CN101318842B - Process for manufacturing surface decoration layer of ceramic - Google Patents
Process for manufacturing surface decoration layer of ceramic Download PDFInfo
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- CN101318842B CN101318842B CN2008100294847A CN200810029484A CN101318842B CN 101318842 B CN101318842 B CN 101318842B CN 2008100294847 A CN2008100294847 A CN 2008100294847A CN 200810029484 A CN200810029484 A CN 200810029484A CN 101318842 B CN101318842 B CN 101318842B
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Abstract
A manufacturing method for a ceramic surface decoration layer is characterized in that: the method comprises the following steps of: (1) making decorations on a ceramic piece through an underglaze blue and white pigment; (2) drying the underglaze blue and white pigment on the ceramic piece by baking; (3) applying or spraying three-dimensional crystalline art glaze on the underglaze blue and white pigment on the ceramic piece; (4) heating the ceramic piece to 1300 to 1320 DEG C in an oxidative atmosphere, and then quickly reducing the temperature to 130 DEG C; (5) keeping the ceramic at the temperature of 1130 DEG C for 1.5 to 2 hours and then naturally cooling down the ceramic piece through extinguishing fire. Compared with the prior art, the method has the advantages that: the ceramic surface decoration layer manufactured through the method has the underglaze blue and white pigment blending under the three-dimensional crystalline art glaze; the underglaze blue and white pigment has a blue and smooth color with high clearness and can be used for drafting patterns such as Chinese painting with high requirements on clearness; crystalline patterns on the glaze are three dimensional and give off lofty rays of light with brilliant and rich color, harmony and good appearance.
Description
Technical field
The present invention relates to a kind of manufacture method of surface decoration layer of ceramic.
Background technology
Underglaze blue pigment is with the cobalt ore raw material that contains cobalt oxide, is used for describing on ceramic body decorative pattern.Cover last layer three-dimensional crystals artistic glaze on the decorative pattern that underglaze blue pigment plots just can be through high temperature reduction flame once-firing surface decoration layer of ceramic.And the three-dimensional crystals artistic glaze is to contain artificial crystal in a kind of glaze and the artistic glaze that presents brilliant flower of all kinds, and is resplendent, peculiar.The formation condition of the artificial crystalline of three-dimensional crystals artistic glaze pins down mutually with firing condition, glazing thickness but holds mutually mutually, the flowability of glaze is big, underglaze blue in addition pigment is positioned at three-dimensional crystals artistic glaze bottom, be difficult to control the pattern readability of underglaze blue pigment, the optimum regime of Cheng Jing, the pattern that therefore still can't obtain underglaze blue pigment so far is clear, the good surface decoration layer of ceramic of artificial crystal crystallization effect of three-dimensional crystals artistic glaze, can't be used for forming traditional Chinese Painting etc. to the demanding pattern of sharpness at ceramic surface.
Summary of the invention
The objective of the invention is prior art is improved, a kind of manufacture method of surface decoration layer of ceramic is provided, the pattern that can obtain underglaze blue pigment is clear, the good surface decoration layer of ceramic of artificial crystal crystallization effect of three-dimensional crystals artistic glaze, and the technical scheme of employing is as follows:
The manufacture method of surface decoration layer of ceramic of the present invention is characterized in that: comprise following steps:
1) glosses on pottery with underglaze blue pigment;
2) with the underglaze blue pigment oven dry on the pottery;
3) Shi Shanghuo sprays the three-dimensional crystals artistic glaze on the underglaze blue pigment on the pottery;
4) pottery is warmed up to 1300-1320 ℃ under oxidizing atmosphere, then fast cooling to 1130 ℃;
5) pottery is incubated 1.5-2 hour at 1130 ℃, flame-out then its naturally cooling that allows.
The speed that pottery heats up in the above-mentioned steps 4: 1000 ℃ with interior per hour 180-200 ℃, and with interior per hour 80-100 ℃, the time of cooling is 20-40 minute more than 1000 ℃.
A kind of scheme, described three-dimensional crystals artistic glaze contains following components in weight percentage: SiO
240-50%, Al
2O
38-12%, CaO 6-10%, MgO 3-5%, K
2O 4-6%, Na
2O 4-5%, ZnO 18-25%, Co
2O
3The chemical ingredients of decomposing or volatilizing under the impurity of 0.6-1.2% and other content and the temperature of glaze firing.
It is raw material that described three-dimensional crystals artistic glaze adopts following ore or compound, and it is formed and weight percent is: the chemical ingredients of decomposing or volatilizing under the impurity of feldspar 32-40%, water mill quartzy 24-30%, zinc oxide 18-25%, rhombspar 15-20%, tricobalt tetroxide 0.5-1.5% and other content and the temperature of glaze firing.
Another kind of scheme, described three-dimensional crystals artistic glaze contains following components in weight percentage: SiO
245-55%, Al
2O
35-10%, CaO 3-6%, MgO 2-4%, Na
2O 8-14%, ZnO 25-30%, TiO
2The chemical ingredients of decomposing or volatilizing under the impurity of 1-2% and other content and the temperature of glaze firing.
It is raw material that described three-dimensional crystals artistic glaze adopts following ore or compound, and it is formed and weight percent is: the chemical ingredients of decomposing or volatilizing under the impurity of glass 60-65%, kaolin 10-15%, zinc oxide 24-29%, titanium oxide 1-2% and other content and the temperature of glaze firing.
The third scheme, described three-dimensional crystals artistic glaze contains following components in weight percentage: SiO
265-73%, Al
2O
320-25%, CaO 1-5%, MgO 0.3-2%, K
2O 3-5%, Na
2O1-2%, Fe
2O
3The chemical ingredients of decomposing or volatilizing under the impurity of 1-2% and other content and the temperature of glaze firing.
It is raw material that described three-dimensional crystals artistic glaze adopts following ore or compound, and it is formed and weight percent is: the chemical ingredients of decomposing or volatilizing under feldspar 35-40%, the quartzy 15-20% of water mill, the impurity that burns talcum 10-15%, bone ash 12-18%, ferric oxide 15%-20% and other content and the temperature of glaze firing.
It is raw material that described underglaze blue pigment adopts following ore or compound, and it is formed and weight percent is: cobalt oxide 30-40%, zinc oxide 10-20%, quartzy 20-30%, feldspar 15-25%.
It is raw material that more excellent scheme, above-mentioned underglaze blue pigment adopt following ore or compound, and it is formed and weight percent is: cobalt oxide 38-40%, zinc oxide 15-18%, quartzy 24-27%, feldspar 20-23%.
The raw material of described underglaze blue pigment obtains underglaze blue pigment through mixing, grind, cross the 10000-hole sieve several steps successively, the preferred technical parameter of 10000-hole sieve is 300 orders, grind and adopt wet ball mill, by weight, underglaze blue pigment: the ball of wet ball mill: water=1: (5-6): (0.8-1).
The raw material of described three-dimensional crystals artistic glaze obtains the three-dimensional crystals artistic glaze through mixing, pulverizing, wet ball mill several steps successively, the time range of wet ball mill is 20-25 hour, by weight, three-dimensional crystals artistic glaze: the ball of wet ball mill: water=1: (1.5-2.5): (0.5-0.7), the glaze slip proportion of three-dimensional crystals artistic glaze is 1.48-1.52.
Described pottery is art bottle or porcelain plate, pottery is obtained through the klining operation by biscuit of ceramics, and then with underglaze blue pigment decorative patterns on pottery, work is finished on the baking dry application or is sprayed the three-dimensional crystals artistic glaze, and the optimization technique parameter is: the glaze layer thickness scope of this three-dimensional crystals artistic glaze is 0.8-1.4mm.
Described klining operation is: at the common high melting glaze of biscuit of ceramics last layer, pass through 1300-1320 ℃ klining again, obtain pottery.
The present invention's beneficial effect against existing technologies is, produced surface decoration layer of ceramic, underglaze blue pigment is melted into three-dimensional crystals artistic glaze bottom, the blue profit of underglaze blue pigment color and luster, the sharpness height can be used in and draws traditional Chinese Painting etc. to the demanding pattern of sharpness, crystalline substance is spent solid on the glaze, radiate and shine with boundless radiance, bright in luster colourful, harmonious attractive in appearance.
Embodiment
Embodiment 1
In the present embodiment, get 40 kilograms of feldspars, quartzy 24 kilograms of water mill, 20 kilograms in zinc oxide, 15 kilograms of rhombspars, 1 kilogram of tricobalt tetroxide.Add 60 kilograms in water, 150 kilograms in ball milling ball, wet ball grinding 24 hours.Fineness is controlled at 10000-hole sieve and tails over 0.03%, and the gained slurry is a three-dimensional crystals artistic glaze slurry of the present invention.Get 39 kilograms of cobalt oxides, 14 kilograms in zinc oxide, 26 kilograms in quartz, 21 kilograms of feldspars, calcine, ground 300 order 10000-hole sieves, the gained material is underglaze blue pigment.
After the biscuit of ceramics passed examination, at the common high melting glaze of biscuit of ceramics last layer, through 1310 ℃ klining acquisition pottery, get the underglaze blue pigment of small portion more again, water is transferred and is opened, and draws decorative patterns, airing on pottery.The glaze slip proportion of three-dimensional crystals artistic glaze is 1.48 grams per milliliters, takes local spray glazing glazing, and the glaze layer thickness of three-dimensional crystals artistic glaze is 0.8mm, obtains slipware.The glaze layer should not be too thick, and is big if the flowability of too thick glaze just becomes, and the foot of implements can a large amount of poly-glaze, and underglaze blue pigment can be subjected to flowing of glaze and flow, and grain pattern fogs.Glaze can gather in a large number in the foot of implements, influence the attractive in appearance of whole device shape and increase the difficulty of pedicure.
Introduce sintering procedure below:
Above-mentioned slipware (i.e. pottery) is carried out roasting in the coal gas kiln, adopt oxidizing atmosphere, be warmed up to 1310 ℃, at 1000 ℃ with interior per hour 180 ℃, with interior per hour 100 ℃, cool to 1130 ℃ in 40 minutes then more than 1000 ℃, be incubated 2 hours, allow its naturally cooling then, obtain the three-dimensional crystals artistic glaze and melt the surface decoration layer of ceramic that forms mutually with underglaze blue pigment.
Embodiment 2
In the present embodiment, get 32 kilograms of feldspars, quartzy 30 kilograms of water mill, 18 kilograms in zinc oxide, 18.5 kilograms of rhombspars, 1.5 kilograms of tricobalt tetroxides.Add 50 kilograms in water, 150 kilograms in ball milling ball, wet ball grinding 22 hours.Fineness is controlled at 10000-hole sieve and tails over 0.03%, and the gained slurry is a three-dimensional crystals artistic glaze of the present invention.Get 30 kilograms of cobalt oxides, 20 kilograms in zinc oxide, 30 kilograms in quartz, 20 kilograms of feldspars, calcine, ground 300 order 10000-hole sieves, the gained material is underglaze blue pigment.
After the biscuit of ceramics passed examination, at the common high melting glaze of biscuit of ceramics last layer, through 1300 ℃ klining acquisition pottery, get the underglaze blue pigment of small portion more again, water is transferred and is opened, and draws decorative patterns, airing on pottery.Three-dimensional crystals artistic glaze glaze slip proportion is 1.52 grams per milliliters, takes local glaze method glazing, and the glaze layer thickness of three-dimensional crystals artistic glaze is 1.4mm, obtains slipware.
Introduce sintering procedure below:
Slipware is carried out roasting in the coal gas kiln, adopt oxidizing atmosphere, be warmed up to 1320 ℃, at 1000 ℃ with interior per hour 200 ℃, with interior per hour 80 ℃, cool to 1130 ℃ in 20 minutes then more than 1000 ℃, be incubated 2 hours, allow its naturally cooling then, obtain the three-dimensional crystals artistic glaze and melt the surface decoration layer of ceramic that forms mutually with underglaze blue pigment.
Embodiment 3
In the present embodiment, get 35 kilograms of feldspars, quartzy 25 kilograms of water mill, 19.5 kilograms in zinc oxide, 20 kilograms of rhombspars, 0.5 kilogram of tricobalt tetroxide.Add 70 kilograms in water, 250 kilograms in ball milling ball, wet ball grinding 20 hours.Fineness is controlled at 10000-hole sieve and tails over 0.03%, and the gained slurry is a three-dimensional crystals artistic glaze of the present invention.Get 40 kilograms of cobalt oxides, 10 kilograms in zinc oxide, 25 kilograms in quartz, 25 kilograms of feldspars, calcine, ground 300 order 10000-hole sieves, the gained material is underglaze blue pigment.
After the biscuit of ceramics passed examination, at the common high melting glaze of biscuit of ceramics last layer, through 1320 ℃ klining acquisition pottery, get the underglaze blue pigment of small portion more again, water is transferred and is opened, and draws decorative patterns, airing on pottery.The glaze slip proportion of three-dimensional crystals artistic glaze is 1.50 grams per milliliters, takes local spray glazing glazing, and the glaze layer thickness of three-dimensional crystals artistic glaze is 1.2mm, obtains slipware.
Introduce sintering procedure below:
Slipware is carried out roasting in the coal gas kiln, adopt oxidizing atmosphere, be warmed up to 1300 ℃, at 1000 ℃ with interior per hour 190 ℃, with interior per hour 90 ℃, cool to 1130 ℃ in 30 minutes then more than 1000 ℃, be incubated 2 hours, allow its naturally cooling then, obtain the three-dimensional crystals artistic glaze and melt the surface decoration layer of ceramic that forms mutually with underglaze blue pigment.
Embodiment 4
In the present embodiment, get 32 kilograms of feldspars, quartzy 24 kilograms of water mill, 25 kilograms in zinc oxide, 18 kilograms of rhombspars, 1 kilogram of tricobalt tetroxide.Add 80 kilograms in water, 500 kilograms in ball milling ball, wet ball grinding 25 hours.Fineness is controlled at 10000-hole sieve and tails over 0.03%, and the gained slurry is a three-dimensional crystals artistic glaze of the present invention.Get 40 kilograms of cobalt oxides, 20 kilograms in zinc oxide, 25 kilograms in quartz, 15 kilograms of feldspars, calcine, ground 300 order 10000-hole sieves, the gained material is underglaze blue pigment.
After the biscuit of ceramics passed examination, at the common high melting glaze of biscuit of ceramics last layer, through 1310 ℃ klining acquisition pottery, get the underglaze blue pigment of small portion more again, water is transferred and is opened, and draws decorative patterns, airing on pottery.The glaze slip proportion of three-dimensional crystals artistic glaze is 1.51 grams per milliliters, takes local spray glazing glazing, and three-dimensional crystals artistic glaze glaze layer thickness is 1.1mm, obtains slipware.
Introduce sintering procedure below:
Slipware is carried out roasting in the coal gas kiln, adopt oxidizing atmosphere, be warmed up to 1300 ℃, at 1000 ℃ with interior per hour 190 ℃, with interior per hour 90 ℃, cool to 1130 ℃ in 30 minutes then more than 1000 ℃, be incubated 2 hours, allow its naturally cooling then, obtain the three-dimensional crystals artistic glaze and melt the surface decoration layer of ceramic that forms mutually with underglaze blue pigment.
Embodiment 5
In the present embodiment, get 62 kilograms in glass, 11 kilograms of kaolin, 26 kilograms in zinc oxide, 1 kilogram of titanium oxide.Add 50 kilograms in water, 150 kilograms in ball milling ball, wet ball grinding 24 hours.Fineness is controlled at 10000-hole sieve and tails over 0.03%, and the gained slurry is a three-dimensional crystals artistic glaze of the present invention.Get 36 kilograms of cobalt oxides, 20 kilograms in zinc oxide, 20 kilograms in quartz, 24 kilograms of feldspars, calcine, ground 300 order 10000-hole sieves, the gained material is underglaze blue pigment.
After the biscuit of ceramics passed examination, at the common high melting glaze of biscuit of ceramics last layer, through 1310 ℃ klining acquisition pottery, get the underglaze blue pigment of small portion more again, water is transferred and is opened, and glosses over airing on pottery.Proportion 1.50 grams per milliliters of the glaze slip of three-dimensional crystals artistic glaze are taked local glaze method glazing, and the glaze layer thickness of three-dimensional crystals artistic glaze obtains slipware at 1.4mm.
Introduce sintering procedure below:
Slipware is carried out roasting in the coal gas kiln, adopt oxidizing atmosphere, be warmed up to 1300 ℃, at 1000 ℃ with interior per hour 190 ℃, with interior per hour 90 ℃, cool to 1130 ℃ in 30 minutes then more than 1000 ℃, be incubated 2 hours, allow its naturally cooling then, obtain the three-dimensional crystals artistic glaze and melt the surface decoration layer of ceramic that forms mutually with underglaze blue pigment.
Embodiment 6
In the present embodiment, get 60 kilograms in glass, 15 kilograms of kaolin, 24 kilograms in zinc oxide, 1 kilogram of titanium oxide.Add 100 kilograms in water, 600 kilograms in ball milling ball, wet ball grinding 23 hours.Fineness is controlled at 10000-hole sieve and tails over 0.03%, and the gained slurry is a three-dimensional crystals artistic glaze of the present invention.Get 38 kilograms of cobalt oxides, 18 kilograms in zinc oxide, 24 kilograms in quartz, 20 kilograms of feldspars, calcine, ground 300 order 10000-hole sieves, the gained material is underglaze blue pigment.
After the biscuit of ceramics passed examination,, ceramic through 1320 ℃ klining acquisition again at the common high melting glaze of biscuit of ceramics last layer, get the underglaze blue pigment of small portion again, water is transferred and is opened, and glosses on pottery, airing, proportion 1.50 grams per milliliters of the glaze slip of three-dimensional crystals artistic glaze.Take local spray glazing glazing.The glaze layer thickness of three-dimensional crystals artistic glaze obtains slipware at 1.2mm.
Introduce sintering procedure below:
Slipware is carried out roasting in the coal gas kiln, adopt oxidizing atmosphere, be warmed up to 1300 ℃, at 1000 ℃ with interior per hour 190 ℃, with interior per hour 90 ℃, cool to 1130 ℃ in 30 minutes then more than 1000 ℃, be incubated 2 hours, allow its naturally cooling then, obtain the three-dimensional crystals artistic glaze and melt the surface decoration layer of ceramic that forms mutually with underglaze blue pigment.
Embodiment 7
In the present embodiment, get 65 kilograms in glass, 10 kilograms of kaolin, 24 kilograms in zinc oxide, 1 kilogram of titanium oxide.Add 100 kilograms in water, 500 kilograms in ball milling ball, wet ball grinding 22 hours.Fineness is controlled at 10000-hole sieve and tails over 0.03%, and the gained slurry is a three-dimensional crystals artistic glaze of the present invention.Get 40 kilograms of cobalt oxides, 15 kilograms in zinc oxide, 25 kilograms in quartz, 20 kilograms of feldspars, calcine, ground 300 order 10000-hole sieves, the gained material is underglaze blue pigment.
After the biscuit of ceramics passed examination, at the common high melting glaze of biscuit of ceramics last layer, through 1320 ℃ klining acquisition pottery, get the underglaze blue pigment of small portion more again, water is transferred and is opened, and glosses over airing on pottery.Proportion 1.51 grams per milliliters of the glaze slip of three-dimensional crystals artistic glaze are taked local spray glazing glazing, and the glaze layer thickness of three-dimensional crystals artistic glaze obtains slipware at 0.9mm.
Introduce sintering procedure below:
Slipware is carried out roasting in the coal gas kiln, adopt oxidizing atmosphere, be warmed up to 1300 ℃, at 1000 ℃ with interior per hour 190 ℃, with interior per hour 90 ℃, cool to 1130 ℃ in 30 minutes then more than 1000 ℃, be incubated 2 hours, allow its naturally cooling then, obtain the three-dimensional crystals artistic glaze and melt the surface decoration layer of ceramic that forms mutually with underglaze blue pigment.
Embodiment 8
In the present embodiment, get 60 kilograms in glass, 10 kilograms of kaolin, 28 kilograms in zinc oxide, 2 kilograms of titanium oxide.Add 100 kilograms in water, 600 kilograms in ball milling ball, wet ball grinding 23 hours.Fineness is controlled at 10000-hole sieve and tails over 0.03%, and the gained slurry is a three-dimensional crystals artistic glaze of the present invention.Get 38 kilograms of cobalt oxides, 15 kilograms in zinc oxide, 27 kilograms in quartz, 20 kilograms of feldspars, calcine, ground 300 order 10000-hole sieves, the gained material is underglaze blue pigment.
After the biscuit of ceramics passed examination, at the common high melting glaze of biscuit of ceramics last layer, through 1320 ℃ klining acquisition pottery, get the underglaze blue pigment of small portion more again, water is transferred and is opened, and glosses over airing on pottery.Proportion 1.50 grams per milliliters of three-dimensional crystals artistic glaze glaze slip are taked local glaze method glazing, and three-dimensional crystals artistic glaze glaze layer thickness obtains slipware at 1.2mm.
Introduce sintering procedure below:
Slipware is carried out roasting in the coal gas kiln, employing oxidizing atmosphere, be warmed up to 1300 ℃, at 1000 ℃ with interior per hour 185 ℃, with interior per hour 95 ℃, cool to 1130 ℃ in 35 minutes then more than 1000 ℃, be incubated 2 hours, allow its naturally cooling then, obtain the three-dimensional crystals artistic glaze and melt the surface decoration layer of ceramic that forms mutually with underglaze blue pigment.
Embodiment 9
In the present embodiment, get 60 kilograms in glass, 10 kilograms of kaolin, 29 kilograms in zinc oxide, 1 kilogram of titanium oxide.Add 90 kilograms in water, 550 kilograms in ball milling ball, wet ball grinding 22 hours.Fineness is controlled at 10000-hole sieve and tails over 0.03%, and the gained slurry is a three-dimensional crystals artistic glaze of the present invention.Get 38 kilograms of cobalt oxides, 15 kilograms in zinc oxide, 24 kilograms in quartz, 23 kilograms of feldspars, calcine, ground 300 order 10000-hole sieves, the gained material is underglaze blue pigment.
After the biscuit of ceramics passed examination, at the common high melting glaze of biscuit of ceramics last layer, through 1320 ℃ klining acquisition pottery, get the underglaze blue pigment of small portion more again, water is transferred and is opened, and glosses over airing on art bottle or porcelain plate.Proportion 1.48 grams per milliliters of the glaze slip of three-dimensional crystals artistic glaze are taked local glaze method glazing, and the glaze layer thickness of three-dimensional crystals artistic glaze obtains slipware at 1.3mm.
Introduce sintering procedure below:
Slipware is carried out roasting in the coal gas kiln, adopt oxidizing atmosphere, be warmed up to 1300 ℃, at 1000 ℃ with interior per hour 190 ℃, with interior per hour 90 ℃, cool to 1130 ℃ in 30 minutes then more than 1000 ℃, be incubated 2 hours, allow its naturally cooling then, obtain the three-dimensional crystals artistic glaze and melt the surface decoration layer of ceramic that forms mutually with underglaze blue pigment.
Embodiment 10
In the present embodiment, get 38 kilograms of feldspars, quartzy 20 kilograms of water mill, burn 10 kilograms in talcum, 12 kilograms in bone ash, 20 kilograms of ferric oxide.Add 60 kilograms in water, 150 kilograms in ball milling ball, wet ball grinding 24 hours.Fineness is controlled at 10000-hole sieve and tails over 0.03%, and the gained slurry is a three-dimensional crystals artistic glaze of the present invention.Get 34 kilograms of cobalt oxides, 16 kilograms in zinc oxide, 26 kilograms in quartz, 24 kilograms of feldspars, calcine, ground 300 order 10000-hole sieves, the gained material is underglaze blue pigment.
After the biscuit of ceramics passed examination, at the common high melting glaze of biscuit of ceramics last layer, through 1300 ℃ klining acquisition pottery, get the underglaze blue pigment of small portion more again, water is transferred and is opened, and glosses over airing on pottery.Glaze slip proportion 1.5 grams per milliliters of three-dimensional crystals artistic glaze are taked local spray glazing glazing, and the glaze layer thickness of three-dimensional crystals artistic glaze obtains slipware at 1.1mm.
Introduce sintering procedure below:
Slipware is carried out roasting in the coal gas kiln, adopt oxidizing atmosphere, be warmed up to 1320 ℃, at 1000 ℃ with interior per hour 195 ℃, with interior per hour 95 ℃, cool to 1130 ℃ in 33 minutes then more than 1000 ℃, be incubated 1.5 hours, allow its naturally cooling then, obtain the three-dimensional crystals artistic glaze and melt the surface decoration layer of ceramic that forms mutually with underglaze blue pigment.
Embodiment 11
In the present embodiment, get 35 kilograms of feldspars, quartzy 15 kilograms of water mill, burn 15 kilograms in talcum, 18 kilograms in bone ash, 17 kilograms of ferric oxide.Add 60 kilograms in water, 150 kilograms in ball milling ball, wet ball grinding 24 hours.Fineness is controlled at 10000-hole sieve and tails over 0.03%, and the gained slurry is a three-dimensional crystals artistic glaze of the present invention.Get 34 kilograms of cobalt oxides, 16 kilograms in zinc oxide, 26 kilograms in quartz, 24 kilograms of feldspars, calcine, ground 300 order 10000-hole sieves, the gained material is underglaze blue pigment.
After the biscuit of ceramics passed examination, at the common high melting glaze of biscuit of ceramics last layer, through 1300 ℃ klining acquisition pottery, get the underglaze blue pigment of small portion more again, water is transferred and is opened, and glosses over airing on pottery.Glaze slip proportion 1.5 grams per milliliters of three-dimensional crystals artistic glaze are taked local spray glazing glazing, and the glaze layer thickness of three-dimensional crystals artistic glaze obtains slipware at 1.1mm.
Introduce sintering procedure below:
Slipware is carried out roasting in the coal gas kiln, adopt oxidizing atmosphere, be warmed up to 1310 ℃, at 1000 ℃ with interior per hour 185 ℃, with interior per hour 95 ℃, cool to 1130 ℃ in 37 minutes then more than 1000 ℃, be incubated 1.8 hours, allow its naturally cooling then, obtain the three-dimensional crystals artistic glaze and melt the surface decoration layer of ceramic that forms mutually with underglaze blue pigment.
Embodiment 12
In the present embodiment, get 40 kilograms of feldspars, quartzy 20 kilograms of water mill, burn 10 kilograms in talcum, 15 kilograms in bone ash, 15 kilograms of ferric oxide.Add 60 kilograms in water, 150 kilograms in ball milling ball, wet ball grinding 24 hours.Fineness is controlled at 10000-hole sieve and tails over 0.03%, and the gained slurry is a three-dimensional crystals artistic glaze of the present invention.Get 34 kilograms of cobalt oxides, 16 kilograms in zinc oxide, 26 kilograms in quartz, 24 kilograms of feldspars, calcine, ground 300 order 10000-hole sieves, the gained material is underglaze blue pigment.
After the biscuit of ceramics passed examination, at the common high melting glaze of biscuit of ceramics last layer, through 1300 ℃ klining acquisition pottery, get the underglaze blue pigment of small portion more again, water is transferred and is opened, and glosses over airing on pottery.Glaze slip proportion 1.49 grams per milliliters of three-dimensional crystals artistic glaze are taked local glaze method glazing, and the glaze layer thickness of three-dimensional crystals artistic glaze obtains slipware at 1.2mm.
Introduce sintering procedure below:
Slipware is carried out roasting in the coal gas kiln, adopt oxidizing atmosphere, be warmed up to 1310 ℃, at 1000 ℃ with interior per hour 185 ℃, with interior per hour 85 ℃, cool to 1130 ℃ in 36 minutes then more than 1000 ℃, be incubated 1.6 hours, allow its naturally cooling then, obtain the three-dimensional crystals artistic glaze and melt the surface decoration layer of ceramic that forms mutually with underglaze blue pigment.
Embodiment 13
In the present embodiment, get 37 kilograms of feldspars, quartzy 18 kilograms of water mill, burn 12 kilograms in talcum, 15 kilograms in bone ash, 18 kilograms of ferric oxide.Add 70 kilograms in water, 200 kilograms in ball milling ball, wet ball grinding 21 hours.Fineness is controlled at 10000-hole sieve and tails over 0.03%, and the gained slurry is a three-dimensional crystals artistic glaze of the present invention.Get 34 kilograms of cobalt oxides, 16 kilograms in zinc oxide, 26 kilograms in quartz, 24 kilograms of feldspars, calcine, ground 300 order 10000-hole sieves, the gained material is underglaze blue pigment.
After the biscuit of ceramics passed examination, at the common high melting glaze of biscuit of ceramics last layer, through 1300 ℃ klining acquisition pottery, get the underglaze blue pigment of small portion more again, water is transferred and is opened, and glosses over airing on pottery.Glaze slip proportion 1.52 grams per milliliters of three-dimensional crystals artistic glaze are taked local spray glazing glazing, and the glaze layer thickness of three-dimensional crystals artistic glaze obtains slipware at 1.3mm.
Introduce sintering procedure below:
Slipware is carried out roasting in the coal gas kiln, adopt oxidizing atmosphere, be warmed up to 1310 ℃, at 1000 ℃ with interior per hour 195 ℃, with interior per hour 85 ℃, cool to 1130 ℃ in 31 minutes then more than 1000 ℃, be incubated 1.9 hours, allow its naturally cooling then, obtain the three-dimensional crystals artistic glaze and melt the surface decoration layer of ceramic that forms mutually with underglaze blue pigment.
The above only is several preferred embodiment of the present invention, is not to be used for limiting practical range of the present invention; Be all equivalents of being done according to claim scope of the present invention, be claim scope of the present invention and cover.
Claims (7)
1. the manufacture method of a surface decoration layer of ceramic is characterized in that: comprise following steps:
1) glosses on pottery with underglaze blue pigment;
2) with the underglaze blue pigment oven dry on the pottery;
3) Shi Shanghuo sprays the three-dimensional crystals artistic glaze on the underglaze blue pigment on the pottery;
4) pottery is warmed up to 1300-1320 ℃ under oxidizing atmosphere, cools to 1130 ℃ then;
5) pottery is incubated 1.5-2 hour at 1130 ℃, flame-out then its naturally cooling that allows;
It is raw material that described underglaze blue pigment adopts following ore or compound, and it is formed and weight percent is: cobalt oxide 30-40%, zinc oxide 10-20%, quartzy 20-30%, feldspar 15-25%;
Described three-dimensional crystals artistic glaze contains following chemical constitution and weight percent: SiO
240-50%, Al
2O
38-12%, CaO 6-10%, MgO 3-5%, K
2O 4-6%, Na
2O 4-5%, ZnO 18-25%, Co
2O
3The chemical ingredients of decomposing or volatilizing under the impurity of 0.6-1.2% and other content and the temperature of glaze firing;
The speed of intensification of pottery in the above-mentioned steps 4: 1000 ℃ with interior per hour 180-200 ℃, and more than 1000 ℃ per hour 80-100 ℃, the time of cooling is 20-40 minute.
2. the manufacture method of surface decoration layer of ceramic as claimed in claim 1, it is characterized in that: it is raw material that described three-dimensional crystals artistic glaze adopts following ore or compound, and it is formed and weight percent is: the chemical ingredients of decomposing or volatilizing under the impurity of feldspar 32-40%, water mill quartzy 24-30%, zinc oxide 18-25%, rhombspar 15-20%, tricobalt tetroxide 0.5-1.5% and other content and the temperature of glaze firing.
3. the manufacture method of a surface decoration layer of ceramic is characterized in that: comprise following steps:
1) glosses on pottery with underglaze blue pigment;
2) with the underglaze blue pigment oven dry on the pottery;
3) Shi Shanghuo sprays the three-dimensional crystals artistic glaze on the underglaze blue pigment on the pottery;
4) pottery is warmed up to 1300-1320 ℃ under oxidizing atmosphere, cools to 1130 ℃ then;
5) pottery is incubated 1.5-2 hour at 1130 ℃, flame-out then its naturally cooling that allows;
It is raw material that described underglaze blue pigment adopts following ore or compound, and it is formed and weight percent is: cobalt oxide 30-40%, zinc oxide 10-20%, quartzy 20-30%, feldspar 15-25%;
Described three-dimensional crystals artistic glaze contains following chemical constitution and weight percent: SiO
245-55%, Al
2O
35-10%, CaO 3-6%, MgO 2-4%, Na
2O 8-14%, ZnO 25-30%, TiO
2The chemical ingredients of decomposing or volatilizing under the impurity of 1-2% and other content and the temperature of glaze firing;
The speed of intensification of pottery in the above-mentioned steps 4: 1000 ℃ with interior per hour 180-200 ℃, and more than 1000 ℃ per hour 80-100 ℃, the time of cooling is 20-40 minute.
4. the manufacture method of surface decoration layer of ceramic as claimed in claim 3, it is characterized in that: it is raw material that described three-dimensional crystals artistic glaze adopts following ore or compound, and it is formed and weight percent is: the chemical ingredients of decomposing or volatilizing under the impurity of glass 60-65%, kaolin 10-15%, zinc oxide 24-29%, titanium oxide 1-2% and other content and the temperature of glaze firing.
5. the manufacture method of a surface decoration layer of ceramic is characterized in that: comprise following steps:
1) glosses on pottery with underglaze blue pigment;
2) with the underglaze blue pigment oven dry on the pottery;
3) Shi Shanghuo sprays the three-dimensional crystals artistic glaze on the underglaze blue pigment on the pottery;
4) pottery is warmed up to 1300-1320 ℃ under oxidizing atmosphere, cools to 1130 ℃ then;
5) pottery is incubated 1.5-2 hour at 1130 ℃, flame-out then its naturally cooling that allows;
It is raw material that described underglaze blue pigment adopts following ore or compound, and it is formed and weight percent is: cobalt oxide 30-40%, zinc oxide 10-20%, quartzy 20-30%, feldspar 15-25%;
Described three-dimensional crystals artistic glaze contains following chemical constitution and weight percent: SiO
265-73%, Al
2O
320-25%, CaO 1-5%, MgO 0.3-2%, K
2O 3-5%, Na
2O 1-2%, Fe
2O
3The chemical ingredients of decomposing or volatilizing under the impurity of 1-2% and other content and the temperature of glaze firing;
The speed of intensification of pottery in the above-mentioned steps 4: 1000 ℃ with interior per hour 180-200 ℃, and more than 1000 ℃ per hour 80-100 ℃, the time of cooling is 20-40 minute.
6. the manufacture method of surface decoration layer of ceramic as claimed in claim 5, it is characterized in that: it is raw material that described three-dimensional crystals artistic glaze adopts following ore or compound, and it is formed and weight percent is: the chemical ingredients of decomposing or volatilizing under feldspar 35-40%, the quartzy 15-20% of water mill, the impurity that burns talcum 10-15%, bone ash 12-18%, ferric oxide 15%-20% and other content and the temperature of glaze firing.
7. as the manufacture method of any described surface decoration layer of ceramic among the claim 1-6, it is characterized in that: the raw material of described underglaze blue pigment obtains underglaze blue pigment through mixing, grind, cross the 10000-hole sieve several steps successively, the technical parameter of 10000-hole sieve is 300 orders, grind and adopt wet ball mill, by weight, underglaze blue pigment: the ball of wet ball mill: water=1: (5-6): (0.8-1); The raw material of described three-dimensional crystals artistic glaze obtains the three-dimensional crystals artistic glaze through mixing, pulverizing, wet ball mill several steps successively, the time range of wet ball mill is 20-25 hour, by weight, three-dimensional crystals artistic glaze: the ball of wet ball mill: water=1: (1.5-2.5): (0.5-0.7), the glaze slip proportion of three-dimensional crystals artistic glaze is 1.48-1.52; Described pottery is art bottle or porcelain plate, pottery is obtained through the klining operation by biscuit of ceramics, and then with underglaze blue pigment decorative patterns on pottery, do to finish on the baking dry application or spray the three-dimensional crystals artistic glaze, the glaze layer thickness scope of this three-dimensional crystals artistic glaze is 0.8-1.4mm; Described klining operation is: at the common high melting glaze of biscuit of ceramics last layer, pass through 1300-1320 ℃ klining again, obtain pottery.
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| CN103144184B (en) * | 2013-03-22 | 2015-06-17 | 唐山红玫瑰陶瓷制品有限公司陶瓷研究院 | Ceramic glaze painting method |
| CN104744078A (en) * | 2015-03-31 | 2015-07-01 | 马健 | Firing technique of blue-and-white underglaze red |
| CN107382089B (en) * | 2017-05-26 | 2018-07-27 | 广东先朗照明有限公司 | A kind of technique of glass surface graphic-print |
| CN108706879A (en) * | 2017-10-30 | 2018-10-26 | 福建省德化县恒昇陶瓷有限公司 | Color material and its manufacture craft of ceramics under furnace transmutation glaze |
| CN108529881A (en) * | 2018-07-16 | 2018-09-14 | 界首市伟盛古窑彩陶制作发展有限公司 | A kind of high-compactness viridescent colour glaze |
| CN109485258A (en) * | 2019-01-16 | 2019-03-19 | 德化县英发陶瓷有限公司 | Crystalline glaze and the method for preparing crystalline glaze ceramic with it |
| CN114835476B (en) * | 2022-03-15 | 2023-06-13 | 福建省德化县豪发陶瓷有限公司 | High-strength blue-and-white five-color glazed porcelain and preparation method thereof |
| CN114907148A (en) * | 2022-05-23 | 2022-08-16 | 孙赛华 | Formula and processing method of over-glaze blue and white pigment |
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| CN1821170A (en) * | 2006-02-28 | 2006-08-23 | 石春沙 | Composite material product of permanent magnetic ferrite material and ceramic material and its producing process |
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| CN1821170A (en) * | 2006-02-28 | 2006-08-23 | 石春沙 | Composite material product of permanent magnetic ferrite material and ceramic material and its producing process |
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