CN101475364A - Antistatic powder for antistatic ceramic tile - Google Patents
Antistatic powder for antistatic ceramic tile Download PDFInfo
- Publication number
- CN101475364A CN101475364A CNA200910014123XA CN200910014123A CN101475364A CN 101475364 A CN101475364 A CN 101475364A CN A200910014123X A CNA200910014123X A CN A200910014123XA CN 200910014123 A CN200910014123 A CN 200910014123A CN 101475364 A CN101475364 A CN 101475364A
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- CN
- China
- Prior art keywords
- antistatic
- powder
- ceramic tile
- glaze
- static
- Prior art date
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Links
- 239000000843 powder Substances 0.000 title claims abstract description 34
- 239000000919 ceramic Substances 0.000 title claims abstract description 33
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 20
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000011787 zinc oxide Substances 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims description 12
- GHPGOEFPKIHBNM-UHFFFAOYSA-N antimony(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Sb+3].[Sb+3] GHPGOEFPKIHBNM-UHFFFAOYSA-N 0.000 claims description 7
- 229910006404 SnO 2 Inorganic materials 0.000 claims description 2
- 239000011449 brick Substances 0.000 abstract description 8
- 230000003068 static effect Effects 0.000 abstract description 8
- 230000005611 electricity Effects 0.000 abstract description 6
- 230000036541 health Effects 0.000 abstract description 3
- 229910000410 antimony oxide Inorganic materials 0.000 abstract 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 abstract 1
- 229910001887 tin oxide Inorganic materials 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 description 16
- 238000007639 printing Methods 0.000 description 10
- 238000010304 firing Methods 0.000 description 8
- 239000002994 raw material Substances 0.000 description 8
- 239000000758 substrate Substances 0.000 description 7
- 238000012216 screening Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 238000005303 weighing Methods 0.000 description 5
- 238000000748 compression moulding Methods 0.000 description 4
- 239000012467 final product Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000003825 pressing Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 230000003712 anti-aging effect Effects 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 229910052573 porcelain Inorganic materials 0.000 description 3
- 238000001694 spray drying Methods 0.000 description 3
- 229910052572 stoneware Inorganic materials 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 235000012222 talc Nutrition 0.000 description 2
- 239000000454 talc Substances 0.000 description 2
- 229910052623 talc Inorganic materials 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000009941 weaving Methods 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 229910052656 albite Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- BNWPUUZJGBXAFM-UHFFFAOYSA-N azane oxalonitrile Chemical compound N.N#CC#N BNWPUUZJGBXAFM-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 230000009758 senescence Effects 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
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- Finishing Walls (AREA)
Abstract
The invention relates to antistatic powder for an antistatic ceramic brick, is used for producing the antistatic ceramic brick, and belongs to the technical field of architectural ceramics. The antistatic powder comprises the following components in mass percentage: 60 to 80 percent of tin oxide, 10 to 39 percent of zinc oxide and 0.2 to 10 percent of antimony oxide. The antistatic powder can be conveniently used for producing the antistatic ceramic brick to eliminate the static electricity, promote the human health, and protect a high precision apparatus.
Description
Technical field
The present invention relates to a kind of antistatic powder for antistatic ceramic tile, be used to produce anti-static ceramic tile, belong to the architectural pottery technical field.
Background technology
In daily life, especially in northern exsiccant winter, indoor have " " everywhere, touches door handle and can be shocked by electricity, and touches water pipe and can be shocked by electricity, and goes home to hold a baby in one's arms and also can be shocked by electricity, even unblank to touch keyhole, also can be shocked by electricity.Discover that these electric shock phenomenons bring very big harm can for people's body ﹠ mind, influence the physiological equilibrium of personal human body, cause all illness subtlely, quicken human senescence.
Electrostatic phenomenon is very general in production, processing and the use of information industry, weaving industry, petrochemical complex, plastics and rubber industry, paint industry etc.Gathering of static electric charge may cause very big harm, and the hertzian wave that produces during as static discharge may disturb the work of precision electronic device, even cause the flase operation of automotive electronics; Pharmaceutically draw dirt, drawing bacterium; Cause the electricity accident of quivering on the medical operating; Cause fire, blast on mine, the petrochemical complex; Cause that on electronic industry unicircuit destroys; In weaving, cause fibril aggregation or the like.In the material of construction of anti-electrostatic, what research at present and application were maximum is polymkeric substance Antistatic Paint and earth material, and these materials add conducting material such as metal and carbon black in polymkeric substance makes, as epoxy and trichlorine cyanogen ammonia Antistatic Paint, floor etc.Though this class material improved to some extent at anti-aging, anti-soil, aspect such as wear-resisting in recent years, be difficult to solve problem such as weather resistance and fire resistance be not good enough.Though the anti-electrostatic terrazzo that occurs has better solved fire safety problem in the recent period, its powder amount index is still higher, has limited it in clean room and machine room application in engineering.
Summary of the invention
The object of the present invention is to provide a kind of antistatic powder for antistatic ceramic tile, can make anti-static ceramic tile easily,, promote health, the use of protection highly sophisticated device to eliminate static.
Antistatic powder for antistatic ceramic tile of the present invention, its batching quality percentage composition is: stannic oxide 60～80%, zinc oxide 10～39% and weisspiessglanz 0.2～10%.
Wherein:
Stannic oxide purity is: SnO
2Content 〉=98%;
Zinc oxide purity is: ZnO content 〉=99%;
Weisspiessglanz purity is: Sb
2O
3Content 〉=98%.
Batching is put into equipment such as high aluminium ball grinding machine and mixed and get final product, generally need to mix 3～6 hours, cross 120 mesh sieves.
The same with additive, can directly add ceramic body batching, glaze batching to or/and use in the stamp glaze and get final product.In base substrate batching, can account for 10～25% of weight, i.e. 10～25% powder for antistatic, 75～90%; In the glaze batching, can account for 35～55%; In stamp glaze batching, can account for 40～60%.
The anti-static ceramic tile that obtains, not only antistatic performance is stable, and has the advantage that other antistatic materials such as attractive and durable, fire prevention, corrosion resistant, anti-aging, resistance to compression are difficult to all have concurrently, is a kind of novel antistatic material.By laying anti-static ceramic tile, static can be drawn and let out in the earth, change the normal current potential of body surface, make between human body and the earth and form equi-potential, avoided the electric shock phenomenon, eliminated the discomfort that electric shock is brought, promote healthy.Eliminate static, also satisfied the Working environment requirement and must not have the electrostatic requirement, the use of protection highly sophisticated device; Eliminate static, also help environment protection, meet ecological requirement.
After the batching, utilize common floor tile production technique to get final product.General technological process is as follows:
Body preparation:
Each is prepared burden grinds into mud into barreling, and powdered granule is made in oven dry then, through pressing machine compression moulding, after the oven dry work in-process---base substrate.
Glaze preparation and glazing:
Each is prepared burden grinds into glaze slip into barreling, dries after glazing on the base substrate.
In the time of need applying printing glaze, equally prepare printing glaze, apply printing glaze with the glaze preparation.Printing glaze adds corresponding toner according to the requirement difference of pattern, requires operation to get final product according to routine.
Product burns till: firing period 50～90 minutes, 1050～1260 ℃ of firing temperatures get product after burning till.
Through laying evidence, with the anti-static ceramic tile that powder for antistatic of the present invention is made, not only attractive and durable, fire prevention, corrosion resistant, anti-aging, resistance to compression, and also after testing, surface resistivity and volume resistance are: 1 * 10
6～1 * 10
9Ω, conformance with standard≤1 * 10
9The requirement of Ω can be eliminated static, promotes health protection live and work environment, the use of protection highly sophisticated device.
Embodiment
The invention will be further described below in conjunction with embodiment.
(continued on next page)
Testing raw materials used chemical quality percentage composition sees the following form
| SiO 2 | Al 2O 3 | Fe 2O 3 | TiO 2 | CaO | MgO | K 2O | Na 2O | Burn and lose | |
| Potassium felspar sand | 65.33 | 19.66 | 0.02 | 0.06 | 0.04 | 10.80 | 3.32 | 0.68 | |
| Albite | 72.33 | 15.38 | 0.07 | 0.69 | 0.13 | 2.01 | 8.77 | 0.38 | |
| Calcite | 56.03 | 18.00 | 25.50 | ||||||
| Burn talcum | 64.30 | 34.06 | |||||||
| Calcined earth | 56.40 | 42.80 | |||||||
| Kaolin | 52.50 | 38.23 | 8.40 | ||||||
| Feldspar | 70.01 | 16.43 | 0.37 | 0.52 | 0.35 | 2.77 | 8.10 | 0.39 | |
| Clay | 71.42 | 14.91 | 0.70 | 0.06 | 1.77 | 3.18 | 1.22 | 0.55 | 6.19 |
| Flint clay | 44.69 | 39.27 | 0.50 | 0.08 | 0.17 | 0.38 | 13.96 | ||
| Talcum | 59.56 | 1.51 | 0.38 | 0.11 | 0.40 | 32.37 | 0.02 | 0.05 | 5.59 |
| Quartzy | 99.20 | 0.09 | 0.70 |
The composition deficiency of raw material in the table, surplus is conventional dirt, ore deposit, ground raw material is kept away carrying secretly of unavoidable dirt, thinks pure also not pure.
Other raw material is a technical pure chemical industry raw material.
The quality percentage composition of frit is: R
2O (K
2O and Na
2O's and) 4.07%, CaO8.2%, BaO1.5%, ZnO6.2%, PbO 0.47%, Al
2O
38.7%, B
2O
32.67%, SiO
267.38% and ZrO
20.81%.
The making of embodiment 1, anti-electrostatic ceramic brick.
The quality percentage composition of conducting powder is: the weisspiessglanz of stannic oxide 70%, zinc oxide 15% and surplus.
1.1 blank preparation:
1.1.1 the powder for antistatic of 11% anti-static ceramic tile, 89% conventional ceramic adobe body raw material (pressing siccative weight calculates)
Add an amount of water in the suction pit again and mix 1.1.2 be placed on, and old 13 hours.
1.1.3 mud is crossed 80 order vibratory screening apparatuss, by spray-drying tower powder process.
1.1.4 compression moulding.
1.2 glaze preparation:
1.2.1 the powder for antistatic of 45% anti-static ceramic tile, the common glaze of 55% weight is put into ball mill and is ground.
1.2.2 the glaze slip fineness is ground to tails over 0.5%/100ml, use 325 sub-sieves.
1.2.3 cross 120 order vibratory screening apparatuss, it is stand-by to put into jar.
1.3 the preparation of printing glaze
1.3.1 according to taking by weighing tinctorial pattern without pattern
1.3.2 weight proportion: common printed powder 41%, the powder for antistatic 59% of anti-static ceramic tile.
1.3.3 take by weighing the stamp emulsifiable paste 60% of purchase, the 1.3.1 of remaining 40% weight and 1.3.2 are all put into mixing tank stirred 25 minutes, cross 250 order vibration screens, put into container, stand-by.
1.4 the preparation of anti-electrostatic ceramic brick
1.4.1, dry by 265 ℃ of pyritous dry kilns with the base substrate after the moulding.
1.4.2 1.2 glaze that prepare are sprayed on billet surface.
1.4.3 1.3 printing glazes that prepare are imprinted on the glaze that is sprayed with antistatic performance.
1.4.4 go into klining, firing temperature is 1080 ℃, firing time is 50 minutes, detects through electrical property, and surface resistivity is 2 * 10
7Ω, volume resistance are 4 * 10
7Ω.
The making of embodiment 2, anti-electrostatic fine stoneware tile.
The quality percentage composition of conducting powder is: the weisspiessglanz of stannic oxide 75%, zinc oxide 20% and surplus.
2.1 blank preparation:
2.1.1 the powder for antistatic of 15% anti-static ceramic tile, 85% ceramic fine stoneware tile blank raw material (pressing siccative weight calculates)
Add an amount of water in the suction pit again and mix 2.1.2 be placed on, and old 14 hours.
2.1.3 mud is crossed 80 order vibratory screening apparatuss, by spray-drying tower powder process.
2.1.4 compression moulding.
2.2 glaze preparation:
2.2.1 the powder for antistatic of 50% anti-static ceramic tile, the common glaze of 50% weight is put into ball mill and is ground.
2.2.2 the glaze slip fineness is ground to tails over 0.7%/100ml, use 325 sub-sieves.
2.2.3 cross 120 order vibratory screening apparatuss, it is stand-by to put into jar.
2.3 the preparation of printing glaze
2.3.1 according to taking by weighing tinctorial pattern without pattern
2.3.2 weight proportion: common printed powder 50%, the powder for antistatic 50% of anti-static ceramic tile.
2.3.3 take by weighing the stamp emulsifiable paste 60% of purchase, the 1.3.1 of 40% residuals weight and 1.3.2 are all put into mixing tank stirred 25 minutes, cross 250 order vibration screens, put into container, stand-by.
2.4 the preparation of anti-electrostatic fine stoneware tile
2.4.1, dry by 275 ℃ of pyritous dry kilns with the base substrate after the moulding.
2.4.2 1.2 glaze that prepare are sprayed on billet surface.
2.4.3 1.3 printing glazes that prepare are imprinted on the glaze that is sprayed with antistatic performance.
2.4.4 go into klining, firing temperature is 1190 ℃, firing time is 55 minutes, detects through electrical property, and surface resistivity is 3 * 10
8Ω, volume resistance are 6 * 10
7Ω.
The making of embodiment 3, anti-electrostatic porcelain brick.
The quality percentage composition of conducting powder is: the weisspiessglanz of stannic oxide 62%, zinc oxide 16% and surplus.
3.1 blank preparation:
3.1.1 the powder for antistatic of 15% anti-static ceramic tile, 85% porcelain brick blank raw material (pressing siccative weight calculates)
Add an amount of water in the suction pit again and mix 3.1.2 be placed on, and old 13 hours.
3.1.3 mud is crossed 80 order vibratory screening apparatuss, by spray-drying tower powder process.
3.1.4 compression moulding.
3.2 glaze preparation:
3.2.1 the powder for antistatic of 53% anti-static ceramic tile, the common glaze of 47% weight is put into ball mill and is ground.
3.2.2 the glaze slip fineness is ground to tails over 0.7%/100ml, use 325 sub-sieves.
3.2.3 cross 120 order vibratory screening apparatuss, it is stand-by to put into jar.
3.3 the preparation of printing glaze
3.3.1 according to taking by weighing tinctorial pattern without pattern
3.3.2 weight proportion: common printed powder 50%, the powder for antistatic 50% of anti-static ceramic tile.
3.3.3 claim to go the stamp emulsifiable paste 60% bought, the 1.3.1 of 40% residuals weight and 1.3.2 all to be put into batch mixing lack and stirred 25 minutes, mistake 250 order vibration screens are put into container, and are stand-by.
3.4 the preparation of anti-electrostatic porcelain brick
3.4.1, dry by 275 ℃ of pyritous dry kilns with the base substrate after the moulding.
3.4.2 1.2 glaze that prepare are sprayed on billet surface.
3.4.3 1.3 printing glazes that prepare are imprinted on the glaze that is sprayed with antistatic performance.
3.4.4 go into klining, firing temperature is 1210 ℃, firing time is 60 minutes, detects through electrical property, and surface resistivity is 1 * 10
7Ω, volume resistance are 2 * 10
8Ω.
(continued on next page)
Other comprises base substrate and glaze layer with the anti-static ceramic tile that powder for antistatic of the present invention is made, and its ingredients by weight composition sees the following form:
Other carries out according to conventional preparation technology.
Claims (4)
1, a kind of antistatic powder for antistatic ceramic tile is characterized in that its batching quality percentage composition is: stannic oxide 60～80%, zinc oxide 10～39% and weisspiessglanz 0.2～10%.
2, antistatic powder for antistatic ceramic tile according to claim 1 is characterized in that stannic oxide purity is: SnO
2Content 〉=98%.
3, antistatic powder for antistatic ceramic tile according to claim 1 is characterized in that zinc oxide purity is: ZnO content 〉=99%.
4, antistatic powder for antistatic ceramic tile according to claim 1 is characterized in that weisspiessglanz purity is: Sb
2O
3Content 〉=98%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910014123XA CN101475364B (en) | 2009-02-02 | 2009-02-02 | Antistatic powder for antistatic ceramic tile |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910014123XA CN101475364B (en) | 2009-02-02 | 2009-02-02 | Antistatic powder for antistatic ceramic tile |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101475364A true CN101475364A (en) | 2009-07-08 |
| CN101475364B CN101475364B (en) | 2011-10-19 |
Family
ID=40836155
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200910014123XA Active CN101475364B (en) | 2009-02-02 | 2009-02-02 | Antistatic powder for antistatic ceramic tile |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101475364B (en) |
Cited By (17)
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| CN102030519A (en) * | 2010-11-30 | 2011-04-27 | 广东特地陶瓷有限公司 | Anti-static ceramic brick and production method thereof |
| CN101708988B (en) * | 2009-11-24 | 2011-09-14 | 袁国梁 | Compound conductive powder for anti-static ceramic tile |
| CN102219525A (en) * | 2011-05-10 | 2011-10-19 | 广东东鹏陶瓷股份有限公司 | Anti-static ceramic tile and manufacturing method thereof |
| CN102418407A (en) * | 2011-10-11 | 2012-04-18 | 信益陶瓷(中国)有限公司 | Anti-static ceramic tile |
| CN102543247A (en) * | 2012-01-14 | 2012-07-04 | 佛山市中国科学院上海硅酸盐研究所陶瓷研发中心 | Composite conductive powder |
| CN102568639A (en) * | 2012-01-14 | 2012-07-11 | 佛山市中国科学院上海硅酸盐研究所陶瓷研发中心 | Light-colored composite conductive powder |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ATE113266T1 (en) * | 1991-08-23 | 1994-11-15 | Coopcostruttori Societa Cooper | PROCESS FOR THE MANUFACTURE OF ANTISTATIC CERAMIC TILES WITH LOW WATER ABSORPTION CAPACITY. |
| ES2143402B1 (en) * | 1998-03-05 | 2001-01-01 | Colorobbia Espana Sa | FRITA DOPANTE SUITABLE FOR THE MANUFACTURE OF DRIVING CERAMIC Enamels. |
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2009
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| CN102030519B (en) * | 2010-11-30 | 2013-02-13 | 广东特地陶瓷有限公司 | Anti-static ceramic brick and production method thereof |
| CN102030519A (en) * | 2010-11-30 | 2011-04-27 | 广东特地陶瓷有限公司 | Anti-static ceramic brick and production method thereof |
| CN102219525A (en) * | 2011-05-10 | 2011-10-19 | 广东东鹏陶瓷股份有限公司 | Anti-static ceramic tile and manufacturing method thereof |
| CN102219525B (en) * | 2011-05-10 | 2013-09-11 | 广东东鹏陶瓷股份有限公司 | Anti-static ceramic tile and manufacturing method thereof |
| CN102418407A (en) * | 2011-10-11 | 2012-04-18 | 信益陶瓷(中国)有限公司 | Anti-static ceramic tile |
| CN102543247B (en) * | 2012-01-14 | 2015-12-09 | 佛山市中国科学院上海硅酸盐研究所陶瓷研发中心 | A kind of composite conductive powder |
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| CN102568639A (en) * | 2012-01-14 | 2012-07-11 | 佛山市中国科学院上海硅酸盐研究所陶瓷研发中心 | Light-colored composite conductive powder |
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| CN102561656B (en) * | 2012-02-15 | 2014-01-08 | 山东电盾科技有限公司 | Anti-static ceramic-wood composite floor |
| CN104860658A (en) * | 2015-05-04 | 2015-08-26 | 安徽省亚欧陶瓷有限责任公司 | Anti-static ceramic tile and production method thereof |
| CN105174815A (en) * | 2015-08-21 | 2015-12-23 | 武汉大江豪新材料有限公司 | Microlite environment-friendly base material and multifunctional plate |
| CN105174815B (en) * | 2015-08-21 | 2017-05-24 | 武汉大江豪新材料有限公司 | Microlite environment-friendly base material and multifunctional plate |
| CN105837169A (en) * | 2016-04-25 | 2016-08-10 | 山东电盾科技有限公司 | Anti-static antimicrobial ceramic tile prepared from coal ash and preparation method of anti-static antimicrobial ceramic tile |
| CN105924136A (en) * | 2016-04-25 | 2016-09-07 | 山东电盾科技有限公司 | Antistatic ceramic tile prepared from fly ash and preparation method thereof |
| CN105924133A (en) * | 2016-04-25 | 2016-09-07 | 山东电盾科技有限公司 | Antistatic ceramic tile and production method thereof |
| CN105924132A (en) * | 2016-04-25 | 2016-09-07 | 山东电盾科技有限公司 | Antistatic electromagnetic shielding ceramic brick and preparation method thereof |
| CN106045478A (en) * | 2016-05-31 | 2016-10-26 | 淄博成畅建筑陶瓷有限公司 | Anti-static ink-jet polished tile and preparing method thereof |
| CN106045478B (en) * | 2016-05-31 | 2019-03-22 | 淄博成畅建筑陶瓷有限公司 | Antistatic ink-jet polished bricks and preparation method thereof |
| CN106116569A (en) * | 2016-06-28 | 2016-11-16 | 郭舒洋 | A kind of preparation method of green antistatic zirconia ceramics |
| CN108640651A (en) * | 2018-07-05 | 2018-10-12 | 常州五荣化工有限公司 | A kind of anti-static ceramic tile and preparation method thereof |
| CN110804331A (en) * | 2019-11-20 | 2020-02-18 | 佛山市东鹏陶瓷有限公司 | Antistatic agent, preparation method thereof, and preparation methods of paint and ceramic tile using antistatic agent |
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