CN101469088B - Composition and nano clay composite material containing the same - Google Patents
Composition and nano clay composite material containing the same Download PDFInfo
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- CN101469088B CN101469088B CN2007103008306A CN200710300830A CN101469088B CN 101469088 B CN101469088 B CN 101469088B CN 2007103008306 A CN2007103008306 A CN 2007103008306A CN 200710300830 A CN200710300830 A CN 200710300830A CN 101469088 B CN101469088 B CN 101469088B
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- 239000000203 mixture Substances 0.000 title claims abstract description 79
- 239000002131 composite material Substances 0.000 title claims abstract description 37
- 239000012802 nanoclay Substances 0.000 title claims description 32
- 229920000642 polymer Polymers 0.000 claims abstract description 85
- 239000000843 powder Substances 0.000 claims abstract description 40
- 238000002156 mixing Methods 0.000 claims abstract description 27
- 239000000463 material Substances 0.000 claims description 48
- 239000003795 chemical substances by application Substances 0.000 claims description 37
- 239000013543 active substance Substances 0.000 claims description 33
- -1 polyoxyethylene Polymers 0.000 claims description 30
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 18
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 15
- 239000011538 cleaning material Substances 0.000 claims description 15
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
- 239000011858 nanopowder Substances 0.000 claims description 11
- 239000000178 monomer Substances 0.000 claims description 9
- URAYPUMNDPQOKB-UHFFFAOYSA-N triacetin Chemical group CC(=O)OCC(OC(C)=O)COC(C)=O URAYPUMNDPQOKB-UHFFFAOYSA-N 0.000 claims description 9
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 9
- 229920002554 vinyl polymer Polymers 0.000 claims description 9
- 230000015572 biosynthetic process Effects 0.000 claims description 8
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 7
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 7
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 7
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 7
- 239000005642 Oleic acid Substances 0.000 claims description 7
- 229920001131 Pulp (paper) Polymers 0.000 claims description 7
- 239000013538 functional additive Substances 0.000 claims description 7
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- 229960001866 silicon dioxide Drugs 0.000 claims description 6
- 235000012239 silicon dioxide Nutrition 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 4
- 229920001083 polybutene Polymers 0.000 claims description 4
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims description 3
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims description 3
- 239000000391 magnesium silicate Substances 0.000 claims description 3
- 229910052919 magnesium silicate Inorganic materials 0.000 claims description 3
- 235000019792 magnesium silicate Nutrition 0.000 claims description 3
- 239000004408 titanium dioxide Substances 0.000 claims description 3
- 235000010215 titanium dioxide Nutrition 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- 235000014692 zinc oxide Nutrition 0.000 claims description 3
- 239000004094 surface-active agent Substances 0.000 abstract description 7
- 239000004927 clay Substances 0.000 abstract 3
- 230000001680 brushing effect Effects 0.000 abstract 1
- 239000003398 denaturant Substances 0.000 abstract 1
- 239000011159 matrix material Substances 0.000 description 13
- 238000004140 cleaning Methods 0.000 description 7
- 238000009826 distribution Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 238000001125 extrusion Methods 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 150000002430 hydrocarbons Chemical class 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 229920001169 thermoplastic Polymers 0.000 description 4
- 239000004416 thermosoftening plastic Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 3
- 150000005215 alkyl ethers Chemical class 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000796 flavoring agent Substances 0.000 description 2
- 235000019634 flavors Nutrition 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000006210 lotion Substances 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229920001748 polybutylene Polymers 0.000 description 2
- 229920001610 polycaprolactone Polymers 0.000 description 2
- 239000004632 polycaprolactone Substances 0.000 description 2
- 229920000909 polytetrahydrofuran Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000005201 scrubbing Methods 0.000 description 2
- IFGRPRNMPKCMHL-UHFFFAOYSA-N CC(C)CO.CC(C)CO.CC(C)(C)CCCC(O)O Chemical compound CC(C)CO.CC(C)CO.CC(C)(C)CCCC(O)O IFGRPRNMPKCMHL-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- RNAHRGJHYXOCID-UHFFFAOYSA-N NN=CN=N.NN=CN=N.C1=CC=CC=C1.Cl Chemical compound NN=CN=N.NN=CN=N.C1=CC=CC=C1.Cl RNAHRGJHYXOCID-UHFFFAOYSA-N 0.000 description 1
- 229920006197 POE laurate Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 150000001491 aromatic compounds Chemical class 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229960000686 benzalkonium chloride Drugs 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- DIEXWTMZAWQPHZ-UHFFFAOYSA-N dibutyl benzene-1,2-dicarboxylate;3,4-dibutylphthalic acid Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC.CCCCC1=CC=C(C(O)=O)C(C(O)=O)=C1CCCC DIEXWTMZAWQPHZ-UHFFFAOYSA-N 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-M dodecanoate Chemical compound CCCCCCCCCCCC([O-])=O POULHZVOKOAJMA-UHFFFAOYSA-M 0.000 description 1
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 1
- KWKXNDCHNDYVRT-UHFFFAOYSA-N dodecylbenzene Chemical compound CCCCCCCCCCCCC1=CC=CC=C1 KWKXNDCHNDYVRT-UHFFFAOYSA-N 0.000 description 1
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000013773 glyceryl triacetate Nutrition 0.000 description 1
- 239000001087 glyceryl triacetate Substances 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 229940070765 laurate Drugs 0.000 description 1
- 229940094506 lauryl betaine Drugs 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 229960002622 triacetin Drugs 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000004018 waxing Methods 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Detergent Compositions (AREA)
Abstract
The invention provides a composition for forming pliable nanometer clay composite material and a composite material formed by the composition. The nanometer clay composite material is prepared through the mixing of the composition which comprises a high molecular polymer, a surfactant, a high molecular denaturant and a micrometer/nanometer powder body. The nanometer clay composite material is pliable and can be completely adhered to the surface to scrape off dirt and produce a brushing effect through the release of the surfactant and the frictional force between the micrometer/nanometer powder body and the surface.
Description
Technical field
The invention provides a kind of tool pliability nano clay composite material, preferably, the invention relates to a kind of family, automobile-used and industrial Clean-nano clay composite material of being used for.
Background technology
In industrial production or life staying idle at home, cleaning, peace and quiet program are to belong to the program that must implement every day.
General kitchen tools and the sanitary bath equipment of cleaning in family life; be by sanitising agent is poured in the water; be aided with foam or scrubbing tool cleans; remain after having scrubbed and still have the solution of cleanup action and can only be used as discharge of wastewater; and scrubbing tool is perhaps limited on the effect of cleaning through regular meeting damage utensil surface.
In addition, aspect car detailing, because automobile collides with airborne dust in the process of moving, cause the grit that is difficult to remove, general foam car-washing method can't remove completely, and may cause the damage of baking finish for car because of the friction of grit.
On the other hand, be no lack of visible various means and improve the manufacturing process dose rate industrial by various cleanings, for example in semiconductor wafer (wafer) manufacturing process, be extensive use of various cmp manufacturing process and carry out silicon wafer polishing, constantly consume lapping liquid and a large amount of water in the process and clean, and grind the major issue in the environmental protection of being treated to of waste liquid.
In view of this, the present invention attempts using/use the cleaning material of solvent hardly, and use the use of the water/solvent when reducing industry, family or automobile-used cleaning, and have concurrently simultaneously and scrub and the surfactant washing function, with demand, reduce the burden of environment in response to environmental protection.
Summary of the invention
Because the disappearance of prior art, the object of the present invention is to provide a kind of non-expendable cleaning material, the pliability that it had, itself and desire clean Surface are fitted tightly, and do not have fully lotion or a small amount of lotion in the presence of, remove the unexpected material of desiring the clean surface by avidity and/or contact force mode.
Further, the invention provides a kind of composition that is used to form described non-expendable cleaning material, said composition can be made the flexual non-expendable cleaning material of tool by the mixing technology of polymer.
For reaching above-mentioned purpose, the invention provides a kind of composition that is used to form the pliability nano clay composite material, said composition comprises high molecular polymer, tensio-active agent, polymer denaturing agent, and the micrometer/nanometer powder.
Micrometer/nanometer powder of the present invention comprises the mixture of nano-powder or micro-powder and nano-powder.
Each proportion of composing of above-mentioned composition is preferably the tensio-active agent of 100 weight part high molecular polymers, 0.1 to 40 weight part, the polymer denaturing agent of 0.1 to 40 weight part and the micrometer/nanometer powder of 0.1 to 100 weight part.
In the embodiment of part, the composition that is used to form the pliability nano clay composite material of the present invention can further comprise filamentary material, and its preferred usage quantity is 0.1 to 10 weight part (is benchmark with above-mentioned composition weight ratio).
In a preferred embodiment, composition of the present invention preferably comprises the tensio-active agent of 100 weight part high molecular polymers, 0.1 to 40 weight part, the polymer denaturing agent of 0.1 to 40 weight part, the micrometer/nanometer powder of 0.1 to 100 weight part and the filamentary material of 0.1 to 8 weight part.
In preferred embodiment, composition of the present invention comprises the tensio-active agent of 100 weight part high molecular polymers, 0.5 to 30 weight part, the polymer denaturing agent of 0.5 to 30 weight part, the micrometer/nanometer powder of 0.1 to 50 weight part and the filamentary material of 0.1 to 8 weight part.
In another preferred embodiment, composition of the present invention comprises the tensio-active agent of 100 weight part high molecular polymers, 1 to 20 weight part, the polymer denaturing agent of 1 to 20 weight part, the micrometer/nanometer powder of 0.1 to 25 weight part and the filamentary material of 0.5 to 5 weight part.
The present invention provides a kind of nano clay composite material simultaneously, it is with comprising the composition of high molecular polymer, tensio-active agent, polymer denaturing agent and micrometer/nanometer powder through the mixing formation of polymer, wherein, formed nano clay composite material has pliability after polymer is mixing.
Wherein, be preferably 100 weight part high molecular polymers in order to the composition between each composition of composition that forms this nano clay composite material; 0.1 tensio-active agent to 40 weight parts; 0.1 polymer denaturing agent to 40 weight parts; And the micrometer/nanometer powder of 0.1 to 100 weight part.
In the embodiment of part, the composition that is used to form nano clay composite material of the present invention can further comprise filamentary material, consists of benchmark with the weight part of above-mentioned composition, and the preferable amount of this filamentary material is 0.1 to 10 weight part.
In a preferred embodiment of the invention, comprise the tensio-active agent of 100 weight part high molecular polymers, 0.5 to 30 weight part, the polymer denaturing agent of 0.5 to 30 weight part, the micrometer/nanometer powder of 0.1 to 50 weight part and the filamentary material of 0.1 to 8 weight part in order to polymer is mixing with the composition that makes nano clay composite material of the present invention.
In addition, be applicable to that in preparation car body beauty treatment, industry remove among printing ink or the de-odorised embodiment, comprise the tensio-active agent of 100 weight part high molecular polymers, 1 to 20 weight part, the polymer denaturing agent of 1 to 20 weight part, the micrometer/nanometer powder of 0.1 to 25 weight part and the filamentary material of 0.5 to 5 weight part in order to polymer is mixing with the composition that makes nano clay composite material of the present invention.
The composition of pliability nano clay composite material that is used to form of the present invention is after polymer is mixing, it can form the flexual nano clay composite material of tool, and can be used as industry or at home Clean-non-expendable cleaning material, reduce the use of expendable cleaning supplies such as water and/or other solvents, reach the effect of environmental protection.
Embodiment
Describe the present invention in detail below in conjunction with embodiment, but do not limit practical range of the present invention.
The composition that is used to form the pliability nano clay composite material of the present invention, it comprises: high molecular polymer, tensio-active agent, polymer denaturing agent and powder, this powder are the micrometer/nanometer powder.The preferred proportion of composing of composition of the present invention is: the polymer denaturing agent of the tensio-active agent of 100 weight part high molecular polymers, 0.1 to 40 weight part, 0.1 to 40 weight part and the micrometer/nanometer powder of 0.1 to 100 weight part.
In the part preferred embodiment, the composition that is used to form the pliability nano clay composite material of the present invention can further comprise filamentary material, and its preferred consumption is 0.1 to 10 weight part.
In a preferred embodiment, the composition that is used to form the pliability nano clay composite material of the present invention comprises the tensio-active agent of 100 weight part high molecular polymers, 0.5 to 30 weight part, the polymer denaturing agent of 0.5 to 30 weight part, the micrometer/nanometer powder of 0.1 to 50 weight part and the filamentary material of 0.1 to 8 weight part.
In another preferred embodiment, composition of the present invention comprises the tensio-active agent of 100 weight part high molecular polymers, 1 to 20 weight part, the polymer denaturing agent of 1 to 20 weight part, the micrometer/nanometer powder of 0.1 to 25 weight part and the filamentary material of 0.5 to 5 weight part.
Alleged " high molecular polymer " of the present invention is the base material in the composition that is used to form the pliability nano clay composite material, and it can be itself promptly has flexual macromolecular material, perhaps by having pliability with other compositions mixing.The material that is applicable to high molecular polymer of the present invention comprises polyethylene, polypropylene, poly-vinyl acetic monomer, rubber or its mixture.
Alleged " tensio-active agent " of the present invention comprises aniorfic surfactant, cationic surfactant, nonionic surface active agent or its mixture, when one of its effect is to make composition of the present invention formed matrix material is with other surperficial contacts through mixing after, by matrix material contained tensio-active agent and other lip-deep material polarization-polarity reactive force or nonpolar-non-polar action power, and then with this material band from this surface, in addition, tensio-active agent also can be by disengaging the effect that forms sanitising agent in the matrix material.Be applicable to that aniorfic surfactant of the present invention comprises polyoxyethylene glycol alkyl alkyl ether phosphate (Polyoxyethylene Alkyl Ether Phosphate), carboxylated alkyl ethoxy ester (CarboxylatedAlkyl Ethoxylate), carboxylated dodecylbenzene sulfuric ester (Carboxylated Dodecyl BenzeneSulfonate), ammonium polyoxyethylene glycol alkyl alkyl ether sulphate (NH
4Polyoxyethylene Alkyl EtherSulfate); Be applicable to that cationic surfactant of the present invention comprises quaternary ammonium salt (QuartenernaryAmmonium Salt), Benzene Chloride diformazan hydrocarbon ammonium (Benzalkonium Chloride), lauryl betaine (Lauryl Betain); Be applicable to that nonionic surface active agent of the present invention comprises polyoxyethylene glycol alkyl alkyl oxide (Polyoxyethylene Alkyl Ether), polyoxyethylene glycol alkyl oleic acid ester (PolyoxyethyleneOleate), polyoxyethylene glycol alkyl stearate (Polyoxyethylene Stearate) or polyoxyethylene glycol alkyl laurate (Polyoxyethylene Laurate).
Alleged " the polymer denaturing agent " of the present invention known the knowledgeable usually for tool in the technical field of macromolecules and made an addition in the polymer in order to change the polymer rigidity, toughness, or the material of character such as pliability, therefore being applicable to that polymer denaturing agent of the present invention comprises in the technical field of macromolecules can be in order to change plastic modified dose of described character, thickening material (being also referred to as tackifier), hydrocarbon mixture oil, vegetables oil, animal oil or its mixture, for example plastic modified dose can be polyoxyethylene glycol (Polyethylene Glycols), polytetramethylene ether glycol (Polytetramethylene-ether-glycol), polycaprolactone polyol (Polycaprolactone), polycarbonate diol (Polycarbonatediol), dioctyl phthalate (DOP) (Di-Octyl Phthalate), Dibutyl phthalate (Dibutyl Phthalate), vanay (Triacetin), front three pentanediol isobutyl ester (Trimethyl-Pentanediol Di-isobutylate) or its mixture; Then for having the compound of CnH2n+2 formula, wherein n is 6 to 30 positive integer to hydrocarbon mixture oil, and hydrocarbon mixture oil can be saturated or unsaturated naphthenic or aromatic compounds.
Alleged " the micrometer/nanometer powder " of the present invention is the mixture of nano-powder or micro-powder and nano-powder, it acts on and makes composition of the present invention formed matrix material and other surfaces when contacting after polymer is mixing, " micrometer/nanometer powder " contained by matrix material contacts with other surperficial materials, and then the effect of striking off this material is ground in generation, simultaneously because the pliability of matrix material, make the material that is struck off enter in the matrix material so that by composite material tape from this surface.The material of micro-powder is anyly knownly to have the having rigidity/low flexual material of micron grain size and need not limit; The material of nano-powder then is any material with nanometer particle size, including but not limited to silicon-dioxide, titanium dioxide, zinc oxide, lime carbonate, aluminum oxide, Magnesium Silicate q-agent or its mixture.
Alleged " filamentary material " of the present invention comprises cotton, paper pulp or its mixture.
In part embodiment, the composition that is used to form the pliability nano clay composite material of the present invention can further comprise functional additive according to demand, for example Losantin, citric acid or Weibull etc., make by these functional additives and to utilize its obtained matrix material to increase or strengthen original function or effect, for example fragrance, oil removing characteristic etc.
Nano clay composite material of the present invention, its for the composition that comprises following composition through the mixing formation of polymer: the polymer denaturing agent of the tensio-active agent of 100 weight part high molecular polymers, 0.1 to 40 weight part, 0.1 to 40 weight part, the micrometer/nanometer powder of 0.1 to 100 weight part; Wherein, described composition formed nano clay composite material after polymer is mixing has pliability.
It is to adopt above-mentioned composition through the mixing formation of polymer for a matrix material of the present invention, and wherein the definition of the high molecular polymer that is comprised in the composition, tensio-active agent, polymer denaturing agent, micrometer/nanometer powder and filamentary material as mentioned above.
Alleged " polymer is mixing " of the present invention is meant other compositions that polymer mixed upgrading with other desires, through mixing facilities each composition is uniformly dispersed.It can be by any known in the art or reach the operation of equipment of this purpose, for example single screw extrusion machine, twin screw extruder, abrasive disk type forcing machine or continuous extruder etc. and need not limit.
In a preferred embodiment, matrix material of the present invention its adopt the composition that comprises following composition through the mixing formation of polymer: the polymer denaturing agent of the tensio-active agent of 100 weight part high molecular polymers, 0.5 to 30 weight part, 0.5 to 30 weight part, the micrometer/nanometer powder of 0.1 to 50 weight part and the filamentary material of 0.1 to 8 weight part.
Matrix material of the present invention is applicable to general household cleaning, the washing of for example wiping on furniture or floor, dish vessel, bowl surface dirty, that electromagnetic oven is surperficial is dirty, and car body cosmetic cleansing usefulness, for example wiped clean before the car body waxing.
In another preferred embodiment, matrix material of the present invention its adopt the composition that comprises following composition through the mixing formation of polymer: the polymer denaturing agent of the tensio-active agent of 100 weight part high molecular polymers, 1 to 20 weight part, 1 to 20 weight part, the micrometer/nanometer powder of 0.1 to 25 weight part and the filamentary material of 0.5 to 5 weight part.
Matrix material of the present invention is applicable to the industrial printing ink removing use or the smelly purposes that disappears of going to distinguish the flavor of.
Following examples are to be used for further understanding advantage of the present invention, are not to be used to limit the present invention.
The preparation of embodiment 1. nano clay composite materials
Universal nano clay composite material
| Material | Material category | Ratio (weight part) |
| High molecular polymer | Polybutene, poly-vinyl acetic monomer | Total 100 is polybutene 1～5 wherein |
| The polymer denaturing agent | Vanay | 5～20 |
| Tensio-active agent | Polyoxyethylene glycol alkyl oleic acid ester | 5～20 |
| Nano-powder | Silicon-dioxide size distribution 100nm～1000nm | 0.1～1 |
| Aluminum oxide size distribution 100nm～1000nm | 0.1～1 | |
| Other additives | Paper pulp | 1～5 |
With each form in heating boiler, carry out thermoplastic and stir after again through single screw extrusion machine fill part mixing after, make the family expenses nano clay composite material.
Automobile-used nano clay composite material
| Material | Material category | Ratio (weight part) |
| High molecular polymer | Polybutene, poly-vinyl acetic monomer | Total 100 is polybutene 1～5 wherein |
| The polymer denaturing agent | Vanay | 5～20 |
| Tensio-active agent | Polyoxyethylene glycol alkyl oleic acid ester | 5～20 |
| Nano-powder | Silicon-dioxide size distribution 50nm～300nm | 1～20 |
| Aluminum oxide size distribution 50nm～300nm | 1～20 | |
| Other additives | Paper pulp | 1～5 |
With each form in heating boiler, carry out thermoplastic and stir after again through single screw extrusion machine fill part mixing after, make automobile-used nano clay composite material.
Industrial nano clay composite material (PU skin printing ink is removed and used)
| Material | Material category | Ratio (weight part) |
| High molecular polymer | Poly-vinyl acetic monomer | 100 |
| The polymer denaturing agent | Vanay | 5～20 |
| Tensio-active agent | Polyoxyethylene glycol alkyl oleic acid ester | 1～5 |
| Nano-powder | Silicon-dioxide size distribution 50nm～300nm | 0.1～5 |
| Aluminum oxide size distribution 50nm～300nm | 0.1～5 | |
| Other additives | Paper pulp | 1～5 |
| Losantin | 0.1～1 |
With each form in heating boiler, carry out thermoplastic and stir after again through single screw extrusion machine fill part mixing after, make nano clay composite material.
Industrial nano clay composite material (the smelly removing usefulness that disappears of going to distinguish the flavor of)
| Material | Material category | Ratio (weight part) |
| High molecular polymer | Poly-vinyl acetic monomer | 100 |
| The polymer denaturing agent | Vanay | 1～5 |
| Tensio-active agent | Polyoxyethylene glycol alkyl oleic acid ester | 1～10 |
| Nano-powder | Activated carbon particle size distribution 100nm～500nm | 0.1～5 |
| Other additives | Paper pulp | 1～5 |
| Functional additive | Citric acid | 0.1～1 |
| Weibull | 0.1～1 |
With each form in heating boiler, carry out thermoplastic and stir after again through single screw extrusion machine fill part mixing after, make nano clay composite material.
Comprehensively above-mentioned, composition of the present invention and the nano clay composite material that utilizes said composition to make, it has pliability, attaching surface strikes off dirt fully, and by disengaging and the contact force of micrometer/nanometer powder of tensio-active agent, produce simultaneously and scrub function, so can avoid superfluous sanitising agent to cause the pollution of environment.
Other embodiment
Disclosed in this manual all features all may combine with additive method, disclosed each feature all may optionally be replaced with identical, equal or similar purpose feature in this specification sheets, therefore, except special notable attribute, the disclosed feature of this all specification sheetss only is an example in equal or the similar features.
Though the present invention discloses as above with preferred embodiment, so it is not in order to qualification the present invention, any those skilled in the art, without departing from the spirit and scope of the present invention, when being used for a variety of modifications and variations.
Claims (12)
1. composition that is used to form the pliability nano clay composite material of non-expendable cleaning material, it comprises the high molecular polymer of 100 weight parts, the tensio-active agent of 0.1 to 40 weight part, the polymer denaturing agent of 0.1 to 40 weight part, the filamentary material of 0.1 to 10 weight part and the micrometer/nanometer powder of 0.1 to 100 weight part, and this micrometer/nanometer powder is the mixture of nano-powder or micro-powder and nano-powder;
Wherein, described high molecular polymer is poly-vinyl acetic monomer, or is the mixture of polybutene and poly-vinyl acetic monomer;
Described tensio-active agent is a polyoxyethylene glycol alkyl oleic acid ester; Described polymer denaturing agent is a vanay; Described filamentary material is a paper pulp.
2. composition as claimed in claim 1, it comprises:
The high molecular polymer of 100 weight parts;
0.5 tensio-active agent to 30 weight parts;
0.5 polymer denaturing agent to 30 weight parts;
0.1 micrometer/nanometer powder to 50 weight parts; And
0.1 filamentary material to 8 weight parts.
3. composition as claimed in claim 1, it comprises:
The high molecular polymer of 100 weight parts;
The tensio-active agent of 1 to 20 weight part;
The polymer denaturing agent of 1 to 20 weight part;
0.1 micrometer/nanometer powder to 25 weight parts; And
0.5 filamentary material to 5 weight parts.
4. composition as claimed in claim 1, the material of wherein said micrometer/nanometer powder comprise silicon-dioxide, titanium dioxide, zinc oxide, lime carbonate, aluminum oxide, Magnesium Silicate q-agent or its mixture.
5. composition as claimed in claim 1, the particle diameter of wherein said micrometer/nanometer powder are 50nm-900nm.
6. composition as claimed in claim 1, it also comprises functional additive, and this functional additive is Losantin, citric acid or Weibull.
7. non-expendable cleaning material, its for the composition that comprises following composition through the mixing formation of polymer:
100 weight part high molecular polymers;
0.1 tensio-active agent to 40 weight parts;
0.1 polymer denaturing agent to 40 weight parts;
0.1 filamentary material to 10 weight parts; And
0.1 micrometer/nanometer powder to 100 weight parts;
Wherein, described high molecular polymer is poly-vinyl acetic monomer, or is the mixture of polybutene and poly-vinyl acetic monomer;
Described tensio-active agent is a polyoxyethylene glycol alkyl oleic acid ester; Described polymer denaturing agent is a vanay; Described filamentary material is a paper pulp;
Wherein, described composition formed non-expendable cleaning material after polymer is mixing has pliability.
8. non-expendable cleaning material as claimed in claim 7, its for the composition that comprises following composition through the mixing formation of polymer:
100 weight part high molecular polymers;
0.5 tensio-active agent to 30 weight parts;
0.5 polymer denaturing agent to 30 weight parts;
0.1 micrometer/nanometer powder to 50 weight parts; And
0.1 filamentary material to 8 weight parts;
Wherein, described composition formed non-expendable cleaning material after polymer is mixing has pliability.
9. non-expendable cleaning material as claimed in claim 7, its for the composition that comprises following composition through the mixing formation of polymer:
100 weight part high molecular polymers;
The tensio-active agent of 1 to 20 weight part;
The polymer denaturing agent of 1 to 20 weight part;
0.1 micrometer/nanometer powder to 25 weight parts; And
0.5 filamentary material to 5 weight parts;
Wherein, described composition formed non-expendable cleaning material after polymer is mixing has pliability.
10. non-expendable cleaning material as claimed in claim 7, the material of wherein said micrometer/nanometer powder comprise silicon-dioxide, titanium dioxide, zinc oxide, lime carbonate, aluminum oxide, Magnesium Silicate q-agent or its mixture.
11. non-expendable cleaning material as claimed in claim 7, the particle diameter of wherein said micrometer/nanometer powder are 50nm-900nm.
12. non-expendable cleaning material as claimed in claim 7, it also comprises functional additive, and this functional additive is Losantin, citric acid or Weibull.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2007103008306A CN101469088B (en) | 2007-12-29 | 2007-12-29 | Composition and nano clay composite material containing the same |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007103008306A CN101469088B (en) | 2007-12-29 | 2007-12-29 | Composition and nano clay composite material containing the same |
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| Publication Number | Publication Date |
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| CN101469088A CN101469088A (en) | 2009-07-01 |
| CN101469088B true CN101469088B (en) | 2011-12-28 |
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| CN101817974A (en) * | 2010-05-10 | 2010-09-01 | 北京寰宇力道国际科技有限公司 | Nanometer antibacterial makrolon material and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0708056A1 (en) * | 1994-10-21 | 1996-04-24 | Fuji Chemical Industry Co., Ltd. | Hydrotalcite compound, process for producing the same, infrared absorber and agricultural film |
| CN1358791A (en) * | 2000-12-12 | 2002-07-17 | 海尔科化工程塑料国家工程研究中心有限公司 | Polymer organic nano composite ocmposition for making agriculture greenhouse film and preparation process thereof |
| CN1370221A (en) * | 1999-07-01 | 2002-09-18 | 宝洁公司 | Detergent compsns. components |
-
2007
- 2007-12-29 CN CN2007103008306A patent/CN101469088B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0708056A1 (en) * | 1994-10-21 | 1996-04-24 | Fuji Chemical Industry Co., Ltd. | Hydrotalcite compound, process for producing the same, infrared absorber and agricultural film |
| CN1370221A (en) * | 1999-07-01 | 2002-09-18 | 宝洁公司 | Detergent compsns. components |
| CN1358791A (en) * | 2000-12-12 | 2002-07-17 | 海尔科化工程塑料国家工程研究中心有限公司 | Polymer organic nano composite ocmposition for making agriculture greenhouse film and preparation process thereof |
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| CN101469088A (en) | 2009-07-01 |
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