CN101550554A - Method for controlling quality of de-ionized water of electrolytic ozonizer - Google Patents
Method for controlling quality of de-ionized water of electrolytic ozonizer Download PDFInfo
- Publication number
- CN101550554A CN101550554A CNA2009100142868A CN200910014286A CN101550554A CN 101550554 A CN101550554 A CN 101550554A CN A2009100142868 A CNA2009100142868 A CN A2009100142868A CN 200910014286 A CN200910014286 A CN 200910014286A CN 101550554 A CN101550554 A CN 101550554A
- Authority
- CN
- China
- Prior art keywords
- water tank
- deionized water
- water
- deionization
- ionized water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Water Treatment By Electricity Or Magnetism (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
Abstract
The invention discloses a method for controlling the quality of de-ionized water of an electrolytic ozonizer. A de-ionized water tank is used for containing the de-ionized water, the electrolytic ozonizer is connected with the water tank, and a liquid level meter used for monitoring the liquid level is arranged in the electrolytic ozonizer. When the liquid level meter generates a water shortage signal, the de-ionized water is added into the de-ionized water tank; when the liquid level meter generates a full water signal, the de-ionized water is stopped being added into the de-ionized water tank. The invention is characterized in that the method further comprises the following steps: when the ion content of the de-ionized water in the de-ionized water tank increases, the de-ionized water is forcibly added into the de-ionized water tank for at least 5 minutes immediately and the original de-ionized water in the de-ionized water tank is drained so as to reduce the ion content of the de-ionized water. The method is cycled continuously and ensures that the de-ionized water, as raw material, can maintain excellent low electrical conductivity after a long-time operation of the electrolytic ozonizer, thus leading the electrolytic ozonizer to generate stable ozone output and achieving stable performance.
Description
Technical field:
The present invention relates to a kind of is the control method of quality of de-ionized water in the electrolysis ozone generator of raw material with the deionized water, belongs to the electrolysis ozone generator technical field.
Background technology:
At present, with the deionized water control method that the electrolysis ozone generator of raw material has multiple quality of de-ionized water, for example: Chinese patent application 97122126.X is arranged, and denomination of invention is the patent of invention of " electrolytic ozone generator ".Its control method to deionized water is: when liquidometer produces the lack of water signal, begin to add deionized water to the deionization water tank; When liquidometer produces the full water signal, stop to add deionized water to the deionization water tank.
Above-mentioned control method has following shortcoming:
1, electrolysis ozone generator is raw material with the deionized water, in operational process, be hydrogen and oxygen constantly with the deionized water electrolysis, deionized water is constantly consumed, the liquidometer monitoring liquid level that relies on the deionization bucket to be set up, only keep supplying the water yield of electrolysis generator demand, can't effectively control the water quality of deionized water.
2, the needed raw material of electrolysis ozone generator is a deionized water, but all ions in the water can't be removed fully with present scientific approach and technology, because electrolysis ozone generator is deionized water completely because of electrolysis consumed, other ions of these trace do not participate in electrolytic reaction consumption, make it along with the electrolysis generator running will exist always; Along with deionized water constantly consumes, will constantly add deionized water, also add other ions of trace simultaneously, so circulation causes the continuous cumulative rises of other ions of these trace, and then pollutes the water quality of deionized water, make the electrolysis ozone generator degradation, the ozone generation amount reduces.
3, ozone has extremely strong oxidation corrosion, and in operational process, most of material that contacts with ozone all can oxidizedly corrode, and generates oxide compound and impurity; Even after long-time the use, the material of contact other ions that also can dissociate, no matter produce in which kind of mode, when these materials with will pollute quality of de-ionized water after deionized water contacts.
4, when the extremely low liquid level of liquidometer monitoring, produce the lack of water signal, adding deionized water only dilutes the concentration of other ions, impurity and oxide compound in original deionized water, there is no and discharge original deionized water, wherein other ions, impurity and oxide compound are constantly increased, cause water quality constantly to worsen, influence the electrolysis ozone generator performance, and then the reduction of ozone generation amount, see the following form 1.
Table 1
The test result of the frequent switch running of existing ozonizer
Accumulated running time (hrs) | 1 | 75 | 150 | 200 | 250 | 300 |
Deionized water specific conductivity (us/cm) in the deionization water tank | 40 | 426 | 687 | 804 | 900 | 917 |
Ozone generating capacity (mg/hr) | 599 | 549 | 504 | 456 | 400 | 380 |
In sum, run down, cause ozonizer degradation problem no matter improve the adding up pollution of other ions, impurity and oxide compound that all can't avoid water quality to be subjected to trace fully in which way.
Summary of the invention:
The objective of the invention is to overcome the deficiency of above-mentioned prior art and provide a kind of control easy, cost is low, quality of de-ionized water control is good, realize commercial scale production easily, guarantee that electrolysis ozone generator is through long-play, still can keep good quality of de-ionized water, make electrolysis ozone generator produce stable ozone generation amount, and reach the control method of the quality of de-ionized water that is used for electrolysis ozone generator that makes the electrolysis ozone generator stable performance.
The present invention can reach by following measure: a kind of control method that is used for quality of de-ionized water of electrolytic ozonizer, with deionization water tank splendid attire deionized water, electrolysis ozone generator is connected with this water tank, be provided with the liquidometer of monitoring liquid level in it, when liquidometer produces the lack of water signal, begin to add deionized water to the deionization water tank, when liquidometer produces the full water signal, stop to add deionized water to the deionization water tank, it is characterized in that this method also comprises: the deionized water in the deionization water tank contains ionic weight and improves, begin to force to add deionized water immediately to deionization water tank at least 5 minutes, and the deionized water that deionization water tank Central Plains is had is discharged, make deionized water contain ionic weight and reduce, this method constantly circulates.
In order further to realize purpose of the present invention, it is described that totally the working hour reached setting-up time 5 hours to 500 hours at every turn when electrolysis ozone generator, begin to force to add deionized water immediately to deionization water tank at least 5 minutes, and the deionized water that deionization water tank Central Plains is had is discharged, make deionized water contain ionic weight and reduce, this method constantly circulates.
In order further to realize purpose of the present invention, it is described that totally the working hour reached setting-up time 20 hours to 200 hours at every turn when electrolysis ozone generator, begin to force to add deionized water immediately to deionization water tank 10 minutes to 60 minutes, and the deionized water that deionization water tank Central Plains is had is discharged, make deionized water contain ionic weight and reduce, this method constantly circulates.
In order further to realize purpose of the present invention, described deionization water tank internal conductance rate proofing unit, deionized water specific conductivity in the deionization water tank reaches at every turn sets specific conductivity 50us/cm to 1000us/cm, begin to force to add deionized water immediately to deionization water tank at least 5 minutes, and the deionized water that deionization water tank Central Plains is had is discharged, make deionized water contain ionic weight and reduce, this method constantly circulates.
Compared with the prior art the present invention has following positively effect:
1. because ion, impurity and oxide compound in the deionized water of adding constantly increase, when electrolysis ozone generator after every running for some time, water is changed in pressure.The old water that injects new deionized water and will constantly worsen is discharged, avoid worsening ion, impurity and oxide compound in the water quality, influence electrolysis and generate oxygen and ozone performance, good electrolytic environments of electrolysis generator and stable operation condition are provided, make electrolysis ozone generator produce stable ozone generation amount, and reach the stable performance electrolysis ozone generator, see the following form 2.
Table 2
Ozonizer has the test result of forcing to change the frequent switch running of water function:
2. the system configuration of utilizing original deionized water to add need not increase any excessive zero parts, and cost is low, level of automation is high, easy to maintenance.
Embodiment:
Embodiment 1: a kind of control method that is used for the quality of de-ionized water of electrolysis ozone generator, and deionization water tank splendid attire deionized water, the amount of being filled with water of deionization bucket is at 100ml, and electrolysis ozone generator is connected with this water tank, is provided with the liquidometer of monitoring liquid level in it; When liquidometer produces the lack of water signal, begin to add deionized water to the deionization water tank, to liquidometer generation full water signal, stop to add deionized water to the deionization water tank; In addition, reached setting-up time 5 hours when the electrolysis ozone generator accumulative total working hour at every turn, begin to force to add deionized water immediately to deionization water tank at least 5 minutes, and the deionized water that deionization water tank Central Plains is had is discharged, making deionized water contain ionic weight reduces, this method constantly circulates, and aforesaid method can adopt control device to control automatically.
The control method of this kind quality of de-ionized water was longer than the life-span of electrolysis ozone generator 10000 hours.
Embodiment 2: a kind of control method that is used for the quality of de-ionized water of electrolysis ozone generator, and deionization water tank splendid attire deionized water, the amount of being filled with water of deionization bucket is at 2000ml, and electrolysis ozone generator is connected with this water tank, is provided with the liquidometer of monitoring liquid level in it; When liquidometer produces the lack of water signal, begin to add deionized water to the deionization water tank, to liquidometer generation full water signal, stop to add deionized water to the deionization water tank; In addition, reached setting-up time 500 hours when the electrolysis ozone generator accumulative total working hour at every turn, begin to force to add deionized water immediately to deionization water tank at least 60 minutes, and the deionized water that deionization water tank Central Plains is had is discharged, making deionized water contain ionic weight reduces, this method constantly circulates, and aforesaid method can adopt control device to control automatically.
The control method of this kind quality of de-ionized water was longer than the life-span of electrolysis ozone generator 10000 hours.
Embodiment 3: a kind of control method that is used for the quality of de-ionized water of electrolysis ozone generator, and deionization water tank splendid attire deionized water, the amount of being filled with water of deionization bucket is at 1000ml, and electrolysis ozone generator is connected with this water tank, is provided with the liquidometer of monitoring liquid level in it; When liquidometer produces the lack of water signal, begin to add deionized water to the deionization water tank, to liquidometer generation full water signal, stop to add deionized water to the deionization water tank; In addition, reached setting-up time 200 hours when the electrolysis ozone generator accumulative total working hour at every turn, begin to force to add deionized water immediately to deionization water tank at least 20 minutes, and the deionized water that deionization water tank Central Plains is had is discharged, making deionized water contain ionic weight reduces, this method constantly circulates, and aforesaid method can adopt control device to control automatically.
The control method of this kind quality of de-ionized water was longer than the life-span of electrolysis ozone generator 10000 hours.
Embodiment 4: a kind of control method that is used for the quality of de-ionized water of electrolysis ozone generator, and deionization water tank splendid attire deionized water, the amount of being filled with water of deionization bucket is at 500ml, and electrolysis ozone generator is connected with this water tank, is provided with the liquidometer of monitoring liquid level in it; When liquidometer produces the lack of water signal, begin to add deionized water to the deionization water tank, to liquidometer generation full water signal, stop to add deionized water to the deionization water tank; In addition, be provided with the specific conductivity proofing unit in the deionization water tank, deionized water specific conductivity in the deionization water tank reaches at every turn sets specific conductivity 50us/cm, begin to force to add deionized water immediately to deionization water tank at least 5 minutes, and the deionized water that deionization water tank Central Plains is had is discharged, make deionized water contain ionic weight and reduce, this method constantly circulates, and aforesaid method can adopt control device to control automatically.
The control method of this kind quality of de-ionized water was longer than the life-span of electrolysis ozone generator 10000 hours.
Embodiment 5: a kind of control method that is used for the quality of de-ionized water of electrolysis ozone generator, and deionization water tank splendid attire deionized water, the amount of being filled with water of deionization bucket is at 1500ml, and electrolysis ozone generator is connected with this water tank, is provided with the liquidometer of monitoring liquid level in it; When liquidometer produces the lack of water signal, begin to add deionized water to the deionization water tank, to liquidometer generation full water signal, stop to add deionized water to the deionization water tank; In addition, be provided with the specific conductivity proofing unit in the deionization water tank, deionized water specific conductivity in the deionization water tank reaches at every turn sets specific conductivity 1000us/cm, begin to force to add deionized water immediately to deionization water tank at least 60 minutes, and the deionized water that deionization water tank Central Plains is had is discharged, make deionized water contain ionic weight and reduce, this method constantly circulates, and aforesaid method can adopt control device to control automatically.
The control method of this kind quality of de-ionized water was longer than the life-span of electrolysis ozone generator 10000 hours.
Embodiment 6: a kind of control method that is used for the quality of de-ionized water of electrolysis ozone generator, and deionization water tank splendid attire deionized water, the amount of being filled with water of deionization bucket is at 800ml, and electrolysis ozone generator is connected with this water tank, is provided with the liquidometer of monitoring liquid level in it; When liquidometer produces the lack of water signal, begin to add deionized water to the deionization water tank, to liquidometer generation full water signal, stop to add deionized water to the deionization water tank; In addition, be provided with the specific conductivity proofing unit in the deionization water tank, deionized water specific conductivity in the deionization water tank reaches at every turn sets specific conductivity 300us/cm, begin to force to add deionized water immediately to deionization water tank at least 20 minutes, and the deionized water that deionization water tank Central Plains is had is discharged, make deionized water contain ionic weight and reduce, this method constantly circulates.
The control method of this kind quality of de-ionized water was longer than the life-span of electrolysis ozone generator 10000 hours.
Claims (4)
1, a kind of control method that is used for quality of de-ionized water of electrolytic ozonizer, with deionization water tank splendid attire deionized water, electrolysis ozone generator is connected with this water tank, be provided with the liquidometer of monitoring liquid level in it, when liquidometer produces the lack of water signal, begin to add deionized water to the deionization water tank, when liquidometer produces the full water signal, stop to add deionized water to the deionization water tank, it is characterized in that this method also comprises: the deionized water in the deionization water tank contains ionic weight and improves, begin to force to add deionized water immediately to deionization water tank at least 5 minutes, and the deionized water that deionization water tank Central Plains is had is discharged, make deionized water contain ionic weight and reduce, this method constantly circulates.
2, according to the described a kind of control method that is used to control quality of de-ionized water of electrolytic ozonizer of claim 1, it is characterized in that describedly the working hour reaching setting-up time 5 hours to 500 hours when electrolysis ozone generator accumulative total at every turn, begin to force to add deionized water immediately to deionization water tank at least 5 minutes, and the deionized water that deionization water tank Central Plains is had is discharged, make deionized water contain ionic weight and reduce, this method constantly circulates.
3, according to the described a kind of control method that is used to control quality of de-ionized water of electrolytic ozonizer of claim 2, it is characterized in that describedly the working hour reaching setting-up time 20 hours to 200 hours when electrolysis ozone generator accumulative total at every turn, begin to force to add deionized water immediately to deionization water tank 10 minutes to 60 minutes, and the deionized water that deionization water tank Central Plains is had is discharged, make deionized water contain ionic weight and reduce, this method constantly circulates.
4, according to the described a kind of control method that is used to control quality of de-ionized water of electrolytic ozonizer of claim 1, it is characterized in that being provided with the specific conductivity proofing unit in the described deionization water tank, deionized water specific conductivity in the deionization water tank reaches at every turn sets specific conductivity 50us/cm to 1000us/cm, begin to force to add deionized water immediately to deionization water tank at least 5 minutes, and the deionized water that deionization water tank Central Plains is had is discharged, make deionized water contain ionic weight and reduce, this method constantly circulates.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNA2009100142868A CN101550554A (en) | 2009-02-20 | 2009-02-20 | Method for controlling quality of de-ionized water of electrolytic ozonizer |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNA2009100142868A CN101550554A (en) | 2009-02-20 | 2009-02-20 | Method for controlling quality of de-ionized water of electrolytic ozonizer |
Publications (1)
Publication Number | Publication Date |
---|---|
CN101550554A true CN101550554A (en) | 2009-10-07 |
Family
ID=41155037
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNA2009100142868A Pending CN101550554A (en) | 2009-02-20 | 2009-02-20 | Method for controlling quality of de-ionized water of electrolytic ozonizer |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN101550554A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103268110A (en) * | 2013-05-27 | 2013-08-28 | 福耀集团北京福通安全玻璃有限公司 | Deionized water automatic replacing device |
CN113502492A (en) * | 2021-05-31 | 2021-10-15 | 江西强盛科技有限公司 | Garbage transfer station disinfection deodorization is with low pressure ozone preparation equipment of hydrolysising convenient to operation |
-
2009
- 2009-02-20 CN CNA2009100142868A patent/CN101550554A/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103268110A (en) * | 2013-05-27 | 2013-08-28 | 福耀集团北京福通安全玻璃有限公司 | Deionized water automatic replacing device |
CN113502492A (en) * | 2021-05-31 | 2021-10-15 | 江西强盛科技有限公司 | Garbage transfer station disinfection deodorization is with low pressure ozone preparation equipment of hydrolysising convenient to operation |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Morel et al. | Microbial desalination cells packed with ion-exchange resin to enhance water desalination rate | |
Zhang et al. | Accelerating anodic biofilms formation and electron transfer in microbial fuel cells: role of anionic biosurfactants and mechanism | |
CN100545321C (en) | Graphite felt surface modifying method and modified graphite felt | |
Wang et al. | The influence of Ferric ion contamination on the solid polymer electrolyte water electrolysis performance | |
WO2007126818A3 (en) | Single crystal diamond electrode and electrolytic cell comprising such electrode | |
CN104152905A (en) | Acidic copper chloride etching liquid electrolytic regeneration recycling and copper plate recovery device and method | |
CN103080019A (en) | Electrolytic device and method for producing weakly acidic electrolysed water | |
CN101250744A (en) | Method for erosion of supervoltage high specific volume anode foil | |
CN103663634B (en) | A kind of Waste Water Treatment adopting Based on Three-dimensional Electrode Method | |
CN201785505U (en) | NaCIO generator | |
CN112714803A (en) | Plating solution production and regeneration process and device for insoluble anode acid copper electroplating | |
Huang et al. | Long-term electricity generation and denitrification performance of MFCs with different exchange membranes and electrode materials | |
Zhang et al. | Anolyte recirculation effects in buffered and unbuffered single-chamber air-cathode microbial fuel cells | |
CN110550704A (en) | method for realizing ultralow-energy-consumption continuous desalting by using mixed fluid electrode material | |
CN101550554A (en) | Method for controlling quality of de-ionized water of electrolytic ozonizer | |
CN203976921U (en) | The circulation of acid copper chloride etching liquid electrolytic regeneration and copper coin retrieving arrangement | |
CN101748428B (en) | Preparation method for preparing expanded graphite modified composite electrode of hydrogen peroxide | |
KR20130077164A (en) | Water treatment apparatus for fuel cell | |
CN203307434U (en) | Regeneration treatment system of acidic etching waste liquid | |
CN110289171A (en) | A kind of manufacturing method of without phosphorus reaming aluminum electrolytic capacitor electrode foil | |
CN113078331A (en) | Electrolyte of hydrogen battery and application thereof | |
CN207659531U (en) | A kind of javelle water process units | |
Zhao et al. | Electrochemical Degradation of 4, 4’-(propane-2, 2-diyl) diphenol in Water with CeO2/ß-PbO2/Ti Electrode | |
CN212076542U (en) | Catalyst generator for advanced sewage treatment | |
CN214004135U (en) | Electrolysis device for preparing hydrogen-rich water |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
WD01 | Invention patent application deemed withdrawn after publication |
Open date: 20091007 |