CN101343108A - Method for coupling treatment of sewage water of waterpower cavitation and ozone - Google Patents

Method for coupling treatment of sewage water of waterpower cavitation and ozone Download PDF

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Publication number
CN101343108A
CN101343108A CNA200810139592XA CN200810139592A CN101343108A CN 101343108 A CN101343108 A CN 101343108A CN A200810139592X A CNA200810139592X A CN A200810139592XA CN 200810139592 A CN200810139592 A CN 200810139592A CN 101343108 A CN101343108 A CN 101343108A
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China
Prior art keywords
cavitation
sewage
ozone
producer
coupling
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CNA200810139592XA
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Chinese (zh)
Inventor
李清方
张建
于殿强
张宁宁
张新军
赵海培
刘海丽
宋辉
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Sinopec Petroleum Engineering Corp
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Shengli Engineering Construction Group Co Ltd
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Priority to CNA200810139592XA priority Critical patent/CN101343108A/en
Publication of CN101343108A publication Critical patent/CN101343108A/en
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Abstract

Disclosed is a method for treating sewage by hydrodynamic cavitation and ozone coupling, which is characterized in that: the sewage treatment technique is composed of a centrifugal pump, an ozone generator and a cavitation generator and is realized by utilizing the cavitation effect produced by hydrodynamic cavitation and strong oxidation and coupling functions of ozone, the ozone produced by the ozone generator is doped into the sewage to enter the cavitation generator together and produce the cavitation effect in the cavitation generator, the contact area of ozone and sewage is increased through the micro-jet produced in a cavitation region, so as to extend the action time of ozone in sewage and change the amount of gas nucleus and distribution of gas nucleus in sewage, degrade oxygen consuming matters in the sewage, improve the coupling effect of cavitation and ozone, and achieve the purpose of reducing sewage COD, and the treated sewage can surely reach the required COD indexes by adjusting the treatment grade as required. Compared with the prior art, the technique has the advantages of simple process flow, convenient operation, high energy utilization ratio, strong adaptability, high efficiency, large treatment capacity, non secondary pollution and low cost.

Description

The method of Hydrodynamic cavitation and ozone coupling treatment of sewage water
One, technical field
The present invention relates to the method for a kind of Hydrodynamic cavitation and ozone coupling treatment of sewage water.This method utilizes sewage through cavitation producer cavitation effect that produces and the streams of ozone coupling synergy of mixing, and makes the aerobic substance degraded in the sewage, to reach the purpose that reduces COD of sewage.
Two, background technology
Oil field extracted water is formed more complicated: it is not only polluted by crude oil, and it has also dissolved various salts and the gas in the stratum at high temperature, highly compressed oil reservoir; In oil recovery process, in oil reservoir, many suspended solidss have been carried; In oil recovery, oil-gas gathering and transportation, dehydrating of crude oil process, all kinds of chemical agents have also been added; Also have large amount of organic in the recovered water, the environment of suitable microorganism growth breeding is arranged.Therefore recovered water is the trade effluent that contains plurality of impurities.
Oxygen consumption pollutent in each that contains in the recovered water, the dissolved oxygen in the meeting consume water causes water oxygen content to reduce, water quality deterioration, hydrobiont is difficult to existence, is the important factor that influences water quality at present.Chemical oxygen demand (COD) is called for short COD, is an overall target of oxygen consumption pollution substance content in the expression water.COD content is too high, and the water quality corruption is seriously polluted.Therefore, sewage disposal requires the COD value not to be above standard.
The method that reduces COD has a lot, and commonly used is physics method, chemical method and biological process, and biological process is low than physics or chemical process cost, less investment, efficient height, non-secondary pollution, but the oil field waste biodegradability is relatively poor, and contains the organism of difficult degradation, has restricted the application of biochemical processing.
Three, summary of the invention
The method that the purpose of this invention is to provide a kind of Hydrodynamic cavitation and ozone coupling treatment of sewage water, solve difficult problems such as cost height, secondary pollution, biodegradability that above-mentioned sewage disposal faces are poor, difficult degradation, remedy the shortcoming and defect that prior art exists, the technology of a kind of low cost, high efficiency reduction COD of sewage is provided.
Technical scheme of the present invention realizes in the following manner:
The present invention is by by impeller pump, the cavitation effect that utilizes the Hydrodynamic cavitation generation that cavitation producer and ozonizer are formed and the strong oxidation of ozone and coupling sewage treatment are realized, the ozone that ozonizer is produced mixes in the sewage, together enter the cavitation producer, cavitation effect takes place in the cavitation producer, the microjet that produces by cavitation zone increases the contact area of ozone with sewage, the gas nuclear amount and the gas nuclear that prolong the action time of ozone in sewage and change in the sewage distribute, aerobic substance in the degradation of sewage, improve cavitation and ozone coupling effect, make COD reach the technical indicator of regulation.
Sewage treatment process of the present invention be sewage come water by pipeline through the impeller pump supercharging, by under meter metering again with produce by ozonizer and together enter the cavitation producer cavitation process that is coupled through the ozone of metering.Establish a vertical tank behind the cavitation producer, on jar pressure regulator valve is set, be used for the buffering of liquid and the release of gas, when the jar internal pressure is higher than setting pressure, open automatically, close automatically during less than setting pressure.The import and export of vertical tank are located at the middle and lower part and the middle and upper part of jar respectively.
In order to reach the COD index request, available multiple-stage treatment, and progression is adjustable.What this example adopted is the second-stage treatment flow process.
Compared with the prior art the present invention has the following advantages:
(1) Hydrodynamic cavitation and ozone coupling treatment of sewage water device simply, easily form skid system, energy consumption relative little, easy to operate, maintenance cost is low, easily realize mass-producing;
(2) Hydrodynamic cavitation and ozone coupling treatment of sewage water system utilize the Hydrodynamic cavitation effect, and liquid flow rate is big, and the device processes amount is big; Under the same treatment ability, its volume is less relatively;
(3) Hydrodynamic cavitation and ozone coupling treatment of sewage water system do not need to add any chemical agent, non-secondary pollution;
(4) Hydrodynamic cavitation and ozone coupling treatment of sewage water system are strong to the adaptation of sewage, can good Degradation all be arranged biochemical material poor, difficult degradation to some;
(5) Hydrodynamic cavitation and ozone coupling treatment of sewage water system handles cost are low, do not need the oversize residence time, the processing efficiency height.
Four, description of drawings
Fig. 1-process flow sheet of the present invention (is example with the second-stage treatment).
1-impeller pump 2-tensimeter 3 under meter 4-cavitation producer 5-ozonizer 6-pressure regulator valve 7-sampling valve 8-vertical tanks among the figure
Fig. 2 M shape cavitation generator architecture synoptic diagram
Fig. 3 radiation cavitation generator architecture synoptic diagram
Five, embodiment
The present invention is by by impeller pump 1 as shown in Figure 1, the cavitation effect that utilizes the Hydrodynamic cavitation generation that cavitation producer 4 and ozonizer 5 are formed and the strong oxidation of ozone and coupling sewage treatment are realized, the ozone that ozonizer 5 is produced mixes in the sewage, together enter cavitation producer 4, cavitation effect takes place in the cavitation producer, the microjet that produces by cavitation zone increases the contact area of ozone with sewage, the gas nuclear amount and the gas nuclear that prolong the action time of ozone in sewage and change in the sewage distribute, aerobic substance in the degradation of sewage, improve cavitation and ozone coupling effect, make COD reach the technical indicator of regulation.
Sewage enters from inlet pipe, through impeller pump 1, obtains certain pressure and flow velocity, and the ozone gas by ozonizer 5 generations with feeding from the aeration mouth together flows into the cavitation producer, in the cavitation producer cavitation effect takes place.The microjet that cavitation zone produces has played churned mechanically effect, increased the contact area of ozone with liquid, feed ozone to the cavitation pipeline simultaneously, not only prolonged the action time of ozone in solution, measure gentle nuclear distribution but also changed the gas nuclear in the liquid, help the nascent of cavitation, active effect has been played in the development of cavitation.Therefore, under the coupling of Hydrodynamic cavitation and ozone, the oxidation that is degraded of the aerobic substance in the sewage has reached the purpose that reduces COD.Sewage enters vertical tank 8 after flowing out from cavitation producer 4, and by air content in pressure regulator valve 6 controlling tank, sewage has so far been finished the one-level processing from vertical tank 8 outlet outputs.Sewage can together enter the cavitation producer with the ozone gas that feeds from the aeration hole once more and carry out second-stage treatment after flowing out from vertical tank 8.By sampling valve 7 sampling analysis, judge whether COD of sewage satisfies index request, and adjust processing progression with this.Note the pressure of tensimeter 2, remain the pressure that mixes ozone and necessarily be higher than pump discharge pressure, otherwise ozone just can not mix smoothly, mix up the mixed ratio of ozone and sewage, guarantee processing quality sewage by under meter 3.

Claims (3)

1, the method of a kind of Hydrodynamic cavitation and ozone coupling treatment of sewage water, it is characterized in that by by impeller pump, the cavitation effect that utilizes the Hydrodynamic cavitation generation that ozonizer and cavitation producer are formed and the strong oxidation of ozone and coupling sewage treatment are realized, the ozone that ozonizer is produced mixes and together enters the cavitation producer in the sewage, cavitation effect takes place in the cavitation producer, the microjet that produces by cavitation zone increases the contact area of ozone with sewage, the gas nuclear amount and the gas nuclear that prolong the action time of ozone in sewage and change in the sewage distribute, aerobic substance in the degradation of sewage, improve cavitation and ozone coupling effect, make COD reach the technical indicator of regulation.
2, the method for Hydrodynamic cavitation according to claim 1 and ozone coupling treatment of sewage water, it is characterized in that the sewage disposal flow process is that sewage comes that water produces with ozonizer through the metering of impeller pump supercharging, under meter by pipeline and together enters the cavitation producer cavitation process that is coupled through the ozone of metering, and can adjust processing progression as required, the sewage after guaranteeing to handle reaches the technical indicator that COD requires.
3. the method for Hydrodynamic cavitation according to claim 1 and ozone coupling treatment of sewage water, it is characterized in that the cavitation producer adopts the form of many holes plate, behind the cavitation producer, establish a vertical tank, jar is provided with pressure regulator valve, be used for the release of gas, when the jar internal pressure is higher than setting pressure, open automatically, close automatically during less than setting pressure.
CNA200810139592XA 2008-08-22 2008-08-22 Method for coupling treatment of sewage water of waterpower cavitation and ozone Pending CN101343108A (en)

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102153185A (en) * 2011-02-25 2011-08-17 浙江工业大学 Wastewater treatment device based on hydrodynamic cavitation reaction
CN102351285A (en) * 2011-09-20 2012-02-15 环境保护部南京环境科学研究所 Device and method for killing tiny organisms in water body by using hydrodynamic cavitation and strengthened ozone
CN103689100A (en) * 2013-12-13 2014-04-02 广西科技大学 Method of passivating trypsin inhibitor in soybean milk by means of hydrodynamic cavitation technology
CN105967413A (en) * 2016-07-25 2016-09-28 杨阳 Polished-wastewater integrated treatment device
CN106348425A (en) * 2016-11-14 2017-01-25 东北大学 Gas-nucleus targeting catalytic oxidation reactor based on hydrodynamic cavitation effect
CN108017197A (en) * 2017-12-15 2018-05-11 广东省矿产应用研究所 Hydrodynamic cavitation coupling H2O2Process for recycling mineral processing wastewater of purified lead-zinc sulfide ore
CN108408976A (en) * 2018-04-09 2018-08-17 北京天地人环保科技有限公司 A kind of organic wastewater catalytic ozonation processing system and method
CN110078196A (en) * 2019-06-05 2019-08-02 中石化石油工程技术服务有限公司 The system of Hydrodynamic cavitation and ozone Combined Treatment sour water
CN110386634A (en) * 2019-08-27 2019-10-29 青岛思普润水处理股份有限公司 A kind of adjustable O of operating pressure3/H2O2/ UV advanced oxidation system and its operation process
CN113929243A (en) * 2020-06-29 2022-01-14 中国石油天然气集团有限公司 Processing equipment and processing method for hydraulic cavitation composite sterilization of fracturing flow-back fluid
CN114702217A (en) * 2022-06-02 2022-07-05 山东奥美环境股份有限公司 Gas coupling type hydrodynamic cavitation device

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102153185A (en) * 2011-02-25 2011-08-17 浙江工业大学 Wastewater treatment device based on hydrodynamic cavitation reaction
CN102153185B (en) * 2011-02-25 2012-08-22 浙江工业大学 Wastewater treatment device based on hydrodynamic cavitation reaction
CN102351285A (en) * 2011-09-20 2012-02-15 环境保护部南京环境科学研究所 Device and method for killing tiny organisms in water body by using hydrodynamic cavitation and strengthened ozone
CN103689100A (en) * 2013-12-13 2014-04-02 广西科技大学 Method of passivating trypsin inhibitor in soybean milk by means of hydrodynamic cavitation technology
CN103689100B (en) * 2013-12-13 2015-02-04 广西科技大学 Method of passivating trypsin inhibitor in soybean milk by means of hydrodynamic cavitation technology
CN105967413A (en) * 2016-07-25 2016-09-28 杨阳 Polished-wastewater integrated treatment device
CN106348425A (en) * 2016-11-14 2017-01-25 东北大学 Gas-nucleus targeting catalytic oxidation reactor based on hydrodynamic cavitation effect
CN108017197A (en) * 2017-12-15 2018-05-11 广东省矿产应用研究所 Hydrodynamic cavitation coupling H2O2Process for recycling mineral processing wastewater of purified lead-zinc sulfide ore
CN108408976A (en) * 2018-04-09 2018-08-17 北京天地人环保科技有限公司 A kind of organic wastewater catalytic ozonation processing system and method
CN110078196A (en) * 2019-06-05 2019-08-02 中石化石油工程技术服务有限公司 The system of Hydrodynamic cavitation and ozone Combined Treatment sour water
CN110078196B (en) * 2019-06-05 2024-04-12 中石化石油工程技术服务有限公司 System for treating sulfur-containing sewage by combining hydrodynamic cavitation and ozone
CN110386634A (en) * 2019-08-27 2019-10-29 青岛思普润水处理股份有限公司 A kind of adjustable O of operating pressure3/H2O2/ UV advanced oxidation system and its operation process
CN113929243A (en) * 2020-06-29 2022-01-14 中国石油天然气集团有限公司 Processing equipment and processing method for hydraulic cavitation composite sterilization of fracturing flow-back fluid
CN114702217A (en) * 2022-06-02 2022-07-05 山东奥美环境股份有限公司 Gas coupling type hydrodynamic cavitation device

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Open date: 20090114