940117389 dichlorobenzene Drugs 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 239000010439 graphite Substances 0.000 description 3
- 229910002804 graphite Inorganic materials 0.000 description 3
- 230000001678 irradiating effect Effects 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 238000007493 shaping process Methods 0.000 description 3
- 235000010265 sodium sulphite Nutrition 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- RELMFMZEBKVZJC-UHFFFAOYSA-N 1,2,3-trichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1Cl RELMFMZEBKVZJC-UHFFFAOYSA-N 0.000 description 2
- XKEFYDZQGKAQCN-UHFFFAOYSA-N 1,3,5-trichlorobenzene Chemical compound ClC1=CC(Cl)=CC(Cl)=C1 XKEFYDZQGKAQCN-UHFFFAOYSA-N 0.000 description 2
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 2
- XWUCFAJNVTZRLE-UHFFFAOYSA-N 7-thiabicyclo[2.2.1]hepta-1,3,5-triene Chemical compound C1=C(S2)C=CC2=C1 XWUCFAJNVTZRLE-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- 229920000265 Polyparaphenylene Polymers 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000012765 fibrous filler Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052976 metal sulfide Inorganic materials 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 239000002798 polar solvent Substances 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- VMHYWKBKHMYRNF-UHFFFAOYSA-N (2-chlorophenyl)-phenylmethanone Chemical class ClC1=CC=CC=C1C(=O)C1=CC=CC=C1 VMHYWKBKHMYRNF-UHFFFAOYSA-N 0.000 description 1
- GMVJKSNPLYBFSO-UHFFFAOYSA-N 1,2,3-tribromobenzene Chemical compound BrC1=CC=CC(Br)=C1Br GMVJKSNPLYBFSO-UHFFFAOYSA-N 0.000 description 1
- FWAJPSIPOULHHH-UHFFFAOYSA-N 1,2,4-tribromobenzene Chemical compound BrC1=CC=C(Br)C(Br)=C1 FWAJPSIPOULHHH-UHFFFAOYSA-N 0.000 description 1
- YWDUZLFWHVQCHY-UHFFFAOYSA-N 1,3,5-tribromobenzene Chemical compound BrC1=CC(Br)=CC(Br)=C1 YWDUZLFWHVQCHY-UHFFFAOYSA-N 0.000 description 1
- ZPQOPVIELGIULI-UHFFFAOYSA-N 1,3-dichlorobenzene Chemical compound ClC1=CC=CC(Cl)=C1 ZPQOPVIELGIULI-UHFFFAOYSA-N 0.000 description 1
- SWJPEBQEEAHIGZ-UHFFFAOYSA-N 1,4-dibromobenzene Chemical compound BrC1=CC=C(Br)C=C1 SWJPEBQEEAHIGZ-UHFFFAOYSA-N 0.000 description 1
- JRGGUPZKKTVKOV-UHFFFAOYSA-N 1-bromo-3-chlorobenzene Chemical compound ClC1=CC=CC(Br)=C1 JRGGUPZKKTVKOV-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- CXKCZFDUOYMOOP-UHFFFAOYSA-N 3,5-dichlorobenzoic acid Chemical compound OC(=O)C1=CC(Cl)=CC(Cl)=C1 CXKCZFDUOYMOOP-UHFFFAOYSA-N 0.000 description 1
- YTBRNEUEFCNVHC-UHFFFAOYSA-N 4,4'-dichlorobiphenyl Chemical group C1=CC(Cl)=CC=C1C1=CC=C(Cl)C=C1 YTBRNEUEFCNVHC-UHFFFAOYSA-N 0.000 description 1
- SOHCOYTZIXDCCO-UHFFFAOYSA-N 6-thiabicyclo[3.1.1]hepta-1(7),2,4-triene Chemical group C=1C2=CC=CC=1S2 SOHCOYTZIXDCCO-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 229910052582 BN Inorganic materials 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- OJMOMXZKOWKUTA-UHFFFAOYSA-N aluminum;borate Chemical compound [Al+3].[O-]B([O-])[O-] OJMOMXZKOWKUTA-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 229910000085 borane Inorganic materials 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 229920006038 crystalline resin Polymers 0.000 description 1
- 230000000254 damaging effect Effects 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- QTNDMWXOEPGHBT-UHFFFAOYSA-N dicesium;sulfide Chemical compound [S-2].[Cs+].[Cs+] QTNDMWXOEPGHBT-UHFFFAOYSA-N 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 1
- GLNWILHOFOBOFD-UHFFFAOYSA-N lithium sulfide Chemical compound [Li+].[Li+].[S-2] GLNWILHOFOBOFD-UHFFFAOYSA-N 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 229960001708 magnesium carbonate Drugs 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 235000014380 magnesium carbonate Nutrition 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 150000001282 organosilanes Chemical class 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- DPLVEEXVKBWGHE-UHFFFAOYSA-N potassium sulfide Chemical compound [S-2].[K+].[K+] DPLVEEXVKBWGHE-UHFFFAOYSA-N 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- AHKSSQDILPRNLA-UHFFFAOYSA-N rubidium(1+);sulfide Chemical compound [S-2].[Rb+].[Rb+] AHKSSQDILPRNLA-UHFFFAOYSA-N 0.000 description 1
- 239000010980 sapphire Substances 0.000 description 1
- 229910052594 sapphire Inorganic materials 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Substances CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L81/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing sulfur with or without nitrogen, oxygen or carbon only; Compositions of polysulfones; Compositions of derivatives of such polymers
- C08L81/02—Polythioethers; Polythioether-ethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
Abstract
A polyphenylene sulfide resin molded article is composed of a polyphenylene sulfide resin composition in which 10 to 200 parts by mass of a glass fiber having a flat cross section is added to 100 parts by mass of polyphenylene sulfide, and the thickness of a thin portion of the molded article is 0.3 to 1.4 mm.
Description
Technical field
The present invention relates to polyphenylene sulfide resin molded article.
Background technology
In the past, light picker such as CD, DVD (pick-up), high-speed color duplicating machine, high-speed color laser beam printer optical systems such as (LBP) shell optical elements such as (base) were made by the two castings of metals such as aluminum oxide, zinc.But, since in recent years to product reduce cost, demand such as lightweight uprises, begin one's study they resinifying and replaced gradually.For example, for the lightweight of light picker, save purpose such as space, advancing a part of resinifying of shell, be accompanied by the resinifying of the fine elongated light picker of popularizing of laptop.
With the light picker is in the product at center, and it is more and more common less than the molding of the thinner wall section of 1.4mm to have thickness.Though in half high pick-up shell in the past, do not have such thinner wall section, can see about 5～50% of shadow area in the fine elongated pick-up shell and be the product of thinner wall section.
During with above-mentioned fine elongated pick-up shell resinifying, there is the Young's modulus of thinner wall section such problem points that descends.
Again, the resin material that is used for optical element, corresponding to the function of optical element, characteristics such as the dimensional precision when requiring (injection) to be shaped, dimensional stability, plasticity (flowability), physical strength, rigidity, environment resistant (heat, humidity, medicine etc.), flame retardant resistance.
Be accompanied by high record densityizatioies such as CD, DVD or high speed such as processingization or duplicating machine, LBP colorize etc. highly, in the characteristic of resinification optical element, particularly reduce the optical axis deviation that optical system changes for environment (temperature, humidity etc.) for dimensional stability, require more and more stricter.
Generally, in order to improve the optical axis characteristic, (PPE: high Tg non-crystalline resin) method that improves the dimensional stability of material is (patent documentation 1) effectively by adding filler or polyphenylene oxide.But this is not best suited for the method to the many fine elongated light pickers of thinner wall section.
On the other hand, known, by the glass fibre that filling has flattened, can provide the thermoplastic resin composition of excellent in dimensional stability.
Patent documentation 1: the Japanese Patent spy opens the 2001-294751 communique
Patent documentation 2: the Japanese Patent spy opens clear 62-268612 communique
Patent documentation 3: the Japanese Patent spy opens the 2003-268252 communique
The object of the present invention is to provide a kind of thinner wall section to show the polyphenylene sulfide resin molded article of high elastic coefficient and dimensional stability.
Summary of the invention
The invention people concentrates on studies for achieving the above object, and found that, adds a certain amount of glass fibre with specified shape by the p-poly-phenyl thioether, can obtain the polyphenylene sulfide resin molded article that thinner wall section shows high elastic coefficient.
And then the contriver finds, by add a certain amount of weighting agent again in above-mentioned polyphenylene sulfide, can access optical axis deviation is reduced to minimum, gives the also resin forming product of excellent optical element of physical strength, and finish the present invention.
According to the present invention, provide following polyphenylene sulfide resin molded article.
1. polyphenylene sulfide resin molded article, constitute by polyphenyl thioether resin composition, in the described polyphenyl thioether resin composition, with respect to 100 mass parts polyphenylene sulfides, be added with 10～200 mass parts and have the glass fibre in flat pattern cross section, the thickness of the thinner wall section of described molding is 0.3～1.4mm.
2. according to the polyphenylene sulfide resin molded article of 1 record, the flat ratio of described glass fibre is 0.1～0.5.
3. according to the polyphenylene sulfide resin molded article of 1 or 2 records,, also be added with inorganic filling material 0～200 mass parts with respect to 100 mass parts polyphenylene sulfides.
4. optical element is made of each polyphenylene sulfide resin molded article of putting down in writing in 1～3.
5. light picker shell is made of each polyphenylene sulfide resin molded article of putting down in writing in 1～3.According to the present invention, can provide thinner wall section to show the polyphenylene sulfide resin molded article of high elastic coefficient and dimensional stability.
Description of drawings
Fig. 1: the figure that represents the flat ratio of glass fibre used in the present invention.
Fig. 2: the figure that concerns between the molding thickness (mm) of molding that expression is obtained by the resin combination of embodiment 2 and the molding that obtains by the resin combination of comparative example 2 and the bending elastic modulus (GPa).
Fig. 3: the figure that concerns between the molding thickness (mm) of molding that expression is obtained by the resin combination of embodiment 4 and the molding that obtains by the resin combination of comparative example 4 and the bending elastic modulus (GPa).
Embodiment
Polyphenylene sulfide resin molded article of the present invention is made of polyphenyl thioether resin composition, in the described polyphenyl thioether resin composition, with respect to 100 mass parts polyphenylene sulfides, is added with the glass fibre that 10～200 mass parts have the flat pattern cross section.
The polyphenylene sulfide that the present invention uses is a kind of polymkeric substance, and its repeating unit is shown below:
-(Ph-S)-
(in the formula, Ph represents phenylene, and S represents sulphur.)
Repeating unit (Ph-S) is defined as 1mol (basic mol), polyphenylene sulfide used in the present invention be contain usually 50mol% above, be preferably the polymkeric substance that 70mol% is above, be more preferably the above repeating unit of 90mol%.
Phenylene can exemplify, p-phenylene, m-phenylene, o-phenylene, alkyl substituted phenylene (be preferably carbonatoms be 1～6 alkyl), phenyl substituted phenylene, halogen substituted phenylene, amino substituted phenylene, acid amides substituted phenylene, p, p '-diphenylene sulfone, p, p '-diphenylene, p, p '-bis-phenylene ether, p, p '-diphenylene carbonyl and naphthalene etc.Multipolymer that the polyphenylene sulfide that these phenylenes constitute can exemplify the homopolymer that is made of same repeating unit, be made of two or more different phenylenes and composition thereof.
In these polyphenylene sulfides, be to repeat the polyphenylene sulfide of unitary main composition key element with the p-phenylene sulfide, because it is its excellent in workability and industrial ratio are easier to acquisition, therefore comparatively desirable.In addition, can use polyphenylene ketone thioether, polyphenylene ketone ketone thioether etc.The object lesson of multipolymer has: have p-phenylene sulfide repeating unit and m-phenylene sulfide repeating unit random or segmented copolymer, have phenylene sulfide repeating unit and phenylene ketone thioether repeating unit random or segmented copolymer, have phenylene sulfide repeating unit and phenylene ketone ketone thioether repeating unit random or segmented copolymer, have the random or segmented copolymer of phenylene sulfide repeating unit and phenylene sulfone thioether repeating unit etc.It is desirable to these polyphenylene sulfides is crystalline polymer.
Polyphenylene sulfide can obtain by the known method that makes alkali metalsulphide and two halogen substituted aromatic compound polymerization reaction take places in polar solvent.Alkali metalsulphide can be enumerated lithium sulfide, sodium sulphite, potassium sulphide, rubidium sulfide, cesium sulfide etc.Also can be by the sodium sulphite that the reaction of sodium sulfhydrate and sodium hydroxide is generated.Two halogen substituted aromatic compounds can exemplify, p-dichlorobenzene, m-dichlorobenzene, 2,5-toluene dichloride, p-dibromo-benzene, 2,6-naphthalene dichloride, 1-methoxyl group-2,5-dichlorobenzene, 4,4 '-dichloro-biphenyl, 3,5-dichlorobenzoic acid, p, p '-dichloro-diphenyl ether, 4,4 '-dichlorobenzene sulfone, 4,4 '-dichloro thionyl benzene and 4,4 '-two chloro benzophenones etc.They can use separately respectively or be used in combination more than 2 kinds.
In order in polyphenylene sulfide, to introduce some branched structures or crosslinking structure, can be also with the poly-halogen substituted aromatic compound that has 3～6 halogenic substituents in the per molecule.The example of poly-halogen substituted aromatic compound has 1,2,3-trichloro-benzene, 1,2,3-tribromo-benzene, 1,2,4-trichloro-benzene, 1,2,4-tribromo-benzene, 1,3,5-trichloro-benzene, 1,3,5-tribromo-benzene, 1, three halogenated aromatic compounds and their alkyl substituents such as 3-two chloro-5-bromobenzene.They can use separately respectively or be used in combination more than 2 kinds.Wherein, from viewpoints such as economy, reactivity, physical propertiess, be preferably 1,2,4-trichloro-benzene, 1,3,5-trichloro-benzene and 1,2,3-trichloro-benzene.
As polar solvent, N-alkyl pyrrolidones, 1 such as N-N-methyl-2-2-pyrrolidone N-, the aromatic series organic amide solvent of representatives such as 3-dialkyl group-2-imidazolidyl ketone, tetraalkyl urea, hexyl alkylphosphonic acid carboxylic acid triamide since the stability of reactive system high, be easy to obtain high molecular weight polymers, therefore comparatively desirable.The present invention except that straight catenate polyphenylene sulfide, also can use and implement various clean operations, heat treated polyphenylene sulfide after polymerization in itself.
The glass fibre that the present invention uses has the cross section of flat pattern, and it is desirable to flat ratio is 0.1～0.5, is more preferably 0.2～0.3.Flat ratio is more than 0.2, and flexural strength can maintain extra high level, below 0.3, can maintain extra high level in the thinner wall section bending elastic modulus.
As shown in Figure 1, the minor axis in cross section is the major diameter in D1, cross section when being D2, and flat ratio is meant D1/D2.During flat ratio less than 0.1, the flexural strength of molding has the worry of decline unsatisfactory.On the other hand, flat ratio surpasses at 0.5 o'clock, and the thinner wall section of molding does not show high elastic coefficient, and the common glass fibre of optical axis characteristic, physical strength and use is the same in optical element, and the worry that can not significantly show effect of the present invention is arranged.
The minor axis D1 in the cross section of glass fibre is preferably 0.5～25 μ m, and the major diameter D2 in cross section is preferably 1.0～250 μ m.The cross section of glass fibre is too thin, and the difficulty that spins sometimes of glass fibre is too thick, reduces sometimes owing to the contact area with resin reduces to wait the reinforced effects as glass fibre reinforcement.
With respect to 100 mass parts polyphenylene sulfides, add 10～200 mass parts glass fibre.Addition less than 10 mass parts, the rigidity of molding has the worry of reduction.Surpass 200 mass parts on the other hand, the worry that has the dimensional stability of the worry that flowability reduces and shock strength reduces of resin combination or molding to reduce, therefore, undesirable.
With respect to 100 mass parts polyphenylene sulfides, it is better to add 20～160 mass parts glass fibre.Addition is in above-mentioned scope, and the intensity of molding such as increases, is difficult for shrinking at the shaping bad phenomenon, and flowability is also high.
Polyphenyl thioether resin composition used in the present invention is preferably with respect to 100 mass parts polyphenylene sulfides, also is added with 0～200 mass parts inorganic filling material (except the glass fibre).The addition of inorganic filling material surpasses 200 mass parts, and the flowability of resin combination reduces, or the big residual stress of the thinner wall section of molding generation, and the worry that causes thermal distortion is arranged, and is therefore, unsatisfactory.
With respect to 100 mass parts polyphenylene sulfides, the addition of inorganic filling material is more preferably 50～200 mass parts, and good especially is 50～170 mass parts.Addition surpasses 50 mass parts, and the additive effect of inorganic filling material can fully show.Again, addition is difficult for causing mobile and the intensity reduction below 170 mass parts.
Inorganic filling material limits so long as be used as then not having especially of inorganic filling material usually, and in addition, its shape also is not particularly limited, and any in unsetting, spherical or tabular all can.
The object lesson of inorganic filling material has, carbon fiber, potassium titanate crystal whisker, ZnOw, aluminium borate whisker, aramid fibre, sapphire whisker, silicon carbide fiber, ceramic fiber, fibrous magnesium silicate, the stone ore fiber, fibrous fillers such as steel fiber, tabular weighting agent such as glass flake and mica, wollastonite, zeolite, sericite, talcum, kaolin, clay, agalmatolite, wilkinite, silicate such as asbestos and alumina silicate, silicon oxide, magnesium oxide, aluminum oxide, zirconium white, metallic compound such as titanium oxide and ferric oxide, lime carbonate, carbonate such as magnesiumcarbonate, vitriol such as calcium sulfate and barium sulfate, calcium hydroxide, oxyhydroxide such as magnesium hydroxide and aluminium hydroxide, granulated glass sphere, ceramic bead, boron nitride, silicon carbide, graphite, non-fibrous filler such as carbon black and silicon-dioxide, they can hollow, and then, also two or more kinds may be used these weighting agents.Again, with coupling agents such as isocyanic ester based compound, organosilane based compound, organic titanate based compound, organic borane based compound and epoxy compoundss these weighting agents being carried out using after the pre-treatment is comparatively ideal on the meaning that can obtain more excellent physical strength.
Above-mentioned polyphenyl thioether resin composition in the scope of not damaging effect of the present invention, can add various additives, for example, and lubricant, antistatic agent, antioxidant, UV light absorber, releasing agent and tinting material etc.
Again, polyphenyl thioether resin composition can come down to by polyphenylene sulfide and the glass fibre with flat pattern cross section, or constitute by polyphenylene sulfide, the glass fibre with flat pattern cross section and inorganic filling material, again, also can only there be these compositions to constitute." come down to by ... constitute " expression, above-mentioned composition mainly is by polyphenylene sulfide and the glass fibre with flat pattern cross section, perhaps, is made of polyphenylene sulfide, the glass fibre with flat pattern cross section and inorganic filling material, except that these compositions, can contain above-mentioned additive.
The thickness of the thinner wall section of polyphenylene sulfide resin molded article of the present invention (the thinnest part of molding) is 0.3～1.4mm, is preferably 0.4～1.4mm, and that good especially is 0.6～1.2mm.
The not enough 0.3mm of the thickness of thinner wall section has the inadequate worry of filling when being shaped.On the other hand, the thickness of thinner wall section surpasses 1.4mm, and the characteristic of molding can not change, and can not obtain effect of the present invention.
Polyphenylene sulfide resin molded article of the present invention shows high elastic coefficient and dimensional stability in thinner wall section, has excellent formability, physical strength height, optical axis deviation be very little, therefore, is useful as optical element, particularly light picker.Light picker is meant as CD and reads the optical element of base station, the plasticity of requirement precision, the heat-resisting dimensional stability of height.
Resin forming product of the present invention, even the ratio of the thinner wall section of above-mentioned thickness is 5%～50% (in the shared ratio of shadow area) of all molding, the reduction of the Young's modulus of thinner wall section is also little, the also suitable optical element that is used as.
Optical element of the present invention except light picker, also has excellent performance as products such as the optics box of LBP, camera gun tubes.
The manufacturing process that obtains polyphenylene sulfide resin molded article of the present invention is not particularly limited, and can use any known method.
[embodiment]
The polyphenylene sulfide that uses in embodiment and the comparative example is by following method manufacturing.
Production Example 1
Moisture sodium sulphite (Na packs in the polymerization tank with composition stirrer
2S5H
2O) 833mol, lithium chloride 830mol and N-N-methyl-2-2-pyrrolidone N-500L, decompression 145 ℃ of maintenances down, processed 1 hour.Then, reactive system is cooled to 45 ℃ after, add the 905mol dichlorobenzene, 260 ℃ of polymerizations 4 hours.The resultant that obtains is cleaned according to the N-N-methyl-2-2-pyrrolidone N-1 time of 5 times, 170 ℃ of hot water, the order of water 3 times, and 185 ℃ of dryings obtain polyphenylene sulfide (PPS-1) thus.This resin is at 300 ℃ of velocity of shear 200sec
-1In melt viscosity be 12Pas.
Composition beyond the polyphenylene sulfide that uses in embodiment and the comparative example is as follows.
[glass fibre]
GF-1: flat GF CSG 3PA-830S, day eastern weaving formula Co., Ltd. system, flat ratio: 0.25 (minor axis 7 μ m/ major diameters 28 μ m)
GF-2: short GF CS 03 JAFT591, オ one ウ エ Application ス コ one ニ Application グ system (circle shape cross section: diameter 10 μ m)
[inorganic filling material]
Plate-like fillers: powdered graphite CB-150, Japanese graphite Industrial Co., Ltd system
Embodiment 1
(1) manufacturing of resin combination
Mix the PPS-1 of 100 mass parts and the GF-1 of 25 mass parts, behind the use Henschel mixer uniform mixing, use double-shafted extruder (TEM35, Toshiba Machinery Co., Ltd.'s system), the bowl temperature of extrusion machine is set at 280～350 ℃, and melting mixing is made particle.
(2) the physical properties evaluation of polyphenyl thioether resin composition
Use 50 tons of injection molding machines (Corporation Japan Steel Works's system), to be modulated into according to the particle that above-mentioned (1) obtains with ASTM D790 is the testing plate (125 * 12.5 * 0.4～3.2mm) of benchmark, according to being the method for benchmark, measure bending elastic modulus (GPa) with ASTM D790.The results are shown in table 1.
(3) manufacturing of optical element
Use 50 tons of injection molding machines (Corporation Japan Steel Works's system) as forming mill, under the condition of 320 ℃ of resin temperatures, 135 ℃ of metal die temperature, the shaping particles that will obtain according to above-mentioned (1) is the light picker shell.
The size of the light picker shell that obtains is as follows.
Length: 48.7mm
Width: 37.80mm
Highly: 5.25mm
The part of wall thickness: 0.45mm (shadow area of the light emission direction of optical Pickup device) in shadow area accounts for 30%.The wall thickness of other parts mainly is 1.5～2mm, and a part (about number %) is that 4mm is thick.
(4) performance evaluation of optical element
(i) failing load test
The light picker shell that obtains in (3) is installed in (the デ ジ タ Le Off オ one ス ゲ one イ マ ダ of ジ DPS-20 Co., Ltd. system) in the rupture test machine, loads loading, measure the loading when destroying at pick-up (pick) central part.What obtain the results are shown in table 1.
(ii) initial stage optical axis deviation
Use autocollimator, on the authentic specimen of silica glass system,, on the light picker shell that in above-mentioned (3), obtains speculum is set with after the tilt adjustments to 0 of back light minute, under state, measure inclined light shaft by specularly reflected jiong back light with axle fixed main shaft and countershaft.What obtain the results are shown in table 1.
(iii) at 80 ℃ optical axis deviation
The light picker shell is in the evaluation of 80 ℃ optical axis deviation, use has the cylindrical furnace of diameter 20cm, to the device of the central vertical irradiating laser of stove with measure the determinator of the noncontact goniometry device of the catoptrical reflection angle of laser, the light picker shell that obtains in above-mentioned (3) is determined as follows.
Semi-transparent semi-reflecting lens is installed on the certain location of the light picker shell that obtains according to above-mentioned (3).Then, fixed light pick-up shell is so that semi-transparent semi-reflecting minute surface is a horizontality in above-mentioned stove, and (23 ℃) irradiating laser under the room temperature is measured reflection angle.Then, making furnace temperature is 80 ℃, keeps after 60 minutes, and irradiating laser is measured reflection angle once more.With the difference of reflection angle in 80 ℃ and the reflection angle in the room temperature (23 ℃) as optical axis deviation (angle, branch).The resolution of noncontact goniometry device is 0.02 minute.What obtain the results are shown in table 1.
Embodiment 2～4 and comparative example 1～4
Mix according to table 1, obtain particle and light picker shell similarly to Example 1.Estimate various physical propertiess similarly to Example 1 again.The results are shown in table 1.
Fig. 2 and Fig. 3 are the figure that concerns between expression thickness (mm) of molding and the bending elastic modulus (GPa).■ is the molding that the resin combination by embodiment 2 obtains, ◆ be the molding that the resin combination by comparative example 2 obtains, ▲ be the molding that the resin combination by embodiment 4 obtains, ● be the resin combination that obtains by comparative example 4 and the molding that obtains.
[table 1]
Utilizability on the industry
The present invention can provide the suitable used for optical elements resin forming product that is used as the shaping material of the optical system shell such as optical Pickup device.
Claims (4)
1. polyphenylene sulfide resin molded article, constitute by polyphenyl thioether resin composition, in the described polyphenyl thioether resin composition, with respect to 100 mass parts polyphenylene sulfides, be added with 10～200 mass parts and have the glass fibre in flat pattern cross section, the thickness of the thinner wall section of described molding is 0.3～1.4mm, and the flat ratio of described glass fibre is 0.1～0.5.
2. according to the polyphenylene sulfide resin molded article of claim 1 record,, also be added with inorganic filling material 0～200 mass parts with respect to 100 mass parts polyphenylene sulfides.
3. an optical element is made of claim 1 or 2 polyphenylene sulfide resin molded articles of being put down in writing.
4. a light picker shell is made of claim 1 or 2 polyphenylene sulfide resin molded articles of being put down in writing.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006258531 | 2006-09-25 | ||
| JP258531/2006 | 2006-09-25 | ||
| PCT/JP2007/067617 WO2008038512A1 (en) | 2006-09-25 | 2007-09-11 | Polyphenylene sulfide resin molded article |
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| Publication Number | Publication Date |
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| CN101553537A CN101553537A (en) | 2009-10-07 |
| CN101553537B true CN101553537B (en) | 2011-05-11 |
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| CN2007800354856A Expired - Fee Related CN101553537B (en) | 2006-09-25 | 2007-09-11 | Polyphenylene sulfide resin molded article |
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| Country | Link |
|---|---|
| JP (1) | JP5339912B2 (en) |
| KR (1) | KR20090064395A (en) |
| CN (1) | CN101553537B (en) |
| TW (1) | TW200836912A (en) |
| WO (1) | WO2008038512A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015024439A1 (en) | 2013-08-22 | 2015-02-26 | 东丽先端材料研究开发（中国）有限公司 | Polyphenylene sulfide resin composition, and moulding and manufacturing process for moulding thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| KR20100015680A (en) * | 2007-04-20 | 2010-02-12 | 이데미쓰 고산 가부시키가이샤 | Resin composition for electronic tag sealing, resin-sealed electronic tag and method for producing the same |
| JP2010043229A (en) * | 2008-08-18 | 2010-02-25 | Idemitsu Kosan Co Ltd | Thermally conductive resin composition and resin molding of the composition |
| CN103374216A (en) * | 2012-04-24 | 2013-10-30 | 苏州汉扬精密电子有限公司 | Glass fibre reinforced polyphenyl ether/polyphenylene sulphide composite material and preparation method for same |
| CN103374217A (en) * | 2012-04-24 | 2013-10-30 | 苏州汉扬精密电子有限公司 | Glass fibre reinforced polyphenyl ether resin |
| CN103509342A (en) * | 2012-06-28 | 2014-01-15 | 苏州汉扬精密电子有限公司 | Glass fiber reinforced polyphenylene sulfide resin and preparation method thereof |
| CN103509343A (en) * | 2012-06-28 | 2014-01-15 | 苏州汉扬精密电子有限公司 | Glass fiber reinforced polyphenylene sulfide/polyphenyl ether composite material and preparation method thereof |
| CN103627173A (en) * | 2012-08-24 | 2014-03-12 | 苏州汉扬精密电子有限公司 | Glass fiber strengthened polyphenylene sulfide/aromatic polyamide composite material and preparation method thereof |
| KR101674242B1 (en) * | 2013-03-15 | 2016-11-08 | 롯데첨단소재(주) | Thermoplastic Resine Composition Having Excellent EMI Shielding Property |
| CN104650584A (en) * | 2013-08-22 | 2015-05-27 | 东丽先端材料研究开发（中国）有限公司 | Polyphenylene sulfide resin composition and molded product thereof |
| CN103965632A (en) * | 2014-04-23 | 2014-08-06 | 安徽依采妮纤维材料科技有限公司 | Expanded graphite modified polyphenyl thioether material for car plastic parts |
| JP6896731B2 (en) | 2015-12-11 | 2021-06-30 | ティコナ・エルエルシー | Polyarylene sulfide composition |
| KR20180092824A (en) | 2015-12-11 | 2018-08-20 | 티코나 엘엘씨 | The crosslinkable polyarylene sulfide composition |
| US11383491B2 (en) | 2016-03-24 | 2022-07-12 | Ticona Llc | Composite structure |
| US11118053B2 (en) | 2018-03-09 | 2021-09-14 | Ticona Llc | Polyaryletherketone/polyarylene sulfide composition |
| KR20210148112A (en) | 2019-03-27 | 2021-12-07 | 도레이 카부시키가이샤 | Polyphenylene sulfide resin composition and molded article |
| CN111117244B (en) * | 2019-12-16 | 2022-08-05 | 中广核俊尔(浙江)新材料有限公司 | Special high-fluidity reinforced polyphenylene sulfide composite material for electronic tags, and preparation method and application thereof |
| KR102571437B1 (en) | 2021-07-19 | 2023-08-25 | 도레이첨단소재 주식회사 | Polyphenylenesulfide complex resin containing high content of filler and Molded article using the same |
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- 2007-09-11 JP JP2008536324A patent/JP5339912B2/en not_active Expired - Fee Related
- 2007-09-11 CN CN2007800354856A patent/CN101553537B/en not_active Expired - Fee Related
- 2007-09-11 WO PCT/JP2007/067617 patent/WO2008038512A1/en active Application Filing
- 2007-09-20 TW TW096135208A patent/TW200836912A/en unknown
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| JP2004176062A (en) * | 2002-11-15 | 2004-06-24 | Toray Ind Inc | Tablet for optical pickup part, optical pickup part obtained therefrom, and method for preparation of the same |
| JP2004196837A (en) * | 2002-12-16 | 2004-07-15 | Idemitsu Petrochem Co Ltd | Polyarylene sulfide resin composition and its molded article |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2015024439A1 (en) | 2013-08-22 | 2015-02-26 | 东丽先端材料研究开发（中国）有限公司 | Polyphenylene sulfide resin composition, and moulding and manufacturing process for moulding thereof |
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| JPWO2008038512A1 (en) | 2010-01-28 |
| KR20090064395A (en) | 2009-06-18 |
| TW200836912A (en) | 2008-09-16 |
| JP5339912B2 (en) | 2013-11-13 |
| WO2008038512A1 (en) | 2008-04-03 |
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