CN101312708A - Compositions and methods for imparting vibrancy - Google Patents

Abstract

Leave-on hair care composition, comprising from about 0.1% to about 20% of a shine enhancing system comprising a first non-soluble particle reflecting a first color, a second non-soluble particle reflecting a second color, and a third non-soluble particle reflecting a third color; from about 0.001% to about 5% of a film-forming agent; and a dermatologically-acceptable carrier.

Description

The compositions and the method that are used for imparting vibrancy

Invention field

The present invention relates to be used for compositions and method to mammiferous hair imparting vibrancy.

Background of invention

The reciprocal action of light and hair is arranged by the outer surface of hair shaft and the reflection at inner surface place usually.The outer surface of hair shaft comprises the flat tabular cell that is called epidermis cell.Epidermis cell is arranged to produce flat-top hairdo effect in eclipsed mode, and this effect exists in quite orderly mode in the virgin hair of health.This pattern generation can cause the diffraction effect and the interference effect of bright prismatic colour.As if the array of color occurs as different color dots, and these color dots are when natural light and hair interaction " unlatching ".When (with the naked eye or by means of amplifier) close examination, can find these colors, and they can produce low-light.A long way off, these colors mix again and form total bright whitish reflection.Therefore, Jian Kang virgin hair shows bright prismatic shine when being illuminated.

When being damaged by the natural microstructure that epidermis cell produced that overlaps or hiding, it is dim or unhealthy that hair can seem.Damage can be produced by multiple source, and these sources comprise for example combing hair and other physical abrasion, and such as chemical treatments such as bleaching and hair-wavings.If natural microstructure is covered by sebum or the material part ground that for example is administered on the hair via shampoo, hair products and/or approved product, it also can lose some in its light interference properties so.For permeating the painted hair of coloring agent with dyestuff and other routine, making us unhappy obfuscation also can be along with the time occurs.Have hair dyed once in consumer's every several weeks of possibility or some months impermanency ground, chroma-luminance or color saturation can weaken between each time handled, thereby cause hair to seem dim.Therefore, needing can be to the hair imparting vibrancy, thereby makes hair have the hair care composition of healthy virgin hair and/or new pigmented hair outward appearance.

Thereby the mode that a kind of reciprocal action of regulating light is improved the collenchyme outward appearance is by using particulate matter.Multiple particulate matter (comprising coated interference pigment) has been used for personal care composition, for example is used for cosmetics and skin care compositions with the covering flaw or in order to produce the more uniform colour of skin.Yet there are some difficulties in the particulate application material on hair.The color of a great variety in hair may comprise from ocean-grey to the atrous scope one or more.Therefore, the bottom substrate that can use compositions thereon is variation more, thereby selects suitable color or color combination to reach just difficulty more of desired effects.In addition, be not intended to bound by theory, granule can agglomeration or " in heaps " when the compositions that will comprise particulate matter is administered on the skin.Yet this is out of question to skin, even can help to provide expectation " covering " beneficial effect, but in fact particulate agglomeration can make the outward appearance deepening of hair.Because the structure different (as mentioned above) of hair and skin, wish that therefore granule forms monolayer and fitly is in line with respect to hair shaft.This makes it possible to and light generation reciprocal action, thereby gives healthy beautiful color, particularly when relevant with motion.Therefore, also need to provide the hair care composition that comprises to the particulate matter combination of hair imparting vibrancy.

Summary of the invention

The present invention has satisfied aforementioned needs by the leave-on hair care composition that comprises blast system and dermatological acceptable carrier (comprising film former) is provided.The blast system comprises at least three kinds of soluble granules.The applicant believes, gloss and color that the compositions that comprises at least three kinds of blast systems can form natural look on being administered to hair the time strengthen.For example, have the visible spectrum of leap by blend and change the great color soluble coloring agent of (perhaps comprising green even blueness) (for example reflective paint), just can realize bright but the gloss of unexpected natural look, can reduce dimness, brass and withered simultaneously.Without being limited by theory, the applicant believes that the seemingly minute surface character of these types of colorants (sticking on the hair of crossing over the wide range of angles orientation) produces the low-light character that simulated light shines upon the mode on the healthy virgin hair.In addition, when selecting pigment color, use multiple distinguishable tone to strengthen the visibility of this natural gloss effect.When the scope of color is enough wide, just realize prismatic effect, wherein when close examination, can see multiple color, be the gloss of brilliant white but these colors are mixed when distant surveillance.This has simulated the effect of sunlight on healthy virgin hair, is highly desirable therefore.The applicant also believes because the hair of color and/or the correlated multiformity vibrancy of gained is complexity or multidimensional, therefore uses the compositions that only comprises one or both coloring agent (soluble or insoluble) and will not give healthy beautiful color on hair.

Non-limiting embodiments more of the present invention are described below.

According to first embodiment of the present invention, a kind of leave-on hair care composition is provided, said composition comprises about 0.1% to about 10% blast system, about 0.001% to about 5% film former and dermatological acceptable carrier.Described blast system comprises the first soluble granule that reflects first color, the second soluble granule of reflection second color and the 3rd soluble granule that reflects the 3rd color.

According to second embodiment of the present invention, a kind of method to mammiferous hair imparting vibrancy is provided, this method comprises the step of using according to the leave compositions of first embodiment on hair.

According to another embodiment of the invention, a kind of cover box is provided, and this cover box comprises at least a compositions according to first embodiment, at least a additional hair care composition and abides by the operation instruction that the hair treatment scheme is used described compositions.

Detailed Description Of The Invention

Though this description be believed by following explanation and can understand the present invention better by particularly pointing out and clearly claimed claim of the present invention is drawn a conclusion.Compositions of the present invention can exist by multiple leave product form, and these forms include but not limited to leave conditioner, approved product, mousse, gel and their combination.

Unless stated otherwise, in all embodiments of the present invention all percentage ratio all by the weight of described total composition.Unless specify that in addition all ratios is weight rate.All scopes are all-embracing and associable.The number of significant digits is neither represented restriction to certainty of measurement is not represented in indicated quantitative limitation yet.Unless otherwise specified, all umerical amounts all are understood that to be modified by " pact " word.All are measured and all to be understood that to carry out under 25 ℃ and environmental condition, and " environmental condition " is meant the condition at an about atmospheric pressure and about 50% relative humidity herein.Except as otherwise noted, all above-mentioned weight relevant with ingredients listed are all based on content of active substance, and do not comprise carrier or by-product in the raw material that may be included in commercially available acquisition.

Herein, " leave " is meant at any remaining set compound that trichoxerosis (comprise and use high temperature, dry up, combing, curl or the step of typing in other words) needn't be rinsed from hair before.

Herein, " strengthen healthy beautiful color " is meant that compositions of the present invention gives complicated gloss to substrate (for example hair), make when the observer with 20/20 vision (uncorrected or corrected) at 10cm or when more the substrate crossed with compositions-treated of the present invention of close-ups and substrate are illuminated, the observer can tell different luminous objects.These objects seem inhomogeneous on color (being tone, saturation and/or brightness), and flicker or shimmer when the observer changes his or her viewing angle.If the substrate of handling (substrate itself or its visual) is exaggerated (for example about 10 times), so different color (variation of tone, saturation and/or brightness) can subjectively be seen clearly and be formed contrast each other, and can be discerned objectively with image analysis tool in color space (for example RGB or HSI)." strengthen healthy beautiful color " is understood to include one or more in the following: increase the weight of hair color, increase (or enhancing) gloss, give and choose and dye (for example than light-colored a few thread hairs of hair) on every side, change hair discernable color, increase luminosity (gray scale gloss), increase saturation and bring out transformation in tone, contrast and/or the low-light (promptly when light, hair or observer move component color dot begin flash of light and stop flash of light).

As used herein, " dermatological acceptable carrier " is meant that carrier is suitable for topical application leave-on hair care composition on collenchyme, and, and will can not cause any safety or toxicity problem with blast system of the present invention and any other component compatibility.

Multiple color model and color space can be used for describing a kind of color of object, and will be known by those skilled in the art.A kind of method of measuring and describing color is found in the The Imaging Processing Handbook of John C.Russ, and the 4th edition, CRC Press, 2002.Each color models/spaces comprises three umerical ingredients, and these ingredients and brightness, the colorful degree of color harmony are relevant.A kind of suitable color models/spaces that is used to describe color is the HSI color model, and wherein tone (" H "), saturation (" S ") and brightness (" I ") character can be used for describing color.HSI visually can be described as two cones of end-to-end arrangement, wherein their bottom and put and their summit is an inverse relationship.Make the model of HSI with cylindrical coordinates.Article one, axis passes juxtaposed cone extension and relevant with brightness, and one of them cone apex is represented white (1,0 coordinate), and another cone apex is represented black (0,0 coordinate).Cone radius or relevant with saturation from the radial size of luminance axis, from 0 to 1 does not wait.When S=0, color is a gray scale.Tone is represented by azimuth, the wherein red tone angular range that generally belongs to 0 ° to 30 ° and 310 ° to 360 °, yellow belongs to 40 ° to 90 ° tone angular range, and green belongs to 70 ° to 160 ° tone angular range, and the blue tone angular range that belongs to 160 ° to 270 °.

As used herein, phrase " different colours ", " different tone " and " the different tones of color " are meant the discernable variation of under given tone angle brightness and/or saturation, and/or the variation of tone angle.When brightness or saturation change at least about 1% the time, or when the tone angle changed to less about 1 °, the difference of color or tone was considered to perceptible.

As used herein, " colour system " is meant according to all colours in the particular shade of color angular range of HSI color space.Red colour system generally belongs to the tone angular range of 0 ° to 30 ° and 310 ° to 360 °.Yellow system generally belongs to 40 ° to 90 ° tone angular range.Green system generally belongs to 70 ° to 160 ° tone angular range.And blue system generally belongs to 160 ° to 270 ° tone angular range.

As used herein, " blast system " is meant three kinds or more kinds of discrete soluble particulate mixture, and wherein " dispersing ", it is indivedual different to be understood to mean.For example, dyestuff will be understood that it is different with soluble colorant.

As used herein, " reflection " is meant that light wherein leaves the reciprocal action of the light and the object of object from the one side/surface that is illuminated." transmission " is meant the reciprocal action that light wherein passes the light and the object of object.As used herein, except as otherwise noted, " reflection " is understood that not only to comprise reflection but also comprise transmission.

As used herein, " transmission " is meant that wherein light is from leaving the reciprocal action of the light and the object of object with isolated one side of a side surface/surface that is illuminated.

As used herein, " soluble granule " and alternatively " soluble coloring agent " is meant the solid matter that can not be dissolved in or can not be dissolved in fully in the dermatological acceptable carrier.

As used herein, " absorption pigment " is meant the coloring agent that is obtained color by the light that absorbs some wavelength rather than other light.Reflected light of being seen or the light that sees through a kind of like this pigment have a kind of color, and this color may not depend on the interactive geometry of pigment and light.

As used herein, " non-absorption pigment " is meant the coloring agent that is obtained color by the interactive geometry of pigment and light.When illuminating under the situation that does not satisfy the required geometric standard of generation color, a kind of like this pigment may present white or approaching colourless.

As used herein, " reflective paint " is meant the coloring agent that obtains outward appearance by reflection (rather than transmission), and typically also with minute surface mode reflected light, thereby the outward appearance of glittering (being also referred to as brilliance, gloss or radiance in some cases) is provided.These pigment can be that absorb or non-absorption.Absorb pigment although term reflective pigment typically is used for describing, and term (for example coated interference pigment) is used to describe non-absorption pigment or had both described absorption pigment and described non-absorption pigment more specifically.

As used herein, " goniochromatic materials (gonichromatic material) " is meant that the angle that depends on observation can reflect or transmission surpasses a kind of any material of color.

As used herein, " luminous pigment " is meant that in wave-length coverage absorbing light sends the pigment of light then in a different wave-length coverage.Fluorescent pigment and phosphorescent pigment are the examples of luminous pigment.

Assay method

Multiple image analysis method can be used for estimating the substrate of crossing with compositions-treated of the present invention.Image analysis typically comprises an image collection step, is one or more analytical procedures subsequently.A kind ofly be used to estimate the image analysis method of crossing with compositions-treated of the present invention of sending out bunch and may further comprise the steps.By replacing the peephole viewer with the digital camera that is contained on the shelf, and the fibre optics lens assembly of replacing on the illumination swing arm with light beam probe unit (being fibre optics condenser lens molectron) improves Flex Products, the direct observation device clinometer of Inc..The xenon arc lamp that use is furnished with light filter cuts off light outside 400 to 700 nanometer range as light source.The all component of light source all derives from Newport Stratford, Inc..With the liquid lightguide lamp is connected to the beam probe lens assembly.The distance far away from about 32cm focuses the light on the hair.A neutral density thin film (25% transmittance) is pasted on the outlet opening of beam probe to weaken the brightness of light, make photographing unit can obtain qualitative picture.On improved observer's shelf, lay digital camera (the Canon EOS-1 Ds Mark II that for example is furnished with the 100mm macro lens).10 grams are sent out bunch vertically be placed under the metallic plate, make the visible sample in hole by intermediary 40mm diameter, and the hair butt is upwards lain low under plate.With respect to the angle of photographing unit with 20 ° of gradient fixed sample clampers (this is a viewing angle).The firewire cable of digital camera is connected to the computer (Microsoft XP platform) of operation EOS Viewer Utility software.With exposure settings is manually, and wherein shutter speed is 1/160, f-number be 4.0 and ISO speed be 400.For first image taking light source is set at 25 ° light angle, then later each image taking is increased progressively with 1 °, reach 65 ° (totally 41 images) up to this angle.Use EOS Capture pattern that image is input in the Viewer software.

Can be with any image analysis step of carrying out in several available software kits.Photoshop (for example version 6.0 or version CS) is a kind of exemplary software package that is applicable to image analysis with Fovea Pro 4.0 plug-in units (ReindeerGraphics).Can be by the many optical parametrics of collected image analysis.A kind of such parameter is an accumulation gray value (IGV).IGV is the result of calculation that can obtain in the standard test instrument relevant with program Optimas.In order to calculate, measuring all pixels of arda sampling, make each gray level (brightness value) multiply by the number of the pixel that is in this gray level, the summation of getting product then.In Photoshop and Fovea Pro, in each image, select onesize resample area, use IP Measure Global＞Histogram plug-in unit to come to obtain to comprise the text of a hurdle pixel counts then for each brightness binary file.Use Microsoft Excel to open these texts, take advantage of these brightness values and calculate summation, the IGV value that calculates is copied to a position, and the figure that draws them then is to obtain to cross over the glossy relatively curve to the angular range of the captured image of each sample.

Can be to comparing of handling with the untreated IGV value of sending out bunch.Compare with tester, the increase of IGV value can be the significant any increase of the statistics that is in 90% confidence level.In preferred embodiments, the cocooning tool of handling of sending out has than untreated contrast object height 10% or more IGV value.

The colorful prismatic effect that the hair of crossing when the virgin hair of health or with compositions-treated of the present invention can be taken place when illuminating by sunlight (or mimic sunlight) near the time (for example in 10cm) visible, and seen as point (speckle, round dot, pixel).In order to measure the appearing and subsiding of these colors when light is crossed hair and moved, can on the pointwise basis, measure these variations.In order to accomplish this point, can use the IP Measure Global＞Profiles plug-in unit among Photoshop and the Fovea Pro. to estimate each visual identical single line of going up pixel in 41 visual groups of forming.That instrument can generate a text, the rgb value of each pixel on line when this document is included in given light angle for each mensuration.In Microsoft Excel, can use standard conversion protocols that these rgb values are converted to L ^*a ^*b ^*Value.Can use the L of same pixel on the consecutive image ^*a ^*b ^*Difference between the value obtains Δ L, Δ a and Δ b value, uses these to be worth then and calculates Δ E (square root sum squares of these three values).In the line Δ E value of all pixels and be that accumulated value to light angle, and a picture group resemble in (40 values) all continuously the figure of right accumulated value be the figure of the change color that when light skims over hair, occurs.Curve fitting (for example via three grades of polynomial trend lines of available standard in Excel, or via Gaussian match instrument) can show the difference of Δ E trend between each sample.To approved for distribution bunch with handled bunch between comparative optimization prove for each pixel comparison at least 1 Δ E---correspondingly accumulating Δ E will be more than or equal to the number of surveying pixel.

The blast system

Compositions of the present invention comprises one or more soluble particulate blast systems that comprises of about 0.1% to about 10%, perhaps about 0.5% to about 8%, perhaps about 0.1% to about 5%, perhaps about 0.1% to about 2%.Soluble granule can have about 1 micron to about 150 microns, perhaps about 1 micron to about 100 microns, perhaps about 1 micron to about 50 microns, perhaps about 5 microns to about 25 microns size.In one embodiment, the blast system is substantially free of dyestuff, is substantially free of to be understood to include to be less than 0.001% herein.

Soluble granule can reflect monochromatic visible light, and this paper is called " monochromatic soluble coloring agent ", maybe can be the goniochromatic coloring agent.Monochrome can belong to redness, yellow (being understood to include golden yellow), blue or green system, as defined herein.

The monochromatic soluble coloring agent of example also comprises the coating particle that comprises one or more core material that applies with one or more coating materials at least in part.Granule can be made by one or more materials.Suitable core materials includes but not limited to natural mica, synthetic mica, graphite, metal-oxide, Talcum, Kaolin, alumina wafer, bismuth oxychloride, silicon dioxide thin slice, pottery, glass, silicate (for example aluminosilicate and borosilicate), titanium dioxide, CaSO ₄, CaCO ₃, BaSO ₄, and their mixture.Substrate can be solid or hollow, natural or synthetic, organic or mineral.In one embodiment, substrate is Muscovitum, ferrum oxide, titanium dioxide, boron nitride, coated interference pigment or their mixture.The suitable coating compounds material includes but not limited to metal and metallic compound.Suitable metal includes but not limited to Ag, Al, Au, Cr, Cu, Ge, Mg, Mo, Ni, Rb, Se, Te, Ti, Va, W, Zn and their alloy.Suitable metallic compound comprises TiO ₂, Fe ₂O ₃, SnO ₂, Cr ₂O ₃, ZnO, ZnS, SnO, ZrO ₂, CaF ₂, Al ₂O ₃, BiOCl, MgF ₂, CrF ₃, ZnSe, SiO ₂, MgO, SeO ₃, SiO, ZrO ₂, CeO ₂, Nb ₂O ₅, Ta ₂O ₅, MoS ₂, and their mixture.Substrate can comprise single coating or multiple coating.

Monochromatic soluble coloring agent can comprise other multiple structure, and wherein each individual course preferably has different refractive indexes.Each layer can for polymer or metal.Can form plural layers and each thin film is divided into discrete element or granule.This type of granule is disclosed in PCT patent application WO99/36477 and United States Patent (USP) 6,299,979 and 6,387,498.The reflection grain that comprises two layers of polymers at least by 3M with trade name MirrorGlitter ^TMSell.Only for example, these layers can be made by following polymer: PEN (PEN) and isomer thereof, for example 2,6-, 1,4-, 1,5-, 2,7-and 2,3-PEN, the polyalkylene terephthalate, polyimides, polyimide, random polystyrene, Merlon, many alkylmethacrylates and many alkyl acrylates, syndiotactic polystyrene, syndiotaxy gathers-α-Jia Jibenyixi, the syndiotaxy polydichlorstyrene, the copolymer of these polystyrene and blend, cellulose derivative, polyalkylene polymer, fluoropolymer polymer, the chlorine polymer, polysulfones, polyether sulfone, polyacrylonitrile, polyamide, silicone resin, epoxy resin, polyvinyl acetate, polyetheramides, ionomer resin, elastomer, the copolymer of polyurethane and analog.

Monochromatic soluble coloring agent also comprises luminous pigment, for example fluorescent pigment and phosphorescent pigment.Other monochromatic soluble coloring agent known in the art can be used for the present invention.

Suitable goniochromatic materials comprises multi-coated interference structure, liquid crystal stain and/or photonic crystal.Goniochromatic materials comprises one or more core material and two-layer or more multi-layered coating material, and they all are described in above.Coating material can be for each layer identical or each layer difference.

An example of goniochromatic materials is a coated interference pigment.Herein, " coated interference pigment " is meant one type coated interference pigment with feature reflection colour.For the purpose of this description, coated interference pigment is defined as containing the granule with differing refraction indices of two or more controlled thickness layers.Coated interference pigment by two kinds on classic ground of the granule of different layers (they can for thin with tabular) but the once in a while interference effect of more kinds of luminous reflectance produces the feature reflection colour.The limiting examples that is used for the suitable interference pigments of compositions of the present invention comprises the base matrix granule, and this granule is made of natural or synthetic mica, borosilicate glass, silicon dioxide and their mixture.Use TiO ₂, silicon dioxide, stannum oxide, ferrum oxide and their mixture the thin film stratification, wherein the thickness of each layer is about 50nm about 300nm extremely.

Available coated interference pigment can be commercially available from a large amount of suppliers, and these suppliers comprise for example Rona (Timiron ^TM), Sensient (Covapearl ^TM), Englehard (Flamenco ^TM), Kobo (KTZInterval ^TMAnd Interfine ^TM) and Eckart (Prestige ^TM).In a non-limiting embodiments, coated interference pigment has about 5 microns to about 75 microns in the longest direction, and perhaps about 5 microns to about 25 microns, perhaps about 10 to about 20 microns independent particulate average diameter.

Also can use the goniochromatic materials with multiple structure, this multiple structure comprises for example alternating polymer layer of PEN and polyethylene terephthalate type.This type of stain is described in PCT patent application WO-A-96/19347 and WO-A-99/36478.

Available pigment with polymer multi-layer structure comprises those that sold with trade name Color Glitter by 3M.The liquid crystal stain for example comprises the siloxanes or the cellulose ether of the mesomorphic base of grafting on it.The particulate example of available liquid crystal goniochromatic for example comprises those that sold by Chenix, and also comprises by Wacker with trade name Helicone

Those products that HC sells.Interference fibers with multiple structure can be used as the blast system.The case description of this fibrid is in european patent application 921,217 and 686,858 and United States Patent (USP) 5,472,798.Multiple structure can comprise two-layer at least, and wherein each layer (can maybe cannot be independent of other layer) made by at least a synthetic polymer.The polymer that is present in the fiber can have 1.30 to 1.82, the refractive index in preferred 1.35 to 1.75 scopes.The polymer that is preferred for making fiber is a polyester, as polyethylene terephthalate, PEN, Merlon; Acrylic polymer is as polymethyl methacrylate; Polyamide.Goniochromatic fibers with polyethylene terephthalate/nylon-6 double-layer structure is sold with trade name Morphotex by Teijin.

In one embodiment, blast system comprises reflective paint, coated interference pigment (being with or without basic color), effect pigment, mobile pigment, spiral pigment changeable colors along with angle, pearlescent pigment, luminous pigment, fluorescent colorant, is considered to other multiple structure and aforementioned any mixture of monochromatic soluble coloring agent or goniochromatic materials (those terms as used herein).

The surface that can improve the blast system is to improve for example stability, the compatibility, to send and deposit.A kind ofly improve one's methods that the surface is become is hydrophobic.The limiting examples of suitable hydrophobic surface treatments comprises adds siloxanes, acrylate silicone copolymers, acrylate polymer, alkyl silane, three isostearic acid titanium isopropyl esters, sodium stearate, magnesium myristate, perfluor alcohol phosphate ester, the poly-methyl isopropyl ether of perfluor, lecithin, Carlow crust wax, polyethylene, chitosan, lauroyl lysine, cerolipoid extract and their mixture.

The exemplary blast system that comprises pigment composition is shown in following table 1.Some mixture comprise the combination of reflective paint, and some comprises the combination of reflective paint and coated interference pigment, and some comprises the combination of dissimilar coated interference pigments.Table 1 comprises that name is called a hurdle of " color ".This reference color is to note by the subjective visual inspection to material.The color that is used for reflective paint generally belongs to red, yellow, green or blue system, golden yellow herein a member that is considered to yellow system.When the listed color that is used for coated interference pigment was indicated as " white " or " pearl ", coated interference pigment did not significantly reflect the color that belongs to one of above-mentioned colour system.

Table 1

Sequence number	The blast system	Supplier	Colour system
				1	1％ Covapearl TM Bright 933 AS 1.4％ Cloisonne TM Cerise Flambe 1.4％ Cloisonne TM Imperial Gold 0.7％ Cloisonne TM Blue 0.7％ Cloisonne TM Green	SENSIENT ENGELHARD ENGELHARD ENGELHARD ENGELHARD	White is red yellow blue green
2	1％ Covapearl TM Bright 933 AS 1.4％ Chroma-Lite TM Red 1.4％ Chroma-Lite TM Yellow 0.7％ Chroma-Lite TM Dark Blue 0.7％ Chroma-Lite TM Green	SENSIENT ENGELHARD ENGELHARD ENGELHARD ENGELHARD	White is red yellow blue green
				3	2.5％ Covapearl TM Bright 933 AS 0.9％ KTZ Xian Vistas 0.9％ Cloisonne TM Imperial Gold 0.9％ Colorona TM Bright Gold	SENSIENT KOBO ENGELHARD EMD/RONA	White gold is yellow golden yellow

4	1.2％Covapearl TM Bright 933AS 1.2％KTZ Xian Vistas 1.2％Colorona TM Bright Gold 0.8％Chroma-Lite TM Red 0.4％Chroma-Lite TM Green 0.4％Chroma-Lite TM Dark Blue	SENSIENT KOBO EMD/RONA ENGELHARD ENGELHARD ENGELHARD	White gold is yellow golden yellow red green blue
				5	1％Prestige TM Bright Silver 1.25％Sicopearl TM Fantastico Gold 1.5％Sicopearl TM Fantastico Ruby 0.85％Sicopearl TM Fantastico Green 0.85％Sicopearl TM Fantastico Rose	ECKART BASF BASF BASF BASF	White gold is yellow red green red
6	1％ Covapearl TM Bright 933AS 1.4％Desert Reflections Canyon Sunset 1.4％Desert Reflections Sunlit Cactus 0.7％Desert Reflections Painted Desert Plum 0.7％Desert Reflections Midnight Sagebrush	SENSIENT ENGELHARD ENGELHARD ENGELHARD ENGELHARD	White orange green green
				7	1％Covapearl TM Bright 933AS 1.4％Duocrome TM YR 1.4％Duocrome TM YB 0.7％Duocrome TM GY 0.7％Duocrome TM BV	SENSIENT ENGELHARD ENGELHARD ENGELHARD ENGELHARD	White is yellow golden yellow green blue
8	2％Covapearl TM Bright 933AS 2％Covapearl TM Dore Gold 232 AS 0.6％Covapearl TM Blue 635 AS 0.6％Covapearl TM Fire Red 333AS	SENSIENT SENSIENT SENSIENT SENSIENT	The yellow white of white is red
				9	2％KTZ Interfine TM Gold 2％KTZ Xian Vistas 0.6％KTZ Interfine TM Blue 0.6％KTZ Interfine TM Red	KOBO KOBO KOBO KOBO	The golden yellow pearl pearl of pearl

10	2.67％Timiron TMSilk Gold 1.27％Timiron TM Silk Blue 1.27％Timiron TM Silk Red	EMD/RONA EMD/RONA EMD/RONA	Pearl white white
				11	2％Sicopearl TM Fantastico Gold 2％Sicopearl TM Fantastico Ruby 0.6％Sicopearl TM Fantastico Green 0.6％Sicopearl TM Fantastico Rose	BASF BASF BASF BASF	Golden yellow red green red
12	2％Covapearl TM Bright 933AS 1％Sicopearl TM Fantastico Gold 1％Sicopearl TM Fantastico Ruby 0.6％Sicopearl TM Fantastico Green 0.6％Sicopearl TM Fantastico Rose	SENSIENT BASF BASF BASF BASF	White gold is yellow red green red
				13	1.6％Covapearl TM Bright 933AS 1.2％Covapearl TM Dore Gold 232AS 1.2％KTZ Interfine TM Red 0.6％KTZ Interfine TM Blue 0.6％Sicopearl TM Fantastico Green	SENSIENT SENSIENT KOBO KOBO BASF	The yellow pearl pearl green of white
14	1.2％Covapearl TM Bright 933AS 1％Sicopearl TM Fantastico Gold 1％Sicopearl TM Fantastico Ruby 1％KTZ Xian Vistas 0.5％KTZ Interfine TM Blue 0.5％KTZ Interfine TM Red	SENSIENT BASF BASF KOBO KOBO KOBO	The yellow red golden yellow pearl pearl of White gold
				15	1％Covapearl TM Bright 933AS 1.25％Sicopearl TM Fantastico Gold 1.25％SicopearI TM Fantastico Ruby 0.85％Sicopearl TM Fantastico Green 0.85％Sicopearl TM Fantastico Pink	SENSIENT BASF BASF BASF BASF	White gold is yellow red green red

16	0.6％Covapearl TM Bright 933AS 0.75％Sicopearl TM Fantastico Gold 0.75％Sicopearl TM Fantastico Ruby 0.51％Sicopearl TM Fantastico Green 0.51％Sicopearl TM Fantastico Rose	SENSIENT BASF BASF BASF BASF	White gold is yellow red green red
				17	0.2％Covapearl TM Bright 933AS 0.25％Sicopearl TM Fantastico Gold 0.25％Sicopearl TM Fantastico Ruby 0.17％Sicopearl TM Fantastico Green 0.17％Sicopearl TM Fantastico Rose	SENSIENT BASF BASF BASF BASF	White gold is yellow red green red
18	1％Covapearl TM Bright 933AS 0.5％Covapearl TM Dore Gold 232AS 1％Sicopearl TM Fantastico Gold 0.85％Sicopearl TM Fantastico Ruby 0.425％Sicopearl TM Fantastico Green 0.425％Sicopearl TM Fantastico Rose 0.5％KTZ Xian Vistas 0.5％Timiron TMMP-20Fine Gold	SENSIENT SENSIENT BASF BASF BASF BASF KOBO EMD/RONA	White is yellow golden yellow red green red golden yellow yellow
				19	l％Covapearl TM Bright 933AS 1.0％Timiron MP-20Fine Gold 0.75％Covapearl TM Dore Gold 232AS 0.75％Sicopearl TM Fantastico Gold 0.75％KTZ Xian Vistas 0.48％Sicopearl TM Fantastico Ruby 0.25％Sicopearl TM Fantastico Green 0.25％Sicopearl TM Fantastico Rose	SENSIENT EMD/RONA SENSIENT BASF KOBO BASF BASF BASF	White gold is yellow golden yellow golden yellow red green red

20	1％Covapearl TM Bright 933AS 0.35％Sicopearl TM Fantastico Gold 0.85％Sicopearl TM Fantastico Ruby 0.40％Sicopearl TM Fantastico Green 0.85％Sicopearl TM Fantastico Rose 0.3％Colorona TM Bronze Fine 0.3％Colorona TM Sienna Fine 0.3％Colorona TM Copper Fine 0.85％Xirona Indian Summer	SENSIENT BASF BASF BASF BASF EMD/RONA EMD/RONA EMD/RONA EMD/RONA	White gold is yellow red green red red
				21	1％Covapearl TM Bright 933AS 1.4％Gemtone Ruby 1.4％Gemtone Topaz 0.7％Gemtone Sapphire 0.7％Gemtone Jade	SENSIENT ENGELHARD ENGELHARD ENGELHARD ENGELHARD	White is red green blue green
22	1％Covapearl TM Bright 933AS 1.4％Cellini Red 1.4％Cellini Yellow 0.7％Cellini Blue 0.7％Cellini Green	SENSIENT ENGELHARD ENGELHARD ENGELHARD ENGELHARD	White is red yellow blue green
				23	1％Timica Extra Bright 1.25％Sicopearl TM Fantastico Gold 1.25％Sicopearl TM Fantastico Ruby 0.85％Sicopearl TM Fantastico Green 0.85％Sicopearl TMFantastico Rose	ENGELHARD BASF BASF BASF BASF	White gold is yellow red green red
24	1％Timiron TM Artic Silver 1.25％Sicopearl TM Fantastico Gold 1.25％Sicopearl TM Fantastico Ruby 0.85％Sicopearl TM Fantastico Green 0.85％Sicopearl TM Fantastico Rose	EMD/RONA BASF BASF BASF BASF	Pearl is golden yellow red green red

25	1％Flamenco Superpearl 1.25％Sicopearl TM Gold 1.25％Sicopearl TM Ruby 0.85％Sicopearl TM Green 0.85％Sicopearl TM Rose	ENGELHARD BASF BASF BASF BASF	Golden yellow red green red
				26	1％Covapearl TM Bright 933AS 1.4％Cloisonne TM Cerise Flambe 1.4％Covapearl TM Fire Red 333AS 0.7％Cloisonne TM Rouge Flambe 0.7％Cellini Red	SENSIENT ENGELHARD SENSIENT ENGELHARD ENGELHARD	White is red
27	1％Covapearl TM Bright 933AS 0.8％Cloisonne TM Cerise Flambe 0.8％Cloisonne TM Imperial Gold 0.4％Cloisonne TM Blue 0.4％Cloisonne TM Green 0.8％Covapearl TM Red 333AS 0.5％Cellini Red 0.5％Cloisonne TM Rouge Flambe	SENSIENT ENGELHARD ENGELHARD ENGELHARD ENGELHARD SENSIENT ENGELHARD ENGELHARD	White is red yellow blue green red red
				28	1％Covapearl TM Bright 933AS 1％Timica Golden Bronze 1.2％Cloisonne TMCerise Flambe 1.2％Covapearl TM Fire Red 333AS 0.5％Cloisonne TM Rouge Flambe 0.5％Cellini Red	SENSIENT ENGELHARD ENGELHARD SENSIENT ENGELHARD ENGELHARD	White is red
29	1％Covapearl TM Bright 933AS 1％Cloisonne TM Nu-Antique Copper 1.2％Cloisonne TM Cerise Flambe 1.2％Covapearl TM Fire Red 333AS 0.5％Cloisonne TM Rouge Flambe 0.5％Cellini Red	SENSIENT ENGELHARD ENGELHARD SENSIENT ENGELHARD ENGELHARD	White is red

30	2.5％Mearlmaid AA 0.9％KTZ Xian Vistas 0.9％Cloisonne TM Imperial Gold 0.9％Colorona TM Bright Gold	ENGELHARD KOBO ENGELHARD EMD/RONA	Pearl is golden yellow yellow golden yellow
				31	2.5％Mearlmaid BU 0.9％KTZ Xian Vistas 0.9％Cloisonne TM Imperial Gold 0.9％Colorona TM Bright Gold	ENGELHARD KOBO ENGELHARD EMD/RONA	Pearl is golden yellow yellow golden yellow
32	1.0％CovaPearl TM Bright 933AS 1.4％KTZ Xian Vistas 1.4％KTZ Bolero Cromatico 0.5％KTZ Foliage Flutter 0.5％KTZ Winterveld 0.4％KTZ Jaipur Sunset	SENSIENT KOBO KOBO KOBO KOBO KOBO	White gold is yellow red red
				33	1.0％Covapearl TM Bright 933AS 1.4％DGl4 DermaGlow TM Fire Orange 1.4％DGY410 DermaGlow TM Yellow 410 0.7％DGP20 Cosmetic Phosphorescent Pigment 0.7％DG-20DermaGlow TM Venetian Violet	SENSIENT DAYGLO COLOR DAYGLO COLOR DAYGLO COLOR DAYGLO COLOR	White is red yellow green blue
34	1％Prestige TM Soft Silver 1.25％Sicopearl TM Fantastico Gold 1.25％Sicopearl TM Fantastico Ruby 0.85％Sicopearl TM Fantastico Green 0.85％Sicopearl TM Fantastico Pink	ECKART BASF BASF BASF BASF	White gold is yellow red green red

35	1％Prestige Silver Star 1.25％Sicopearl TM Fantastico Gold 1.25％Sicopearl TM Fantastico Ruby 0.85％Sicopearl TM Fantastico Green 0.85％Sicopearl TM Fantastico Pink	ECKART BASF BASF BASF BASF	White gold is yellow red green red
				36	1％Prestige Bright Silver Star 1.25％Sicopearl TM Fantastico Gold 1.25％Sicopearl TM Fantastico Ruby 0.85％Sicopearl TM Fantastico Green 0.85％Sicopearl TM Fantastico Pink	ECKART BASF BASF BASF BASF	White gold is yellow red green red
37	2.6％KTZ Interfine TMBlue 2.6％KTZ Interfine TM Gold	KOBO KOBO	Blue yellow
				38	2.6％KTZ Interfine TM Blue 2.6％KTZ Interfine TM Green	KOBO KOBO	Blue green
39	2.6％KTZ Interfine TM Blue 2.6％KTZ Interfine TM Red	KOBO KOBO	Blue red
				40	2.6％KTZ Interfine TM Gold 2.6％KTZ Interfine TM Green	KOBO KOBO	Yellow green
41	2.6％KTZ Interfine TM Gold 2.6％KTZ Interfine TM Red	KOBO KOBO	Yellow red
				42	2.6％KTZ Interfine TM Green 2.6％KTZ Interfine TM Red	KOBO KOBO	Green red
43	1.7％Colorona TM Blackstar Gold 1.7％Colorona TM Blackstar Red 0.9％Colorona TM Blackstar Blue 0.9％Colorona TM Blackstar Green	EMD/RONA EMD/RONA EMD/RONA EMD/RONA	Golden yellow red blue green
				44	1.74％Colorona TM Bronze Fine 1.74％Colorona TM Copper Fine 1.74％Colorona TM Sienna Fine	EMD/RONA EMD/RONA EMD/RONA

45	1.74％Colorona TM Bright Gold 1.74％Colorona TM Red Gold 1.74％Colorona TM Dore Gold	EMD/RONA EMD/RONA EMD/RONA	Golden yellow yellow
				46	1.74％Timica TM Golden Bronze 1.74％Timica TM Nu-Antique Bronze 1.74％Timica TM Nu-Antique Copper	ENGELHARD ENGELHARD ENGELHARD
47	1.74％Cloisonne TM Sparkle Bronze 1.74％Cloisonne TM SpaTkle Copper 1.74％Duocrome TM Sparkle BR	ENGELHARD ENGELHARD ENGELHARD
				48	1.74％Lowa TM Color Variable Pearls Peony OG73 1.74％Lowa TM Starlight Sparkle Orange 1.74％Lowa TM Starlight Sparkle Golden	ARYSTA ARYSTA ARYSTA	Red golden yellow
49	1.0％Synmica TM Super 1.2％Sunshine Glitter Khaki Gold 1.2％Sunchroma TM D&C Red 7Ca Lake 1.0％Sunshine Super Deep Blue 1.0％Soft-Tex TM Brown Iron Oxide	SUN CHEMICAL SUN CHEMICAL SUN CHEMICAL SUN CHEMICAL SUN CHEMICAL	White gold is yellow red blue
				50	1.0％Synmica TM Super 1.4％C37-038D&C Red Al Lake 1.4％C23-009D&C Red 36 1.4％Sunchroma TM D&C Red No.6Ba Lake	SUN CHEMICAL SUN CHEMICAL SUN CHEMICAL SUN CHEMICAL	White is red red
51	1.0％Synmica TM Super 1.1％Soft-Tex TM D&C Red 7Ca Salt 1.0％Sunchroma TM D&C Red 21Al Lake 1.1％Sunchroma TM D&C Red 7Ca Lake (lot 5A9606) 1.0％Sunchroma TM D&C Red 7Ca Lake (lot 591133)	SUN CHEMICAL SUN CHEMICAL SUN CHEMICAL SUN CHEMICAL SUN CHEMICAL	White is red

Reflection comprises that the pigment composition of redness, yellow, green and blue a series of colors or four corner color can be used for being suitable for the hair care composition of the consumer of any base hair color (for example golden hair, hair color, red etc.).Yet the applicant believes that some examples are more suitable for being administered on the special base hair color.For example, in one embodiment, being used in mixture in the compositions of planning to be administered on the light hair (for example golden hair or light brown hair) goes up substantially and does not contain the pigment with blue base color, because blueness may form contrast with the base hair color background and be seen, and may make hair seem not beautiful or unclean.

The applicant believes that also the pigment composition with different tones of monochromatic system is applicable to some base hair color, for example golden hair or red.This type of mixture preferably comprises coated interference pigment.In this case, combine with the additional color enhancing that is used for red color tone and gold tone hair by the gloss of aforesaid prismatic effect, but keep low-light and color expectation.The applicant believes, selects multiple tone extremely important for the visibility that strengthens this effect in monochromatic system.

Refer again to table 1, embodiment that is applicable to the red color tone hair is to comprise five kinds of different reflective paint being included in the red colour system and a kind of No. 29 mixture of coated interference pigment.Embodiment that is applicable to the gold tone hair is to comprise three kinds of different reflective paint being included in the yellow system and a kind of No. 3 mixture of coated interference pigment.An embodiment that is applicable to dark-brown and/or black tone hair is to comprise golden yellow, redness, blueness or green direct reflection and brown or irreflexive No. 43 mixture of black.

The pigment composition that is included in the table 1 only is exemplary, and other pigment composition can be used in according in the hair care composition of the present invention.

Dermatological acceptable carrier compositions of the present invention comprises about 50% to about 99.9% dermatological acceptable carrier.In one embodiment, the dermatological acceptable carrier is aqueous carrier and comprises water, described water can choose wantonly comprise other liquid can dissolve each other with water or water miscible solvent such as lower alkyl alcohol, for example C ₁-C ₅Alkyl monocarbon alcohol or C ₂-C ₃Alkylol.

Other suitable carriers includes but not limited to water, silicone oil, organic solvent such as C ₁-C ₆Alkanol, carbitol, acetone and their combination.Appropriate C ₁-C ₆The instantiation of alkanol includes but not limited to ethanol, normal propyl alcohol, isopropyl alcohol, n-butyl alcohol, amylalcohol and their mixture.Other suitable carriers comprises the emulsion that contains water and oil phase.These oil can be derived from animal, plant or oil, can be for natural or synthetic, and can comprise silicone oil.Emulsion carriers includes but not limited to oil-in-water, Water-In-Oil, W/O/W and water-in-silicone bag fat liquor.

In one embodiment, compositions comprises and is less than 5%, perhaps is less than one or more surfactants of 2%.Alternatively, compositions is substantially free of surfactant, " is substantially free of " to be interpreted as and to be meant and to be less than one or more surfactants of 1% herein.

Film former

Compositions of the present invention comprises about 0.001% to about 5% film former, can be used for promoting the blast system sedimentation on multiple substrate and do not have significant agglomeration.Suitable film former includes but not limited to copolymer, the osamine of siloxanes film forming polymer, siloxysilicates, poly methyl silsesquioxane, siloxanes/(methyl) acrylate copolymer, silicone esters, vinyl pyrrolidone and long-chain olefin and comprises the polymer of osamine.

In one embodiment, film former comprises one or more osamines (being also referred to as amino sugar).As used herein, " osamine " is meant the amine derivative of hexose.The example that can be used for osamine of the present invention comprises glycosamine, N-acetyl glucosamine, mannosamine, N-acetyl group mannosamine, galactosamine, N-acetyl group galactosamine and their mixture.In one embodiment, osamine is the N-acetyl glucosamine.In one embodiment, compositions comprises about 0.001% to about osamine of 1%, perhaps about 0.01% to about 0.5%.Alternatively, the ratio of the percentage ratio of the percentage ratio of brightener and film former is about 10: 1.

Optional components

Compositions of the present invention can comprise various optional components, comprising the component that is used for any kind of leave hair care product known in the art.Optional components includes but not limited to siloxanes, natural gum, resin, solvent, except about described soluble granule, surfactant, dispersing aid, deposition aid, propellant, wetting agent and the conditioner those of blast system.Other optional components comprises the fixedly polymer of hair; Detersive surfactant is as anion, nonionic, both sexes and zwitterionic surfactant; Thickening agent and suspending agent are as xanthan gum, guar gum, hydroxyethyl-cellulose, methylcellulose, hydroxyethyl-cellulose, starch and starch derivatives; Viscosity modifier is as the methanol amide of long-chain fatty acid; Crystalline suspending agent; Pearlescent additive is as glycol distearate; Antiseptic is as benzylalcohol, methyl parahydroxybenzoate, propyl p-hydroxybenzoate and imidazolidinyl urea; Polyvinyl alcohol; Ethanol; The pH regulator agent is as citric acid, sodium citrate, succinic acid, phosphoric acid, sodium hydroxide, sodium carbonate; Salt is as potassium acetate and sodium chloride; The hair oxidant is as hydrogen peroxide, perborate and persulfate; The hair Reducing agent is as thioglycolate salt; Spice; Intercalating agent is as disodiumedetate; Polymeric plasticizer is as glycerol, diisobutyl adipate, butyl stearate and propylene glycol.

Compositions of the present invention can comprise setting agent and be used for helping typing, for example combing, drying, dry up, heat, curl (using or do not use high temperature) etc.The limiting examples of suitable setting agent comprises poly alkylene glycol, polyethylene/polypropylene glycol copolymer, the polyethylene/polypropylene diol copolymer, polyglycereol, the polysaccharide styling polymer, polyvinylpyrrolidone (PVP), the copolymer of PVP and methylmethacrylate, the copolymer of PVP and vinyl acetate (VA), polyvinyl alcohol (PVA), the copolymer of PVA and .beta.-methylacrylic acid, the copolymer of PVA and maleic anhydride, hydroxypropyl cellulose, hydroxypropyl guar gum, kayexalate, PVP/ ethyl methacrylate/metering system acid ter-polymer, vinyl acetate/.beta.-methylacrylic acid/vinyl neodecanoate copolymer, octyl acrylamide/acrylate copolymer, single ethyl ester of polymethyl vinyl ether-maleic acid, and octyl acrylamide/acrylate/methacrylate butyl amino ethyl ester copolymer, acrylic acid/tert-butyl acrylate copolymer, methacrylate dimethylaminoethyl/methacrylate isobutyl ester/2-methacrylate Octyl Nitrite terpolymer, tert-butyl acrylate/acrylic copolymer, with polysiloxane grafted terpolymer, tert-butyl acrylate/acrylic acid/PDMS for example, and their mixture.

The limiting examples of suitable polysaccharide styling polymer comprises anion polysaccharide, cationic polysaccharide and their mixture.The cationic polysaccharide styling polymer includes but not limited to the copolymer (being called polyquaternary ammonium salt-4 by CTFA in the industry) of hydroxyethyl-cellulose and diallyldimethylammonium chloride, as can trade name CELQUAT (for example CELQUAT L-200 and CELQUAT H-100) from National Starch, Bridgewater, those that New Jersey is commercially available; Contain quaternary ammonium polymer with cation, comprise the epoxide reactive homopolymer (being called polyquaternary ammonium salt-10 by CTFA) that for example hydroxyethyl-cellulose and trimethyl ammonium replace in the industry, as can trade name UCARE (for example UCARE POLYMER JR-400 and UCARE POLYMER LR-400) from AmercholCorp., Edison, those that New Jersey is commercially available, and can trade name CELQUAT (CELQUAT SC 230 and CELQUAT SC 240) from National Starch, Bridgewater, those that New Jersey is commercially available.Also can use nonionic cellulose derivatives, as methyl and hydroxy alkyl cellulose.For example, with multiple trade name (for example by Aqualon with Natrosel and by Union Carbide with Cellosize) hydroxyethyl-cellulose sold, derive from the methylcellulose of DowChemical Company and derive from the hydroxypropyl emthylcellulose of Aqualon.

Compositions of the present invention can also comprise one or more conditioners.Exemplary conditioner comprises cationic crosslinked polymeric conditioning agents and silicone conditioning agent, as is described in United States Patent (USP) 5,674, those of 478 (comprising those conditioners that are disclosed in the reference of incorporating into wherein).Cationic crosslinked polymeric conditioning agents can be described by following general formula: (A) _m(B) _n(C) _pWherein (A) is propenoic acid dialkyl aminoalkyl ester monomer or its quaternary ammonium or acid-adducting salt, (B) be methacrylate dialkyl aminoalkyl ester monomer or its quaternary ammonium or acid-adducting salt, (C) be can with (A) or (B) polymeric non-ionic monomer, m is 0 or bigger integer, n is 0 or bigger integer, and p is 0 or bigger integer, and wherein m or n or both sides are necessary for 1 or bigger.Silicone conditioning agent can comprise polydimethylsiloxane, poly-alkylsiloxane, poly-aryl siloxanes, polyoxyethylene alkyl aryl radical siloxane and polyether siloxane copolymer.Additional exemplary conditioner comprises the low melting point aliphatic alcohol, for example unsaturated monobasic straight-chain fatty alcohol, saturated branched fatty alcohol, saturated C ₈-C ₁₂Straight-chain fatty alcohol and their mixture.Other exemplary conditioner comprises for example cationic surfactant, cationic polymer, non-volatile siloxane (comprising solvable and insoluble siloxanes), fixed hydrocarbon, saturated C ₁₄To C ₂₂Straight-chain fatty alcohol, fixed hydrocarbon ester and their mixture.

The included example of this paper can also provide optional components to the degree that does not above have to describe.Should understand, except optional components mentioned above or that be included in the example those also can be used in according in the compositions of the present invention.

Using method

Compositions of the present invention can be administered on wet hair or the dried hair.In one embodiment, compositions is administered on the wet hair.In addition or alternatively, handled before compositions can being administered to, for example " scalded " (impermanency ground curls or does waviness), stretching, dye and/or stand on the hair of the permanent or impermanency processing of other type.In addition or alternatively, compositions can be administered on the damaged hair, for example dry, crisp, dim, curl, have the hair of hair bifurcated and/or in other words for example by being exposed to high temperature, ultraviolet radiation, environmental chemicals, chemicals inferior etc. on the impaired hair.The amount of being used will be according to changing such as factor such as the desired amount of hair length and vibrancy, gloss etc., yet an example of typical amount can comprise the compositions of about 1g to about 10g.Can use compositions in several ways, these modes comprise with palm, with finger tip, spraying, directly are extruded on the hair or use such as instruments such as comb, brush, sponges.Compositions can also be administered to any part of hair, for example be administered to hair, be administered to hair, or be administered to the enhanced any part of expectation vibrancy of hair away from the part of scalp near the part of scalp.

After using, plan to make compositions to stay on the hair up to washing next time.After using, can make the hair natural drying, or for example by combing, brush, with cold or hot air drying, curl (with or without high temperature), stretching, tie up or in other words fix etc. its moulding.

The cover box

Compositions of the present invention can form the part of cover box.The cover box can comprise the packaging unit that contains at least a compositions described herein, outer package unit for example, and this unit can comprise one or more inner packing unit then.Inner packing unit and outer package unit can be for being suitable for comprising, present and/or the not impaired any kind of content of appropriate protective sleeve box.Alternatively, the cover box can comprise and is sold to row's product that consumer or professional use in hair salon individually.

Except one or more additive compositions and/or assembly, the cover box can also comprise one or more compositionss as herein described.The example of suitable additional compositions includes but not limited to hair dyes and coloring agent, bleaching hair or light color agent, shampoo, conditioner and/or setting agent.The example of add-on assemble comprise instrument, application device, comb, brush, typing auxiliary agent, ornament, one or more can be oral dietary supplement, send the operation instruction of intensifier (for example ultrasound wave and/or electronic installation), device etc.The cover box can also be for example comprises compositions of the present invention and the additive composition of cover box and/or the operation instruction of assembly as the part of hair treatment scheme.For example, these explanations can pass on first hair care composition that contains the coloring agent that can permeate hair shaft use, contain the use of second hair care composition of brightener, and pass on the frequency of using first and second hair care compositions.Alternatively, processing scheme can comprise hair washing, hair care, rinsing hair, use the compositions that comprises brightener, shaping hair and aforementioned any one the step of combination.Alternatively, processing scheme can comprise to using oxidant or other coloring agent on the hair and use the step of compositions of the present invention on hair, and it is greater or lesser that the frequency ratio of wherein using compositions of the present invention on hair is used the frequency of coloring agent.Only explanation for example, can consumption guidance person or professional stylist on hair, used once oxidation agent or other coloring agent in per 6 months, and use once compositions of the present invention every month.

Embodiment

Embodiment 1: be suitable for the hair styling product by one or more methods uses as herein described Can be prepared as follows:

Component	Expection percentage by weight (%) in the finished product
		Water	In right amount
The blast system 1	5.000
		Acrylate/Beheneth-25 methacrylate copolymer (Aculyn-28)	3.000

Hydroxyethyl-cellulose (HHR250)	0.666
		Laureth-23	0.600
Acetyl glucosamine	0.500
		Benzylalcohol	0.500
The amino methyl propanol	0.316
		DMDM Hydantoin (1,3-dihydroxymethyl-5,5-dimethyl hydantoin)	0.370
Aloe	0.250
		Disodiumedetate	0.115
Spice	0.100
		Nicotiamide	0.010
The DL pantothenylol	0.020
		General benzyl ethyl ether	0.090

¹Except described other blast system in this paper other places, can also use any example of the described suitable blast system of table 1.

In mixer, add entry and make it reach the suitable temperature that is used to make the hair-care approved product, begin then to stir.Add disodiumedetate and DMDM Hydantoin, continue then to mix.Add acrylate/Beheneth-25 methacrylate copolymer, mix till homodisperse then.Emulsify perfume and general benzyl ethyl ether add in the major ingredient then in hot laureth-23.Add nicotiamide and acetyl glucosamine, and guarantee that solid dispersion is even.Add benzylalcohol and DL pantothenylol.Add hydroxyethyl-cellulose, mix up to homodisperse then and till not having fritter.In producing liquid stream, add the blast system, mix till homodisperse then.In mixer, add the amino methyl propanol, continue then to mix till batch of material evenly.The amount of amino methyl propanol that can regulate adding is to be controlled at pH the level of expectation.Compositions is administered on clean wet the sending out.Do not rinse or remove excessive compositions before the infra once washing from hair.Typing as required.

Embodiment 2: be suitable for the hair care agent used by one or more methods as herein described can as Following preparation:

Component	Expection percentage by weight (%) in the finished product
		Water	In right amount
The blast system 1	2.000
		L-glutamic acid	0.640
The amino propyl group dimethylamine (SAPDMA) of stearoyl	2.300
		Spermol	2.500
Stearyl alcohol	4.500
		Polydimethylsiloxane/ring-type polymethyl siloxane (Cyclomethicone) (15/85 blend)	4.200
Ethylenediaminetetraacetic acid (EDTA)	0.100
		Benzylalcohol	0.400
Isothiazolone CG	0.0005
		The general benzyl ethyl ether of dl-	0.050
The dl-pantothenylol	0.050

¹Except described other blast system in this paper other places, can also use any example of the described suitable blast system of table 1.

In suitable mixer, following formation lamellar gel matrix: obtain the deionized water of about 85 ℃ of temperature, add the amino propyl group dimethylamine of stearoyl, spermol, stearyl alcohol and L-glutamic acid then.Mixture is maintained at about 85 ℃ temperature 5 minutes, makes each composition homogenize and do not observe solid.Described mixture is cooled to about 55 ℃, remains on then under this temperature, till forming lamellar gel matrix.Adding the blast system mixed about 15 minutes under about 35 ℃ temperature then.Also in lamellar gel matrix, add remaining composition.Compositions is administered on the dried expectation part of sending out.Do not rinse or remove excessive compositions before the infra once washing from hair.Typing as required.

Embodiment 3: be suitable for the hair care agent used by one or more methods as herein described can as Following preparation:

Component	Expection percentage by weight (%) in the finished product
		Water	In right amount
The blast system 1	0.1000
		Propylene glycol two caprylic/capric esters (Polyquaterium-37)	1.000
Polyethylene Glycol (Peg-4)	0.500
		Polyquaternary ammonium salt-39	0.500
Polydimethylsiloxane and dimethiconol blend (Q2-1403)	0.500
		Disodiumedetate	0.127
Phenyl phenol	0.200
		Methyl parahydroxybenzoate	0.200

1 except described other blast system in this paper other places, can also use any example of the described suitable blast system of table 1.

In suitable mixer, the deionized water that adds room temperature begins to mix then.Add propylene glycol two caprylic/capric esters (polyquaternary ammonium salt-37).Then, add the blast system.Add remaining composition.Compositions is administered on the expectation part of the wet hair that previous dyeing handled.Do not rinse or remove excessive compositions before the infra once washing from hair.Typing as required.

Embodiment 4: be suitable for the hair care agent used by one or more methods as herein described can as Following preparation:

Component	Expection percentage by weight (%) in the finished product
		Water	In right amount
The blast system 1	5.000
		Triethanolamine	0.820
C974P BufferGel (acrylate copolymer 981)	0.100
		Acrylate/C10-C30 alkyl acrylate crosspolymer (Pemulen TR-1)	0.700

Polydimethylsiloxane and dimethiconol blend (Q2-1403)	0.500
		Polyquaternary ammonium salt-39	0.100
Peg-4	0.100
		Phenyl phenol	0.200
Methyl parahydroxybenzoate	0.200
		Disodiumedetate	0.127

1 except described other blast system in this paper other places, can also use any example of the described suitable blast system of table 1.

In suitable mixer, add entry and make C974P BufferGel and acrylate/C10-C30 alkyl acrylate crosspolymer is distributed to wherein.Fiercely mix dispersion and be heated to about 50 ℃.Mixture is cooled to is lower than 40 ℃, add triethanolamine then.Neutralization adds remaining composition then.Compositions is administered on the wet hair of before having scalded.Do not rinse or remove excessive compositions before the infra once washing from hair.Typing as required.

Embodiment 5: be suitable for the hair-care mousse by one or more methods uses as herein described Preparation can be prepared as follows:

Component	Expection percentage by weight (%) in the finished product
		Water	In right amount
The blast system 1	10.000
		Polyquaternary ammonium salt-4	2.750
Pareth-91-8	0.229
		Propylene glycol	0.458
DMDM Hydantoin	0.356
		Citric acid (50% solution)	0.0183
Disodiumedetate	0.0940
		Propellant A-55	6.0000

1 except described other blast system in this paper other places, can also use any example of the described suitable blast system of table 1.

Adding entry in mixer makes it reach suitable temperature (26 ℃ to 85 ℃) to mix polyquaternary ammonium salt-4 then.To make the material homodisperse in the industry production liquid stream in the polyquaternary ammonium salt-4 adding mixer.In mixer, add disodiumedetate and a part of citric acid, mix and incorporate into wherein up to solid.In case solution does not obviously have solid, just vessel temp is set to new processing conditions (26 ℃ to 38 ℃), add Pareth 91-8 and propylene glycol then.In case satisfying, new processing conditions just adds DMDM Hydantoin.The blast system is mixed in the production liquid stream.Mixing is up to uniform distribution.Press required adjusting pH with extra citric acid.With the concentrate of making above aerosol container is filled to suitable liquid level, evacuation and in position with valve clip.Add required propellant blend by valve, do not surpass 6% of volume.Compositions is administered on the clean wet hair.Do not rinse or remove excessive compositions before the infra once washing from hair.Typing as required.

Embodiment 6: be suitable for the limpid conditioner preparation by one or more methods uses as herein described Can be prepared as follows:

Water	In right amount
		The blast system 1、2、3、4、5	Such as mark 1、2、3、4、5
Polyquaternary ammonium salt 37	1.50
		Solubilisant TM LRI 6	0.30
Methyl parahydroxybenzoate	0.20
		Propyl p-hydroxybenzoate	0.20
Propylene glycol	40.00
		Genamin TM KDMP 7	0.80
Castor oil hydrogenated PEG-40	0.30
		Pearl spice	0.20

¹Following blast system especially is useful on the dark hair: 1.00%Covapearl ^TMBright (SENSIENT), 1.40%Chroma Lite ^TMRed (ENGLEHARD), 1.40%ChromaLite ^TMYellow (ENGLEHARD), 0.7%Chroma Lite ^TMDark Blue (ENGLEHARD), 0.70%Chroma Light ^TMGreen (ENGLEHARD).

²Following blast system is particularly useful on dark hair producing redness and chooses and dye: 1.00%Covapearl ^TMBright (SENSIENT), 1.40% Cloisonne ^TMCeriseFlambe (ENGLEHARD), 1.40%Cloisonne ^TMImperial Gold (ENGLEHARD), 0.7% Cloisonne ^TMGreen (ENGLEHARD), 0.70% Chroma Light ^TMDarkBlue (ENGLEHARD).

³Following brightener is particularly useful on dark hair producing golden brown and chooses and dye: 1.00%Covapearl ^TMBright (SENSIENT), 1.40% Desert Reflection CanyonSunset (ENGLEHARD), 1.40%Desert Reflection Sunlit Cactus (ENGLEHARD), 0.7%Desert Reflection Painted Desert Plum (ENGLEHARD), 0.70%DesertReflection Midnight Sagebrush (ENGLEHARD).

⁴Following brightener is particularly useful for strengthening the vibrancy of golden hair: 0.6% KTZInterfine ^TMBlue (KOBO), 2.00% KTZ Interfine ^TMGold (KOBO), 0.60% KTZInterfine ^TMRed (KOBO), 2.00%Xian Vistas (KOBO).

⁵Following blast system is particularly useful for strengthening red vibrancy: 1.00%Covapearl ^TMBright (SENSIENT), 1.00% Cloisonne ^TMNu-AntiqueCopper (ENGELHARD), 1.20% Cloisonne ^TMCerise Flambe (ENGELHARD), 1.20% Covapearl ^TMFire Red (SENSIENT), 0.50% Cloisonne ^TMRougeFlambe (ENGELHARD), 0.50% Cellini Red (ENGELHARD).

⁶Comprise 53%PPG-26-buteth-26,37%PEG-40 castor oil hydrogenated and 10% water.

⁷Comprise 80% INCROQUAT TMC-80 ECONOL TM22 and 20% isopropyl alcohol.

In suitable containers, mix polyquaternary ammonium salt-37 and Solubilisant LRI and about 3/4'sths water, to produce limpid gel (mixture A).In independent suitable vessel, mix remaining composition, comprise remaining water, be heated to 70 ℃ while stirring, up to all the components dissolving (mixture B).Cooling mixture B slowly adds among the mixture A then while stirring.Transfer in the suitable storage container.Resulting composition is administered on the clean wet hair.Do not rinse or remove excessive compositions before the infra once washing from hair.Typing as required.

Size disclosed herein and numerical value should not be understood that to be strictly limited to described exact numerical values recited.On the contrary, except as otherwise noted, each above-mentioned size is intended to be meant described value and near the function equivalent scope of this value.For example, the size that is disclosed as " 40mm " is intended to be meant " about 40mm ".

The relevant portion of the document that all are quoted in the specific embodiment all is incorporated herein with way of reference; Quoting of any document may not be interpreted as its approval as prior art of the present invention.When any implication of the term in any implication of term in this written document record or definition and the document of incorporating into way of reference or define when conflicting, will be as the criterion with the implication or the definition of giving the term in this written document record.

Although illustrated and described the present invention with specific embodiments, it will be apparent to those skilled in the art that and to make many other variation and modifications in the case of without departing from the spirit and scope of protection of the present invention.Therefore, in additional claims, comprise all such changes and modifications that belong in the scope of the invention consciously.

Claims (12)

1. leave-on hair care composition, described compositions comprises:

A) 0.1% to 10% blast system, described blast system comprise the 4th soluble granule of the 3rd soluble granule of the second soluble granule, reflection the 3rd color of the first soluble granule that reflects first color, reflection second color, optional reflection the 4th color and the additional soluble granule of optional at least a other color of at least a reflection;

B) 0.001% to 5% film former;

C) dermatological acceptable carrier; With

D) Ren Xuan dyestuff.

2. compositions as claimed in claim 1, wherein said film former comprises one or more osamines of 0.001% to 1%, and preferably wherein said osamine comprises glycosamine, N-acetyl glucosamine, mannosamine, N-acetyl group mannosamine, galactosamine, N-acetyl group galactosamine or their mixture; And more preferably wherein said osamine is the N-acetyl glucosamine.

3. the described compositions of each claim as described above, the ratio of the percentage ratio of wherein said blast system and the percentage ratio of described osamine is 10: 1.

4. the described compositions of each claim as described above, the wherein said first soluble granule, the described second soluble granule and the described the 3rd soluble granule have 1 micron to 150 microns mean diameter.

5. the described compositions of each claim as described above, wherein said first color belongs to red colour system, and described second color belongs to yellow system, and described the 3rd color belongs to green system, and described the 4th optional color belongs to blue system.

6. the described compositions of each claim as described above, at least a in wherein said first, second or the 3rd soluble granule comprises reflection grain, goniochromatic granule, photonic crystal, luminous pigment, fluorescent pigment, phosphorescent pigment or their combination, preferably wherein said goniochromatic granule is a coated interference pigment, and the more preferably wherein said first soluble granule, the described second soluble granule and the described the 3rd soluble granule are coated interference pigment.

7. the described compositions of each claim as described above, the wherein said first soluble granule is a reflection grain, and the described second soluble granule is a coated interference pigment.

8. the use beauty method of the described compositions of each claim as described above, described method comprises the leave compositions is administered to mammiferous hair, preferred people's hair, the hair of Canis familiaris L. or the hair of cat, and the more preferably step on people's the hair, described compositions comprises:

A) 0.1% to 10% blast system, described blast system comprise the second soluble granule of the first soluble granule that reflects first color, reflection second color and reflect the 4th soluble granule of the 3rd soluble granule of the 3rd color, optional reflection the 4th color and the additional soluble granule of optional at least a other color of at least a reflection;

B) 0.001% to 5% film former; With

C) dermatological acceptable carrier;

D) randomly wherein described compositions is administered on the part of described mammalian hair.

9. available beauty method as claimed in claim 8, wherein said mammiferous hair has golden base hair color, and described first color belongs to red colour system, and described second color belongs to yellow system, and described the 3rd color belongs to green system.

10. available beauty method as claimed in claim 9, the ratio of the wherein said first soluble particulate percentage ratio and the described second soluble particulate percentage ratio and described the 3rd soluble particulate percentage ratio is 1: 1: 3.

11. available beauty method as claimed in claim 8, wherein said hair has the base hair color of brown or black, and described the 4th color belongs to blue system.

12. available beauty method as claimed in claim 11, the ratio of the wherein said first soluble particulate percentage ratio and the described second soluble particulate percentage ratio and the described the 3rd soluble particulate percentage ratio and described the 4th soluble particulate percentage ratio is 2: 2: 1: 1.