CN101444221B - Composite containing oxadiazines and pyrromonazole pesticide - Google Patents
Composite containing oxadiazines and pyrromonazole pesticide Download PDFInfo
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- CN101444221B CN101444221B CN2008101907398A CN200810190739A CN101444221B CN 101444221 B CN101444221 B CN 101444221B CN 2008101907398 A CN2008101907398 A CN 2008101907398A CN 200810190739 A CN200810190739 A CN 200810190739A CN 101444221 B CN101444221 B CN 101444221B
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- fipronil
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Abstract
The invention relates to a desinsection composite which belongs to the technical field of pesticide. The desinsection composite comprises Indoxacarb and one of pyrromonazole pesticides of crotonylfipronil or ethiprole; wherein, the weight portion ratio of the Indoxacarb to the pyrethroid pesticides is 20:1-1:20. The Indoxacarb after being complexly mixed with the crotonylfipronil or the ethiprole has remarkable synergy, and is used for controlling the pests on the crops like rice, fruit trees, cotton, vegetables, and the like, in particular the insect pests with piercing sucking mouthparts like asparagus caterpillar, diamond back moth, Chilo suppressalis, paddy borer, rice leaf roller, cotton bollworm, and the like.
Description
Technical field
The present invention relates to a kind of composition pesticide, particularly contain the Pesticidal combination of indenes worm prestige and Insecticidal pyrazolines.
Background technology
Lepidoptera pest such as beet armyworm, diamond-back moth, the snout moth's larva of rice, cotton bollworm and plant hopper, thrips etc. are the important pests on the crops such as vegetables, cotton, paddy rice, and their occurrence degrees are heavy, and are very harmful.In recent years, because single drug and the medication of non-science have caused these insects that the agricultural chemicals of current use has been produced resistance in various degree, become a great problem of chemical control.Simultaneously, for controlling its harm, peasant's frequent dispenser of having to, this not only causes peasant burden to increase the weight of, and has also aggravated the pollution of environment and the destruction of natural, ecological.Therefore, be badly in need of efficient, good, as to overcome and delay pest resistance to insecticide insecticide new product with Environmental compatibility.
Indenes worm prestige is a kind of Xin Xing oxadiazine insecticides, and main rising tagged and stomach poison function, and its insecticidal mechanism is by the sodium-ion channel in the blocking-up insect nerve cell, makes the nerve cell loss of function, and insect is benumbed, and the coordination ability descends, and is final dead.Medicament enters in the polypide by contacting or get food, does not have cross resistance with other insecticide.Active high to insect, particularly lepidoptera pest is as safe as a house to natural enemy insect, and is residual low in crop.But therefore indenes worm prestige action spectrum relative narrower, and agricultural cost height have limited it to a certain extent and have applied.
Butene-fipronil belongs to the Phenylpyrazole insecticides, be a kind of insecticide that China has independent intellectual property right, be mainly used in the control of paddy rice, fruit tree and vegetable-crop pest-insect, fine to striped rice borer, diamond-back moth effect, but its systemic action is poor, to nocturnal moth class insect weak effect.
Second worm nitrile is a kind of novel pyrazole insecticides, and insecticidal spectrum is wide.By disturbing the chloride channel of γ-An Jidingsuan (GABA) mediation, insect is caused death thereby destroy central nervous system (CNS) normal activity.Important pests such as leafhopper, plant hopper, lepidopterous larvae, fly class and coleoptera there is very high insecticidal activity, to aquatile safety.It has very high selection toxicity, and its mechanism of action uniqueness, and there is not interactivity in the insecticide existing with majority.Second worm nitrile is relatively poor to the lepidoptera pest effect, uses restricted separately.
Summary of the invention
In order to satisfy the needs of agricultural production, make full use of two kinds of active components the be mixed synergistic effect that is produced, the generation that improves preventive effect and delay pest resistance to insecticide, the present invention proposes a kind of efficient, low toxicity, environmental protection and help the Pesticidal combination of pest resistance treatment, be used to prevent and treat the insect of crops such as paddy rice, cotton, vegetables.
In order to reach goal of the invention, the inventor is by a large amount of biologicall test screenings, and unexpected discovery indenes worm prestige and butene-fipronil or second worm nitrile are composite with certain proportion, and insects such as antagonism property of medicine rice fulgorid have significant synergies.
On the basis of above-mentioned discovery, through composition is carried out symphyogenetic quantitative analysis, determine optimal proportion, formed technical scheme of the present invention, promptly be a kind of active ingredient (A), be another active ingredient (B) with Insecticidal pyrazolines butene-fipronil or second worm nitrile with indenes worm prestige, the mass ratio of A and B is 20: 1-1: 20, and all the other are to allow in the agricultural chemicals to use and the acceptable auxiliary element.
Pesticidal combination of the present invention is prepared into known method and is fit to any one formulation that agricultural is used, and reasonable formulation is missible oil, water dispersible granules, suspending agent, aqueous emulsion and microemulsion.
The auxiliary agent that uses in the composition of the present invention comprises that solvent, dispersant, emulsifier, stabilizing agent, antifreezing agent, thickener etc. and other are of value to the known substance that active ingredient is stablized and drug effect is brought into play in preparation, all be the various compositions of using or allow use in the pesticidal preparations always, be not particularly limited, concrete composition and consumption require to determine by simple experiment according to prescription.
Product described in the invention can the finished product preparation form provide, and promptly each material mixes in the composition, and the composition of composition also can provide with single agent form, directly directly mixes in bucket or jar before the use, is diluted to required concentration then.
Pesticidal combination of the present invention can be used for preventing and treating various pest, be mainly used in the control of insect of crops such as paddy rice, cotton, vegetables, fruit tree, especially lepidoptera pest and suckings pest such as plant hopper, thrips such as beet armyworm, diamond-back moth, striped rice borer, paddy stem borer, rice leaf roller, cotton bollworm.
Beneficial effect of the present invention is: 1. being mixed has obvious synergistic effect, has reduced the consumption of active ingredient, has improved control efficiency; 2. composition is made up of the different active ingredient of two class mechanism of action, helps overcoming and delaying the pesticide resistance of insect; 3. compare with single agent, enlarged the control spectrum; 4. compare with the single agent of indenes worm prestige, lasting effect obviously improves, more remarkable effect; 5. compare with butene-fipronil or the agent of second worm nitrile list, good quick-acting is arranged.
Embodiment
In order to make purpose of the present invention, technical scheme and advantage clearer, the present invention describes with following specific embodiment, but the present invention is limited to these examples absolutely not.The following stated only is the present invention embodiment preferably, only is used to explain the present invention, can not therefore be interpreted as the restriction to claim of the present invention.Should be pointed out that all any modifications of being made within the spirit and principles in the present invention, be equal to replacement and improvement etc., all should be included within protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.
The combination of active principles of different agricultural chemicals is made agricultural chemicals, is a kind of mode effectively and efficiently that exploitation at present and development novel pesticide and control agricultural go up resistant insect.The agricultural chemicals of different cultivars shows three kinds of type of action: summation action, synergistic effect and antagonism after mixing usually.But be specially which kind of effect, unpredictable, have only by a large amount of tests and just can know.
The inventor is by a large amount of screening tests, find that indenes worm prestige and butene-fipronil or second worm nitrile combination antagonism rice fulgorid, striped rice borer have obvious role in synergism, its effect is not only the simple addition of two kinds of medicaments, specifically is illustrated with following biologicall test example.
Biologicall test example 1: indenes worm prestige and butene-fipronil composite Toxicity Determination and proportioning screening to striped rice borer
Adopt spray-on process, the indenes worm prestige of mensuration different proportion and butene-fipronil compound drug are to the indoor virulence of striped rice borer.
Calculate the toxicity index of each medicament and the co-toxicity coefficient of mixture (CTC value) according to the abundant method of Sun Yun, promptly CTC≤80 are antagonism, and 80＜CTC＜120 are summation action, and CTC 〉=120 are synergistic effect.
Actual measurement toxicity index (ATI)=standard medicament LC
50/ reagent agent LC
50* 100
The percentage composition of B in percentage composition+B medicament toxicity index * mixture of A in theoretical toxicity index (TTI)=A medicament toxicity index * mixture
Co-toxicity coefficient (CTC)=mixture actual measurement toxicity index (the ATI)/theoretical toxicity index (TTI) * 100 of mixture
The result shows, indenes worm prestige and butene-fipronil are at proportioning 20: 1-1: between 20, obvious synergistic effect is arranged, co-toxicity coefficient is at (table 1) more than 125.
The composite indoor co-toxicity coefficient measurement result of table 1 indenes worm prestige and butene-fipronil to striped rice borer
| Handle | LC 50(mg/L) | ATI | TTI | Co-toxicity coefficient CTC |
| Butene-fipronil | 6.37 | 100.0 | ||
| Indenes worm prestige | 6.25 | 101.9 | ||
| Indenes worm prestige 20: butene-fipronil 1 | 4.98 | 127.9 | 100.1 | 127.8 |
| Indenes worm prestige 10: butene-fipronil 1 | 4.45 | 143.1 | 100.2 | 142.9 |
| Indenes worm prestige 5: butene-fipronil 1 | 4.08 | 156.1 | 100.3 | 155.6 |
| Indenes worm prestige 1: butene-fipronil 1 | 3.53 | 180.5 | 101.0 | 178.7 |
| Indenes worm prestige 1: butene-fipronil 3 | 2.84 | 224.3 | 101.4 | 221.1 |
| Indenes worm prestige 1: butene-fipronil 5 | 3.11 | 204.8 | 101.6 | 201.6 |
| Indenes worm prestige 1: butene-fipronil 10 | 3.98 | 160.1 | 101.7 | 157.3 |
| Indenes worm prestige 1: butene-fipronil 20 | 4.67 | 136.4 | 101.8 | 134.0 |
Biologicall test example 2: indenes worm prestige and second worm nitrile composite Toxicity Determination and proportioning screening to rice fulgorid
Adopt spray-on process, the indenes worm prestige of mensuration different proportion and second worm nitrile compound drug are to the indoor virulence of rice fulgorid.Calculate the toxicity index of each medicament and the co-toxicity coefficient of mixture (CTC value) according to the abundant method of Sun Yun, promptly CTC≤80 are antagonism, and 80＜CTC＜120 are summation action, and CTC 〉=120 are synergistic effect.The result shows, indenes worm prestige and second worm nitrile are at proportioning 20: 1-1: between 20, show obvious synergistic effect, co-toxicity coefficient is at (table 2) more than 130.
The composite indoor co-toxicity coefficient measurement result of table 2 indenes worm prestige and second worm nitrile to rice fulgorid
| Handle | LC 50(mg/L) | AT1 | TTI | Co-toxicity coefficient CTC |
| Indenes worm prestige | 9.65 | 100.0 | ||
| Second worm nitrile | 3.44 | 280.5 | ||
| Indenes worm prestige 20: second worm nitrile 1 | 5.39 | 179.0 | 108.6 | ?164.9 |
| Indenes worm prestige 10: second worm nitrile 1 | 4.76 | 202.7 | 116.4 | ?174.2 |
| Indenes worm prestige 3: second worm nitrile 1 | 2.85 | 338.6 | 145.1 | ?233.3 |
| Indenes worm prestige 1: second worm nitrile 1 | 2.07 | 466.2 | 190.3 | ?245.0 |
| Indenes worm prestige 1: second worm nitrile 5 | 1.45 | 665.5 | 250.4 | 265.7 |
| Indenes worm prestige 1: second worm nitrile 10 | 2.01 | 480.1 | 264.1 | 181.8 |
| Indenes worm prestige 1: second worm nitrile 20 | 2.66 | 362.8 | 271.9 | 133.4 |
Pesticidal combination of the present invention can be prepared into known method and be fit to any one formulation that agricultural is used, and reasonable formulation is missible oil, water dispersible granules, suspending agent, aqueous emulsion and microemulsion.Below describe with specific embodiment.Percentage all is weight percentage in all prescriptions.The processing technology of the various preparations of the present composition is prior art, can change to some extent according to different situations.
Embodiment 1:22% indenes worm prestige butene-fipronil suspending agent
Indenes worm prestige 20%
Butene-fipronil 2%
Methyl naphthalene sulfonate formaldehyde condensate 10%
Xanthans 1%
Bentonite 1%
The newborn 500# 5% of farming
Isopropyl alcohol 5%
Water complements to 100%.
The ratio of each component such as active component, dispersant, wetting agent and water in prescription mixed, after grinding and/or high speed shear, obtain 22% indenes worm prestige butene-fipronil suspending agent.
This embodiment is applied to prevent and treat the wild cabbage diamond-back moth.By 5000 extraordinarily water dilution sprayings, the control efficiency of 1 day, 7 days and 15 days is respectively 86.1%, 95.8%, 93.5% behind the medicine with 22% indenes worm prestige butene-fipronil suspending agent.15% indenes worm prestige suspending agent, is used with the quadrat method use by 1200 times by 3500 times and 5% butene-fipronil missible oil, and 1 day preventive effect is respectively 78.4%, 70.3% behind the medicine, and the preventive effect of 7 days and 15 days is respectively 87.3%, 88.2% and 78.8%, 91.4% behind the medicine.The synergistic effect of the composite back of indenes worm prestige and butene-fipronil is obvious, to preventive effect, quick-acting and the lasting effect of diamond-back moth all significantly better than single agent.
Embodiment 2:25% indenes worm prestige butene-fipronil missible oil
Indenes worm prestige 20%
Butene-fipronil 5%
N-Methyl pyrrolidone 10%
The newborn 1601# 5% of farming
The newborn 500# 5% of farming
Dimethylbenzene complements to 100%.
Active component, emulsifier and the auxiliary agent ratio in prescription is added in the mixing kettle successively, stir, make 25% indenes worm prestige butene-fipronil missible oil.
This embodiment is applied to prevent and treat rice leaf roller.By 5000 extraordinarily water dilution sprayings, the control efficiency of 1 day, 7 days and 15 days is respectively 87.2%, 96.3%, 96.8% behind the medicine with 25% indenes worm prestige butene-fipronil missible oil.15% indenes worm prestige suspending agent, is used with the quadrat method use by 1200 times by 3500 times and 5% butene-fipronil missible oil, and 1 day preventive effect is respectively 76.7%, 68.5% behind the medicine, and the preventive effect of 7 days and 15 days is respectively 88.5%, 95.5% and 75.8%, 92.5% behind the medicine.The synergistic effect of the composite back of indenes worm prestige and butene-fipronil is obvious, to preventive effect, quick-acting and the lasting effect of rice leaf roller all significantly better than single agent.
Embodiment 3:12% indenes worm prestige butene-fipronil microemulsion
Indenes worm prestige 2%
Butene-fipronil 10%
N-Methyl pyrrolidone 10%
The newborn 500# 5% of farming
The newborn 1601# 5% of farming
Water complements to 100%.
Former medicine, solvent, emulsifier are added together, make and be dissolved into even oil phase; With water-soluble component and the mixed water that gets of water; Under high-speed stirred, oil phase is mixed with water, make 12% indenes worm prestige butene-fipronil microemulsion.
This embodiment is applied to prevent and treat the cotton green plant bug.By 3000 extraordinarily water dilution sprayings, the control efficiency of 1 day, 7 days and 15 days is respectively 84.7%, 91.9%, 89.3% behind the medicine with 12% indenes worm prestige butene-fipronil microemulsion.15% indenes worm prestige suspending agent, is used with the quadrat method use by 1200 times by 3500 times and 5% butene-fipronil missible oil, and 1 day preventive effect is respectively 77.2%, 65.3% behind the medicine, and the preventive effect of 7 days and 15 days is respectively 86.4%, 88.0% and 76.1%, 89.1% behind the medicine.The synergistic effect of the composite back of indenes worm prestige and butene-fipronil is obvious, to preventive effect, quick-acting and the lasting effect of cotton bollworm all significantly better than single agent.
Embodiment 4:66% indenes worm prestige butene-fipronil water dispersible granules
Indenes worm prestige 6%
Butene-fipronil 60%
Negel 5%
Sodium lignin sulfonate 7%
Lauryl sodium sulfate 2%
Ammonium sulfate 5%
Precipitated calcium carbonate complements to 100%.
Active component, dispersant, wetting agent, disintegrant and the filler ratio in prescription is mixed, become wetting powder through comminution by gas stream, add a certain amount of water mixing extruding again and make material, obtain 66% indenes worm prestige butene-fipronil water-dispersible granules after the drying screening.
This embodiment is applied to prevent and treat rice thrips.By 10000 extraordinarily water dilution sprayings, the control efficiency of 1 day, 7 days and 15 days is respectively 88.9%, 97.4%, 95.6% behind the medicine with 66% indenes worm prestige butene-fipronil water dispersible granules.15% indenes worm prestige suspending agent, is used with the quadrat method use by 1200 times by 3500 times and 5% butene-fipronil missible oil, and 1 day preventive effect is respectively 54.1%, 70.3% behind the medicine, and the preventive effect of 7 days and 15 days is respectively 81.7%, 93.4% and 61.8%, 91.6% behind the medicine.The synergistic effect of the composite back of indenes worm prestige and butene-fipronil is obvious, to preventive effect, quick-acting and the lasting effect of rice thrips all significantly better than single agent.
Embodiment 5:42% indenes worm prestige second worm nitrile suspending agent
Indenes worm prestige 40%
Second worm nitrile 2%
Methyl naphthalene sulfonate formaldehyde condensate 10%
Xanthans 1%
Bentonite 1%
Glycerine 5%
Water complements to 100%.
The ratio of each component such as active component, dispersant, wetting agent and water in prescription mixed, after grinding and/or high speed shear, obtain 42% indenes worm prestige second worm nitrile suspending agent.
This embodiment is applied to prevent and treat the apple apple leaf miner.By 5000 extraordinarily water dilution sprayings, the control efficiency of 1 day, 7 days and 15 days is respectively 87.9%, 93.3%, 90.8% behind the medicine with 42% indenes worm prestige second worm nitrile suspending agent.15% indenes worm prestige suspending agent, is used with the quadrat method use by 3000 times by 3500 times and 10% second worm nitrile suspending agent, and 1 day preventive effect is respectively 78.5%, 69.7% behind the medicine, and the preventive effect of 7 days and 15 days is respectively 88.5%, 85.5% and 77.8%, 88.6% behind the medicine.The synergistic effect of the composite back of indenes worm prestige and second worm nitrile is obvious, to preventive effect, quick-acting and the lasting effect of apple apple leaf miner all significantly better than single agent.
Embodiment 6:20% indenes worm prestige second worm nitrile missible oil
Indenes worm prestige 18%
Second worm nitrile 2%
N-Methyl pyrrolidone 10%
The newborn 1601# 5% of farming
The newborn 500# 5% of farming
Dimethylbenzene complements to 100%.
Active component, emulsifier and the auxiliary agent ratio in prescription is added in the mixing kettle successively, stir, make 20% indenes worm prestige second worm nitrile missible oil.
This embodiment is applied to prevent and treat the wild cabbage beet armyworm.By 5000 extraordinarily water dilution sprayings, the control efficiency of 1 day, 7 days and 15 days is respectively 86.4%, 93.5%, 91.1% behind the medicine with 20% indenes worm prestige second worm nitrile missible oil.15% indenes worm prestige suspending agent, is used with the quadrat method use by 3000 times by 3500 times and 10% second worm nitrile suspending agent, and 1 day preventive effect is respectively 79.4%, 62.1% behind the medicine, and the preventive effect of 7 days and 15 days is respectively 89.3%, 68.5% and 86.8%, 50.6% behind the medicine.The synergistic effect of the composite back of indenes worm prestige and second worm nitrile is obvious, to preventive effect, quick-acting and the lasting effect of beet armyworm all significantly better than single agent.
Embodiment 7:10% indenes worm prestige ethiprole emulsion in water
Indenes worm prestige 5%
Second worm nitrile 5%
N-Methyl pyrrolidone 10%
Calcium dodecyl benzene sulfonate 5%
The newborn 600# 5% of farming
Water complements to 100%.
Former medicine, solvent, emulsifier are added together, make and be dissolved into even oil phase; With water-soluble component and the mixed water that gets of water; Under high-speed stirred, oil phase is mixed with water, make 10% indenes worm prestige ethiprole emulsion in water.
This embodiment is applied to prevent and treat cotton bollworm.By 3000 extraordinarily water dilution sprayings, the control efficiency of 1 day, 7 days and 15 days is respectively 82.7%, 92.7%, 88.6% behind the medicine with 10% indenes worm prestige ethiprole emulsion in water.15% indenes worm prestige suspending agent, is used with the quadrat method use by 3000 times by 3500 times and 10% second worm nitrile suspending agent, and 1 day preventive effect is respectively 76.4%, 69.2% behind the medicine, and the preventive effect of 7 days and 15 days is respectively 85.3%, 84.2% and 73.8%, 85.8% behind the medicine.The synergistic effect of the composite back of indenes worm prestige and second worm nitrile is obvious, to preventive effect, quick-acting and the lasting effect of cotton bollworm all significantly better than single agent.
Embodiment 8:24% indenes worm prestige second worm nitrile suspending agent
Indenes worm prestige 4%
Second worm nitrile 20%
Methyl naphthalene sulfonate formaldehyde condensate 10%
Xanthans 1%
Bentonite 1%
Glycerine 2%
Water complements to 100%.
The ratio of each component such as active component, dispersant, wetting agent and water in prescription mixed, after grinding and/or high speed shear, obtain 24% indenes worm prestige second worm nitrile suspending agent.
This embodiment is applied to rice fulgorid.By 5000 extraordinarily water dilution sprayings, the control efficiency of 1 day, 7 days and 30 days is respectively 85.2%, 89.3%, 94.8% behind the medicine with 24% indenes worm prestige second worm nitrile suspending agent.15% indenes worm prestige suspending agent, is used with the quadrat method use by 3000 times by 3500 times and 10% second worm nitrile suspending agent, and 1 day preventive effect is respectively 74.5%, 66.7% behind the medicine, and the preventive effect of 7 days and 30 days is respectively 78.5%, 82.5% and 45.8%, 91.7% behind the medicine.The synergistic effect of the composite back of indenes worm prestige and second worm nitrile is obvious, to preventive effect, quick-acting and the lasting effect of rice fulgorid all significantly better than single agent.
Embodiment 9:42% indenes worm prestige second worm nitrile water dispersible granules
Indenes worm prestige 2%
Second worm nitrile 40%
Negel 5%
Sodium lignin sulfonate 5%
Lauryl sodium sulfate 2%
Ammonium sulfate 5%
Precipitated calcium carbonate complements to 100%.
Active component, dispersant, wetting agent, disintegrant and the filler ratio in prescription is mixed, become wetting powder, add a certain amount of water mixing extruding again and make material, obtain 42% indenes worm prestige second worm nitrile water-dispersible granules after the drying screening through comminution by gas stream.
This embodiment is applied to prevent and treat striped rice borer.By 4000 extraordinarily water dilution sprayings, the control efficiency of 1 day, 7 days and 15 days is respectively 87.7%, 97.4%, 93.6% behind the medicine with 42% indenes worm prestige second worm nitrile water dispersible granules.15% indenes worm prestige suspending agent, is used with the quadrat method use by 3000 times by 3500 times and 10% second worm nitrile suspending agent, and 1 day preventive effect is respectively 81.7%, 71.2% behind the medicine, and the preventive effect of 7 days and 15 days is respectively 88.7%, 89.2% and 79.8%, 91.3% behind the medicine.The synergistic effect of the composite back of indenes worm prestige and second worm nitrile is obvious, to preventive effect, quick-acting and the lasting effect of striped rice borer all significantly better than single agent.
Claims (1)
1. a Pesticidal combination is characterized in that active ingredient is indenes worm prestige and butene-fipronil, and the ratio of quality and the number of copies of indenes worm prestige and butene-fipronil is 10: 1-1: 10.
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| Application Number | Priority Date | Filing Date | Title |
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| CN2008101907398A CN101444221B (en) | 2008-12-27 | 2008-12-27 | Composite containing oxadiazines and pyrromonazole pesticide |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008101907398A CN101444221B (en) | 2008-12-27 | 2008-12-27 | Composite containing oxadiazines and pyrromonazole pesticide |
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| CN101444221A CN101444221A (en) | 2009-06-03 |
| CN101444221B true CN101444221B (en) | 2011-11-30 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101735210B (en) * | 2009-12-03 | 2013-04-24 | 湖南化工研究院 | N-substituted oxadiazine compounds with insecticidal and bactericidal activities, preparation method thereof and use thereof |
| CN101911943B (en) * | 2010-06-28 | 2013-04-17 | 陕西上格之路生物科学有限公司 | Methoxyfenozide-containing insecticidal composition |
| CN103283761B (en) * | 2012-02-27 | 2015-11-25 | 陕西韦尔奇作物保护有限公司 | A kind of Pesticidal combination containing second worm nitrile |
| CN105660626A (en) * | 2016-02-19 | 2016-06-15 | 河北岗恩生物科技有限公司 | Indoxacarb aromatic-free missible oil and preparation method thereof |
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| CN1373636A (en) * | 1999-09-14 | 2002-10-09 | 阿方蒂农科股份有限公司 | Compositions and methods for controlling insects which damage rice and other crops |
| CN1398515A (en) * | 2002-07-30 | 2003-02-26 | 王正权 | N-phenyl pyrazole derivative pesticide |
| WO2008030385A2 (en) * | 2006-09-01 | 2008-03-13 | E. I. Du Pont De Nemours And Company | Local topical administration formulations containing indoxacarb |
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2008
- 2008-12-27 CN CN2008101907398A patent/CN101444221B/en active Active
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1373636A (en) * | 1999-09-14 | 2002-10-09 | 阿方蒂农科股份有限公司 | Compositions and methods for controlling insects which damage rice and other crops |
| CN1398515A (en) * | 2002-07-30 | 2003-02-26 | 王正权 | N-phenyl pyrazole derivative pesticide |
| WO2008030385A2 (en) * | 2006-09-01 | 2008-03-13 | E. I. Du Pont De Nemours And Company | Local topical administration formulations containing indoxacarb |
Non-Patent Citations (1)
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