CN101408016B - 造纸湿部多价金属阳离子垃圾清除剂与制备方法及应用 - Google Patents
造纸湿部多价金属阳离子垃圾清除剂与制备方法及应用 Download PDFInfo
- Publication number
- CN101408016B CN101408016B CN2008101229830A CN200810122983A CN101408016B CN 101408016 B CN101408016 B CN 101408016B CN 2008101229830 A CN2008101229830 A CN 2008101229830A CN 200810122983 A CN200810122983 A CN 200810122983A CN 101408016 B CN101408016 B CN 101408016B
- Authority
- CN
- China
- Prior art keywords
- polyvalent metal
- metal cation
- paper making
- wet part
- natural polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 150000001768 cations Chemical class 0.000 title claims abstract description 50
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 43
- 239000002184 metal Substances 0.000 title claims abstract description 43
- 238000000034 method Methods 0.000 title description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 30
- 229920005615 natural polymer Polymers 0.000 claims abstract description 21
- 238000002360 preparation method Methods 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims abstract description 15
- 239000002516 radical scavenger Substances 0.000 claims abstract description 12
- 238000007069 methylation reaction Methods 0.000 claims abstract description 9
- 239000002904 solvent Substances 0.000 claims abstract description 7
- 238000006266 etherification reaction Methods 0.000 claims abstract description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 38
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 15
- LTVDFSLWFKLJDQ-UHFFFAOYSA-N α-tocopherolquinone Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)(O)CCC1=C(C)C(=O)C(C)=C(C)C1=O LTVDFSLWFKLJDQ-UHFFFAOYSA-N 0.000 claims description 14
- 238000006243 chemical reaction Methods 0.000 claims description 12
- -1 hydroxyl carboxy Chemical group 0.000 claims description 12
- 239000000783 alginic acid Substances 0.000 claims description 9
- 235000010443 alginic acid Nutrition 0.000 claims description 9
- 229920000615 alginic acid Polymers 0.000 claims description 9
- 229960001126 alginic acid Drugs 0.000 claims description 9
- FDRCDNZGSXJAFP-UHFFFAOYSA-M sodium chloroacetate Chemical compound [Na+].[O-]C(=O)CCl FDRCDNZGSXJAFP-UHFFFAOYSA-M 0.000 claims description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 230000011987 methylation Effects 0.000 claims description 8
- 229920002472 Starch Polymers 0.000 claims description 6
- 239000008107 starch Substances 0.000 claims description 6
- 235000019698 starch Nutrition 0.000 claims description 6
- 150000004781 alginic acids Chemical class 0.000 claims description 5
- 229920002907 Guar gum Polymers 0.000 claims description 3
- 239000000665 guar gum Substances 0.000 claims description 3
- 235000010417 guar gum Nutrition 0.000 claims description 3
- 229960002154 guar gum Drugs 0.000 claims description 3
- 125000001453 quaternary ammonium group Chemical group 0.000 claims description 2
- 230000010148 water-pollination Effects 0.000 claims 1
- 229910021645 metal ion Inorganic materials 0.000 abstract description 19
- 239000010813 municipal solid waste Substances 0.000 abstract description 8
- 239000000835 fiber Substances 0.000 abstract description 5
- 229920001131 Pulp (paper) Polymers 0.000 abstract description 4
- 239000002253 acid Substances 0.000 abstract 2
- 239000013522 chelant Substances 0.000 abstract 1
- 238000006467 substitution reaction Methods 0.000 description 10
- 239000011575 calcium Substances 0.000 description 9
- 239000000706 filtrate Substances 0.000 description 6
- 239000011347 resin Substances 0.000 description 6
- 229920005989 resin Polymers 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 5
- 239000011777 magnesium Substances 0.000 description 5
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 4
- 239000001768 carboxy methyl cellulose Substances 0.000 description 4
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 4
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 238000005115 demineralization Methods 0.000 description 3
- 230000002328 demineralizing effect Effects 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229920000371 poly(diallyldimethylammonium chloride) polymer Polymers 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000000967 suction filtration Methods 0.000 description 3
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000003456 ion exchange resin Substances 0.000 description 2
- 229920003303 ion-exchange polymer Polymers 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N 1,4a-dimethyl-7-propan-2-yl-2,3,4,4b,5,6,10,10a-octahydrophenanthrene-1-carboxylic acid Chemical compound C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- QXDMQSPYEZFLGF-UHFFFAOYSA-L calcium oxalate Chemical compound [Ca+2].[O-]C(=O)C([O-])=O QXDMQSPYEZFLGF-UHFFFAOYSA-L 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000008235 industrial water Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- SURQXAFEQWPFPV-UHFFFAOYSA-L iron(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O SURQXAFEQWPFPV-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229940032147 starch Drugs 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Landscapes
- Polysaccharides And Polysaccharide Derivatives (AREA)
- Paper (AREA)
Abstract
Description
Claims (2)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2008101229830A CN101408016B (zh) | 2008-06-20 | 2008-06-20 | 造纸湿部多价金属阳离子垃圾清除剂与制备方法及应用 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2008101229830A CN101408016B (zh) | 2008-06-20 | 2008-06-20 | 造纸湿部多价金属阳离子垃圾清除剂与制备方法及应用 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101408016A CN101408016A (zh) | 2009-04-15 |
CN101408016B true CN101408016B (zh) | 2011-05-18 |
Family
ID=40571206
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2008101229830A Expired - Fee Related CN101408016B (zh) | 2008-06-20 | 2008-06-20 | 造纸湿部多价金属阳离子垃圾清除剂与制备方法及应用 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN101408016B (zh) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104003475B (zh) * | 2013-02-26 | 2016-03-23 | 南京林业大学 | 一种造纸白水中胶体性干扰物的分离方法 |
CN104532402A (zh) * | 2014-12-31 | 2015-04-22 | 福建恒安集团有限公司 | 一种多功能超吸水海藻纤维的制备 |
CN104878653B (zh) * | 2015-06-08 | 2017-01-18 | *** | 再生纸料胶粘物控制剂的制备方法 |
CN108042842A (zh) * | 2017-12-14 | 2018-05-18 | 傅婵 | 中草药抑菌芯片及其制备方法 |
CN109082937A (zh) * | 2018-09-04 | 2018-12-25 | 南京林业大学 | 一种适用于高电解质环境的纸张强度增强方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1229800A (zh) * | 1998-03-18 | 1999-09-29 | 国家淀粉及化学投资控股公司 | 制备两性瓜耳胶衍生物的方法 |
CN1554670A (zh) * | 2003-12-22 | 2004-12-15 | 盐城工学院 | 双子型两性壳聚糖衍生物的制备 |
CN1939932A (zh) * | 2006-06-23 | 2007-04-04 | 中国科学院成都有机化学有限公司 | 一种水溶性两性淀粉的合成方法 |
-
2008
- 2008-06-20 CN CN2008101229830A patent/CN101408016B/zh not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1229800A (zh) * | 1998-03-18 | 1999-09-29 | 国家淀粉及化学投资控股公司 | 制备两性瓜耳胶衍生物的方法 |
CN1554670A (zh) * | 2003-12-22 | 2004-12-15 | 盐城工学院 | 双子型两性壳聚糖衍生物的制备 |
CN1939932A (zh) * | 2006-06-23 | 2007-04-04 | 中国科学院成都有机化学有限公司 | 一种水溶性两性淀粉的合成方法 |
Non-Patent Citations (8)
Title |
---|
安郁琴 刘忠.制浆造纸助剂 1.中国轻工业出版社,2003,195-197. |
安郁琴 刘忠.制浆造纸助剂 1.中国轻工业出版社,2003,195-197. * |
张光华 房瑜红 陈维滕.一种新型两性淀粉的制备方法.造纸化学品 1.2005,(1),3-4. |
张光华 房瑜红 陈维滕.一种新型两性淀粉的制备方法.造纸化学品 1.2005,(1),3-4. * |
王杰 肖锦 詹怀宇.两性高分子水处理剂的研究进展.环境污染治理技术与设备1 3.2000,1(3),14-18. |
王杰 肖锦 詹怀宇.两性高分子水处理剂的研究进展.环境污染治理技术与设备1 3.2000,1(3),14-18. * |
胡惠仁等.造纸化学品(第二版) 2.化学工业出版社,2008,83-84. |
胡惠仁等.造纸化学品(第二版) 2.化学工业出版社,2008,83-84. * |
Also Published As
Publication number | Publication date |
---|---|
CN101408016A (zh) | 2009-04-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101408016B (zh) | 造纸湿部多价金属阳离子垃圾清除剂与制备方法及应用 | |
Mautner et al. | Phosphorylated nanocellulose papers for copper adsorption from aqueous solutions | |
Liimatainen et al. | Flocculation performance of a cationic biopolymer derived from a cellulosic source in mild aqueous solution | |
Wahlström et al. | Lignin cationization with glycidyltrimethylammonium chloride aiming at water purification applications | |
Suopajärvi | Functionalized nanocelluloses in wastewater treatment applications | |
EP3294674B1 (en) | Water treatment | |
EP3294675B1 (en) | Water treatment | |
CN101525856B (zh) | 低分子量高阳离子取代度淀粉控制废纸浆微胶黏物 | |
CN102174505B (zh) | 一种处理造纸白水用颗粒状载体固定化双酶的制备方法 | |
CN103865060B (zh) | 一种含有苯硼酸官能团的高分子助留助滤剂的制备方法及其应用 | |
EP0005419B1 (en) | Aluminium sulphate compositions containing polynuclear complexes and a method of producing the same and the use thereof | |
RU2495830C1 (ru) | Способ извлечения ионов тяжелых металлов из водных растворов | |
CN102329398B (zh) | 多功能造纸用瓜尔胶衍生物及其制备方法与应用 | |
US5907037A (en) | Cellulosic ion-exchange medium, and method of making and using the same | |
CN110642357B (zh) | 一种用于微藻捕捉的絮凝剂及其制备方法和应用 | |
CN109162144B (zh) | 一种纸与纸制品湿强增效剂的制备方法及应用 | |
Abu Taleb et al. | Hybrid bioadsorbents for heavy metal decontamination from wastewater: A review | |
CN105776481A (zh) | 黄原酸酯阳离子双变性秸秆纤维印染废水处理剂及其制备方法 | |
Liu et al. | Analysis of dissolved and colloidal substances in old corrugated containers’ whitewater and dissolved substances’ impact on colloidal substances’ stability | |
JP5817381B2 (ja) | 酸化パルプの洗浄・脱水方法 | |
Li et al. | Sustainable cationic cellulose for highly efficient flocculation of Kaolin suspension | |
CN106883349A (zh) | 一种絮凝剂的制备方法及絮凝剂的应用 | |
KR101776572B1 (ko) | 음이온성 나노셀룰로오스 응집제의 제조방법 | |
JPH10502871A (ja) | 製紙における廃棄物の排除 | |
JP2020019859A (ja) | セルロースナノファイバーの製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Hailong Paper Industry (Taicang) Co.,Ltd. Assignor: Nanjing Forestry University Contract record no.: 2011320010010 Denomination of invention: Paper making wet part polyvalent metal cation refuse removal agent and preparing method and application thereof Granted publication date: 20110518 License type: Exclusive License Open date: 20090415 Record date: 20110719 |
|
EC01 | Cancellation of recordation of patent licensing contract |
Assignee: Hailong Paper Industry (Taicang) Co.,Ltd. Assignor: Nanjing Forestry University Contract record no.: 2011320010010 Date of cancellation: 20140610 |
|
LICC | Enforcement, change and cancellation of record of contracts on the licence for exploitation of a patent or utility model | ||
EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20090415 Assignee: HEBEI YONGXIN PAPER INDUSTRY CO.,LTD. Assignor: Nanjing Forestry University Contract record no.: 2014320010116 Denomination of invention: Paper making wet part polyvalent metal cation refuse removal agent and preparing method and application thereof Granted publication date: 20110518 License type: Exclusive License Record date: 20140625 |
|
LICC | Enforcement, change and cancellation of record of contracts on the licence for exploitation of a patent or utility model | ||
EM01 | Change of recordation of patent licensing contract | ||
EM01 | Change of recordation of patent licensing contract |
Change date: 20180228 Contract record no.: 2014320010116 Assignee after: NINE DRAGONS PAPER (HEBEI) CO.,LTD. Assignee before: HEBEI YONGXIN PAPER INDUSTRY CO.,LTD. |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20211027 Address after: 223600 the northern side of Yinshan Road, the eastern side of the sponge plant in Shuyang County, Suqian, Jiangsu. Patentee after: JIANGSU NINGSHU PAPER CO.,LTD. Address before: Longpan road Xuanwu District of Nanjing city of Jiangsu Province, No. 159 210037 Patentee before: NANJING FORESTRY University |
|
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20110518 |
|
CF01 | Termination of patent right due to non-payment of annual fee |