CN101323719A - Construction curtain wall ceramic - Google Patents
Construction curtain wall ceramic Download PDFInfo
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- CN101323719A CN101323719A CNA2007100421053A CN200710042105A CN101323719A CN 101323719 A CN101323719 A CN 101323719A CN A2007100421053 A CNA2007100421053 A CN A2007100421053A CN 200710042105 A CN200710042105 A CN 200710042105A CN 101323719 A CN101323719 A CN 101323719A
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Abstract
The invention discloses a nanometer ceramic building curtain wall paint which comprises a nanometer oxide, a coloring pigment, an organosilicon curing agent and an auxiliary agent. The paint is characterized by super weather resistance, scratch resistance, fireproofness, non-inflammability and self-cleaning, etc. The products of the invention are applicable to the hull painting of an outdoor aluminum curtain wall, and an aluminum veneer and an aluminum honeycomb panel which are used for indoor decoration.
Description
Technical field
The invention belongs to technical field of coatings, relate in particular to coating composition based on inorganics.
Background technology
Along with rapid economy development, the building curtain wall decoration materials are constantly taking place to develop and innovation, and aluminium matter curtain wall is because preferred object in light weight, characteristics have become decorating outer wall of building such as appearance is magnificent.Be accompanied by the baking vanish development of technology, the update speed of aluminum screen wall is also very fast.Fluorocarbon coating has remedied the deficiency of first-generation product as s-generation aluminium decorative material, adds colorful diversity, and can keep the resisting power about 10 years, so applied rapidly.Yet, propelled at high velocity along with industrialization, the generation of all contaminations matter such as the waste gas of motor vehicle emission and dust, acid rain, rubber dust, fatal resisting power and the stain resistance that has influence on fluororine-carbon coating, thereby press for more outstanding new generation product and replace.The construction curtain wall ceramic of the present invention's exploitation, the organic coating that ultraviolet ray, auto exhaust thing, topsoil, acid rain will wear out, pollute is different with running into, the porcelain coating can be brought into play its distinctive coating performance, not only possess various color and beautiful appearance, also have remarkable stain resistance and resisting power, allow building remain brand-new image.Simultaneously,, in the large common facility construction, have special advantages, shown great attention to because it has fabulous fire prevention and does not fire characteristic.
Summary of the invention
1, goal of the invention
The present invention is intended to further improve the resisting power and the stain resistance of aluminum screen wall coating.Have shortcomings such as weather resistance is not good enough, fire resistance is relatively poor at prior art, the present invention utilizes that porcelain is gone through thousands of year constant resisting powers, fire prevention is not fired and characteristic such as automatically cleaning, prepares construction curtain wall ceramic of new generation.
2, technology contents
Wherein the weight part of each component of A component is:
Base-material 20-70
Water 4-30
Pigment 10-60
Organic solvent 14-30
Organic acid conditioning agent and nonionogenic tenside 2-6
The weight part of each component of B component is:
Silica solidifying agent 60-100
Organic solvent and silane coupling agent 0-40
A component: B component=3: 1-1: 1 (weight ratio)
(1) paint composite
Construction curtain wall ceramic of the present invention is made up of two components of A, B, and wherein the A component is made up of base-material, pigment, organic solvent, organic acid conditioning agent and nonionogenic tenside; The B component mainly is made up of organosilicone compounds, organic solvent and silane coupling agent.
The A component: its pH value is between 2-6, preferably between 3-5.5, more preferably between 3.5-4.3.
A, base-material
Base-material also claims filmogen, and its main effect is face (filling out) material to be waited be bonded to an integral body, and gives and filming with functions such as gloss, antiseptic properties.
The base-material of ceramic paint of the present invention is a nano level 10-100nm oxide compound.Nano-oxide is to adopt the preparation of sol-gel sol-gel method and get.Promptly make presoma with the compound that contains high chemically reactive component, under liquid phase with these raw material uniform mixing, and be hydrolyzed, the condensation chemical reaction, in solution, form stable vitreosol system, colloidal sol is through ageing, slowly polymerization between micelle, the gel of formation three-dimensional space network structure, gel is prepared the material of nanostructure behind super-dry, sintering curing.Mainly contain silicon oxide, aluminum oxide, zirconium white, yttrium oxide, strontium oxide etc.
B, pigment
The pigment that adopts in the prior art coating is mineral dye.Because the singularity of system, the matching of pigment and system is extremely important, is embodied in: the one, and pigment is highly stable in the strongly-acid medium, and the 2nd, the content of water-soluble salt is enough low in the pigment; The 3rd, pigment is as far as possible little to the pH value influence of system.Secondly as the pigment of paint for building curtain wall, for the super wear properties with system is complementary, the weathering resistance data of pigment also are the important evidence that prescription is selected for use.
Pigment is an important component part of construction curtain wall ceramic, and pigment makes to film and presents color, and making films has the ability of certain covering coated article spare.Pigment can also strengthen the mechanical property and the endurance quality of filming.Pigment is generally very thin pulverous coloring matter, it is evenly dispersed in forms colored paint in the coating, is evenly distributed in to film after film forming.In construction curtain wall ceramic, tinting pigment commonly used has that titanium dioxide, ferrochrome are black, iron oxide black, red iron oxide, iron oxide yellow, cobalt blue, titanium nickel yellow, strontium yellow, chrome yellow, iron oxide red, molybdenum red, cadmium red, barba hispanica, chrome green, carbon black, nacreous mica pigment etc.
Filler (pigment extender) commonly used has process white, china clay, silica powder etc.;
Effect pigment commonly used comprises aluminium powder, pearlescence, stained glass powder, colour stone powder.
C, auxiliary agent
The effect of auxiliary agent is that the performance (as the moisture dispersibility energy of pigment, the antifoam performance of coating etc.) to the construction curtain wall ceramic or a certain particular aspects of filming plays improved action.Certainly owing to the singularity of system, the stability of auxiliary agent and system needs careful assessment.Auxiliary agent commonly used has wetting aid, dispersing auxiliary, froth breaking auxiliary agent, auxiliary rheological agents etc.Also comprise organic acid regulator and nonionogenic tenside.Ionic surfactant pack is drawn together: the HLB value is the alkylphenol polyoxyethylene class of 8-10, preferred OP and TX series, as OP-4, OP-7, OP-9, OP-10, OP-13, OP-15, OP-20, OP-30, OP-40, OP-50, TX-4, TX-7, TX-5, TX-9, TX-10 (NP-10), TX-12, TX-13, TX-15, TX-18, TX-21, TX-30, TX-4, wherein specifically comprise: OP-10, OP-30, OP-40; The organic acid conditioning agent comprises: acrylic acid aqueous solution, glacial acetic acid aqueous solution, aqueous formic acid.
D, solvent
The effect of solvent is dissolving or is dispersed into membrane substance, and coating can be adjusted to suitable working viscosity and be beneficial to the carrying out of constructing.Employed solvent mainly is alcoholic solvent, ketones solvent and water among the present invention.
The B component:
Solidifying agent is formed by organo-siloxane and auxiliary agent.Organo-siloxane, the silane coupling agent that preferred front three (second) oxygen base replaces specifically comprises: C
1-C
4Alkyl front three/Ethoxysilane, phenyl front three/Ethoxysilane, tolyl front three/Ethoxysilane etc.Adjusting agent is solvent or silane coupling agent.In film process, hydrolysis at first takes place in solidifying agent, then with base-material generation copolyreaction and the condensation reaction of self.Copolymerization between nano-oxide and the silicoorganic compound and the polycondensation between the silicoorganic compound are the film forming ultimate principles of ceramic paint.
(2) production technique of ceramic paint
The production technique of the production of ceramic paint and common solvent based coating is similar substantially.Different is the stability that will fully pay close attention to system in process of production.Concrete production technique comprises following operation: the grinding of mill base; Join lacquer; The adjustment of color; The adjustment of viscosity, solids constituent and pH value; The examination and test of products and packing and product warehousing etc.
Ceramic paint production equipment commonly used mainly contains high speed dispersor, sand mill, paint filling or stainless steel scuffing of cylinder bore etc.Because system is the strongly-acid system, equipment and container material will consider to adopt stainless steel or the good plastic material of acid resistance, and note in time cleaning, in order to avoid get rusty.
(3) construction technology
A, join lacquer: in joining in the paint can of acid proof stainless steel or plastic material, be weighed into the A component (the A component need stir in advance) of metering, slightly through stirring, by fixing than being metered into the B component, keep stirring 20-30 minute (stirring velocity is controlled in the 800r/m), added a cover static slaking 2.5-3 hour, and before construction, will stir once more, and filter with the above copper mesh of 200 orders.
Also can adopt the method for rolling slaking, soon A, B component mix by proportioning, place sealed plastic container, continuous rolling slaking 4-5h on twin-roll machine.
The surface treatment of b, workpiece:
Workpiece carries out sandblasting (80-120 purpose emergy is better) after oil removing, remove rusty stain, the spot on surface, and sandblast is wanted evenly, and the workpiece of sandblast will spray paint in 8 hours.The workpiece of sandblasting will be at 50-55 ℃ environment preheating 5-10min before applying.
C, construction: adopt spraying application, pressure 0.4-0.6MPa; To regulate lessly with going out the lacquer amount during spraying, be convenient to control coating thickness and prevent that sagging, film thickness are controlled at 20-25 μ m like this, thin coating film opacifying property bad to base material too, coating film gloss is low; Too thick, film to the bonding force decline of base material, easily produce cracking.It is better second that viscosity during spraying (being coated with-4 glasss) is controlled at 13-17; Regulate viscosity and cleaning spray gun and use industrial alcohol or acetone; Interim no lacquer liquid will in time be added a cover, and prevents skinning and volatilization; The painting workshop well-ventilated, Ex-all dust, no open flames.
D, curing:
Construction curtain wall ceramic of the present invention can be cured under 120-200 ℃/15-60min condition, and the curing process of recommendation is: 180 ℃/20min.
The characteristics of porcelain paint for building curtain wall of the present invention are: the first, and porcelain is filmed and can be easy to be worn out by ultraviolet ray, acid rain, automobile exhaust gas and topsoil etc. as organic coating film, can bring into play better etch resistant properties, belongs to the semipermanent material; The second, porcelain is filmed can variable color below 300 ℃ or film impairedly, and fire prevention is not fired; The 3rd, porcelain is filmed can not adhere to pollution substance in the atmosphere, remains magnificent outward appearance, and metabolism plays active function to the far infrared rays that it discharged simultaneously to human body; The 4th, the porcelain color of filming is various, but regulated at will gloss can satisfy the different requirements of buildings to color and luminosity, provides more wide space to building designers.
Embodiment
Embodiment 1
Building curtain wall white ceramic paint A component
Building curtain wall white ceramic paint B component
Wherein KH560 is γ-glycidyl ether oxygen propyl trimethoxy silicane.The pH value of A component need be controlled between the 3.5-4.3.
A component manufacturing process:
1, in container, adds material 1, stir adding material 2, material 5 and material 6 down, stir.
2, add material 3, stir.
3, adopt sand mill to be ground to fineness≤25um.
4, under agitation slowly add material 4, mechanical stirring is even.
B component manufacturing process:
In container, add material 1, stir down slowly adding material 2, stir.
Application:
After aluminium section bar carried out skimming treatment, carry out sandblasting (down with) with 120 order emergies.Above-mentioned coating is pressed A: B=2: 1 (weight ratio) mixed, and sprays behind the rolling slaking 4h.Coating thickness is controlled at 20-30um.
Embodiment 2
The blue ceramic paint A of building curtain wall component
| Sequence number | Title | Specification | Quantity wt |
| 1 | Zirconium white | Nyacol | 40.0 |
| 2 | Pure water | Industry | 12.0 |
| 3 | The R-930 titanium dioxide | Japan's stone is former | 20.0 |
| 4 | The HD555 cobalt blue | Triumphant one hundred | 5.0 |
| 5 | Virahol | Industry | 20.0 |
| 6 | OP-10 | Industry | 1.0 |
| 7 | 20% vinylformic acid | Industry | 2.0 |
Building curtain wall blue ceramic coating B component
| Sequence number | Title | Specification | Quantity wt |
| 1 | Union carbide A-162 | Import | 60.0-90.0 |
| 2 | KH-560 | Import | 10.0-40.0 |
A component: B component=1.5: 1 (weight ratio)
Film performance is detected, and data are as follows:
| Test event | Blue building curtain wall ceramic coating |
| 60 ° of gloss | 32 |
| Pencil hardness | 5H |
| Sticking power, level | 0 |
| Impact cm | 50 |
| Solvent resistance, acetone 200 times repeatedly | No gloss appearance is unusual |
| Stain resistance, permanent pen are drawn the back and are removed with alcohol | Pollution-free |
| Acidproof, 5% sulfuric acid, drop 48h | No abnormal |
| Alkaline-resisting, 5% yellow soda ash, drop 48h | No abnormal |
| Chilling behind the 300 ℃/1h of thermotolerance | Do not have cracking and come off the color no change |
| Resistivity against fire | Do not fire, do not produce poison gas and smog |
Embodiment 3
The red ceramic paint A of building curtain wall component
| Sequence number | Title | Specification | Quantity wt |
| 1 | Silicon oxide | Nyacol | 50.0 |
| 2 | Pure water | Industry | 4.0 |
| 3 | Tico655 | Triumphant one hundred | 23.0 |
| 4 | Virahol | Industry | 20.0 |
| 5 | Nonionogenic tenside | Nanmu originally | 1.0 |
| 6 | Glacial acetic acid aqueous solution | Industry | 2.0 |
Tico655 in the table is the compound pigment of organic-inorganic.The nonionogenic tenside of selecting for use is a polyoxyethylene alkylphenol condenses class, and its HLB value is 8-10.
The red ceramic paint B of building curtain wall component
A component: B component=3: 1 (weight ratio)
Film performance is detected, and data are as follows:
| Test event | The red ceramic paint of building curtain wall |
| 60 ° of gloss | 54 |
| Pencil hardness | 6H |
| Sticking power, level | 0 |
| Impact cm | 50 |
| Solvent resistance, acetone 200 times repeatedly | No gloss appearance is unusual |
| Stain resistance, permanent pen are drawn the back and are removed with alcohol | Pollution-free |
| Acidproof, 5% sulfuric acid, drop 48h | No abnormal |
| Alkaline-resisting, 5% yellow soda ash, drop 48h | No abnormal |
| Resistivity against fire | Do not fire, do not produce poison gas and smog |
The above-mentioned description to embodiment is can understand and apply the invention for ease of those skilled in the art.The person skilled in the art obviously can easily make various modifications to these embodiment, and needn't pass through performing creative labour being applied in the General Principle of this explanation among other embodiment.Therefore, the invention is not restricted to the embodiment here, those skilled in the art should be within protection scope of the present invention for improvement and modification that the present invention makes according to announcement of the present invention.
Claims (10)
1, a kind of construction curtain wall ceramic is characterized in that, coating is made up of in 3: 1～1: 1 weight part ratio two components of A, B,
Wherein the weight part of each component of A component is:
Base-material 20-70
Water 4-30
Pigment 10-60
Organic solvent 14-30
Organic acid conditioning agent and nonionogenic tenside 2-6
The weight part of each component of B component is:
Silica solidifying agent 60-100
Organic solvent and silane coupling agent 0-40
The pH value of A component is between 2-6, and wherein base-material is a nano-oxide,
The silica solidifying agent comprises front three/Ethoxysilane substitutive derivative in the B component,
Silane coupling agent comprises γ-glycidyl ether oxygen propyl trimethoxy silicane, γ-methacryloxypropyl trimethoxy silane,
Organic solvent comprises alcohols, ethers, ketone.
2, coating as claimed in claim 1, the pH value that it is characterized in that described A component is preferably between 3-5.5, more preferably between 3.5-4.3.
3, coating as claimed in claim 1 is characterized in that the ionic surfactant pack of described A component is drawn together: the HLB value is the alkylphenol polyoxyethylene class of 8-10, and preferred OP and TX series of surfactants specifically comprise: OP-10, OP-30, OP-40.
4, coating as claimed in claim 1, the organic solvent that it is characterized in that described A and B component comprises the alkyl alcohol of C1-C6, specifically comprise methyl alcohol, ethanol, Virahol, glycol ether, Triethylene glycol, and butyl glycol ether, propylene glycol monomethyl ether, acetone, butanone.
5, coating as claimed in claim 1 is characterized in that described A component nano-oxide base-material comprises zinc oxide, titanium oxide, calcium oxide, weisspiessglanz, aluminum oxide, zirconium white, boron oxide, silicon oxide; The particle diameter of nano-oxide between 1-150nm, preferably between 10-100nm, the best 20-80nm that is chosen as.
6, coating as claimed in claim 1, it is characterized in that A component pigment is: neutral mineral dye specifically comprises: titanium white, iron oxide yellow, titanium nickel yellow, strontium yellow, chrome yellow, iron oxide red, molybdenum red, cadmium red, barba hispanica, chrome green, iron oxide black, carbon black, ferrochrome are black, cobalt blue, nacreous mica pigment.
7, coating as claimed in claim 1 is characterized in that the used organic acid conditioning agent of A component comprises: acrylic acid aqueous solution, glacial acetic acid aqueous solution, aqueous formic acid.
8, coating as claimed in claim 1 is characterized in that solidifying agent specifically comprises C in the B component
1-C
4Alkyl front three/Ethoxysilane, phenyl front three/Ethoxysilane, tolyl front three/Ethoxysilane.
9, preparation is as the method for coating as described in arbitrary among the claim 1-6, and its construction procedure is as follows:
A, join lacquer:
In joining in the paint can of acid proof stainless steel or plastic material, be weighed into the A component that the warp of metering stirs in advance, slightly through stirring, be metered into the B component by proportioning, place airtight container, on twin-roll machine with speed rolling slaking 4-5h less than 20r/m, before construction with the strainer filtering more than 200 orders;
The surface treatment of b, workpiece:
Workpiece carries out sandblasting after oil removing, remove rusty stain, the spot on surface; The processing of spraying paint in 8 hours, the workpiece of sandblasting will be at 50-55 ℃ environment preheating 5-10min before applying;
C, construction:
The pressure of spraying application is between 0.4-0.6MPa; Film thickness is controlled at 20-25 μ m, and viscosity is coated with-4 glasss and is controlled at 13-17s during spraying; Regulate viscosity and cleaning spray gun and use industrial alcohol or acetone;
D, curing:
Construction curtain wall ceramic of the present invention is cured under 120-200 ℃/15-60min condition, and preferred curing process is: 180 ℃/20min.
10, method as claimed in claim 9 is characterized in that step a adopts the method for rolling slaking, and A, B component are mixed by proportioning, places sealed plastic container, continuous rolling slaking 4-5h on twin-roll machine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007100421053A CN101323719A (en) | 2007-06-15 | 2007-06-15 | Construction curtain wall ceramic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2007100421053A CN101323719A (en) | 2007-06-15 | 2007-06-15 | Construction curtain wall ceramic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101323719A true CN101323719A (en) | 2008-12-17 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2007100421053A Pending CN101323719A (en) | 2007-06-15 | 2007-06-15 | Construction curtain wall ceramic |
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Cited By (13)
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| CN102009037A (en) * | 2010-10-25 | 2011-04-13 | 江苏考普乐新材料股份有限公司 | Method for protecting metal by photoelectrochemistry |
| CN102061126A (en) * | 2010-11-25 | 2011-05-18 | 上海金力泰化工股份有限公司 | Ceramic coating film composite and preparation method thereof |
| CN102675935A (en) * | 2012-05-17 | 2012-09-19 | 珠海市氟特科技有限公司 | Ceramic crystal coating for metal surfaces and preparation method thereof |
| CN101597434B (en) * | 2009-06-30 | 2012-11-28 | 陕西师范大学 | Green pigment for substituting paris green with strong toxicity |
| CN102924982A (en) * | 2012-08-22 | 2013-02-13 | 赵加军 | Tough inorganic baked-porcelain paint |
| CN101760057B (en) * | 2009-12-28 | 2013-04-17 | 上海金力泰化工股份有限公司 | Ceramic coating and preparation method thereof and method for preventing cracking of ceramic coating |
| CN103711278A (en) * | 2013-12-19 | 2014-04-09 | 方大新材料（江西）有限公司 | Rare earth ceramic aluminum-coated single board for building decoration and manufacturing method |
| CN103788790A (en) * | 2014-01-22 | 2014-05-14 | 南通市海鸥救生防护用品有限公司 | Fireproof coating and preparation method thereof |
| CN106009800A (en) * | 2016-07-19 | 2016-10-12 | 上海宜瓷龙新材料股份有限公司 | Easily-cleaned porcelain plate capable of releasing negative ions and preparation method thereof |
| CN108192389A (en) * | 2018-01-16 | 2018-06-22 | 成都今天化工有限公司 | A kind of preparation method of nano ceramics fireproof coating |
| CN109836995A (en) * | 2017-09-22 | 2019-06-04 | 上海涂尊新材料科技有限公司 | Interior architecture wall ceramic coating |
| CN112251057A (en) * | 2020-09-23 | 2021-01-22 | 内蒙古工业大学 | Indoor thick steel structure fireproof coating and preparation method thereof |
| CN112757830A (en) * | 2020-12-21 | 2021-05-07 | 浙江和美集成新材料科技有限公司 | Porcelain wood grain decorative plate and manufacturing process thereof |
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- 2007-06-15 CN CNA2007100421053A patent/CN101323719A/en active Pending
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| CN101597434B (en) * | 2009-06-30 | 2012-11-28 | 陕西师范大学 | Green pigment for substituting paris green with strong toxicity |
| CN101760057B (en) * | 2009-12-28 | 2013-04-17 | 上海金力泰化工股份有限公司 | Ceramic coating and preparation method thereof and method for preventing cracking of ceramic coating |
| CN102009037B (en) * | 2010-10-25 | 2013-06-19 | 江苏考普乐新材料股份有限公司 | Method for protecting metal by photoelectrochemistry |
| CN102009037A (en) * | 2010-10-25 | 2011-04-13 | 江苏考普乐新材料股份有限公司 | Method for protecting metal by photoelectrochemistry |
| CN102061126A (en) * | 2010-11-25 | 2011-05-18 | 上海金力泰化工股份有限公司 | Ceramic coating film composite and preparation method thereof |
| CN102061126B (en) * | 2010-11-25 | 2013-08-14 | 上海金力泰化工股份有限公司 | Ceramic coating film composite and preparation method thereof |
| CN102675935B (en) * | 2012-05-17 | 2014-10-08 | 珠海市氟特科技有限公司 | Ceramic crystal coating for metal surfaces and preparation method thereof |
| CN102675935A (en) * | 2012-05-17 | 2012-09-19 | 珠海市氟特科技有限公司 | Ceramic crystal coating for metal surfaces and preparation method thereof |
| CN102924982A (en) * | 2012-08-22 | 2013-02-13 | 赵加军 | Tough inorganic baked-porcelain paint |
| CN102924982B (en) * | 2012-08-22 | 2015-03-11 | 赵加军 | Tough inorganic baked-porcelain paint |
| CN103711278A (en) * | 2013-12-19 | 2014-04-09 | 方大新材料（江西）有限公司 | Rare earth ceramic aluminum-coated single board for building decoration and manufacturing method |
| CN103711278B (en) * | 2013-12-19 | 2015-09-16 | 方大新材料（江西）有限公司 | A kind of architectural decoration rare-earth ceramic coated with aluminum veneer and preparation method |
| CN103788790A (en) * | 2014-01-22 | 2014-05-14 | 南通市海鸥救生防护用品有限公司 | Fireproof coating and preparation method thereof |
| CN106009800A (en) * | 2016-07-19 | 2016-10-12 | 上海宜瓷龙新材料股份有限公司 | Easily-cleaned porcelain plate capable of releasing negative ions and preparation method thereof |
| CN106009800B (en) * | 2016-07-19 | 2018-12-04 | 上海宜瓷龙新材料股份有限公司 | A kind of porcelain plate easy to clean capable of releasing negative ion and preparation method thereof |
| CN109836995A (en) * | 2017-09-22 | 2019-06-04 | 上海涂尊新材料科技有限公司 | Interior architecture wall ceramic coating |
| CN108192389A (en) * | 2018-01-16 | 2018-06-22 | 成都今天化工有限公司 | A kind of preparation method of nano ceramics fireproof coating |
| CN112251057A (en) * | 2020-09-23 | 2021-01-22 | 内蒙古工业大学 | Indoor thick steel structure fireproof coating and preparation method thereof |
| CN112757830A (en) * | 2020-12-21 | 2021-05-07 | 浙江和美集成新材料科技有限公司 | Porcelain wood grain decorative plate and manufacturing process thereof |
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Open date: 20081217 |