CN101449203A - Liquid crystal devices - Google Patents
Liquid crystal devices Download PDFInfo
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- CN101449203A CN101449203A CNA2007800181166A CN200780018116A CN101449203A CN 101449203 A CN101449203 A CN 101449203A CN A2007800181166 A CNA2007800181166 A CN A2007800181166A CN 200780018116 A CN200780018116 A CN 200780018116A CN 101449203 A CN101449203 A CN 101449203A
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/137—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells characterised by the electro-optical or magneto-optical effect, e.g. field-induced phase transition, orientation effect, guest-host interaction or dynamic scattering
- G02F1/13725—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells characterised by the electro-optical or magneto-optical effect, e.g. field-induced phase transition, orientation effect, guest-host interaction or dynamic scattering based on guest-host interaction
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/137—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells characterised by the electro-optical or magneto-optical effect, e.g. field-induced phase transition, orientation effect, guest-host interaction or dynamic scattering
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y20/00—Nanooptics, e.g. quantum optics or photonic crystals
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01P—WAVEGUIDES; RESONATORS, LINES, OR OTHER DEVICES OF THE WAVEGUIDE TYPE
- H01P1/00—Auxiliary devices
- H01P1/18—Phase-shifters
- H01P1/19—Phase-shifters using a ferromagnetic device
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F2202/00—Materials and properties
- G02F2202/36—Micro- or nanomaterials
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- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F2203/00—Function characteristic
- G02F2203/13—Function characteristic involving THZ radiation
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- Physics & Mathematics (AREA)
- Nonlinear Science (AREA)
- Chemical & Material Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Optics & Photonics (AREA)
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- Nanotechnology (AREA)
- Engineering & Computer Science (AREA)
- Biophysics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mathematical Physics (AREA)
- Liquid Crystal (AREA)
- Variable-Direction Aerials And Aerial Arrays (AREA)
- Control Of Motors That Do Not Use Commutators (AREA)
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Abstract
The present invention provides an electrical component comprising a substrate (30) carrying a LC cell (10) wherein the LC cell (10) comprises liquid crystal material (20) containing anisotropic particles (25), at least one conductive member (36) disposed on the substrate (30) and at least one conductive member (34) disposed over the LC cell (10), and means for affecting the alignment of the anisotropic particles (25) whereby the permittivity between the conductive members (34, 36) is varied.
Description
The application relates to electric assembly, slab guide, antenna, beam-shaper (beam shaper) and electric tunable dielectric.
Embodiment is applicable to the zone of terahertz (terahertz) frequency or millimeter wavelength; Other embodiment are used for the zone of superfrequency (VHF), ultrahigh frequency (UHF) and microwave.
On the one hand, the invention provides a kind of electric assembly, comprise the substrate that is loaded with liquid crystal (LC) unit, wherein lc unit comprises the liquid crystal material that contains anisotropic particles; Comprise that also at least one places conducting element (conductive member) on the substrate and at least one to place the conducting element of lc unit top; And be used to influence the device (means) that anisotropic particles is arranged (alignment), in order to change the permittivity (permittivity) between conducting element.
Said modules can be used for frequency sensitivity antenna (frequency agile antenna), steerable antenna (steerable antenna), tunable optic filter (tuneable filter), polarization variable antenna (polarisation variable antennas), voltage-controlled oscillator (voltage controlledoscillator), vairable delay line (variable delay line), automatic impedance match circuit (automaticimpedance matching circuit), be used for the active temperature compensation (activetemperature compensation for microwave circuits) of microwave circuit.
On the other hand, the invention provides a kind of slab guide, comprise the substrate that is loaded with lc unit, wherein lc unit comprises the liquid crystal material that contains anisotropic particles; Comprise that also at least one places the conducting element on the substrate to place the conducting element of lc unit top with at least one; And the device that is used to influence the arrangement of anisotropic particles, to change the permittivity between conducting element.
Another aspect the invention provides a kind of antenna, comprises the substrate that is loaded with lc unit, and wherein lc unit comprises the liquid crystal material that contains anisotropic particles; Comprise that also at least one places the conducting element on the substrate to place the conducting element of lc unit top with at least one; And the device that is used to influence the arrangement of anisotropic particles, to change the permittivity between conducting element.
Again on the one hand, the invention provides the beam-shaper that a kind of free space that is used for the terahertz frequency wave is propagated, comprise the substrate that is loaded with lc unit, wherein lc unit comprises the liquid crystal material that contains anisotropic particles; Comprise that also at least one places the conducting element on the substrate to place the conducting element of lc unit top with at least one; And the device that is used to influence the arrangement of anisotropic particles, to change the permittivity between conducting element.
The device that is used to influence arrangement can comprise conducting element.
On the one hand, the invention provides a kind of electric tunable dielectric again, comprise lc unit, wherein lc unit comprises the liquid crystal material that contains anisotropic particles; And the control electrode that is used to influence the arrangement of anisotropic particles.
Lc unit can comprise polymer dispersed formula liquid crystal (PDLC, i.e. Polymer Dispersed LiquidCrystal) material.
Anisotropic particles can comprise carbon nano-tube (CNT).
With reference to hereinafter describing and will more being expressly understood the present invention, wherein in conjunction with annexed drawings:
Fig. 1 a is the synoptic diagram of liquid crystal cells, is illustrated in the anisotropic particles under " field-free " condition;
Fig. 1 b is the synoptic diagram of liquid crystal cells, is illustrated in the anisotropic particles under " field is arranged " condition;
Fig. 2 is the sectional view of test cell;
Fig. 3 is the skeleton view of the paster antenna (patch antenna) in the embodiment of the invention;
Fig. 4 is the sectional view of III-III ' along the line among Fig. 2;
Fig. 5 is the sectional view that passes strip line (stripline) waveguide in the embodiment of the invention;
Fig. 6 is the synoptic diagram of the beam-shaper in the embodiment of the invention.
Referring to Fig. 1 a and Fig. 1 b, liquid crystal cells 10 has liquid crystal material layer 20, has (dispersed) anisotropic particles 25 of distribution in the described liquid crystal material layer 20.In described embodiment, these particles are CNT.In another embodiment, adopt dyeing (dye) impurity in the described liquid crystal material layer 20.In another embodiment, liquid crystal material is not for containing the PDLC material of CNT.By relative, be generally the scope that glass substrate 30,32 flat and that be parallel to each other limits liquid crystal material 20, wherein glass substrate 30,32 is loaded with indium tin oxide (ITO) electrode 34,36, and by distance piece (spacer) 33,35 substrate is separated.Come connection electrode by conductor 37,38.
Distance s between the substrate is in fact less than the length e of substrate.
In Fig. 1 a, general liquid crystal material 20 makes anisotropic particles 25 be parallel to substrate and arranges.
In Fig. 1 b, therefore applied field between ITO electrode 34,36 causing the molecule tilt of liquid crystal material 20, and guides particle 25 to enter position of rotation, and at this, described position of rotation is with respect to about average out to 35 degree in the plane of substrate.Described 35 degree angles are not the essential feature of described device.The change that anisotropic particles is arranged causes the variation of permittivity between the ITO electrode 34,36.
By people such as K C Lim " liquid crystal 14 (1993) 327-337 pages or leaves " as can be known, the birefringence scope of commercial liquid crystal in the millimeter wave zone is the 46%-67% of visible area thresholding.In addition, by people such as Weil " electronic letter 39 (24) 1732-4 (2003) " as can be known, synthesize conventional liquid crystal, and the loss of the tangent δ in mm ripple zone is similar to FR4 by the dielectric anisotropy (enhanced dielectric anisotropy) (Δ ε=1) that strengthens.
When test device constructed in accordance,, adopt multiple material system to make liquid crystal layer based on to row nucleus (nematic host) and carbon nano-tube material.Make suitable material by mixing carbon nano-tube and liquid crystal.Potpourri after injecting is passed through sonicated (sonication), so that carbon nano-tube is scattered in liquid crystal.
Referring to Fig. 2, have supporting substrate 401 than the test cell 400 of existing test cell thick (can the thick 1mm of reaching), described supporting substrate 401 is used to support the copper ground plane (groundplane) 410 that extends to its upper surface.Liquid crystal material layer 420 is placed on the ground plane, and support overlayer 430 with the definition liquid crystal cells by distance piece 435.In other unit, adopt polymkeric substance to replace glass.Top electrode 440 is made of copper, for example is made of little band copper path (microstrip copper track).The width of top electrode 440 is that the thickness of w and lc unit is h, to pass through z
o~h/[(w+2h) ε
oc
oε
r 1/2] and electrical length β L~2pL/ λ
g(λ wherein
g=c
o/ [f ε
r 1/2]) determine the characteristic impedance Z of microstrip transmission line
o, the very part of microstrip transmission line wherein powers on.
For electricity conversion liquid crystal and the described device of adjusting, the liquid crystal with following feature is adopted in suggestion:
Birefringence through electric control; And
Bifrequency is to row.
In one embodiment, because the previous work that anisotropy metal microtubule is dispersed in the liquid crystal nucleus shows, distribution by 0.2%, can increase the birefringence that is in the liquid crystal of 30GHz more than 50% (referring to people's such as AM Lackner " liquid crystal 14 (1993); 351-359 page or leaf "), therefore can adopt liquid crystal nucleus doped carbon nanometer pipe (CNT), to enlarge tuning range.
Also very important for other application of the CNT polymkeric substance with liquid crystal or polymkeric substance or activated monomer (reactivemonomer) at CNT orderly in the organic media, these other application examples are as can be used as the conducting polymer that is used for holograph or optical nonlinearity material etc.
In order to maximize dielectric anisotropy, the essential acquisition preferably and stable CNT arrangement.CNT functionalization technology (Functionalisationtechniques) in organic media (for example comprising liquid crystal and activated monomer), be used to chemical modification (functionalization of covalent bond (covalent functionalisation)), polymer encapsulated (functionalization of non-covalent bond (noncovalent functionalisation)), and be used for the surfactant of organic media.Other problems comprises the understanding for the concrete spectrum property of absorption characteristic and dielectric characteristic.
Predictably, the electric-optical appliance by these made can be used for controlling radiation (for example in imaging of medical), in antenna, radio and the radar application categories such as (for example artificial satellite and mobile phones) that in microwave, is suitable for.
Predicted the application of LCs (being mixed with or not being mixed with CNT) on realization " solid-state (solid) " substrate (making microwave circuit on this substrate) that polymer dispersed is arranged by embodiment, should be similar to existing P TFE and glass fibre substrate by " solid-state " substrate, this application is applicable to little band (microstrip), strip line (stripline), the line of rabbet joint (slotline) and other slab guide technology.Compare with the structure of employing LC " unit " type that is proposed, this mode can be simplified the manufacturing of microwave circuit, and its cost is to have dwindled tuning range.In some cases, preferably limited tuning range for example is used for the fine tuning of oscillator.
Steerable antenna (steerable antenna) is the embodiment that is used for radio LAN and/or mobile phone, for example in order to obtain higher customer density in the given area.For phone, steerable antenna allows the user to reduce radiation irradiation (radiation exposure).The non-finiteness example of other of application of the present invention is little band and strip-line circuit (microstrip ﹠amp; Stripline circuits), phase-shifter (phaseshifters), match circuit (matching circuits), tunable and controlled paster antenna (tuneableand steerable patch antennas), wave filter and circulator (circulators) etc.
Referring to Fig. 3 and Fig. 4, paster antenna 100 has dielectric base plate 110, and the upper end of described dielectric base plate 110 (upperside) has copper electrode 114.Liquid crystal cells 120 is placed on the upper end of substrate 110 and place copper electrode 114 tops.Limited by distance piece 124 around the border of described liquid crystal cells 120, described distance piece 124 is made of the glue envelope (glue seal) that is loaded with iron particle.In this embodiment, liquid crystal material 128 forms active material, and comprises the CNT that adopts Merck BL037 and scatter.
It on the top of liquid crystal cells (top) copper electrode 122 that forms paster.Described electrode 122 has suitable thickness, minimizes to make conduction loss (conduction losses) on operating frequency, thereby obtains acceptable Q factor.
Adopt iron particle to form magnetic field boundaries, thereby help to reduce to crosstalk (crosstalk).High frequency (for example kilo-mega cycles per second) signal is applied to paster 122, and applies (for example direct current) bias voltage of lower frequency, the permittivity of the LC 128 that mixes with control CNT.Bias voltage can be actual direct current or low frequency transformation, and what need careful note is that reaction time of LC material is Millisecond.
Referring to Fig. 5, on dielectric base plate 210, form first waveguide or transmission line 220, described dielectric base plate 210 upper ends have ground plane (earth plane) 214, and form ground plane by copper conductor 226.The LC material 228 that CNT mixes forms the unit, the side of this unit limits its border by distance piece 224, then limit on it by upper substrate 218, the top of CNT doping LC material 228 formed unit, wherein said substrate 218 supports the copper cash electrode 222 that is positioned on its inside.
Described operation is similar to the operation among first embodiment substantially.
Fig. 6 illustrates the embodiment of second transmission line.In this embodiment, the upper surface and the lower surface of line electrode 222 are limited by liquid crystal material, and this line electrode 222 is between two ground planes 220,224.Other waveguides and similar structures can have been predicted.
Referring to Fig. 7, beam-shaper 300 is made up of paster antenna electrode 310 square matrices of routine, and these paster antenna electrodes 310 are spaced from each other in a plane, and are positioned at the top of base plate 301.In certain embodiments, only need the antenna element of minority, for example 4 or 5 elements.
Fig. 8 shows the substituting setting to Fig. 1, and this set can be used when adopting the bifrequency material.Described situation about illustrating when only applying the low frequency field and only applying high-frequency field (reaction time than liquid crystal material is a lot of soon).
In Fig. 8 a, anisotropic particles 25 is arranged in the mode that is basically perpendicular to glass substrate 30,32, and wherein glass substrate 30,32 is parallel to each other.This arrangement mode causes by apply low-frequency current field between ITO electrode 34,36.This approximately perpendicular arrangement mode is pure illustrative.
In Fig. 8 b, anisotropic particles 25 is arranged in the mode that is basically parallel to glass substrate 30,32, and wherein glass substrate 30,32 is parallel to each other.This arrangement mode causes by apply high-frequency electric field between ITO electrode 34,36.
The liquid crystal cells that oneself is all arranged under each patch electrode 310 in one embodiment; In another slightly inferior optimal way, provide single liquid crystal cells.By conductor 304a-304d signal and bias voltage are fed back to each patch electrode.By bias voltage the permittivity value of each paster is set, so that in known mode, change signal distributions (signal distribution) and guiding radiation laser beam.
Embodiments of the invention have above been described.Yet the present invention is not limited to the details of the foregoing description.
Claims (8)
1. an electric assembly comprises the substrate that is loaded with lc unit, and wherein said lc unit comprises the liquid crystal material that contains anisotropic particles; Comprise that also at least one places the conducting element on the described substrate to place the conducting element of described lc unit top with at least one; And the device that is used to influence the arrangement of anisotropic particles, to change the permittivity between described conducting element.
2. a slab guide comprises the substrate that is loaded with lc unit, and wherein said lc unit comprises the liquid crystal material that contains anisotropic particles; Comprise that also at least one places the conducting element on the described substrate to place the conducting element of described lc unit top with at least one; And the device that is used to influence the arrangement of described anisotropic particles, to change the permittivity between described conducting element.
3. an antenna comprises the substrate that is loaded with lc unit, and wherein said lc unit comprises the liquid crystal material that contains anisotropic particles; Comprise that also at least one places the conducting element on the described substrate to place the conducting element of described lc unit top with at least one; And the device that is used to influence the arrangement of described anisotropic particles, to change the permittivity between described conducting element.
4. a beam-shaper is used for the free space propagation of terahertz frequency wave, and this beam-shaper comprises the substrate that is loaded with lc unit, and wherein said lc unit comprises the liquid crystal material that contains anisotropic particles; Comprise that also at least one places the conducting element on the described substrate to place the conducting element of described lc unit top with at least one; And the device that is used to influence the arrangement of described anisotropic particles, to change the permittivity between described conducting element.
5. an electric tunable dielectric comprises lc unit, and wherein said lc unit comprises the liquid crystal material that contains anisotropic particles; The control electrode that also comprises the arrangement that is used to influence described anisotropic particles.
6. electric assembly according to claim 1, slab guide according to claim 2, antenna according to claim 3 or beam-shaper according to claim 4, the described device that wherein is used to influence the arrangement of described anisotropic particles comprises described conducting element.
7. electric assembly according to claim 1, slab guide according to claim 2, antenna according to claim 3, beam-shaper according to claim 4 or electric tunable dielectric according to claim 5, wherein said lc unit comprises the PDLC material.
8. electric assembly according to claim 1, slab guide according to claim 2, antenna according to claim 3, beam-shaper according to claim 4 or electric tunable dielectric according to claim 5, wherein said anisotropic particles comprises CNT.
Applications Claiming Priority (2)
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GB0608055.0 | 2006-04-24 | ||
GBGB0608055.0A GB0608055D0 (en) | 2006-04-24 | 2006-04-24 | Liquid crystal devices |
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CN101449203A true CN101449203A (en) | 2009-06-03 |
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EP (1) | EP2016459A1 (en) |
JP (1) | JP2009534974A (en) |
KR (1) | KR20090057940A (en) |
CN (1) | CN101449203A (en) |
BR (1) | BRPI0710770A2 (en) |
GB (1) | GB0608055D0 (en) |
TW (1) | TW200801758A (en) |
WO (1) | WO2007122409A1 (en) |
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US7119161B2 (en) * | 2004-03-31 | 2006-10-10 | Solaris Nanosciences, Inc. | Anisotropic nanoparticles and anisotropic nanostructures and pixels, displays and inks using them |
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-
2006
- 2006-04-24 GB GBGB0608055.0A patent/GB0608055D0/en not_active Ceased
-
2007
- 2007-04-23 TW TW096114206A patent/TW200801758A/en unknown
- 2007-04-24 EP EP07732527A patent/EP2016459A1/en not_active Withdrawn
- 2007-04-24 BR BRPI0710770-6A patent/BRPI0710770A2/en not_active IP Right Cessation
- 2007-04-24 KR KR1020087028740A patent/KR20090057940A/en not_active IP Right Cessation
- 2007-04-24 WO PCT/GB2007/001488 patent/WO2007122409A1/en active Application Filing
- 2007-04-24 CN CNA2007800181166A patent/CN101449203A/en active Pending
- 2007-04-24 JP JP2009507146A patent/JP2009534974A/en active Pending
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Also Published As
Publication number | Publication date |
---|---|
KR20090057940A (en) | 2009-06-08 |
TW200801758A (en) | 2008-01-01 |
GB0608055D0 (en) | 2006-05-31 |
EP2016459A1 (en) | 2009-01-21 |
BRPI0710770A2 (en) | 2011-06-07 |
WO2007122409A1 (en) | 2007-11-01 |
JP2009534974A (en) | 2009-09-24 |
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