CN101492696A - High-efficiency method for producing hydrogen gas and methyl hydride with mix fermentation of sewage sludge and garbage - Google Patents
High-efficiency method for producing hydrogen gas and methyl hydride with mix fermentation of sewage sludge and garbage Download PDFInfo
- Publication number
- CN101492696A CN101492696A CNA2008100305574A CN200810030557A CN101492696A CN 101492696 A CN101492696 A CN 101492696A CN A2008100305574 A CNA2008100305574 A CN A2008100305574A CN 200810030557 A CN200810030557 A CN 200810030557A CN 101492696 A CN101492696 A CN 101492696A
- Authority
- CN
- China
- Prior art keywords
- hydrogen
- methane
- sludge
- mud
- producing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/20—Sludge processing
Abstract
The invention relates to a method for effectively manufacturing hydrogen and methane by means of mixed fermentation of municipal sludge and trash. The method is characterized in that activated sludge for anaerobic digestion in sewage plants and heated and labilized anaerobic activated sludge are respectively used as methane-producing seed sludge and hydrogen-producing seed sludge; the municipal sludge and trash are mixed based on a certain proportion, then lime is added, the municipal sludge, the trash and the lime are placed in an alkaline hydrolysis reactor for carrying out alkaline hydrolysis; the mixture and the hydrogen-producing seed sludge after the alkaline hydrolysis are pumped into a hydrogen-producing reactor for carrying out hydrogen-producing reaction; generated biogas containing hydrogen is collected; the left mixture after hydrogen production and the methane-producing seed sludge are pumped into a methane-producing reactor for producing methane by means of hybrid reaction, so that clean energy such as hydrogen and methane featuring high heating value can be obtained and waste can be turned into resources, moreover, the problem of pollution of the municipal sludge and trash to the environment is solved, in addition, the reactors of the invention can either be operated in a sequencing batch way or in a continuous way, the needed equipment is simple, the operation is convenient and the cost is low.
Description
Technical field
The present invention relates to a kind of changing waste into resources technology, the method for particularly a kind of municipal sludge and rubbish mixed fermentation High-efficient Production hydrogen and methane.
Background technology
At present, normally adopt methods such as landfill, agricultural or burning to handle, dispose to municipal sludge and rubbish.But because water accounts 40%~60% in the most of domestic waste of China, organic composition only accounts for 30%~55% in its dried solid; The moisture percentage in sewage sludge that the municipal sewage plant produces reaches 85%~99.5%, organic content 40%-60% in its dried solid, and rubbish and sludge calorific value generally are lower than 4000kJ/kg, and are unwell to burning disposal.When heavy metal content is higher in rubbish and the mud, also be not suitable for agricultural.Therefore most rubbish all adopt landfill disposal, but the secondary pollution problem of underground water and atmospheric environment be can not be ignored; And mud will carry out landfill disposal, also needs further dehydration, especially trouble, cost height.
Summary of the invention
The objective of the invention is in order to solve above-mentioned technical problem, for the processing of municipal sludge and rubbish provides a kind of more valuable method of resource, i.e. the method for municipal sludge and rubbish mixed fermentation High-efficient Production hydrogen and methane.
For achieving the above object, the concrete production method of the present invention's employing is as follows:
1, planting mud prepares: produce methane kind mud and adopt Sewage Plant anaerobic digestion active sludge.Producing hydrogen kind mud is to utilize Sewage Plant anaerobic digestion active sludge to obtain through heat treated and activation, promptly get the anaerobic digestion active sludge air-dry, grind, sieve, at 105 ℃ of heating 2h down, kill non-sporeformer methanogen.To add in the 3g/L glucose nutrient solution through anaerobic activated sludge that heat treated is crossed, transfer pH to 6.5,35 ℃ of activation 24h and make and produce hydrogen kind mud down.
2, alkaline hydrolysis: the rubbish that will remove behind the non-degradable organism is wherein pulverized, is sieved, get lime, pulverize, sieve, adopt primary sludge, excess sludge, thickened sludge or the dewatered sludge of Sewage Plant, with pack into alkaline hydrolysis reactor and mix of above-mentioned mud, rubbish and lime, make the carbon-nitrogen ratio C/N of mixture remain on 10-30, lime and organism ratio C aO/VS remain on 0.05-0.2, water ratio remains on 85%-99%, and the alkaline hydrolysis reaction times is 0.5-3d.
3, produce hydrogen: the mixture behind the alkaline hydrolysis is pumped into the product hydrogen reactor, is the ratio adding product hydrogen kind mud of 0.1-0.5 in kind of mud and substrate volume ratio, mixes, and starts and produces hydrogen reactor, 30 ℃-60 ℃ of temperature, reaction times 3-8d.
4, produce methane: the remaining mixture that will produce behind the hydrogen pumps into methane-producing reactor, is that the ratio of 0.1-0.5 adds product methane kind mud in kind of mud and substrate volume ratio, mixes startup methane-producing reactor, 30 ℃-60 ℃ of temperature, reaction times 7-15d.
After the normal operation, produce hydrogen reactor and methane-producing reactor in displacer during mixture, all can reserve a certain proportion of mixture respectively as the product hydrogen kind mud of next batch reaction with produce methane kind mud.
The present invention is owing to adopt above processing method, utilize municipal sludge and rubbish to make raw material, adopt the lime alkaline hydrolysis to strengthen and produce hydrogen and produce the methane process, obtain high heating value, clear energy sources hydrogen and methane, realize changing waste into resources, solve the pollution problem of municipal sludge and rubbish environment.Nitrogenous abundant municipal sludge is carried out mixed fermentation with the municipal garbage that contains carbon rich, help the physiological metabolism of anaerobion, simultaneously by adding lime, can strengthen the alkaline hydrolysis of municipal sludge and rubbish, help improving the degradation rate of organic composition in municipal sludge and the rubbish, strengthen and produce hydrogen and produce the methane effect, hydrogen yield reaches as high as 52mL/gVS, methane production reaches as high as 103mL/gVS, improves 2-4 respectively when not adding lime doubly and 2-3 times.Only need add a small-sized alkaline hydrolysis reactor at the two-phase anaerobic digestion system front end, only need to wherein adding lime cheap and easy to get, and needn't add chemical agents such as soda acid in addition to producing hydrogen reactor and methane-producing reactor, can realize municipal sludge and rubbish mixed fermentation High-efficient Production hydrogen and methane, but the operation of each reactor sequence batch (, also continuously-running, required equipment is simple, easy to operate, with low cost.
Description of drawings
Fig. 1 is an experimental installation of the present invention.
Wherein: 1. alkaline hydrolysis reactor, 2. produce hydrogen reactor, 3. methane-producing reactor, 4-8. slush pump.
Embodiment
Embodiment 1: in the alkaline hydrolysis reactor, and C/N=30, CaO/VS=0.1, water ratio=95%, time 1d.Produce in the hydrogen reactor, planting mud and substrate volume ratio is 0.1,55 ℃ of temperature, time 8d.In the methane-producing reactor, planting mud and substrate volume ratio is 0.2,35 ℃ of temperature, time 9d.The hydrogen yield that obtains is 23mL/gVS, and methane production is 67mL/gVS.
Embodiment 2: in the alkaline hydrolysis reactor, and C/N=10, CaO/VS=0.05, water ratio=85%, time 3d.Produce in the hydrogen reactor, planting mud and substrate volume ratio is 0.3,40 ℃ of temperature, time 5d.In the methane-producing reactor, planting mud and substrate volume ratio is 0.4,40 ℃ of temperature, time 14d.The hydrogen yield that obtains is 40mL/gVS, and methane production is 84mL/gVS.
Embodiment 3: in the alkaline hydrolysis reactor, and C/N=20, CaO/VS=0.2, water ratio=90%, time 2d.Produce in the hydrogen reactor, planting mud and substrate volume ratio is 0.3,35 ℃ of temperature, time 8d.In the methane-producing reactor, planting mud and substrate volume ratio is 0.3,35 ℃ of temperature, time 15d.The hydrogen yield that obtains is 52mL/gVS, and methane production is 103mL/gVS.
Embodiment 4: in the alkaline hydrolysis reactor, and C/N=15, CaO/VS=0.15, water ratio=95%, time 0.5d.Produce in the hydrogen reactor, planting mud and substrate volume ratio is 0.5,35 ℃ of temperature, time 3d.In the methane-producing reactor, planting mud and substrate volume ratio is 0.3,40 ℃ of temperature, time 10d.The hydrogen yield that obtains is 44mL/gVS, and methane production is 93mL/gVS.
Claims (1)
1, the method for a kind of municipal sludge and rubbish mixed fermentation High-efficient Production hydrogen and methane is characterized in that adopting following processing, production technique:
(1) planting mud prepares: produce methane kind mud and adopt Sewage Plant anaerobic digestion active sludge, producing hydrogen kind mud is to utilize Sewage Plant anaerobic digestion active sludge to obtain through heat treated and activation, promptly get the anaerobic digestion active sludge air-dry, grind, sieve, heat 2h down at 105 ℃, kill non-sporeformer methanogen, to add in the 3g/L glucose nutrient solution through anaerobic activated sludge that heat treated is crossed, transfer pH to 6.5,35 ℃ of activation 24h and make and produce hydrogen kind mud down;
(2) alkaline hydrolysis: the rubbish that will remove behind the non-degradable organism is wherein pulverized, is sieved, get lime, pulverize, sieve, adopt primary sludge, excess sludge, thickened sludge or the dewatered sludge of Sewage Plant, with pack into alkaline hydrolysis reactor and mix of above-mentioned mud, rubbish and lime, make the carbon-nitrogen ratio C/N of mixture remain on 10-30, lime and organism ratio C aO/VS remain on 0.05-0.2, water ratio remains on 85%-99%, and the alkaline hydrolysis reaction times is 0.5-3d;
(3) produce hydrogen: the mixture behind the alkaline hydrolysis is pumped into the product hydrogen reactor, is the ratio adding product hydrogen kind mud of 0.1-0.5 in kind of mud and substrate volume ratio, mixes, and starts and produces hydrogen reactor, 30 ℃-60 ℃ of temperature, reaction times 3-8d;
(4) produce methane: the remaining mixture that will produce behind the hydrogen pumps into methane-producing reactor, is that the ratio of 0.1-0.5 adds product methane kind mud in kind of mud and substrate volume ratio, mixes startup methane-producing reactor, 30 ℃-60 ℃ of temperature, reaction times 7-15d.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2008100305574A CN101492696B (en) | 2008-01-26 | 2008-01-26 | High-efficiency method for producing hydrogen gas and methyl hydride with mix fermentation of sewage sludge and garbage |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2008100305574A CN101492696B (en) | 2008-01-26 | 2008-01-26 | High-efficiency method for producing hydrogen gas and methyl hydride with mix fermentation of sewage sludge and garbage |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101492696A true CN101492696A (en) | 2009-07-29 |
CN101492696B CN101492696B (en) | 2012-11-14 |
Family
ID=40923485
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2008100305574A Expired - Fee Related CN101492696B (en) | 2008-01-26 | 2008-01-26 | High-efficiency method for producing hydrogen gas and methyl hydride with mix fermentation of sewage sludge and garbage |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN101492696B (en) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101886040A (en) * | 2010-06-13 | 2010-11-17 | 安徽大学 | Method for preparing hydrogen-producing and ethanol-producing microbial aggregate |
CN101935139A (en) * | 2010-09-21 | 2011-01-05 | 同济大学 | Method for producing mash gas from municipal sludge through dry method anaerobic fermentation |
CN102030456A (en) * | 2010-11-09 | 2011-04-27 | 同济大学 | Method for enhancing dry-process fermentation stability of sludge by adding kitchen waste |
CN101654322B (en) * | 2009-09-08 | 2011-06-22 | 同济大学 | Method for producing methane by sludge |
CN102492727A (en) * | 2011-12-08 | 2012-06-13 | 杭州迪利生态循环经济工程有限公司 | Method for preparing hydrogen and methane step by step through anaerobic fermentation of excess sludge of sewage treatment |
CN102492726A (en) * | 2011-11-21 | 2012-06-13 | 浙江大学 | Method and device for producing hydrogen and methane through fermentation of residual sludge |
CN103421678A (en) * | 2012-05-22 | 2013-12-04 | 北京低碳清洁能源研究所 | System for preparing mixed hydrogen alkane by biomass fermentation and production method |
CN108178473A (en) * | 2017-12-31 | 2018-06-19 | 江苏省港海环保科技集团有限公司 | A kind of environmental protection and energy saving processing method of municipal sludge |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1031392C (en) * | 1992-12-12 | 1996-03-27 | 哈尔滨建筑工程学院 | Method and apparatus of organic waste water treatment and biological hydrogen production |
JP4373700B2 (en) * | 2002-06-05 | 2009-11-25 | 三菱電機株式会社 | Organic waste liquid processing method and processing apparatus |
CN100595279C (en) * | 2006-09-05 | 2010-03-24 | 江南大学 | Method of transforming abandoned biomass to acetic acid by two-phase coupling process of hydrogen-producing acid-producing and hydrogen-consuming hydrogen-producing |
-
2008
- 2008-01-26 CN CN2008100305574A patent/CN101492696B/en not_active Expired - Fee Related
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101654322B (en) * | 2009-09-08 | 2011-06-22 | 同济大学 | Method for producing methane by sludge |
CN101886040A (en) * | 2010-06-13 | 2010-11-17 | 安徽大学 | Method for preparing hydrogen-producing and ethanol-producing microbial aggregate |
CN101886040B (en) * | 2010-06-13 | 2012-11-21 | 安徽大学 | Method for preparing hydrogen-producing and ethanol-producing microbial aggregate |
CN101935139A (en) * | 2010-09-21 | 2011-01-05 | 同济大学 | Method for producing mash gas from municipal sludge through dry method anaerobic fermentation |
CN101935139B (en) * | 2010-09-21 | 2011-11-16 | 同济大学 | Method for producing mash gas from municipal sludge through dry method anaerobic fermentation |
CN102030456A (en) * | 2010-11-09 | 2011-04-27 | 同济大学 | Method for enhancing dry-process fermentation stability of sludge by adding kitchen waste |
CN102492726A (en) * | 2011-11-21 | 2012-06-13 | 浙江大学 | Method and device for producing hydrogen and methane through fermentation of residual sludge |
CN102492727A (en) * | 2011-12-08 | 2012-06-13 | 杭州迪利生态循环经济工程有限公司 | Method for preparing hydrogen and methane step by step through anaerobic fermentation of excess sludge of sewage treatment |
CN103421678A (en) * | 2012-05-22 | 2013-12-04 | 北京低碳清洁能源研究所 | System for preparing mixed hydrogen alkane by biomass fermentation and production method |
CN108178473A (en) * | 2017-12-31 | 2018-06-19 | 江苏省港海环保科技集团有限公司 | A kind of environmental protection and energy saving processing method of municipal sludge |
Also Published As
Publication number | Publication date |
---|---|
CN101492696B (en) | 2012-11-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101492696B (en) | High-efficiency method for producing hydrogen gas and methyl hydride with mix fermentation of sewage sludge and garbage | |
CN108558162B (en) | Method for recycling residual sludge hydrothermal carbonization liquid | |
Ngan et al. | Anaerobic digestion of rice straw for biogas production | |
Han et al. | Performance of an innovative two-stage process converting food waste to hydrogen and methane | |
US6342378B1 (en) | Biogasification of solid waste with an anaerobic-phased solids-digester system | |
CN101935139B (en) | Method for producing mash gas from municipal sludge through dry method anaerobic fermentation | |
CN105855275A (en) | Method for processing sludge and kitchen wastes | |
CN101778944A (en) | Method for the conversion of biomass from renewable raw materials in anaerobic fermenters | |
EP2521768A2 (en) | Combined dry and wet dual phase anaerobic process for biogas production | |
Kang et al. | Enhanced anaerobic digestion of organic waste | |
CN105060669A (en) | Sludge comprehensive utilization method by anaerobic fermentation-carbonization combination technique | |
CN111518843A (en) | Anaerobic fermentation hydrogen production method and additive using excess sludge as raw material | |
Shao et al. | Combined effects of liquid digestate recirculation and biochar on methane yield, enzyme activity, and microbial community during semi-continuous anaerobic digestion | |
CN112979119B (en) | High-value treatment system or method for wet garbage in cities and towns | |
CN102363794B (en) | Method for producing hydrogen through kitchen waste enzymolysis and reinforced dark fermentation | |
CN110305775A (en) | A kind of hydrolysis reactor and its application method handling solid waste | |
Liu et al. | Review of enhanced processes for anaerobic digestion treatment of sewage sludge | |
Ekwenna et al. | Bioenergy production from pretreated rice straw in Nigeria: An analysis of novel three-stage anaerobic digestion for hydrogen and methane co-generation | |
Lay et al. | Continuous anaerobic hydrogen and methane production using water hyacinth feedstock | |
CN102924189B (en) | Method for recovering carbon-based ammonium bicarbonate in refuse landfill | |
CN216027034U (en) | System for sludge, kitchen waste and reed carry out closed loop treatment | |
JP4844951B2 (en) | Processing method and apparatus for garbage and paper waste | |
CN101962258B (en) | Circular inoculation method used for accelerating fermentation process of municipal sludge dry method | |
CN114378105A (en) | Kitchen waste and cellulose biomass synergistic multi-stage treatment system and method | |
Xu et al. | Strategies to increase energy recovery from phase-separated anaerobic digestion of organic solid waste |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20121114 Termination date: 20150126 |
|
EXPY | Termination of patent right or utility model |