CN101348633B - Wet transfer printing dye intaglio printing ink and preparation thereof - Google Patents
Wet transfer printing dye intaglio printing ink and preparation thereof Download PDFInfo
- Publication number
- CN101348633B CN101348633B CN 200810196039 CN200810196039A CN101348633B CN 101348633 B CN101348633 B CN 101348633B CN 200810196039 CN200810196039 CN 200810196039 CN 200810196039 A CN200810196039 A CN 200810196039A CN 101348633 B CN101348633 B CN 101348633B
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- Prior art keywords
- dye
- printing ink
- dyestuff
- transfer printing
- intaglio printing
- Prior art date
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Links
- 238000007639 printing Methods 0.000 title claims abstract description 46
- 238000010023 transfer printing Methods 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title description 4
- 239000000975 dye Substances 0.000 claims abstract description 96
- 239000002904 solvent Substances 0.000 claims abstract description 12
- 239000000463 material Substances 0.000 claims abstract description 10
- 238000001914 filtration Methods 0.000 claims abstract description 9
- 239000000980 acid dye Substances 0.000 claims abstract description 5
- 238000003756 stirring Methods 0.000 claims description 39
- 125000002091 cationic group Chemical group 0.000 claims description 30
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 15
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 claims description 10
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 8
- 238000000247 postprecipitation Methods 0.000 claims description 8
- 238000009288 screen filtration Methods 0.000 claims description 8
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical group OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- SZIFAVKTNFCBPC-UHFFFAOYSA-N 2-chloroethanol Chemical compound OCCCl SZIFAVKTNFCBPC-UHFFFAOYSA-N 0.000 claims description 5
- 229920000742 Cotton Polymers 0.000 claims description 5
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 claims description 5
- HOCVBLVNCCMUAT-UHFFFAOYSA-N acetic acid;chloroethene;ethene Chemical group C=C.ClC=C.CC(O)=O HOCVBLVNCCMUAT-UHFFFAOYSA-N 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- 229920001038 ethylene copolymer Polymers 0.000 claims description 5
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 5
- 229920006122 polyamide resin Polymers 0.000 claims description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 4
- -1 polypropylene Polymers 0.000 claims description 4
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 4
- 230000002378 acidificating effect Effects 0.000 claims description 3
- DHKHKXVYLBGOIT-UHFFFAOYSA-N 1,1-Diethoxyethane Chemical compound CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims description 2
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical class CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims description 2
- 239000004925 Acrylic resin Substances 0.000 claims description 2
- 229920000178 Acrylic resin Polymers 0.000 claims description 2
- 241000223678 Aureobasidium pullulans Species 0.000 claims description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 2
- 229920013649 Paracril Polymers 0.000 claims description 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical group OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 2
- 239000004743 Polypropylene Substances 0.000 claims description 2
- 239000011354 acetal resin Substances 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims description 2
- 150000004676 glycans Chemical class 0.000 claims description 2
- 239000000983 mordant dye Substances 0.000 claims description 2
- 230000007935 neutral effect Effects 0.000 claims description 2
- 229920006324 polyoxymethylene Polymers 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 229920001282 polysaccharide Polymers 0.000 claims description 2
- 239000005017 polysaccharide Substances 0.000 claims description 2
- 125000000714 pyrimidinyl group Chemical group 0.000 claims description 2
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 10
- 238000000034 method Methods 0.000 abstract description 10
- 239000000203 mixture Substances 0.000 abstract description 7
- 239000012528 membrane Substances 0.000 abstract description 4
- 239000004033 plastic Substances 0.000 abstract description 3
- 229920003023 plastic Polymers 0.000 abstract description 3
- 238000000576 coating method Methods 0.000 abstract description 2
- 238000007646 gravure printing Methods 0.000 abstract description 2
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 230000006866 deterioration Effects 0.000 abstract 1
- 239000000835 fiber Substances 0.000 description 12
- 229920001778 nylon Polymers 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 6
- 239000002002 slurry Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 102000004169 proteins and genes Human genes 0.000 description 5
- 108090000623 proteins and genes Proteins 0.000 description 5
- 229920002972 Acrylic fiber Polymers 0.000 description 4
- 239000004677 Nylon Substances 0.000 description 3
- 229920002799 BoPET Polymers 0.000 description 2
- 239000011127 biaxially oriented polypropylene Substances 0.000 description 2
- 229920006378 biaxially oriented polypropylene Polymers 0.000 description 2
- 239000002985 plastic film Substances 0.000 description 2
- 229920006255 plastic film Polymers 0.000 description 2
- 239000000985 reactive dye Substances 0.000 description 2
- 229920004933 Terylene® Polymers 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000006223 plastic coating Substances 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- SEEPANYCNGTZFQ-UHFFFAOYSA-N sulfadiazine Chemical compound C1=CC(N)=CC=C1S(=O)(=O)NC1=NC=CC=N1 SEEPANYCNGTZFQ-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses dye intaglio printing ink for transfer printing by the wet method, comprising the following compositions in weight percentage: 1 to 60 percent of dye, 1 to 20 percent of a bonding material and 20 to 98 percent of a solvent. The invention also discloses a method for preparing dye intaglio printing ink for transfer printing by the wet method . The method comprises three steps, namely dissolving of the dye, filtering of solution and preparing the printing ink. The dye intaglio printing ink for transfer printing by the wet method has the advantages that the manufacturing process of the printing ink is simplified greatly, the manufacturing time of the printing ink is shortened; the hydrolyzation of the dye and the deterioration of the remaining printing ink are avoided, and the printing ink can be used for a plurality of times; the printing ink has good printing adaptability to various common plastic membranes; the gravure printing ink has high quality, an active dye or an acid dye or a positive ion dye printed on the plastic membrane or the paper of a coating separating agent has excellent dissolving performance in the wet state, and the dye intaglio printing ink is suitable for transfer printing process by the wet method.
Description
Technical field
The present invention relates to a kind of is gravure ink of tinting material and preparation method thereof with reactive dyestuffs, matching stain, cationic dyestuff, this ink printing is in the PET film, the BOPP film, the PE film, behind the paper that nylon membrane and separant are handled, can shift under the wet method state on the corresponding fiber of this kind dyestuff.
Background technology
Transfer printing, the characteristics that distil when all using dispersed dye to pass through high temperature at present are used for hydrophobic fibers such as terylene.Because transfer printing is the technology that printing combines with printing in textiles, gained flower type is meticulous, can print photograph effect pattern, and non-common screen printing can obtain.In addition, the transfer printing less investment, technology controlling and process is simple, and three waste discharge is few, is environmental protection technology.So transfer printing is used for cellulosic fibre, protein fibre is the research focus always.Though the hot transfer printing of dispersed dye also can be used for the transfer printing of fibers such as nylon and acrylic fibers, gained stamp product coloured light withers secretly, and colour fastness is not good enough.
Summary of the invention
The objective of the invention is at the deficiencies in the prior art, a kind of gravure ink that can realize protein fibre, cellulosic fibre, nylon fiber, acrylic fiber transfer printing reactive dyestuffs, matching stain and cationic dyestuff smoothly is provided.
Another purpose of the present invention provides the preparation method of a kind of above-mentioned reactive dyestuffs, matching stain and cationic dyestuff gravure ink.
For achieving the above object, the technical solution adopted in the present invention is as follows:
A kind of wet transfer printing dye intaglio printing ink, it comprises the component of following weight percent: dyestuff 1～60%, connection material 1～20%, solvent 20～98%.
Wherein, described dyestuff is reactive dyestuffs, matching stain or cationic dyestuff.
Wherein, described reactive dyestuffs are the dyestuff that contains reactive group, as contain the dyestuff of cyanuro, pyrimidyl (claim not only diazine), ethene sulfuryl, composite reactive base (but also claiming multi-active base) or phosphonate group active group, this dyestuff under certain condition can with cellulosic fibre, protein fibre and nylon fiber generation covalent attachment.
Wherein, described matching stain is the dyestuff of general reference dsred protein fiber and nylon fiber on energy under acidity or the neutrallty condition, as strongly-acid dyestuff, weak acid dye, neutral dye, acidic complex dye or acid mordant dye.
Wherein, described cationic dyestuff be meant under the certain condition can on dye the dyestuff of acrylic fiber, as basic dyestuff, coventional type cationic dyestuff, X type cationic dyestuff, M type cationic dyestuff or disperse type cationic dye.
Wherein, described connection material is for being dissolved in the polymer substance that also can form thick liquid in the solvent, as polyvinyl acetal resin, soluble cotton, polyamide resin, chlorinated polypropylene, vinylchlorid-acetate ethylene copolymer, thermoprene, paracril, chloroprene rubber, urethane resin, Synolac, acrylic resin, various cellulosics, copolyvidone or Aureobasidium pullulans polysaccharide.
Wherein, described solvent is the intensive polar solvent of energy dissolving dye, as methyl alcohol, ethanol, tetrahydrofuran (THF), acetonitrile, methyl-2-pyrrolidone, dimethyl formamide, methyl-sulphoxide, chloroethanol, acetone, methylethylketone, cellosolve series or diacetone alcohol.
Reactive dyestuffs of the present invention, matching stain and cationic dyestuff gravure ink, be can on dye cellulosic fibre, protein fibre, nylon fiber, acrylic fiber reactive dyestuffs, matching stain and cationic dyestuff make gravure ink, by gravure printing machine with this ink printing in the PET film, the BOPP film, the PE film, on nylon membrane and the paper, by wet transfer printing, design pattern is shifted on the lining of undertaking the printing of again through the separant processing.
Prepare the method for above-mentioned wet transfer printing dye intaglio printing ink, it comprises the steps:
1, the dissolving of dyestuff: solvent is placed agitator, when stirring at low speed, dyestuff is slowly added, stir and dissolve fully, staticly settle until dyestuff;
2, solution filters: go in bucket stand-by with screen filtration the solution of post precipitation;
3, configuration printing ink: the dye solution that above-mentioned filtration is good places agitator, when stirring at low speed, add and connect material, after the material dissolving fully to be connected, continue to stir 30～45 minutes (this moment, stirring velocity can be brought up to 1000～1500 rev/mins), add solvent, regulate viscosity to 10～60s (No. 3 examine grace viscosity cup).
Beneficial effect: wet transfer printing dye intaglio printing ink of the present invention has following advantage:
1, simplify printing ink to manufacture technology greatly, shorten the printing ink to manufacture time, it is now with the current that printing ink can be accomplished, reduces the stock.
2, owing to adopt organic solution to make solvent, stopped the hydrolysis of dyestuff and going bad of residual ink, help the repeatedly use of printing ink.
3, owing to adopt organic solution to make solvent, make that printing ink and various common plastics film printing adaptability are good.
4, the present invention is not only high-quality gravure ink, and the reactive dyestuffs or matching stain or the cationic dyestuff that are printed on the paper of plastic film or coating separant have splendid solubility property when hygrometric state, is adapted to wet transfer printing technology.
5, owing to can replace paper by enough plastic films, can realize not having the paper transfer printing, conserve forests, avoided traditional transfer printing to use a large amount of paper, reduce lumber consumption, avoided a large amount of simultaneously because the waste water that papermaking produces.
Embodiment:
Embodiment 1:
The composition of reactive dye intaglio printing ink and weight percent are: reactive dyestuffs (containing cyanuro) 10%, vinylchlorid-acetate ethylene copolymer 10%, methylethylketone 80%.
Production method is as follows:
The dissolving of dyestuff: methylethylketone is placed agitator, when stirring at low speed, reactive dyestuffs are slowly added, stir and dissolve fully, turn off stirrer, staticly settle until dyestuff.
Solution filters: go in bucket stand-by with screen filtration the reactive dyestuffs solution of post precipitation.
Configuration printing ink: the reactive dyestuffs solution that above-mentioned filtration is good places agitator, when stirring at low speed, add vinylchlorid-acetate ethylene copolymer, after treating vinylchlorid-acetate ethylene copolymer dissolving fully, continue to stir, stirring velocity can be brought up to 1000 rev/mins, and 30 minutes, the test color slurry viscosity, add methylethylketone, regulate viscosity to 10～60s (No. 3 examine grace viscosity cup).
Embodiment 2:
The composition of reactive dye intaglio printing ink and weight percent are: reactive dyestuffs (containing the ethene sulfuryl) 1%, chloroprene rubber 1%, chloroethanol 98%.
Production method is as follows:
The dissolving of dyestuff: chloroethanol is placed agitator, when stirring at low speed, reactive dyestuffs are slowly added, stir and dissolve fully, turn off stirrer, staticly settle until dyestuff.
Solution filters: go in bucket stand-by with screen filtration the reactive dyestuffs solution of post precipitation.
Configuration printing ink: the reactive dyestuffs solution that above-mentioned filtration is good places agitator, when stirring at low speed, add chloroprene rubber, after treating chloroprene rubber dissolving fully, continue to stir, stirring velocity can be brought up to 1000 rev/mins, and 30 minutes, the test color slurry viscosity, add chloroethanol, regulate viscosity to 10～60s (No. 3 examine grace viscosity cup).
Embodiment 3:
The composition of acid dye intaglio printing ink and weight percent are: strongly-acid dyestuff 20%, polyamide resin 15%, diacetone alcohol 65%.
Production method is as follows:
The dissolving of dyestuff: diacetone alcohol is placed agitator, when stirring at low speed, matching stain is slowly added, stir and dissolve fully, turn off stirrer, staticly settle until dyestuff.
Solution filters: go in bucket stand-by with screen filtration the matching stain solution of post precipitation.
Configuration printing ink: the matching stain solution that above-mentioned filtration is good places agitator, when stirring at low speed, add polyamide resin, after treating polyamide resin dissolving fully, continue to stir, stirring velocity can be brought up to 1300 rev/mins, and 40 minutes, the test color slurry viscosity, add diacetone alcohol, regulate viscosity to 10～60s (No. 3 examine grace viscosity cup).
Embodiment 4:
The composition of acid dye intaglio printing ink and weight percent are: acidic complex dye 40%, Synolac 20%, methyl-sulphoxide 40%.
Production method is as follows:
The dissolving of dyestuff: methyl-sulphoxide is placed agitator, when stirring at low speed, matching stain is slowly added, stir and dissolve fully, turn off stirrer, staticly settle until dyestuff.
Solution filters: go in bucket stand-by with screen filtration the matching stain solution of post precipitation.
Configuration printing ink: the matching stain solution that above-mentioned filtration is good places agitator, when stirring at low speed, add Synolac, after treating Synolac dissolving fully, continue to stir, stirring velocity can be brought up to 1300 rev/mins, and 40 minutes, the test color slurry viscosity, add methyl-sulphoxide, regulate viscosity to 10～60s (No. 3 examine grace viscosity cup).
Embodiment 5:
The composition of cationic dyestuff gravure ink and weight ratio are: X type cationic dyestuff 30%, soluble cotton 20%, ethanol 50%.
Production method is as follows:
The dissolving of dyestuff: ethanol is placed agitator, when stirring at low speed, cationic dyestuff is slowly added, stir and dissolve fully, turn off stirrer, staticly settle until cationic dyestuff.
Solution filters: go in bucket stand-by with screen filtration the cationic dyestuff solution of post precipitation.
Configuration printing ink: the cationic dyestuff solution that above-mentioned filtration is good places agitator, when stirring at low speed, add soluble cotton, after treating soluble cotton dissolving fully, continue to stir, stirring velocity can be brought up to 1500 rev/mins, and 45 minutes, the test color slurry viscosity, add ethanol, regulate viscosity to 10～60s (No. 3 examine grace viscosity cup).
Embodiment 6:
The composition of cationic dyestuff gravure ink and weight ratio are: disperse type cationic dye 30%, thermoprene 15%, dimethyl formamide 55%.
Production method is as follows:
The dissolving of dyestuff: dimethyl formamide is placed agitator, when stirring at low speed, cationic dyestuff is slowly added, stir and dissolve fully, turn off stirrer, staticly settle until cationic dyestuff.
Solution filters: go in bucket stand-by with screen filtration the cationic dyestuff solution of post precipitation.
Configuration printing ink: the cationic dyestuff solution that above-mentioned filtration is good places agitator, when stirring at low speed, add thermoprene, after treating thermoprene dissolving fully, continue to stir, stirring velocity can be brought up to 1500 rev/mins, and 45 minutes, the test color slurry viscosity, add dimethyl formamide, regulate viscosity to 10～60s (No. 3 examine grace viscosity cup).
Claims (6)
1. a wet transfer printing dye intaglio printing ink is characterized in that it comprises the component of following weight percent: dyestuff 1～60%, connection material 1～20%, solvent 20～98%;
Wherein,
Described dyestuff is reactive dyestuffs, matching stain or cationic dyestuff;
Described solvent is methyl alcohol, ethanol, tetrahydrofuran (THF), acetonitrile, methyl-2-pyrrolidone, dimethyl formamide, methyl-sulphoxide, chloroethanol, acetone, methylethylketone, cellosolve series or diacetone alcohol;
Described wet transfer printing dye intaglio printing ink prepares as follows and gets:
(1) dissolving of dyestuff: solvent is placed agitator, when stirring at low speed, dyestuff is slowly added, stir and dissolve fully, staticly settle until dyestuff;
(2) solution filters: go in bucket stand-by with screen filtration the solution of post precipitation;
(3) configuration printing ink: the dye solution that above-mentioned filtration is good places agitator, adds when stirring at low speed and connects material, after the material dissolving fully to be connected, continues to stir 30～45 minutes, adds solvent, regulates viscosity to 10～60s.
2. wet transfer printing dye intaglio printing ink according to claim 1 is characterized in that described reactive dyestuffs are the dyestuff that contains reactive group.
3. wet transfer printing dye intaglio printing ink according to claim 2 is characterized in that described reactive dyestuffs are the dyestuff that contains cyanuro, pyrimidyl, ethene sulfuryl, composite reactive base or phosphonate group active group.
4. wet transfer printing dye intaglio printing ink according to claim 1 is characterized in that described matching stain is strongly-acid dyestuff, weak acid dye, neutral dye, acidic complex dye or acid mordant dye.
5. wet transfer printing dye intaglio printing ink according to claim 1 is characterized in that described cationic dyestuff is basic dyestuff, coventional type cationic dyestuff, X type cationic dyestuff, M type cationic dyestuff or disperse type cationic dye.
6. wet transfer printing dye intaglio printing ink according to claim 1 is characterized in that described connection material is polyvinyl acetal resin, soluble cotton, polyamide resin, chlorinated polypropylene, vinylchlorid-acetate ethylene copolymer, thermoprene, paracril, chloroprene rubber, urethane resin, Synolac, acrylic resin, various cellulosics, copolyvidone or Aureobasidium pullulans polysaccharide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200810196039 CN101348633B (en) | 2008-09-11 | 2008-09-11 | Wet transfer printing dye intaglio printing ink and preparation thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200810196039 CN101348633B (en) | 2008-09-11 | 2008-09-11 | Wet transfer printing dye intaglio printing ink and preparation thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101348633A CN101348633A (en) | 2009-01-21 |
| CN101348633B true CN101348633B (en) | 2010-09-15 |
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| CN 200810196039 Expired - Fee Related CN101348633B (en) | 2008-09-11 | 2008-09-11 | Wet transfer printing dye intaglio printing ink and preparation thereof |
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Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101717596B (en) * | 2009-12-08 | 2012-05-23 | 湖州杭华油墨科技有限公司 | Water-based ink for package printing of high-adhesion film and manufacturing method thereof |
| CN101837692B (en) * | 2010-03-23 | 2014-11-12 | 常州涵源新印花有限公司 | New micro fiber leather or leather or cork wet transfer printing method and wet transfer printing film thereof |
| CN102161850B (en) * | 2011-05-24 | 2013-12-04 | 常州涵源新印花有限公司 | Fabric pattern transfer ink and preparation method thereof |
| CN102604482A (en) * | 2012-03-09 | 2012-07-25 | 冯建忠 | Fabric pattern transfer ink and preparing method thereof |
| CN102936860A (en) * | 2012-11-16 | 2013-02-20 | 刘静 | Fabric pattern transfer method |
| CN102935768B (en) * | 2012-11-21 | 2015-07-08 | 袁建穗 | Chinese ink painting intaglio printing method |
| CN104497702A (en) * | 2015-01-16 | 2015-04-08 | 英科·卡乐油墨(苏州)有限公司 | Printing ink combination for plastic label paper, and printing ink and varnish using printing ink combination |
| CN105086588A (en) * | 2015-10-08 | 2015-11-25 | 苏州市永津彩印包装有限公司 | Light-fast high-performance printing ink |
| CN106012594B (en) * | 2016-06-24 | 2019-03-15 | 常州旭荣针织印染有限公司 | Milk protein fiber/cotton fiber union wet method transfer printing method |
| CN107011557A (en) * | 2017-05-05 | 2017-08-04 | 常州卓源橡胶制品有限公司 | A kind of preparation method of rubber pange calico paper |
| CN107190538B (en) * | 2017-06-02 | 2019-09-10 | 马鞍山市永运家纺有限公司 | A kind of wet transfer printing technique of polyester cotton |
| CN107556817A (en) * | 2017-09-25 | 2018-01-09 | 东莞印美涂料有限公司 | A kind of gravure printing ink and its production technology |
| WO2019074519A1 (en) | 2017-10-13 | 2019-04-18 | Hp Indigo B.V. | Liquid electrophotography printing on fabrics |
| CN108842484A (en) * | 2018-06-28 | 2018-11-20 | 绍兴市海印数码科技有限公司 | A kind of ink-jet printed reactive dye ink applied to hemp blended fabric |
| CN113072838B (en) * | 2021-04-06 | 2022-09-06 | 绍兴柯桥佑彩纺织股份有限公司 | Dye gravure ink for ecological transfer printing and ecological transfer printing process |
| CN116729012A (en) * | 2023-06-12 | 2023-09-12 | 河南东方印新材料科技有限公司 | Machine tattooing transfer film and production process and use method thereof |
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2008
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| CN101348633A (en) | 2009-01-21 |
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