CN101550379A - Environment-friendly plant cleaning agent and processing method thereof - Google Patents
Environment-friendly plant cleaning agent and processing method thereof Download PDFInfo
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- CN101550379A CN101550379A CNA2009100985888A CN200910098588A CN101550379A CN 101550379 A CN101550379 A CN 101550379A CN A2009100985888 A CNA2009100985888 A CN A2009100985888A CN 200910098588 A CN200910098588 A CN 200910098588A CN 101550379 A CN101550379 A CN 101550379A
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- 239000012459 cleaning agent Substances 0.000 title claims abstract description 32
- 238000003672 processing method Methods 0.000 title 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 45
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 41
- 239000000341 volatile oil Substances 0.000 claims abstract description 31
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 30
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 20
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 20
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 16
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 15
- 238000004140 cleaning Methods 0.000 claims abstract description 12
- 238000000034 method Methods 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 241000196324 Embryophyta Species 0.000 claims description 64
- -1 acyl diethanolamine Chemical compound 0.000 claims description 35
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 24
- 244000060011 Cocos nucifera Species 0.000 claims description 24
- 238000004821 distillation Methods 0.000 claims description 24
- 239000000463 material Substances 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 21
- 239000003921 oil Substances 0.000 claims description 19
- 238000003756 stirring Methods 0.000 claims description 15
- 235000017550 sodium carbonate Nutrition 0.000 claims description 14
- 239000002002 slurry Substances 0.000 claims description 13
- 235000013311 vegetables Nutrition 0.000 claims description 13
- 239000007788 liquid Substances 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 10
- 238000001704 evaporation Methods 0.000 claims description 8
- 230000008020 evaporation Effects 0.000 claims description 8
- 241000911175 Citharexylum caudatum Species 0.000 claims description 6
- 244000068988 Glycine max Species 0.000 claims description 6
- 235000010469 Glycine max Nutrition 0.000 claims description 6
- 240000002657 Thymus vulgaris Species 0.000 claims description 6
- 235000007303 Thymus vulgaris Nutrition 0.000 claims description 6
- 239000006260 foam Substances 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 239000001257 hydrogen Substances 0.000 claims description 6
- 239000000177 juniperus communis l. berry Substances 0.000 claims description 6
- 230000001105 regulatory effect Effects 0.000 claims description 6
- 238000012360 testing method Methods 0.000 claims description 6
- 239000001585 thymus vulgaris Substances 0.000 claims description 6
- 241000468081 Citrus bergamia Species 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 239000005662 Paraffin oil Substances 0.000 claims description 5
- 239000012153 distilled water Substances 0.000 claims description 5
- 235000013399 edible fruits Nutrition 0.000 claims description 5
- 238000000605 extraction Methods 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 5
- 238000011010 flushing procedure Methods 0.000 claims description 5
- 239000012535 impurity Substances 0.000 claims description 5
- 238000011068 loading method Methods 0.000 claims description 5
- 238000000199 molecular distillation Methods 0.000 claims description 5
- 230000008569 process Effects 0.000 claims description 5
- 238000002791 soaking Methods 0.000 claims description 5
- 239000007921 spray Substances 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 3
- 238000011049 filling Methods 0.000 claims 1
- 150000002431 hydrogen Chemical class 0.000 claims 1
- 241001465754 Metazoa Species 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 3
- 231100000331 toxic Toxicity 0.000 abstract description 2
- 230000002588 toxic effect Effects 0.000 abstract description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 abstract 1
- 229940043237 diethanolamine Drugs 0.000 abstract 1
- 230000000694 effects Effects 0.000 abstract 1
- 230000007794 irritation Effects 0.000 abstract 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 7
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- RNMDNPCBIKJCQP-UHFFFAOYSA-N 5-nonyl-7-oxabicyclo[4.1.0]hepta-1,3,5-trien-2-ol Chemical compound C(CCCCCCCC)C1=C2C(=C(C=C1)O)O2 RNMDNPCBIKJCQP-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 238000007599 discharging Methods 0.000 description 3
- 238000005194 fractionation Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 208000027418 Wounds and injury Diseases 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000013043 chemical agent Substances 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 208000014674 injury Diseases 0.000 description 2
- 231100000957 no side effect Toxicity 0.000 description 2
- 231100000252 nontoxic Toxicity 0.000 description 2
- 230000003000 nontoxic effect Effects 0.000 description 2
- 239000000419 plant extract Substances 0.000 description 2
- 235000019633 pungent taste Nutrition 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 241000675108 Citrus tangerina Species 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000007059 acute toxicity Effects 0.000 description 1
- 231100000403 acute toxicity Toxicity 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000011538 cleaning material Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000693 micelle Substances 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000012466 permeate Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- 239000012855 volatile organic compound Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
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- Detergent Compositions (AREA)
Abstract
The invention discloses a plant environment-friendly cleaning agent, which is prepared from the following raw materials in percentage by weight: 20-30% of fatty alcohol-polyoxyethylene ether (with the polymerization degree n of 6-18), 20-30% of cocoyl diethanol amine essential oil, 3-8% of sodium carbonate, 8-13% of propylene glycol and the balance of softened water; and a method for processing the same. The cleaning agent disclosed by the invention is safe to people, animals and surrounding working environments, free of toxic and side effects, free of irritation, good in cleaning performance, wide in application range and potential in economic benefits.
Description
Technical field
The present invention relates to a kind of plant environment-friendly type cleaning agent and working method thereof.
Background technology
The cleaning agent formula of present industrial use belongs to the chemical agent prescription mostly, belongs to strong acid, highly basic or leaning solvent.Have following shortcoming during use: when use (1) security not enough, liquid has corrosive nature to cleaning material surface, toxic to human body, some clean-out system is inflammable and explosive.(2) damage ratio to environment is bigger, and atmosphere, water resources are had biological accumulation.(3) cleaning performance is lower, and life cycle is short.(4) remained on surface or uniform passivation.(5) foam is higher, and rust-preventing characteristic is poor.
The aq. type clean-out system of up-to-date research and development also is, and to be that main raw material is composite with the chemical agent form, and exist drawback too: the scope of application that has is narrow, can only be applicable to a certain class field, a certain class material surface; The meeting injury human skin that has; The meeting injury clean surface material that has; The performance that has is gentle but cleaning performance is not good.
Announced " a kind of water-solubility printing ink washing agent and preparation technology thereof " patent of invention on January 26th, 2005 as Patent Office of the People's Republic of China, the patent No.: 03119639.X, the water-soluble washing agent that this technical scheme has adopted components such as polyoxyethylene octyl phenolic ether or polyoxyethylene nonylphenol ether, trolamine, ethylene glycol butyl ether (ethylene glycol monobutyl ether), soft water to make.Along with the continuous appearance of cleaning agent formula, we find that present used clean-out system adopts polyoxyethylene octyl phenolic ether or polyoxyethylene nonylphenol ether more, and these compounds have pungency to skin; And this raw material that the compound of acute toxicity is arranged as cleaning agent formula of ethylene glycol monobutyl ether, ethylene glycol butyl ether is that ethylene glycol monobutyl ether is as solublization, its solublization shows: when surfactant polyoxyethylene octyl phenolic ether or polyoxyethylene nonylphenol ether form micella in the aqueous solution after, have organic solubleness insoluble or that be slightly soluble in water is enlarged markedly.But cause murder by poisoning to human body and environment.
Summary of the invention
The object of the present invention is to provide a kind of plant environment-friendly type cleaning agent and working method thereof, clean-out system of the present invention all has safety, no side effects to people, animal and surrounding working environment, nonirritant, cleaning performance is good, and is applied widely, has the potential economic benefit.
In order to achieve the above object, technical scheme of the present invention is:
Plant environment-friendly type cleaning agent of the present invention is removed greasy dirt mechanism: adopt the clean-out system of low surface tension, by acting on the interface that is cleaned thing surface and contact thereof, dirt removal.On the interface of surface that is cleaned and the schmutzband of being cleaned thing, contact cleaning, can on surface to be cleaned and dirt interface, soak into diffusion, play a part to peel off from being cleaned the schmutzband on thing surface.Because the surface tension of dirt generally than big many of 30N/m, adds clean-out system of the present invention, and surface tension is dropped to below the 20mN/m, the aqueous solution of clean-out system is easy to the surface removal dirt that is being cleaned.
A kind of plant environment-friendly type cleaning agent, it is formulated by following weight percentages:
Fatty alcohol-polyoxyethylene ether (polymerization degree n is 6～18) 20%～30%;
Coconut acyl diethanolamine volatile oil 20%～30%;
Yellow soda ash 3%～8%;
Propylene glycol 8%～13%;
Surplus is a softening water.
Fatty alcohol-polyoxyethylene ether is bought in Guangzhou Yue Ji chemical industry company limited, and model is a kind of among AEO7, AEO9 or the AEO37.
The weight percent of described each raw material is:
Fatty alcohol-polyoxyethylene ether 25%
Coconut acyl diethanolamine volatile oil 25%;
Yellow soda ash 5%;
Propylene glycol 10%;
Surplus is a softening water.
Described coconut acyl diethanolamine volatile oil is formulated by the plant material of following weight per-cent: juniper berry 30%, Thymus vulgaris 40%, soybean leaf 30%.
Described coconut acyl diethanolamine volatile oil is formulated by the plant material of following weight per-cent: W-Gum 40%, Citrus bergamia fruit 20%, plam oil 40%.
A kind of working method of plant environment-friendly type cleaning agent comprises the steps:
(1) plant material cleans: with weight percent: the plant material surface impurity dirt 0.5%Na of juniper berry 30%, Thymus vulgaris 40%, soybean leaf 30% or W-Gum 40%, Citrus bergamia fruit 20%, plam oil 40%
2CO
3Solution soaking is cleaned 1～3min, and it is stand-by that the clear water rinsing drains the back.
(2) plant pulverising mill oil: the plant material after will cleaning is earlier poured in the loading hopper, and the rotation by mill is constantly rotated plant on mill, and rotating speed is controlled at 60～80 rev/mins, makes to flow out vegetable slurries on the mill.Simultaneously, open spray water oil flushing is got off, flow in the Receiving bin, stir into the vegetable slurries raw material by filtration.
(3) adopt molecular distillation equipment and evaporation equipment, wherein adopt paraffin oil to add thermal distillation, distillation temperature: 30～45 ℃, the time: 2～3 hours, vacuum tightness was the 0.5-1.8 mmhg, distilled out coconut acyl diethanolamine essential oil mixture.
(4) plant environment-friendly type cleaning agent complex process
A) add softening water in mixing tank, water hardness is controlled between 10～100ppm.Temperature remains on 15～25 ℃;
B) in stainless reactor with a small amount of dissolved in distilled water fatty alcohol-polyoxyethylene ether (polymerization degree n is 6～18), fatty alcohol-polyoxyethylene ether (polymerization degree n is 6～18) after slowly will dissolving successively then, yellow soda ash, propylene glycol join in the mixing tank, slowly stir, to prevent to produce foam, fully stirred 16～26 minutes, mix, make the clean-out system intermediate liquid;
C) then the coconut acyl diethanolamine essential oil mixture of plant distillation extraction is added in the clean-out system intermediate liquid, wherein the weight percent that adds between each component is: polyoxyethylene straight-chain alcohol ethoxylate (polymerization degree n is 6～18) 20%～30%, coconut acyl diethanolamine volatile oil 20%～30%, yellow soda ash 3%～8%, propylene glycol 8%～13%, surplus are softening water; Stir mixed in 18～25 minutes after, potential of hydrogen is also regulated in test, pH is 7～10 in control, makes plant environment-friendly type cleaning agent.
Beneficial effect of the present invention is: the present invention is to be host with the volatile oil of plant extract and non-ionic type polyoxyethylene straight-chain alcohol ethoxylate (polymerization degree n is 6～18) tensio-active agent, at the auxilliary aq. type clean-out system that adds activation permeate agent and solubilizing agent.Mainly utilize the amphipathic characteristic of polyoxyethylene straight-chain alcohol ethoxylate (polymerization degree n is 6～18) nonionogenic tenside, promptly in the plant type surfactant molecule, there are hydrophilic group and hydrophobic group simultaneously, has adsorption, in solution, play micelle and turn usefulness into, reduce surface tension, thereby have very strong penetrating power, have functions such as emulsification, wetting, diffusion, directly being penetrated into the contact surface of greasy dirt and clean surface, is the actives of clean-out system.
Coconut acyl diethanolamine among the present invention belongs to nonionogenic tenside, water soluble, have stronger latherability, detersive power and soak into ability, make clean-out system of the present invention have stronger cleansing power, also have dispersiveness preferably in addition, make that greasy dirt can be good at coming off from scavenger surface.It also has certain antirust power, after the metallic surface is cleaned, has antirust function.
Plant environment-friendly type cleaning agent of the present invention does not contain ethylene glycol monobutyl ether class toxic compounds, or this class of polyoxyethylene nonylphenol ether has pungent to skin.
Plant environment-friendly type cleaning agent of the present invention has following characteristics:
(1) pure plant extract clean-out system main component does not contain strong acid, highly basic, etching reagent, phosphoric acid salt, oranges and tangerines derivative, muriate, petroleum distillate, the butyl-like compound.
(2) nontoxic to environment, fully biodegradable.
(3) nontoxic, do not contain cancer-causing chemicals, not carcinogenic.
(4) content of volatile organic compound is almost nil.
(5) ozone depletion potential is zero.
(6) do not contain the alkylphenol polyoxyethylene compounds, aromatic solvent, organic chloride, butyl cellosolve etc. in the prescription.
(7) harmless to surfaces such as rubber, plastics and paint.
(8) human body skin there is not any pungency.
(9) cleaning performance is good, and noresidue after the metallic surface is cleaned, has antirust function.
In sum: clean-out system of the present invention all has safety to people, animal and surrounding working environment, no side effects, and nonirritant, cleaning performance is good, and is applied widely, has the potential economic benefit.The present invention can be used for the clean-out operation in fields such as automobile, aviation, oil mining, communications and transportation, electric power, government, medical treatment.
Embodiment
Embodiment 1
A kind of plant environment-friendly type cleaning agent of present embodiment indication comprises the steps:
(1) plant material cleans: with weight percent: the plant material of juniper berry 30%, Thymus vulgaris 40%, soybean leaf 30%, surface impurity dirt 0.5%Na
2CO
3Solution soaking is cleaned 1～3min, and it is stand-by that the clear water rinsing drains the back.
(2) plant pulverising mill oil: the plant material after will cleaning is earlier poured in the loading hopper, and the rotation by mill is constantly rotated plant on mill, and rotating speed is controlled at 60～80 rev/mins, makes to flow out vegetable slurries on the mill.Simultaneously, open spray water oil flushing is got off, flow in the Receiving bin, stir into the vegetable slurries raw material by filtration.
(3) adopt U.S. Pope molecular distillation equipment and evaporation equipment, wherein adopt paraffin oil to add thermal distillation, distillation temperature: 30～45 ℃, the time: 2～3 hours, vacuum tightness was the 0.5-1.8 mmhg, distilled out coconut acyl diethanolamine essential oil mixture.
Vegetable slurries enters in the distiller under vacuum state, and is launched into film rapidly, down to water surface of evaporation.
Heated wall and high vacuum are ordered about more volatile composition (volatile oil) to approaching built-in condenser, and not volatile composition (residue) continues to flow back to matrass along distillation column simultaneously.
The fraction of separating like this exports out by independent discharging.According to the application of volatile oil, required product or distillment, remaining fraction give over to distillation next time, reuse.Thermal Release Technology is isolated the plant essence oil production, and this fractionation by distillation efficient height can reach more than 20～30%.
(4) plant environment-friendly type cleaning agent complex process
A) add softening water in mixing tank, water hardness is controlled between 10～100ppm.Temperature remains on 15～25 ℃;
B) in stainless reactor with a small amount of dissolved in distilled water fatty alcohol-polyoxyethylene ether (polymerization degree n is 6～18), fatty alcohol-polyoxyethylene ether (polymerization degree n is 6～18) after slowly will dissolving successively then, yellow soda ash, propylene glycol join in the mixing tank, slowly stir, to prevent to produce foam, fully stirred 16～26 minutes, mix, make the clean-out system intermediate liquid;
C) then the coconut acyl diethanolamine essential oil mixture of plant distillation extraction is added in the clean-out system intermediate liquid, wherein the weight percent that adds between each component is: fatty alcohol-polyoxyethylene ether, model is AEO7, buy in Guangzhou Yue Ji chemical industry company limited, 20%, coconut acyl diethanolamine volatile oil 30%, yellow soda ash 3%, propylene glycol 13%, surplus are softening water; Stir mixed in 18～25 minutes after, potential of hydrogen is also regulated in test, pH is 7～10 in control, makes plant environment-friendly type cleaning agent.
Embodiment 2
A kind of plant environment-friendly type cleaning agent of present embodiment indication comprises the steps:
(1) plant material cleans: with weight percent: the plant material of W-Gum 40%, Citrus bergamia fruit 20%, plam oil 40%, surface impurity dirt 0.5%Na
2CO
3Solution soaking is cleaned 1～3min, and it is stand-by that the clear water rinsing drains the back.
(2) plant pulverising mill oil: the plant material after will cleaning is earlier poured in the loading hopper, and the rotation by mill is constantly rotated plant on mill, and rotating speed is controlled at 60～80 rev/mins, makes to flow out vegetable slurries on the mill.Simultaneously, open spray water oil flushing is got off, flow in the Receiving bin, stir into the vegetable slurries raw material by filtration.
(3) adopt U.S. Pope molecular distillation equipment and evaporation equipment, wherein adopt paraffin oil to add thermal distillation, distillation temperature: 30～45 ℃, the time: 2～3 hours, vacuum tightness was the 0.5-1.8 mmhg, distilled out coconut acyl diethanolamine essential oil mixture.Vegetable slurries enters in the distiller under vacuum state, and is launched into film rapidly, down to water surface of evaporation.
Heated wall and high vacuum are ordered about more volatile composition (volatile oil) to approaching built-in condenser, and not volatile composition (residue) continues to flow back to matrass along distillation column simultaneously.
The fraction of separating like this exports out by independent discharging.According to the application of volatile oil, required product or distillment, remaining fraction give over to distillation next time, reuse.Thermal Release Technology is isolated the plant essence oil production, and this fractionation by distillation efficient height can reach more than 20～30%.
(4) plant environment-friendly type cleaning agent complex process
A) add softening water in mixing tank, water hardness is controlled between 10～100ppm.Temperature remains on 15～25 ℃;
B) in stainless reactor with a small amount of dissolved in distilled water fatty alcohol-polyoxyethylene ether (polymerization degree n is 6～18), fatty alcohol-polyoxyethylene ether (polymerization degree n is 6～18) after slowly will dissolving successively then, yellow soda ash, propylene glycol join in the mixing tank, slowly stir, to prevent to produce foam, fully stirred 16～26 minutes, mix, make the clean-out system intermediate liquid;
C) then the coconut acyl diethanolamine essential oil mixture of plant distillation extraction is added in the clean-out system intermediate liquid, wherein the weight percent that adds between each component is: fatty alcohol-polyoxyethylene ether, model is AEO9, buy in Guangzhou Yue Ji chemical industry company limited, 30%, coconut acyl diethanolamine volatile oil 20%, yellow soda ash 8%, propylene glycol 8%, surplus are softening water; Stir mixed in 18～25 minutes after, potential of hydrogen is also regulated in test, pH is 7～10 in control, makes plant environment-friendly type cleaning agent.
Embodiment 3
A kind of plant environment-friendly type cleaning agent of present embodiment indication comprises the steps:
(1) plant material cleans: with weight percent: the plant material of juniper berry 30%, Thymus vulgaris 40%, soybean leaf 30%, surface impurity dirt 0.5%Na
2CO
3Solution soaking is cleaned 1～3min, and it is stand-by that the clear water rinsing drains the back.
(2) plant pulverising mill oil: the plant material after will cleaning is earlier poured in the loading hopper, and the rotation by mill is constantly rotated plant on mill, and rotating speed is controlled at 60～80 rev/mins, makes to flow out vegetable slurries on the mill.Simultaneously, open spray water oil flushing is got off, flow in the Receiving bin, stir into the vegetable slurries raw material by filtration.
(3) adopt U.S. Pope molecular distillation equipment and evaporation equipment, wherein adopt paraffin oil to add thermal distillation, distillation temperature: 30～45 ℃, the time: 2～3 hours, vacuum tightness was the 0.5-1.8 mmhg, distilled out coconut acyl diethanolamine essential oil mixture.
Vegetable slurries enters in the distiller under vacuum state, and is launched into film rapidly, down to water surface of evaporation.
Heated wall and high vacuum are ordered about more volatile composition (volatile oil) to approaching built-in condenser, and not volatile composition (residue) continues to flow back to matrass along distillation column simultaneously.
The fraction of separating like this exports out by independent discharging.According to the application of volatile oil, required product or distillment, remaining fraction give over to distillation next time, reuse.Thermal Release Technology is isolated the plant essence oil production, and this fractionation by distillation efficient height can reach more than 20～30%.
(4) plant environment-friendly type cleaning agent complex process
A) add softening water in mixing tank, water hardness is controlled between 10～100ppm.Temperature remains on 15～25 ℃;
B) in stainless reactor with a small amount of dissolved in distilled water fatty alcohol-polyoxyethylene ether (polymerization degree n is 6～18), fatty alcohol-polyoxyethylene ether (polymerization degree n is 6～18) after slowly will dissolving successively then, yellow soda ash, propylene glycol join in the mixing tank, slowly stir, to prevent to produce foam, fully stirred 16～26 minutes, mix, make the clean-out system intermediate liquid;
C) then the coconut acyl diethanolamine essential oil mixture of plant distillation extraction is added in the clean-out system intermediate liquid, wherein the weight percent that adds between each component is: fatty alcohol-polyoxyethylene ether, model is AEO37, buy in Guangzhou Yue Ji chemical industry company limited, 25%, coconut acyl diethanolamine volatile oil 25%, yellow soda ash 5%, propylene glycol 10%, surplus are softening water; Stir mixed in 18～25 minutes after, potential of hydrogen is also regulated in test, pH is 7～10 in control, makes plant environment-friendly type cleaning agent.
Claims (5)
1, a kind of plant environment-friendly type cleaning agent is characterized in that, it is formulated by following weight percentages:
Fatty alcohol-polyoxyethylene ether 20%～30%;
Coconut acyl diethanolamine volatile oil 20%～30%;
Yellow soda ash 3%～8%;
Propylene glycol 8%～13%;
Surplus is a softening water.
2, plant environment-friendly type cleaning agent according to claim 1 is characterized in that, the weight percent of described each raw material is:
Fatty alcohol-polyoxyethylene ether 25%;
Coconut acyl diethanolamine volatile oil 25%;
Yellow soda ash 5%;
Propylene glycol 10%;
Surplus is a softening water.
3, plant environment-friendly type cleaning agent according to claim 2 is characterized in that, described coconut acyl diethanolamine volatile oil is formulated by the plant material of following weight per-cent: juniper berry 30%, Thymus vulgaris 40%, soybean leaf 30%.
4, plant environment-friendly type cleaning agent according to claim 2 is characterized in that, described coconut acyl diethanolamine volatile oil is formulated by the plant material of following weight per-cent: W-Gum 40%, Citrus bergamia fruit 20%, plam oil 40%.
5, the working method of plant environment-friendly type cleaning agent according to claim 1 is characterized in that, comprises the steps:
(1) plant material cleans: with weight percent: the plant material surface impurity dirt 0.5%Na of juniper berry 30%, Thymus vulgaris 40%, soybean leaf 30% or W-Gum 40%, Citrus bergamia fruit 20%, plam oil 40%
2CO
3Solution soaking is cleaned 1～3min, and it is stand-by that the clear water rinsing drains the back;
(2) plant pulverising mill oil: the plant material after will cleaning is earlier poured in the loading hopper, and the rotation by mill is constantly rotated plant on mill, and rotating speed is controlled at 60～80 rev/mins, makes to flow out vegetable slurries on the mill; Simultaneously, open spray water oil flushing is got off, flow in the Receiving bin, stir into the vegetable slurries raw material by filtration;
(3) adopt molecular distillation equipment and evaporation equipment, wherein adopt paraffin oil to add thermal distillation, distillation temperature: 30～45 ℃, the time: 2～3 hours, vacuum tightness was the 0.5-1.8 mmhg, distilled out coconut acyl diethanolamine essential oil mixture;
(4) plant environment-friendly type cleaning agent complex process:
A) add softening water in mixing filling, water hardness is controlled between 10～100ppm, and temperature remains on 15～25 ℃;
B) in stainless reactor with a small amount of dissolved in distilled water fatty alcohol-polyoxyethylene ether (polymerization degree n is 6～18), fatty alcohol-polyoxyethylene ether (polymerization degree n is 6～18) after slowly will dissolving successively then, yellow soda ash, propylene glycol joins in the mixing tank, slowly stir,, fully stirred 16～26 minutes to prevent to produce foam, mix, make the clean-out system intermediate liquid;
C) then the coconut acyl diethanolamine essential oil mixture of plant distillation extraction is added in the clean-out system intermediate liquid, wherein the weight percent that adds between each component is: fatty alcohol-polyoxyethylene ether (polymerization degree n is 6～18) 20%～30%, coconut acyl diethanolamine volatile oil 20%～30%, yellow soda ash 3%～8%, propylene glycol 8%～13%, surplus are softening water; Stir mixed in 18～25 minutes after, potential of hydrogen acid is also regulated in test, potential of hydrogen is also regulated in test, pH is 7～10 in control, makes plant environment-friendly type cleaning agent.
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| CN2009100985888A CN101550379B (en) | 2009-05-14 | 2009-05-14 | Plant environment-friendly type cleaning agent and processing method thereof |
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| CN101550379B CN101550379B (en) | 2011-01-05 |
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| CN103275821A (en) * | 2013-02-25 | 2013-09-04 | 冯俏琼 | Automobile dry cleaning agent and preparation method thereof |
| CN103468424A (en) * | 2013-09-26 | 2013-12-25 | 陈理敬 | Environmentally-friendly multifunctional cleanser formula |
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| IN184497B (en) * | 1990-10-12 | 2000-08-26 | Procter & Gamble | |
| US5232632A (en) * | 1991-05-09 | 1993-08-03 | The Procter & Gamble Company | Foam liquid hard surface detergent composition |
| CN1182788A (en) * | 1997-02-03 | 1998-05-27 | 熊光明 | Health care detergent for preventing and controlling venereal disease and infections disease |
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| CN103275821A (en) * | 2013-02-25 | 2013-09-04 | 冯俏琼 | Automobile dry cleaning agent and preparation method thereof |
| CN103468424A (en) * | 2013-09-26 | 2013-12-25 | 陈理敬 | Environmentally-friendly multifunctional cleanser formula |
| CN103666871A (en) * | 2013-11-16 | 2014-03-26 | 克拉玛依市金山石油化工有限公司 | Cotton picker spindle cleaning solution and preparation and application methods thereof |
| CN103666871B (en) * | 2013-11-16 | 2016-06-29 | 克拉玛依市金山石油化工有限公司 | Spindling cleaning solution of cotton picker and preparation, using method |
| CN108559649A (en) * | 2018-05-07 | 2018-09-21 | 合肥仁德电子科技有限公司 | A kind of cleaning with Chinese herbal agent and preparation method thereof for electronic product |
| CN111218691A (en) * | 2018-11-26 | 2020-06-02 | 中国石油天然气股份有限公司 | Cleaning agent for scrapped oil pipelines and preparation method thereof |
| CN111218691B (en) * | 2018-11-26 | 2022-03-01 | 中国石油天然气股份有限公司 | Cleaning agent for scrapped oil pipelines and preparation method thereof |
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| CN101550379B (en) | 2011-01-05 |
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