CN101492615B - Gasification furnace and charge-in system - Google Patents

Gasification furnace and charge-in system Download PDF

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Publication number
CN101492615B
CN101492615B CN 200810003954 CN200810003954A CN101492615B CN 101492615 B CN101492615 B CN 101492615B CN 200810003954 CN200810003954 CN 200810003954 CN 200810003954 A CN200810003954 A CN 200810003954A CN 101492615 B CN101492615 B CN 101492615B
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vapourizing furnace
thermal insulation
insulation layer
gas
high temperature
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CN101492615A (en
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沈政宪
许品超
徐恒文
陈美燕
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Industrial Technology Research Institute ITRI
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Industrial Technology Research Institute ITRI
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E20/00Combustion technologies with mitigation potential
    • Y02E20/16Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
    • Y02E20/18Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]

Abstract

The invention discloses a gasification furnace and a feeding system thereof; wherein the gasification furnace comprises a feeding combustor and a gasification furnace, the discharge port of the feeding combustor is communicated with the reaction zone of a gasification furnace core, the feeding port of the feeding combustor is communicated with the outside of the gasification furnace, and the feeding combustor respectively and sequentially passes through the wall of the gasification furnace, the heat insulating layer, the insulating layer and the high temperature resistance layer from the outside of the gasification furnace and finally reaches the reaction zone of the gasification furnace core; the system is characterized in that high temperature resistance material is wrapped around the feeding combustor and respectively and sequentially passes through the heat insulating layer to the insulating layer from the wall of the gasification furnace. The invention can effectively prevent intense mobility caused by instability and temperature variation during gasification, enhance the security of integrated operation and running period, and improve the gasification efficiency.

Description

Vapourizing furnace and feed system thereof
Technical field
The invention relates to a kind of vapourizing furnace and feed system thereof, refer to especially a kind ofly make mechanism combines to transport fine coal and delivering gas with the charging burner high-temperature gasification stove and feed system thereof through executing of different fire proofed woods.
Background technology
In recent years because the whole world faces environmental protection and energy problem simultaneously, so that national governments and industry member are all paid much attention to the research and development relevant for high energy gamma source efficient and oligosaprobic clean coal technology (clean coal technology).How to promote the service efficiency of coal and reduce the coal pollution for using the primary problem of clean coal technology development at present.In various clean coal technologies; (gasification technique) attracts most attention with gasification technology; Capable of using with various fuel such as coal, refinery coke, give birth to mass-energy and waste etc. as charging; And the synthetic gas of producing (syngas) but diversification use, as producing electric power, be used as fuel and change into chemical etc., so the equal develop actively gasification technology in various countries.
Gasification of coal is meant that coal is in specific equipment; Under certain temperature and pressure; Make organic and oxygenant (like steam/air or oxygen etc.) generation series of chemical in the coal, the solid coal is converted into the process of inflammable gass such as containing CO, H2, CH4 and incombustible gas such as CO2, N2.During gasification of coal, must possess three conditions, i.e. vapourizing furnace, oxygenant and heat supplied, the three is indispensable.The reaction that gasification takes place comprises pyrolysis, gasification and the combustion reactions of coal.The pyrolysis of coal is meant that coal becomes the process of gas, solid, liquid three-phase product from solid phase.Coal gasification and combustion reactions then comprise two kinds of reaction types; Be heterogeneous gas-solid reaction and homogeneous gas-phase reaction; Mainly be two kinds of oxygen and air as for the selection of oxygenant, oxygen will help the lifting of synthetic gas calorific value, but relatively the cost of oxygen generating plant need be provided; Opposite air then need not provide system gas equipment, but the synthetic gas calorific value that is obtained is then relatively low.
Relevant at present vapourizing furnace can roughly be divided into four kinds of patterns; The important consideration parameter of selecting comprises inlet amount, working pressure, service temperature, output synthetic gas composition ... The wherein high-pressure gasified volume that helps saving the design body of heater reduces the utilizations of construction cost and back outlet synthetic gas high-pressure delivery, then depends on the composition ratio of back outlet synthetic gas as for the vapourizing furnace service temperature; Mainly the product by required manufacturing decides the synthetic gas composition; The interior temperature of general stove is between 1000~1500 ℃, and in order to keep the temperature of vapourizing furnace, vapourizing furnace inside is used the refractory mortar (or refractory brick) of three stratotype formulas usually.See also Fig. 7; It is for showing the sectional view of known high-temperature gasification stove; Three layers of refractory mortar have different characteristic and function respectively; The innermost layer refractory mortar is a high-temperature-resistant layer 21, and the characteristic of this high-temperature-resistant layer 21 is the high temperature between about 1600~1700 ℃ for the upper temperature limit that can bear, and can continue to keep the high temperature of vapourizing furnace heart reaction zone 24 to carry out in order to gasification.Outermost layer is a thermal insulation layer 23 with the refractory mortar that gasification furnace wall 25 is connected, and main is to block the material of heat-conduction effect with protection gasification furnace wall 25, and the general permissible temperature upper limit is between 1000~1200 ℃.Refractory mortar as for the middle layer is a thermal insulation layer 22 then, lets the interior high temperature of vapourizing furnace be able to keep, and the upper temperature limit of generally allowing is between 1200~1400 ℃.
Be fuel (fine coal, coal water slurry, refinery coke), oxygen (air) and steam sent in the vapourizing furnace simultaneously as for the 26 main work of charging burner and burn-gasification reaction; It is one of considerable gordian technique in the gasification technology; In order before charging, fuel to be mixed completion in advance with oxygen, the premix charging burner 26 that generally can adopt so-called inside and outside tubular type is as feed system.The outer tube 27 of charging burner 26 is used for delivering gas (being generally oxygen or air); The interior pipe 28 of charging burner 26 is used for transfer the fuel-fine coal; And the fuel-fine coal of the gas of outer tube 27 and interior pipe 28 is after the converging transition 29 of charging burner 26 is pre-mixed, and spirt carries out gasification reaction in vapourizing furnace heart reaction zone 24 again.
Because gasification of coal generally all is under the intense environment of HTHP, to carry out; So must be quite careful in operation, must avoid charging burner 26 exit end occur taking place because of externalities fusing and in generation fuel blockage, and then generation high tempering phenomenon; Possibly have this moment under fuel (coal), oxygenant (oxygen) and three kinds of conditions of hot environment at the same time; Directly carry out combustion reactions, directly corrode the more low temperature resistant thermal insulation layer 22 of charging burner 26 or the refractory mortar of thermal insulation layer 23 through high temperature on every side, because fuel and oxygenant still continue charging in charging burner 26 inside; And furnace temperature does not have considerable change; So quite be difficult for discovering, possibly can't bear high temperature because of gasification furnace wall 25 at last, and cause great danger.So the feed system of known vapourizing furnace still has disappearance and haves much room for improvement.
At present the improvement design of feed system is that for example the Chinese patent notification number the 1st, 407 on the demand of promoting efficiency of combustion mostly, No. 274 with No. the 7th, 021,222, USP notification number.No. the 1st, 407,274, Chinese patent notification number " coal powder direct supplying burner "; It is the improvement that is conceived to shower nozzle and nozzle; Install plate washer additional at exit end, shower nozzle has bluff body or hull, and fine coal is changed in the distribution of outlet; Form favourable stable burning things which may cause a fire disaster, to reach underload and high efficiency burning feature.This piece Chinese patent case and the present invention have an otherness in that mechanism is conceptive; The present invention be directed to the demand of improving safety; And proof is under the improvement of improving safety; Do not have influence on its efficiency of combustion, so design focal point is at whole feed system, the pipe outer tube is carried the particular design high temperature material peripheral with the charging burner of different materials, discharge port end respectively in comprising.
USP notification number the 7th; 021; No. 222 " Coal-burning boiler ' s IgnitionBurner "; It in the freezing air cylinder (cooling air cylinder) of burner port end introducing air and the effect that enlarges passage, promotes the efficient of pulverized coal friring in order to increase the incendiary economic benefit.This piece patent major technique is to promote efficiency of combustion at introducing air.
Summary of the invention
The object of the invention is providing a kind of high-temperature gasification stove and feed system thereof; Around the burning feeder, coat a high temperature material; Even so produce because of high tempering phenomenon external or that internal factor causes; Also be unlikely and corrode the peripheral thermal insulation layer of charging burner and the refractory mortar of thermal insulation layer, so be coated on the effect that the high temperature material of burning feeder has the refractory mortar of peripheral thermal insulation layer of protection charging burner and thermal insulation layer.
Another object of the present invention is providing a kind of high-temperature gasification stove and feed system thereof; This burning feeder is non-premixed burning feeder; The interior pipe transfer the fuel and first gas of burning feeder; The outer tube of burning feeder is carried second gas, can reduce the fusing and the phenomenon of blocking of burning feeder exit end; And the interior pipe transfer the fuel and first gas and outer tube are carried second gas, the chance that can avoid the fuel and second gas in the burning feeder, to contact; And outer tube carries second gas more can continue the front end of fuel-feed device is cooled.
Above-mentioned purpose of the present invention can realize through following technical scheme; A kind of high-temperature gasification stove; Have a charging burner, the discharge port of this charging burner is communicated with a vapourizing furnace heart reaction zone, and the opening for feed of this charging burner is communicated with the external world of this vapourizing furnace; This charging burner passes through this gasification furnace wall, thermal insulation layer, thermal insulation layer and high-temperature-resistant layer respectively in regular turn from the external world of this vapourizing furnace; And arrive this vapourizing furnace heart reaction zone, wherein this charging burner around coat a high temperature material, this high temperature material extends to this thermal insulation layer through this thermal insulation layer respectively in regular turn from this gasification furnace wall.
The invention allows for a kind of high-temperature gasification stove; Has a charging burner; The discharge port of this charging burner is communicated with a vapourizing furnace heart reaction zone; And the opening for feed of this charging burner is communicated with the external world of this vapourizing furnace, and this charging burner passes through this gasification furnace wall, thermal insulation layer, thermal insulation layer and high-temperature-resistant layer respectively in regular turn from the external world of this vapourizing furnace, and arrives this vapourizing furnace heart reaction zone; Wherein this charging burner around coat a high temperature material, this high temperature material extends to this high-temperature-resistant layer through this thermal insulation layer, this thermal insulation layer respectively in regular turn from this gasification furnace wall.
The invention allows for a kind of high-temperature gasification stove; Has a charging burner; The discharge port of this charging burner is communicated with a vapourizing furnace heart reaction zone, and the opening for feed of this charging burner is communicated with the external world of this vapourizing furnace, and this vapourizing furnace includes a gasification furnace wall, a thermal insulation layer, a thermal insulation layer and a high-temperature-resistant layer; This thermal insulation layer is between this gasification furnace wall and this thermal insulation layer; This thermal insulation layer is between this thermal insulation layer and this high-temperature-resistant layer, and this high-temperature-resistant layer is between this thermal insulation layer and this vapourizing furnace heart reaction zone, and wherein this vapourizing furnace has a hole slot; This hole slot is positioned between this thermal insulation layer and this thermal insulation layer, and is provided with a high temperature material in this hole slot to coat this charging burner.
The present invention has proposed a kind of feed system of high-temperature gasification stove again, and this feed system has a charging burner, and this charging burner is coated with a high temperature material, and this high temperature material is positioned between the thermal insulation layer and thermal insulation layer of a vapourizing furnace.
In preferred embodiments of the present invention, this charging burner has Guan Yuyi outer tube in, and pipe is carried fuel and one first gas in this, and this outer tube is carried one second gas.
In preferred embodiments of the present invention, this fuel comprises fine coal, coal water slurry or refinery coke.
In preferred embodiments of the present invention, this second gas is oxygen or air.
In preferred embodiments of the present invention, discharge port place of pipe forms a reducing in this.
In preferred embodiments of the present invention, this high temperature material is a ring texture.
In preferred embodiments of the present invention, this high temperature material is coated by a pipe shape body.
In preferred embodiments of the present invention, this hole slot further lies along this high-temperature-resistant layer.
In preferred embodiments of the present invention, this hole slot has a perforation, and this perforation supplies this charging burner setting and makes the discharge port of this charging burner be communicated to this vapourizing furnace heart reaction zone.
In preferred embodiments of the present invention, this first gas is the gas that has the gas of ignition quality or do not have ignition quality.
In preferred embodiments of the present invention, this gas with ignition quality is oxygen or air.
In preferred embodiments of the present invention, this second gas is the gas with ignition quality.
Therefore, the advantage of high-temperature gasification stove of the present invention comprises following points:
One, the high temperature material that is coated on this burning feeder has the effect of refractory mortar of thermal insulation layer and the thermal insulation layer of protection charging burner periphery.
Two, because this burning feeder is non-premixed burning feeder; The outer tube of this burning feeder is carried second gas; The interior pipe transfer the fuel and first gas of this burning feeder; Can reduce the fusing and the phenomenon of blocking of this burning feeder discharge port, and this outer tube carries second gas more can continue the front end effect of cooling to this fuel-feed device.
Three, execute through different fire proofed woods and do mechanism and change with the mode that the charging burner combines to transport fine coal and delivering gas; Make feed system can be applicable to the vapourizing furnace operational condition under high temperature and the high pressure; And effectively prevent the violent mobility that instability and temperature variation produced in the gasification; Promote the security and the runtime of integrated operation, and also promote to some extent for gasification efficiency.
Four, fine coal inlet of the present invention is to use simple split tunnel with delivering gas; Its burning feeder is to adopt not premixed design; And the fire proofed wood mechanism of improvement burning feeder periphery not only promotes gasification efficiency, and increases the security of gasification.
Description of drawings
Fig. 1 is the sectional view that shows high-temperature gasification stove first embodiment of the present invention.
Fig. 2 is the sectional view that shows the charging burner.
Fig. 3 is the enlarged view that shows the C portion of Fig. 2.
Fig. 4 shows the sectional view of Fig. 2 along the A-A line.
Fig. 5 shows the sectional view of Fig. 2 along the B-B line.
Fig. 6 is the sectional view that shows high-temperature gasification stove second embodiment of the present invention.
Fig. 7 is the sectional view that shows known high-temperature gasification stove.
Description of reference numerals:
1,31---high-temperature gasification stove
2---charging burner
The 3---body of heater that gasifies
The 4---discharge port
5---vapourizing furnace heart reaction zone
The 6---furnace wall of gasifying
The 7---thermal insulation layer
The 8---thermal insulation layer
The 9---high-temperature-resistant layer
The 10---hole slot
The 11---high temperature material
Pipe in the 12---
The 13---outer tube
14---pipe shape body
The 15---perforation
The 16---reducing
The 17---circular hole
Embodiment
Though the present invention will consult the accompanying drawing that contains preferred embodiment of the present invention and fully describe,, this should be appreciated that those skilled in the art can revise invention described herein, obtain effect of the present invention simultaneously before describing.Therefore, the description below must understanding is an announcement widely to those skilled in the art, and its content does not lie in restriction the present invention.
See also Fig. 1, show the sectional view of high-temperature gasification stove 1 first embodiment of the present invention.In this embodiment; High-temperature gasification stove 1 of the present invention comprises a charging burner 2 and a gasification body of heater 3; The discharge port 4 of this charging burner 2 is communicated with a vapourizing furnace heart reaction zone 5; And the opening for feed of this charging burner 2 (figure do not show) is communicated with the external world of this vapourizing furnace 3, and this gasification body of heater 3 includes a gasification furnace wall 6, a thermal insulation layer 7, a thermal insulation layer 8 and a high-temperature-resistant layer 9, and this thermal insulation layer 7 gasifies between furnace wall 6 and this thermal insulation layer 8 between this; This thermal insulation layer 8 is between this thermal insulation layer 7 and this high-temperature-resistant layer 9, and this high-temperature-resistant layer 9 is between this thermal insulation layer 8 and this vapourizing furnace heart reaction zone 5.Wherein, " high temperature " of the present invention is about 1800~1600 ℃, and " middle temperature " is about 1600~1400 ℃, and " low temperature " is about 1400~1200 ℃.
This gasification body of heater 3 further has a hole slot 10; This hole slot 10 is positioned at 8 of this thermal insulation layer 7 and this thermal insulation layers; Wherein be provided with a high temperature material 11 in this hole slot 10; This high temperature material 11 can be a ring texture and in order to coating this charging burner 2, and this high temperature material 11 is coated by a pipe shape body 14.This hole slot 10 has a perforation 15, and this perforation 15 supplies this charging burner 2 to be provided with and makes the discharge port 4 of this charging burner 2 be communicated to this vapourizing furnace heart reaction zone 5.
See also Fig. 2, it is the sectional view that shows this charging burner 2, and Fig. 1 is consulted in cooperation.This charging burner 2 passes through this gasification furnace wall 6, this thermal insulation layer 7, this thermal insulation layer 8 and high-temperature-resistant layer 9 respectively in regular turn from the external world of this gasification body of heater 3, and is communicated to this vapourizing furnace heart reaction zone 5.This charging burner 2 has pipe 12 and one outer tube 13 in, and pipe 12 is carried fuel and one first gas in this, and this outer tube 13 is carried one second gas.And this fuel can be fine coal, coal water slurry or refinery coke etc.; This first gas can be the gas with ignition quality, and like oxygen or air, this first gas also can be the gas with ignition quality again; This second gas is the gas with ignition quality, like oxygen, air.
See also Fig. 3, it is the enlarged view that shows C portion among Fig. 2; Fig. 4 shows the sectional view of Fig. 2 along the A-A line; Fig. 5 shows the sectional view of Fig. 2 along the B-B line.The discharge port place of pipe 12 forms a reducing 16 in being somebody's turn to do; And this reducing 16 can make pipe 12 is carried in this fuel and past post these vapourizing furnace heart reaction zone 5 dischargings of first gas, mixes ahead of time at this discharge port 4 with second gas that this outer tube 13 is carried to avoid pipe 12 is carried in this fuel, first gas.Wherein, The front end of this outer tube 13 forms a plurality of circular holes 17; Second gas that this outer tube 13 is carried can be discharged to this vapourizing furnace heart reaction zone 5 from this outer tube 13 apace, also can avoid pipe 12 is carried in this fuel, first gas to mix ahead of time at this discharge port 4 with the gas that this outer tube 13 is carried simultaneously.And should have the design of reducing 16 and circular hole 17 designs of this outer tube 13 by interior pipe 12; Its purpose all is to make this fuel, this first gas just not to mix at this discharge port 4 with this second gas as far as possible at once; Just mix but delay to this vapourizing furnace heart reaction zone 5; So can avoid causing because of externalities and take place to fuse and the inherent fuel blockage that takes place, and then the high tempering phenomenon that takes place is to burn this charging burner 2.In addition, this outer tube 13 is carried second gas, and for example: oxygen more can continue the front end effect of cooling to this fuel-feed device 2.
See also Fig. 6, it is the sectional view that shows second embodiment of high-temperature gasification stove 31 of the present invention.High-temperature gasification stove 31 second embodiment of the present invention with respect to the difference of this high-temperature gasification stove 1 first embodiment be in: in a second embodiment; Coating this high temperature material 11 around this charging burner 2, and this high temperature material 11 is to extend to this high-temperature-resistant layer 9 through this thermal insulation layer 7, this thermal insulation layer 8 in regular turn respectively from this gasification furnace wall 6.
Though the present invention discloses as above with preferred embodiment; Right its is not that those skilled in the art are not breaking away from the spirit and scope of the present invention, when doing various changes and retouching in order to qualification the present invention; Therefore, protection scope of the present invention is as the criterion when looking claims person of defining.

Claims (19)

1. vapourizing furnace; It has a charging burner and a vapourizing furnace; The discharge port of this charging burner is communicated with a vapourizing furnace heart reaction zone, and the opening for feed of this charging burner is communicated with the external world of this vapourizing furnace, and this charging burner passes through this gasification furnace wall, thermal insulation layer, thermal insulation layer and high-temperature-resistant layer respectively in regular turn from the external world of this vapourizing furnace; And arrive this vapourizing furnace heart reaction zone; It is characterized in that: coat a high temperature material around this charging burner, this high temperature material extends to this thermal insulation layer through this thermal insulation layer respectively in regular turn from this gasification furnace wall, and this charging burner has Guan Yuyi outer tube in; Should carry fuel and one first gas by interior pipe, this outer tube is carried one second gas.
2. vapourizing furnace as claimed in claim 1 is characterized in that this fuel comprises fine coal, coal water slurry or refinery coke.
3. vapourizing furnace as claimed in claim 1 is characterized in that, this second gas is oxygen or air.
4. vapourizing furnace as claimed in claim 1 is characterized in that, discharge port place of pipe forms a reducing in this.
5. vapourizing furnace as claimed in claim 1 is characterized in that, this high temperature material is a ring texture.
6. vapourizing furnace as claimed in claim 1 is characterized in that this high temperature material more extends to this high-temperature-resistant layer.
7. vapourizing furnace, it has a charging burner and a vapourizing furnace, and the discharge port of this charging burner is communicated with a vapourizing furnace heart reaction zone; The opening for feed of this charging burner is communicated with the external world of this vapourizing furnace; This vapourizing furnace includes a gasification furnace wall, a thermal insulation layer, a thermal insulation layer and a high-temperature-resistant layer, and this thermal insulation layer is between this gasification furnace wall and this thermal insulation layer, and this thermal insulation layer is between this thermal insulation layer and this high-temperature-resistant layer; This high-temperature-resistant layer is between this thermal insulation layer and this vapourizing furnace heart reaction zone; It is characterized in that: this vapourizing furnace has a hole slot, and this hole slot is positioned between this thermal insulation layer and this thermal insulation layer, wherein is provided with a high temperature material in this hole slot; This high temperature material coats this charging burner; This charging burner has Guan Yuyi outer tube in, and pipe is carried fuel and one first gas in this, and this outer tube is carried one second gas.
8. vapourizing furnace as claimed in claim 7 is characterized in that this fuel comprises fine coal, coal water slurry or refinery coke.
9. vapourizing furnace as claimed in claim 7 is characterized in that, this second gas is oxygen or air.
10. vapourizing furnace as claimed in claim 7 is characterized in that, discharge port place of pipe forms a reducing in this.
11. vapourizing furnace as claimed in claim 7 is characterized in that, this high temperature material is a ring texture.
12. vapourizing furnace as claimed in claim 7 is characterized in that, this high temperature material is coated by a pipe shape body.
13. vapourizing furnace as claimed in claim 7 is characterized in that, this hole slot further lies along this high-temperature-resistant layer.
14. vapourizing furnace as claimed in claim 7 is characterized in that, this hole slot has a perforation, and this perforation supplies this charging burner setting and makes the discharge port of this charging burner be communicated to this vapourizing furnace heart reaction zone.
15. the feed system of a vapourizing furnace; This feed system has a charging burner, it is characterized in that: this charging burner is coated with a high temperature material, and this high temperature material is positioned between the thermal insulation layer and thermal insulation layer of a vapourizing furnace; Wherein this high temperature material is that a pipe shape body coats; This charging burner has Guan Yuyi outer tube in, and pipe is carried fuel and one first gas in this, and this outer tube is carried one second gas.
16. the feed system of vapourizing furnace as claimed in claim 15 is characterized in that, this fuel comprises fine coal, coal water slurry or refinery coke.
17. the feed system of vapourizing furnace as claimed in claim 15 is characterized in that, this second gas is oxygen or air.
18. the feed system of vapourizing furnace as claimed in claim 15 is characterized in that, discharge port place of pipe forms a reducing in this.
19. the feed system of vapourizing furnace as claimed in claim 15 is characterized in that, this high temperature material is a ring texture.
CN 200810003954 2008-01-23 2008-01-23 Gasification furnace and charge-in system Active CN101492615B (en)

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Publication number Priority date Publication date Assignee Title
CN106239064B (en) * 2016-08-29 2019-03-26 中航动力股份有限公司 A kind of gas turbine component heat insulation layer method for coating
CN111286366B (en) * 2018-12-07 2021-08-13 中国科学院工程热物理研究所 Multi-channel nozzle and reactor
CN109939619B (en) * 2019-04-26 2022-02-25 河南百优福生物能源有限公司 Rotational flow cushion layer feeder of biomass pyrolysis liquid fluidized bed reactor and application thereof

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Publication number Priority date Publication date Assignee Title
US4705535A (en) * 1986-03-13 1987-11-10 The Dow Chemical Company Nozzle for achieving constant mixing energy
CN2156396Y (en) * 1993-04-10 1994-02-16 煤炭科学研究总院北京市煤化学研究所 Powder coal fluidized bed gasified furnace
JP2002249786A (en) * 2001-02-27 2002-09-06 Babcock Hitachi Kk Feedstock-jetting burner
JP2003113383A (en) * 2001-10-01 2003-04-18 Babcock Hitachi Kk Gas flow layer gasification furnace, method of gasification and methane-reforming burner used therefor and method for reforming
CN1662633A (en) * 2002-04-18 2005-08-31 伊斯曼化学公司 Coal gasification feed injector shield with oxidation-resistant insert

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4705535A (en) * 1986-03-13 1987-11-10 The Dow Chemical Company Nozzle for achieving constant mixing energy
CN2156396Y (en) * 1993-04-10 1994-02-16 煤炭科学研究总院北京市煤化学研究所 Powder coal fluidized bed gasified furnace
JP2002249786A (en) * 2001-02-27 2002-09-06 Babcock Hitachi Kk Feedstock-jetting burner
JP2003113383A (en) * 2001-10-01 2003-04-18 Babcock Hitachi Kk Gas flow layer gasification furnace, method of gasification and methane-reforming burner used therefor and method for reforming
CN1662633A (en) * 2002-04-18 2005-08-31 伊斯曼化学公司 Coal gasification feed injector shield with oxidation-resistant insert

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