CN101497767B - 一种α-氰基丙烯酸酯粘合剂的制备方法 - Google Patents
一种α-氰基丙烯酸酯粘合剂的制备方法 Download PDFInfo
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- CN101497767B CN101497767B CN200910119146A CN200910119146A CN101497767B CN 101497767 B CN101497767 B CN 101497767B CN 200910119146 A CN200910119146 A CN 200910119146A CN 200910119146 A CN200910119146 A CN 200910119146A CN 101497767 B CN101497767 B CN 101497767B
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- -1 alkyl cyanoacetate Chemical compound 0.000 claims abstract description 16
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- KGWDUNBJIMUFAP-KVVVOXFISA-N Ethanolamine Oleate Chemical compound NCCO.CCCCCCCC\C=C/CCCCCCCC(O)=O KGWDUNBJIMUFAP-KVVVOXFISA-N 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- ANGDWNBGPBMQHW-UHFFFAOYSA-N methyl cyanoacetate Chemical compound COC(=O)CC#N ANGDWNBGPBMQHW-UHFFFAOYSA-N 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
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- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 claims description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 2
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- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 10
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- 238000012691 depolymerization reaction Methods 0.000 description 3
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- 229910052739 hydrogen Inorganic materials 0.000 description 3
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- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
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- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 206010001557 Albinism Diseases 0.000 description 1
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 1
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- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
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- FPVGTPBMTFTMRT-NSKUCRDLSA-L fast yellow Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C(N)=CC=C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 FPVGTPBMTFTMRT-NSKUCRDLSA-L 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
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- 238000010025 steaming Methods 0.000 description 1
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- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
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- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
Description
配方1 | 配方2 | 配方3 | 配方4 | |
外观 | 无色透明液体 | 无色透明液体 | 无色半透明液体 | 无色半透明液体 |
粘度(mps/25℃) | 10-20 | 50-60 | 80-120 | 180-220 |
固化速度(秒) | 小于2 | 小于2 | 小于2 | 小于2 |
拉伸剪断强度(MPa) | 20 | 20 | 18 | 15 |
白化程度(24h后) | 无 | 无 | 无 | 无 |
稳定性(70℃) | 5天无明显增稠 | 5天无明显增稠 | 5天无明显增稠 | 5天无明显增稠 |
Claims (6)
Priority Applications (1)
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CN200910119146A CN101497767B (zh) | 2009-03-04 | 2009-03-04 | 一种α-氰基丙烯酸酯粘合剂的制备方法 |
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CN200910119146A CN101497767B (zh) | 2009-03-04 | 2009-03-04 | 一种α-氰基丙烯酸酯粘合剂的制备方法 |
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Publication Number | Publication Date |
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CN101497767A CN101497767A (zh) | 2009-08-05 |
CN101497767B true CN101497767B (zh) | 2012-10-03 |
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Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102719198A (zh) * | 2011-08-29 | 2012-10-10 | 湖北孚龙管业科技有限公司 | 一种塑料专用胶水 |
CN102603564B (zh) * | 2012-01-19 | 2014-12-31 | 抚顺哥俩好化学有限公司 | α-氰基丙烯酸酯单体的合成工艺 |
CN102775328B (zh) * | 2012-08-13 | 2015-02-25 | 北京康派特医疗器械有限公司 | α-氰基丙烯酸酯类化合物的环保制备方法 |
CN104263255B (zh) * | 2014-08-22 | 2016-07-13 | 林闪光 | α-氰基丙烯酸异辛酯胶粘剂的制备方法 |
TWI704194B (zh) * | 2015-04-28 | 2020-09-11 | 日商東亞合成股份有限公司 | 硬化性組成物及使用該硬化性組成物之模塑物的強化方法 |
CN109233649A (zh) * | 2018-09-17 | 2019-01-18 | 江苏创客新材料科技有限公司 | 一种粘尘纸卷高粘配方及其制备方法 |
JP7255606B2 (ja) * | 2018-10-23 | 2023-04-11 | 東亞合成株式会社 | 2-シアノアクリレート化合物の製造方法、及び、光硬化性接着剤組成物の製造方法 |
CN110760269A (zh) * | 2019-10-22 | 2020-02-07 | 东莞市成铭胶粘剂有限公司 | 一种远洋渔船用耐超低温封箱用热熔胶粘剂 |
CN112795318B (zh) * | 2020-12-31 | 2022-11-04 | 杭州电子科技大学 | 一种光学玻璃抛光用胶粘剂及其制备方法 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1795170A (zh) * | 2003-05-30 | 2006-06-28 | 东亚合成株式会社 | 精制2-氰基丙烯酸酯的制造方法 |
CN101096351A (zh) * | 2006-06-28 | 2008-01-02 | 北京科化新材料科技有限公司 | 控制多聚甲醛粉末粒度的α-氰基丙烯酸酯的制备方法 |
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2009
- 2009-03-04 CN CN200910119146A patent/CN101497767B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1795170A (zh) * | 2003-05-30 | 2006-06-28 | 东亚合成株式会社 | 精制2-氰基丙烯酸酯的制造方法 |
CN101096351A (zh) * | 2006-06-28 | 2008-01-02 | 北京科化新材料科技有限公司 | 控制多聚甲醛粉末粒度的α-氰基丙烯酸酯的制备方法 |
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Application publication date: 20090805 Assignee: Zhongshan Youxing Enterprise Adhesive Co., Ltd. Assignor: Fang Xuexing Contract record no.: 2015440000888 Denomination of invention: Preparation of alpha-cyanacrylate adhesive Granted publication date: 20121003 License type: Exclusive License Record date: 20151225 |
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Effective date of registration: 20160721 Address after: 528463, Zhongshan, Guangdong Province God Bay Road South Patentee after: Zhongshan Youxing Enterprise Adhesive Co., Ltd. Address before: 528463, No. 68, Nan Wan Avenue, Guangdong, Zhongshan Patentee before: Fang Xuexing |