CN101407394A - Brucite fiber reinforced finished cement mortar material - Google Patents

Brucite fiber reinforced finished cement mortar material Download PDF

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Publication number
CN101407394A
CN101407394A CNA2008102322428A CN200810232242A CN101407394A CN 101407394 A CN101407394 A CN 101407394A CN A2008102322428 A CNA2008102322428 A CN A2008102322428A CN 200810232242 A CN200810232242 A CN 200810232242A CN 101407394 A CN101407394 A CN 101407394A
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China
Prior art keywords
cement
mortar
sand
cement mortar
fiber
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Pending
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CNA2008102322428A
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Chinese (zh)
Inventor
刘开平
姜雅峰
王尉和
张晓旭
关博文
张艳
周煜伟
赵秀峰
梁东升
张海鸿
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Changan University
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Changan University
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Priority to CNA2008102322428A priority Critical patent/CN101407394A/en
Publication of CN101407394A publication Critical patent/CN101407394A/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B14/00Use of inorganic materials as fillers, e.g. pigments, for mortars, concrete or artificial stone; Treatment of inorganic materials specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B14/38Fibrous materials; Whiskers
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/0068Ingredients with a function or property not provided for elsewhere in C04B2103/00
    • C04B2103/0082Segregation-preventing agents; Sedimentation-preventing agents
    • C04B2103/0083Bleeding-preventing agents
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2103/00Function or property of ingredients for mortars, concrete or artificial stone
    • C04B2103/46Water-loss or fluid-loss reducers, hygroscopic or hydrophilic agents, water retention agents
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/34Non-shrinking or non-cracking materials
    • C04B2111/343Crack resistant materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/50Flexible or elastic materials

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention relates to a commercial cement mortar material reinforced by natural brucite fibers. The introduction of a chemical dispersion additive and the natural brucite short fibers to the cement mortar solves the contradiction between fiber splitting dispersion and the workability of the cement mortar, avoids the phenomena of fiber matting, aggregation and uneven dispersion when other reinforced fibers are applied to the cement mortar, makes full use of the reinforcement function of the short fibers, improves the breaking strength and tightness of the cement mortar, improves the cracking resistance of the cement mortar, and ensures the cement mortar not to bleed water without using a thickening agent, thus having better moisture retention and cohesiveness.

Description

Brucite fiber reinforced finished cement mortar material
Technical field
The present invention relates to a kind of material of construction, particularly brucite fiber reinforced finished cement mortar material.
Background of invention
The commodity sand-cement slurry comprises wet mixing mortar and dry-mixed mortar, is the commodity-type New Building Materials of being produced by professional production factory.Compare series of advantages such as that the commodity sand-cement slurry has is best in quality and stable, with low cost, great variety of goods, construction civilization, work efficiency raising with the sand-cement slurry that traditional working-yard makes.Along with the issuing and implementation of commodity mortar national sector standard, the commodity sand-cement slurry can be rapidly developed.
But similar to traditional sand-cement slurry performance, the commodity sand-cement slurry remains a kind of poor toughness, hard brittle material inhomogeneous, easy to crack, and it is low to exist tensile pressure ratio, and is dry-shrinkage deformed big, shortcomings such as impermeability, splitting resistance, corrosion-resistant.In recent years, along with the construction work development of modernization, particularly cohesive strength, resistance to cleavage, impermeability etc. are all had higher requirement to mortar performance.The tradition cement mortar material is difficult to satisfy the more and more higher actual requirement of engineering.
Mixing each fiber material is one of effective ways that improve sand-cement slurry toughness and splitting resistance.Fiber commonly used has synthetic organic fibre, glass fibre, steel fiber, carbon fiber etc. in mortar at present.But these fibers or cost are too high, or being difficult to construction mixes, and influences it and applies.
In addition, in order to improve the construction workability of commodity sand-cement slurry, add some admixtures in the composition of being everlasting,, the cost of mortar is improved as water-retaining admixture etc.
Summary of the invention
The purpose of this invention is to provide a kind of with natural brucite staple fibre enhanced commodity cement mortar material.This brucite staple fibre enhanced sand-cement slurry has advantages such as intensity height, mixture water-retentivity and cohesiveness are good, splitting resistance is good, with low cost.
Technical scheme of the present invention is achieved in that
The present invention is made up of cement, sand, water, brucite fiber and dispersion admixture, wherein brucite fiber is the staple fibre of 6 grades and following grade, quality consumption in mortar is the 3-6% of cement amount, disperseing admixture quality consumption in the commodity sand-cement slurry is the 1.0-1.8% of cement amount, the quality consumption of sand is 1.0-7.0 a times of cement amount, and the quality consumption of the water yield is 0.35-1.6 a times of cement amount.
Disperse admixture to be made up of naphthalene series high-efficiency water-reducing agent, sulfamate water reducer or sulfonated lignin water reducer, alcohol and urea, the quality consumption is respectively 0.7-1.2%, 0.15-0.30%, 0-0.25%, the 0-0.25% of cement amount.
The manufacture craft of mixing the commodity sand-cement slurry of doing of the present invention is: packing after cement, sand, brucite staple fibre are stirred in forced mixer, and when site construction, add water again and disperse admixture to stir.The manufacture craft of wet-mixing commodity sand-cement slurry is: cement, sand, brucite fiber, dispersion admixture and water are stirred in forced mixer to get final product.
Brucite fiber be a kind of be the natural mineral fiber of main component with the magnesium hydroxide, be the advantage Mineral resources of China.Brucite fiber has excellent mechanical property and water-dispersion performance, compare with the existing various fortifying fibres that are used for sand-cement slurry, brucite fiber have with low cost and with obvious advantages such as the cement bonding force is strong.
6 grades and following grade brucite fiber are low-grade brucite staple fibres, and they mostly are the tankage of mine ore dressing processing, and staple length is generally less than 5mm.Compare with the brucite macrofiber, 6 grades and following grade brucite fiber are cheap.Because fiber is too short, at present mainly as industrial filler, and can not use as strongthener.
The present invention carries out chemistry by the chemical dispersion admixture to the natural brucite staple fibre and splits branch, can make the Fibre diameter refinement reach nano level, has improved the length-to-diameter ratio of staple fibre, thereby can bring into play the enhancement of fiber effectively, has increased the using value of fiber.Compare with macrofiber, the brucite staple fibre mixes in sand-cement slurry easily, and does not have mat-ups, the group of beating that other fiber occurs in application, disperse phenomenons such as irregular.Fiber has bigger specific surface area after splitting branch, and its water-absorbent is increased, and can influence the workability of sand-cement slurry.The present invention combines the chemical dispersion technology of fiber with the diminishing technology of cement, by selecting suitable fiber dispersion admixture and cement water reducing agent, solved rightly that the fiber of fiber applications in sand-cement slurry splits that branch disperses and the workability of sand-cement slurry between contradiction.
Because the application of chemical dispersion admixture helps promoting the homodisperse of fiber in sand-cement slurry, makes fiber consumption just can bring into play enhancement under situation seldom, helps the cost of controlling fiber sand-cement slurry.
Because the adding of chemical dispersion admixture and brucite staple fibre, increased the endergonic ability of mortar, the folding strength and the toughness of sand-cement slurry have been improved, improved the resistance to cleavage of sand-cement slurry, also make sand-cement slurry have water-retentivity and cohesiveness preferably simultaneously, needn't add water-keeping thickening material again, thereby reduce the production cost of mortar.
Brucite fiber reinforced finished cement mortar can be applied to a plurality of engineerings field, as building, tunnel, airport, road surface, bridge floor etc. build by laying bricks or stones, plaster and ground surface works in.
Embodiment
The present invention is made up of cement, sand, water, brucite fiber and dispersion admixture, wherein brucite fiber is the staple fibre of 6 grades and following grade, quality consumption in mortar is the 3-6% of cement amount, disperseing admixture quality consumption in the commodity sand-cement slurry is the 1.0-1.8% of cement amount, the quality consumption of sand is 1.0-7.0 a times of cement amount, and the quality consumption of the water yield is 0.35-1.6 a times of cement amount.
It is the mixture of four kinds of composition chemical agents that the used fibre chemistry of the present invention is disperseed admixture, and consumption is the 1.0-1.8% of cement amount in the commodity sand-cement slurry.Disperseing first kind of composition of admixture is naphthalene series high-efficiency water-reducing agent, is aniorfic surfactant, and consumption is the 0.7-1.2% of cement amount; Second kind of composition is sulfamate water reducer or sulfonated lignin water reducer, and consumption is the 0.15-0.30% of cement amount; The third composition is that concentration is the industrial spirit more than 95%, and consumption is the 0-0.25% of cement amount; The 4th kind of composition is urea, and consumption is the 0-0.25% of cement amount.
Embodiment one
It is cement by weight: natural river sand: brucite fiber: water: dispersion admixture=1: 3: 0.03: 0.65: 0.01 preparation dry mixing cement mortar.Wherein brucite fiber adopts 7 grades of fibers, disperses admixture to adopt composite admixture, and by naphthalene series high-efficiency water-reducing agent: calcium lignin sulfonate water depressor: the weight ratio mixed preparing of industrial spirit=70: 15: 15 forms.The preparation technology of mortar adds cement, sand and brucite fiber to stir 2-3 minute packing in the forced concrete mixer in proportion, obtains the dry mixing cement mortar.Add entry during construction and disperse admixture to stir and obtain the mortar of constructing.The denseness of mortar, delamination degree test (JGJ70-90) are carried out with reference to " building mortar basic performance tests method ", the resistance to compression of mortar, folding strength test (GB/T17671-1999) are carried out with reference to " cement mortar strength test method ", and mortar bonding tensile strength is measured and carried out with reference to DL/T5150-2001 " concrete for hydraulic structure testing regulation ".The The performance test results of preparation mortar sees Table 1.Listed the The performance test results of the mortar contrast sample that under same process, prepares when cement, sand, water do not have fiber and disperses admixture with proportioning in the table.Contrast as can be known, fiber-reinforced mortar has water-retentivity and cohesiveness preferably, and intensity and shrinkage obviously improve.
Table 1 mortar performance table with test results
Preface Denseness, mm Delamination degree, mm 28d ultimate compression strength, MPa The 28d folding strength, MPa Cohesive strength, MPa Outward appearance
1 81 17 35.3 6.54 3.83 Do not have to split not have and contract
The contrast sample 78 21 28.1 6.02 3.68 Shrink
Embodiment two
It is cement by weight: natural river sand: brucite fiber: water: dispersion admixture=1: 4: 0.03: 0.78: 0.012 preparation wet-mixing sand-cement slurry.Wherein brucite fiber adopts 6 grades of fibers, disperses admixture to adopt composite admixture, and by naphthalene series high-efficiency water-reducing agent: sulfamate water reducer: the weight ratio mixed preparing of urea=80: 20: 20 forms.The preparation technology of mortar adds cement, sand, brucite fiber, water and dispersion admixture to stir 2-3 minute packing in the forced concrete mixer in proportion, obtains the wet-mixing sand-cement slurry.The denseness of mortar, delamination degree, resistance to compression, folding strength and adhesive tensile resistance strength detection method are with embodiment one.Do not occur mat-ups, the group of beating in the preparation, disperse phenomenons such as irregular.The physicals test result of mortar sees Table 2.Contrast sample in the table is a cement: sand: water: naphthalene series high-efficiency water-reducing agent=1: 4: 0.78: 0.08 mortar for preparing under identical blending process.Compare with no fibre mortar sample, the intensity height of fiber-reinforced mortar, no bleeding, nothing are split not have and are contracted.
Table 2 mortar performance table with test results
Preface Denseness, mm Delamination degree, mm 28d ultimate compression strength, MPa The 28d folding strength, MPa Cohesive strength, MPa Outward appearance
2 82 19 18.7 4.81 2.89 Do not have to split not have and contract
The contrast sample 68 (bleedings) 28 14.7 4.17 2.52 Crackle is arranged
Embodiment three
Be cement by weight: natural river sand: brucite fiber: water: dispersion admixture=1: 5: 0.04: 1.07: 0.0145 preparation dry mixing cement mortars.Wherein brucite fiber adopts 7 grades of fibers, disperses admixture to adopt composite admixture, and by naphthalene series high-efficiency water-reducing agent: sodium lignin sulfonate water reducer: industrial spirit: urea=90: 20: 25: 10 weight ratio mixed preparing forms.The preparation technology of mortar adds cement, sand and brucite fiber to stir 2-3 minute packing in the forced concrete mixer in proportion, obtains the dry mixing cement mortar.Add entry during construction and disperse admixture to stir and obtain the mortar of constructing.The denseness of mortar, delamination degree, resistance to compression, folding strength and adhesive tensile resistance strength detection method are with embodiment one.The The performance test results of preparation mortar sees Table 3.Contrast sample in the table is a cement: sand: the mortar of water=under identical blending process prepare at 1: 5: 1.07.Compare with no fiber and dispersion admixture mortar-like, the intensity height of fiber-reinforced mortar does not have to split not have and contracts.
Table 3 mortar performance table with test results
Preface Denseness, mm Delamination degree, mm 28d ultimate compression strength, MPa The 28d folding strength, MPa Cohesive strength, MPa Outward appearance
3 77 19 13.1 3.26 2.31 Do not have to split not have and contract
The contrast sample 76 23 9.9 3.03 2.29 Shrink
Embodiment four
It is cement by weight: natural river sand: brucite fiber: water: dispersion admixture=1: 3: 0.06: 0.7: 0.012 preparation dry mixing cement mortar.Wherein brucite fiber adopts 7 grades of fibers, disperses admixture to adopt composite admixture, and by naphthalene series high-efficiency water-reducing agent: sulfamate water reducer: industrial spirit: urea=120: 30: 15: 15 weight ratio mixed preparing forms.The preparation technology of mortar adds cement, sand and brucite fiber to stir 2-3 minute packing in the forced concrete mixer in proportion, obtains the dry mixing cement mortar.Add entry during construction and disperse admixture to stir and obtain the mortar of constructing.The denseness of mortar, delamination degree, resistance to compression, folding strength and adhesive tensile resistance strength detection method are with embodiment one.The denseness of preparation mortar is 79mm, delamination degree 18mm, and cohesive strength 3.56Mpa does not have after solidifying to split not have and contracts 28d ultimate compression strength 33.3Mpa, 28d folding strength 6.38Mpa.
Embodiment five
It is cement by weight: natural river sand: brucite fiber: water: dispersion admixture=1: 3: 0.04: 0.71: 0.016 preparation wet-mixing sand-cement slurry.Wherein brucite fiber adopts 6 grades of fibers, disperses admixture to adopt composite admixture, and by naphthalene series high-efficiency water-reducing agent: sulfamate water reducer: industrial spirit: urea=100: 25: 10: 25 weight ratio mixed preparing forms.The preparation technology of mortar adds cement, sand, brucite fiber, water and dispersion admixture to stir 2-3 minute packing in the forced concrete mixer in proportion, obtains the wet-mixing sand-cement slurry.The denseness of mortar, delamination degree, resistance to compression, folding strength and adhesive tensile resistance strength detection method are with embodiment one.The preparation mortar has water-retentivity and cohesiveness preferably, mat-ups, the group of beating do not occur, disperses phenomenons such as irregular.The denseness 80mm of mortar, delamination degree 16mm, cohesive strength 3.77Mpa does not have after solidifying to split not have and contracts 28d ultimate compression strength 32.4Mpa, 28d folding strength 6.43Mpa.

Claims (2)

1. brucite staple fibre enhanced commodity cement mortar material, form by cement, sand, water, brucite fiber and dispersion admixture, wherein brucite fiber is the staple fibre of 6 grades and following grade, quality consumption in mortar is the 3-6% of cement amount, disperseing admixture quality consumption in the commodity sand-cement slurry is the 1.0-1.8% of cement amount, the quality consumption of sand is 1.0-7.0 a times of cement amount, and the quality consumption of the water yield is 0.35-1.6 a times of cement amount.
2, a kind of brucite fiber enhanced commodity cement mortar material, it is characterized in that, disperse admixture to be made up of naphthalene series high-efficiency water-reducing agent, sulfamate water reducer or sulfonated lignin water reducer, alcohol and urea, the quality consumption is respectively 0.7-1.2%, 0.15-0.30%, 0-0.25%, the 0-0.25% of cement amount.
CNA2008102322428A 2008-11-12 2008-11-12 Brucite fiber reinforced finished cement mortar material Pending CN101407394A (en)

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101844904A (en) * 2010-06-10 2010-09-29 西北大学 Brucite fiber reinforced fly ash composite material
CN103343218A (en) * 2013-07-08 2013-10-09 济钢集团有限公司 Method for improving strength and size composition of sinter
CN103755254A (en) * 2013-12-27 2014-04-30 安徽省美域节能环保技术应用有限公司 Wear-resisting compression resistance composite cement mortar and preparation method thereof
CN103803871A (en) * 2013-12-20 2014-05-21 安徽省美域节能环保技术应用有限公司 High-strength composite cement mortar and preparation method thereof
CN103803872A (en) * 2013-12-20 2014-05-21 安徽省美域节能环保技术应用有限公司 Radiation-proof reinforcing composite cement mortar
CN104529210A (en) * 2014-12-08 2015-04-22 江苏奥米建材科技有限公司 Hydrophilic slump loss resistant mineral composite fiber granule and preparation method thereof
CN105753429A (en) * 2016-01-28 2016-07-13 绵阳靓固科技有限公司 Binder
CN109231926A (en) * 2018-11-19 2019-01-18 遵义景程环保材料有限公司 A kind of carbon chrome magnesite fiber reinforced fly ash composite material
CN115124284A (en) * 2021-03-25 2022-09-30 振中建设集团有限公司 Novel heat-preservation masonry mortar

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101844904A (en) * 2010-06-10 2010-09-29 西北大学 Brucite fiber reinforced fly ash composite material
CN101844904B (en) * 2010-06-10 2012-12-05 西北大学 Brucite fiber reinforced fly ash composite material
CN103343218A (en) * 2013-07-08 2013-10-09 济钢集团有限公司 Method for improving strength and size composition of sinter
CN103803871A (en) * 2013-12-20 2014-05-21 安徽省美域节能环保技术应用有限公司 High-strength composite cement mortar and preparation method thereof
CN103803872A (en) * 2013-12-20 2014-05-21 安徽省美域节能环保技术应用有限公司 Radiation-proof reinforcing composite cement mortar
CN103755254A (en) * 2013-12-27 2014-04-30 安徽省美域节能环保技术应用有限公司 Wear-resisting compression resistance composite cement mortar and preparation method thereof
CN104529210A (en) * 2014-12-08 2015-04-22 江苏奥米建材科技有限公司 Hydrophilic slump loss resistant mineral composite fiber granule and preparation method thereof
CN105753429A (en) * 2016-01-28 2016-07-13 绵阳靓固科技有限公司 Binder
CN109231926A (en) * 2018-11-19 2019-01-18 遵义景程环保材料有限公司 A kind of carbon chrome magnesite fiber reinforced fly ash composite material
CN115124284A (en) * 2021-03-25 2022-09-30 振中建设集团有限公司 Novel heat-preservation masonry mortar

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Open date: 20090415