CN101475824B - 免水洗、节能环保生产清洁燃料油的工艺方法及***装置 - Google Patents
免水洗、节能环保生产清洁燃料油的工艺方法及***装置 Download PDFInfo
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- CN101475824B CN101475824B CN200910042586A CN200910042586A CN101475824B CN 101475824 B CN101475824 B CN 101475824B CN 200910042586 A CN200910042586 A CN 200910042586A CN 200910042586 A CN200910042586 A CN 200910042586A CN 101475824 B CN101475824 B CN 101475824B
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- oil
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- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 claims abstract description 31
- 238000006243 chemical reaction Methods 0.000 claims abstract description 20
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- 238000005292 vacuum distillation Methods 0.000 claims abstract description 5
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 33
- 239000002551 biofuel Substances 0.000 claims description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 27
- 150000002148 esters Chemical class 0.000 claims description 20
- 238000003756 stirring Methods 0.000 claims description 18
- 239000002994 raw material Substances 0.000 claims description 16
- 239000010409 thin film Substances 0.000 claims description 16
- 150000002632 lipids Chemical class 0.000 claims description 15
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 14
- 238000004062 sedimentation Methods 0.000 claims description 13
- 238000005809 transesterification reaction Methods 0.000 claims description 11
- 239000003054 catalyst Substances 0.000 claims description 10
- 235000011187 glycerol Nutrition 0.000 claims description 7
- 230000000694 effects Effects 0.000 claims description 5
- KIDXYAWWICJAFK-UHFFFAOYSA-N O.[Na].OC Chemical compound O.[Na].OC KIDXYAWWICJAFK-UHFFFAOYSA-N 0.000 claims description 4
- 235000013311 vegetables Nutrition 0.000 claims description 3
- 241001465754 Metazoa Species 0.000 claims description 2
- 238000009434 installation Methods 0.000 claims description 2
- 239000010773 plant oil Substances 0.000 claims 1
- 239000000126 substance Substances 0.000 abstract description 16
- 239000012535 impurity Substances 0.000 abstract description 13
- 238000005406 washing Methods 0.000 abstract description 10
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract description 5
- 239000010865 sewage Substances 0.000 abstract description 4
- 238000001179 sorption measurement Methods 0.000 abstract description 3
- 239000012043 crude product Substances 0.000 abstract 3
- 125000004185 ester group Chemical group 0.000 abstract 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 18
- 239000002351 wastewater Substances 0.000 description 10
- 230000018044 dehydration Effects 0.000 description 7
- 238000006297 dehydration reaction Methods 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 238000009834 vaporization Methods 0.000 description 6
- 230000008016 vaporization Effects 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 5
- 239000002283 diesel fuel Substances 0.000 description 5
- 239000000446 fuel Substances 0.000 description 5
- 238000005554 pickling Methods 0.000 description 5
- 235000019387 fatty acid methyl ester Nutrition 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 238000007599 discharging Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 150000004702 methyl esters Chemical class 0.000 description 3
- 238000010025 steaming Methods 0.000 description 3
- 238000003556 assay Methods 0.000 description 2
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- -1 fatty ester methyl esters Chemical class 0.000 description 2
- 150000002194 fatty esters Chemical class 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- GBMDVOWEEQVZKZ-UHFFFAOYSA-N methanol;hydrate Chemical compound O.OC GBMDVOWEEQVZKZ-UHFFFAOYSA-N 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
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- 150000003904 phospholipids Chemical class 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000010734 process oil Substances 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000004065 wastewater treatment Methods 0.000 description 2
- KKADPXVIOXHVKN-UHFFFAOYSA-N 4-hydroxyphenylpyruvic acid Chemical compound OC(=O)C(=O)CC1=CC=C(O)C=C1 KKADPXVIOXHVKN-UHFFFAOYSA-N 0.000 description 1
- 239000002028 Biomass Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003377 acid catalyst Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 238000011033 desalting Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 238000009775 high-speed stirring Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
Images
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
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- Liquid Carbonaceous Fuels (AREA)
- Fats And Perfumes (AREA)
Abstract
Description
每吨生物柴油用水比较 | 现有技术(kg/吨) | 本发明(kg/吨) |
水用量(kg/吨) | 1000 | 95 |
废水待处理量(kg/吨) | 1000 | 可直接排放 |
水及废水处理成本(kg吨) | 20(元) | 0.5(元) |
蒸汽用量(吨/吨) | 2(吨/吨) | 1.5(吨/吨) |
Claims (6)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN200910042586A CN101475824B (zh) | 2009-01-22 | 2009-01-22 | 免水洗、节能环保生产清洁燃料油的工艺方法及***装置 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN200910042586A CN101475824B (zh) | 2009-01-22 | 2009-01-22 | 免水洗、节能环保生产清洁燃料油的工艺方法及***装置 |
Publications (2)
Publication Number | Publication Date |
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CN101475824A CN101475824A (zh) | 2009-07-08 |
CN101475824B true CN101475824B (zh) | 2012-09-19 |
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CN200910042586A Expired - Fee Related CN101475824B (zh) | 2009-01-22 | 2009-01-22 | 免水洗、节能环保生产清洁燃料油的工艺方法及***装置 |
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CN (1) | CN101475824B (zh) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102465058A (zh) * | 2010-11-04 | 2012-05-23 | 朱建军 | 一种制备生物柴油的生产工艺 |
CN102397777B (zh) * | 2011-09-29 | 2013-05-08 | 中兴能源(湖北)有限公司 | 活化稻壳灰的制备方法及其在纯化生物柴油中的应用 |
CN102827213B (zh) * | 2012-08-31 | 2015-12-16 | 连云港正丰生物能源有限公司 | 一种通过废弃的动植物油脂制备蔗糖脂肪酸酯的方法 |
CN104130867A (zh) * | 2014-07-29 | 2014-11-05 | 李安民 | 两步酯化法生产生物柴油的工艺及设备 |
CN109401833B (zh) * | 2018-12-13 | 2023-07-07 | 湖南楚润石化新能源有限公司 | 一种连续、高效环保精炼清洁液体燃料油的精炼方法 |
CN110747015A (zh) * | 2019-11-27 | 2020-02-04 | 金玖洲新能源有限公司 | 一种生物燃料油的制备方法 |
CN112430474A (zh) * | 2020-12-11 | 2021-03-02 | 辽宁中瀛科技有限公司 | 一种高氢生物燃料油的制备装置 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101016473A (zh) * | 2007-03-02 | 2007-08-15 | 安徽省粮油科学研究所 | 劣质油生产生物燃料油的方法 |
CN101153220A (zh) * | 2006-09-28 | 2008-04-02 | 中山市劲爽科技生物燃油研发中心 | 一种生物柴油的制造方法 |
CN101173175A (zh) * | 2006-10-30 | 2008-05-07 | 黑龙江普华经济技术开发有限公司 | 一种利用废弃动植物油脂制备生物柴油的方法 |
-
2009
- 2009-01-22 CN CN200910042586A patent/CN101475824B/zh not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101153220A (zh) * | 2006-09-28 | 2008-04-02 | 中山市劲爽科技生物燃油研发中心 | 一种生物柴油的制造方法 |
CN101173175A (zh) * | 2006-10-30 | 2008-05-07 | 黑龙江普华经济技术开发有限公司 | 一种利用废弃动植物油脂制备生物柴油的方法 |
CN101016473A (zh) * | 2007-03-02 | 2007-08-15 | 安徽省粮油科学研究所 | 劣质油生产生物燃料油的方法 |
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CN101475824A (zh) | 2009-07-08 |
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Owner name: HUBEI MINGYAO NEW ENERGY CO., LTD. Free format text: FORMER OWNER: WANG LI Effective date: 20140529 |
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Free format text: CORRECT: ADDRESS; FROM: 410000 CHANGSHA, HUNAN PROVINCE TO: 434100 JINGZHOU, HUBEI PROVINCE |
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Effective date of registration: 20140529 Address after: 434100, No. 2, Chu Jiang Road, Jiangling County, Hubei, Jingzhou Patentee after: Hubei Ming Yao new energy Co., Ltd. Address before: 410000 Hunan province Changsha Kaifu District, five Ling National Village Bauhinia Garden A building room 603 Patentee before: Wang Li |
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Effective date of registration: 20160408 Address after: 434020 eight ridge town, Jingzhou District, Hubei, Jingzhou Patentee after: JINGZHOU DADY BIOENGINEERING CO., LTD. Address before: 434100, No. 2, Chu Jiang Road, Jiangling County, Hubei, Jingzhou Patentee before: Hubei Ming Yao new energy Co., Ltd. |
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CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20120919 Termination date: 20190122 |
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CF01 | Termination of patent right due to non-payment of annual fee |