CN101480177A - Aqueous emulsion containing bamboo vinegar pesticide as well as preparation method and use thereof - Google Patents
Aqueous emulsion containing bamboo vinegar pesticide as well as preparation method and use thereof Download PDFInfo
- Publication number
- CN101480177A CN101480177A CNA2009100767008A CN200910076700A CN101480177A CN 101480177 A CN101480177 A CN 101480177A CN A2009100767008 A CNA2009100767008 A CN A2009100767008A CN 200910076700 A CN200910076700 A CN 200910076700A CN 101480177 A CN101480177 A CN 101480177A
- Authority
- CN
- China
- Prior art keywords
- bamboo vinegar
- aqueous emulsion
- pyrethroid
- insecticide aqueous
- percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a bamboo vinegar contained pesticide aqueous emulsion which comprises the following components by weight: 1 to 20 percent of pyrethroid, 5 to 10 percent of organic solvent, 2 to 10 percent of emulsifier, 1 to 3 percent of dispersant, 1 to 5 percent of anti-freeze agent, 0.1 to 3 percent of thickening agent, 30 to 60 percent of bamboo vinegar and balance water. The pyrethroid is shown as a first equation, wherein R1 is a group as follows: Cl2 = CH-, (CH3)2C = CH-, Br2C = CH- or CF3ClC = CH-. The invention also provides a method for preparing the bamboo vinegar contained pesticide aqueous emulsion applied to the prevention of agricultural insects. The bamboo vinegar contained pesticide aqueous emulsion comprises the pyrethroid and the bamboo vinegar and accords with the quality requirements of agricultural preparations without on-site preparation, and moreover, the bamboo vinegar can improve the insecticidal action of the pyrethroid. Compared with the prior agricultural composition only comprising the pyrethroid, the invention achieves the same insecticidal action, decreases the effective ingredient consumption of the pyrethroid by about 50 percent and is non-toxic and pollution-free.
Description
Technical field
The present invention relates to a kind of bamboo vinegar insecticide aqueous emulsion and preparation method thereof, this kind of containing contains application, this kind that bamboo vinegar insecticide aqueous emulsion is used to prevent and treat the insect of cotton, vegetables, fruit tree, tobacco and contains the application that bamboo vinegar insecticide aqueous emulsion is used to prevent and treat cotton bollworm, pink bollworm, cotten aphid, cabbage caterpillar, diamond-back moth, aphid, ceroplastes rubens, leaf miner, oriental tobacco budworm.
Background technology
Along with the raising of agricultural modernization level, modern agricultural chemicals development faces the immense pressure of food, ecology and Environmental security.At first, food security has become global problem, is subjected to the national governments and the people's common concern, and residue of pesticide are the key factors that influence food security, and the usage amount that reduces chemical pesticide becomes common recognition.Secondly, a large amount of organic solvents that use are serious day by day to the influence of environment in the formulations such as missible oil, and developed country is to an organic solvent restriction increasingly stringent, and the low-pollution water base formulations of pesticide become the leading formulation of agricultural chemicals development.The 3rd, the pest pesticide resistance strengthens day by day, and the pesticide combination that exploitation has synergistic effect is subjected to extensive attention, also is one of important measures of answering the antagonism pest.
Bamboo vinegar is an accessory substance of firing bamboo charcoal, and moisture can reach more than 90%, and contains number of chemical compositions such as acetic acid.Studies show that bamboo vinegar has effects such as sterilization, infiltration, and agricultural chemicals is had synergistic effect, can effectively reduce the chemical pesticide consumption.Pyrethroid insectide is a class bionic pesticide, has characteristics such as efficient, low toxicity, low-residual, has critical role on producing, and its output accounts for 20% of insecticide total amount, and usable floor area reaches 25% of total amount.
Though discovery bamboo vinegar and cypermethrin are used with and are had synergistic effect on producing, yet, bamboo vinegar is used for Synergistic fertilizer and carries out the field when using, can only carry out the scene preparation, that is it is now with the current, because bamboo vinegar and agricultural chemicals carry out composite after, the existence that each effective ingredient can not be stable causes difficulty to practical application.Therefore, research and development pyrethroid bamboo vinegar aqueous emulsion has important practical significance, and development prospect is wide.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of bamboo vinegar insecticide aqueous emulsion that contains, its good disinsection effect, and consumption is few, good stability.
In order to solve above technical problem, the invention provides following technical scheme:
A kind of bamboo vinegar insecticide aqueous emulsion that contains comprises following component:
Pyrethroid 1～20%
Organic solvent 5～10%
Emulsifier 2～10%
Dispersant 1～3%
Antifreeze 1～5%
Thickener 0.1～3%
Bamboo vinegar 30～60%
Water surplus;
Each component is all in weight portion, and described pyrethroid is suc as formula shown in (I), wherein, and R
1Be Cl
2C=CH-, (CH
3)
2C=CH-, Br
2C=CH-or CF
3The ClC=CH-group.
Bamboo vinegar is the by product that bamboo charcoal is produced, and by a kind of russet liquid with smoke that bamboo wood and bamboo surplus material of processing obtain in the destructive distillation pyrolytic process, is multiple organic mixture.The purposes of bamboo vinegar is quite extensive, can be applicable to aspects such as agricultural, forestry, livestock breeding, chemical industry, food processing industry and medical and health.Bamboo vinegar has synergy and osmosis to pyrethroid, reduces the agricultural chemicals usage amount, helps from source control agricultural product pesticide residual contamination.。
The main feature of bamboo vinegar and advantage are: the first, derive from natural materials, and free from environmental pollution, people and animals are had no side effect, be the ideal substitute of agricultural chemicals; The second, processing and refining method is simple, and is with low cost, and economic benefit is considerable.China's bamboo timber resource is abundant, and the processing and utilization of bamboo wood comes into one's own day by day.The development and utilization of bamboo vinegar not only helps protecting environment, improves the safety of food, and helps the comprehensive utilization of bamboo timber resource.
Pyrethroid is the broad spectrum pesticide that a class can be prevented and treated various pests, and its insecticidal toxicity improves 10～100 times than older generation insecticide as organochlorine, organic phosphor, carbamates.Pyrethroid has strong action of contace poison to insect, and some kind has stomach toxicity or fumigation action concurrently, but does not all have systemic action.Its mechanism of action is to upset the normal physiological of insect nerve, makes it by excited, spasm death to benumbing.Pyrethroid is little because of consumption, working concentration is low, thus safer to people and animals, very little to the pollution of environment.
The bamboo vinegar insecticide aqueous emulsion that contains provided by the present invention, bamboo vinegar and pyrethroid preparation are become stable insecticide aqueous emulsion, and this insecticide aqueous emulsion meets the pesticidal preparations quality requirement, and the storage time can reach 2 years, therefore can directly use and needn't be on-the-spot composite, easy to use; Compare with the composition pesticide that has only pyrethroid in the prior art, reaching under the situation of identical insecticidal effect, the pyrethroid effective ingredient consumption reduces about 50%, and nontoxic pollution-free.Pyrethroid is also referred to as pyrethroid insecticides or intends the chrysanthemum ester.
Preferably, described organic solvent is at least a in methyl alcohol, ethanol, isopropyl alcohol, isooctanol, isobutanol, cyclohexanone, acetone, MEK, tributyl phosphate, ethyl acetate, dimethyl formamide, dimethylaniline, the benzene,toluene,xylene.
Preferably, described emulsifier is at least a in alkylphenol polyoxyethylene, castor oil polyoxyethylene ether, phenethyl phenol polyethenoxy ether, phenolic resins APEO, fatty alcohol-polyoxyethylene ether, polyoxyethylene carboxylate and derivative thereof, the alkyl benzene calcium sulfonate.
Preferably, described dispersant is at least a in the sweet monostearate APEO of sorbitan monooleate APEO, sorbitol, phosphate, sulfuric ester, the polyvinyl alcohol.
Preferably, described antifreeze is at least a in ethylene glycol, propane diols, glycerine, polyethylene glycol, isopropyl alcohol, butanols, urea, ammonium sulfate, sodium chloride, the calcium chloride.
Preferably, described thickener is at least a in Magnesiumaluminumsilicate, polyacrylate, carboxymethyl cellulose, yellow first glue, the PAA.
The present invention also provides a kind of above-mentioned preparation method who contains bamboo vinegar insecticide aqueous emulsion, comprises the steps:
A) pyrethroid, emulsifier, organic solvent, dispersant are uniformly mixed into oil phase; Antifreeze, thickener and bamboo vinegar are uniformly mixed into water;
B) described oil phase is being carried out in described oil phase, drip water under the situation of high-speed stirred, promptly getting and contain bamboo vinegar insecticide aqueous emulsion.
Water refers to the liquid phase that can dissolve each other with water in the step a); When containing water in containing bamboo vinegar insecticide aqueous emulsion, then this step a) is for to be uniformly mixed into oil phase with pyrethroid, emulsifier, organic solvent, dispersant; Antifreeze, thickener, bamboo vinegar and water are uniformly mixed into water.
The present invention also provides a kind of above-mentioned application that bamboo vinegar insecticide aqueous emulsion is used to prevent and treat the insect of cotton, vegetables, fruit tree, tobacco that contains.
The present invention also provides a kind of above-mentioned application that bamboo vinegar insecticide aqueous emulsion is used to prevent and treat cotton bollworm, pink bollworm, cotten aphid, cabbage caterpillar, diamond-back moth, aphid, ceroplastes rubens, leaf miner, oriental tobacco budworm that contains.
The bamboo vinegar insecticide aqueous emulsion that contains provided by the invention contains pyrethroid and bamboo vinegar, and the bamboo vinegar insecticide aqueous emulsion that contains of formation can long preservation, and does not need on-the-spot composite; And bamboo vinegar can improve the insecticidal action of pyrethroid, compares with the composition pesticide that has only pyrethroid in the prior art, reaching under the situation of identical insecticidal effect, and the pyrethroid effective ingredient consumption reduces about 50%, and nontoxic pollution-free.
Embodiment
In order to understand technical scheme provided by the present invention better, set forth below in conjunction with embodiment.
Embodiment 1
Contain bamboo vinegar insecticide aqueous emulsion according to the following steps preparation:
A) pyrethroid, emulsifier, organic solvent, dispersant are uniformly mixed into oil phase; Antifreeze, thickener, bamboo vinegar and water are uniformly mixed into water;
B) described oil phase is being carried out in described oil phase, drip water under the situation of high-speed stirred, promptly getting and contain bamboo vinegar insecticide aqueous emulsion.
Raw material and the consumption thereof used in the step a) see Table 1.Pyrethroid in the present embodiment is a decis, that is the R in the formula (I)
1Be specially Br
2C=CH-.Make the decis weight content and be 2.5% contain bamboo vinegar insecticide aqueous emulsion.
Embodiment 2
The preparation process that contains bamboo vinegar insecticide aqueous emulsion is identical with embodiment 1.Difference is that raw material and the consumption thereof used in the step a) see Table 2.Pyrethroid in the present embodiment is a cypermethrin, that is the R in the formula (I)
1Be specially Cl
2C=CH-.Make the cypermethrin weight content and be 5% contain bamboo vinegar insecticide aqueous emulsion.
Table 1
Table 2
Embodiment 3
The preparation process that contains bamboo vinegar insecticide aqueous emulsion is identical with embodiment 1.Difference is that raw material and the consumption thereof used in the step a) see Table 3.Do not have water in the table 3, the aqueous phase in the expression step a) is not moisture.Pyrethroid in the present embodiment is a fenpropathrin, that is the R in the formula (I)
1Be specially (CH
3)
2C=CH-.Make the fenpropathrin weight content and be 20% contain bamboo vinegar insecticide aqueous emulsion.
Table 3
Embodiment 1～3 is prepared contain bamboo vinegar insecticide aqueous emulsion can both long term storage, meet the pesticidal preparations quality requirement.
Embodiment 4
Embodiment 1, embodiment 2 and the embodiment 3 prepared bamboo vinegar insecticide aqueous emulsions that contain are carried out stability test, and the method for testing accepted standard is all undertaken by standard GB-1603, and test result is shown in Table 4.
Table 4
As can be seen from Table 4, the every technical indicator of bamboo vinegar insecticide aqueous emulsion that contains provided by the present invention meets quality of the pharmaceutical preparations control requirement.
Embodiment 5
Utilize embodiment 2 prepared contain bamboo vinegar insecticide aqueous emulsion, carry out field control effectiveness test, be used to prevent and treat cabbage caterpillar.And utilize 5% high performance aqueous emulsion of cypermethrin of the prior art to compare test simultaneously.The result of comparative trial is as shown in table 5.
Table 5
| The medicament numbering | Dosing (aig/ha) | 1 day preventive effect (%) behind the medicine | 3 days preventive effects (%) behind the medicine | 7 days preventive effects (%) behind the medicine |
| Embodiment 2 | 18 | 79.19 | 82.31 | 88.50 |
| Prior art | 36 | 77.88 | 82.80 | 87.22 |
Test effect data in the table 5 are 4 tests mean value of gained afterwards.Aig/ha is the weight of the used pesticide active ingredient of hectare, in gram.
As can be seen from Table 5, be under half the situation of prior art in dosage, control efficiency still can obtain the control efficiency suitable with prior art, and the control efficiency that also is higher than prior art after 1 day with the control efficiency after 7 days, therefore bamboo vinegar has obvious synergistic effect for pyrethroid as can be seen, can reduce pesticide dosage, alleviate the pressure of agricultural chemicals environment.
The above only is a preferred implementation of the present invention; should be pointed out that for those skilled in the art, under the prerequisite that does not break away from the principle of the invention; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (9)
1, a kind of bamboo vinegar insecticide aqueous emulsion that contains comprises following component:
Pyrethroid 1～20%
Organic solvent 5～10%
Emulsifier 2～10%
Dispersant 1～3%
Antifreeze 1～5%
Thickener 0.1～3%
Bamboo vinegar 30～60%
Water surplus;
Each component is all in weight portion, and described pyrethroid is suc as formula shown in (I), wherein, and R
1Be C1
2C=CH-, (CH
3)
2C=CH-, Br
2C=CH-or CF
3The C1C=CH-group.
2, the bamboo vinegar insecticide aqueous emulsion that contains according to claim 1, it is characterized in that described organic solvent is at least a in methyl alcohol, ethanol, isopropyl alcohol, isooctanol, isobutanol, cyclohexanone, acetone, MEK, tributyl phosphate, ethyl acetate, dimethyl formamide, dimethylaniline, the benzene,toluene,xylene.
3, the bamboo vinegar insecticide aqueous emulsion that contains according to claim 1, it is characterized in that described emulsifier is at least a in alkylphenol polyoxyethylene, castor oil polyoxyethylene ether, phenethyl phenol polyethenoxy ether, phenolic resins APEO, fatty alcohol-polyoxyethylene ether, polyoxyethylene carboxylate and derivative thereof, the alkyl benzene calcium sulfonate.
4, the bamboo vinegar insecticide aqueous emulsion that contains according to claim 1, it is characterized in that described dispersant is at least a in the sweet monostearate APEO of sorbitan monooleate APEO, sorbitol, phosphate, sulfuric ester, the polyvinyl alcohol.
5, the bamboo vinegar insecticide aqueous emulsion that contains according to claim 1 is characterized in that, described antifreeze is at least a in ethylene glycol, propane diols, glycerine, polyethylene glycol, isopropyl alcohol, butanols, urea, ammonium sulfate, sodium chloride, the calcium chloride.
6, the bamboo vinegar insecticide aqueous emulsion that contains according to claim 1 is characterized in that, described thickener is at least a in Magnesiumaluminumsilicate, polyacrylate, carboxymethyl cellulose, yellow first glue, the PAA.
7, the described preparation method who contains bamboo vinegar insecticide aqueous emulsion of claim 1 comprises the steps:
A) pyrethroid, emulsifier, organic solvent, dispersant are uniformly mixed into oil phase; Antifreeze, thickener and bamboo vinegar are uniformly mixed into water;
B) described oil phase is being carried out in described oil phase, drip water under the situation of high-speed stirred, promptly getting and contain bamboo vinegar insecticide aqueous emulsion.
8, in the claim 1～6 any one describedly contain the application that bamboo vinegar insecticide aqueous emulsion is used to prevent and treat the insect of cotton, vegetables, fruit tree, tobacco.
9, in the claim 1～6 any one describedly contain the application that bamboo vinegar insecticide aqueous emulsion is used to prevent and treat cotton bollworm, pink bollworm, cotten aphid, cabbage caterpillar, diamond-back moth, aphid, ceroplastes rubens, leaf miner, oriental tobacco budworm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910076700A CN101480177B (en) | 2009-01-15 | 2009-01-15 | Aqueous emulsion containing bamboo vinegar pesticide as well as preparation method and use thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910076700A CN101480177B (en) | 2009-01-15 | 2009-01-15 | Aqueous emulsion containing bamboo vinegar pesticide as well as preparation method and use thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101480177A true CN101480177A (en) | 2009-07-15 |
| CN101480177B CN101480177B (en) | 2012-10-10 |
Family
ID=40877596
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200910076700A Expired - Fee Related CN101480177B (en) | 2009-01-15 | 2009-01-15 | Aqueous emulsion containing bamboo vinegar pesticide as well as preparation method and use thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101480177B (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101926385A (en) * | 2010-08-25 | 2010-12-29 | 国际竹藤网络中心 | Composite for antiseptic preservation of fruits and vegetables |
| CN106332921A (en) * | 2016-08-22 | 2017-01-18 | 吉林大学 | Botanical insecticide and preparation method and application thereof |
| CN110150327A (en) * | 2019-06-18 | 2019-08-23 | 杨晓艳 | A kind of compound biological herbicide and its application method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001213705A (en) * | 2000-02-03 | 2001-08-07 | Nittoh Co Ltd | Repellent for underfloor harmful insects and repellent method for harmful insects |
| CN1520728A (en) * | 2003-01-29 | 2004-08-18 | 江 徐 | Natural bamboo leachate mosquito-killing disinfector preparation method and its application |
| CN1802910A (en) * | 2006-01-24 | 2006-07-19 | 浙江林学院 | Agricultural chemicals preparation containing pyracetic acid |
| CN101036457A (en) * | 2006-03-14 | 2007-09-19 | 北京华京五方实用纳米科技开发有限公司 | Microemulsion |
-
2009
- 2009-01-15 CN CN200910076700A patent/CN101480177B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001213705A (en) * | 2000-02-03 | 2001-08-07 | Nittoh Co Ltd | Repellent for underfloor harmful insects and repellent method for harmful insects |
| CN1520728A (en) * | 2003-01-29 | 2004-08-18 | 江 徐 | Natural bamboo leachate mosquito-killing disinfector preparation method and its application |
| CN1802910A (en) * | 2006-01-24 | 2006-07-19 | 浙江林学院 | Agricultural chemicals preparation containing pyracetic acid |
| CN101036457A (en) * | 2006-03-14 | 2007-09-19 | 北京华京五方实用纳米科技开发有限公司 | Microemulsion |
Non-Patent Citations (1)
| Title |
|---|
| 李小荣, 吴全聪, 刘志龙, 王连生, 丁潮洪: "竹醋液对几种杀虫剂的增效作用", 《浙江农业科学》 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101926385A (en) * | 2010-08-25 | 2010-12-29 | 国际竹藤网络中心 | Composite for antiseptic preservation of fruits and vegetables |
| CN106332921A (en) * | 2016-08-22 | 2017-01-18 | 吉林大学 | Botanical insecticide and preparation method and application thereof |
| CN106332921B (en) * | 2016-08-22 | 2018-09-04 | 吉林大学 | A kind of plant insecticide and its preparation method and application |
| CN110150327A (en) * | 2019-06-18 | 2019-08-23 | 杨晓艳 | A kind of compound biological herbicide and its application method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101480177B (en) | 2012-10-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102283258A (en) | Plant protecting agent for plant source and preparation method thereof | |
| CN101218912A (en) | Deinsectization microbicide of piperine | |
| CN102640762A (en) | Hot fogging concentrate containing acetamiprid | |
| CN101066055A (en) | Pesticide composition containing emamectin benzoate | |
| CN103329943A (en) | Insecticide composition containing natural celastrus angulatus and natural pyrethrin | |
| CN101911955B (en) | Biogenic acaricidal water suspension composition and preparation method thereof | |
| CN108029683A (en) | A kind of aqueous emulsion and its preparation process containing phenthoate dimephenthoate cidial and avermectin | |
| CN102210321A (en) | Pesticide composite containing etoxazole | |
| CN103315006B (en) | Insecticidal composition containing natural celastrus angulatus and natural vitex negundo and application thereof | |
| CN102907420B (en) | Insect aerosol synergist | |
| CN101637172A (en) | Insecticidal/acaricidal composition having lufenuron and tebufenozide | |
| CN101480177B (en) | Aqueous emulsion containing bamboo vinegar pesticide as well as preparation method and use thereof | |
| CN101849549B (en) | Pesticide preparation for preventing and treating rice hoppers and other rice pests | |
| CN101406199A (en) | Insecticidal composition containing emamectin-benzoate | |
| CN108812663B (en) | Application of 2-nonanone as female striped rice borer repellent component and repellent | |
| CN102657216A (en) | Use of pesticide mixed preparation containing chlorpyrifos and high-efficiency cypermethrin in control of Athetis lepigone Moschler | |
| CN101124906B (en) | Nimbin-containing injection formulation for tree trunk and application of nimbin in field of injection for tree trunk | |
| CN109042647B (en) | β -myrcene used as Chilo suppressalis female insect repellent component and repellent | |
| CN106490014A (en) | A kind of plant compound pesticide containing ricidine. and preparation method thereof | |
| CN103734168B (en) | Insecticidal pesticide formulation containing biopesticide-rotenone | |
| CN106900757B (en) | A kind of bitter pueraria root extract and the Pesticidal combination of Osthole and application thereof for preventing and treating agricultural pests | |
| CN100399902C (en) | Pesticides compounds of elliptone and cyfiuthrin and their use as pesticides | |
| CN110024803A (en) | A kind of Pesticidal combination and its preparation of spirotetramat | |
| CN101543224B (en) | Insecticidal composition containing triaguron and chlorpyrifos | |
| CN103704228B (en) | The suspension emulsion of a kind of multiple killing teichomycin and cartap and application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20121010 Termination date: 20160115 |
|
| EXPY | Termination of patent right or utility model |