CN101297016A - Compositions comprising a fluoroolefin - Google Patents

Abstract

The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises a fluoroolefin and at least one other component. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents.

Description

The composition that comprises fluoroolefins

The cross reference of related application

The application requires in the benefit of priority of the U.S. Provisional Application 60/732,769 of the U.S. Provisional Application 60/710,439 of the U.S. Provisional Application submission on August 23rd, 60/658,543,2005 of submission on March 4th, 2005 and submission on November 1st, 2005.

Background of invention

1. invention field

The present invention relates to be used to freeze, the composition of air-conditioning and heat pump system, wherein said composition comprises fluoroolefins and at least a other component.Composition of the present invention can be used for refrigeration or heating method, as heat-transfer fluid, whipping agent, aerosol propellants and flame-out and fire-fighting medium.

2. description of related art

Refrigeration industry has made great efforts to seek in decades the Chlorofluorocarbons (CFCs) (CFC) of consumption ozone and the substitute refrigerants of Hydrochlorofluorocarbons (HCFC) (they are owing to Montreal Agreement requires progressively to stop using) in the past.Most of cooling agent producers' solution has been with (HFC) cooling agent industrialization of hydrogen fluorine carbon (hydrogen fluorohydrocarbon).The influence that the current rules Compulsory Feature that new HFC cooling agent (HFC-134a is the most widely used at present) has zero ozone depletion potential and therefore not stipulated by Montreal Agreement stops gradually.

Other legislations of environmental protection can finally cause the whole world of some HFC cooling agent to be stopped using gradually.At present, automotive industry faces for the regulation limitations relevant with global warming potential for the cooling agent that uses in the mobile air conditioner.Therefore, be starved of the new cooling agent of determining to reduce global warming potential at present for mobile air conditioner market.If these rules will be suitable for more widely in future, even more press for the cooling agent that can use in all areas of refrigeration and air-conditioning industry.

The cooling agent of the alternative HFC-134a of suggestion comprises HFC-152a, pure hydrocarbon such as butane or propane, or " natural " cooling agent such as CO at present ₂Many in the substitute of these suggestions are deleterious, and are inflammable, and/or have low energy efficiency.Therefore, seeking new substitute refrigerants.

The purpose of this invention is to provide novel refrigerant compositions and heat-transfer fluid composition, they provide unique characteristic to satisfy low or zero ozone depletion potential requirement and provide with present cooling agent and compare lower global warming potential.

General introduction of the present invention

The present invention relates to comprise HFC-1225ye and at least a compound compositions that is selected from following material:

HFC-1234ze, HFC-1234yf, HFC-1234ye, HFC-1243zf, HFC-32, HFC-125, HFC-134, HFC-134a, HFC-143a, HFC-152a, HFC-161, HFC-227ea, HFC-236ea, HFC-236fa, HFC-245fa, HFC-365mfc, propane, normal butane, Trimethylmethane, 2-methylbutane, Skellysolve A, pentamethylene, dimethyl ether, CF ₃SCF ₃, CO ₂And CF ₃I.

The invention further relates to and comprise HFC-1234ze and at least a compound compositions that is selected from following material: HFC-1234yf, HFC-1234ye, HFC-1243zf, HFC-32, HFC-125, HFC-134, HFC-134a, HFC-143a, HFC-152a, HFC-161, HFC-227ea, HFC-236ea, HFC-236fa, HFC-245fa, HFC-365mfc, propane, normal butane, Trimethylmethane, 2-methylbutane, Skellysolve A, pentamethylene, dimethyl ether, CF ₃SCF ₃, CO ₂And CF ₃I.

The invention further relates to and comprise HFC-1234yf and at least a compound compositions that is selected from following material: HFC-1234ye, HFC-1243zf, HFC-32, HFC-125, HFC-134, HFC-134a, HFC-143a, HFC-152a, HFC-161, HFC-227ea, HFC-236ea, HFC-236fa, HFC-245fa, HFC-365mfc, propane, normal butane, Trimethylmethane, 2-methylbutane, Skellysolve A, pentamethylene, dimethyl ether, CF ₃SCF ₃, CO ₂And CF ₃I.

The invention further relates to and comprise HFC-1234ye and at least a compound compositions that is selected from following material: HFC-1243zf, HFC-32, HFC-125, HFC-134, HFC-134a, HFC-143a, HFC-152a, HFC-161, HFC-227ea, HFC-236ea, HFC-236fa, HFC-245fa, HFC-365mfc, propane, normal butane, Trimethylmethane, 2-methylbutane, Skellysolve A, pentamethylene, dimethyl ether, CF ₃SCF ₃, CO ₂And CF ₃I.

The invention further relates to and comprise HFC-1243zf and at least a compound compositions that is selected from following material: HFC-32, HFC-125, HFC-134, HFC-134a, HFC-143a, HFC-152a, HFC-161, HFC-227ea, HFC-236ea, HFC-236fa, HFC-245fa, HFC-365mfc, propane, normal butane, Trimethylmethane, 2-methylbutane, Skellysolve A, pentamethylene, dimethyl ether, CF ₃SCF ₃, CO ₂And CF ₃I.

The invention further relates to the composition that comprises following material:

(a) at least a lubricant that is selected from polyol ester, polyalkylene glycol, polyvingl ether, mineral oil, alkylbenzene, synthetic paraffin, synthetic naphthenic hydrocarbon and poly-(α) alkene; With

(b) be selected from the composition of the group that constitutes by following material:

The approximately about 99wt%HFC1225ye of 1wt%-and the approximately about 1wt%HFC-152a of 99wt%-;

The approximately about 99wt%HFC1225ye of 1wt%-and the approximately about 1wt%HFC-1234yf of 99wt%-;

Approximately the about 99wt%HFC1225ye of 1wt%-and approximately the about 1wt% of 99wt%-anti--HFC-1234ze;

The approximately about 99wt%HFC-1225ye of 1wt%-and the approximately about 1wt%HFC-1243zf of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-134a of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-152a of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-227ea of 99wt%-; With

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%CF of 99wt%- ₃I.

The invention further relates to the composition that comprises following material:

A) cooling agent or heat-transfer fluid composition, said composition is selected from:

The approximately about 99wt%HFC 1225ye of 1wt%-and the approximately about 1wt%HFC-152a of 99wt%-;

The approximately about 99wt%HFC1225ye of 1wt%-and the approximately about 1wt%HFC-1234yf of 99wt%-;

Approximately the about 99wt%HFC-1225ye of 1wt%-and approximately the about 1wt% of 99wt%-anti--HFC-1234ze;

The approximately about 99wt%HFC-1225ye of 1wt%-and the approximately about 1wt%HFC-1243zf of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-134a of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-152a of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-227ea of 99wt%-; With

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%CF of 99wt%- ₃I; With

Be selected from the expanding material of following material:

I) by general formula R ¹[(OR ²) xOR ³] poly suboxygen alkyl glycol ethers that y represents, wherein: x is the integer of 1-3; Y is the integer of 1-4; R ¹Be selected from hydrogen and the aliphatic hydrocarbyl that contains 1-6 carbon atom and y keyed jointing position; R ²Be selected from the aliphatic alkylene that contains 2-4 carbon atom; R ³Be selected from hydrogen and the aliphatic series and the alicyclic alkyl that contain 1-6 carbon atom; R ¹And R ³In at least one is selected from described alkyl; And wherein said poly suboxygen alkyl glycol ethers has the molecular weight of about 300 atomic mass units of about 100-;

Ii) by general formula R ¹C (O) NR ²R ³And ring-[R ⁴CON (R ⁵The acid amides of expression)-], wherein R ¹, R ², R ³And R ⁵Be independently selected from the aliphatic series that contains 1-12 carbon atom and alicyclic alkyl and aromatic group that contains 6-12 carbon atom at the most; R ⁴Be selected from the aliphatic alkylene that contains 3-12 carbon atom; And wherein said acid amides has about 100)-about 30) molecular weight of 0 atomic mass unit;

Iii) by general formula R ¹C (O) R ²The ketone of expression, wherein R ¹And R ²Be independently selected from the aliphatic series that contains 1-12 carbon atom, alicyclic and aryl alkyl, and wherein said ketone has the molecular weight of about 300 atomic mass units of about 70-;

Iv) by general formula R ¹The nitrile that CN represents, wherein R ¹Be selected from the aliphatic series that contains 5-12 carbon atom, alicyclic or aryl alkyl, and wherein said nitrile has the molecular weight of about 200 atomic mass units of about 90-;

The v) hydrochloric ether of representing by general formula R Clx, wherein: x is 1 or 2; R is selected from aliphatic series and the alicyclic alkyl that contains 1-12 carbon atom; And wherein said hydrochloric ether has the molecular weight of about 200 atomic mass units of about 100-;

Vi) by general formula R ¹OR ²The aryl ethers of expression, wherein: R ¹Be selected from the aryl alkyl that contains 6-12 carbon atom; R ²Be selected from the aliphatic hydrocarbyl that contains 1-4 carbon atom; And wherein said aryl ethers has the molecular weight of about 150 atomic mass units of about 100-;

Vii) by general formula CF ₃R ¹1,1 of expression, 1-trifluoro alkane, wherein R ¹Be selected from the aliphatic series and the alicyclic alkyl that contain about 15 carbon atoms of about 5-;

Viii) by general formula R ¹OCF ₂CF ₂The fluoroether that H represents, wherein R ¹Be selected from the aliphatic series that contains about 15 carbon atoms of about 5-, alicyclic, and aromatic hydrocarbyl; Or wherein said fluoroether is derived from fluoroolefins and polyvalent alcohol, and wherein said fluoroolefins has CF ₂=CXY pattern, wherein X is hydrogen, chlorine or fluorine, Y is chlorine, fluorine, CF ₃Or OR _f, R wherein _fBe CF ₃, C ₂F ₅Or C ₃F ₇With described polyvalent alcohol be linearity or branching, wherein said linear polyvalent alcohol has HOCH ₂(CHOH) x (CRR ') yCH ₂The OH pattern, wherein R and R ' are hydrogen, CH ₃Or C ₂H ₅, x is the integer of 0-4, y is the integer of 0-3, z be 0 or 1 and described branching polyvalent alcohol have C (OH) t (R) u (CH ₂OH) v[(CH ₂) mCH ₂OH] the w pattern, wherein R can be hydrogen, CH ₃Or C ₂H ₅, m is the integer of 0-3, and t and u are 0 or 1, and v and w are the integers of 0-4, in addition t+u+v+w=4 wherein; With

Ix) lactone of representing by structure [B], [C] and [D]:

Wherein, R ₁-R ₈Be independently selected from hydrogen, linearity, branching, ring-type, two rings, saturated and undersaturated alkyl; And molecular weight is about 100 to about 300 atomic mass units; With

X) by general formula R ¹CO ₂R ²The ester of expression, wherein R ¹And R ²Be independently selected from linearity and ring-type, saturated and undersaturated, alkyl and aryl; And wherein said ester has from about 80 molecular weight to about 550 atomic mass units.

The invention further relates to the composition that comprises following material:

(a) at least a UV fluorescent dye, it is selected from naphthalimide ， perylene, tonka bean camphor, anthracene, phenanthrene, xanthene, thioxanthene, naphthoxanthene, fluorescein, the derivative of described dyestuff and their combination; With

(b) be selected from the composition of the group that constitutes by following material:

The approximately about 99wt%HFC1225ye of 1wt%-and the approximately about 1wt%HFC-152a of 99wt%-;

The approximately about 99wt%HFC1225ye of 1wt%-and the approximately about 1wt%HFC-1234yf of 99wt%-;

Approximately the about 99wt%HFC1225ye of 1wt%-and approximately the about 1wt% of 99wt%-anti--HFC-1234ze;

The approximately about 99wt%HFC-1225ye of 1wt%-and the approximately about 1wt%HFC-1243zf of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-134a of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-152a of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-227ea of 99wt%-; With

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%CF of 99wt%- ₃I.

The invention further relates in the refrigeration lubricant that is selected from mineral oil, alkylbenzene, synthetic paraffin, synthetic naphthenic hydrocarbon and poly-(α) alkene method with cooling agent or heat-transfer fluid composition solubilising, under the expanding material that wherein said method is included in significant quantity exists described lubricant is contacted with described cooling agent or heat-transfer fluid composition, wherein said cooling agent or heat-transfer fluid comprise and are selected from following composition;

The approximately about 99wt%HFC-1225ye of 1wt%-and the approximately about 1wt%HFC-152a of 99wt%-;

The approximately about 99wt%HFC-1225ye of 1wt%-and the approximately about 1wt%HFC-1234yf of 99wt%-;

Approximately the about 99wt%HFC-1225ye of 1wt%-and approximately the about 1wt% of 99wt%-anti--HFC-1234ze;

The approximately about 99wt%HFC-1225ye of 1wt%-and the approximately about 1wt%HFC-1243zf of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-134a of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-152a of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-227ea of 99wt%-; With

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%CF3I of 99wt%-;

And wherein said expanding material is selected from:

A) by general formula R ¹[(OR ²) xOR ³] poly suboxygen alkyl glycol ethers that y represents, wherein: x is the integer of 1-3; Y is the integer of 1-4; R ¹Be selected from hydrogen and the aliphatic hydrocarbyl that contains 1-6 carbon atom and y keyed jointing position; R ²Be selected from the aliphatic alkylene that contains 2-4 carbon atom; R3 is selected from hydrogen and contains the aliphatic series and the alicyclic alkyl of 1-6 carbon atom; R ¹And R ³In at least one is selected from described alkyl; And wherein said poly suboxygen alkyl glycol ethers has the molecular weight of about 300 atomic mass units of about 100-;

B) by general formula R ¹C (O) NR ²R ³And ring-[R ⁴CON (R ⁵The acid amides of expression)-], wherein R ¹, R ², R ³And R ⁵Be independently selected from the aliphatic series that contains 1-12 carbon atom and alicyclic alkyl and aromatic group that contains 6-12 carbon atom at the most; R ⁴Be selected from the aliphatic alkylene that contains 3-12 carbon atom; And wherein said acid amides has the molecular weight of about 300 atomic mass units of about 100-;

C) by general formula R ¹C (O) R ²The ketone of expression, wherein R ¹And R ²Be independently selected from the aliphatic series that contains 1-12 carbon atom, alicyclic and aryl alkyl, and wherein said ketone has the molecular weight of about 300 atomic mass units of about 70-;

D) by general formula R ¹The nitrile that CN represents, wherein R ¹Be selected from the aliphatic series that contains 5-12 carbon atom, alicyclic or aryl alkyl, and wherein said nitrile has the molecular weight of about 200 atomic mass units of about 90-;

E) hydrochloric ether of representing by general formula R Clx, wherein: x is 1 or 2; R is selected from aliphatic series and the alicyclic alkyl that contains 1-12 carbon atom; And wherein said hydrochloric ether has the molecular weight of about 200 atomic mass units of about 100-;

F) by general formula R ¹OR ²The aryl ethers of expression, wherein: R ¹Be selected from the aryl alkyl that contains 6-12 carbon atom; R ²Be selected from the aliphatic hydrocarbyl that contains 1-4 carbon atom; And wherein said aryl ethers has the molecular weight of about 150 atomic mass units of about 100-;

G) by general formula CF ₃R ¹1,1 of expression, 1-trifluoro alkane, wherein R ¹Be selected from the aliphatic series and the alicyclic alkyl that contain about 15 carbon atoms of about 5-;

H) by general formula R ¹OCF ₂CF ₂The fluoroether that H represents, wherein R ¹Be selected from the aliphatic series and the alicyclic alkyl that contain about 15 carbon atoms of about 5-; Or wherein said fluoroether is derived from fluoroolefins and polyvalent alcohol, and wherein said fluoroolefins has CF ₂=CXY pattern, wherein X is hydrogen, chlorine or fluorine, Y is chlorine, fluorine, CF ₃Or OR _f, R wherein _fBe CF ₃, C ₂F ₅Or C ₃F ₇Has HOCH with described linear polyvalent alcohol ₂CRR ' (CH ₂) z (CHOH) xCH ₂(CH ₂OH) y pattern, wherein R and R ' are hydrogen, CH ₃Or C ₂H ₅, x is the integer of 0-4, and y is the integer of 0-3, and z is 0 or 1; With

I) lactone of representing by structure [B], [C] and [D]:

Wherein, R ₁-R ₈Be independently selected from hydrogen, linearity, branching, ring-type, two rings, saturated and undersaturated alkyl; And molecular weight is about 100 to about 300 atomic mass units; With

J) by general formula R ¹CO ₂R ²The ester of expression, wherein R ¹And R ²Be independently selected from linearity and ring-type, saturated and undersaturated, alkyl and aryl; And wherein said ester has from about 80 molecular weight to about 550 atomic mass units.

The invention further relates to the method for high GwP cooling agent in alternative refrigeration, air-conditioning or the heat-pump apparatus, wherein said high GWP cooling agent is selected from R134a, R22, R123, R11, R245fa, R114, R236fa, R124, R12, R410A, R407C, R417A, R422A, R507A, R502 and R404A, and described method comprises and will be selected from following composition

The approximately about 99wt%HFC-1225ye of 1wt%-and the approximately about 1wt%HFC-152a of 99wt%-;

The approximately about 99wt%HFC1225ye of 1wt%-and the approximately about 1wt%HFC-1234yf of 99wt%-;

Approximately the about 99wt%HFC-1225ye of 1wt%-and approximately the about 1wt% of 99wt%-anti--HFC-1234ze;

The approximately about 99wt%HFC-1225ye of 1wt%-and the approximately about 1wt%HFC-1243zf of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-134a of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-152a of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-227ea of 99wt%-; With

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%CF3I of 99wt%-;

Offer use, be used for or design the described refrigeration, air-conditioning or the heat-pump apparatus that are used for using described high GWP cooling agent.

The invention further relates to the method that cooling agent leaks in early detection refrigeration, air-conditioning or the heat-pump apparatus, described method is included in the reduction of using non-Azeotrope compositions and monitoring cooling performance in the described equipment.

Detailed description of the present invention

The present invention relates to comprise the composition of at least a fluoroolefins.Composition of the present invention further comprises at least a additional component, and this component can be second fluoroolefins, hydrogen fluorine carbon (HFC), hydrocarbon, dme, two (trifluoromethyl) thioether, CF ₃I or CO ₂The fluoroolefin compounds of the present composition and other component are listed in the table 1.

Table 1

Compound	Chemical name	Chemical formula
			HFC-1225ye	1,2,3,3,3-five fluorine propylene	CF 3CF＝CHF
HFC-1234ze	1,3,3, the 3-tetrafluoeopropene	CF 3CH＝CHF
			HFC-1234yf	2,3,3, the 3-tetrafluoeopropene	CF 3CF＝CH 2
HFC-1234ye	1,2,3, the 3-tetrafluoeopropene	CHF 2CF＝CHF
			HFC-1243zf	3,3, the 3-trifluoro propene	CF 3CH＝CH 2
HFC-32	Methylene fluoride	CH 2F 2
			HFC-125	Pentafluoride ethane	CF 3CHF 2
HFC-134	1,1,2, the 2-Tetrafluoroethane	CHF 2CHF 2
			HFC-134a	1,1,1, the 2-Tetrafluoroethane	CH 2FCF 3
HFC-143a	1,1, the 1-Halothane	CH 3CF 3
			HFC-152a	1, the 1-C2H4F2 C2H4F2	CHF 2CH 3
HFC-161	Fluoroethane	CH 3CH 2F
			HFC-227ea	1,1,1,2,3,3, the 3-heptafluoro-propane	CF 3CHFCF 3
HFC-236ea	1,1,1,2,3, the 3-HFC-236fa	CF 3CHFCHF 2
			HFC-236fa	1,1,1,3,3, the 3-hexafluoroethane	CF 3CH 2CF 3
HC-245fa	1,1,1,3, the 3-pentafluoropropane	CF 3CH 2CHF 2
			HFC-365mfc	1,1,1,3, the 3-3-pentafluorobutane	CF 3CH 2CH 2CHF 2
	Propane	CH 3CH 2CH 3
				Normal butane	CH 3CH 2CH 2CH 3
i-butane	Trimethylmethane	CH 3CH(CH 3)CH 3
				The 2-methylbutane	CH 3CH(CH 3)CH 2CH 3
	Skellysolve A	CH 3CH 2CH 2CH 2CH 3
				Pentamethylene	Ring-(CH 2) 5

DME	Dimethyl ether	CH 3OCH 3
			CO 2	Carbonic acid gas	CO 2
CF 3SCF 3	Two (trifluoromethyl) thioether	CF 3SCF 3
				One iodine trifluoromethane	CF 3I

Each component of listing in the table 1 can be by method preparation as known in the art.

The fluoroolefin compounds that uses in the present composition (HFC-1225ye, HFC-1234ze and HFC-1234ye) can be used as not, and the isomer or the steric isomer of isomorphism type exist.The present invention is intended to comprise all single configurational isomers, single stereoisomers or their any combination or mixture.For example, 1,3,3,3-tetrafluoeopropene (HFC-1234ze) means that expression is along isomer, trans isomer or this two kinds of isomer any combination or mixture by any ratio.Another example is HFC-1225ye, and it is by representing by any combination or the mixture of any ratio along isomer, trans isomer or this two kinds of isomer.

Composition of the present invention comprises following: HFC-1225ye and at least a compound that is selected from following material: HFC-1234ze, HFC-1234yf, HFC-1234ye, HFC-1243zf, HFC-32, HFC-125, HFC-134, HFC-134a, HFC-143a, HFC-152a, HFC-161, HFC-227ea, HFC-236ea, HFC-236fa, HFC-245fa, HFC-365mfc, propane, normal butane, Trimethylmethane, 2-methylbutane, Skellysolve A, pentamethylene, dimethyl ether, CF ₃SCF ₃, CO ₂And CF ₃I;

HFC-1234ze and at least a compound that is selected from following material: HFC-1225ye, HFC-1234yf, HFC-1234ye, HFC-1243zf, HFC-32, HFC-125, HFC-134, HFC-134a, HFC-143a, HFC-152a, HFC-161, HFC-227ea, HFC-236ea, HFC-236fa, HFC-245fa, HFC-365mfc, propane, normal butane, Trimethylmethane, 2-methylbutane, Skellysolve A, pentamethylene, dimethyl ether, CF ₃SCF ₃, CO ₂And CF ₃I;

HFC-1234yf and at least a compound that is selected from following material: HFC-1234ye, HFC-1243zf, HFC-32, HFC-125, HFC-134, HFC-134a, HFC-143a, HFC-152a, HFC-161, HFC-227ea, HFC-236ea, HFC-236fa, HFC-245fa, HFC-365mfc, propane, normal butane, Trimethylmethane, 2-methylbutane, Skellysolve A, pentamethylene, dimethyl ether, CF ₃SCF ₃, CO ₂And CF ₃I; With

HFC-1243zf and at least a compound that is selected from following material: HFC-1234ye, HFC-32, HFC-125, HFC-134, HFC-134a, HFC-143a, HFC-152a, HFC-161, HFC-227ea, HFC-236ea, HFC-236fa, HFC-245fa, HFC-365mfc, propane, normal butane, Trimethylmethane, 2-methylbutane, Skellysolve A, pentamethylene, dimethyl ether, CF ₃SCF ₃, CO ₂And CF ₃I; With

HFC-1234ye and at least a compound that is selected from following material: HFC-32, HFC-125, HFC-134, HFC-134a, HFC-143a, HFC-152a, HFC-161, HFC-227ea, HFC-236ea, HFC-236fa, HFC-245fa, HFC-365mfc, propane, normal butane, Trimethylmethane, 2-methylbutane, Skellysolve A, pentamethylene, dimethyl ether, CF ₃SCF ₃, CO ₂And CF ₃I.

When described fluoroolefins with the about 99wt% of about 1wt%-, the about 99wt% of preferably approximately 20wt%-, more preferably about about 99wt% of 40wt%-, when still more preferably the concentration of the about 99wt% of 50wt%-existed, composition of the present invention may be useful usually.

The present invention further provides the composition of listing in the table 2.

Table 2

When each component with as listed+/-when the concentration of 2wt% exists, of the present invention list in the table 2 most preferred composition usually expection keep required performance and function.Work as CO ₂With listed concentration+/-when 0.2wt% exists, contain CO ₂Composition required performance and function are kept in expection.

Composition of the present invention can be an azeotropic or near the azeotropic composition.So-called Azeotrope compositions is meant the constant boiling mixture of two or more materials that show as one matter.A kind of method of sign Azeotrope compositions is to evaporate or distill the steam that produces by the part of liquid to have identical composition with its evaporation or distillation liquid certainly, i.e. this mixture distillation/backflow under the situation of not composition variation.The constant boiling point composition characterizes and is to show maximum or minimum boiling point because they are compared with the boiling point of the zeotrope of same compound by Azeotrope compositions.Azeotrope compositions can be in operating process fractionation in refrigeration or air-conditioning system, this may reduce the efficient of this system.In addition, Azeotrope compositions can be from refrigeration or air-conditioning system fractionation when leaking.A kind of component is under the situation of combustible components in mixture, and fractionation may produce flammable compositions may in this system or outside this system in leakage process.

Near azeotropic composition (also being commonly referred to " Azeotrope-like compositions ") is the azeotropic substantially liquid mixture that shows as two or more materials of one matter basically.Sign is to evaporate or distill the steam that produces by the part of liquid to have identical substantially composition with its evaporation or distillation liquid certainly, i.e. this mixture distillation/backflow under the situation that is not having remarkable composition to change near a kind of method of azeotropic composition.Sign is that the bubble point vapour pressure of said composition under specified temp is identical substantially with the dew point vapour pressure near the another kind of method of azeotropic composition.At this, if after removing the 50wt% of composition (for example by evaporating or boiling and remove), original composition and removing after the 50wt% original composition vapour pressure difference between the remaining composition less than about 10%, then said composition is near azeotropic.

Azeotrope compositions of the present invention is shown in the table 3 under specified temperature.

Table 3

Component A	B component	Wt％A	Wt％B	Psia	kPa	T(C)
							HFC-1234yf	HFC-32	7.4	92.6	49.2	339	-25
HFC-1234yf	HFC-125	10.9	89.1	40.7	281	-25
							HFC-1234yf	HFC-134a	70.4	29.6	18.4	127	-25
HFC-1234yf	HFC-152a	91.0	9.0	17.9	123	-25
							HFC-1234yf	HFC-143a	17.3	82.7	39.5	272	-25
HFC-1234yf	HFC-227ea	84.6	15.4	18.0	124	-25
							HFC-1234yf	Propane	51.5	48.5	33.5	231	-25
HFC-1234yf	Normal butane	98.1	1.9	17.9	123	-25
							HFC-1234yf	Trimethylmethane	88.1	11.9	19.0	131	-25
HFC-1234yf	DME	53.5	46.5	13.1	90	-25
							HFC-1225ye	Instead-HFC-1234ze	63.0	37.0	11.7	81	-25
HFC-1225ye	HFC-1243zf	40.0	60.0	13.6	94	-25
							HFC-1225ye	HFC-134	52.2	47.8	12.8	88	-25
HFC-1225ye	HFC-152a	7.3	92.7	14.5	100	-25
							HFC-1225ye	Propane	29.7	70.3	30.3	209	-25
HFC-1225ye	Normal butane	89.5	10.5	12.3	85	-25

HFC-1225ye	Trimethylmethane	79.3	20.7	13.9	96	-25
							HFC-1225ye	DME	82.1	17.9	10.8	74	-25
HFC-1225ye	CF 3SCF 3	37.0	63.0	12.4	85	-25
							trans-HFC-1234ze	HFC-1243zf	17.0	83.0	13.0	90	-25
trans-HFC-1234ze	HFC-134	45.7	54.3	12.5	86	-25
							trans-HFC-1234ze	HFC-134a	9.5	90.5	15.5	107	-25
trans-HFC-1234ze	HFC-152a	21.6	78.4	14.6	101	-25
							trans-HFC-1234ze	HFC-227ea	59.2	40.8	11.7	81	-25
trans-HFC-1234ze	Propane	28.5	71.5	30.3	209	-25
							trans-HFC-1234ze	Normal butane	88.6	11.4	11.9	82	-25
trans-HFC-1234ze	Trimethylmethane	77.9	22.1	12.9	89	-25
							trans-HFC-1234ze	DME	84.1	15.9	10.8	74	-25
trans-HFC-1234ze	CF 3SCF 3	34.3	65.7	12.7	88	-25
							HFC-1243zf	HFC-134	63.0	37.0	13.5	93	-25
HFC-1243zf	HFC-134A	25.1	74.9	15.9	110	-25
							HFC-1243zf	HFC-152A	40.7	59.3	15.2	104	-25
HFC-1243zf	HFC-227ea	78.5	21.5	13.1	90	-25
							HFC-1243zf	Propane	32.8	67.2	31.0	213	-25
HFC-1243zf	Normal butane	90.3	9.7	13.5	93	-25
							HFC-1243zf	Trimethylmethane	80.7	19.3	14.3	98	-25
HFC-1243zf	DME	72.7	27.3	12.0	83	-25
							cis-HFC-1234ze	HFC-236ea	20.9	79.1	30.3	209	25
cis-HFC-1234ze	HFC-245fa	76.2	23.8	26.1	180	25
							cis-HFC-1234ze	Normal butane	51.4	48.6	6.08	42	-25
cis-HFC-1234ze	Trimethylmethane	26.2	73.8	8.74	60	-25
							cis-HFC-1234ze	The 2-methylbutane	86.6	13.4	27.2	188	25
cis-HFC-1234ze	Skellysolve A	92.9	7.1	26.2	181	25
							HFC-1234ye	HFC-236ea	24.0	76.0	3.35	23.1	-25
HFC-1234ye	HFC-245fa	42.5	57.5	22.8	157	25
							HFC-1234ye	Normal butane	41.2	58.8	38.0	262	25
HFC-1234ye	Trimethylmethane	16.4	83.6	50.9	351	25
							HFC-1234ye	The 2-methylbutane	80.3	19.7	23.1	159	25
HFC-1234ye	Skellysolve A	87.7	12.3	21.8	150	25

In addition, have been found that the ternary azeotropic compositions listed as table 4.

Table 4

Component A	B component	Component C	Wt％ A	Wt％ B	Wt％ C	Pres (psi)	Pres (kPa)	Temp (℃)
									HFC-1234yf	HFC-32	HFC-143A	3.9	74.3	21.8	50.02	345	-25
HFC-1234yf	HFC-32	Trimethylmethane	1.1	92.1	6.8	50.05	345	-25
									HFC-1234yf	HFC-125	HFC-143A	14.4	43.5	42.1	38.62	266	-25
HFC-1234yf	HFC-125	Trimethylmethane	9.7	89.1	1.2	40.81	281	-25

HFC-1234yf	HFC-134	Propane	4.3	39.1	56.7	34.30	236	-25
									HFC-1234yf	HFC-134	DME	15.2	67.0	17.8	10.38	71.6	-25
HFC-1234yf	HFC-134a	Propane	24.5	31.1	44.5	34.01	234	-25
									HFC-1234yf	HFC-134a	Normal butane	60.3	35.2	4.5	18.58	128	-25
HFC-1234yf	HFC-134a	Trimethylmethane	48.6	37.2	14.3	19.86	137	-25
									HFC-1234yf	HFC-134a	DME	24.0	67.9	8.1	17.21	119	-25
HFC-1234yf	HFC-143a	Propane	17.7	71.0	11.3	40.42	279	-25
									HFC-1234yf	HFC-143a	DME	5.7	93.0	1.3	39.08	269	-25
HFC-1234yf	HFC-152a	Normal butane	86.6	10.8	2.7	17.97	124	-25
									HFC-1234yf	HFC-152a	Trimethylmethane	75.3	11.8	12.9	19.12	132	-25
HFC-1234yf	HFC-152a	DME	24.6	43.3	32.1	11.78	81.2	-25
									HFC-1234yf	HFC-227ea	Propane	35.6	17.8	46.7	33.84	233	-25
HFC-1234yf	HFC-227ea	Normal butane	81.9	16.0	2.1	18.07	125	-25
									HFC-1234yf	HFC-227ea	Trimethylmethane	702	18.2	11.6	19.27	133	-25
HFC-1234yf	HFC-227ea	DME	28.3	55.6	16.1	15.02	104	-25
									HFC-1234yf	Normal butane	DME	48.9	4.6	46.4	13.15	90.7	-25
HFC-1234yf	Trimethylmethane	DME	31.2	26.2	42.6	14.19	97.8	-25
									HFC-1234yf	DME	CF 3I	16.3	10.0	73.7	15.65	108	-25
HFC-1234yf	DME	CF 3SCF 3	34.3	10.5	55.2	14.57	100	-25
									HFC-1225ye	trans-HFC- 1234ze	HFC-134	47.4	5.6	47.0	12.77	88.0	-25
HFC-1225ye	trans-HFC- 1234ze	HFC-227ea	28.4	52.6	19.0	11.63	80.2	-25
									HFC-1225ye	trans-HFC- 1234ze	Propane	20.9	9.1	70.0	30.36	209	-25
HFC-1225ye	trans-HFC- 1234ze	Normal butane	65.8	24.1	10.1	12.39	85.4	-25
									HFC-1225ye	trans-HFC- 1234ze	DME	41.0	40.1	18.9	10.98	75.7	-25
HFC-1225ye	trans-HFC- 1234ze	CF 3SCF 3	1.0	33.7	65.2	12.66	87.3	-25
									HFC-1225ye	HFC-1243zf	HFC-134	28.7	47.3	24.1	13.80	95.1	-25
HFC-1225ye	HFC-1243zf	Normal butane	37.5	55.0	7.5	13.95	96.2	-25
									HFC-1225ye	HFC-1243zf	Trimethylmethane	40.5	43.2	16.3	14.83	102	-25
HFC-1225ye	HFC-1243zf	DME	19.1	51.0	29.9	12.15	83.8	-25
									HFC-1225ye	HFC-1243zf	CF 3I	10.3	27.3	62.3	14.05	96.9	-25

HFC-1225ye	HFC-134	HFC-152a	63.6	26.8	9.6	12.38	85.4	-25
									HFC-1225ye	HFC-134	HFC-227ea	1.3	52.3	46.4	12.32	84.9	-25
HFC-1225ye	HFC-134	Normal butane	18.1	67.1	14.9	14.54	100	-25
									HFC-1225ye	HFC-134	Trimethylmethane	0.7	74.0	25.3	16.68	115	-25
HFC-1225ye	HFC-134	DME	29.8	52.5	17.8	9.78	67.4	-25
									HFC-1225ye	HFC-227ea	DME	63.1	31.0	5.8	10.93	75.4	-25
HFC-1225ye	Normal butane	DME	66.0	13.0	21.1	11.34	78.2	-25
									HFC-1225ye	Normal butane	CF 3SCF 3	71.3	5.6	23.0	12.25	84.5	-25
HFC-1225ye	Trimethylmethane	DME	49.9	29.7	20.4	12.83	88.5	-25
									HFC-1225ye	Trimethylmethane	CF 3I	27.7	2.2	70.1	13.19	90.9	-25
trans-HFC- 1234ze	HFC-1243zf	HFC-227ea	7.1	73.7	19.2	13.11	90.4	-25
									trans-HFC- 1234ze	HFC-1243zf	Normal butane	9.5	81.2	9.3	13.48	92.9	-25
trans-HFC- 1234ze	HFC-1243zf	Trimethylmethane	3.3	77.6	19.1	14.26	98.3	-25
									trans-HFC- 1234ze	HFC-1243zf	DME	2.6	70.0	27.4	12.03	82.9	-25
trans-HFC- 1234ze	HFC-134	HFC-152a	52.0	42.9	5.1	12.37	85.3	-25
									trans-HFC- 1234ze	HFC-134	HFC-227ea	30.0	43.2	26.8	12.61	86.9	-25
trans-HFC- 1234ze	HFC-134	DME	27.7	54.7	17.7	9.76	67.3	-25
									trans-HFC- 1234ze	HFC-134a	HFC-152a	14.4	34.7	51.0	14.42	99.4	-25
trans-HFC- 1234ze	HFC-152a	Normal butane	5.4	80.5	14.1	15.41	106	-25
									trans-HFC- 1234ze	HFC-152a	DME	59.1	16.4	24.5	10.80	74.5	-25
trans-HFC- 1234ze	HFC-227ea	Normal butane	40.1	48.5	11.3	12.61	86.9	-25
									trans-HFC- 1234ze	Normal butane	DME	68.1	13.0	18.9	11.29	77.8	-25
trans-HFC- 1234ze	Normal butane	CF 3I	81.2	9.7	9.1	11.87	81.8	-25

trans-HFC- 1234ze	Trimethylmethane	DME	55.5	28.7	15.8	12.38	85.4	-25
									trans-HFC- 1234ze	Trimethylmethane	CF 3I	34.9	6.1	59.0	12.57	86.7	-25
trans-HFC- 1234ze	Trimethylmethane	CF 3SCF 3	37.7	1.1	61.7	12.66	87.3	-25
									HFC-1243zf	HFC-134	HFC-227ea	58.6	34.1	7.3	13.54	93.4	-25
HFC-1243zf	HFC-134	Normal butane	27.5	58.7	13.9	14.72	101	-25
									HFC-1243zf	HFC-134	DME	18.7	63.5	17.8	10.11	69.7	-25
HFC-1243zf	HFC-134	CF 3I	11.4	23.9	64.7	14.45	99.6	-25
									HFC-1243zf	HFC-134a	HFC-152a	41.5	21.5	37.1	14.95	103	-25
HFC-1243zf	HFC-134A	Normal butane	7.0	81.4	11.6	17.03	117	-25
									HFC-1243zf	HFC-152a	Propane	2.9	34.0	63.0	31.73	219	-25
HFC-1243zf	HFC-152a	Normal butane	28.8	60.3	11.0	15.71	108	-25
									HFC-1243zf	HFC-152a	Trimethylmethane	6.2	68.5	25.3	17.05	118	-25
HFC-1243zf	HFC-152a	DME	33.1	36.8	30.1	11.41	78.7	-25
									HFC-1243zf	HFC-227ea	Normal butane	62.0	28.4	9.6	13.67	94.3	-25
HFC-1243zf	HFC-227ea	Trimethylmethane	27.9	51.0	21.1	15.00	103	-25
									HFC-1243zf	HFC-227ea	DME	48.1	44.8	7.2	12.78	88.1	-25
HFC-1243zf	Normal butane	DME	60.3	10.1	29.6	12.28	84.7	-25
									HFC-1243zf	Trimethylmethane	DME	47.1	26.9	25.9	13.16	90.7	-25
HFC-1243zf	Trimethylmethane	CF 3I	32.8	1.1	66.1	13.97	96.3	-25
									HFC-1243.zf	DME	CF 3SCF 3	41.1	2.3	56.6	13.60	93.8	-25

Of the present inventionly under specified temperature list in the table 5 near the azeotropic composition.

Table 5

Component A	B component	(wt％A/wt％B)	T(C)
				HFC-1234yf	HFC-32	1-57/99-43	-25
HFC-1234yf	HFC-125	1-51/99-49	-25
				HFC-1234yf	HFC-134	1-99/99-1	-25
HFC-1234yf	HFC-134a	1-99/99-1	-25
				HFC-1234yf	HFC-152a	1-99/99-1	-25
HFC-1234yf	HFC-161	1-99/99-1	-25
				HFC-1234yf	HFC-143a	1-60/99-40	-25
HFC-1234yf	HFC-227ea	29-99/71-1	-25
				HFC-1234yf	HFC-236fa	66-99/34-1	-25
HFC-1234yf	HFC-1225ye	1-99/99-1	-25

HFC-1234yf	trans-HFC-1234ze	1-99/99-1	-25
				HFC-1234yf	HFC-1243zf	1-99/99-1	-25
HFC-1234yf	Propane	1-80/99-20	-25
				HFC-1234yf	Normal butane	71-99/29-1	-25
HFC-1234yf	Trimethylmethane	60-99/40-1	-25
				HFC-1234yf	DME	1-99/99-1	-25
HFC-1225ye	trans-HFC-1234ze	1-99/99-1	-25
				HFC-1225ye	HFC-1243zf	1-99/99-1	-25
HFC-1225ye	HFC-134	1-99/99-1	-25
				HFC-1225ye	HFC-134a	1-99/99-1	-25
HFC-1225ye	HFC-152a	1-99/99-1	-25
				HFC-1225ye	HFC-161	1-84/99-16，90- 99/10-1	-25
HFC-1225ye	HFC-227ea	1-99/99-1	-25
				HFC-1225ye	HFC-236ea	57-99/43-1	-25
HFC-1225ye	HFC-236fa	48-99/52-1	-25
				HFC-1225ye	HFC-245fa	70-99/30-1	-25
HFC-1225ye	Propane	1-72/99-28	-25
				HFC-1225ye	Normal butane	65-99/35-1	-25
HFC-1225ye	Trimethylmethane	50-99/50-1	-25
				HFC-1225ye	DME	1-99/99-1	-25
HFC-1225ye	CF 3I	1-99/99-1	-25
				HFC-1225ye	CF 3SCF 3	1-99/99-1	-25
trans-HFC-1234ze	trans-HFC-1234ze	73-99/27-1	-25
				trans-HFC-1234ze	HFC-1243zf	1-99/99-1	-25
trans-HFC-1234ze	HFC-134	1-99/99-1	-25
				trans-HFC-1234ze	HFC-134a	1-99/99-1	-25
trans-HFC-1234ze	HFC-152a	1-99/99-1	-25
				trans-HFC-1234ze	HFC-161	1-52/99-48，87- 99/13-1	-25
trans-HFC-1234ze	HFC-227ea	1-99/99-1	-25
				trans-HFC-1234ze	HFC-236ea	54-99/46-1	-25
trans-HFC-1234ze	HFC-236fa	44-99/56-1	-25
				trans-HFC-1234ze	HFC-245fa	67-99/33-1	-25
trans-HFC-1234ze	Propane	1-71/99-29	-25
				trans-HFC-1234ze	Normal butane	62-99/38-1	-25
trans-HFC-1234ze	Trimethylmethane	39-99/61-1	-25
				trans-HFC-1234ze	DME	1-99/99-1	-25
trans-HFC-1234ze	CF 3SCF 3	1-99/99-1	-25
				trans-HFC-1234ze	CF 3I	1-99/99-1	-25
HFC-1243zf	HFC-134	1-99/99-1	-25
				HFC-1243zf	HFC-134a	1-99/99-1	-25
HFC-1243zf	HFC-152a	1-99/99-1	-25
				HFC-1243zf	HFC-161	1-99/99-1	-25
HFC-1243zf	HFC-227ea	1-99/99-1	-25
				HFC-1243zf	HFC-236ea	53-99/47-1	-25

HFC-1243zf	HFC-236fa	49-99/51-1	-25
				HFC-1243zf	HFC-245fa	66-99/34-1	-25
HFC-1243zf	Propane	1-71/99-29	-25
				HFC-1243zf	Normal butane	62-99/38-1	-25
HFC-1243zf	Trimethylmethane	45-99/55-1	-25
				HFC-1243zf	DME	1-99/99-1	-25
cis-HFC-1234ze	HFC-236ea	1-99/99-1	25
				cis-HFC-1234ze	HFC-236fa	1-99/99-1	25
cis-HFC-1234ze	HFC-245fa	1-99/99-1	25
				cis-HFC-1234ze	Normal butane	1-80/99-20	-25
cis-HFC-1234ze	Trimethylmethane	1-69/99-31	-25
				cis-HFC-1234ze	The 2-methylbutane	60-99/40-1	25
cis-HFC-1234ze	Skellysolve A	63-99/37-1	25
				HFC-1234ye	HFC-134	38-99/62-1	25
HFC-1234ye	HFC-236ea	1-99/99-1	-25
				HFC-1234ye	HFC-236fa	1-99/99-1	25
HFC-1234ye	HFC-245fa	1-99/99-1	25
				HFC-1234ye	cis-HFC-1234ze	1-99/99-1	25
HFC-1234ye	Normal butane	1-78/99-22	25
				HFC-1234ye	Pentamethylene	70-99/30-1	25
HFC-1234ye	Trimethylmethane	1-68/99-32	25
				HFC-1234ye	The 2-methylbutane	47-99/53-1	25
HFC-1234ye	Skellysolve A	57-99/43-1	25

As table 6 listed comprise the ternary of fluoroolefins and more high-order also be determined near Azeotrope compositions.

Table 6

Component	Near azeotropic scope (wt%)	Temperature (℃)
			HFC-1225ye/HFC-134a/HFC-152a	1-98/1-98/1-98	25
HFC-1225ye/HFC-134a/HFC-161	1-98/1-98/1-98	25
			The HFC-1225ye/HFC-134a/ Trimethylmethane	1-98/1-98/1-40	25
HFC-1225ye/HFC-134a/DME	1-98/1-98/1-20	25
			The HFC-1225ye/HFC-152a/ Trimethylmethane	1-98/1-98/1-50	25
HFC-1225ye/HFC-152a/DME	1-98/1-98/1-98	25
			HFC-1225ye/HFC-1234yf/HFC-134a	1-98/1-98/1-98	25
HFC-1225ye/HFC-1234yf/HFC-152a	1-98/1-98/1-98	25
			HFC-1225ye/HFC-1234yf/HFC-125	1-98/1-98/1-20	25
HFC-1225ye/HFC-1234yf/C F 3I	1-98/1-98/1-98	25
			HFC-1225ye/HFC-134a/HFC- 152a/HFC-32	1-97/1-97/1-97/1-10	25

The HFC-125/HFC-1225ye/ Trimethylmethane	80-98/1-19/1-10	25
			HFC-125/trans-HFC-1234ze/ Trimethylmethane	80-98/1-19/1-10	25
The HFC-125/HFC-1234yf/ Trimethylmethane	80-98/1-19/1-10	25
			HFC-32/HFC-125/HFC-1225ye	1-98/1-98/1-4	25
HFC-32/HFC-125//trans-HFC-1234ze	1-98/1-98/1-5	25
			HFC-32/HFC-125/HFC-1234yf	1-98/1-98/1-55	25
The HFC-125/trans-HFC-1234ze/ normal butane	80-98/1-19/1-10	25
			The HFC-125/HFC-1234yf/ normal butane	80-98/1-19/1-10	25
HFC-1234yf/HFC-32/HFC-143a	1-50/1-98/1-98	-25
			The HFC-1234yf/HFC-32/ Trimethylmethane	1-40/59-98/1-30	-25
HFC-1234yf/HFC-125/HFC-143a	1-60/1-98/1-98	-25
			The HFC-1234yf/HFC-125/ Trimethylmethane	1-40/59-98/1-20	-25
HFC-1234yf/HFC-134/ propane	1-80/1-70/19-90	-25
			HFC-1234yf/HFC-134/DME	1-70/1-98/29-98	-25
HFC-1234yf/HFC-134a/ propane	1-80/1-80/19-98	-25
			The HFC-1234yf/HFC-134a/ normal butane	1-98/1-98/1-30	-25
The HFC-1234yf/HFC-134a/ Trimethylmethane	1-98/1-98/1-30	-25
			HFC-1234tf/HFC-134a/DME	1-98/1-98/1-40	-25
HFC-1234yf/HFC-143a/ propane	1-80/1-98/1-98	-25
			HFC-1234yf/HFC-143a/DME	1-40/59-98/1-20	-25
The HFC-1234yf/HFC-152a/ normal butane	1-98/1-98/1-30	-25
			The HFC-1234yf/HFC-152a/ Trimethylmethane	1-98/1-90/1-40	-25
HFC-1234yf/HFC-152a/DME	1-70/1-98/1-98	-25
			HFC-1234yf/HFC-227ea/ propane	1-80/1-70/29-98	-25
The HFC-1234yf/HFC-227ea/ normal butane	40-98/1-59/1-20	-25
			The HFC-1234yf/HFC-227ea/ Trimethylmethane	30-98/1-69/1-30	-25
HFC-1234yf/HFC-227ea/DME	1-98/1-80/1-98	-25
			HFC-1234yf/ normal butane/DME	1-98/1-40/1-98	-25
HFC-1234yf/ Trimethylmethane/DME	1-98/1-50/1-98	-25
			HFC-1234yf/DME/CF 3I	1-98/1-98/1-98	-25
HFC-1234yf/DME/CF 3SCF 3	1-98/1-40/1-80	-25
			HFC-1225ye/trans-HFC- 1234ze/HFC-134	1-98/1-98/1-98	-25
HFC-1225ye/trans-HFC- 1234ze/HFC-227ea	1-98/1-98/1-98	-25

HFC-1225ye/trans-HFC-1234ze/ propane	1-60/1-60/39-98	-25
			The HFC-1225ye/trans-HFC-1234ze/ normal butane	1-98/1-98/1-30	-25
HFC-1225ye/trans-HFC-1234ze/DME	1-98/1-98/1-98	-25
			HFC-1225ye/trans-HFC-1234ze/ CF 3SCF 3	1-98/1-98/1-98	-25
HFC-1225ye/HFC-1243zf/HFC-134	1-98/1-98/1-98	-25
			The HFC-1225ye/HFC-1243zf/ normal butane	1-98/1-98/1-30	-25
The HFC-1225ye/HFC-1243zf/ Trimethylmethane	1-98/1-98/1-40	-25
			HFC-1225ye/HFC-1243zf/DME	1-98/1-98/1-98	-25
HFC-1225ye/HFC-1243zf/CF 3I	1-98/1-98/1-98	-25
			HFC-1225ye/HFC-134/HFC-152a	1-98/1-98/1-98	-25
HFC-1225ye/HFC-134/HFC-227ea	1-98/1-98/1-98	-25
			The HFC-1225ye/HFC-134/ normal butane	1-98/1-90/1-40	-25
The HFC-1225ye/HFC-134/ Trimethylmethane	1-98/1-90/1-40	-25
			HFC-1225ye/HFC-134/DME	1-98/1-98/1-40	-25
HFC-1225ye/HFC-227ea/DME	40-98/1-59/1-30	-25
			HFC-1225ye/ normal butane/DME	1-98/1-30/1-98	-25
HFC-1225ye/ normal butane/CF 3SCF 3	1-98/1-20/1-98	-25
			HFC-1225ye/ Trimethylmethane/DME	1-98/1-60/1-98	-25
HFC-1225ye/ Trimethylmethane/CF 3I	1-98/1-40/1-98	-25
			trans-HFC-1234ze/HFC-1243zf/HFC- 227ea	1-98/1-98/1-98	-25
The trans-HFC-1234ze/HFC-1243zf/ normal butane	1-98/1-98/1-30	-25
			Trans-HFC-1234ze/HFC-1243zf/ Trimethylmethane	1-98/1-98/1-40	-25
trans-HFC-1234ze/HFC-1243zf/DME	1-98/1-98/1-98	-25
			trans-HFC-1234ze/HFC-134/HFC- 152a	1-98/1-98/1-98	-25
trans-HFC-1234ze/HFC-134/HFC- 227ea	1-98/1-98/1-98	-25
			trans-HFC-1234ze/HFC-134/DME	1-98/1-98/1-40	-25
trans-HFC-1234ze/HFC-134a/HFC- 152a	1-98/1-98/1-98	-25

The trans-HFC-1234ze/HFC-152a/ normal butane	1-98/1-98/1-50	-25
			trans-HFC-1234ze/HFC-152a/DME	1-98/1-98/1-98	-25
The trans-HFC-1234ze/HFC-227ea/ normal butane	1-98/1-98/1-40	-25
			Trans-HFC-1234ze/ normal butane/DME	1-98/1-40/1-98	-25
Trans-HFC-1234ze/ normal butane/CF 3I	1-98/1-30/1-98	-25
			Trans-HFC-1234ze/ Trimethylmethane/DME	1-98/1-60/1-98	-25
Trans-HFC-1234ze/ Trimethylmethane/CF 3I	1-98/1-40/1-98	-25
			Trans-HFC-1234ze/ Trimethylmethane/CF 3SCF 3	1-98/1-40/1-98	-25
HFC-1243zf/HFC-134/HFC-227ea	1-98/1-98/1-98	-25
			The HFC-1243zf/HFC-134/ normal butane	1-98/1-98/1-40	-25
HFC-1243zf/HFC-134/DME	1-98/1-98/1-98	-25
			HFC-1243zf/HFC-134/CF 3I	1-98/1-98/1-98	-25
HFC-1243zf/HFC-134a/HFC-152a	1-98/1-98/1-98	-25
			The HFC-1243zf/HFC-134a/ normal butane	1-98/1-98/1-40	-25
HFC-1243zf/HFC-152a/ propane	1-70/1-70/29-98	-25
			The HFC-1243zf/HFC-152a/ normal butane	1-98/1-98/1-30	-25
The HFC-1243zf/HFC-152a/ Trimethylmethane	1-98/1-98/1-40	-25
			HFC-1243zf/HFC-152a/DME	1-98/1-98/1-98	-25
The HFC-1243zf/HFC-227ea/ normal butane	1-98/1-98/1-40	-25
			The HFC-1243zf/HFC-227ea/ Trimethylmethane	1-98/1-90/1-50	-25
HFC-1243zf/HFC-227ea/DME	1-98/1-80/1-90	-25
			HFC-1243zf/ normal butane/DME	1-98/1-40/1-98	-25
HFC-1243zf/ Trimethylmethane/DME	1-98/1-60/1-98	-25
			HFC-1243zf/ Trimethylmethane/CF 3I	1-98/1-40/1-98	-25
HFC-1243zf/DME/CF 3SCF 3	1-98/140/1-90	-25

Some composition of the present invention is non-Azeotrope compositions.The preferable range that belongs to table 2, but can think it is non-azeotropic at table 5 and table 6 near those compositions of the present invention outside the azeotropic scope.

Non-Azeotrope compositions can have some and be better than azeotropic or near the advantage of azeotropic mixture.Non-Azeotrope compositions is the mixture that shows as two or more materials of mixture rather than one matter.A kind of method that characterizes non-Azeotrope compositions be steam that part evaporation by liquid or distillation produce have and its evaporation or distillation from the remarkable different composition of liquid, i.e. this mixture distillation/backflow under sizable composition changes.The another kind of method that characterizes non-Azeotrope compositions is that the bubble point vapour pressure of said composition under specified temp is significantly different with the dew point vapour pressure.At this, if after removing the 50wt% of composition (for example by evaporating or boiling and remove), original composition and removing after the 50wt% original composition vapour pressure difference between the remaining composition greater than about 10%, then said composition is non-azeotropic.

Composition of the present invention can be mixed each component of aequum by any suitable method and prepare.Preferable methods is the amount of the required component of weighing, in suitable containers these components is mixed afterwards.If necessary, can use stirring.

The replacement means of the preparation present composition can be the methods for preparing the cooling agent blend composition, wherein said cooling agent blend composition comprises composition disclosed herein, described method comprises: a large amount of one or more components that (i) reclaim refrigerant compositions from least one cryogen vessel, (ii) impurity is removed to being enough to that the component of described one or more recovery can be re-used, (iii) and randomly, the component of the described yield of all or part is mixed with at least a additional refrigerant compositions or component.

Cryogen vessel can be any container, has wherein stored the cooling agent blend composition that once is used for refrigeration equipment, conditioning unit or heat-pump apparatus.Described cryogen vessel can be refrigeration equipment, conditioning unit or the heat-pump apparatus that wherein uses described cooling agent blend.In addition, cryogen vessel can be the holder that is used to collect the cooling agent blend component that is reclaimed, and includes but not limited to pressurized cylinder.

Remaining cooling agent is meant any amount of cooling agent blend or cooling agent blend component, and it can be discharged from cryogen vessel by any method that becomes known for transmitting cooling agent blend or cooling agent blend component.

Impurity can be any because its use in refrigeration equipment, conditioning unit or heat-pump apparatus and component in cooling agent blend or cooling agent blend component.These impurity include but not limited to refrigeration lubricant, they are previous those that describe of this paper, include but not limited to the particulate of metal, metal-salt or elastomer particles, they may may influence the impurity of the performance of cooling agent blend composition unfriendly from refrigeration equipment, conditioning unit or heat-pump apparatus and any other.

These impurity can be removed and go to the performance that is enough to allow to re-use cooling agent blend or cooling agent blend component and can influences the device that described cooling agent blend or cooling agent blend component will use therein sharply.

In order to produce the composition that conforms with the required specification of given product, with additional cooling agent blend or the cooling agent blend component offers remaining cooling agent blend or the cooling agent blend component may be necessary.For example, if the cooling agent blend has 3 kinds of components in specified weight percentage scope, then add one or more components so that said composition returns to may be necessary in the specification limits by specified rate.

Composition of the present invention has zero or low ozone depleting potential and low global warming potential (GWP).In addition, composition of the present invention will have than the present low global warming potential of many hydrogen fluorine carbon cooling agent in usefulness.One aspect of the present invention provides global warming potential less than 1000, less than 500, less than 150, less than 100 or less than 50 cooling agent.Another aspect of the present invention is by adding the clean GWP that fluoroolefins reduces refrigerant mixture to described mixture.

The present composition can be as low global warming potential (GWP) quid pro quo of the cooling agent that uses at present, the cooling agent of described present use includes but not limited to: R134a (or HFC-134a, 1,1,1, the 2-Tetrafluoroethane), R22 (or HCFC-22, monochlorodifluoromethane), R123 (or HFC-123,2,2-two chloro-1,1, the 1-Halothane), R11 (CFC-11, fluoro trichloromethane), R12 (CFC-12, Refrigerant 12), R245fa (or HFC-245fa, 1,1,1,3, the 3-pentafluoropropane), R114 (or CFC-114,1,2-two chloro-1,1,2, the 2-Tetrafluoroethane), R236fa (or HFC-236fa, 1,1,1,3,3, the 3-HFC-236fa), R124 (or HCFC-124,2-chloro-1,1,1, the 2-Tetrafluoroethane), R407C (52wt%R134a, the ASHRAE name of the blend of 25wt%R125 (pentafluoride ethane) and 23wt%R32 (methylene fluoride)), R410A (the ASHRAE name of the blend of 50wt%R125 and 50wt%R32), R417A (46.6wt%R125, the ASHRAE name of the blend of 50.0wt%R134a and 34wt% normal butane), R422A (85.1wt%R125, the ASHRAE name of the blend of 11.5wt%R134a and 3.4wt% Trimethylmethane), R404A (44wt%R125,52wt%R143a (1,1,1-Halothane) and the ASHRAE of the blend of 4.0wt%R134a name) and R507A (ASHRAE of the blend of 50wt%R125 and 50wt%R143a names).In addition, composition of the present invention can be used as the quid pro quo of R12 (CFC-12, Refrigerant 12) or R502 (the ASHRAE name of the blend of 51.2wt%CFC-115 (chloropentafluoroethane) and 48.8wt%HCFC-22).

Usually, if can be used in the original refrigeration unit that designs for different cooling agent, then quid pro quo cooling agent is the most useful.Composition of the present invention can be as the quid pro quo of the above-mentioned cooling agent in the primitive apparatus.In addition, composition of the present invention can be as the quid pro quo of the above-mentioned cooling agent in the device of the above-mentioned cooling agent of design use.

The present composition can further comprise lubricant.

Lubricant of the present invention comprises refrigeration lubricant, promptly is suitable for freezing, those lubricants of air-conditioning or heat-pump apparatus.These lubricants are included in those that use always in the compression refrigeration equipment that uses fluorochlorohydrocarbon cooling agent.The performance of these lubricants and they is at 1990 ASHRAEH Handbook, Refrigeration Systems and Applications, and the 8th chapter is entitled as " Lubricants inRefrigeration Systems ", discusses in 8.1 to 8.21 pages.Lubricant of the present invention can comprise those that are commonly referred to " mineral oil " in the lubricated field of compression refrigeration.Mineral oil comprises paraffin (being straight chain and branching carbochain, stable hydrocarbon), naphthalene (being cyclic paraffins) and aromatic substance (promptly containing one or more unsaturated cyclic hydrocarbon that are characterised in that the ring of alternately two keys).Lubricant of the present invention further comprises those that are commonly referred to " synthetic oil " in the lubricated field of compression refrigeration.Synthetic oil comprises alkyl aryl compound (promptly linear and branched-alkyl alkylbenzene), synthetic paraffin and naphthenic hydrocarbon and poly-(alhpa olefin).Representational traditional lubrication agent of the present invention is commercially available BVM 100N (by the paraffin mineral oil of BVA Oils sale),

3GS and

5GS (by the naphthenic mineral oil of CromptonCo. sale),

372LT (by the naphthenic mineral oil of Pennzoil sale),

RO-30 (by the naphthenic mineral oil of Calumet Lubricants sale),

75,

150 Hes 500 (by LINEAR ALKYL BENZENE (LAB) of Shrieve Chemicals sale) and HAB22 (by the branched-alkyl benzene of Nippon Oil sale).

Lubricant of the present invention further comprise designed with hydrogen fluorine carbon cooling agent use and under the operational condition of compression refrigeration, air-conditioning or heat-pump apparatus can with those of cooling agent mixing of the present invention.The performance of these lubricants and they is at " Synthetic Lubricants and High-Performance Fluids ", R.L.Shubkin, editor, and Marcel Dekker discusses in 1993.These lubricants include but not limited to that polyol ester (POE) for example

100 (Castrol, United Kingdom), polyalkylene glycol (PAG) for example derive from Dow (DowChemical, Midland, RL-488A Michigan), and polyvingl ether (PVE).These lubricants can easily obtain from various commercial sources.

Lubricant of the present invention is selected by the requirement of given compressor and lubricant are taken in the environment that touches.Lubricant of the present invention preferably has at least approximately dynamic viscosity of 5cs (centistoke) under 40 ℃.

As required, refrigerating system additive commonly used can randomly add in the composition of the present invention, to improve oilness and system stability.These additives are known in the lubricated field of refrigeration compressor, and comprise, antiwear agents, and limit lubricant, corrosion and oxidation retarder, the metallic surface deactivator, free-radical scavengers bubbles and the froth breaking control agent leak detectants etc.Usually, these additives with respect to total lubricant compositions only to exist on a small quantity.Typically, with from being lower than about 0.1% to using them up to the concentration of about 3% each additive.These additives bases system requirements are separately selected.Some representative instances of these additives can include, but not limited to lubricated enhancement additive, as the alkyl or aryl ester of phosphoric acid and thiophosphatephosphorothioate.In addition, the dialkyl dithiophosphoric acid metal-salt (for example zinc dialkyl dithiophosphate or ZDDP, Lubrizol1375) and other member of this class chemical can be used in the composition of the present invention.Other wear preventive additive comprises natural product oil and asymmetric poly-hydroxy slip additive, as Synergol TMS (International Lubricants).Similarly, stablizer such as oxidation inhibitor, free-radical scavengers and water scavenging agent can use.Compound in this kind can include, but not limited to Yoshinox BHT (BHT) and epoxide.

Composition of the present invention can further comprise about 0.01wt% to about 5wt% additive, for example, and stablizer, free-radical scavengers and/or antioxidant.These additives comprise but are not limited to Nitromethane 99Min., hindered phenol, azanol, mercaptan, phosphorous acid ester or lactone.Can use single additive or combination.

Composition of the present invention can further comprise the water scavenging agent (dry use compound) of about 0.01wt% to about 5wt%.These water scavenging agents can comprise ortho ester such as trimethylammonium-, triethyl-or tripropyl ortho-formiate.

Composition of the present invention can further comprise tracer agent, and it is selected from hydrogen fluorine carbon (HFC), deuteroparaffin, hydrogen deuteride fluorine carbon, perfluoroparaffin, fluoroether, brominated compound, iodinated compounds, alcohol, aldehyde, ketone, nitrous oxide (N ₂O) and their combination.Add tracer compounds in the composition any dilution, pollution or other change by predetermined amount, as described in the U.S. Patent Application Serial Number of submitting on February 18th, 2,005 11/062044 to allow detection composition.

The typical tracer compounds that is used for the present composition is listed in table 7.

Table 7

The compound of listing in the table 7 is that (being purchased from chemical supplier) that is purchased maybe can be by method preparation as known in the art.

Can in composition of the present invention, single tracer compounds and refrigeration/heating fluid be used in combination maybe and can multiple tracer compounds be mixed to serve as the tracer agent blend in any ratio.The tracer agent blend can comprise from the multiple tracer compounds of identical category compound or from the multiple tracer compounds of different classes of compound.For example, the tracer agent blend can comprise two or more hydrogen deuteride fluorine carbon, or a kind of hydrogen deuteride fluorine carbon and with it the combination one or more perfluoroparaffins.

In addition, some compounds in the table 7 exist as multiple isomer (constitutional isomer or optical isomer).The individual isomer of same compound or multiple isomer can use with the preparation tracer compounds in any ratio.In addition, the single or multiple isomer of given compound can combine to serve as the tracer agent blend with many other compounds in any ratio.

Tracer compounds or tracer agent blend can be by about 50 weight parts/1,000,000 weight parts (ppm)-approximately the total concn of 1000ppm is present in the composition.Preferably, tracer compounds or tracer agent blend exist with the total concn of the about 500ppm of about 50ppm-, and most preferably, tracer compounds or tracer agent blend exist with the total concn of the about 300ppm of about 100ppm-.

Composition of the present invention can further comprise and is selected from the poly suboxygen alkyl glycol ethers, acid amides, nitrile, ketone, hydrochloric ether, ester, lactone, aryl ethers, fluoroether and 1,1, the expanding material of 1-trifluoro alkane.Described expanding material is used for improving the solvability of hydrogen fluorine carbon cooling agent in conventional refrigeration lubricant.Need refrigeration lubricant to lubricate the compressor of refrigeration, air-conditioning or heat-pump apparatus.Lubricant must move with cooling agent in entire equipment, and especially, it must turn back to compressor to continue the super fatting agent effect and to avoid compressor failure from non-compressor section.

Hydrogen fluorine carbon cooling agent is not compatible with poly-(α) alkene with conventional refrigeration lubricant such as mineral oil, alkylbenzene, synthetic paraffin, synthetic naphthenic hydrocarbon usually.Proposed many quid pro quo lubricants, yet polyalkylene glycol, polyol ester and the polyvingl ether that suggestion is used with hydrogen fluorine carbon cooling agent is expensive and easy suction.Water in refrigeration, air-conditioning system or heat pump can cause that corrosion and particulate form, and described particle may stop up other aperture in kapillary and the system, thereby finally causes thrashing.In addition, in existing installation, need consuming time and expensive wash procedure to make change according to new lubricant.Therefore, be desirable as continuing to use original lubricant.

Therefore the solvability of expanding material improvement hydrogen fluorine carbon cooling agent of the present invention in conventional refrigeration lubricant also improve the oil return to compressor.

Poly suboxygen alkyl glycol ethers expanding material of the present invention is by general formula R ¹[(OR ²) xOR ³] y represents that wherein: x is the integer of 1-3; Y is the integer of 1-4; R ¹Be selected from hydrogen and the aliphatic hydrocarbyl that contains 1-6 carbon atom and y keyed jointing position; R ²Be selected from the aliphatic alkylene that contains 2-4 carbon atom; R ³Be selected from hydrogen and the aliphatic series and the alicyclic alkyl that contain 1-6 carbon atom; R ¹And R ³In at least one is selected from described alkyl; And wherein said poly suboxygen alkyl glycol ethers has the molecular weight of about 300 atomic mass units of about 100-.The employed keyed jointing of this paper position is meant the position that can be used for other group formation covalent linkage.Alkylene is meant bivalent hydrocarbon radical.In the present invention, preferred poly suboxygen alkyl glycol ethers expanding material is by general formula R ¹[(OR ²) xOR ³] y represents that x is preferably 1-2; Y is preferably 1; R ¹And R ³Preferably be independently selected from hydrogen and the aliphatic hydrocarbyl that contains 1-4 carbon atom; R ²Be preferably selected from and contain 2 or 3 carbon atoms, most preferably the aliphatic alkylene of 3 carbon atoms; Described poly suboxygen alkyl glycol ethers molecular weight is preferably about 250 atomic mass units of about 100-, most preferably is about 250 atomic mass units of about 125-.The R that contains 1-6 carbon atom ¹And R ³Alkyl can be linearity, branching or cyclic.Representational R1 and R3 alkyl comprise methyl, ethyl, propyl group, sec.-propyl, butyl, isobutyl-, sec-butyl, the tertiary butyl, amyl group, isopentyl, neo-pentyl, tert-pentyl, cyclopentyl and cyclohexyl.When the free hydroxyl group on this poly suboxygen alkyl glycol ethers expanding material may with some compression refrigeration equipment structured material (for example

) when incompatible, R ¹And R ³Preferably contain 1 to 4 carbon atom, the most preferably aliphatic hydrocarbyl of 1 carbon atom.The R that contains 2-4 carbon atom ²The aliphatics alkylene has formed multiple alkylidene oxide group-(OR ²) x-, the latter comprises oxygen ethylidene group, oxygen propylidene group and oxygen butylidene group.In a poly suboxygen alkyl glycol ethers expanding material molecule, comprise R ²The alkylidene oxide group can be identical, or a molecule can comprise different R ²Alkylidene oxide.Poly suboxygen alkyl glycol ethers expanding material of the present invention preferably comprises at least one oxygen propylidene group.Work as R ¹Be when containing the aliphatics at 1-6 carbon atom and y keyed jointing position or alicyclic hydrocarbon group, this group can be linear, branching or cyclic.The representative R that contains two keyed jointing positions ¹Aliphatic hydrocarbyl comprises, for example, and ethylidene, propylidene, butylidene, pentylidene, hexylidene, cyclopentylidene and cyclohexylidene.The representative R that contains 3 or 4 keyed jointing positions ¹Aliphatic hydrocarbyl comprises from polyvalent alcohol, as TriMethylolPropane(TMP), and glycerine, tetramethylolmethane, 1,2,3-trihydroxy-hexanaphthene and 1,3,5-trihydroxy-hexanaphthene is by removing their hydroxyl institute deutero-residue.

Representational poly suboxygen alkyl glycol ethers expanding material includes but not limited to: CH ₃OCH ₂CH (CH ₃) O (H or CH ₃) (propylene glycol methyl (or dimethyl) ether), CH ₃O[CH ₂CH (CH ₃) O] ₂(H or CH ₃) (dipropylene glycol methyl (or dimethyl) ether), CH ₃O[CH ₂CH (CH ₃) O] ₃(H or CH ₃) (tripropylene glycol methyl (or dimethyl) ether), C ₂H ₅OCH ₂CH (CH ₃) O (H or C ₂H ₅) (propylene glycol ethyl (or diethyl) ether), C ₂H ₅O[CH ₂CH (CH ₃) O] ₂(H or C ₂H ₅) (dipropylene glycol ethyl (or diethyl) ether), C ₂H ₅O[CH ₂CH (CH ₃) O] ₃(H or C ₂H ₅) (tripropylene glycol ethyl (or diethyl) ether), C ₃H ₇OCH ₂CH (CH ₃) O (H or C ₃H ₇) (propylene glycol n-propyl (or di) ether), C ₃H ₇O[CH ₂CH (CH ₃) O] ₂(H or C ₃H ₇) (dipropylene glycol n-propyl (or di) ether), C ₃H ₇O[CH ₂CH (CH ₃) O] ₃(H or C ₃H ₇) (tripropylene glycol n-propyl (or di) ether), C ₄H ₉OCH ₂CH (CH ₃) OH (propylene glycol n-butyl ether), C ₄H ₉O[CH ₂CH (CH ₃) O] ₂(H or C ₄H ₉) (dipropylene glycol normal-butyl (or di-n-butyl) ether), C ₄H ₉O[CH ₂CH (CH ₃) O] ₃(H or C ₄H ₉) (tripropylene glycol normal-butyl (or di-n-butyl) ether), (CH ₃) ₃COCH ₂CH (CH ₃) OH (glycol tertiary butyl ether), (CH ₃) ₃CO[CH ₂CH (CH ₃) O] ₂(H or (CH ₃) ₃) (the dipropylene glycol tertiary butyl (or di-t-butyl) ether), (CH ₃) ₃CO[CH ₂CH (CH ₃) O] ₃(H or (CH ₃) ₃) (the tripropylene glycol tertiary butyl (or di-t-butyl) ether), C ₅H ₁₁OCH ₂CH (CH ₃) OH (propylene glycol n-pentyl ether), C ₄H ₉OCH ₂CH (C ₂H ₅) OH (butyleneglycol n-butyl ether), C ₄H ₉O[CH ₂CH (C ₂H ₅) O] ₂H (dibutylene glycol n-butyl ether), trimethylolpropane tris n-butyl ether (C ₂H ₅C (CH ₂O (CH ₂) ₃CH ₃) ₃) and TriMethylolPropane(TMP) di-n-butyl ether (C ₂H ₅C (CH ₂OC (CH ₂) ₃CH ₃) ₂CH ₂OH).

Acid amides expanding material of the present invention comprises by general formula R ¹C (O) NR ²R ³And ring-[R ⁴C (O) N (R ⁵)] expression those, wherein: R ¹, R ², R ³And R ⁵Be independently selected from the aliphatic series and the alicyclic alkyl that contain 1-12 carbon atom; R ⁴Be selected from the aliphatic alkylene that contains 3-12 carbon atom; And wherein said acid amides has the molecular weight of about 300 atomic mass units of about 100-.The molecular weight of described acid amides is preferably about 250 atomic mass units of about 160-.R ¹, R ², R ³And R ⁵The alkyl that can randomly comprise replacement promptly, contains the substituent group of nonhydrocarbon that is selected from halogen (for example fluorine, chlorine) and alkoxyl group (for example methoxyl group).R ¹, R ², R ³And R ⁵The alkyl that can randomly comprise heteroatoms-replacement promptly, contains Nitrogen Atom (azepine-), the group of oxygen (oxa--) or sulphur (thia-) in the group chain of being made of carbon atom in addition.Usually, at R ^1-3In per 10 carbon atoms existence is no more than three non-hydrocarbon substituents and heteroatoms and preferably is no more than one, and when being suitable for above-mentioned molecular weight restriction, must consider non-hydrocarbon substituent of any of these and heteroatomic existence.Preferred acid amides expanding material is by carbon, hydrogen, and nitrogen and oxygen constitute.Representational R ¹, R ², R ³And R ⁵Aliphatic series and alicyclic alkyl comprise methyl, ethyl, propyl group, sec.-propyl, butyl, isobutyl-, sec-butyl, the tertiary butyl, amyl group, isopentyl, neo-pentyl, tert-pentyl, cyclopentyl, cyclohexyl, heptyl, octyl group, nonyl, decyl, undecyl, dodecyl and their configurational isomer.An embodiment preferred of acid amides solubilizing agent is wherein at above-mentioned general formula ring-[R ⁴C (O) N (R ⁵R in)-] ⁴Can be by alkylene (CR ⁶R ⁷) n represent those, in other words, general formula: ring-[(CR ⁶R ⁷) nC (O) N (R ⁵)-], wherein: the described value for the front of molecular weight is suitable equally; N is the integer of 3-5; R ⁵It is the stable hydrocarbon group that contains 1-12 carbon atom; R ⁶And R ⁷Be used to define R by the front ^1-3Rule select (for each n) independently.By general formula: ring-[(CR ⁶R ⁷) nC (O) N (R ⁵In the lactan of expression)-], whole R ⁶And R ⁷Hydrogen preferably, or contain single stable hydrocarbon group among n MU (methylene unit), R ⁵It is the stable hydrocarbon group that contains 3-12 carbon atom.For example, 1-(saturated hydrocarbyl)-5-methylpyrrolidin-2-ketone.

Representational acid amides solubilizing agent includes but not limited to: 1-octyl group pyrrolidin-2-one, 1-decyl pyrrolidin-2-one, 1-octyl group-5-methylpyrrolidin-2-ketone, 1-butyl hexanolactam, 1-cyclohexyl pyrrolidin-2-one, 1-butyl-5-methyl piperidine-2-ketone, 1-amyl group-5-methyl piperidine-2-ketone, 1-hexyl hexanolactam, 1-hexyl-5-methylpyrrolidin-2-ketone, 5-methyl-1-pentene phenylpiperidines-2-ketone, 1,3-lupetidine-2-ketone, the 1-methyl caprolactam, 1-butyl-pyrrolidin-2-one, 1,5-lupetidine-2-ketone, 1-decyl-5-methylpyrrolidin-2-ketone, 1-dodecyl pyrrolidin-2-one, N, N-dibutyl formamide and N, N-di-isopropyl ethanamide.

Ketone expanding material of the present invention comprises by general formula R ¹C (O) R ²The ketone of expression, wherein R ¹And R ²Be independently selected from the aliphatic series that contains 1-12 carbon atom, alicyclic and aryl alkyl, and wherein said ketone has the molecular weight of about 300 atomic mass units of about 70-.R in the described ketone ¹And R ²Preferably be independently selected from the aliphatic series and the alicyclic alkyl that contain 1-9 carbon atom.The molecular weight of described ketone is preferably about 100-200 atomic mass unit.R ¹And R ²Can form alkylene together, this alkylene connects and forms five, six, or seven-membered ring cyclic ketones, for example cyclopentanone, pimelinketone and suberone.R ¹, R ², R ³And R ⁵The alkyl that can randomly comprise replacement promptly, contains the substituent group of nonhydrocarbon that is selected from halogen (for example fluorine, chlorine) and alkoxyl group (for example methoxyl group).R ¹And R ²Can randomly comprise the alkyl that heteroatoms replaces, that is, in the group chain of forming by carbon atom in addition, contain Nitrogen Atom (azepine-), the group of oxygen (ketone-, oxa--) or sulphur (thia-).Usually, at R ¹And R ²In per 10 carbon atoms existence is no more than three non-hydrocarbon substituents and heteroatoms and preferably is no more than one, and when being suitable for above-mentioned molecular weight restriction, must consider non-hydrocarbon substituent of any of these and heteroatomic existence.At general formula R ¹COR ²In representational R ¹And R ²Aliphatics, alicyclic and aryl hydrocarbyl group comprises methyl, ethyl, propyl group, sec.-propyl, butyl, isobutyl-, sec-butyl, the tertiary butyl, amyl group, isopentyl, neo-pentyl, tert-pentyl, cyclopentyl, cyclohexyl, heptyl, octyl group, nonyl, decyl, undecyl, dodecyl and their configurational isomer, and phenyl, benzyl, cumenyl, 2,4,6-trimethylphenyl, tolyl, 3,5-dimethylphenyl and styroyl.

Representational ketone solubilizing agent includes but not limited to: 2-butanone, 2 pentanone, phenyl methyl ketone, butyrophenone, amyl phenyl ketone, pimelinketone, suberone, 2-heptanone, the 3-heptanone, 5 methy 12 hexanone, methyl hexyl ketone (methyln-hexyl ketone), 3-octanone, diisobutyl ketone, 4-ethyl cyclohexanone, methyl n-heptyl ketone, butyl ketone, 2-decanone, propyl hexyl ketone, the 2-decalone, methyl n-undecyl ketone, dihexyl ketone and dicyclohexyl ketone.

Nitrile expanding material of the present invention comprises by general formula R ¹The nitrile that CN represents, wherein R ¹Be selected from the aliphatic series that contains 5-12 carbon atom, alicyclic or aryl alkyl, and wherein said nitrile has the molecular weight of about 200 atomic mass units of about 90-.R in described nitrile expanding material ¹Be preferably selected from the aliphatic series and the alicyclic alkyl that contain 8-10 carbon atom.The molecular weight of described nitrile expanding material is preferably about 140 atomic mass units of about 120-.R ¹The alkyl that can randomly comprise replacement promptly, contains the substituent group of nonhydrocarbon that is selected from halogen (for example fluorine, chlorine) and alkoxyl group (for example methoxyl group).R ¹Can randomly comprise the alkyl that heteroatoms replaces, that is, in the group chain of forming by carbon atom in addition, contain Nitrogen Atom (azepine-), the group of oxygen (ketone-, oxa--) or sulphur (thia-).Usually, at R ¹In per 10 carbon atoms existence is no more than three non-hydrocarbon substituents and heteroatoms and preferably is no more than one, and when being suitable for above-mentioned molecular weight restriction, must consider non-hydrocarbon substituent of any of these and heteroatomic existence.At general formula R ¹Representational R among the CN ¹Aliphatic series, alicyclic and aryl hydrocarbyl group comprises amyl group, isopentyl, neo-pentyl, tert-pentyl, cyclopentyl, cyclohexyl, heptyl, octyl group, nonyl, decyl, undecyl, dodecyl and their configurational isomer, and phenyl, benzyl, cumenyl, 2,4,6-trimethylphenyl, tolyl, 3,5-dimethylphenyl and styroyl.

Representational nitrile expanding material includes but not limited to: 1-cyano group pentane, 2,2-dimethyl-4-cyano group pentane, 1-cyano group hexane, 1-cyano group heptane, 1-cyano group octane, 2-cyano group octane, 1-cyano group nonane, 1-cyano group decane, 2-cyano group decane, 1-cyano group undecane and 1-cyano group dodecane.

Hydrochloric ether expanding material of the present invention comprises the hydrochloric ether of being represented by general formula R Clx, and wherein: x is selected from 1 or 2 integer; R is selected from aliphatic series and the alicyclic alkyl that contains 1-12 carbon atom; And wherein said hydrochloric ether has the molecular weight of about 200 atomic mass units of about 100-.The molecular weight of described hydrochloric ether expanding material is preferably about 120-150 atomic mass unit.Representational R aliphatic series and alicyclic alkyl in general formula R Clx comprise methyl, ethyl, propyl group, sec.-propyl, butyl, isobutyl-, sec-butyl, the tertiary butyl, amyl group, isopentyl, neo-pentyl, tert-pentyl, cyclopentyl, cyclohexyl, heptyl, octyl group, nonyl, decyl, undecyl, dodecyl and their configurational isomer.

Representational hydrochloric ether expanding material includes but not limited to: 3-(chloromethyl) pentane, 3-chloro-3-methylpentane, 1-chlorohexane, 1,6-dichloro hexane, 1-chloroheptane, 1-chloro-octane, 1-chlorononane, 1-chlorodecane and 1,1,1-three chlorodecanes.

Ester expanding material of the present invention comprises by general formula R ¹CO ₂R ²The ester of expression, wherein R ¹And R ²Be independently selected from linearity and ring-type, saturated and unsaturated alkyl and aryl.Preferred ester mainly is made up of Elements C, H and O, has the molecular weight of about 550 atomic mass units of about 80-.

Representational ester includes but not limited to: (CH ₃) ₂CHCH ₂OOC (CH ₂) _2-4OCOCH ₂CH (CH ₃) ₂(diprotic acid diisobutyl ester), ethyl hexanoate, oil of cognac, n-butyl propionate, propionic acid n-propyl ester, ethyl benzoate, phthalic acid di ester, phenylformic acid ethoxyethyl group ester, dipropyl carbonate, " Exxate 700 " (commodity acetate C7 alkyl ester), " Exxate 800 " (commodity acetate C ₈Alkyl ester), dibutyl phthalate, and tert.-butyl acetate.

Lactone expanding material of the present invention comprises the lactone by structure [A], [B] and [C] expression:

These lactones contain at the ring of six atoms (A), or the functional group-CO in the ring of preferred five atoms (B) ₂-, wherein for structure [A] and [B], R ¹To R ⁸Be independently selected from hydrogen or linearity, branching, ring-type, two rings, saturated and undersaturated alkyl.R ¹To R ⁸In each can with R ¹To R ⁸In another link to each other to form ring.This lactone can have alkylidene, wherein R outside the ring in structure [C] ¹To R ⁶Be independently selected from hydrogen or linearity, branching, ring-type, two rings, saturated and undersaturated alkyl.R ¹To R ⁶In each can with R ¹To R ⁶In another link to each other to form ring.This lactone expanding material has about 300 atomic mass units of about 80-, the molecular weight of about 200 atomic mass units of preferably approximately 80-.

Representational lactone expanding material includes but not limited to the compound listed in table 8.

Table 8

The lactone expanding material generally has the dynamic viscosity that is lower than about 7 centistokes under 40 ℃.For example, under 40 ℃, peach aldehyde has the dynamic viscosity of 5.4 centistokes, has the viscosity of 4.5 centistokes along (3-hexyl-5-methyl) dihydrofuran-2-ketone.The lactone expanding material can be that U.S. Patent application 10/910, the 495 described method that is purchased or pass through to submit to as on August 3rd, 2004 prepares, and the document is hereby incorporated by.

Aryl ethers expanding material of the present invention further comprises by general formula R ¹OR ²The aryl ethers of expression, wherein: R ¹Be selected from the aryl hydrocarbon that contains 6-12 carbon atom; R ²Be selected from the aliphatic hydrocarbyl that contains 1-4 carbon atom; And wherein said aryl ethers has the molecular weight of about 150 atomic mass units of about 100-.At general formula R ¹OR ²In representational R ¹Aryl comprises phenyl, xenyl, cumyl, mesityl, tolyl, 3,5-dimethylphenyl, naphthyl and pyridyl.At general formula R ¹OR ²In representative R2 aliphatic hydrocarbyl comprise methyl, ethyl, propyl group, sec.-propyl, butyl, isobutyl-, sec-butyl and the tertiary butyl.Representational aromatic oxide solubilizing agent includes but not limited to: methyl phenyl ether (phenylmethylether), 1,3-dimethoxy benzene, ethylphenyl ether and butyl phenylate.

Fluoroether expanding material of the present invention comprises by general formula R ¹OCF ₂CF ₂Those that H represents, wherein R ¹Be selected from the aliphatic series that contains about 15 carbon atoms of about 5-, alicyclic and aromatic hydrocarbyl, preferred primary, linear, saturated alkyl.Representational fluoroether expanding material includes but not limited to: C ₈H ₁₇OCF ₂CF ₂H and C ₆H ₁₃OCF ₂CF ₂H.Should be noted that if this cooling agent is fluoroether, then this expanding material can not be identical fluoroether.

The fluoroether expanding material may further include the ether derived from fluoroolefins and polyvalent alcohol.Described fluoroolefins can have CF ₂=CXY pattern, wherein X is hydrogen, chlorine or fluorine, Y is chlorine, fluorine, CF ₃Or OR _f, R wherein _fBe CF ₃, C ₂F ₅Or C ₃F ₇Representational fluoroolefins is tetrafluoroethylene, chloro trifluoro-ethylene, R 1216 and perfluoro methyl vinyl ether.Described polyvalent alcohol can be linearity or branching.Linear polyvalent alcohol can have HOCH ₂(CHOH) x (CRR ') yCH ₂The OH pattern, wherein R and R ' are hydrogen, CH ₃Or C ₂H ₅And wherein x is the integer of 0-4, and y is the integer of 0-4.The branching polyvalent alcohol has C (OH) t (R) u (CH ₂OH) v[(CH ₂) mCH ₂OH] the w pattern, wherein R can be hydrogen, CH ₃Or C ₂H ₅, m is the integer of 0-3, and t and u can be 0 or 1, and v and w are the integers of 0-4, in addition t+u+v+w=4 wherein.Representational polyvalent alcohol is TriMethylolPropane(TMP), tetramethylolmethane, butyleneglycol and ethylene glycol.

Of the present invention 1,1,1-trifluoro alkane expanding material comprises by general formula CF ₃R ¹1,1 of expression, 1-trifluoro alkane, wherein R ¹Be selected from the aliphatic series and the alicyclic alkyl that contain about 15 carbon atoms of about 5-, preferred primary, linear, saturated alkyl.Representational 1,1,1-trifluoro alkane expanding material includes but not limited to: 1,1, and 1-trifluoro hexane and 1,1,1-trifluoro dodecane.

The significant quantity of expanding material is meant and causes lubricant effective solubilising the and therefore amount of the expanding material of the enough oil return operation to optimize refrigeration, air-conditioning or heat-pump apparatus is provided in composition.

Composition of the present invention will comprise usually and account for the about 40wt% of the about 0.1-of the present composition, the about 20wt% of preferably approximately 0.2-, the most preferably about expanding material of the about 10wt% of 0.3-.

The invention further relates to the solubilizing method of cooling agent or heat-transfer fluid composition, said composition is included in the present composition in the refrigeration lubricant that is selected from mineral oil, alkylbenzene, synthetic paraffin, synthetic naphthenic hydrocarbon and poly-(α) alkene, wherein said method is included under the existence of significant quantity expanding material described lubricant is contacted with described composition, wherein said expanding material is selected from poly suboxygen alkyl glycol ethers, acid amides, nitrile, ketone, chlorocarbon, ester, lactone, aryl ethers, fluoroether and 1,1,1-trifluoro alkane.

The invention further relates to and improve in compression refrigeration, air-conditioning or the heat-pump apparatus to the compressor oil returning method, described method is included in and uses the composition that comprises expanding material in the described equipment.

Composition of the present invention can comprise ultraviolet ray (UV) dyestuff and optional solubilizing agent further.This UV dyestuff be allow people the leakage point of refrigeration, air-conditioning or heat-pump apparatus or near described equipment in observation group's compound dye fluorescence with the useful component of the leakage that detects described composition.People can observe the fluorescence of dyestuff under ultraviolet ray.Solubilizing agent needs, owing to the solvability of the difference of this type of UV dyestuff in some compositions.

" ultraviolet ray " dyestuff is meant the UV fluorescent composition of the light in ultraviolet or " closely " ultra-violet region that can be absorbed in electromagnetic spectrum.Have the fluorescence that under the irradiation of UV light, produces from the radiating UV fluorescence dye of any wavelength of 10 nanometers-750 nanometer and can detect by launching.Therefore, leak on the set point of refrigeration, air-conditioning or heat-pump apparatus if contain the composition of this type of UV fluorescence dye, then this fluorescence can detect at this leakage point.This type of UV fluorescence dye includes but not limited to naphthalimide ， perylene, tonka bean camphor, anthracene, phenanthrene, xanthene, thioxanthene, naphthoxanthene, fluorescein and their derivative or combination.

Solubilizing agent of the present invention can comprise at least a hydrocarbon, hydrocarbyl ether, the poly suboxygen alkyl glycol ethers of being selected from, acid amides, nitrile, ketone, chlorocarbon, ester, lactone, aryl hydrocarbon, fluoroether and 1,1, the compound of 1-trifluoro alkane.Described poly suboxygen alkyl glycol ethers, acid amides, nitrile, ketone, chlorocarbon, ester, lactone, aryl ethers, fluoroether and 1,1,1-trifluoro alkane solubilizing agent is defined as the expanding material that is used for conventional refrigeration lubricant before this herein.

Hydrocarbon solubilizing agent of the present invention comprises hydrocarbon, and it comprises and contains 5 or carbon atom and hydrogen is only arranged but do not have straight chain, side chain or cyclic-paraffins or the alkene of other functional group still less.Representational hydrocarbon solubilizing agent comprises propane, propylene, cyclopropane, normal butane, Trimethylmethane, 2-methylbutane and Skellysolve A.Should be noted that if described composition comprises hydrocarbon, then this solubilizing agent can not be identical hydrocarbon.

Hydrocarbyl ether solubilizing agent of the present invention comprises the ether that only contains carbon, hydrogen and oxygen, as dme (DME).

Solubilizing agent of the present invention can be used as the simplification compound and exists, or the mixture that can be used as more than a kind of solubilizing agent exists.The mixture of solubilizing agent can contain two kinds of solubilizing agent that belong in the same classification compound, such as two kinds of lactones, or two kinds of solubilizing agent in the compound that belongs to a different category, as lactone and poly suboxygen alkyl glycol ethers.

Comprise cooling agent and UV fluorescence fluorescence dye or comprise heat-transfer fluid and the present composition of UV fluorescence dye in, the about 1.0wt% of about 0.001wt%-of described composition is the UV dyestuff, the about 0.5wt% of preferably approximately 0.005wt%-, the most preferably about 0.25wt% of 0.01wt%-.

Solubilizing agent such as ketone have unfavorable smell, and it can be covered by the interpolation of odor masking agent or spices.The representative instance of odor masking agent or spices can comprise evergreen (Evergreen), new lemon, and cherry, Chinese cassia tree, peppermint, flower or orange peel, they are all commercially available, and sylvestrene and firpene.This type of odor masking agent can use up to the concentration of about 15wt% by the about 0.001wt%-based on odor masking agent and solubilizing agent gross weight.

The solvability of these UV fluorescence dyes in the present composition may be poor.Therefore, the method that these dyestuffs are incorporated in refrigeration, air-conditioning or the heat-pump apparatus is clumsy, and is expensive with time-consuming.U.S. Patent number RE36,951 have described a kind of method, and it uses dye powder, solid grain or dyestuff slurry in the assembly that can be inserted into refrigeration, air-conditioning or heat-pump apparatus.The circulation time in this equipment when cooling agent and lubricant, this dyestuff dissolving or dispersion also spread all over entire equipment.Described in the literature dyestuff has been incorporated into many other methods in refrigeration or the conditioning unit.

Ideally, described UV fluorescence dye may be dissolved in the cooling agent itself, does not therefore need to be incorporated into any ad hoc approach in refrigeration, conditioning unit or the heat pump.The present invention relates to comprise the composition of UV fluorescence dye, the solution that it can be used as in cooling agent is introduced in the system.The composition that composition of the present invention can allow to contain dyestuff when keeping this dyestuff under dissolved state even under low temperature is stored and conveying.

Comprise cooling agent, UV fluorescence dye and solubilizing agent or comprise heat-transfer fluid and the present composition of UV fluorescence dye and solubilizing agent in, the about 50wt% of about 1-of total composition, the about 25wt% of preferably approximately 2-, most preferably approximately the about 15wt% of 5-is a solubilizing agent.In composition of the present invention, described UV fluorescence dye is with the about 1.0wt% of about 0.001wt%-, the preferred about 0.5wt% of 0.005wt%-, and most preferably the concentration of the about 0.25wt% of 0.01wt%-exists.

The invention further relates to the method for compositions of in refrigeration, air-conditioning or heat-pump apparatus, using the solubilizing agent that further comprises UV fluorescent dye and choose wantonly.This method comprises said composition is incorporated in refrigeration, air-conditioning or the heat-pump apparatus.This can realize by being dissolved in the UV fluorescence dye in the said composition in the presence of solubilizing agent and this combination being incorporated in this equipment.Perhaps, this can by with solubilizing agent and UV fluorescence dye in conjunction with and described combination be incorporated in the refrigeration that contains cooling agent and/or heat-transfer fluid or the conditioning unit realize.The composition of gained can be used for refrigeration, air-conditioning or heat-pump apparatus.

The invention further relates to and use the composition that comprises UV fluorescent dye to detect the method for leaking.The existence of this dyestuff in composition allows to detect the cooling agent that is leaking in refrigeration, air-conditioning or heat-pump apparatus.Leak detection helps to tackle, solve or prevent the inefficiency running or the failure of apparatus of this equipment or system.Leak detection also helps it to contain the chemical that uses in the running of device.

This method comprises to be provided the composition that comprises cooling agent, UV fluorescent dye described here and non-essential solubilizing agent described here and uses for detecting the appropriate device that the cooling agent that contains the UV fluorescence dye is used in refrigeration, air-conditioning or heat-pump apparatus.The suitable equipment that detects dyestuff includes, but not limited to UV-lamp, usually is called " black light " or " blue light ".These UV-lamp can be purchased from special many sources of supply of design for this purpose.Be introduced in this refrigeration, air-conditioning or the heat-pump apparatus and allow it cycle through this system in case contain the composition of UV fluorescent dye, by be radiated at described UV-lamp on this equipment and near any breakthrough the fluorescence of this dyestuff of observation can find to leak.

The invention further relates to the method for high GWP cooling agent in alternative refrigeration, air-conditioning or the heat-pump apparatus, wherein said high GWP cooling agent is selected from R134a, R22, R245fa, R114, R236fa, R124, R410A, R407C, R417A, R422A, R507A and R404A, and described method comprises composition of the present invention is offered use, is used for or designs described refrigeration, air-conditioning or the heat-pump apparatus that is used for using described high GWP cooling agent.Vapor compression refrigeration, air-conditioning or heat pump comprise vaporizer, compressor, condenser, and expansion gear.Vapor-compression cycle re-uses cooling agent in a plurality of steps, thereby produces cooling performance in a step, produces heats in different steps.This circulation can be described below simply.Liquid refrigerant enters vaporizer by expansion gear, and this liquid refrigerant seethes with excitement at low temperatures in vaporizer and forms gas and produce cooling effect then.This low-pressure gas enters in the compressor, and gas is compressed the back and its pressure and temperature of raising therein.Elevated pressures (compression) gaseous refrigerant enters in the condenser then, and cooling agent condenses and its heat is discharged in the environment therein.This cooling agent is got back in this expansion gear, expand into low pressure level in vaporizer by this liquid after this device from the higher-pressure level condenser, therefore repeats this circulation.

Employed motion refrigeration equipment of this paper or motion conditioning unit are meant any refrigeration or the conditioning unit in the transportation unit that is attached to road, track, ocean or sky.In addition, be used for being also included among the present invention for the system's (being called " through transport (intermodal) " system) that does not rely on any mobile vehicle provides the equipment of refrigeration or air-conditioning.This type of through transport system comprises " container " (in conjunction with ocean/land transport) and " permutoid " (in conjunction with road and transportation by railroad).The present invention especially can be used for Road transport refrigeration or conditioning unit, as the road transporting tool of air conditioning equipment of car or refrigeration.

The invention further relates to refrigerating method, be included near the body to be cooled evaporation composition of the present invention and afterwards with described composition condensation.

The invention further relates to the method that produces heat, be included near the body to be heated condensation composition of the present invention and afterwards with described composition evaporation.

The invention further relates to the refrigeration, air-conditioning or the heat-pump apparatus that comprise the present composition, wherein said composition comprises at least a fluoroolefins.

The invention further relates to the motion conditioning unit that comprises the present composition, wherein said composition comprises at least a fluoroolefins.

The invention further relates to the method that cooling agent leaks in early detection refrigeration, air-conditioning or the heat-pump apparatus, described method is included in the reduction of using non-Azeotrope compositions and monitoring cooling performance in the described equipment.Described non-Azeotrope compositions will will at first come out from this equipment leakage from refrigeration, air-conditioning or heat-pump apparatus fractionation and than the component of lower boiling (higher vapor pressure) when leaking.When this takes place, if the more lower boiling component in the said composition provides most of refrigeration capacity, the remarkable reduction of refrigeration capacity and the therefore remarkable reduction of equipment performance appear then.In automotive air-conditioning system, for example the passenger in the automobile will detect the reduction of system cools ability.This reduction of cooling power can be interpreted as being meant that cooling agent is leaking and this system needs to repair.

The invention further relates to and use composition of the present invention as the heat-transfer fluid method for compositions, described method comprises described composition is transported to scatterer from thermal source.

Heat-transfer fluid is utilized to by radiation, conduction or convection current, and from a space, different spaces, position, object or body are shifted, moved or tell in the position in object or the body with heat.Heat-transfer fluid can be used as secondary coolant by the transfer equipment that cools off (or heating) from remote refrigeration (or heating) system is provided.In some systems, described heat-transfer fluid can remain on steady state (that is, do not evaporate or condensation) in whole process.Perhaps, transpiration cooling process can similarly be utilized heat-transfer fluid.

Thermal source can be defined as any space, position, object or the body that heat was therefrom shifted, moves or told in hope.The example of thermal source can be to need refrigeration or refrigerative space (open or sealing), and refrigerator or refrigerator casing as at the supermarket need the space of air-conditioning, or need air-conditioning automobile take the railway carriage or compartment.Scatterer can be defined as any space, position, object or the body that can absorb heat.Vapor compression refrigeration system is an example of this type of scatterer.

In another embodiment, the present invention relates to be used to prepare the foamy foaming agent composotion, it comprises the composition that contains fluoro alkene described herein.In other embodiments, the invention provides foamable composite, optimization polyurethane and polyisocyanates foam composition and preparation foamy method.In these foam embodiments, comprise one or more compositions that contain fluoro alkene of the present invention as the whipping agent in the foamable composite, this foamable composite preferably includes one or more and can react under proper condition and foam to form the annexing ingredient of foam or polynuclear plane.According to foam embodiment of the present invention, any method of knowing in this area, as " Polyurethanes Chemistry and Technology ", I and II volume, Saunders andFrisch, 1962, John Wiley and Sons, New York, those that describe among the N.Y. (document is hereby incorporated by) can use or use through reorganization.

The invention further relates to foamy formation method, comprising: (a) composition that contains fluoro alkene of the present invention is added in the foamable composite; (b) effectively make this foamable composite reaction under the formation foamy condition.

Another embodiment of the invention relates to the composition that contains fluoro alkene described herein is used as propelling agent in Sprayable composition purposes.In addition, the present invention relates to comprise the Sprayable composition that contains the composition of fluoro alkene described herein.Activeconstituents to be sprayed and inert component, solvent and other material also may reside in the Sprayable composition.Preferably, described Sprayable composition is an aerosol.The active material that is fit to be sprayed includes but not limited to cosmetics material, as reodorant, perfume compound, hair spray, sanitising agent and rumbling compound and medicinal materials such as anti-asthma and halitosis medicine.

The invention further relates to the preparation method of aerosol product, comprise step: the composition that contains fluoro alkene described herein is added in the activeconstituents in the aerosol container, and wherein said composition plays the propelling agent effect.

Another aspect provides the method that suppresses flame, and described method comprises makes flame contact with the fluid of the composition that contains fluoro alkene that comprises the disclosure of invention.Can use any suitable method that this flame is contacted with the present composition.For example, can with the composition that contains fluoro alkene of the disclosure of invention by spray, topple over, etc. mode to flame, maybe at least a portion of flame can be immersed in the described flame composite inhibiting.Consider the instruction of this paper, those skilled in the art can easily change various conventional equipments that flame suppresses and method to be used for the disclosure of invention.

Another embodiment provides the method for putting out or suppress fire by total flooding (total-flood) mode of applying, comprising: the reagent that the composition that contains fluoro alkene that comprises the disclosure of invention is provided; Described reagent is arranged in the pressurization blowdown system; With described reagent is discharged in the zone to put out or to suppress fire in that zone.Another embodiment provides and makes regional inerting to prevent the method for fire or blast, comprising: the reagent that the composition that contains fluoro alkene that comprises the disclosure of invention is provided; Described reagent is arranged in the pressurization blowdown system; With described reagent is discharged in this zone to prevent that fire or blast from taking place.

Term " puts out " and is commonly used to represent to eliminate fully fire; And " inhibition " is commonly used to the expression minimizing, and not necessarily eliminates fire or blast fully.Term as used herein " is put out " and " inhibition " will be used interchangeably.The halocarbon fire prevention and the explosion proof applications that have four kinds of general types.(1), described reagent is discharged in the space to obtain to be enough to put out or suppress the concentration of existing fire in the total flooding fire suppression and/or in suppressing to use.The total flooding purposes comprises the space that protection is airtight, may occupy, as computer room and special use, and the cabin in common idle space such as aircraft engine gondola and the carrier.(2) spraying during (streaming) use, be applied directly to described reagent on the fire or in the zone of fire.This uses manually-operated wheel or mancarried device to realize usually.Use " localization (localized) " system as the second method that spray application comprises, it discharges reagent by one or more static jets towards fire.Localizing system can manually or automatically start.(3) in blast suppresses, with the blast of composition discharging that contains fluoro alkene of the disclosure of invention to suppress to be initiated.Term " inhibition " is used in this application usually, because the self-limit normally of exploding.Yet the use of this term means that not necessarily described reagent does not put out blast.In this application, detector is commonly used to detect the expansion fireball that derives from blast, and promptly discharges described reagent to suppress blast.Blast suppresses main but is not only to be used for the defence application.(4) in inerting, the composition that contains fluoro alkene of the disclosure of invention is discharged in the space to prevent that blast or fire are initiated.Usually, the similar or identical system that uses with the total flooding fire suppression or suppress to use.Usually, (for example, the dangerous concentrations of flammable or explosive gases) existence, the composition that contains fluoro alkene that discharges the disclosure of invention then takes place up to remedying described condition to prevent blast or fire to detect unsafe conditions.

Can put out method by described composition being introduced fire sealed area on every side.Operable any known introducing method is as long as be metered into described sealed area in suitable interval with the described composition of appropriate amount.For example, can following introducing composition: spray and for example use conventional portable (or fixing) fire-protection equipment; Atomizing; Or flood (flooding), for example described composition is discharged (using suitable pipeline, valve and controller) in the sealed area of corral a fire.Described composition can be randomly and inert propellant, and for example degradation production or the carbonic acid gas combination of nitrogen, argon gas, glycidyl trinitride polymkeric substance is to improve described composition from the injection used or the speed of flood device discharging.

Preferably, putting out method comprises to be enough to stamp out a fire or the amount of flame is incorporated into fire or flame with the composition that contains fluoro alkene of the disclosure of invention.The amount that those skilled in the art put out the fire inhibitor that specific fire needs with approval will depend on the nature and extent of harm.In the time will introducing fire inhibitor by flood, cup burner testing data can be used for determining putting out the amount or the concentration of the needed fire inhibitor of fire of particular type and scale.

When putting out with total flooding application or the combination of fire inerting mode or suppressing fire, the laboratory test of effective concentration scope of composition that can be used for determining containing fluoro alkene is for example at U.S. Patent number 5, be described in 759,430, the document is incorporated herein for reference.

Embodiment

Embodiment 1

The influence of vapour leakage

At-25 ℃ or if regulation is arranged, in the container of under 25 ℃ temperature, initial composition being packed into, and measure the initial vapour pressure of said composition.Allow said composition from container leakage, keep temperature-resistant simultaneously, remove, at this moment the vapour pressure of remaining composition in the measuring vessel up to the 50wt% of initial composition.The result is shown in the table 9.

Table 9

Form and initially be initially at 50% at 50% Δ P

Wt% P P leaks (%)

(Psia) (kPa) after

(Psia) (kPa)

HFC-1234yf/HFC-32

7.4/92.6 49.2 339 49.2 339 0.0％

1/99 49.2 339 49.2 339 0.0％

20/80 49.0 338 48.8 337 0.3％

40/60 47.5 327 47.0 324 1.0％

57/43 44.9 309 40.5 280 9.6％

58/42 44.6 308 40.1 276 10.2％

HFC-1234yf/HFC-125

1 0.9/89.1 40.8 281 40.8 281 0.0％

1/99 40.3 278 40.2 277 0.0％

20/80 40.5 279 40.3 278 0.4％

40/60 38.7 267 37.0 255 4.4％

50/50 37.4 258 34.0 235 9.0％

51/49 37.3 257 33.7 232 9.6％

52/48 37.1 256 33.3 229 10.3％

HFC-1234yf/HFC-134

1/99 11.7 81 11.6 80 0.7％

10/90 12.8 88 12.2 84 4.5％

20/80 13.7 95 13.0 89 5.6％

40/60 15.2 105 14.6 101 4.1％

60/40 1 6.3 113 16.0 110 2.0％

80/20 17.2 119 17.1 118 0.6％

90/10 17.6 121 17.5 121 0.2％

99/1 17.8 123 17.8 123 0.0％

HFC-1234yf/HFC-134a

70.4/29.6 18.4 127 18.4 127 0.0％

80/20 18.3 126 18.3 126 0.1％

90/10 18.2 125 18.1 125 0.1％

99/1 17.9 123 17.9 123 0.1％

40/60 17.9 123 17.8 123 0.7％

20/80 17.0 117 16.7 115 1.7％

10/90 16.4 113 16.1 111 1.5％

1/99 15.6 107 15.6 107 0.3％

HFC-1234yf/HFC-152a

91.0/9.0 17.9 123 17.9 123 0.0％

99/1 17.9 123 17.8 123 0.1％

60/40 17.4 120 17.2 119 0.7％

40/60 16.6 115 16.4 113 1.6％

20/80 15.7 108 15.4 106 2.0％

10/90 15.1 104 14.9 103 1.5％

1/99 14.6 100 14.5 100 0.2％

HFC-1234yf/HFC-161

1/99 25.3 174 25.3 174 0.0％

10/90 25.2 174 25.2 174 0.1％

20/80 24.9 172 24.8 171 0.8％

40/60 23.8 164 23.2 160 2.6％

60/40 22.0 152 21.3 147 3.2％

80/20 19.8 137 19.5 134 1.9％

90/10 18.8 129 18.6 128 0.9％

99/1 17.9 123 17.9 123 0.1％

HFC-1234yf/FC-143a

17.3/82.7 39.5 272 39.5 272 0.0％

10/90 39.3 271 39.3 271 0.1％

1/99 38.7 267 38.6 266 0.1％

40/60 38.5 266 37.8 260 1.9％

60/40 36.3 250 32.8 226 9.5％

61/39 36.1 249 32.4 223 1 0.2％

HFC-1234yf/HFC-227ea

84.6/15.4 18.0 124 18.0 124 0.0％

90/10 18.0 124 18.0 124 0.0％

99/1 17.9 123 17.9 123 0.0％

60/40 17.6 121 17.4 120 1.2％

40/60 16.7 115 15.8 109 5.4％

29/71 15.8 109 14.2 98 9.7％

28/72 15.7 108 14.1 97 10.2％

HFC-1234yf/HFC-236fa

99/1 17.8 122 17.7 122 0.2％

90/10 17.0 117 16.6 115 2.4％

80/20 16.2 112 15.4 106 5.1％

70/30 15.3 106 14.0 97 8.5％

66/34 15.0 103 13.5 93 10.0％

HFC-1234yf/HFC-1225ye

1/99 11.6 80 11.5 79 0.5％

10/90 12.6 87 12.2 84 3.2％

20/80 13.5 93 12.9 89 4.3％

40/60 15.0 103 14.4 99 3.7％

60/40 16.2 111 15.8 109 2.2％

80/20 17.1 118 16.9 117 0.9％

90/10 17.5 120 17.4 120 0.3％

99/1 17.8 123 17.8 123 0.0％

HFC-1234yf/ is anti--HFC-1234ze

1/99 11.3 78 11.3 78 0.4％

10/90 12.2 84 11.8 81 3.3％

20/80 13.1 90 12.5 86 4.6％

40/60 14.6 101 14.0 96 4.3％

60/40 15.8 109 15.4 106 2.7％

80/20 16.9 117 16.7 115 1.1％

90/10 17.4 120 17.3 119 0.5％

99/1 17.8 123 17.8 123 0.1％

HFC-1234yf/HFC-1243zf

1/99 13.1 90 13.0 90 0.2％

10/90 13.7 94 13.5 93 1.6％

20/80 14.3 99 14.0 97 2.4％

40/60 15.5 107 15.1 104 2.2％

60/40 16.4 113 16.2 112 1.4％

80/20 17.2 119 17.1 118 0.5％

90/10 17.5 121 17.5 121 0.2％

99/1 17.8 123 17.8 123 0.0％

HFC-1234yf/ propane

51.5/48.5 33.5 231 33.5 231 0.0％

60/40 33.4 230 33.3 229 0.4％

80/20 31.8 220 29.0 200 8.9％

81/19 31.7 218 28.5 196 10.0％

40/60 33.3 230 33.1 228 0.6％

20/80 32.1 221 31.2 215 2.9％

10/90 31.0 214 30.2 208 2.6％

1/99 29.6 204 29.5 203 0.4％

The HFC-1234yf/ normal butane

98.1/1.9 17.9 123 17.9 123 0.0％

99/1 17.9 123 17.9 123 0.0％

100/0 17.8 123 17.8 123 0.0％

80/20 16.9 116 16.1 111 4.4％

70/30 16.2 112 14.4 99 10.8％

71/29 16.3 112 14.6 101 9.9％

The HFC-1234yf/ Trimethylmethane

88.1/11.9 19.0 131 19.0 131 0.0％

95/5 18.7 129 18.6 128 0.7％

99/1 18.1 125 18.0 124 0.6％

60/40 17.9 123 16.0 110 10.3％

61/39 17.9 123 16.2 112 9.4％

HFC-1 234yf/DME

53.5/46.5 13.1 90 13.1 90 0.0％

40/60 13.3 92 13.2 91 0.7％

20/80 14.1 97 13.9 96 1.3％

10/90 14.3 99 14.3 98 0.5％

1/99 14.5 100 14.5 100 0.0％

80/20 14.5 100 14.0 96 3.3％

90/10 15.8 109 15.3 105 3.5％

99/1 17.6 121 17.5 121 0.6％

HFC-1234yf/CF ₃SCF ₃

1/99 12.1 83 12.0 83 0.2％

10/90 12.9 89 12.7 87 2.0％

20/80 13.8 95 13.4 92 2.8％

40/60 15.1 104 14.7 101 2.7％

60/40 16.2 112 15.9 110 1.9％

80/20 17.1 118 16.9 117 0.9％

90/10 17.5 120 17.4 120 0.5％

99/1 17.8 123 17.8 123 0.0％

HFC-1234yf/CF ₃I

1/99 12.0 83 12.0 83 0.2％

10/90 12.9 89 12.7 87 1.7％

20/80 13.7 94 13.3 92 2.6％

40/60 15.1 104 14.7 101 2.7％

60/40 16.2 111 15.8 109 2.0％

80/20 17.1 118 16.9 116 1.1％

90/10 17.5 120 17.4 120 0.5％

99/1 17.8 123 17.8 123 0.1％

HFC-125/HFC-1234yf/ Trimethylmethane (25 ℃)

85.1/11.5/3.4 201.3 1388 201.3 1388 0.0％

HFC-125/HFC-1234yf/ normal butane (25 ℃)

67/32/1 194.4 1340 190.2 1311 2.2％

HFC-32/HFC-125/HFC-1234yf(25℃)

40/50/10 240.6 1659 239.3 1650 0.5％

23/25/52 212.6 1466 192.9 1330 9.3％

15/45/40 213.2 1470 201.3 1388 5.6％

10/60/30 213.0 1469 206.0 1420 3.3％

HFC-1225ye/ is anti--HFC-1234ze

63.0/37.0 11.7 81 11.7 81 0.0％

80/20 11.6 80 11.6 80 0.0％

90/10 11.6 80 11.6 80 0.1％

99/1 11.5 79 11.5 79 0.0％

60/40 11.7 81 11.7 81 0.0％

40/60 11.6 80 11.6 80 0.1％

20/80 11.5 79 11.4 79 0.2％

10/90 11.3 78 11.3 78 0.1％

1/99 11.2 77 11.2 77 0.1％

HFC-1225ye/HFC-1243zf

40.0/60.0 13.6 94 13.6 94 0.0％

20/80 13.4 93 13.4 92 0.1％

10/90 13.2 91 13.2 91 0.2％

1/99 13.0 90 13.0 90 0.0％

60/40 13.4 92 13.4 92 0.4％

80/20 12.8 88 12.6 87 1.4％

90/10 12.3 85 12.1 83 1.5％

99/1 11.6 80 11.5 79 0.3％

HFC-1225ye/HFC-134

52.2/47.8 12.8 88 12.8 88 0.0％

80/20 12.4 85 12.3 85 0.6％

90/10 12.0 83 11.9 82 0.8％

99/1 11.5 79 11.5 79 0.2％

40/60 12.7 88 12.7 87 0.2％

20/80 12.3 85 12.2 84 0.8％

1 0/90 12.0 83 11.9 82 0.9％

1/99 11.6 80 11.6 80 0.2％

HFC-1225ye/HFC-134a

1/99 15.5 107 15.5 107 0.0％

10/90 15.2 105 15.2 105 0.3％

20/80 15.0 103 14.9 103 0.5％

40/60 14.4 99 14.2 98 1.0％

60/40 13.6 94 13.4 93 1.4％

80/20 12.7 88 12.5 86 1.6％

90/10 12.2 84 12.0 83 1.3％

99/1 11.5 80 11.5 79 0.2％

HFC-1225ye/HFC-152a

7.3/92.7 14.5 100 14.5 100 0.0％

1/99 14.5 100 14.5 100 0.0％

40/60 14.2 98 14.2 98 0.4％

60/40 13.7 95 13.6 93 1.1％

80/20 12.9 89 12.7 87 1.5％

90/10 12.2 84 12.1 83 1.1％

99/1 11.5 80 11.5 79 0.1％

HFC-1225ye/HFC-161

1/99 25.2 174 25.2 174 0.0％

1 0/90 24.9 172 24.8 171 0.6％

20/80 24.5 169 24.0 165 2.0％

40/60 22.9 158 21.4 148 6.5％

56/44 20.9 144 18.8 130 10.0％

99/1 11.7 81 11.6 80 1.0％

90/10 14.1 97 13.0 90 7.5％

84/16 15.5 107 14.0 96 9.9％

83/17 15.8 109 14.2 98 10.2％

HFC-1225ye/HFC-227ea

1/99 10.0 69 10.0 69 0.0％

10/90 10.1 70 10.1 70 0.2％

20/80 10.3 71 10.3 71 0.2％

40/60 10.6 73 10.6 73 0.4％

60/40 10.9 75 10.9 75 0.4％

80/20 11.2 77 11.2 77 0.3％

90/10 11.3 78 11.3 78 0.1％

99/1 11.5 79 11.5 79 0.0％

HFC-1 225ye/HFC-236ea

99/1 11.4 79 11.4 79 0.0％

90/10 11.3 78 11.2 77 0.5％

80/20 11.0 75 10.7 74 2.0％

60/40 10.2 70 9.4 65 8.3％

57/43 10.1 69 9.1 63 9.9％

56/44 10.0 69 9.0 62 10.6％

H FC-1 225ye/H FC-236fa

99/1 11.4 79 11.4 79 0.1％

90/10 11.1 77 11.0 76 1.1％

80/20 10.7 74 10.4 72 2.4％

60/40 9.8 68 9.2 63 6.6％

48/52 9.2 63 8.2 57 10.0％

HFC-1225ye/HFC-245fa

99/1 11.4 79 11.4 78 0.3％

90/10 10.9 75 10.6 73 2.5％

80/20 10.4 72 9.8 68 5.7％

70/30 9.9 68 8.9 61 9.9％

69/21 9.8 68 8.8 60 10.5％

HFC-1225ye/ propane

29.7/70.3 30.4 209 30.4 209 0.0％

20/80 30.3 209 30.2 208 0.2％

10/90 30.0 207 29.9 206 0.4％

1/99 29.5 203 29.5 203 0.1％

60/40 29.5 203 28.5 197 3.3％

72/28 28.4 195 25.6 176 9.8％

73/27 28.2 195 25.2 174 10.8％

The HFC-1225ye/ normal butane

89.5/10.5 12.3 85 12.3 85 0.0％

99/1 11.7 81 11.6 80 0.9％

80/20 12.2 84 12.0 83 1.5％

65/35 11.7 80 10.5 72 9.9％

64/36 11.6 80 10.4 71 10.9％

The HFC-1225ye/ Trimethylmethane

79.3/20.7 13.9 96 13.9 96 0.0％

90/10 13.6 94 13.3 92 2.4％

99/1 11.9 82 11.6 80 2.8％

60/40 13.5 93 13.0 89 4.1％

50/50 13.1 91 11.9 82 9.6％

49/51 13.1 90 11.8 81 10.2％

HFC-1225ye/DME

82.1/17.9 10.8 74 10.8 74 0.0％

90/10 10.9 75 10.9 75 0.3％

99/1 11.4 78 11.4 78 0.2％

60/40 11.5 79 11.2 77 2.4％

40/60 12.8 88 12.1 84 4.8％

20/80 13.9 96 13.5 93 3.0％

10/90 14.3 98 14.1 97 1.1％

1/99 14.5 100 14. 100 0.1％

HFC-1225ye/CF ₃I

1/99 11.9 82 11.9 82 0.0％

10/90 11.9 82 11.8 82 0.1％

20/80 11.8 81 11.8 81 0.0％

40/60 11.7 80 11.7 80 0.0％

60/40 11.6 80 11.6 80 0.0％

80/20 11.5 79 11.5 79 0.0％

90/10 11.5 79 11.5 79 0.0％

99/1 11.5 79 11.5 79 0.0％

HFC-1225ye/CF ₃SCF ₃

37.0/63.0 12.4 86 12.4 86 0.0％

20/80 12.3 85 12.3 85 0.1％

10/90 12.2 84 12.2 84 0.1％

1/99 12.0 83 12.0 83 0.1％

60/40 12.3 85 12.3 85 0.2％

80/20 12.0 83 11.9 82 0.4％

90/10 11.7 81 11.7 81 0.3％

99/1 11.5 79 11.5 79 0.1％

HFC-1225ye/HFC-134a/HFC-152a(25℃)

76/9/15 81.3 561 80.5 555 1.0％

HFC-1225ye/HFC-134a/HFC-161(25℃)

86/10/4 82.1 566 80.2 553 2.3％

HFC-1225ye/HFC-134a/isobutane(25℃)

87/10/3 83.4 575 80.3 554 3.7％

HFC-1225ye/HFC-134a/DME(25℃)

87/10/3 77.2 532 76.0 524 1.6％

HFC-1225ye/HFC-152a/ Trimethylmethane (25 ℃)

85/13/2 81.2 560 79.3 547 2.3％

HFC-1225ye/HFC-152a/DME(25℃)

85/13/2 76.6 528 76.0 524 0.8％

HFC-1225ye/HFC-1234yf/HFC-134a(25℃)

70/20/10 86.0 593 84.0 579 2.3％

20/70/10 98.2 677 97.5 672 0.7％

HFC-1225ye/HFC-1234yF/HFC-152a(25℃)

70/25/5 85.1 587 83.4 575 2.0％

25/70/5 95.4 658 94.9 654 0.5％

HFC-1225ye/HFC-1234yf/HFC-125(25℃)

25/71/4 105.8 729 96.3 664 9.0％

75/21/4 89.5 617 83.0 572 7.3％

75/24/1 85.3 588 82.3 567 3.5％

25/74/1 98.0 676 95.1 656 3.0％

HFC-1225ye/HFC-1234yf/CF ₃I(25℃)

40/40/20 87.5 603 86.0 593 1.7％

45/45/10 89.1 614 87.7 605 1.6％

HFC-1225ye/HFC-134a/HFC-152a/HFC-32(25℃)

74/8/17/1 86.1 594 81.5 562 5.3％

HFC-125/HFC-1225ye/ Trimethylmethane (25 ℃)

85.1/11.5/3.4 186.2 1284 179.2 1236 3.8％

HFC-32/HFC-125/HFC-1225ye(25℃)

30/40/30 212.7 1467 194.6 1342 8.5％

Instead-HFC-1234ze/cis-HFC-1234ze

99/1 11.1 77 11.1 76 0.4％

90/10 10.5 72 10.1 70 3.4％

80/20 9.8 68 9.1 63 7.1％

73/27 9.3 64 8.4 58 9.9％

72/28 9.3 64 8.3 57 10.3％

Instead-HFC-1234ze/HFC-1243zf

17.0/83.0 13.0 90 13.0 90 0.0％

10/90 13.0 90 13.0 90 0.0％

1/99 13.0 90 13.0 90 0.0％

40/60 12.9 89 12.9 89 0.1％

60/40 12.6 87 12.5 86 0.6％

80/20 12.1 83 12.0 82 0.8％

90/10 11.7 80 11.6 80 0.7％

99/1 11.2 77 11.2 77 0.1％

Instead-HFC-1234ze/HFC-134

45.7/54.3 12.5 86 12.5 86 0.0％

60/40 12.4 85 12.4 85 0.2％

80/20 12.0 83 11.9 82 0.7％

90/10 11.7 80 11.6 80 0.7％

99/1 11.2 77 11.2 77 0.1％

20/80 12.2 84 12.2 84 0.4％

10/90 11.9 82 11.9 82 0.6％

1/99 11.6 80 11.6 80 0.1％

Instead-HFC-1234ze/HFC-134a

9.5/90.5 15.5 107 15.5 107 0.0％

1/99 15.5 107 15.5 107 0.0％

40/60 15.1 104 15.0 103 0.9％

60/40 14.3 99 14.0 96 2.5％

80/20 13.1 90 12.6 87 4.0％

90/10 12.3 85 11.9 82 3.3％

99/1 11.3 78 11.3 78 0.5％

Instead-HFC-1234ze/HFC-152a

21.6/78.4 14.6 101 14.6 101 0.0％

10/90 14.6 101 14.6 101 0.0％

1/99 14.5 100 14.5 100 0.0％

40/60 14.5 100 14.5 100 0.1％

60/40 14.1 97 13.9 96 1.1％

80/20 13.2 91 12.8 88 2.5％

90/10 12.4 85 12.0 83 2.6％

99/1 11.3 78 11.3 78 0.4％

Instead-HFC-1234ze/HFC-161

1/99 25.2 174 25.2 174 0.0％

10/90 25.0 172 24.8 171 0.6％

20/80 24.5 169 24.0 165 2.1％

40/60 22.8 157 21.2 146 7.0％

52/48 21.3 147 19.2 132 9.9％

53/47 21.2 146 19.0 131 10.2％

99/1 11.5 79 11.3 78 1.2％

90/10 13.8 95 12.6 87 8.6％

88/12 14.3 99 12.9 89 9.5％

87/13 14.5 100 13.1 90 10.0％

Instead-HFC-1234ze/HFC-227ea

59.2/40.8 11.7 81 11.7 81 0.0％

40/60 11.6 80 11.5 79 0.3％

20/80 11.1 76 10.9 75 1.3％

10/90 10.6 73 10.5 72 1.3％

1/99 10.0 69 10.0 69 0.2％

80/20 11.6 80 11.5 80 0.2％

90/10 11.4 79 11.4 78 0.3％

99/1 11.2 77 11.2 77 0.0％

Instead-HFC-1234ze/HFC-236ea

99/1 11.2 77 11.2 77 0.0％

90/10 11.0 76 11.0 76 0.4％

80/20 10.8 75 10.6 73 1.6％

60/40 10.2 70 9.5 66 6.6％

54/46 9.9 69 9.0 62 9.5％

53/47 9.9 68 8.9 61 10.1％

Instead-HFC-1234ze/H FC-236fa

99/1 11.2 77 11.2 77 0.1％

90/10 10.9 75 10.8 75 0.8％

80/20 10.6 73 10.4 71 2.0％

60/40 9.8 67 9.3 64 5.4％

44/56 9.0 62 8.1 56 9.7％

43/57 8.9 62 8.0 55 10.1％

Instead-HFC-1234ze/HFC-245fa

99/1 11.2 77 11.1 77 0.2％

90/10 10.7 74 10.5 73 2.0％

80/20 10.3 71 9.8 68 4.7％

70/30 9.8 68 9.0 62 8.2％

67/33 9.7 67 8.7 60 9.7％

66/34 9.6 66 8.7 60 10.2％

Instead-HFC-1234ze/ propane

28.5/71.5 30.3 209 30.3 209 0.0％

10/90 30.0 206 29.9 206 0.3％

1/99 29.5 203 29.5 203 0.1％

40/60 30.2 208 30.1 207 0.4％

60/40 29.3 202 28.3 195 3.4％

71/29 28.4 196 25.7 177 9.3％

72/28 28.3 195 25.4 175 10.2％

Instead-the HFC-1234ze/ normal butane

88.6/11.4 11.9 82 11.9 82 0.0％

95/5 11.7 81 11.7 80 0.7％

99/1 11.4 78 11.3 78 0.6％

70/30 11.5 79 11.0 76 4.2％

62/38 11.2 77 10.2 70 9.3％

61/39 11.2 77 10.0 69 10.1％

Instead-the HFC-1234ze/ Trimethylmethane

77.9/22.1 12.9 89 12.9 89 0.0％

90/10 12.6 87 12.4 85 1.6％

99/1 11.4 79 11.3 78 1.1％

60/40 12.6 87 12.3 85 2.4％

39/61 11.7 81 10.6 73 9.8％

38/62 11.7 81 10.5 72 10.1％

Instead-HFC-1234ze/DME

84.1/15.9 10.8 74 10.8 74 0.0％

90/10 10.8 75 10.8 75 0.0％

99/1 11.1 77 11.1 77 0.0％

60/40 11.5 79 11.3 78 2.2％

40/60 12.7 88 12.2 84 4.4％

20/80 13.9 96 13.5 93 2.9％

10/90 14.3 98 14.1 97 1.0％

1/99 14.5 100 14.5 100 0.0％

Instead-HFC-1234ze/CF ₃SCF ₃

34.3/65.7 12.7 87 12.7 87 0.0％

20/80 12.6 87 12.6 87 0.2％

10/90 12.4 85 12.3 85 0.3％

1/99 12.0 83 12.0 83 0.1％

60/40 12.4 86 12.4 85 0.5％

80/20 12.0 82 11.8 81 1.1％

90/10 11.6 80 11.5 79 0.9％

99/1 11.2 77 11.2 77 0.2％

Instead-HFC-1234ze/CF ₃I

1/99 11.9 82 11.9 82 0.0％

10/90 11.9 82 11.9 82 0.0％

20/80 11.8 81 11.8 81 0.0％

40/60 11.6 80 11.6 80 0.1％

60/40 11.4 79 11.4 79 0.1％

80/20 11.3 78 11.3 78 0.1％

90/10 11.3 78 11.2 77 0.1％

99/1 11.2 77 11.2 77 0.0％

HFC-32/HFC-125/ is anti--HFC-1234ze (25 ℃)

30/40/30 221.5 1527 209.4 1444 5.5％

30/50/20 227.5 1569 220.2 1518 3.2％

HFC-125/ is anti--HFC-1234ze/ normal butane (25 ℃)

66/32/2 180.4 1244 170.3 1174 5.6％

HFC-1243zf/HFC-134

63.0/37.0 13.5 93 13.5 93 0.0％

80/20 13.4 93 13.4 92 0.1％

90/10 13.2 91 13.2 91 0.2％

99/1 13.0 90 13.0 90 0.0％

40/60 13.3 92 13.3 91 0.5％

20/80 12.7 88 12.6 87 1.3％

10/90 12.3 84 12.1 83 1.5％

1/99 11.6 80 11.6 80 0.3％

HFC-1243zf/HFC-134a

25.1/74.9 15.9 110 15.9 110 0.0％

10/90 15.8 109 15.8 109 0.1％

1/99 15.5 107 15.5 107 0.1％

40/60 15.8 109 15.8 109 0.2％

60/40 15.3 106 15.1 104 1.2％

80/20 14.4 99 14.1 97 2.1％

90/10 13.8 95 13.5 93 1.7％

99/1 13.1 90 13.0 90 0.2％

HFC-1243zf/HFC-152a

40.7/59.3 15.2 104 15.2 104 0.0％

20/80 15.0 103 15.0 103 0.2％

10/90 14.8 102 14.7 102 0.3％

1/99 14.5 100 14.5 100 0.1％

60/40 15.0 103 14.9 103 0.3％

80/20 14.4 99 14.2 98 1.1％

90/10 13.8 95 13.6 94 1.2％

99/1 13.1 90 13.1 90 0.2％

HFC-1243zf/HFC-161

1/99 25.2 174 25.2 174 0.0％

10/90 24.9 172 24.8 171 0.3％

20/80 24.5 169 24.2 167 0.9％

40/60 23.3 160 22.6 156 2.9％

60/40 21.5 148 20.1 139 6.3％

78/22 18.8 130 16.9 117 10.0％

90/10 16.2 111 14.6 101 9.5％

99/1 13.4 92 13.1 90 1.7％

HFC-1243zf/HFC-227ea

78.5/21.5 13.1 90 13.1 90 0.0％

90/10 13.1 90 13.1 90 0.0％

99/1 13.0 90 13.0 90 0.0％

60/40 13.0 90 13.0 89 0.2％

40/60 12.6 87 12.5 86 1.1％

20/80 11.8 81 11.5 79 2.7％

10/90 11.1 76 10.7 74 2.8％

1/99 10.1 69 10.0 69 0.6％

HFC-1243zf/HFC-236ea

99/1 13.0 89 13.0 89 0.0％

90/10 12.8 88 12.7 87 0.5％

80/20 12.5 86 12.3 84 1.8％

60/40 11.7 81 11.0 76 6.6％

53/47 11.4 79 10.3 71 9.9％

52/48 11.4 78 10.2 70 10.5％

HFC-1243zf/HFC-236fa

99/1 13.0 89 12.9 89 0.1％

90/10 12.6 87 12.5 86 1.0％

80/20 12.2 84 11.9 82 2.5％

60/40 11.3 78 10.5 73 6.6％

49/51 10.6 73 9.6 66 9.9％

48/52 10.6 73 9.5 65 10.2％

HFC-1243zf/HFC-245fa

99/1 12.9 89 12.9 89 0.2％

90/10 12.5 86 12.2 84 2.1％

80/20 12.0 83 11.4 79 4.6％

70/30 11.5 79 10.6 73 7.9％

66/34 11.3 78 10.2 70 9.6％

65/35 11.2 77 10.1 69 10.2％

HFC-1243zf/ propane

32.8/67.2 31.0 213 31.0 213 0.0％

10/90 30.3 209 30.1 207 0.7％

1/99 29.5 204 29.5 203 0.1％

60/40 30.1 208 29.2 201 3.2％

72/28 29.0 200 26.1 180 10.2％

71/29 29.2 201 26.5 182 9.3％

The HFC-1243zf/ normal butane

90.3/9.7 13.5 93 13.5 93 0.0％

99/1 13.1 90 13.1 90 0.2％

62/38 12.6 87 11.4 79 9.4％

61/39 12.6 87 11.3 78 10.3％

The HFC-1243zf/ Trimethylmethane

80.7/19.3 14.3 98 14.3 98 0.0％

90/10 14.1 97 14.0 96 0.9％

99/1 13.2 91 13.1 90 0.7％

60/40 13.8 95 13.4 92 3.2％

45/55 13.1 91 11.9 82 9.5％

44/56 13.1 90 11.8 81 10.1％

HFC-1243zf/DME

72.7/27.3 12.0 83 12.0 83 0.0％

90/10 12.4 85 12.3 85 0.5％

99/1 12.9 89 12.9 89 0.1％

60/40 12.2 84 12.1 84 0.5％

40/60 13.0 90 12.7 88 2.2％

20/80 14.0 96 13.7 95 2.0％

10/90 14.3 99 14.2 98 0.6％

1/99 14.5 100 14.5 100 0.0％

Suitable-HFC-1234ze/HFC-236ea (25 ℃)

20.9/79.1 30.3 209 30.3 209 0.0％

10/90 30.2 208 30.2 208 0.0％

1/99 29.9 206 29.9 206 0.0％

40/60 30/0 207 30.0 207 0.2％

60/40 29.2 201 28.9 199 0.9％

80/20 27.8 191 27.4 189 1.4％

90/10 26.8 185 26.5 183 1.1％

99/1 25.9 178 25.8 178 0.2％

Suitable-HFC-1234ze/HFC-236fa (25 ℃)

1/99 39.3 271 39.3 271 0.0％

10/90 38.6 266 38.4 265 0.3％

20/80 37.6 259 37.3 257 0.9％

40/60 35.4 244 34.5 238 2.5％

60/40 32.8 226 31.4 216 4.3％

78/22 29.6 204 28.2 195 4.8％

90/10 27.8 192 26.9 185 3.4％

99/1 26.0 179 25.8 178 0.5％

Suitable-HFC-1234ze/HFC-245fa (25 ℃)

76.2/23.7 26.2 180 26.2 180 0.0％

90/10 26.0 179 26.0 179 0.0％

99/1 25.8 178 25.8 178 0.0％

60/40 26.0 179 25.9 179 0.2％

40/60 25.3 174 25.0 173 0.9％

20/80 23.9 164 23.5 162 1.7％

10/90 22.8 157 22.5 155 1.5％

1/99 21.6 149 21.5 149 0.2％

Suitable-the HFC-1234ze/ normal butane

51.4/48.6 6.1 42 6.1 42 0.0％

80/20 5.8 40 5.2 36 9.3％

81/19 5.8 40 5.2 36 10.4％

40/60 6.1 42 6.0 41 0.7％

20/80 5.8 40 5.6 39 3.3％

10/90 5.6 38 5.4 37 3.1％

1/99 5.3 36 5.2 36 0.6％

Suitable-the HFC-1234ze/ Trimethylmethane

26.2/73.8 8.7 60 8.7 60 0.0％

10/90 8.7 60 8.6 59 0.3％

1/99 8.5 59 8.5 59 0.0％

40/60 8.7 60 8.6 60 0.5％

60/40 8.4 58 8.0 55 4.3％

70/30 8.1 56 7.3 50 10.3％

69/31 8.2 56 7.4 51 9.4％

Suitable-the HFC-1234ze/2-methylbutane (25 ℃)

86.6/13.4 27.3 188 27.3 188 0.0％

90/10 27.2 187 27.2 187 0.1％

99/1 26.0 180 25.9 179 0.5％

60/40 25.8 178 24.0 166 6.9％

55/45 25.3 174 22.8 157 10.0％

Suitable-the HFC-1234ze/ Skellysolve A (25 ℃)

92.9/9.1 26.2 181 26.2 181 0.0％

99/1 25.9 178 25.9 178 0.1％

80/20 25.6 177 25.2 174 1.8％

70/30 24.8 171 23.5 162 5.6％

64/36 24.3 167 22.0 152 9.2％

63/37 24.2 167 21.8 150 9.9％

HFC-1234ye/HFC-134(25℃)

1/99 75.9 523 75.8 523 0.1％

10/90 73.8 509 73.0 503 1.1％

20/80 71.3 491 69.0 476 3.1％

38/62 66.0 455 59.6 411 9.7％

39/61 65.7 453 58.9 406 10.2％

H FC-1234ye/HFC-236ea(-25℃)

24.0/76.0 3.4 23 3.4 23 0.0％

10/90 3.3 23 3.3 23 0.3％

1/99 3.3 23 3.3 23 0.0％

40/60 3.3 23 3.3 23 0.0％

60/40 3.2 22 3.2 22 0.9％

80/20 3.1 21 3.0 21 1.6％

90/10 2.9 20 2.9 20 1.4％

99/1 2.8 19 2.8 19 0.0％

HFC-1234ye/HFC-236fa(25℃)

1/99 39.2 270 39.2 270 0.1％

10/90 37.7 260 37.3 257 1.1％

20/80 36.1 249 35.2 243 2.5％

40/60 32.8 226 31.0 213 5.7％

60/40 29.3 202 26.7 184 8.8％

78/22 25.4 175 23.1 159 9.1％

90/10 23.2 160 21.7 150 6.3％

99/1 21.0 145 20.8 144 0.8％

HFC-1234ye/HFC-245fa(25℃)

42.5/57.5 22.8 157 22.8 157 0.0％

20/80 22.5 155 22.4 155 0.3％

10/90 22.1 152 22.0 152 0.3％

1/99 21.5 148 21.5 148 0.0％

60/40 22.6 156 22.6 156 0.2％

80/20 22.0 152 21.9 151 0.6％

90/10 21.5 148 21.3 147 0.6％

99/1 20.8 144 20.8 143 0.1％

HFC-1234ye/ is suitable-HFC-1234ze (25 ℃)

1/99 25.7 177 25.7 177 0.0％

10/90 25.6 176 25.6 176 0.0％

20/80 25.3 175 25.3 174 0.1％

40/60 24.7 170 24.5 169 0.5％

60/40 23.7 163 23.5 162 1.0％

78/22 22.4 155 22.2 153 1.2％

90/10 21.7 149 21.5 148 0.9％

99/1 20.9 144 20.8 144 0.1％

HFC-1234ye/ normal butane (25 ℃)

41.2/58.8 38.0 262 38.0 262 0.0％

20/80 37.3 257 37.0 255 0.8％

10/90 36.4 251 36.1 249 0.9％

1/99 35.4 244 35.3 243 0.2％

60/40 37.4 258 36.9 254 1.4％

70/30 36.5 252 34.9 241 4.4％

78/22 35.3 243 31.8 219 9.9％

79/21 35.1 242 31.3 216 10.9％

HFC-1234ye/ pentamethylene (25 ℃)

99/1 20.7 143 20.7 143 0.0％

90/10 20.3 140 20.0 138 1.0％

80/20 19.5 134 18.7 129 4.1％

70/30 18.6 128 16.9 116 9.5％

69/31 18.5 128 16.6 115 10.3％

HFC-1234ye/ Trimethylmethane (25 ℃)

16.4/83.6 50.9 351 50.9 351 0.0％

10/90 50.9 351 50.9 351 0.0％

1/99 50.5 348 50.5 348 0.0％

40/60 50.1 345 49.6 342 1.0％

60/40 47.8 330 45.4 313 5.2％

68/32 46.4 320 42.0 289 9.5％

69/31 46.2 318 41.4 286 10.3％

HFC-1234ye/2-methylbutane (25 ℃)

80.3/19.7 23.1 159 23.1 159 0.0％

90/10 22.8 157 22.6 156 1.1％

99/1 21.2 146 20.9 144 1.0％

60/40 22.5 155 21.7 149 3.6％

47/53 21.5 148 19.4 134 9.6％

46/54 21.4 148 19.2 133 10.1％

HFC-1234ye/ Skellysolve A (25 ℃)

87.7/12.3 21.8 150 21.8 150 0.0％

95/5 21.5 149 21.4 148 0.5％

99/1 21.0 145 20.9 144 0.4％

60/40 20.5 141 18.9 131 7.7％

57/43 20.3 140 18.3 126 9.7％

56/44 20.2 139 18.1 125 10.4％

For composition of the present invention, original composition and removing after the 50wt% vapour pressure difference between the remaining composition then less than about 10%.This shows that composition of the present invention may be an azeotropic or near azeotropic.

Embodiment 2

The refrigeration performance data

Table 10 shows the performance that various refrigerant compositions of the present invention are compared with HFC-134a.In table 10, Evap Pres is an evaporator pressure, and Cond Pres is a condenser pressure, and Comp Disch T is the compressor temperature out, and COP is an energy efficiency, and CAP is capacity (capacity).Data are based on following condition.

Evaporator temperature 40.0 (4.4 ℃)

Condenser temperature 130.0 (54.4 ℃)

Supercooling temperature 10.0 (5.5 ℃)

Return gas temperature 60.0 (15.6 ℃)

Compressor efficiency is 100%

Should point out that it is overheated to have considered during cooling capacity calculates.

Table 10

Form (wt%)	Evap Pres (Psia)	Evap Pres (kPa)	Cond Pres (Psia)	Cond Pres (kPa)	Comp Disch T (F)	Comp Disch T (C)	Cap (Btu/ min)	Cap (kW)	COP
										HFC-134a	50.3	346	214	1476	156	68.9	213	3.73	4.41
HFC-1225ye/HFC-152a(85/15)	39.8	274	173	1193	151	66.1	173	3.03	4.45
HFC-1225ye/HFC-32 (95/5)	46.5	321	197	1358	151	66.1	200	3.50	4.53
										HFC-1225ye/HFC-32 (97/3)	43.1	297	184	1269	149	65.0	186	3.26	4.50
HFC-1225ye/HFC-134a (90/10)	39.5	272	172	1186	147	63.9	169	2.96	4.40
										HFC-1225ye/CO 2 (99/1)	43.2	298	179	1234	146	63.3	177	3.10	4.63
HFC-1225ye/HFC-134a/HFC-32 (88/9/3)	44.5	307	190	1310	150	65.6	191	3.35	4.49
										HFC-1225ye/HFC-134a/HFC- 152a (76/9/15)	41.0	283	178	1227	153	67.2	178	3.12	4.44
HFC-1225ye/HFC-134a/HFC- 161 (86/10/4)	42.0	290	181	1248	150	65.6	179	3.13	4.42
										HFC-1225ye/HFC-134a/ propane (87/10/3)	47.0	324	195	1345	146	64.4	197	3.45	4.49
HFC-1225ye/HFC-134a/ Trimethylmethane (87/10/3)	41.7	288	178	1227	146	63.3	175	3.06	4.39
										HFC-1225ye/HFC-134a/DME (87/10/3)	38.7	267	169	1165	149	65.0	168	2.94	4.44
HFC-1225ye/HFC-134a/CO 2 (88.5/11/.5)	42.4	292	180	1241	147	63.9	182	3.18	4.51
										HFC-1225ye/HFC-134/HFC-32 (88/9/3)	43.0	296	185	1276	150	65.6	187	3.27	4.51
HFC-1225ye/HFC-152a/HFC-32 (85/10/5)	46.7	322	198	1365	155	68.3	203	3.55	4.53
										HFC-1225ye/HFC-152a/HFC-32 (81/15/4)	45.5	314	193	1331	155	68.3	198	3.47	4.52
HFC-1225ye/HFC-152a/HFC-32 (82/15/3)	44.1	304	188	1296	155	68.3	192	3.36	4.50
										HFC-1225ye/HFC-152a/ propane (85/13/2)	44.4	306	185	1276	151	66.1	190	3.33	4.52

HFC-1225ye/HFC-152a/ Trimethylmethane (85/13/2)	40.9	282	176	1214	150	65.6	175	3.06	4.44
										HFC-1225ye/HFC-152a/DME (85/13/2)	39.0	269	170	1172	152	66.7	171	3.00	4.46
HFC-1225ye/HFC-152a/CO 2 (84/15/1)	44.8	309	185	1276	151	66.1	195	3.42	4.64
										HFC-1225ye/HFC-152a/CO 2 (84/15.5/0.5)	42.3	292	179	1234	151	66.1	184	3.22	4.55
HFC-1234yf/HFC-32 (95/5)	58.6	404	230	1586	149	65.0	228	4.00	4.36
										HFC-1234yf/HFC-134a (90/10)	52.7	363	210	1448	145	62.8	206	3.61	4.33
HFC-1234yf/HFC-152a (80/20)	53.5	369	213	1468	150	65.6	213	3.73	4.38
										trans-H FC-1234ze/HFC-32 (95/5)	42.6	294	183	1262	153	67.2	186	3.26	4.51
trans-HFC-1234ze/HFC-134a (90/10)	38.1	263	166	1145	149	65.0	165	2.89	4.44
										trans-HFC-1234ze/HFC-152a (80/20)	41.0	284	176	1214	154	67.8	177	3.10	4.48
HFC-1225ye/HFC-1234yf (51/49)	46.0	317	190	1310	145	62.8	186	3.26	4.35
										HFC-1225ye/HFC-1234yf (60/40)	44.0	303	187	1289	146	63.3	179	3.13	4.30
HFC-1225ye/HFC-1234yf/HFC- 134a(70/20/10)	43.0	296	183	1261	147	63.9	179	3.13	4.38
										HFC-1225ye/HFC-1234yf/HFC- 134a(20/70/10)	50.7	350	205	1412	145	62.8	200	3.50	4.34
HFC-1225ye/HFC-1234yf/HFC- 32(25/73/2)	53.0	365	212	1464	146	63.3	210	3.68	4.37
										H FC-1225ye/H FC-1234yf/HFC- 32(75/23/2)	45.3	312	190	1312	148	64.4	189	3.31	4.43
HFC-1225ye/HFC-1234yf/HFC- 152a(70/25/5)	42.8	295	181	1250	147	63.9	179	3.13	4.40
										HFC-1225ye/HFC-1234yf/HFC- 152a(25/70/5)	49.9	344	202	1392	146	63.3	199	3.49	4.35
HFC-1225ye/HFC-1234yf/HFC- 125(25/71/4)	51.6	356	207	1429	145	62.8	202	3.54	4.33
										HFC-1225ye/HFC-1234yf/HFC- 125(75/21/4)	43.4	299	184	1268	146	63.3	180	3.15	4.38
HFC-1225ye/HFC-1234yf/HFC- 125(75/24/1)	42.4	292	180	1241	145	62.8	176	3.08	4.39
										HFC-1225ye/HFC-1234yf/HFC- 125(25/74/1)	50.2	346	202	1395	144	62.2	198	3.47	4.33
HFC-1225ye/HFC-1234yf (25/75)	49.8	343	201	1383	144	62.2	196	3.43	4.34
										HFC-1225ye/HFC-1234yf/CF 3I (40/40/20)	47.9	330	195.0	1344	147.5	64.2	192	3.36	4.34
HFC-1225ye/HFC-1234yf/CF 3I (45/45/10)	47.0	324	192.9	1330	146	63.3	189	3.31	4.35
										HFC-1225ye/HFC-1234yf/HFC- 32 (49/49/2)	49.5	341	202.5	1396	146.9	63.8	201	3.52	4.4
HFC-1225ye/HFC-134a/HFC- 152a/HFC-32(74/8/17/1)trans- HFC	42.5	293	183	1260	154	67.8	184.3	3.23	4.47

Several compositions has even the energy efficiency (COP) higher than HFC-134a, keeps lower outlet pressure and temperature simultaneously.The capacity of the present composition is also similar to R134a, and this shows that they may be used as the replacement cooling agent of R134a at refrigeration and air-conditioning in the especially motion air conditioning applications.Those compositions of hydrocarbonaceous can also improve the oily solvability with conventional mineral oil and alkyl benzene lubricants.

Embodiment 3

The refrigeration performance data

Table 11 shows the performance that various refrigerant compositions of the present invention and R404A compare with R422A.

In table 11, Evap Pres is an evaporator pressure, and Cond Pres is a condenser pressure, and CompDisch T is the compressor temperature out, and EER is an energy efficiency, and CAP is a capacity.Data are based on following condition.

Evaporator temperature-17.8 ℃

46.1 ℃ of condenser temperatures

5.5 ℃ of supercooling temperatures

Return 15.6 ℃ of gas temperatures

Compressor efficiency is 70%

Should point out that it is overheated to have considered during cooling capacity calculates.

Table 11

Several compositions has and R404A and the similar energy efficiency of R422A (COP).Exhaust temperature also is lower than R404A and R507A.The capacity of the present composition is also similar with R422A to R404A, R507A, and this shows that they may be used as replacement cooling agent in refrigeration and air-conditioning.Those compositions of hydrocarbonaceous can also improve the oily solvability with conventional mineral oil and alkyl benzene lubricants.

Embodiment 4

The refrigeration performance data

Table 12 has shown the performance that various refrigerant compositions of the present invention is compared with HCFC-22, R410A, R407C and R417A.In table 12, Evap Pres is an evaporator pressure, and Cond Pres is a condenser pressure, and Comp Disch T is the compressor temperature out, and EER is an energy efficiency, and CAP is a capacity.Data are based on following condition.

4.4 ℃ of evaporator temperatures

54.4 ℃ of condenser temperatures

5.5 ℃ of supercooling temperatures

Return 15.6 ℃ of gas temperatures

Compressor efficiency is 100%

Should point out that it is overheated to have considered during cooling capacity calculates.

Table 12

Composition has and R22, R407C, R417A and the similar energy efficiency of R410A (EER), keeps low exhaust temperature simultaneously.The capacity of the present composition is also similar with R417A to R22, R407C, and this shows that they may be used as replacement cooling agent in refrigeration and air-conditioning.Those compositions of hydrocarbonaceous can also improve the oily solvability with conventional mineral oil and alkyl benzene lubricants.

Embodiment 5

The refrigeration performance data

Table 12 has shown the performance that various refrigerant compositions of the present invention and HCFC-22 compare with R410A.In table 12, Evap Pres is an evaporator pressure, and Cond Pres is a condenser pressure, and CompDisch T is the compressor temperature out, and EER is an energy efficiency, and CAP is a capacity.Data are based on following condition.

4 ℃ of evaporator temperatures

43 ℃ of condenser temperatures

6 ℃ of supercooling temperatures

Return 18 ℃ of gas temperatures

Compressor efficiency is 70%

Should point out that it is overheated to have considered during cooling power is calculated.

Table 13

Composition has and R22 and the similar energy efficiency of R410A (EER), keeps rational exhaust temperature simultaneously.The capacity of the present composition is also similar to R22, and this shows that they may be used as replacement cooling agent in refrigeration and air-conditioning.

Embodiment 6

Incendivity

Combustible cpd can adopt an electrical ignition element source to test definite by under ASTM (American Society of Testing andMaterials) E681-01.Under 101kPa (14.7psia), 100 ℃ (212) and 50% relative humidity, the mixture of HFC-1234yf, HFC-1225ye and the disclosure of invention is carried out this type of flammability test to determine the incendivity lower limit (LFL) and the incendivity upper limit (UFL) with aerial various concentration.The result provides in table 13.

Table 14

Form	LFL (vol% is in air)	UFL (vol% is in air)
			HFC-1225ye(100wt％)	Do not fire	Do not fire
HFC-1234yf(100wt％)	5.0	14.5
			HFC-1234yf/225ye (50/50wt％)	8.5	12.0
HFC-1234yf/1225ye (40/60wt％)	Do not fire	Do not fire

The result shows that the interpolation of HFC-1225ye reduces incendivity as HFC-1234yf when being combustible.Therefore, comprise the about 49wt%HFC-1234yf of about 1wt%-and approximately the composition of the about 51wt%HFC-1225ye of 99wt%-be preferred.

Claims (68)

1. comprise HFC-1225ye and at least a compound compositions that is selected from following material: HFC-1234ze, HFC-1234yf, HFC-1234ye, HFC-1243zf, HFC-32, HFC-125, HFC-134, HFC-134a, HFC-143a, HFC-152a, HFC-161, HFC-227ea, HFC-236ea, HFC-236fa, HFC-245fa, HFC-365mfc, propane, normal butane, Trimethylmethane, 2-methylbutane, Skellysolve A, pentamethylene, dimethyl ether, CF ₃SCF ₃, CO ₂And CF ₃I.

2. comprise HFC-1234ze and at least a compound compositions that is selected from following material: HFC-1234yf, HFC-1234ye, HFC-1243zf, HFC-32, HFC-125, HFC-134, HFC-134a, HFC-143a, HFC-152a, HFC-161, HFC-227ea, HFC-236ea, HFC-236fa, HFC-245fa, HFC-365mfc, propane, normal butane, Trimethylmethane, 2-methylbutane, Skellysolve A, pentamethylene, dimethyl ether, CF ₃SCF ₃, CO ₂And CF ₃I.

3. comprise HFC-1234yf and at least a compound compositions that is selected from following material: HFC-1234ye, HFC-1243zf, HFC-32, HFC-125, HFC-134, HFC-134a, HFC-143a, HFC-152a, HFC-161, HFC-227ea, HFC-236ea, HFC-236fa, HFC-245fa, HFC-365mfc, propane, normal butane, Trimethylmethane, 2-methylbutane, Skellysolve A, pentamethylene, dimethyl ether, CF ₃SCF ₃, CO ₂And CF ₃I.

4. comprise HFC-1234ye and at least a compound compositions that is selected from following material: HFC-1243zf, HFC-32, HFC-125, HFC-134, HFC-134a, HFC-143a, HFC-152a, HFC-161, HFC-227ea, HFC-236ea, HFC-236fa, HFC-245fa, HFC-365mfc, propane, normal butane, Trimethylmethane, 2-methylbutane, Skellysolve A, pentamethylene, dimethyl ether, CF ₃SCF ₃, CO ₂And CF ₃I.

5. comprise HFC-1243zf and at least a compound compositions that is selected from following material: HFC-32, HFC-125, HFC-134, HFC-134a, HFC-143a, HFC-152a, HFC-161, HFC-227ea, HFC-236ea, HFC-236fa, HFC-245fa, HFC-365mfc, propane, normal butane, Trimethylmethane, 2-methylbutane, Skellysolve A, pentamethylene, dimethyl ether, CF ₃SCF ₃, CO ₂And CF ₃I.

6. the composition of claim 1 is selected from:

HFC-1225ye and HFC-32;

HFC-1225ye and HFC-134a;

HFC-1225ye and HFC-134;

HFC-1225ye and CO ₂

HFC-1225ye, HFC-152a and HFC-32;

HFC-1225ye, HFC-152a and CO ₂

HFC-1225ye, HFC-152a and propane;

HFC-1225ye, HFC-152a and Trimethylmethane;

HFC-1225ye, HFC-152a and dimethyl ether;

HFC-1225ye, HFC-134a and HFC-152a;

HFC-1225ye, HFC-134a, HFC-152a and HFC-32;

HFC-1225ye, HFC-134a and HFC-32;

HFC-1225ye, HFC-134a and HFC-161;

HFC-1225ye, HFC-134a and CO ₂

HFC-1225ye, HFC-134a and propane;

HFC-1225ye, HFC-134a and Trimethylmethane;

HFC-1225ye, HFC-134a and dimethyl ether;

HFC-1225ye, HFC-134 and HFC-32;

HFC-1225ye, HFC-1234yf and HFC-134a;

HFC-1225ye, HFC-1234yf and HFC-32;

HFC-1225ye, HFC-1234yf and HFC-152a;

HFC-1225ye, HFC-1234yf and HFC-125;

HFC-1225ye, HFC-1234yf and CF ₃I;

HFC-1225ye, HFC-32 and HFC-125;

HFC-1225ye, HFC-125 and normal butane;

HFC-1225ye, HFC-125 and Trimethylmethane;

HFC-1225ye, anti--HFC-1234ze and HFC-134;

HFC-1225ye, anti--HFC-1234ze and HFC-227ea;

HFC-1225ye, anti--HFC-1234ze and propane;

HFC-1225ye, anti--HFC-1234ze and normal butane;

HFC-1225ye, anti--HFC-1234ze and dimethyl ether;

HFC-1225ye, anti--HFC-1234ze and CF ₃SCF ₃

HFC-1225ye, HFC-1243zf and HFC-134;

HFC-1225ye, HFC-1243zf and normal butane;

HFC-1225ye, HFC-1243zf and Trimethylmethane;

HFC-1225ye, HFC-1243zf and dimethyl ether;

HFC-1225ye, HFC-1243zf and CF ₃I;

HFC-1225ye, HFC-134 and HFC-152a;

HFC-1225ye, HFC-134 and HFC-227ea;

HFC-1225ye, HFC-134 and normal butane;

HFC-1225ye, HFC-134 and Trimethylmethane;

HFC-1225ye, HFC-134 and dimethyl ether;

HFC-1225ye, HFC-227ea and dimethyl ether;

HFC-1225ye, normal butane and dimethyl ether;

HFC-1225ye, normal butane and CF ₃SCF ₃

HFC-1225ye, Trimethylmethane and dimethyl ether;

HFC-1225ye, Trimethylmethane and CF ₃I;

HFC-1225ye, HFC-32 and CF ₃I;

HFC-1225ye, HFC-1234yf, HFC-32 and HFC-125;

HFC-1225ye, HFC-1234yf, HFC-32, HFC-125 and CF ₃I;

HFC-1225ye, HFC-32, HFC-125 and HFC-152a;

HFC-1225ye, HFC-32, HFC-125 and Trimethylmethane;

HFC-1225ye, HFC-32, HFC-125 and propane;

HFC-1225ye, HFC-32, HFC-125 and dimethyl ether;

HFC-1225ye, HFC-32, CF ₃I and dimethyl ether;

HFC-1225ye, HFC-32, HFC-125 and CF ₃I; And

HFC-1225ye, HFC-1234yf, HFC-32 and HFC-134a.

7. the composition of claim 1 is selected from:

The approximately about 99wt%HFC-1225ye of 1wt%-and the approximately about 1wt%HFC-32 of 99wt%-;

The approximately about 99wt%HFC-1225ye of 1wt%-and the approximately about 1wt%HFC-134a of 99wt%-;

The approximately about 99.9wt%HFC-1225ye of 0.1wt%-and the approximately about 0.1wt%CO of 99.9wt%- ₂

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-152a of 1wt%-and the approximately about 98wt%HFC-32 of 1-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-152a of 1wt%-and the approximately about 98wt%CO of 0.1- ₂

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-152a of 1wt%-and the approximately about 98wt% propane of 1-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-152a of 1wt%-and the approximately about 98wt% Trimethylmethane of 1-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-152a of 1wt%-and the approximately about 98wt% dimethyl ether of 1-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-134a of 1wt%-and the approximately about 98wt%HFC-152a of 1-;

About about 97wt%HFC-1225ye of 1wt%-, about about 97wt%HFC-134a of 1wt%-, about about 97wt%HFC-152a of 1wt%-and about about 97wt%HFC-32 of 0.1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-134a of 1wt%-and the approximately about 98wt%HFC-32 of 1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-134a of 1wt%-and the approximately about 98wt%HFC-161 of 1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-134a of 1wt%-and the approximately about 98wt%CO of 0.1- ₂

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-134a of 1wt%-and the approximately about 98wt% propane of 1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-134a of 1wt%-and the approximately about 98wt% Trimethylmethane of 1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-134a of 1wt%-and the approximately about 98wt% dimethyl ether of 1wt%-; With

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-134 of 1wt%-and the approximately about 98wt%HFC-32 of 1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-1234yf of 1wt%-and the approximately about 98wt%HFC-134a of 0.1-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-1234yf of 1wt%-and the approximately about 98wt%HFC-32 of 0.1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-1234yf of 1wt%-and the approximately about 98wt%HFC-152a of 0.1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-1234yf of 1wt%-and the approximately about 98wt%HFC-125 of 0.1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-1234yf of 1wt%-and the approximately about 98wt%CF of 0.1- ₃I;

The approximately about 98wt%HFC-32 of 0.1wt%-, about about 98wt%HFC-125 of 0.1wt%-and the approximately about 98wt%HFC-1225ye of 0.1wt%-;

The approximately about 98wt%HFC-125 of 0.1wt%-, about about 98wt%HFC-1225ye of 0.1wt%-and the approximately about 98wt% normal butane of 0.1wt%-; With

The approximately about 98wt%HFC-125 of 0.1wt%-, about about 98wt%HFC-1225ye of 0.1wt%-and the approximately about 98wt% Trimethylmethane of 0.1wt%-;

Approximately the about 98wt%HFC-1225ye of 1wt%-, approximately the about 98wt% of 1wt%-anti--HFC-1234ze and the about about 98wt%HFC-134 of 1wt%-;

Approximately the about 98wt%HFC-1225ye of 1wt%-, approximately the about 98wt% of 1wt%-anti--HFC-1234ze and the about about 98wt%HFC-227ea of 1wt%-;

Approximately the about 60wt%HFC-1225ye of 1wt%-, approximately the about 60wt% of 1wt%-anti--HFC-1234ze and the about about 98wt% propane of 39wt%-;

Approximately the about 98wt%HFC-1225ye of 1wt%-, approximately the about 98wt% of 1wt%-anti--HFC-1234ze and the about about 30wt% normal butane of 1wt%-;

Approximately the about 98wt%HFC-1225ye of 1wt%-, approximately the about 98wt% of 1wt%-anti--HFC-1234ze and the about about 98wt% dimethyl ether of 1wt%-;

Approximately the about 98wt%HFC-1225ye of 1wt%-, approximately the about 98wt% of 1wt%-anti--HFC-1234ze and the about about 98wt%CF of 1wt%- ₃SCF ₃

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-1243zf of 1wt%-and the approximately about 98wt%HFC-134 of 1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-1243zf of 1wt%-and the approximately about 30wt% normal butane of 1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-1243zf of 1wt%-and the approximately about 40wt% Trimethylmethane of 1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-1243zf of 1wt%-and the approximately about 98wt% dimethyl ether of 1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-1243zf of 1wt%-and the approximately about 98wt%CF of 1wt%- ₃I;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-134 of 1wt%-and the approximately about 98wt%HFC-152a of 1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-134 of 1wt%-and the approximately about 98wt%HFC-227ea of 1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-134 of 1wt%-and the approximately about 40wt% normal butane of 1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-134 of 1wt%-and the approximately about 40wt% Trimethylmethane of 1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-134 of 1wt%-and the approximately about 40wt% dimethyl ether of 1wt%-;

The approximately about 98wt%HFC-1225ye of 40wt%-, about about 59wt%HFC-227ea of 1wt%-and the approximately about 30wt% dimethyl ether of 1wt%-;

About about 98wt%HFC-1225ye of 1wt%-, about about 30wt% normal butane of 1wt%-and about about 98wt% dimethyl ether of 1wt%-;

About about 98wt%HFC-1225ye of 1wt%-, about about 20wt% normal butane of 1wt%-and about about 98wt%CF of 1wt%- ₃SCF ₃

About about 98wt%HFC-1225ye of 1wt%-, about about 60wt% Trimethylmethane of 1wt%-and about about 98wt% dimethyl ether of 1wt%-;

About about 98wt%HFC-1225ye of 1wt%-, about about 40wt% Trimethylmethane of 1wt%-and about about 98wt%CF of 1wt%- ₃I;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-32 of 1wt%-and the approximately about 98wt%CF of 1wt%- ₃I;

The approximately about 97wt%HFC-1225ye of 1wt%-, about about 97wt%HFC-1234yf of 1wt%-and the approximately about 97wt%HFC-32 of 1wt%-and about about 97wt%HFC-125 of 1wt%-;

The approximately about 97wt%HFC-1225ye of 1wt%-, about about 97wt%HFC-1234yf of 1wt%-and the approximately about 97wt%HFC-32 of 1wt%-and about about 97wt%HFC-134a of 1wt%-;

The approximately about 96wt%HFC-1225ye of 1wt%-, about about 96wt%HFC-1234yf of 1wt%-and the approximately about 96wt%HFC-32 of 1wt%-and the approximately about 96wt%HFC-125 of 1wt%-and the approximately about 97wt%CF of 1wt%- ₃I;

The approximately about 97wt%HFC-1225ye of 1wt%-, about about 97wt%HFC-32 of 1wt%-and the approximately about 97wt%HFC-125 of 1wt%-and about about 97wt%HFC-152a of 1wt%-;

The approximately about 97wt%HFC-1225ye of 1wt%-, about about 97wt%HFC-32 of 1wt%-and the approximately about 97wt%HFC-125 of 1wt%-and about about 50wt% Trimethylmethane of 1wt%-;

The approximately about 97wt%HFC-1225ye of 1wt%-, about about 97wt%HFC-32 of 1wt%-and the approximately about 97wt%HFC-125 of 1wt%-and about about 50wt% propane of 1wt%-;

The approximately about 97wt%HFC-1225ye of 1wt%-, about about 97wt%HFC-32 of 1wt%-and the approximately about 97wt%HFC-125 of 1wt%-and about about 50wt%DME of 1wt%-;

The approximately about 97wt%HFC-1225ye of 1wt%-, about about 97wt%HFC-32 of 1wt%-and the approximately about 97wt%HFC-125 of 1wt%-and about about 97wt%CF of 1wt%- ₃I; With

The approximately about 97wt%HFC-1225ye of 1wt%-, about about 97wt%HFC-32 of 1wt%-and the approximately about 97wt%CF of 1wt%- ₃I and about about 50wt%DME of 1wt%-.

8. the composition of claim 1 is selected from:

The approximately about 99wt%HFC-1225ye of 50wt%-and the approximately about 1wt%HFC-32 of 50wt%-;

The approximately about 99wt%HFC-1225ye of 40wt%-and the approximately about 1wt%HFC-134a of 60wt%-;

The approximately about 99.7wt%HFC-1225ye of 70wt%-and the approximately about 0.3wt%CO of 30wt%- ₂

The approximately about 99wt%HFC-1225ye of 51wt%-and the approximately about 1wt%HFC-1234yf of 49wt%-;

The approximately about 98wt%HFC-1225ye of 50wt%-, about about 40wt%HFC-152a of 1wt%-and the approximately about 40wt%HFC-32 of 1wt%-;

The approximately about 98wt%HFC-1225ye of 50wt%-, about about 40wt%HFC-152a of 1wt%-and the approximately about 30wt%HFC-CO of 0.3wt%- ₂

The approximately about 98wt%HFC-1225ye of 50wt%-, about about 40wt%HFC-152a of 1wt%-and the approximately about 20wt% propane of 1wt%-;

The approximately about 98wt%HFC-1225ye of 50wt%-, about about 40wt%HFC-152a of 1wt%-and the approximately about 20wt% Trimethylmethane of 1wt%-;

The approximately about 98wt%HFC-1225ye of 50wt%-, about about 40wt%HFC-152a of 1wt%-and the approximately about 20wt% dimethyl ether of 1wt%-;

The approximately about 98wt%HFC-1225ye of 40wt%-, about about 50wt%HFC-134a of 1wt%-and the approximately about 40wt%HFC-152a of 1wt%-;

About about 97wt%HFC-1225ye of 20wt%-, about about 80wt%HFC-134a of 1wt%-, about about 50wt%HFC-152a of 1wt%-and about about 50wt%HFC-32 of 0.1wt%-;

The approximately about 98wt%HFC-1225ye of 20wt%-, about about 50wt%HFC-134a of 1wt%-and the approximately about 40wt%HFC-32 of 1wt%-;

The approximately about 98wt%HFC-1225ye of 40wt%-, about about 50wt%HFC-134a of 1wt%-and the approximately about 20wt%HFC-161 of 1wt%-;

The approximately about 98wt%HFC-1225ye of 40wt%-, about about 50wt%HFC-134a of 1wt%-and the approximately about 30wt%CO of 0.3wt%- ₂

The approximately about 98wt%HFC-1225ye of 40wt%-, about about 50wt%HFC-134a of 1wt%-and the approximately about 20wt% propane of 1wt%-;

The approximately about 98wt%HFC-1225ye of 40wt%-, about about 50wt%HFC-134a of 1wt%-and the approximately about 20wt% Trimethylmethane of 1wt%-;

The approximately about 98wt%HFC-1225ye of 40wt%-, about about 50wt%HFC-134a of 1wt%-and the approximately about 20wt% dimethyl ether of 1wt%-;

The approximately about 98wt%HFC-1225ye of 40wt%-, about about 50wt%HFC-134 of 1wt%-and the approximately about 40wt%HFC-32 of 1wt%-;

The approximately about 90wt%HFC-1225ye of 10wt%-, about about 90wt%HFC-1234yf of 10wt%-and the approximately about 50wt%HFC-134a of 0.1wt%-;

The approximately about 90wt%HFC-1225ye of 10wt%-, about about 90wt%HFC-1234yf of 11wt%-and the approximately about 50wt%HFC-32 of 0.1wt%-;

The approximately about 90wt%HFC-1225ye of 10wt%-, about about 90wt%HFC-1234yf of 10wt%-and the approximately about 50wt%HFC-152a of 0.1wt%-;

The approximately about 90wt%HFC-1225ye of 10wt%-, about about 90wt%HFC-1234yf of 10wt%-and the approximately about 50wt%HFC-125 of 0.1wt%-;

The approximately about 90wt%HFC-1225ye of 9wt%-, about about 90wt%HFC-1234yf of 9wt%-and the approximately about 60wt%CF of 1wt%- ₃I;

The approximately about 70wt%HFC-32 of 5wt%-, about about 70wt%HFC-125 of 5wt%-and the approximately about 70wt%HFC-1225ye of 5wt%-;

The approximately about 70wt%HFC-125 of 5wt%-, about about 70wt%HFC-1225ye of 5wt%-and the approximately about 20wt% normal butane of 1wt%-;

The approximately about 70wt%HFC-125 of 5wt%-, about about 70wt%HFC-1225ye of 5wt%-and the approximately about 20wt% Trimethylmethane of 1wt%-;

Approximately the about 80wt%HFC-1225ye of 10wt%-, approximately the about 80wt% of 10wt%-anti--HFC-1234ze and the about about 80wt%HFC-134 of 10wt%-;

Approximately the about 80wt%HFC-1225ye of 10wt%-, approximately the about 80wt% of 10wt%-anti--HFC-1234ze and the about about 80wt%HFC-227ea of 10wt%-;

Approximately the about 60wt%HFC-1225ye of 10wt%-, approximately the about 60wt% of 10wt%-anti--HFC-1234ze and the about about 80wt% propane of 39wt%-;

Approximately the about 80wt%HFC-1225ye of 10wt%-, approximately the about 80wt% of 10wt%-anti--HFC-1234ze and the about about 20wt% normal butane of 1wt%-;

Approximately the about 80wt%HFC-1225ye of 10wt%-, approximately the about 80wt% of 10wt%-anti--HFC-1234ze and the about about 30wt% dimethyl ether of 1wt%-;

Approximately the about 80wt%HFC-1225ye of 10wt%-, approximately the about 80wt% of 10wt%-anti--HFC-1234ze and the about about 80wt%CF of 10wt%- ₃SCF ₃

The approximately about 80wt%HFC-1225ye of 10wt%-, about about 80wt%HFC-1243zf of 10wt%-and the approximately about 80wt%HFC-134 of 10wt%-;

The approximately about 80wt%HFC-1225ye of 10wt%-, about about 80wt%HFC-1243zf of 10wt%-and the approximately about 20wt% normal butane of 1wt%-;

The approximately about 80wt%HFC-1225ye of 10wt%-, about about 80wt%HFC-1243zf of 10wt%-and the approximately about 30wt% Trimethylmethane of 1wt%-;

The approximately about 80wt%HFC-1225ye of 10wt%-, about about 80wt%HFC-1243zf of 10wt%-and the approximately about 30wt% dimethyl ether of 1wt%-;

The approximately about 80wt%HFC-1225ye of 10wt%-, about about 80wt%HFC-1243zf of 10wt%-and the approximately about 80wt%CF of 10wt%- ₃I;

The approximately about 80wt%HFC-1225ye of 10wt%-, about about 80wt%HFC-134 of 10wt%-and the approximately about 50wt%HFC-152a of 1wt%-;

The approximately about 80wt%HFC-1225ye of 10wt%-, about about 80wt%HFC-134 of 10wt%-and the approximately about 80wt%HFC-227ea of 10wt%-;

The approximately about 80wt%HFC-1225ye of 10wt%-, about about 80wt%HFC-134 of 10wt%-and the approximately about 30wt% normal butane of 1wt%-;

The approximately about 80wt%HFC-1225ye of 10wt%-, about about 80wt%HFC-134 of 10wt%-and the approximately about 30wt% Trimethylmethane of 1wt%-;

The approximately about 80wt%HFC-1225ye of 10wt%-, about about 80wt%HFC-134 of 10wt%-and the approximately about 30wt% dimethyl ether of 1wt%-;

The approximately about 80wt%HFC-1225ye of 50wt%-, about about 49wt%HFC-227ea of 1wt%-and the approximately about 20wt% dimethyl ether of 1wt%-;

About about 98wt%HFC-1225ye of 60wt%-, about about 20wt% normal butane of 1wt%-and about about 20wt% dimethyl ether of 1wt%-;

About about 80wt%HFC-1225ye of 10wt%-, about about 10wt% normal butane of 1wt%-and about about 80wt%CF of 10wt%- ₃SCF ₃

About about 90wt%HFC-1225ye of 40wt%-, about about 30wt% Trimethylmethane of 1wt%-and about about 30wt% dimethyl ether of 1wt%-; With

About about 80wt%HFC-1225ye of 10wt%-, about about 30wt% Trimethylmethane of 1wt%-and about about 80wt%CF of 10wt%- ₃I;

The approximately about 80wt%HFC-1225ye of 5wt%-, about about 70wt%HFC-32 of 1wt%-and the approximately about 80wt%CF of 1wt%- ₃I;

The approximately about 80wt%HFC-1225ye of 1wt%-, about about 70wt%HFC-1234yf of 1wt%-and the approximately about 70wt%HFC-32 of 5wt%-and about about 70wt%HFC-125 of 5wt%-;

The approximately about 80wt%HFC-1225ye of 5wt%-, about about 70wt%HFC-1234yf of 5wt%-and the approximately about 70wt%HFC-32 of 5wt%-and about about 70wt%HFC-134a of 5wt%-;

The approximately about 70wt%HFC-1225ye of 1wt%-, about about 60wt%HFC-1234yf of 1wt%-and the approximately about 70wt%HFC-32 of 1wt%-and the approximately about 60wt%HFC-125 of 1wt%-and the approximately about 60wt%CF of 1wt%- ₃I;

The approximately about 80wt%HFC-1225ye of 10wt%-, about about 70wt%HFC-32 of 5wt%-and the approximately about 70wt%HFC-125 of 5wt%-and about about 70wt%HFC-152a of 5wt%-;

The approximately about 70wt%HFC-1225ye of 5wt%-, about about 70wt%HFC-32 of 5wt%-and the approximately about 70wt%HFC-125 of 5wt%-and about about 30wt% Trimethylmethane of 1wt%-;

The approximately about 70wt%HFC-1225ye of 5wt%-, about about 70wt%HFC-32 of 5wt%-and the approximately about 70wt%HFC-125 of 5wt%-and about about 30wt% propane of 1wt%-;

The approximately about 70wt%HFC-1225ye of 5wt%-, about about 70wt%HFC-32 of 5wt%-and the approximately about 70wt%HFC-125 of 5wt%-and about about 30wt%DME of 1wt%-;

The approximately about 80wt%HFC-1225ye of 10wt%-, about about 70wt%HFC-32 of 5wt%-and the approximately about 70wt%HFC-125 of 5wt%-and about about 80wt%CF of 1wt%- ₃I; With

The approximately about 70wt%HFC-1225ye of 5wt%-, about about 70wt%HFC-32 of 5wt%-and the approximately about 70wt%CF of 5wt%- ₃I and about about 30wt%DME of 1wt%-.

9. the composition of claim 1 is selected from;

Approximately 95wt%HFC-1225ye and approximately 5wt%HFC-32;

Approximately 97wt%HFC-1225ye and approximately 3wt%HFC-32;

Approximately 90wt%HFC-1225ye and approximately 10wt%HFC-134a;

Approximately 99wt%HFC-1225ye and approximately 1wt%CO ₂

Approximately 75wt%HFC-1225ye and approximately 25wt%HFC-1234yf;

Approximately 60wt%HFC-1225ye and approximately 40wt%HFC-1234yf;

Approximately 85wt%HFC-1225ye, about 10wt%HFC-152a and approximately 5wt%HFC-32;

Approximately 81wt%HFC-1225ye, about 15wt%HFC-152a and approximately 4wt%HFC-32;

Approximately 82wt%HFC-1225ye, about 15wt%HFC-152a and approximately 3wt%HFC-32;

Approximately 84wt%HFC-1225ye, about 15wt%HFC-152a and approximately 1wt%CO ₂

Approximately 84wt%HFC-1225ye, about 15.5wt%HFC-152a and approximately 0.5wt%CO ₂

Approximately 85wt%HFC-1225ye, about 13wt%HFC-152a and approximately 2wt% propane;

Approximately 85wt%HFC-1225ye, about 13wt%HFC-152a and approximately 2wt% Trimethylmethane;

Approximately 85wt%HFC-1225ye, about 13wt%HFC-152a and approximately 2wt% dimethyl ether;

Approximately 76wt%HFC-1225ye, about 9wt%HFC-134a and approximately 15wt%HFC-152a;

About 74wt%HFC-1225ye, about 8wt%HFC-134a, 17wt%HFC-152a and about 1wt%HFC-32;

Approximately 88wt%HFC-1225ye, about 9wt%HFC-134a and approximately 3wt%HFC-32;

Approximately 86wt%HFC-1225ye, about 10wt%HFC-134a and approximately 4wt%HFC-161;

Approximately 885wt%HFC-1225ye, about 11wt%HFC-134a and approximately 0.5wt%CO ₂

Approximately 87wt%HFC-1225ye, about 10wt%HFC-134a and approximately 3wt% propane;

Approximately 87wt%HFC-1225ye, about 10wt%HFC-134a and approximately 3wt% Trimethylmethane;

Approximately 87wt%HFC-1225ye, about 10wt%HFC-134a and approximately 3wt% dimethyl ether;

Approximately 88wt%HFC-1225ye, about 9wt%HFC-134 and approximately 3wt%HFC-32;

Approximately 70wt%HFC-1225ye, about 20wt%HFC-1234yf and approximately 10wt%HFC-134a;

Approximately 20wt%HFC-1225ye, about 70wt%HFC-1234yf and approximately 10wt%HFC-134a;

Approximately 25wt%HFC-1225ye, about 73wt%HFC-1234yf and approximately 2wt%HFC-32;

Approximately 75wt%HFC-1225ye, about 23wt%HFC-1234yf and approximately 2wt%HFC-32;

Approximately 70wt%HFC-1225ye, about 25wt%HFC-1234yf and approximately 5wt%HFC-152a;

Approximately 25wt%HFC-1225ye, about 70wt%HFC-1234yf and approximately 5wt%HFC-152a;

Approximately 25wt%HFC-1225ye, about 71wt%HFC-1234yf and approximately 4wt%HFC-125;

Approximately 75wt%HFC-1225ye, about 21wt%HFC-1234yf and approximately 4wt%HFC-125;

Approximately 75wt%HFC-1225ye, about 24wt%HFC-1234yf and approximately 1wt%HFC-125;

Approximately 40wt%HFC-1225ye, about 40wt%HFC-1234yf and approximately 20wt%CF ₃I;

Approximately 45wt%HFC-1225ye, about 45wt%HFC-1234yf and approximately 10wt%CF ₃I;

Approximately 25wt%HFC-1225ye, about 74wt%HFC-1234yf and approximately 1wt%HFC-125;

Approximately 30wt%HFC-32, about 40wt%HFC-125 and approximately 30wt%HFC-1225ye;

Approximately 23wt%HFC-32, about 25wt%HFC-125 and approximately 52wt%HFC-1225ye;

Approximately 65wt%HFC-125, about 32wt%HFC-1225ye and approximately 3wt% normal butane; With

Approximately 85.1wt%HFC-125, about 11.5wt%HFC-1225ye and approximately 3.4wt% Trimethylmethane.

10. the composition of claim 2 is selected from:

Suitable-HFC-1234ze and HFC-1234ye;

Suitable-HFC-1234ze and HFC-236ea;

Suitable-HFC-1234ze and HFC-236fa;

Suitable-HFC-1234ze and HFC-245fa;

Suitable-HFC-1234ze and normal butane;

Suitable-HFC-1234ze and Trimethylmethane;

Suitable-HFC-1234ze and 2-methylbutane;

Suitable-HFC-1234ze and Skellysolve A;

Instead-HFC-1234ze and HFC-134a;

Instead-HFC-1234ze and HFC-152a;

Instead-HFC-1234ze and HFC-32;

Instead-HFC-1234ze, HFC-125 and normal butane;

Instead-HFC-1234ze, HFC-32 and HFC-125;

Instead-HFC-1234ze, HFC-125 and Trimethylmethane;

Instead-HFC-1234ze, HFC-1243zf and HFC-227ea;

Instead-HFC-1234ze, HFC-1243zf and normal butane;

Instead-HFC-1234ze, HFC-1243zf and Trimethylmethane;

Instead-HFC-1234ze, HFC-1243zf and dimethyl ether;

Instead-HFC-1234ze, HFC-134 and HFC-152a;

Instead-HFC-1234ze, HFC-134 and HFC-227ea;

Instead-HFC-1234ze, HFC-134 and dimethyl ether;

Instead-HFC-1234ze, HFC-134a and HFC-152a;

Instead-HFC-1234ze, HFC-152a and normal butane;

Instead-HFC-1234ze, HFC-152a and dimethyl ether;

Instead-HFC-1234ze, HFC-227ea and normal butane;

Instead-HFC-1234ze, normal butane and dimethyl ether;

Instead-HFC-1234ze, normal butane and CF ₃I;

Instead-HFC-1234ze, Trimethylmethane and dimethyl ether;

Instead-HFC-1234ze, Trimethylmethane and CF ₃I; With

Instead-HFC-1234ze, Trimethylmethane and CF ₃SCF ₃

11. the composition of claim 2 is selected from:

Approximately the about 99wt% of 1wt%-suitable-HFC-1234ze and the about about 1wt%HFC-1234ye of 99wt%-;

Approximately the about 99wt% of 1wt%-suitable-HFC-1234ze and the about about 1wt%HFC-236ea of 99wt%-;

Approximately the about 99wt% of 1wt%-suitable-HFC-1234ze and the about about 1wt%HFC-236fa of 99wt%-;

Approximately the about 99wt% of 1wt%-suitable-HFC-1234ze and the about about 1wt%HFC-245fa of 99wt%-;

Approximately the about 80wt% of 1wt%-suitable-HFC-1234ze and the about about 20wt% normal butane of 99wt%-;

Approximately the about 69wt% of 1wt%-suitable-HFC-1234ze and the about about 31wt% Trimethylmethane of 99wt%-;

Approximately the about 99wt% of 60wt%-suitable-HFC-1234ze and the about about 1wt%2-methylbutane of 40wt%-;

Approximately the about 99wt% of 63wt%-suitable-HFC-1234ze and the about about 1wt% Skellysolve A of 37wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-134a of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-32 of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-152a of 99wt%-;

Approximately the about 98wt%HFC-32 of 0.1wt%-, approximately the about 98wt%HFC-125 of 0.1wt%-and approximately the about 98wt% of 0.1wt%-anti--HFC-1234ze;

Approximately the about 98wt%HFC-125 of 0.1wt%-, approximately the about 98wt% of 0.1wt%-anti--HFC-1234ze and the about about 98wt% normal butane of 0.1wt%-;

Approximately the about 98wt%HFC-125 of 0.1wt%-, approximately the about 98wt% of 0.1wt%-anti--HFC-1234ze and the about about 98wt% Trimethylmethane of 0.1wt%-;

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 98wt%HFC-1243zf of 1wt%-and the about about 98wt%HFC-227ea of 1wt%-;

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 98wt%HFC-1243zf of 1wt%-and the about about 30wt% normal butane of 1wt%-;

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 98wt%HFC-1243zf of 1wt%-and the about about 40wt% Trimethylmethane of 1wt%-;

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 98wt%HFC-1243zf of 1wt%-and the about about 98wt% dimethyl ether of 1wt%-;

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 98wt%HFC-134 of 1wt%-and the about about 98wt%HFC-152a of 1wt%-;

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 98wt%HFC-134 of 1wt%-and the about about 98wt%HFC-227ea of 1wt%-;

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 98wt%HFC-134 of 1wt%-and the about about 40wt% dimethyl ether of 1wt%-;

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 98wt%HFC-134a of 1wt%-and the about about 98wt%HFC-152a of 1wt%-;

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 98wt%HFC-152a of 1wt%-and the about about 50wt% normal butane of 1wt%-;

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 98wt%HFC-152a of 1wt%-and the about about 98wt% dimethyl ether of 1wt%-;

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 98wt%HFC-227ea of 1wt%-and the about about 40wt% normal butane of 1wt%-;

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 40wt% normal butane of 1wt%-and the about about 98wt% dimethyl ether of 1wt%-;

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 30wt% normal butane of 1wt%-and the about about 98wt%CF of 1wt%- ₃I;

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 60wt% Trimethylmethane of 1wt%-and the about about 98wt% dimethyl ether of 1wt%-;

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 40wt% Trimethylmethane of 1wt%-and the about about 98wt%CF of 1wt%- ₃I; With

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 40wt% Trimethylmethane of 1wt%-and the about about 98wt%CF of 1wt%- ₃SCF ₃

12. the composition of claim 2 is selected from:

Approximately the about 99wt% of 30wt%-anti--HFC-1234ze and the about about 1wt%HFC-134a of 70wt%-;

Approximately the about 99wt% of 40wt%-anti--HFC-1234ze and the about about 1wt%HFC-32 of 60wt%-;

Approximately the about 99wt% of 40wt%-anti--HFC-1234ze and the about about 1wt%HFC-152a of 60wt%-;

Approximately the about 70wt%HFC-32 of 5wt%-, approximately the about 70wt%HFC-125 of 5wt%-and approximately the about 70wt% of 5wt%-anti--HFC-1234ze;

Approximately the about 70wt%HFC-125 of 5wt%-, approximately the about 70wt% of 5wt%-anti--HFC-1234ze and the about about 20wt% normal butane of 1wt%-; With

Approximately the about 70wt%HFC-125 of 5wt%-, approximately the about 70wt% of 5wt%-anti--HFC-1234ze and the about about 20wt% Trimethylmethane of 1wt%-;

Approximately the about 80wt% of 10wt%-anti--HFC-1234ze, approximately about 80wt%HFC-1243zf of 10wt%-and the about about 80wt%HFC-227ea of 10wt%-;

Approximately the about 80wt% of 10wt%-anti--HFC-1234ze, approximately about 80wt%HFC-1243zf of 10wt%-and the about about 20wt% normal butane of 1wt%-;

Approximately the about 80wt% of 10wt%-anti--HFC-1234ze, approximately about 80wt%HFC-1243zf of 10wt%-and the about about 30wt% Trimethylmethane of 1wt%-;

Approximately the about 80wt% of 10wt%-anti--HFC-1234ze, approximately about 80wt%HFC-1243zf of 10wt%-and the about about 40wt% dimethyl ether of 1wt%-;

Approximately the about 80wt% of 10wt%-anti--HFC-1234ze, approximately about 80wt%HFC-134 of 10wt%-and the about about 50wt%HFC-152a of 1wt%-;

Approximately the about 80wt% of 10wt%-anti--HFC-1234ze, approximately about 80wt%HFC-134 of 10wt%-and the about about 80wt%HFC-227ea of 10wt%-;

Approximately the about 80wt% of 10wt%-anti--HFC-1234ze, approximately about 80wt%HFC-134 of 10wt%-and the about about 30wt% dimethyl ether of 1wt%-;

Approximately the about 80wt% of 10wt%-anti--HFC-1234ze, approximately about 80wt%HFC-134a of 10wt%-and the about about 50wt%HFC-152a of 1wt%-;

Approximately the about 80wt% of 10wt%-anti--HFC-1234ze, approximately about 80wt%HFC-152a of 10wt%-and the about about 30wt% normal butane of 1wt%-;

Approximately the about 90wt% of 20wt%-anti--HFC-1234ze, approximately about 50wt%HFC-152a of 1wt%-and the about about 30wt% dimethyl ether of 1wt%-;

Approximately the about 80wt% of 10wt%-anti--HFC-1234ze, approximately about 80wt%HFC-227ea of 10wt%-and the about about 30wt% normal butane of 1wt%-;

Approximately the about 90wt% of 10wt%-anti--HFC-1234ze, approximately about 30wt% normal butane of 1wt%-and the about about 30wt% dimethyl ether of 1wt%-;

Approximately the about 80wt% of 10wt%-anti--HFC-1234ze, approximately about 20wt% normal butane of 1wt%-and the about about 80wt%CF of 10wt%- ₃I;

Approximately the about 90wt% of 10wt%-anti--HFC-1234ze, approximately about 30wt% Trimethylmethane of 1wt%-and the about about 30wt% dimethyl ether of 1wt%-;

Approximately the about 80wt% of 10wt%-anti--HFC-1234ze, approximately about 20wt% Trimethylmethane of 1wt%-and the about about 80wt%CF of 10wt%- ₃I; With

Approximately the about 80wt% of 10wt%-anti--HFC-1234ze, approximately about 20wt% Trimethylmethane of 1wt%-and the about about 80wt%CF of 10wt%- ₃SCF ₃

13. the composition of claim 2 is selected from:

Approximately 90wt% anti--HFC-1234ze and about 10wt%HFC-134a;

Approximately 95wt% anti--HFC-1234ze and about 5wt%HFC-32;

Approximately 80wt% anti--HFC-1234ze and about 20wt%HFC-152a;

Approximately 30wt%HFC-32, approximately 50wt%HFC-125 and approximately 20wt% anti--HFC-1234ze;

Approximately 23wt%HFC-32, approximately 25wt%HFC-125 and approximately 52wt% anti--HFC-1234ze;

Approximately 66wt%HFC-125, approximately 32wt% anti--HFC-1234ze and about 2wt% normal butane; With

Approximately 86.1wt%HFC-125, approximately 11.5wt% anti--HFC-1234ze and about 2.4wt% Trimethylmethane.

14. the composition of claim 3 is selected from:

HFC-1234yf and HFC-134a;

HFC-1234yf and HFC-152a;

HFC-1234yf and HFC-32;

HFC-1234yf, HFC-125 and normal butane;

HFC-1234yf, HFC-32 and HFC-125;

HFC-1234yf, HFC-125 and Trimethylmethane;

HFC-1234yf, HFC-32 and HFC-143a;

HFC-1234yf, HFC-32 and Trimethylmethane;

HFC-1234yf, HFC-125 and HFC-143a;

HFC-1234yf, HFC-125 and Trimethylmethane;

HFC-1234yf, HFC-134 and propane;

HFC-1234yf, HFC-134 and dimethyl ether;

HFC-1234yf, HFC-134a and propane;

HFC-1234yf, HFC-134a and normal butane;

HFC-1234yf, HFC-134a and Trimethylmethane;

HFC-1234wf, HFC-134a and dimethyl ether;

HFC-1234yf, HFC-143a and propane;

HFC-1234yf, HFC-143a and dimethyl ether;

HFC-1234yf, HFC-152a and normal butane;

HFC-1234yf, HFC-152a and Trimethylmethane;

HFC-1234yf, HFC-152a and dimethyl ether;

HFC-1234yf, HFC-227ea and propane;

HFC-1234yf, HFC-227ea and normal butane;

HFC-1234yf, HFC-227ea and Trimethylmethane;

HFC-1234yf, HFC-227ea and dimethyl ether;

HFC-1234yf, normal butane and dimethyl ether;

HFC-1234yf, Trimethylmethane and dimethyl ether;

HFC-1234yf, dimethyl ether and CF ₃I;

HFC-1234yf, dimethyl ether and CF ₃SCF ₃

HFC-1234yf, HFC-32 and CF ₃I;

HFC-1234yf, HFC-32 and HFC-125;

HFC-1234yf, HFC-32, HFC-125 and CF ₃I; With

HFC-1234yf, HFC-32, HFC-134a and CF ₃I.

15. the composition of claim 3 is selected from:

The approximately about 99wt%HFC-1234yf of 1wt%-and the approximately about 1wt%HFC-134a of 99wt%-;

The approximately about 99wt%HFC-1234yf of 1wt%-and the approximately about 1wt%HFC-32 of 99wt%-;

The approximately about 99wt%HFC-1234yf of 1wt%-and the approximately about 1wt%HFC-152a of 99wt%-;

The approximately about 98wt%HFC-32 of 0.1wt%-, about about 98wt%HFC-125 of 0.1wt%-and the approximately about 98wt%HFC-1234yf of 0.1wt%-;

The approximately about 98wt%HFC-125 of 0.1wt%-, about about 98wt%HFC-1234yf of 0.1wt%-and the approximately about 98wt% normal butane of 0.1wt%-; With

The approximately about 98wt%HFC-125 of 0.1wt%-, about about 98wt%HFC-1234yf of 0.1wt%-and the approximately about 98wt% Trimethylmethane of 0.1wt%-;

The approximately about 50wt%HFC-1234yf of 1wt%-, about about 98wt%HFC-32 of 1wt%-and the approximately about 98wt%HFC-143a of 1wt%-;

The approximately about 40wt%HFC-1234yf of 1wt%-, about about 98wt%HFC-32 of 59wt%-and the approximately about 30wt% Trimethylmethane of 1wt%-;

The approximately about 60wt%HFC-1234yf of 1wt%-, about about 98wt%HFC-125 of 1wt%-and the approximately about 98wt%HFC-143a of 1wt%-;

The approximately about 40wt%HFC-1234yf of 1wt%-, about about 98wt%HFC-125 of 59wt%-and the approximately about 20wt% Trimethylmethane of 1wt%-;

The approximately about 80wt%HFC-1234yf of 1wt%-, about about 70wt%HFC-134 of 1wt%-and the approximately about 90wt% propane of 19wt%-;

The approximately about 70wt%HFC-1234yf of 1wt%-, about about 98wt%HFC-134 of 1wt%-and the approximately about 98wt% dimethyl ether of 29wt%-;

The approximately about 80wt%HFC-1234yf of 1wt%-, about about 80wt%HFC-134a of 1wt%-and the approximately about 98wt% propane of 19wt%-;

The approximately about 98wt%HFC-1234yf of 1wt%-, about about 98wt%HFC-134a of 1wt%-and the approximately about 30wt% normal butane of 1wt%-;

The approximately about 98wt%HFC-1234yf of 1wt%-, about about 98wt%HFC-134a of 1wt%-and the approximately about 30wt% Trimethylmethane of 1wt%-;

The approximately about 98wt%HFC-1234yf of 1wt%-, about about 98wt%HFC-134a of 1wt%-and the approximately about 40wt% dimethyl ether of 1wt%-;

The approximately about 80wt%HFC-1234yf of 1wt%-, about about 98wt%HFC-143a of 1wt%-and the approximately about 98wt% propane of 1wt%-;

The approximately about 40wt%HFC-1234yf of 1wt%-, about about 98wt%HFC-143a of 59wt%-and the approximately about 20wt% dimethyl ether of 1wt%-;

The approximately about 98wt%HFC-1234yf of 1wt%-, about about 98wt%HFC-152a of 1wt%-and the approximately about 30wt% normal butane of 1wt%-;

The approximately about 98wt%HFC-1234yf of 1wt%-, about about 90wt%HFC-152a of 1wt%-and the approximately about 40wt% Trimethylmethane of 1wt%-;

The approximately about 70wt%HFC-1234yf of 1wt%-, about about 98wt%HFC-152a of 1wt%-and the approximately about 98wt% dimethyl ether of 1wt%-;

The approximately about 80wt%HFC-1234yf of 1wt%-, about about 70wt%HFC-227ea of 1wt%-and the approximately about 98wt% propane of 29wt%-;

The approximately about 98wt%HFC-1234yf of 40wt%-, about about 59wt%HFC-227ea of 1wt%-and the approximately about 20wt% normal butane of 1wt%-;

The approximately about 98wt%HFC-1234yf of 30wt%-, about about 69wt%HFC-227ea of 1wt%-and the approximately about 30wt% Trimethylmethane of 1wt%-;

The approximately about 98wt%HFC-1234yf of 1wt%-, about about 80wt%HFC-227ea of 1wt%-and the approximately about 98wt% dimethyl ether of 1wt%-;

About about 98wt%HFC-1234yf of 1wt%-, about about 40wt% normal butane of 1wt%-and about about 98wt% dimethyl ether of 1wt%-;

About about 98wt%HFC-1234yf of 1wt%-, about about 50wt% Trimethylmethane of 1wt%-and about about 98wt% dimethyl ether of 1wt%-;

About about 98wt%HFC-1234yf of 1wt%-, about about 98wt% dimethyl ether of 1wt%-and about about 98wt%CF of 1wt%- ₃I;

About about 98wt%HFC-1234yf of 1wt%-, about about 40wt% dimethyl ether of 1wt%-and about about 98wt%CF of 1wt%- ₃SCF ₃

The approximately about 98wt%HFC-1234yf of 1wt%-, about about 98wt%HFC-32 of 1wt%-and the approximately about 98wt%HFC-125 of 1wt%-;

The approximately about 97wt%HFC-1234yf of 1wt%-, about about 97wt%HFC-32 of 1wt%-and the approximately about 97wt%HFC-125 of 1wt%-and about about 97wt%CF of 1wt%- ₃I;

The approximately about 97wt%HFC-1234yf of 1wt%-, about about 97wt%HFC-32 of 1wt%-and the approximately about 97wt%HFC-134a of 1wt%-and about about 97wt%CF of 1wt%- ₃I; With

The approximately about 98wt%HFC-1234yf of 1wt%-, about about 98wt%HFC-32 of 1wt%-and the approximately about 98wt%CF of 1wt%- ₃I.

16. the composition of claim 3 is selected from:

The approximately about 99wt%HFC-1234yf of 30wt%-and the approximately about 1wt%HFC-134a of 70wt%-;

The approximately about 99wt%HFC-1234yf of 40wt%-and the approximately about 1wt%HFC-32 of 60wt%-;

The approximately about 99wt%HFC-1234yf of 40wt%-and the approximately about 1wt%HFC-152a of 60wt%-;

The approximately about 70wt%HFC-32 of 5wt%-, about about 70wt%HFC-125 of 5wt%-and the approximately about 70wt%HFC-1234yf of 5wt%-;

The approximately about 70wt%HFC-125 of 5wt%-, about about 70wt%HFC-1234yf of 5wt%-and the approximately about 20wt% normal butane of 1wt%-;

The approximately about 70wt%HFC-125 of 5wt%-, about about 70wt%HFC-1234yf of 5wt%-and the approximately about 20wt% Trimethylmethane of 1wt%-;

The approximately about 50wt%HFC-1234yf of 15wt%-, about about 80wt%HFC-32 of 20wt%-and the approximately about 60wt%HFC-143a of 5wt%-;

The approximately about 40wt%HFC-1234yf of 10wt%-, about about 90wt%HFC-32 of 59wt%-and the approximately about 10wt% Trimethylmethane of 1wt%-;

The approximately about 60wt%HFC-1234yf of 10wt%-, about about 70wt%HFC-125 of 20wt%-and the approximately about 70wt%HFC-143a of 20wt%-;

The approximately about 40wt%HFC-1234yf of 10wt%-, about about 90wt%HFC-125 of 59wt%-and the approximately about 10wt% Trimethylmethane of 1wt%-;

The approximately about 80wt%HFC-1234yf of 20wt%-, about about 70wt%HFC-134 of 10wt%-and the approximately about 50wt% propane of 19wt%-;

The approximately about 70wt%HFC-1234yf of 20wt%-, about about 70wt%HFC-134 of 10wt%-and the approximately about 50wt% dimethyl ether of 29wt%-;

The approximately about 80wt%HFC-1234yf of 10wt%-, about about 80wt%HFC-134a of 10wt%-and the approximately about 50wt% propane of 19wt%-;

The approximately about 80wt%HFC-1234yf of 10wt%-, about about 80wt%HFC-134a of 10wt%-and the approximately about 20wt% normal butane of 1wt%-;

The approximately about 80wt%HFC-1234yf of 10wt%-, about about 80wt%HFC-134a of 10wt%-and the approximately about 20wt% Trimethylmethane of 1wt%-;

The approximately about 80wt%HFC-1234yf of 10wt%-, about about 80wt%HFC-134a of 10wt%-and the approximately about 20wt% dimethyl ether of 1wt%-;

The approximately about 80wt%HFC-1234yf of 10wt%-, about about 80wt%HFC-143a of 10wt%-and the approximately about 50wt% propane of 1wt%-;

The approximately about 40wt%HFC-1234yf of 5wt%-, about about 90wt%HFC-143a of 59wt%-and the approximately about 10wt% dimethyl ether of 1wt%-;

The approximately about 80wt%HFC-1234yf of 10wt%-, about about 80wt%HFC-152a of 10wt%-and the approximately about 20wt% normal butane of 1wt%-;

The approximately about 80wt%HFC-1234yf of 10wt%-, about about 80wt%HFC-152a of 10wt%-and the approximately about 20wt% Trimethylmethane of 1wt%-;

The approximately about 70wt%HFC-1234yf of 10wt%-, about about 80wt%HFC-152a of 10wt%-and the approximately about 20wt% dimethyl ether of 1wt%-;

The approximately about 60wt%HFC-1234yf of 10wt%-, about about 60wt%HFC-227ea of 10wt%-and the approximately about 50wt% propane of 29wt%-;

The approximately about 98wt%HFC-1234yf of 50wt%-, about about 49wt%HFC-227ea of 10wt%-and the approximately about 10wt% normal butane of 1wt%-;

The approximately about 98wt%HFC-1234yf of 50wt%-, about about 49wt%HFC-227ea of 10wt%-and the approximately about 10wt% Trimethylmethane of 1wt%-;

The approximately about 80wt%HFC-1234yf of 10wt%-, about about 80wt%HFC-227ea of 10wt%-and the approximately about 20wt% dimethyl ether of 1wt%-;

About about 80wt%HFC-1234yf of 10wt%-, about about 40wt% normal butane of 10wt%-and about about 20wt% dimethyl ether of 1wt%-;

About about 90wt%HFC-1234yf of 10wt%-, about about 40wt% Trimethylmethane of 1wt%-and about about 20wt% dimethyl ether of 1wt%-;

About about 80wt%HFC-1234yf of 10wt%-, about about 20wt% dimethyl ether of 1wt%-and about about 80wt%CF3I of 10wt%-;

About about 80wt%HFC-1234yf of 10wt%-, about about 20wt% dimethyl ether of 1wt%-and about about 70wt%CF of 10wt%- ₃SCF ₃

The approximately about 80wt%HFC-1234yf of 10wt%-, about about 80wt%HFC-32 of 10wt%-and the approximately about 80wt%HFC-125 of 10wt%-;

The approximately about 80wt%HFC-1234yf of 10wt%-, about about 70wt%HFC-32 of 5wt%-and the approximately about 80wt%HFC-125 of 10wt%-and about about 80wt%CF of 5wt%- ₃I;

The approximately about 70wt%HFC-1234yf of 1wt%-, about about 70wt%HFC-32 of 5wt%-and the approximately about 80wt%HFC-134a of 5wt%-and about about 70wt%CF of 5wt%- ₃I; With

The approximately about 80wt%HFC-1234yf of 10wt%-, about about 70wt%HFC-32 of 1wt%-and the approximately about 80wt%CF of 1wt%- ₃I.

17. the composition of claim 3 is selected from:

Approximately 90wt%HFC-1234yf and approximately 10wt%HFC-134a;

Approximately 95wt%HFC-1234yf and approximately 5wt%HFC-32;

Approximately 80wt%HFC-1234yf and approximately 20wt%HFC-152a;

Approximately 40wt%HFC-32, about 50wt%HFC-125 and approximately 10wt%HFC-1234yf;

Approximately 23wt%HFC-32, about 25wt%HFC-125 and approximately 52wt%HFC-1234yf;

Approximately 15wt%HFC-32, about 45wt%HFC-125 and approximately 40wt%HFC-1234yf;

Approximately 10wt%HFC-32, about 60wt%HFC-125 and approximately 30wt%HFC-1234yf;

Approximately 67wt%HFC-125, about 32wt%HFC-1234yf and approximately 1wt% normal butane; With

Approximately 87.1wt%HFC-125, about 11.5wt%HFC-1234yf and approximately 1.4wt% Trimethylmethane.

18. the composition of claim 5 is selected from:

HFC-1243zf, HFC-134 and HFC-227ea;

HFC-1243zf, HFC-134 and normal butane;

HFC-1243zf, HFC-134 and dimethyl ether;

HFC-1243zf, HFC-134 and CF ₃I;

HFC-1243zf, HFC-134a and HFC-152a;

HFC-1243zf, HFC-134a and normal butane;

HFC-1243zf, HFC-152a and propane;

HFC-1243zf, HFC-152a and normal butane;

HFC-1243zf, HFC-152a and Trimethylmethane;

HFC-1243zf, HFC-152a and dimethyl ether;

HFC-1243zf, HFC-227ea and normal butane;

HFC-1243zf, HFC-227ea and Trimethylmethane;

HFC-1243zf, HFC-227ea and dimethyl ether;

HFC-1243zf, normal butane and dimethyl ether;

HFC-1243zf, Trimethylmethane and dimethyl ether;

HFC-1243zf, Trimethylmethane and CF ₃I; With

HFC-1243zf, dimethyl ether and CF ₃SCF ₃

19. the composition of claim 5 is selected from:

The approximately about 98wt%HFC-1243zf of 1wt%-, about about 98wt%HFC-134 of 1wt%-and the approximately about 98wt%HFC-227ea of 1wt%-;

The approximately about 98wt%HFC-1243zf of 1wt%-, about about 98wt%HFC-134 of 1wt%-and the approximately about 40wt% normal butane of 1wt%-;

The approximately about 98wt%HFC-1243zf of 1wt%-, about about 98wt%HFC-134 of 1wt%-and the approximately about 98wt% dimethyl ether of 1wt%-;

The approximately about 98wt%HFC-1243zf of 1wt%-, about about 98wt%HFC-134 of 1wt%-and the approximately about 98wt%CF of 1wt%- ₃I;

The approximately about 98wt%HFC-1243zf of 1wt%-, about about 98wt%HFC-134a of 1wt%-and the approximately about 98wt%HFC-152a of 1wt%-;

The approximately about 98wt%HFC-1243zf of 1wt%-, about about 98wt%HFC-134a of 1wt%-and the approximately about 40wt% normal butane of 1wt%-;

The approximately about 70wt%HFC-1243zf of 1wt%-, about about 70wt%HFC-152a of 1wt%-and the approximately about 98wt% propane of 29wt%-;

The approximately about 98wt%HFC-1243zf of 1wt%-, about about 98wt%HFC-152a of 1wt%-and the approximately about 30wt% normal butane of 1wt%-;

The approximately about 98wt%HFC-1243zf of 1wt%-, about about 98wt%HFC-152a of 1wt%-and the approximately about 40wt% Trimethylmethane of 1wt%-;

The approximately about 98wt%HFC-1243zf of 1wt%-, about about 98wt%HFC-152a of 1wt%-and the approximately about 98wt% dimethyl ether of 1wt%-;

The approximately about 98wt%HFC-1243zf of 1wt%-, about about 98wt%HFC-227ea of 1wt%-and the approximately about 40wt% normal butane of 1wt%-;

The approximately about 98wt%HFC-1243zf of 1wt%-, about about 90wt%HFC-227ea of 1wt%-and the approximately about 50wt% Trimethylmethane of 1wt%-;

The approximately about 98wt%HFC-1243zf of 1wt%-, about about 80wt%HFC-227ea of 1wt%-and the approximately about 90wt% dimethyl ether of 1wt%-;

About about 98wt%HFC-1243zf of 1wt%-, about about 40wt% normal butane of 1wt%-and about about 98wt% dimethyl ether of 1wt%-;

About about 98wt%HFC-1243zf of 1wt%-, about about 60wt% Trimethylmethane of 1wt%-and about about 98wt% dimethyl ether of 1wt%-;

About about 98wt%HFC-1243zf of 1wt%-, about about 40wt% Trimethylmethane of 1wt%-and about about 98wt%CF of 1wt%- ₃I; With

About about 98wt%HFC-1243zf of 1wt%-, about about 40wt% dimethyl ether of 1wt%-and about about 90wt%CF of 1wt%- ₃SCF ₃

20. the composition of claim 5 is selected from:

The approximately about 80wt%HFC-1243zf of 10wt%-, about about 80wt%HFC-134 of 10wt%-and the approximately about 80wt%HFC-227ea of 10wt%-;

The approximately about 80wt%HFC-1243zf of 10wt%-, about about 80wt%HFC-134 of 10wt%-and the approximately about 30wt% normal butane of 1wt%-;

The approximately about 80wt%HFC-1243zf of 10wt%-, about about 80wt%HFC-134 of 10wt%-and the approximately about 30wt% dimethyl ether of 1wt%-;

The approximately about 80wt%HFC-1243zf of 10wt%-, about about 80wt%HFC-134 of 10wt%-and the approximately about 80wt%CF of 10wt%- ₃I;

The approximately about 80wt%HFC-1243zf of 10wt%-, about about 80wt%HFC-134a of 10wt%-and the approximately about 50wt%HFC-152a of 1wt%-;

The approximately about 80wt%HFC-1243zf of 10wt%-, about about 80wt%HFC-134a of 10wt%-and the approximately about 30wt% normal butane of 1wt%-;

The approximately about 70wt%HFC-1243zf of 10wt%-, about about 50wt%HFC-152a of 1wt%-and the approximately about 40wt% propane of 29wt%-;

The approximately about 80wt%HFC-1243zf of 10wt%-, about about 80wt%HFC-152a of 1wt%-and the approximately about 20wt% normal butane of 1wt%-;

The approximately about 80wt%HFC-1243zf of 10wt%-, about about 80wt%HFC-152a of 1wt%-and the approximately about 30wt% Trimethylmethane of 1wt%-;

The approximately about 80wt%HFC-1243zf of 10wt%-, about about 80wt%HFC-152a of 1wt%-and the approximately about 30wt% dimethyl ether of 1wt%-;

The approximately about 80wt%HFC-1243zf of 10wt%-, about about 80wt%HFC-227ea of 1wt%-and the approximately about 30wt% normal butane of 1wt%-;

The approximately about 80wt%HFC-1243zf of 10wt%-, about about 80wt%HFC-227ea of 1wt%-and the approximately about 30wt% Trimethylmethane of 1wt%-;

The approximately about 80wt%HFC-1243zf of 10wt%-, about about 80wt%HFC-227ea of 1wt%-and the approximately about 30wt% dimethyl ether of 1wt%-;

About about 90wt%HFC-1243zf of 10wt%-, about about 30wt% normal butane of 109wt%-and about about 30wt% dimethyl ether of 1wt%-;

About about 90wt%HFC-1243zf of 10wt%-, about about 30wt% Trimethylmethane of 1wt%-and about about 30wt% dimethyl ether of 1wt%-;

About about 80wt%HFC-1243zf of 10wt%-, about about 30wt% Trimethylmethane of 1wt%-and about about 80wt%CF of 10wt%- ₃I; With

About about 80wt%HFC-1243zf of 10wt%-, about about 30wt% dimethyl ether of 1wt%-and about about 80wt%CF of 10wt%- ₃SCF ₃

21. the composition of claim 1 comprises being selected from following azeotropic or near Azeotrope compositions:

The approximately about 34wt%HFC-1225ye of 1wt%-and the approximately about 66wt%HFC-1234yf of 99wt%-;

Approximately the about 99wt%HFC-1225ye of 1wt%-and approximately the about 1wt% of 99wt%-anti--HFC-1234ze;

The approximately about 99wt%HFC-1225ye of 1wt%-and the approximately about 1wt%HFC-1243zf of 99wt%-;

The approximately about 99wt%HFC-1225ye of 1wt%-and the approximately about 1wt%HFC-134 of 99wt%-;

The approximately about 99wt%HFC-1225ye of 1wt%-and the approximately about 1wt%HFC-134a of 99wt%-;

The approximately about 84wt%HFC-1225ye of 1wt%-and the approximately about 16wt%HFC-161 of 99wt%-and the approximately about 99wt%HFC-1225ye of 90wt%-and the approximately about 1wt%HFC-161 of 10wt%-;

The approximately about 99wt%HFC-1225ye of 1wt%-and the approximately about 1wt%HFC-227ea of 99wt%-;

The approximately about 99wt%HFC-1225ye of 57wt%-and the approximately about 1wt%HFC-236ea of 43wt%-;

The approximately about 99wt%HFC-1225ye of 48wt%-and the approximately about 1wt%HFC-236fa of 52wt%-;

The approximately about 99wt%HFC-1225ye of 70wt%-and the approximately about 1wt%HFC-245fa of 30wt%-;

The approximately about 72wt%HFC-1225ye of 1wt%-and the approximately about 28wt% propane of 99wt%-;

The approximately about 99wt%HFC-1225ye of 65wt%-and the approximately about 1wt% normal butane of 35wt%-;

The approximately about 99wt%HFC-1225ye of 50wt%-and the approximately about 1wt% Trimethylmethane of 50wt%-;

The approximately about 99wt%HFC-1225ye of 1wt%-and the approximately about 1wt% dimethyl ether of 99wt%-;

The approximately about 99wt%HFC-1225ye of 1wt%-and approximately two (trifluoromethyl) thioethers of the about 1wt% of 99wt%-;

The approximately about 99wt%HFC-1225ye of 1wt%-and the approximately about 1wt%CF of 99wt%- ₃I;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-134a of 1wt%-and the approximately about 98wt%HFC-152a of 1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-134a of 1wt%-and the approximately about 98wt%HFC-161 of 1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-134a of 1wt%-and the approximately about 40wt% Trimethylmethane of 1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-134a of 1wt%-and the approximately about 20wt% dimethyl ether of 1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-152a of 1wt%-and the approximately about 50wt% Trimethylmethane of 1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-152a of 1wt%-and the approximately about 98wt% dimethyl ether of 1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-1234yf of 1wt%-and the approximately about 98wt%HFC-134a of 1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-1234yf of 1wt%-and the approximately about 98wt%HFC-152a of 1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-1234yf of 1wt%-and the approximately about 20wt%HFC-125 of 1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-1234yf of 1wt%-and the approximately about 98wt%CF of 1- ₃I;

About about 97wt%HFC-1225ye of 1wt%-, about about 97wt%HFC-134a of 1wt%-, about about 97wt%HFC-152a of 1wt%-and about about 10wt%HFC-32 of 1wt%-;

The approximately about 98wt%HFC-125 of 80wt%-, about about 19wt%HFC-1225ye of 1wt%-and the approximately about 10wt% Trimethylmethane of 1wt%-;

The approximately about 98wt%HFC-32 of 1wt%-, about about 98wt%HFC-125 of 1wt%-and the approximately about 4wt%HFC-1225ye of 1wt%-;

Approximately the about 98wt%HFC-1225ye of 1wt%-, approximately the about 98wt% of 1wt%-anti--HFC-1234ze and the about about 98wt%HFC-134 of 1wt%-;

Approximately the about 98wt%HFC-1225ye of 1wt%-, approximately the about 98wt% of 1wt%-anti--HFC-1234ze and the about about 98wt%HFC-227ea of 1wt%-;

Approximately the about 60wt%HFC-1225ye of 1wt%-, approximately the about 60wt% of 1wt%-anti--HFC-1234ze and the about about 98wt% propane of 3wt%-;

Approximately the about 98wt%HFC-1225ye of 1wt%-, approximately the about 98wt% of 1wt%-anti--HFC-1234ze and the about about 30wt% normal butane of 1wt%-;

Approximately the about 98wt%HFC-1225ye of 1wt%-, approximately the about 98wt% of 1wt%-anti--HFC-1234ze and the about about 98wt% dimethyl ether of 1wt%-;

Approximately the about 98wt%HFC-1225ye of 1wt%-, approximately the about 98wt% of 1wt%-anti--HFC-1234ze and the about about 98wt%CF of 1wt%- ₃SCF ₃

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-1243zf of 1wt%-and the approximately about 98wt%HFC-134 of 1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-1243zf of 1wt%-and the approximately about 30wt% normal butane of 1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-1243zf of 1wt%-and the approximately about 40wt% Trimethylmethane of 1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-1243zf of 1wt%-and the approximately about 98wt% dimethyl ether of 1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-1243zf of 1wt%-and the approximately about 98wt%CF of 1wt%- ₃I;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-134 of 1wt%-and the approximately about 98wt%HFC-152a of 1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-134 of 1wt%-and the approximately about 98wt%HFC-227ea of 1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-134 of 1wt%-and the approximately about 40wt% normal butane of 1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-134 of 1wt%-and the approximately about 40wt% Trimethylmethane of 1wt%-;

The approximately about 98wt%HFC-1225ye of 1wt%-, about about 98wt%HFC-134 of 1wt%-and the approximately about 40wt% dimethyl ether of 1wt%-;

The approximately about 98wt%HFC-1225ye of 40wt%-, about about 59wt%HFC-227ea of 1wt%-and the approximately about 30wt% dimethyl ether of 1wt%-;

About about 98wt%HFC-1225ye of 1wt%-, about about 30wt% normal butane of 1wt%-and about about 98wt% dimethyl ether of 1wt%-;

About about 98wt%HFC-1225ye of 1wt%-, about about 20wt% normal butane of 1wt%-and about about 98wt%CF of 1wt%- ₃SCF ₃

About about 98wt%HFC-1225ye of 1wt%-, about about 60wt% Trimethylmethane of 1wt%-and about about 98wt% dimethyl ether of 1wt%-; With

About about 98wt%HFC-1225ye of 1wt%-, about about 40wt% Trimethylmethane of 1wt%-and about about 98wt%CF of 1wt%- ₃I.

22. the composition of claim 2 comprises being selected from following azeotropic or near Azeotrope compositions:

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-1234yf of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-1243zf of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-134 of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-134a of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-152a of 99wt%-;

Approximately the about 52wt% of 1wt%-anti--HFC-1234ze and approximately the about 48wt%HFC-161 of 99wt%-and approximately the about 99wt% of 87wt%-anti--HFC-1234ze and the about about 1wt%HFC-161 of 13wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-227ea of 99wt%-;

Approximately the about 99wt% of 54wt%-anti--HFC-1234ze and the about about 1wt%HFC-236ea of 46wt%-;

Approximately the about 99wt% of 44wt%-anti--HFC-1234ze and the about about 1wt%HFC-236fa of 56wt%-;

Approximately the about 99wt% of 67wt%-anti--HFC-1234ze and the about about 1wt%HFC-245fa of 33wt%-;

Approximately the about 71wt% of 1wt%-anti--HFC-1234ze and the about about 29wt% propane of 99wt%-;

Approximately the about 99wt% of 62wt%-anti--HFC-1234ze and the about about 1wt% normal butane of 38wt%-;

Approximately the about 99wt% of 39wt%-anti--HFC-1234ze and the about about 1wt% Trimethylmethane of 61wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt% dimethyl ether of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and about two (trifluoromethyl) thioethers of the about 1wt% of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%CF of 99wt%- ₃I;

Approximately the about 98wt%HFC-125 of 80wt%-, approximately the about 19wt% of 1wt%-anti--HFC-1234ze and the about about 10wt% Trimethylmethane of 1wt%-;

Approximately the about 98wt%HFC-32 of 1wt%-, approximately the about 98wt%HFC-125 of 1wt%-and approximately the about 5wt% of 1wt%-anti--HFC-1234ze;

Approximately the about 98wt%HFC-125 of 80wt%-, approximately the about 19wt% of 1wt%-anti--HFC-1234ze and the about about 10wt% normal butane of 1wt%-;

Approximately the about 99wt% of 1wt%-suitable-HFC-1234ze and the about about 1wt%HFC-1234ye of 99wt%-;

Approximately the about 99wt% of 1wt%-suitable-HFC-1234ze and the about about 1wt%HFC-236ea of 99wt%-;

Approximately the about 99wt% of 1wt%-suitable-HFC-1234ze and the about about 1wt%HFC-236fa of 99wt%-;

Approximately the about 99wt% of 1wt%-suitable-HFC-1234ze and the about about 1wt%HFC-245fa of 99wt%-;

Approximately the about 80wt% of 1wt%-suitable-HFC-1234ze and the about about 20wt% normal butane of 99wt%-;

Approximately the about 69wt% of 1wt%-suitable-HFC-1234ze and the about about 31wt% Trimethylmethane of 99wt%-;

Approximately the about 99wt% of 60wt%-suitable-HFC-1234ze and the about about 1wt%2-methylbutane of 40wt%-;

Approximately the about 99wt% of 63wt%-suitable-HFC-1234ze and the about about 1wt% Skellysolve A of 37wt%-;

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 98wt%HFC-1243zf of 1wt%-and the about about 98wt%HFC-227ea of 1wt%-;

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 98wt%HFC-1243zf of 1wt%-and the about about 30wt% normal butane of 1wt%-;

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 98wt%HFC-1243zf of 1wt%-and the about about 40wt% Trimethylmethane of 1wt%-;

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 98wt%HFC-1243zf of 1wt%-and the about about 98wt% dimethyl ether of 1wt%-;

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 98wt%HFC-134 of 1wt%-and the about about 98wt%HFC-152a of 1wt%-;

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 98wt%HFC-134 of 1wt%-and the about about 98wt%HFC-227ea of 1wt%-;

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 98wt%HFC-134 of 1wt%-and the about about 40wt% dimethyl ether of 1wt%-;

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 98wt%HFC-134a of 1wt%-and the about about 98wt%HFC-152a of 1wt%-;

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 98wt%HFC-152a of 1wt%-and the about about 50wt% normal butane of 1wt%-;

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 98wt%HFC-152a of 1wt%-and the about about 98wt% dimethyl ether of 1wt%-;

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 98wt%HFC-227ea of 1wt%-and the about about 40wt% normal butane of 1wt%-;

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 40wt% normal butane of 1wt%-and the about about 98wt% dimethyl ether of 1wt%-;

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 30wt% normal butane of 1wt%-and the about about 98wt%CF of 1wt%- ₃I;

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 60wt% Trimethylmethane of 1wt%-and the about about 98wt% dimethyl ether of 1wt%-;

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 40wt% Trimethylmethane of 1wt%-and the about about 98wt%CF of 1wt%- ₃I; With

Approximately the about 98wt% of 1wt%-anti--HFC-1234ze, approximately about 40wt% Trimethylmethane of 1wt%-and the about about 98wt%CF of 1wt%- ₃SCF ₃

23. the composition of claim 3 comprises being selected from following azeotropic or near Azeotrope compositions:

The approximately about 57wt%HFC-1234yf of 1wt%-and the approximately about 43wt%HFC-32 of 99wt%-;

The approximately about 51wt%HFC-1234yf of 1wt%-and the approximately about 49wt%HFC-125 of 99wt%-;

The approximately about 99wt%HFC-1234yf of 1wt%-and the approximately about 1wt%HFC-134 of 99wt%-;

The approximately about 99wt%HFC-1234yf of 1wt%-and the approximately about 1wt%HFC-134a of 99wt%-;

The approximately about 99wt%HFC-1234yf of 1wt%-and the approximately about 1wt%HFC-152a of 99wt%-;

The approximately about 99wt%HFC-1234yf of 1wt%-and the approximately about 1wt%HFC-161 of 99wt%-;

The approximately about 60wt%HFC-1234yf of 1wt%-and the approximately about 1wt%HFC-143a of 40wt%-;

The approximately about 99wt%HFC-1234yf of 29wt%-and the approximately about 1wt%HFC-227ea of 71wt%-;

The approximately about 99wt%HFC-1234yf of 66wt%-and the approximately about 1wt%HFC-236fa of 34wt%-;

The approximately about 99wt%HFC-1234yf of 1wt%-and the approximately about 1wt%HFC-1243zf of 99wt%-;

The approximately about 80wt%HFC-1234yf of 1wt%-and the approximately about 20wt% propane of 99wt%-;

The approximately about 99wt%HFC-1234yf of 71wt%-and the approximately about 1wt% normal butane of 29wt%-;

The approximately about 99wt%HFC-1234yf of 60wt%-and the approximately about 1wt% Trimethylmethane of 40wt%-;

The approximately about 99wt%HFC-1234yf of 1wt%-and the approximately about 1wt% dimethyl ether of 99wt%-;

The approximately about 98wt%HFC-125 of 80wt%-, about about 19wt%HFC-1234yf of 1wt%-and the approximately about 10wt% Trimethylmethane of 1wt%-;

The approximately about 98wt%HFC-125 of 80wt%-, about about 19wt%HFC-1234yf of 1wt%-and the approximately about 10wt% normal butane of 1wt%-;

The approximately about 98wt%HFC-32 of 1wt%-, about about 98wt%HFC-125 of 1wt%-and the approximately about 55wt%HFC-1234yf of 1wt%-;

The approximately about 50wt%HFC-1234yf of 1wt%-, about about 98wt%HFC-32 of 1wt%-and the approximately about 98wt%HFC-143a of 1wt%-;

The approximately about 40wt%HFC-1234yf of 1wt%-, about about 98wt%HFC-32 of 59wt%-and the approximately about 30wt% Trimethylmethane of 1wt%-;

The approximately about 60wt%HFC-1234yf of 1wt%-, about about 98wt%HFC-125 of 1wt%-and the approximately about 98wt%HFC-143a of 1wt%-;

The approximately about 40wt%HFC-1234yf of 1wt%-, about about 98wt%HFC-125 of 59wt%-and the approximately about 20wt% Trimethylmethane of 1wt%-;

The approximately about 80wt%HFC-1234yf of 1wt%-, about about 70wt%HFC-134 of 1wt%-and the approximately about 90wt% propane of 19wt%-;

The approximately about 70wt%HFC-1234yf of 1wt%-, about about 98wt%HFC-134 of 1wt%-and the approximately about 98wt% dimethyl ether of 29wt%-;

The approximately about 80wt%HFC-1234yf of 1wt%-, about about 80wt%HFC-134a of 1wt%-and the approximately about 98wt% propane of 19wt%-;

The approximately about 98wt%HFC-1234yf of 1wt%-, about about 98wt%HFC-134a of 1wt%-and the approximately about 30wt% normal butane of 1wt%-;

The approximately about 98wt%HFC-1234yf of 1wt%-, about about 98wt%HFC-134a of 1wt%-and the approximately about 30wt% Trimethylmethane of 1wt%-;

The approximately about 98wt%HFC-1234yf of 1wt%-, about about 98wt%HFC-134a of 1wt%-and the approximately about 40wt% dimethyl ether of 1wt%-;

The approximately about 80wt%HFC-1234yf of 1wt%-, about about 98wt%HFC-143a of 1wt%-and the approximately about 98wt% propane of 1wt%-;

The approximately about 40wt%HFC-1234yf of 1wt%-, about about 98wt%HFC-143a of 59wt%-and the approximately about 20wt% dimethyl ether of 1wt%-;

The approximately about 98wt%HFC-1234yf of 1wt%-, about about 98wt%HFC-152a of 1wt%-and the approximately about 30wt% normal butane of 1wt%-;

The approximately about 98wt%HFC-1234yf of 1wt%-, about about 90wt%HFC-152a of 1wt%-and the approximately about 40wt% Trimethylmethane of 1wt%-;

The approximately about 70wt%HFC-1234yf of 1wt%-, about about 98wt%HFC-152a of 1wt%-and the approximately about 98wt% dimethyl ether of 1wt%-;

The approximately about 80wt%HFC-1234yf of 1wt%-, about about 70wt%HFC-227ea of 1wt%-and the approximately about 98wt% propane of 29wt%-;

The approximately about 98wt%HFC-1234yf of 40wt%-, about about 59wt%HFC-227ea of 1wt%-and the approximately about 20wt% normal butane of 1wt%-;

The approximately about 98wt%HFC-1234yf of 30wt%-, about about 69wt%HFC-227ea of 1wt%-and the approximately about 30wt% Trimethylmethane of 1wt%-;

The approximately about 98wt%HFC-1234yf of 1wt%-, about about 80wt%HFC-227ea of 1wt%-and the approximately about 98wt% dimethyl ether of 1wt%-;

About about 98wt%HFC-1234yf of 1wt%-, about about 40wt% normal butane of 1wt%-and about about 98wt% dimethyl ether of 1wt%-;

About about 98wt%HFC-1234yf of 1wt%-, about about 50wt% Trimethylmethane of 1wt%-and about about 98wt% dimethyl ether of 1wt%-;

About about 98wt%HFC-1234yf of 1wt%-, about about 98wt% dimethyl ether of 1wt%-and about about 98wt%CF3I of 1wt%-; With

About about 98wt%HFC-1234yf of 1wt%-, about about 40wt% dimethyl ether of 1wt%-and about about 98wt%CF of 1wt%- ₃SCF ₃

24. the composition of claim 4 comprises being selected from following azeotropic or near Azeotrope compositions:

The approximately about 99wt%HFC-1234ye of 38wt%-and the approximately about 1wt%HFC-134 of 62wt%-;

The approximately about 99wt%HFC-1234ye of 1wt%-and the approximately about 1wt%HFC-236ea of 99wt%-;

The approximately about 99wt%HFC-1234ye of 1wt%-and the approximately about 1wt%HFC-236fa of 99wt%-;

The approximately about 99wt%HFC-1234ye of 1wt%-and the approximately about 1wt%HFC-245fa of 99wt%-;

The approximately about 78wt%HFC-1234ye of 1wt%-and the approximately about 22wt% normal butane of 99wt%-;

The approximately about 99wt%HFC-1234ye of 70wt%-and the approximately about 1wt% pentamethylene of 30wt%-;

The approximately about 68wt%HFC-1234ye of 1wt%-and the approximately about 32wt% Trimethylmethane of 99wt%-;

The approximately about 99wt%HFC-1234ye of 47wt%-and the approximately about 1wt%2-methylbutane of 53wt%-; With

The approximately about 99wt%HFC-1234ye of 57wt%-and the approximately about 1wt% Skellysolve A of 43wt%-.

25. the composition of claim 5 comprises being selected from following azeotropic or near Azeotrope compositions:

The approximately about 99wt%HFC-1243zf of 1wt%-and the approximately about 1wt%HFC-134 of 99wt%-;

The approximately about 99wt%HFC-1243zf of 1wt%-and the approximately about 1wt%HFC-134a of 99wt%-;

The approximately about 99wt%HFC-1243zf of 1wt%-and the approximately about 1wt%HFC-152a of 99wt%-;

The approximately about 99wt%HFC-1243zf of 1wt%-and the approximately about 1wt%HFC-161 of 99wt%-;

The approximately about 99wt%HFC-1243zf of 1wt%-and the approximately about 1wt%HFC-227ea of 99wt%-;

The approximately about 99wt%HFC-1243zf of 53wt%-and the approximately about 1wt%HFC-236ea of 47wt%-;

The approximately about 99wt%HFC-1243zf of 49wt%-and the approximately about 1wt%HFC-236fa of 51wt%-;

The approximately about 99wt%HFC-1243zf of 66wt%-and the approximately about 1wt%HFC-245fa of 34wt%-;

The approximately about 71wt%HFC-1243zf of 1wt%-and the approximately about 29wt% propane of 99wt%-;

The approximately about 99wt%HFC-1243zf of 62wt%-and the approximately about 1wt% normal butane of 38wt%-;

The approximately about 99wt%HFC-1243zf of 45wt%-and the approximately about 1wt% Trimethylmethane of 55wt%-;

The approximately about 99wt%HFC-1243zf of 1wt%-and the approximately about 1wt% dimethyl ether of 99wt%-;

The approximately about 98wt%HFC-1243zf of 1wt%-, about about 98wt%HFC-134 of 1wt%-and the approximately about 98wt%HFC-227ea of 1wt%-;

The approximately about 98wt%HFC-1243zf of 1wt%-, about about 98wt%HFC-134 of 1wt%-and the approximately about 40wt% normal butane of 1wt%-;

The approximately about 98wt%HFC-1243zf of 1wt%-, about about 98wt%HFC-134 of 1wt%-and the approximately about 98wt% dimethyl ether of 1wt%-;

The approximately about 98wt%HFC-1243zf of 1wt%-, about about 98wt%HFC-134 of 1wt%-and the approximately about 98wt%CF of 1wt%- ₃I;

The approximately about 98wt%HFC-1243zf of 1wt%-, about about 98wt%HFC-134a of 1wt%-and the approximately about 98wt%HFC-152a of 1wt%-;

The approximately about 98wt%HFC-1243zf of 1wt%-, about about 98wt%HFC-134a of 1wt%-and the approximately about 40wt% normal butane of 1wt%-;

The approximately about 70wt%HFC-1243zf of 1wt%-, about about 70wt%HFC-152a of 1wt%-and the approximately about 98wt% propane of 29wt%-;

The approximately about 98wt%HFC-1243zf of 1wt%-, about about 98wt%HFC-152a of 1wt%-and the approximately about 30wt% normal butane of 1wt%-;

The approximately about 98wt%HFC-1243zf of 1wt%-, about about 98wt%HFC-152a of 1wt%-and the approximately about 40wt% Trimethylmethane of 1wt%-;

The approximately about 98wt%HFC-1243zf of 1wt%-, about about 98wt%HFC-152a of 1wt%-and the approximately about 98wt% dimethyl ether of 1wt%-;

The approximately about 98wt%HFC-1243zf of 1wt%-, about about 98wt%HFC-227ea of 1wt%-and the approximately about 40wt% normal butane of 1wt%-;

The approximately about 98wt%HFC-1243zf of 1wt%-, about about 90wt%HFC-227ea of 1wt%-and the approximately about 50wt% Trimethylmethane of 1wt%-;

The approximately about 98wt%HFC-1243zf of 1wt%-, about about 80wt%HFC-227ea of 1wt%-and the approximately about 90wt% dimethyl ether of 1wt%-;

About about 98wt%HFC-1243zf of 1wt%-, about about 40wt% normal butane of 1wt%-and about about 98wt% dimethyl ether of 1wt%-;

About about 98wt%HFC-1243zf of 1wt%-, about about 60wt% Trimethylmethane of 1wt%-and about about 98wt% dimethyl ether of 1wt%-;

About about 98wt%HFC-1243zf of 1wt%-, about about 40wt% Trimethylmethane of 1wt%-and about about 98wt%CF of 1wt%- ₃I; With

About about 98wt%HFC-1243zf of 1wt%-, about about 40wt% dimethyl ether of 1wt%-and about about 90wt%CF of 1wt%- ₃SCF ₃

26. the composition of claim 1 comprises being selected from following Azeotrope compositions:

Under temperature approximately-25 ℃ vapour pressure be the 63.0wt%HFC-1225ye of about 11.7psia (81kPa) and 37.0wt% anti--HFC-1234ze;

Under temperature approximately-25 ℃ vapour pressure be the 40.0wt%HFC-1225ye of about 13.6psia (94kPa) and 60.0wt% anti--HFC-1243zf;

Vapour pressure is 52.2wt%HFC-1225ye and the 47.8wt%HFC-134 of about 12.8psia (88kPa) under temperature approximately-25 ℃;

Vapour pressure is 7.3wt%HFC-1225ye and the 92.7wt%HFC-152a of about 14.5psia (100kPa) under temperature approximately-25 ℃;

Vapour pressure is 29.7wt%HFC-1225ye and the 70.3wt% propane of about 30.3psia (209kPa) under temperature approximately-25 ℃;

Vapour pressure is 89.5wt%HFC-1225ye and the 10.5wt% normal butane of about 12.3psia (85kPa) under temperature approximately-25 ℃;

Vapour pressure is 79.3wt%HFC-1225ye and the 20.7wt% Trimethylmethane of about 13.9psia (96kPa) under temperature approximately-25 ℃;

Vapour pressure is 82.1wt%HFC-1225ye and the 17.9wt% dimethyl ether of about 10.8psia (74kPa) under temperature approximately-25 ℃;

Vapour pressure is 37.0wt%HFC-1225ye and the 63.0wt%CF of about 124psia (85kPa) under temperature approximately-25 ℃ ₃SCF ₃

Under temperature approximately-25 ℃ vapour pressure be 47.4wt%HFC-1225ye, the 5.6wt% of about 12.8psia (88kPa) anti--HFC-1234ze and 47.0wt%HFC-134;

Under temperature approximately-25 ℃ vapour pressure be 28.4wt%HFC-1225ye, the 52.6wt% of about 11.6psia (80.2kPa) anti--HFC-1234ze and 19.0wt%HFC-227ea;

Under temperature approximately-25 ℃ vapour pressure be 20.9wt%HFC-1225ye, the 9.1wt% of about 30.4psia (209kPa) anti--HFC-1234ze and 70.0wt% propane;

Under temperature approximately-25 ℃ vapour pressure be 65.8wt%HFC-1225ye, the 24.1wt% of about 12.4psia (85.4kPa) anti--HFC-1234ze and 10.1wt%HFC-134;

Under temperature approximately-25 ℃ vapour pressure be 41.0wt%HFC-1225ye, the 40.1wt% of about 11.0psia (75.7kPa) anti--HFC-1234ze and 18.9wt% dimethyl ether;

Under temperature approximately-25 ℃ vapour pressure be 1.0wt%HFC-1225ye, the 33.7wt% of about 12.7psia (87.3kPa) anti--HFC-1234ze and 65.2wt%CF ₃SCF ₃

Vapour pressure is 28.7wt%HFC-1225ye, 47.3wt%HFC-1243zf and the 24.1wt%HFC-134 of about 13.8psia (95.1kPa) under temperature approximately-25 ℃;

Vapour pressure is 37.5wt%HFC-1225ye, 55.0wt%HFC-1243zf and the 7.5wt% normal butane of about 14.0psia (96.2kPa) under temperature approximately-25 ℃;

Vapour pressure is 40.5wt%HFC-1225ye, 43.2wt%HFC-1243zf and the 16.3wt% Trimethylmethane of about 14.8psia (102kPa) under temperature approximately-25 ℃;

Vapour pressure is 19.1wt%HFC-1225ye, 51.0wt%HFC-1243zf and the 29.9wt% dimethyl ether of about 12.2psia (83.8kPa) under temperature approximately-25 ℃;

Vapour pressure is 10.3wt%HFC-1225ye, 27.3wt%HFC-1243zf and the 62.3wt%CF3I of about 14.1psia (96.9kPa) under temperature approximately-25 ℃;

Vapour pressure is 63.6wt%HFC-1225ye, 26.8wt%HFC-134 and the 9.6wt%HFC-152a of about 12.4psia (85.4kPa) under temperature approximately-25 ℃;

Vapour pressure is 1.3wt%HFC-1225ye, 52.3wt%HFC-134 and the 46.4wt%HFC-227ea of about 12.3psia (84.9kPa) under temperature approximately-25 ℃;

Vapour pressure is 18.1wt%HFC-1225ye, 67.1wt%HFC-134 and the 14.9wt% normal butane of about 14.5psia (100kPa) under temperature approximately-25 ℃;

Vapour pressure is 0.7wt%HFC-1225ye, 74.0wt%HFC-134 and the 25.3wt% Trimethylmethane of about 16.7psia (115kPa) under temperature approximately-25 ℃;

Vapour pressure is 29.8wt%HFC-1225ye, 52.5wt%HFC-134 and the 17.8wt% dimethyl ether of about 9.8psia (67.4kPa) under temperature approximately-25 ℃;

Vapour pressure is 63.1wt%HFC-1225ye, 31.0wt%HFC-227ea and the 5.8wt% dimethyl ether of about 10.9psia (75.4kPa) under temperature approximately-25 ℃;

Vapour pressure is 66.0wt%HFC-1225ye, 13.0wt% normal butane and the 21.1wt% dimethyl ether of about 11.3psia (78.2kPa) under temperature approximately-25 ℃;

Vapour pressure is 71.3wt%HFC-1225ye, 5.6wt% normal butane and the 23.0wt%CF of about 12.3psia (84.5kPa) under temperature approximately-25 ℃ ₃SCF ₃

Vapour pressure is 49.9wt%HFC-1225ye, 29.7wt% Trimethylmethane and the 20.4wt% dimethyl ether of about 12.8psia (88.5kPa) under temperature approximately-25 ℃; With

Vapour pressure is 27.7wt%HFC-1225ye, 2.2wt% Trimethylmethane and the 70.1wt%CF of about 13.2psia (90.9kPa) under temperature approximately-25 ℃ ₃I.

27. the composition of claim 2 comprises being selected from following Azeotrope compositions:

Under temperature approximately-25 ℃ vapour pressure be the 17.0wt% of about 13.0psia (90kPa) anti--HFC-1234ze and 83.0wt%HFC-1243zf;

Under temperature approximately-25 ℃ vapour pressure be the 45.7wt% of about 12.5psia (86kPa) anti--HFC-1234ze and 54.3wt%HFC-134;

Under temperature approximately-25 ℃ vapour pressure be the 9.5wt% of about 15.5psia (107kPa) anti--HFC-1234ze and 90.5wt%HFC-134a;

Under temperature approximately-25 ℃ vapour pressure be the 21.6wt% of about 14.6psia (101kPa) anti--HFC-1234ze and 78.4wt%HFC-152a;

Under temperature approximately-25 ℃ vapour pressure be the 59.2wt% of about 11.7psia (81kPa) anti--HFC-1234ze and 40.8wt%HFC-227ea;

Under temperature approximately-25 ℃ vapour pressure be the 28.5wt% of about 30.3psia (209kPa) anti--HFC-1234ze and 71.5wt% propane;

Under temperature approximately-25 ℃ vapour pressure be the 88.6wt% of about 11.9psia (82kPa) anti--HFC-1234ze and 11.4wt% normal butane;

Under temperature approximately-25 ℃ vapour pressure be the 77.9wt% of about 12.9psia (89kPa) anti--HFC-1234ze and 22.1wt% Trimethylmethane;

Under temperature approximately-25 ℃ vapour pressure be the 84.1wt% of about 108psia (74kPa) anti--HFC-1234ze and 15.9wt% dimethyl ether;

Under temperature approximately-25 ℃ vapour pressure be the 34.3wt% of about 12.7psia (88kPa) anti--HFC-1234ze and 65.7wt%CF ₃SCF ₃

Under temperature approximately-25 ℃ vapour pressure be the 7.1wt% of about 13.1psia (90.4kPa) anti--HFC-1234ze, 73.7wt%HFC-1243zf and 19.2wt%HFC-227ea;

Under temperature approximately-25 ℃ vapour pressure be the 9.5wt% of about 135psia (92.9kPa) anti--HFC-1234ze, 81.2wt%HFC-1243zf and 9.3wt% normal butane;

Under temperature approximately-25 ℃ vapour pressure be the 3.3wt% of about 14.3psia (98.3kPa) anti--HFC-1234ze, 77.6wt%HFC-1243zf and 19.1wt% Trimethylmethane;

Under temperature approximately-25 ℃ vapour pressure be the 2.6wt% of about 12.0psia (82.9kPa) anti--HFC-1234ze, 70.0wt%HFC-1243zf and 27.4wt% dimethyl ether;

Under temperature approximately-25 ℃ vapour pressure be the 52.0wt% of about 12.4psia (85.3kPa) anti--HFC-1234ze, 42.9wt%HFC-134 and 5.1wt%HFC-152a;

Under temperature approximately-25 ℃ vapour pressure be the 30.0wt% of about 12.6psia (86.9kPa) anti--HFC-1234ze, 43.2wt%HFC-134 and 26.8wt%HFC-227ea;

Under temperature approximately-25 ℃ vapour pressure be the 27.7wt% of about 9.8psia (67.3kPa) anti--HFC-1234ze, 54.7wt%HFC-134 and 17.7wt% dimethyl ether;

Under temperature approximately-25 ℃ vapour pressure be the 14.4wt% of about 14.4psia (99.4kPa) anti--HFC-1234ze, 34.7wt%HFC-134a and 51.0wt%HFC-152a;

Under temperature approximately-25 ℃ vapour pressure be the 5.4wt% of about 15.4psia (106kPa) anti--HFC-1234ze, 80.5wt%HFC-152a and 14.1wt% normal butane;

Under temperature approximately-25 ℃ vapour pressure be the 59.1wt% of about 10.8psia (74.5kPa) anti--HFC-1234ze, 16.4wt%HFC-152a and 24.5wt% dimethyl ether;

Under temperature approximately-25 ℃ vapour pressure be the 40.1wt% of about 12.6psia (86.9kPa) anti--HFC-1234ze, 48.5wt%HFC-227ea and 11.3wt% normal butane;

Under temperature approximately-25 ℃ vapour pressure be the 68.1wt% of about 11.3psia (77.8kPa) anti--HFC-1234ze, 13.0wt% normal butane and 18.9wt% dimethyl ether;

Under temperature approximately-25 ℃ vapour pressure be the 81.2wt% of about 11.9psia (81.8kPa) anti--HFC-1234ze, 9.7wt% normal butane and 9.1wt%CF ₃I;

Under temperature approximately-25 ℃ vapour pressure be the 55.5wt% of about 12.4psia (85.4kPa) anti--HFC-1234ze, 28.7wt% Trimethylmethane and 15.8wt% dimethyl ether;

Under temperature approximately-25 ℃ vapour pressure be the 34.9wt% of about 12.6psia (86.7kPa) anti--HFC-1234ze, 6.1wt% Trimethylmethane and 59.0wt%CF ₃I;

Under temperature approximately-25 ℃ vapour pressure be the 37.7wt% of about 12.7psia (87.3kPa) anti--HFC-1234ze, 1.1wt% Trimethylmethane and 61.7wt%CF ₃SCF ₃

Vapour pressure is the 20.9wt% of about 30.3psia (209kPa) under temperature approximately-25 ℃ suitable-HFC-1234ze and 79.1wt%HFC-236ea;

Vapour pressure is the 76.2wt% of about 26.1psia (180kPa) under temperature approximately-25 ℃ suitable-HFC-1234ze and 23.8wt%HFC-245fa;

Vapour pressure is the 51.4wt% of about 6.1psia (41.9kPa) under temperature approximately-25 ℃ suitable-HFC-1234ze and 48.6wt% normal butane;

Vapour pressure is the 26.2wt% of about 8.7psia (60.3kPa) under temperature approximately-25 ℃ suitable-HFC-1234ze and 73.8wt% Trimethylmethane;

Vapour pressure is the 86.6wt% of about 27.2psia (188kPa) under about 25 ℃ temperature suitable-HFC-1234ze and 13.4wt%2-methylbutane;

Vapour pressure is the 92.9wt% of about 26.2psia (181kPa) under about 25 ℃ temperature suitable-HFC-1234ze and 7.1wt% Skellysolve A.

28. the composition of claim 3 comprises being selected from following Azeotrope compositions:

Vapour pressure is 7.4wt%HFC-1234yf and the 92.6wt%HFC-32 of about 49.2psia (339kPa) under temperature approximately-25 ℃;

Vapour pressure is 10.9wt%HFC-1234yf and the 89.1wt%HFC-125 of about 40.7psia (281kPa) under temperature approximately-25 ℃;

Vapour pressure is 70.4wt%HFC-1234yf and the 29.6wt%HFC-134a of about 18.4psia (127kPa) under temperature approximately-25 ℃;

Vapour pressure is 91.0wt%HFC-1234yf and the 9.0wt%HFC-152a of about 17.9psia (123kPa) under temperature approximately-25 ℃;

Vapour pressure is 17.3wt%HFC-1234yf and the 82.7wt%HFC-143a of about 29.5psia (272kPa) under temperature approximately-25 ℃;

Vapour pressure is 84.6wt%HFC-1234yf and the 15.4wt%HFC-227ea of about 18.0psia (124kPa) under temperature approximately-25 ℃;

Vapour pressure is 51.5wt%HFC-1234yf and the 48.5wt% propane of about 33.5psia (231kPa) under temperature approximately-25 ℃;

Vapour pressure is 98.1wt%HFC-1234yf and the 19wt% normal butane of about 179psia (123kPa) under temperature approximately-25 ℃;

Vapour pressure is 88.1wt%HFC-1234yf and the 11.9wt% Trimethylmethane of about 19.0psia (131kPa) under temperature approximately-25 ℃;

Vapour pressure is 53.5wt%HFC-1234yf and the 46.5wt% dimethyl ether of about 13.1psia (90kPa) under temperature approximately-25 ℃;

Vapour pressure is 89.1wt%HFC-125,9.7wt%HFC-1234yf and the 1.2wt% Trimethylmethane of about 40.8psia (281kPa) under temperature approximately-25 ℃;

Vapour pressure is 3.9wt%HFC-1234yf, 74.3wt%HFC-32 and the 21.8wt%HFC-143a of about 50.0psia (345kPa) under temperature approximately-25 ℃;

Vapour pressure is 1.1wt%HFC-1234yf, 92.1wt%HFC-32 and the 6.8wt% Trimethylmethane of about 50.0psia (345kPa) under temperature approximately-25 ℃;

Vapour pressure is 14.4wt%HFC-1234yf, 43.5wt%HFC-125 and the 42.1wt%HFC-143a of about 38.6psia (266kPa) under temperature approximately-25 ℃;

Vapour pressure is 4.3wt%HFC-1234yf, 39.1wt%HFC-134 and the 56.7wt% propane of about 34.3psia (236kPa) under temperature approximately-25 ℃;

Vapour pressure is 15.2wt%HFC-1234yf, 67.0wt%HFC-134 and the 17.8wt% dimethyl ether of about 10.4psia (71.6kPa) under temperature approximately-25 ℃;

Vapour pressure is 24.5wt%HFC-1234yf, 31.1wt%HFC-134a and the 44.5wt% propane of about 34.0psia (234kPa) under temperature approximately-25 ℃;

Vapour pressure is 60.3wt%HFC-1234yf, 35.2wt%HFC-134a and the 4.5wt% normal butane of about 18.6psia (128kPa) under temperature approximately-25 ℃;

Vapour pressure is 48.6wt%HFC-1234yf, 37.2wt%HFC-134a and the 14.3wt% Trimethylmethane of about 19.9psia (137kPa) under temperature approximately-25 ℃;

Vapour pressure is 24.0wt%HFC-1234yf, 67.9wt%HFC-134a and the 8.1wt% dimethyl ether of about 17.2psia (119kPa) under temperature approximately-25 ℃;

Vapour pressure is 17.7wt%HFC-1234yf, 71.0wt%HFC-143a and the 11.3wt% propane of about 40.4psia (279kPa) under temperature approximately-25 ℃;

Vapour pressure is 5.7wt%HFC-1234yf, 93.0wt%HFC-143a and the 1.3wt% dimethyl ether of about 39.1psia (269kPa) under temperature approximately-25 ℃;

Vapour pressure is 86.6wt%HFC-1234yf, 10.8wt%HFC-152a and the 2.7wt% normal butane of about 18.0psia (124kPa) under temperature approximately-25 ℃;

Vapour pressure is 75.3wt%HFC-1234yf, 11.8wt%HFC-152a and the 12.9wt% Trimethylmethane of about 19.1psia (132kPa) under temperature approximately-25 ℃;

Vapour pressure is 24.6wt%HFC-1234yf, 43.3wt%HFC-152a and the 32.1wt% dimethyl ether of about 11.8psia (81.2kPa) under temperature approximately-25 ℃;

Vapour pressure is 35.6wt%HFC-1234yf, 17.8wt%HFC-227ea and the 46.7wt% propane of about 33.8psia (233kPa) under temperature approximately-25 ℃;

Vapour pressure is 81.9wt%HFC-1234yf, 16.0wt%HFC-227ea and the 2.1wt% normal butane of about 18.1psia (125kPa) under temperature approximately-25 ℃;

Vapour pressure is 86.6wt%HFC-1234yf, 10.8wt%HFC-152a and the 2.7wt% normal butane of about 18.0psia (124kPa) under temperature approximately-25 ℃;

Vapour pressure is 70.2wt%HFC-1234yf, 18.2wt%HFC-227ea and the 11.6wt% Trimethylmethane of about 19.3psia (133kPa) under temperature approximately-25 ℃;

Vapour pressure is 28.3wt%HFC-1234yf, 55.6wt%HFC-227ea and the 16.1wt% dimethyl ether of about 15.0psia (104kPa) under temperature approximately-25 ℃;

Vapour pressure is 48.9wt%HFC-1234yf, 4.6wt% normal butane and the 46.4wt% dimethyl ether of about 13.2psia (90.7kPa) under temperature approximately-25 ℃;

Vapour pressure is 31.2wt%HFC-1234yf, 26.2wt% Trimethylmethane and the 42.6wt% dimethyl ether of about 14.2psia (97.8kPa) under temperature approximately-25 ℃;

Vapour pressure is 16.3wt%HFC-1234yf, 10.0wt% dimethyl ether and the 73.7wt%CF of about 15.7psia (108kPa) under temperature approximately-25 ℃ ₃I;

Vapour pressure is 34.3wt%HFC-1234yf, 10.5wt% dimethyl ether and the 55.2wt%CF of about 14.6psia (100kPa) under temperature approximately-25 ℃ ₃SCF ₃

29. the composition of claim 4 comprises being selected from following Azeotrope compositions:

Vapour pressure is 24.0wt%HFC-1234ye and the 76.0wt%HFC-236ea of about 3.35psia (23.1kPa) under temperature approximately-25 ℃;

Vapour pressure is 42.5wt%HFC-1234ye and the 57.5wt%HFC-245fa of about 22.8psia (157kPa) under about 25 ℃ temperature;

Vapour pressure is 41.2wt%HFC-1234ye and the 58.8wt% normal butane of about 38.0psia (262kPa) under about 25 ℃ temperature;

Vapour pressure is 16.4wt%HFC-1234ye and the 83.6wt% Trimethylmethane of about 50.9psia (351kPa) under about 25 ℃ temperature;

Vapour pressure is 80.3wt%HFC-1234ye and the 19.7wt%2-methylbutane of about 23.1psia (159kPa) under about 25 ℃ temperature;

Vapour pressure is 87.7wt%HFC-1234ye and the 12.3wt% Skellysolve A of about 21.8psia (150kPa) under about 25 ℃ temperature;

30. the composition of claim 5 comprises being selected from following Azeotrope compositions:

Vapour pressure is 63.0wt%HFC-1243zf and the 37.0wt%HFC-134 of about 13.5psia (93kPa) under temperature approximately-25 ℃;

Vapour pressure is 25.1wt%HFC-1243zf and the 74.9wt%HFC-134a of about 15.9psia (110kPa) under temperature approximately-25 ℃;

Vapour pressure is 40.7wt%HFC-1243zf and the 59.3wt%HFC-152a of about 15.2psia (104kPa) under temperature approximately-25 ℃;

Vapour pressure is 78.5wt%HFC-1243zf and the 21.5wt%HFC-227ea of about 13.1psia (90kPa) under temperature approximately-25 ℃;

Vapour pressure is 32.8wt%HFC-1243zf and the 67.2wt% propane of about 310psia (213kPa) under temperature approximately-25 ℃;

Vapour pressure is 90.3wt%HFC-1243zf and the 9.7wt% normal butane of about 13.5psia (93kPa) under temperature approximately-25 ℃;

Vapour pressure is 80.7wt%HFC-1243zf and the 19.3wt% Trimethylmethane of about 14.3psia (98kPa) under temperature approximately-25 ℃; With

Vapour pressure is 72.7wt%HFC-1243zf and the 27.3wt% dimethyl ether of about 12.0psia (83kPa) under temperature approximately-25 ℃;

Vapour pressure is 58.6wt%HFC-1243zf, 34.1wt%HFC-134 and the 7.3wt%HFC-227ea of about 13.5psia (93.4kPa) under temperature approximately-25 ℃;

Vapour pressure is 27.5wt%HFC-1243zf, 58.7wt%HFC-134 and the 13.9wt% normal butane of about 14.7psia (101kPa) under temperature approximately-25 ℃;

Vapour pressure is 18.7wt%HFC-1243zf, 63.5wt%HFC-134 and the 17.8wt% dimethyl ether of about 10.1psia (69.7kPa) under temperature approximately-25 ℃;

Vapour pressure is 11.4wt%HFC-1243zf, 23.9wt%HFC-134 and the 647wt%CF of about 14.5psia (99.6kPa) under temperature approximately-25 ℃ ₃I;

Vapour pressure is 41.5wt%HFC-1243zf, 215wt%HFC-134a and the 37.1wt%HFC-152a of about 15.0psia (103kPa) under temperature approximately-25 ℃;

Vapour pressure is 7.0wt%HFC-1243zf, 81.4wt%HFC-134a and the 11.6wt% normal butane of about 17.0psia (117kPa) under temperature approximately-25 ℃;

Vapour pressure is 2.9wt%HFC-1243zf, 34.0wt%HFC-152a and the 63.0wt% propane of about 31.7psia (219kPa) under temperature approximately-25 ℃;

Vapour pressure is 28.8wt%HFC-1243zf, 60.3wt%HFC-152a and the 11.0wt% normal butane of about 15.7psia (108kPa) under temperature approximately-25 ℃;

Vapour pressure is 6.2wt%HFC-1243zf, 68.5wt%HFC-152a and the 25.3wt% Trimethylmethane of about 17.1psia (118kPa) under temperature approximately-25 ℃;

Vapour pressure is 33.1wt%HFC-1243zf, 36.8wt%HFC-152a and the 30.1wt% dimethyl ether of about 11.4psia (78.7kPa) under temperature approximately-25 ℃;

Vapour pressure is 62.0wt%HFC-1243zf, 28.4wt%HFC-227ea and the 9.6wt% normal butane of about 13.7psia (94.3kPa) under temperature approximately-25 ℃;

Vapour pressure is 27.9wt%HFC-1243zf, 51.0wt%HFC-227ea and the 21.1wt% Trimethylmethane of about 15.0psia (103kPa) under temperature approximately-25 ℃;

Vapour pressure is 48.1wt%HFC-1243zf, 44.8wt%HFC-227ea and the 7.2wt% dimethyl ether of about 12.8psia (88.1kPa) under temperature approximately-25 ℃;

Vapour pressure is 60.3wt% HFC-1243zf, 10.1wt% normal butane and the 29.6wt% dimethyl ether of about 12.3psia (84.7kPa) under temperature approximately-25 ℃;

Vapour pressure is 47.1wt%HFC-1243zf, 26.9wt% Trimethylmethane and the 25.9wt% dimethyl ether of about 13.2psia (90.7kPa) under temperature approximately-25 ℃;

Vapour pressure is 32.8wt%HFC-1243zf, 1.1wt% Trimethylmethane and the 66.1wt%CF of about 14.0psia (96.3kPa) under temperature approximately-25 ℃ ₃I;

Vapour pressure is 41.1wt%HFC-1243zf, 2.3wt% dimethyl ether and the 56.6wt%CF of about 13.6psia (93.8kPa) under temperature approximately-25 ℃ ₃SCF ₃

31. each composition among the claim 1-30 also comprises the lubricant that is selected from polyol ester, polyalkylene glycol, polyvingl ether, mineral oil, alkylbenzene, synthetic paraffin, synthetic naphthenic hydrocarbon and poly-(α) alkene.

32. each composition among the claim 1-30 also comprises tracer agent, it is selected from hydrogen fluorine carbon, deuteroparaffin, hydrogen deuteride fluorine carbon, perfluoroparaffin, fluoroether, brominated compound, iodinated compounds, alcohol, aldehyde, ketone, nitrous oxide (N ₂O) and their combination.

33. the composition of claim 32 also comprises the tracer agent that is selected from following material:

CD ₃CD ₃, CD ₃CD ₂CD ₃, CD ₂F ₂, CF ₃CD ₂CF ₃, CD ₂FCF ₃, CD ₃CF ₃, CDF ₂CF ₃, CF ₃CDFCF ₃, CF ₃CF ₂CDF ₂, CDF ₂CDF ₂, CF ₃CF ₂CD ₃, CF ₃CD ₂CH ₃, CF ₂CH ₂CD ₃, CF ₃CF ₃, ring-CF ₂CF ₂CF ₂-, CF ₃CF ₂CF ₃, ring-CF ₂CF ₂CF ₂CF ₂-, CF ₃CF ₂CF ₂CF ₃, CF ₃CF (CF ₃) ₂, ring-CF (CF ₃) CF ₂CF (CF ₃) CF ₂-, trans-ring-OF ₂CF (CF ₃) CF (CF ₃) CF ₂-, cis-ring-CF ₂CF (CF ₃) CF (CF ₃) CF ₂-, CF ₃OCHF ₂, CF ₃OCH ₂F, CF ₃OCH ₃, CF ₃OCHFCF ₃, CF ₃OCH ₂CF ₃, CF ₃OCH ₂CHF ₂, CF ₃CH ₂OCHF ₂CH ₃OCF ₂CF ₃, CH ₃CF ₂OCF ₃CF ₃CF ₂CF ₂OCHFCF ₃, CF ₃CF ₂CF ₂OCF (CF ₃) CF ₂OCHFCF ₃, CHF ₃, CH ₂FCH ₃, CHF ₂CH ₃, CHF ₂CHF ₂, CF ₃CHFCF ₃, CF ₃CF ₂CHF ₂, CF ₃CF ₂CH ₂F, CHF ₂CHFCF ₃, CF ₃CH ₂CF ₃, CF ₃CF ₂CH ₃, CF ₃CH ₂CHF ₂, CHF ₂CF ₂CH ₃, CF ₃CHFCH ₃, CF ₃CH ₂CH ₃, CH ₃CF ₂CH ₃, CH ₃CHFCH ₃, CH ₂FCH ₂CH ₃, CHF ₂CF ₂CF ₂CF ₃, (CF ₃) ₂CHCF ₃, CF ₃CH ₂CF ₂CF ₃, CHF ₂CF ₂CF ₂CHF ₂, CH ₃CF ₂CF ₂CF ₃, CF ₃CHFCHFCF ₂CF ₃,

Trifluoromethyl-cyclopentane, perfluoromethyl cyclohexane, perfluorodimethylcyclohexane (adjacent, or to), perfluor ethylcyclohexane, Perfluoroindan, perfluor trimethyl-cyclohexane and their isomer, perfluor normenthane, along perfluorodecalin, anti-perfluorodecalin, along or anti-perfluoro-methyl naphthalane and their isomer, CH ₃Br, CH ₂FBr, CHF ₂Br, CHFBr ₂, CHBr ₃, CH ₂BrCH ₃, CHBr=CH ₂, CH ₂BrCH ₂Br, CFBr=CHF, CF ₃I, CHF ₂I, CH ₂FI, CF ₂ICH ₂F, CF ₂ICHF ₂, CF ₂ICF ₂I, C ₆F ₅I, ethanol, n-propyl alcohol, Virahol, acetone, positive propionic aldehyde, butyraldehyde-n, methyl ethyl ketone, nitrous oxide and their combination.

34. each composition among the claim 1-30 also comprises the expanding material that is selected from following material:

A) by general formula R ¹[(OR ²) xOR ³] poly suboxygen alkyl glycol ethers that y represents, wherein: x is the integer of 1-3; Y is the integer of 1-4; R ¹Be selected from hydrogen and the aliphatic hydrocarbyl that contains 1-6 carbon atom and y keyed jointing position; R ²Be selected from the aliphatic alkylene that contains 2-4 carbon atom; R ³Be selected from hydrogen and the aliphatic series and the alicyclic alkyl that contain 1-6 carbon atom; R ¹And R ³In at least one is selected from described alkyl; And wherein said poly suboxygen alkyl glycol ethers has the molecular weight of about 300 atomic mass units of about 100-;

B) by general formula R ¹C (O) NR ²R ³And ring-[R ⁴CON (R ⁵The acid amides of expression)-], wherein R ¹, R ², R ³And R ⁵Be independently selected from the aliphatic series that contains 1-12 carbon atom and alicyclic alkyl and aromatic group that contains 6-12 carbon atom at the most; R ⁴Be selected from the aliphatic alkylene that contains 3-12 carbon atom; And wherein said acid amides has about 100)-molecular weight of about 300 atomic mass units;

C) by general formula R ¹C (O) R ²The ketone of expression, wherein R ¹And R ²Be independently selected from the aliphatic series that contains 1-12 carbon atom, alicyclic and aryl alkyl, and wherein said ketone has the molecular weight of about 300 atomic mass units of about 70-;

D) by general formula R ¹The nitrile that CN represents, wherein R ¹Be selected from the aliphatic series that contains 5-12 carbon atom, alicyclic or aryl alkyl, and wherein said nitrile has the molecular weight of about 200 atomic mass units of about 90-;

E) hydrochloric ether of representing by general formula R Clx, wherein: x is 1 or 2; R is selected from aliphatic series and the alicyclic alkyl that contains 1-12 carbon atom; And wherein said chlorocarbon has the molecular weight of about 200 atomic mass units of about 100-;

F) by general formula R ¹OR ²The aryl ethers of expression, wherein: R ¹Be selected from the aryl alkyl that contains 6-12 carbon atom; R ²Be selected from the aliphatic hydrocarbyl that contains 1-4 carbon atom; And wherein said aryl ethers has the molecular weight of about 150 atomic mass units of about 100-;

G) by general formula CF ₃R ¹1,1 of expression, 1-trifluoro alkane, wherein R ¹Be selected from the aliphatic series and the alicyclic alkyl that contain about 15 carbon atoms of about 5-;

H) by general formula R ¹OCF ₂CF ₂The fluoroether that H represents, wherein R ¹Be selected from the aliphatic series that contains about 15 carbon atoms of about 5-, alicyclic, and aromatic hydrocarbyl; Or wherein said fluoroether is derived from fluoroolefins and polyvalent alcohol, and wherein said fluoroolefins has CF ₂=CXY pattern, wherein X is hydrogen, chlorine or fluorine, Y is chlorine, fluorine, CF ₃Or OR _f, R wherein _fBe CF ₃, C ₂F ₅Or C ₃F ₇With described polyvalent alcohol be linearity or branching, wherein said linear polyvalent alcohol has HOCH ₂(CHOH) x (CRR ') yCH ₂The OH pattern, wherein R and R ' are hydrogen, CH ₃Or C ₂H ₅, x is the integer of 0-4, y is the integer of 0-3, z be 0 or 1 and described branching polyvalent alcohol have C (OH) t (R) u (CH ₂OH) v[(CH ₂) mCH ₂OH] the w pattern, wherein R can be hydrogen, CH ₃Or C ₂H ₅, m is the integer of 0-3, and t and u are 0 or 1, and v and w are the integers of 0-4, in addition t+u+v+w=4 wherein; With

I) lactone of representing by structure [B], [C] and [D]:

Wherein, R ¹-R ⁸Be independently selected from hydrogen, linearity, branching, ring-type, two rings, saturated and undersaturated alkyl; And molecular weight is about 100 to about 300 atomic mass units; With

J) by general formula R ¹CO ₂R ²The ester of expression, wherein R ¹And R ²Be independently selected from linearity and ring-type, saturated and undersaturated, alkyl and aryl; And wherein said ester has from about 80 molecular weight to about 550 atomic mass units.

35. each composition among the claim 1-30 also comprises at least a naphthalimide ， perylene that is selected from, tonka bean camphor, anthracene, phenanthrene, xanthene, thioxanthene, naphthoxanthene, fluorescein, the UV fluorescent dye of the derivative of described dyestuff and their combination.

36. the composition of claim 35 also comprises at least a hydrocarbon, dimethyl ether, poly suboxygen alkyl glycol ethers, acid amides, ketone, nitrile, hydrochloric ether, ester, lactone, aryl ethers, the hydrogen fluoroether and 1,1 of being selected from, the solubilizing agent of 1-trifluoro alkane.

37. the composition of claim 36, wherein said solubilizing agent is selected from:

A) by general formula R ¹[(OR ²) xOR ³] poly suboxygen alkyl glycol ethers that y represents, wherein: x is the integer of 1-3; Y is the integer of 1-4; R ¹Be selected from hydrogen and the aliphatic hydrocarbyl that contains 1-6 carbon atom and y keyed jointing position; R ²Be selected from the aliphatic alkylene that contains 2-4 carbon atom; R ³Be selected from hydrogen and the aliphatic series and the alicyclic alkyl that contain 1-6 carbon atom; R ¹And R ³In at least one is selected from described alkyl; And wherein said poly suboxygen alkyl glycol ethers has the molecular weight of about 300 atomic mass units of about 100-;

B) by general formula R ¹C (O) NR ²R ³And ring-[R ⁴CON (R ⁵The acid amides of expression)-], wherein R ¹, R ², R ³And R ⁵Be independently selected from the aliphatic series that contains 1-12 carbon atom and alicyclic alkyl and aromatic group that contains 6-12 carbon atom at the most; R ⁴Be selected from the aliphatic alkylene that contains 3-12 carbon atom; And wherein said acid amides has the molecular weight of about 300 atomic mass units of about 100-;

C) by general formula R ¹C (O) R ²The ketone of expression, wherein R ¹And R ²Be independently selected from the aliphatic series that contains 1-12 carbon atom, alicyclic and aryl alkyl, and wherein said ketone has the molecular weight of about 300 atomic mass units of about 70-;

D) by general formula R ¹The nitrile that CN represents, wherein R ¹Be selected from the aliphatic series that contains 5-12 carbon atom, alicyclic or aryl alkyl, and wherein said nitrile has the molecular weight of about 200 atomic mass units of about 90-;

E) hydrochloric ether of representing by general formula R Clx, wherein: x is 1 or 2; R is selected from aliphatic series and the alicyclic alkyl that contains 1-12 carbon atom; And wherein said hydrochloric ether has the molecular weight of about 200 atomic mass units of about 100-;

F) by general formula R ¹OR ²The aryl ethers of expression, wherein: R ¹Be selected from the aryl alkyl that contains 6-12 carbon atom; R ²Be selected from the aliphatic hydrocarbyl that contains 1-4 carbon atom; And wherein said aryl ethers has the molecular weight of about 150 atomic mass units of about 100-;

G) by general formula CF ₃R ¹1,1 of expression, 1-trifluoro alkane, wherein R ¹Be selected from the aliphatic series and the alicyclic alkyl that contain about 15 carbon atoms of about 5-;

H) by general formula R ¹OCF ₂CF ₂The fluoroether that H represents, wherein R ¹Be selected from the aliphatic series that contains about 15 carbon atoms of about 5-, alicyclic, and aromatic hydrocarbyl; Or wherein said fluoroether is derived from fluoroolefins and polyvalent alcohol, and wherein said fluoroolefins has CF ₂=CXY pattern, wherein X is hydrogen, chlorine or fluorine, Y is chlorine, fluorine, CF ₃Or OR _f, R wherein _fBe CF ₃, C ₂F ₅Or C ₃F ₇With described polyvalent alcohol be linearity or branching, wherein said linear polyvalent alcohol has HOCH ₂(CHOH) x (CRR ') yCH ₂The OH pattern, wherein R and R ' are hydrogen, CH ₃Or C ₂H ₅, x is the integer of 0-4, y is the integer of 0-3, z be 0 or 1 and described branching polyvalent alcohol have C (OH) t (R) u (CH ₂OH) v[(CH ₂) mCH ₂OH] the w pattern, wherein R can be hydrogen, CH ₃Or C ₂H ₅, m is the integer of 0-3, and t and u are 0 or 1, and v and w are the integers of 0-4, in addition t+u+v+w=4 wherein; With

I) lactone of representing by structure [B], [C] and [D]:

Wherein, R ¹-R ⁸Be independently selected from hydrogen, linearity, branching, ring-type, two rings, saturated and undersaturated alkyl; And molecular weight is about 100 to about 300 atomic mass units; With

J) by general formula R ¹CO ₂R ²The ester of expression, wherein R ¹And R ²Be independently selected from linearity and ring-type, saturated and undersaturated, alkyl and aryl; And wherein said ester has from about 80 molecular weight to about 550 atomic mass units.

38. each composition among the claim 1-30 also comprises stablizer, water scavenging agent or smell screening agent.

39. the composition of claim 38, wherein said stablizer is selected from Nitromethane 99Min., hindered phenol, azanol, mercaptan, phosphorous acid ester and lactone.

40. composition comprises:

(a) at least a lubricant that is selected from polyol ester, polyalkylene glycol, polyvingl ether, mineral oil, alkylbenzene, synthetic paraffin, synthetic naphthenic hydrocarbon and poly-(α) alkene; With

(b) be selected from the composition of the group that constitutes by following material:

The approximately about 99wt%HFC-1225ye of 1wt%-and the approximately about 1wt%HFC-152a of 99wt%-;

The approximately about 99wt%HFC-1225ye of 1wt%-and the approximately about 1wt%HFC-1234yf of 99wt%-;

Approximately the about 99wt%HFC-1225ye of 1wt%-and approximately the about 1wt% of 99wt%-anti--HFC-1234ze;

The approximately about 99wt%HFC-1225ye of 1wt%-and the approximately about 1wt%HFC-1243zf of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-134a of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-152a of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-227ea of 99wt%-; With

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%CF of 99wt%- ₃I.

41. composition comprises:

B) cooling agent or heat transfer fluid composition, said composition is selected from:

The approximately about 99wt%HFC-1225ye of 1wt%-and the approximately about 1wt%HFC-152a of 99wt%-;

The approximately about 99wt%HFC-1225ye of 1wt%-and the approximately about 1wt%HFC-1234yf of 99wt%-;

Approximately the about 99wt%HFC-1225ye of 1wt%-and approximately the about 1wt% of 99wt%-anti--HFC-1234ze;

The approximately about 99wt%HFC-1225ye of 1wt%-and the approximately about 1wt%HFC-1243zf of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-134a of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-152a of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-227ea of 99wt%-; With

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%CF of 99wt%- ₃I; And b) be selected from the expanding material of following material:

I) by general formula R ¹[(OR ²) xOR ³] poly suboxygen alkyl glycol ethers that y represents, wherein: x is the integer of 1-3; Y is the integer of 1-4; R ¹Be selected from hydrogen and the aliphatic hydrocarbyl that contains 1-6 carbon atom and y keyed jointing position; R ²Be selected from the aliphatic alkylene that contains 2-4 carbon atom; R ³Be selected from hydrogen and the aliphatic series and the alicyclic alkyl that contain 1-6 carbon atom; R ¹And R ³In at least one is selected from described alkyl; And wherein said poly suboxygen alkyl glycol ethers has the molecular weight of about 300 atomic mass units of about 100-;

Ii) by general formula R ¹C (O) NR ²R ³And ring-[R ⁴CON (R ⁵The acid amides of expression)-], wherein R ¹, R ², R ³And R ⁵Be independently selected from the aliphatic series that contains 1-12 carbon atom and alicyclic alkyl and aromatic group that contains 6-12 carbon atom at the most; R ⁴Be selected from the aliphatic alkylene that contains 3-12 carbon atom; And wherein said acid amides has the molecular weight of about 300 atomic mass units of about 100-;

Iii) by general formula R ¹C (O) R ²The ketone of expression, wherein R ¹And R ²Be independently selected from the aliphatic series that contains 1-12 carbon atom, alicyclic and aryl alkyl, and wherein said ketone has the molecular weight of about 300 atomic mass units of about 70-;

Iv) by general formula R ¹The nitrile that CN represents, wherein R ¹Be selected from the aliphatic series that contains 5-12 carbon atom, alicyclic or aryl alkyl, and wherein said nitrile has the molecular weight of about 200 atomic mass units of about 90-;

The v) hydrochloric ether of representing by general formula R Clx, wherein: x is 1 or 2; R is selected from aliphatic series and the alicyclic alkyl that contains 1-12 carbon atom; And wherein said hydrochloric ether has the molecular weight of about 200 atomic mass units of about 100-;

Vi) by general formula R ¹OR ²The aryl ethers of expression, wherein: R ¹Be selected from the aryl alkyl that contains 6-12 carbon atom; R ²Be selected from the aliphatic hydrocarbyl that contains 1-4 carbon atom; And wherein said aryl ethers has the molecular weight of about 150 atomic mass units of about 100-;

Vii) by general formula CF ₃R ¹1,1 of expression, 1-trifluoro alkane, wherein R ¹Be selected from the aliphatic series and the alicyclic alkyl that contain about 15 carbon atoms of about 5-;

Viii) by general formula R ¹OCF ₂CF ₂The fluoroether that H represents, wherein R ¹Be selected from the aliphatic series that contains about 15 carbon atoms of about 5-, alicyclic, and aromatic hydrocarbyl; Or wherein said fluoroether is derived from fluoroolefins and polyvalent alcohol, and wherein said fluoroolefins has CF ₂=CXY pattern, wherein X is hydrogen, chlorine or fluorine, Y is chlorine, fluorine, CF ₃Or OR _f, R wherein _fBe CF ₃, C ₂F ₅Or C ₃F ₇With described polyvalent alcohol be linearity or branching, wherein said linear polyvalent alcohol has HOCH ₂(CHOH) x (CRR ') yCH ₂The OH pattern, wherein R and R ' are hydrogen, CH ₃Or C ₂H ₅, x is the integer of 0-4, y is the integer of 0-3, z be 0 or 1 and described branching polyvalent alcohol have C (OH) t (R) u (CH ₂OH) v[(CH ₂) mCH ₂OH] the w pattern, wherein R can be hydrogen, CH ₃Or C ₂H ₅, m is the integer of 0-3, and t and u are 0 or 1, and v and w are the integers of 0-4, in addition t+u+v+w=4 wherein; With

Ix) lactone of representing by structure [B], [C] and [D]:

Wherein, R ¹-R ⁸Be independently selected from hydrogen, linearity, branching, ring-type, two rings, saturated and undersaturated alkyl; And molecular weight is about 100 to about 300 atomic mass units; And x) by general formula R ¹CO ₂R ²The ester of expression, wherein R ¹And R ²Be independently selected from linearity and ring-type, saturated and undersaturated, alkyl and aryl; And wherein said ester has from about 80 molecular weight to about 550 atomic mass units.

42. composition comprises:

(a) at least a UV fluorescent dye, it is selected from naphthalimide ， perylene, tonka bean camphor, anthracene, phenanthrene, xanthene, thioxanthene, naphthoxanthene, fluorescein, the derivative of described dyestuff and their combination; With

(b) be selected from the composition of the group that constitutes by following material:

The approximately about 99wt%HFC-1225ye of 1wt%-and the approximately about 1wt%HFC-152a of 99wt%-;

The approximately about 99wt%HFC-1225ye of 1wt%-and the approximately about 1wt%HFC-1234yf of 99wt%-;

Approximately the about 99wt%HFC-1225ye of 1wt%-and approximately the about 1wt% of 99wt%-anti--HFC-1234ze;

The approximately about 99wt%HFC-1225ye of 1wt%-and the approximately about 1wt%HFC-1243zf of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-134a of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-152a of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-227ea of 99wt%-;

With the about 99wt% of about 1wt%-anti--HFC-1234ze and the about about 1wt%CF of 99wt%- ₃I.

43. the composition of claim 42 also comprises at least a hydrocarbon, dimethyl ether, poly suboxygen alkyl glycol ethers, acid amides, ketone, nitrile, hydrochloric ether, ester, lactone, the aryl ethers of being selected from, hydrogen fluoroether and 1,1, the solubilizing agent of 1-trifluoro alkane.

44. the composition of claim 43, wherein said solubilizing agent is selected from:

A) by general formula R ¹[(OR ²) xOR ³] poly suboxygen alkyl glycol ethers that y represents, wherein: x is the integer of 1-3; Y is the integer of 1-4; R ¹Be selected from hydrogen and the aliphatic hydrocarbyl that contains 1-6 carbon atom and y keyed jointing position; R ²Be selected from the aliphatic alkylene that contains 2-4 carbon atom; R ³Be selected from hydrogen and the aliphatic series and the alicyclic alkyl that contain 1-6 carbon atom; R ¹And R ³In at least one is selected from described alkyl; And wherein said poly suboxygen alkyl glycol ethers has the molecular weight of about 300 atomic mass units of about 100-;

B) by general formula R ¹C (O) NR ²R ³And ring-[R ⁴CON (R ⁵The acid amides of expression)-], wherein R ¹, R ², R ³And R ⁵Be independently selected from the aliphatic series that contains 1-12 carbon atom and alicyclic alkyl and aromatic group that contains 6-12 carbon atom at the most; R ⁴Be selected from the aliphatic alkylene that contains 3-12 carbon atom; And wherein said acid amides has the molecular weight of about 300 atomic mass units of about 100-;

C) by general formula R ¹C (O) R ²The ketone of expression, wherein R ¹And R ²Be independently selected from the aliphatic series that contains 1-12 carbon atom, alicyclic and aryl alkyl, and wherein said ketone has the molecular weight of about 300 atomic mass units of about 70-;

D) by general formula R ¹The nitrile that CN represents, wherein R ¹Be selected from the aliphatic series that contains 5-12 carbon atom, alicyclic or aryl alkyl, and wherein said nitrile has the molecular weight of about 200 atomic mass units of about 90-;

E) hydrochloric ether of representing by general formula R Clx, wherein: x is 1 or 2; R is selected from aliphatic series and the alicyclic alkyl that contains 1-12 carbon atom; And wherein said hydrochloric ether has the molecular weight of about 200 atomic mass units of about 100-;

F) by general formula R ¹OR ²The aryl ethers of expression, wherein: R ¹Be selected from the aromatic hydrocarbyl that contains 6-12 carbon atom; R ²Be selected from the aliphatic hydrocarbyl that contains 1-4 carbon atom; And wherein said aryl ethers has the molecular weight of about 150 atomic mass units of about 100-;

G) by general formula CF ₃R ¹1,1 of expression, 1-trifluoro alkane, wherein R ¹Be selected from the aliphatic series and the alicyclic alkyl that contain about 15 carbon atoms of about 5-;

H) by general formula R ¹OCF ₂CF ₂The fluoroether that H represents, wherein R ¹Be selected from the aliphatic series that contains about 15 carbon atoms of about 5-, alicyclic, and aromatic hydrocarbyl; Or wherein said fluoroether is derived from fluoroolefins and polyvalent alcohol, and wherein said fluoroolefins has CF ₂=CXY pattern, wherein X is hydrogen, chlorine or fluorine, Y is chlorine, fluorine, CF ₃Or OR _f, R wherein _fBe CF ₃, C ₂F ₅Or C ₃F ₇Has HOCH with described polyvalent alcohol ₂CRR ' (CH ₂) z (CHOH) xCH ₂(CH ₂OH) y pattern, wherein R and R ' are hydrogen, CH ₃Or C ₂H ₅, x is the integer of 0-4, and y is the integer of 0-3, and z is 0 or 1; With

I) lactone of representing by structure [B], [C] and [D]:

Wherein, R ¹-R ⁸Be independently selected from hydrogen, linearity, branching, ring-type, two rings, saturated and undersaturated alkyl; And molecular weight is about 100 to about 300 atomic mass units; With

J) by general formula R ¹CO ₂R ²The ester of expression, wherein R ¹And R ²Be independently selected from linearity and ring-type, saturated and undersaturated, alkyl and aryl; And wherein said ester has from about 80 molecular weight to about 550 atomic mass units.

45. refrigerating method, described method comprises: near body to be cooled each composition among the claim 1-30 is evaporated, afterwards with described composition condensation.

46. produce the method for heat, described method comprises: near body to be heated with each composition condensation among the claim 1-30, afterwards with described composition evaporation.

47. refrigerating method, described method comprises: near body to be cooled with claim 41, the evaporation of 42 or 43 composition, afterwards with described composition condensation.

48. produce the method for heat, described method comprises: near body to be heated with claim 41,42 or 43 composition condensation, afterwards with described composition evaporation.

49. test right requires 35 method for compositions in compression refrigeration, air-conditioning or heat-pump apparatus, described method comprises: described composition is offered described equipment, and at the leakage point place of described equipment or the appropriate device that detects described composition is provided near described equipment.

50. test right requires 42 or 43 method for compositions in compression refrigeration, air-conditioning or heat-pump apparatus, described method comprises: described composition is offered described equipment, and at the leakage point place of described equipment or the appropriate device that detects described composition is provided near described equipment.

51. in the refrigeration lubricant that is selected from mineral oil, alkylbenzene, synthetic paraffin, synthetic naphthenic hydrocarbon and poly-(α) alkene, will comprise the method for the cooling agent or the heat-transfer fluid composition solubilising of each composition among the claim 1-30, wherein said method comprises: described lubricant is contacted with described composition, and wherein said expanding material is selected from:

A) by general formula R ¹[(OR ²) xOR ³] poly suboxygen alkyl glycol ethers that y represents, wherein: x is the integer of 1-3; Y is the integer of 1-4; R ¹Be selected from hydrogen and the aliphatic hydrocarbyl that contains 1-6 carbon atom and y keyed jointing position; R ²Be selected from the aliphatic alkylene that contains 2-4 carbon atom; R ³Be selected from hydrogen and the aliphatic series and the alicyclic alkyl that contain 1-6 carbon atom; R ¹And R ³In at least one is selected from described alkyl; And wherein said poly suboxygen alkyl glycol ethers has the molecular weight of about 300 atomic mass units of about 100-;

B) by general formula R ¹C (O) NR ²R ³And ring-[R ⁴CON (R ⁵The acid amides of expression)-], wherein R ¹, R ², R ³And R ⁵Be independently selected from the aliphatic series that contains 1-12 carbon atom and alicyclic alkyl and aromatic group that contains 6-12 carbon atom at the most; R ⁴Be selected from the aliphatic alkylene that contains 3-12 carbon atom; And wherein said acid amides has the molecular weight of about 300 atomic mass units of about 100-;

C) by general formula R ¹C (O) R ²The ketone of expression, wherein R ¹And R ²Be independently selected from the aliphatic series that contains 1-12 carbon atom, alicyclic and aryl alkyl, and wherein said ketone has the molecular weight of about 300 atomic mass units of about 70-;

D) by general formula R ¹The nitrile that CN represents, wherein R ¹Be selected from the aliphatic series that contains 5-12 carbon atom, alicyclic or aryl alkyl, and wherein said nitrile has the molecular weight of about 200 atomic mass units of about 90-;

E) hydrochloric ether of representing by general formula R Clx, wherein: x is 1 or 2; R is selected from aliphatic series and the alicyclic alkyl that contains 1-12 carbon atom; And wherein said hydrochloric ether has the molecular weight of about 200 atomic mass units of about 100-;

F) by general formula R ¹OR ²The aryl ethers of expression, wherein: R ¹Be selected from the aryl alkyl that contains 6-12 carbon atom; R ²Be selected from the aliphatic hydrocarbyl that contains 1-4 carbon atom; And wherein said aryl ethers has the molecular weight of about 150 atomic mass units of about 100-;

G) by general formula CF ₃R ¹1,1 of expression, 1-trifluoro alkane, wherein R ¹Be selected from the aliphatic series and the alicyclic alkyl that contain about 15 carbon atoms of about 5-;

H) by general formula R ¹OCF ₂CF ₂The fluoroether that H represents, wherein R ¹Be selected from the aliphatic series and the alicyclic alkyl that contain about 15 carbon atoms of about 5-; Or wherein said fluoroether is derived from fluoroolefins and polyvalent alcohol, and wherein said fluoroolefins has CF ₂=CXY pattern, wherein X is hydrogen, chlorine or fluorine, Y is chlorine, fluorine, CF ₃Or OR _f, R wherein _fBe CF ₃, C ₂F ₅Or C ₃F ₇Has HOCH with described polyvalent alcohol ₂CRR ' (CH ₂) z (CHOH) xCH ₂(CH ₂OH) y pattern, wherein R and R ' are hydrogen, CH ₃Or C ₂H ₅, x is the integer of 0-4, and y is the integer of 0-3, and z is 0 or 1; With

I) lactone of representing by structure [B], [C] and [D]:

Wherein, R ¹-R ⁸Be independently selected from hydrogen, linearity, branching, ring-type, two rings, saturated and undersaturated alkyl; And molecular weight is about 100 to about 300 atomic mass units; With

J) by general formula R ¹CO ₂R ²The ester of expression, wherein R ¹And R ²Be independently selected from linearity and ring-type, saturated and undersaturated, alkyl and aryl; And wherein said ester has from about 80 molecular weight to about 550 atomic mass units.

52. improve to the compressor oil returning method in compression refrigeration, air-conditioning or heat-pump apparatus, described method comprises: the composition that in described equipment, uses claim 31.

53. in the refrigeration lubricant that is selected from mineral oil, alkylbenzene, synthetic paraffin, synthetic naphthenic hydrocarbon and poly-(α) alkene with the method for cooling agent or heat-transfer fluid composition solubilising, wherein said method comprises: described lubricant is contacted with described cooling agent or heat-transfer fluid composition, and wherein said cooling agent or heat-transfer fluid comprise and are selected from following composition:

The approximately about 99wt%HFC-1225ye of 1wt%-and the approximately about 1wt%HFC-152a of 99wt%-;

Approximately the about 99wt%HFC-1225ye of 1wt%-and approximately the about 1wt% of 99wt%-anti--HFC-1234ze;

The approximately about 99wt%HFC-1225ye of 1wt%-and the approximately about 1wt%HFC-1243zf of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-134a of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-152a of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-227ea of 99wt%-; With

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%CF of 99wt%- ₃I; Be selected from wherein said expanding material:

A) by general formula R ¹[(OR ²) xOR ³] poly suboxygen alkyl glycol ethers that y represents, wherein: x is the integer of 1-3; Y is the integer of 1-4; R ¹Be selected from hydrogen and the aliphatic hydrocarbyl that contains 1-6 carbon atom and y keyed jointing position; R ²Be selected from the aliphatic alkylene that contains 2-4 carbon atom; R ³Be selected from hydrogen and the aliphatic series and the alicyclic alkyl that contain 1-6 carbon atom; R ¹And R ³In at least one is selected from described alkyl; And wherein said poly suboxygen alkyl glycol ethers has the molecular weight of about 300 atomic mass units of about 100-;

B) by general formula R ¹C (O) NR ²R ³And ring-[R ⁴CON (R ⁵The acid amides of expression)-], wherein R ¹, R ², R ³And R ⁵Be independently selected from the aliphatic series that contains 1-12 carbon atom and alicyclic alkyl and aromatic group that contains 6-12 carbon atom at the most; R ⁴Be selected from the aliphatic alkylene that contains 3-12 carbon atom; And wherein said acid amides has the molecular weight of about 300 atomic mass units of about 100-;

C) by general formula R ¹C (O) R ²The ketone of expression, wherein R ¹And R ²Be independently selected from the aliphatic series that contains 1-12 carbon atom, alicyclic and aryl alkyl, and wherein said ketone has the molecular weight of about 300 atomic mass units of about 70-;

D) by general formula R ¹The nitrile that CN represents, wherein R ¹Be selected from the aliphatic series that contains 5-12 carbon atom, alicyclic or aryl alkyl, and wherein said nitrile has the molecular weight of about 200 atomic mass units of about 90-;

E) hydrochloric ether of representing by general formula R Clx, wherein: x is 1 or 2; R is selected from aliphatic series and the alicyclic alkyl that contains 1-12 carbon atom; And wherein said hydrochloric ether has the molecular weight of about 200 atomic mass units of about 100-;

F) by general formula R ¹OR ²The aryl ethers of expression, wherein: R ¹Be selected from the aryl alkyl that contains 6-12 carbon atom; R ²Be selected from the aliphatic hydrocarbyl that contains 1-4 carbon atom; And wherein said aryl ethers has the molecular weight of about 150 atomic mass units of about 100-;

G) by general formula CF ₃R ¹1,1 of expression, 1-trifluoro alkane, wherein R ¹Be selected from the aliphatic series and the alicyclic alkyl that contain about 15 carbon atoms of about 5-;

H) by general formula R ¹OCF ₂CF ₂The fluoroether that H represents, wherein R ¹Be selected from the aliphatic series and the alicyclic alkyl that contain about 15 carbon atoms of about 5-; Or wherein said fluoroether is derived from fluoroolefins and polyvalent alcohol, and wherein said fluoroolefins has CF ₂=CXY pattern, wherein X is hydrogen, chlorine or fluorine, Y is chlorine, fluorine, CF ₃Or OR _f, R wherein _fBe CF ₃, C ₂F ₅Or C ₃F ₇Has HOCH with described polyvalent alcohol ₂CRR ' (CH ₂) z (CHOH) xCH ₂(CH ₂OH) y pattern, wherein R and R ' are hydrogen, CH ₃Or C ₂H ₅, x is the integer of 0-4, and y is the integer of 0-3, and z is 0 or 1; With

I) lactone of representing by structure [B], [C] and [D]:

Wherein, R ¹-R ⁸Be independently selected from hydrogen, linearity, branching, ring-type, two rings, saturated and undersaturated alkyl; And molecular weight is about 100 to about 300 atomic mass units; With

J) by general formula R ¹CO ₂R ²The ester of expression, wherein R ¹And R ²Be independently selected from linearity and ring-type, saturated and undersaturated, alkyl and aryl; And wherein said ester has from about 80 molecular weight to about 550 atomic mass units.

54. improve to the compressor oil returning method in compression refrigeration, air-conditioning or heat-pump apparatus, described method comprises: the composition that in described equipment, uses claim 41.

55. substitute the method for high GwP cooling agent in refrigeration, air-conditioning or the heat-pump apparatus, wherein said high GWP cooling agent is selected from R134a, R22, R123, R11, R245fa, R114, R236fa, R124, R12, R410A, R407C, R417A, R422A, R507A, R502 and R404A, and described method comprises: each composition among the claim 1-30 is offered use, is used for or designs described refrigeration, air-conditioning or the heat-pump apparatus that is used for using described high GwP cooling agent.

56. substitute the method for high GWP cooling agent in refrigeration, air-conditioning or the heat-pump apparatus, wherein said high GWP cooling agent is selected from R134a, R22, R123, R11, R245fa, R114, R236fa, R124, R12, R410A, R407C, R417A, R422A, R507A, R502 and R404A, and described method comprises: will be selected from following composition:

The approximately about 99wt%HFC-1225ye of 1wt%-and the approximately about 1wt%HFC-152a of 99wt%-;

The approximately about 99wt%HFC-1225ye of 1wt%-and the approximately about 1wt%HFC-1234yf of 99wt%-;

Approximately the about 99wt%HFC-1225ye of 1wt%-and approximately the about 1wt% of 99wt%-anti--HFC-1234ze;

The approximately about 99wt%HFC-1225ye of 1wt%-and the approximately about 1wt%HFC-1243zf of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-134a of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-152a of 99wt%-;

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%HFC-227ea of 99wt%-; With

Approximately the about 99wt% of 1wt%-anti--HFC-1234ze and the about about 1wt%CF of 99wt%- ₃I;

Offer use, be used for or design the described refrigeration, air-conditioning or the heat-pump apparatus that are used for using described high GWP cooling agent.

57. the composition that uses among the claim 1-30 each is as the heat-transfer fluid method for compositions, described method comprises described composition is transported to scatterer from thermal source.

58. each preparation of compositions method among the claim 1-30, described method comprises:

(i) reclaim a large amount of one or more components of refrigerant compositions from least one cryogen vessel, (ii) impurity is removed to being enough to that the component of described one or more recovery can be re-used, (iii) and randomly, the component of the described yield of all or part is mixed with at least a additional refrigerant compositions or component.

59. refrigeration, air-conditioning or heat-pump apparatus that contains each composition among the claim 1-30,40,41 or 42.

60. refrigeration, air-conditioning or heat-pump apparatus that comprises the claim of motion conditioning unit.

61. the method that early detection cooling agent leaks in refrigeration, air-conditioning or heat-pump apparatus, described method comprises: in described equipment, use non-Azeotrope compositions, and the reduction of monitoring cooling performance.

62. whipping agent that comprises each composition among the claim 1-30.

63. one kind forms the foamy method, comprising:

(a) each composition among the claim 1-30 is added in the foamable composite; With

(b) effectively make this foamable composite reaction under the formation foamy condition.

64. comprise the Sprayable composition of each composition among the claim 1-30.

65. the preparation method of an aerosol product comprises step: each composition among the interpolation claim 1-30 in the activeconstituents in aerosol container, wherein said composition plays the propelling agent effect.

66. the inhibition method of a flame comprises that the fluid of each composition in making this flame and comprising claim 1-30 contacts.

67. put out or suppress the method for fire with the total flooding application mode, comprising:

(a) provide the reagent that comprises each composition among the claim 1-30;

(b) this reagent is arranged in the pressurization blowdown system; With

(c) this reagent is discharged in the zone to put out or to suppress fire in this zone.

68. make regional inerting to prevent the method for fire or blast, comprising:

(a) provide the reagent that comprises each composition among the claim 1-30;

(b) this reagent is arranged in the pressurization blowdown system; With

(c) this reagent is discharged in this zone to prevent that fire or blast from taking place.