CN101283839A - Stink prevention hosiery preparation method - Google Patents
Stink prevention hosiery preparation method Download PDFInfo
- Publication number
- CN101283839A CN101283839A CNA2007100680382A CN200710068038A CN101283839A CN 101283839 A CN101283839 A CN 101283839A CN A2007100680382 A CNA2007100680382 A CN A2007100680382A CN 200710068038 A CN200710068038 A CN 200710068038A CN 101283839 A CN101283839 A CN 101283839A
- Authority
- CN
- China
- Prior art keywords
- preparation
- socks
- stink
- oxygen supply
- stink prevention
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 230000002265 prevention Effects 0.000 title claims description 16
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 21
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 21
- 239000001301 oxygen Substances 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000126 substance Substances 0.000 claims abstract description 9
- 150000001450 anions Chemical class 0.000 claims abstract description 8
- 239000004530 micro-emulsion Substances 0.000 claims abstract description 8
- 239000008367 deionised water Substances 0.000 claims abstract description 5
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 5
- 239000000835 fiber Substances 0.000 claims abstract description 5
- 239000003094 microcapsule Substances 0.000 claims abstract description 5
- 239000007787 solid Substances 0.000 claims abstract description 5
- 239000000725 suspension Substances 0.000 claims abstract description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 15
- 241001148471 unidentified anaerobic bacterium Species 0.000 claims description 9
- 150000002148 esters Chemical class 0.000 claims description 7
- 230000000844 anti-bacterial effect Effects 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 238000009395 breeding Methods 0.000 claims description 5
- 230000001488 breeding effect Effects 0.000 claims description 5
- 238000005516 engineering process Methods 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 239000004743 Polypropylene Substances 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- -1 polypropylene Polymers 0.000 claims description 4
- 229920001155 polypropylene Polymers 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 3
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 3
- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 238000004332 deodorization Methods 0.000 abstract description 8
- 238000000034 method Methods 0.000 abstract description 8
- 239000000203 mixture Substances 0.000 abstract description 4
- 229920000742 Cotton Polymers 0.000 abstract 1
- 239000002781 deodorant agent Substances 0.000 abstract 1
- 238000000643 oven drying Methods 0.000 abstract 1
- 229920000058 polyacrylate Polymers 0.000 abstract 1
- 229920001296 polysiloxane Polymers 0.000 abstract 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 9
- 239000003205 fragrance Substances 0.000 description 8
- 238000005406 washing Methods 0.000 description 7
- 210000001124 body fluid Anatomy 0.000 description 5
- 239000010839 body fluid Substances 0.000 description 5
- 125000003118 aryl group Chemical group 0.000 description 4
- 239000002775 capsule Substances 0.000 description 4
- 239000005416 organic matter Substances 0.000 description 4
- 238000007598 dipping method Methods 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 241001647745 Banksia Species 0.000 description 2
- 241000220317 Rosa Species 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 230000002421 anti-septic effect Effects 0.000 description 2
- 229940088710 antibiotic agent Drugs 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 2
- 239000012634 fragment Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 235000015097 nutrients Nutrition 0.000 description 2
- 230000027272 reproductive process Effects 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000004599 antimicrobial Substances 0.000 description 1
- 229940064004 antiseptic throat preparations Drugs 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 210000004013 groin Anatomy 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 235000019615 sensations Nutrition 0.000 description 1
Abstract
The invention discloses method for preparing deodorant socks. In the method, a chemical mixture solution is adopted, which can be condensed on the fiber surface to form a network to continuously generate oxygen supply anions under a wearing condition, thus providing abundant oxygen source for the small neighboring environment, effectively suppressing propagation of anaerobe and preventing the generation of stink. The mixture solution comprises water-based silicone sol (containing silicon hydroxide 20%) 5 to 30 g/L; specially made polyacrylate microemulsion (solid content 30%) 50 to 70 g/L; specially made cologne or other proper essence microcapsule suspension (containing 20%) 5 to 30 g/L; and deionized water added to 1 L. The preparation method comprises following steps: preparing the mixture solution according to the above formula, processing cotton socks, dewatering to achieve pickup ratio 80%, and oven-drying at 100 DEG C for 3 to 4 min. The processed socks have pleasant fragrant smell, and have about 4,000 to 5,000 oxygen supply anions per cm<3>. The method is suitable for deodorization processing of various socks or for underwear.
Description
Technical field
The invention belongs to the light industry field, relate to a kind of stink prevention hosiery, especially relate to a kind of preparation method of the novel stink prevention hosiery based on oxygen enrichment mechanism.
Background technology
Socks are people's daily living articles, but, people are in wearing the process of socks, can make pin and socks produce stink, the basic reason that produces foul smell, stink is to decompose organic matter in the body fluid in the anaerobic bacteria reproductive process, anaerobic bacteria is a nutrient source with the organic matter in the body fluid, and breeding in a large number decomposites organic substance in organic amine, aldehyde, the sulfide with foul odour under oxygen free condition.For example armpit, groin and the foot at human body all is that air is difficult for the position that circulation lacks oxygen, these local anoxics, humidity, abundant body fluid are assembled and higher conditions such as temperature are just meeting the active condition of breeding of anaerobic bacteria, also are the places of the easiest generation foul smell flavor.So, raising along with people's quality of life, requirement to socks is also more and more higher, present popular on the market stink prevention hosiery, odor-resistant result is undesirable, its major defect is: most of stink prevention hosieries all are to work by all antiseptics, as cationic antibacterial agent, heavy metal antiseptic and other antibacterials commonly used are combined on the hosiery fabric with method chemistry or physics, reach the purpose of antibacterial deodourizing with its drug effect.These antibacterials commonly used all have bio-toxicity, have the hidden danger that influence the health aspect, a bit outside, the washing fastness of this class stink prevention hosiery is often not good yet, antibacterial effect is also undesirable.
Summary of the invention
The objective of the invention is at the existing defective of above-mentioned stink prevention hosiery, a kind of preparation method of the novel stink prevention hosiery based on oxygen enrichment mechanism is provided.
In order to achieve the above object, the present invention has mainly adopted following technical scheme to realize.
Principle of the present invention is:
Because it is to decompose organic matter in the body fluid in the anaerobic bacteria reproductive process that people's pin and socks produce the basic reason of foul smell, stink, anaerobic bacteria is a nutrient source with the organic matter in the body fluid, breeding in a large number decomposites organic substance in organic amine, aldehyde, the sulfide with foul odour under oxygen free condition.So, the present invention is directed to These characteristics, handle hosiery with a kind of predetermined substance of sufficient oxygen source that can provide, make it to be incorporated into securely on the processed fabric, can anaerobic bacteria can not be bred smoothly, thereby reach the effect of deodorization safe and harmlessly often for sufficient oxygen source closely is provided in week.
Technical scheme of the present invention:
The used special chemical article of the present invention is a kind of mixed liquor, but not antibacterial material, can form a kind of network in the fiber surface condensation, it combines with fiber is close, rub resistance, wash resistant can constantly produce the oxygen supply anion under the condition of wearing, thereby provide abundant oxygen source for nearly all subenvironments, suppress the breeding of anaerobic bacteria effectively, avoid the generation of foul odour.Specifically, this class chemical substance is to contain many hydroxyizations silicon, titanium, or mixes the hydrosol that trace rare-earth element is arranged, and its consumption is 0.8-2%, renders a service inadequately in the time of very little, and then cost is too high too much.
Simultaneously; also selected a kind of certain hydrophilic film forming polymer that has for use, the flexible film that it forms can be protected above-mentioned network film effectively, just in case above-mentioned network film is subjected to the accidental mechanical effect and comes off; the fragment that then comes off can be aggregated the thing film and fix, and unlikelyly flies in the air and loses its effectiveness.Simultaneously, this film forming matter also has the effect that strengthens generation oxygen supply ion, specifically, it is a kind of flexibility polyacrylic ester microemulsion that does not contain formaldehyde, need not bake, contain more hydrophilic radical, its consumption is 1-10%, water-fastly in the time of very little washes not by force, can influence feel when too many.
In order to give the fragranced of stink prevention hosiery with necessity, increase wearer's joyful sense, the present invention has also selected special small fragrant capsule for use, and contained fragrance kind can be the fragrance of a flower, the banksia rose, fruital or other suitable odor types.Because the existence of film forming polymer, fragrance has certain washing resistance performance.Specifically, be the tiny capsules that contains certain aromatic substance, the average diameter of capsule is below 0.5 μ m.Diameter is crossed greatly and glow the lime look on dark socks material, and its consumption is 0.1-2%.Then fragrance is light excessively very little for consumption, and then fragrance is too dense too much, gives the offending sensation of people.
The prescription of mixed liquor of the present invention and every liter component are:
Water base Ludox (containing tetrahydrochysene silica 20%) 5-30 grams per liter
Handtailor polypropylene acid esters microemulsion (solid content 30%) 50-70 grams per liter
The imperial essence of special Gu or other suitable essence microcapsule suspension (containing 20%) 5-30 grams per liters
Deionized water adds to 1 liter
Preparation technology of the present invention is:
Make mixed liquor by above-mentioned prescription and handle quilted stockings (dipping or spray method all can), dewater to liquid carrying rate about 80%, 100 ℃ of oven dry 3-4 minute, socks have happy aromatic odor, the oxygen supply anion is about 4000-5000/cm3, have tangible odor-resistant result, still have tangible odor-resistant result through 5 washings.
The present invention compared with prior art has following tangible advantage and innovation.(1) prescription and preparation technology are scientific and reasonable.The present invention adopts a kind of water base Ludox (containing tetrahydrochysene silica 20%) of sufficient oxygen source or the titanium hydrosol, handtailor polypropylene acid esters microemulsion (solid content 30%), the imperial essence of special Gu or other suitable essence microcapsule suspensions (containing 20%) of providing to handle quilted stockings for the specific blend liquid of raw material, anaerobic bacteria can not be bred smoothly, thereby reach the effect of deodorization safe and harmlessly.(2) odor-resistant result is good.Experiment showed, that stink prevention hosiery of the present invention has tangible deodorization effect and good washing resistance performance, and do not have the worry of the side effect of anti-microbial type medicine.(3) pollution-free.The present invention has also selected a kind of certain hydrophilic film forming polymer that has for use; the flexible film that it forms is the protecting network film effectively; just in case the network film is subjected to the accidental mechanical effect and comes off,, unlikelyly fly in the air and lose its effectiveness then the fragment that comes off can be aggregated the thing film and fix.Simultaneously, this film forming matter also has the effect that strengthens generation oxygen supply ion, specifically, is a kind of flexibility polyacrylic ester microemulsion that does not contain formaldehyde, need not bake, contain more hydrophilic radical, and its consumption is 1-10%.(4) the present invention increases wearer's joyful sense in order to give the fragranced of stink prevention hosiery with necessity, has also selected special small fragrant capsule for use, and contained fragrance kind can be the fragrance of a flower, the banksia rose, fruital or other suitable odor types.Because the existence of film forming polymer, fragrance has certain washing resistance performance.
The present invention is applicable to the deodorization processing of various socks, and the deodorization that also can be used for underwear, underpants is handled.
The specific embodiment
The actual effect that the following examples can illustrate, but do not limit the scope of the invention.
Embodiment 1
Treatment fluid is grouped into by following one-tenth:
Water base Ludox (containing tetrahydrochysene silica 20%) 10 grams per liters
Handtailor polypropylene acid esters microemulsion (solid content 30%) 60 grams per liters
The imperial essence microcapsule suspension of special Gu (containing 20%) 10 grams per liters
Deionized water adds to 1 liter
Preparation technology of the present invention is:
Make mixed liquor by above-mentioned prescription and handle quilted stockings (dipping or spray method all can), dewater to liquid carrying rate about 80%, 100 ℃ of oven dry 3-4 minute, socks had happy aromatic odor, and the oxygen supply anion is about 4000-5000/cm3.Have tangible odor-resistant result, still have tangible odor-resistant result through 5 washings.
Embodiment 2
Treatment fluid is grouped into by following one-tenth:
Water base Ludox (containing tetrahydrochysene silica 20%) 10 grams per liters
Deionized water adds to 1 liter
With above-mentioned liquid handling quilted stockings (dipping or spray method all can), dewater to liquid carrying rate about 80%, 100 ℃ of oven dry 3-4 minute, socks had happy aromatic odor, and the oxygen supply anion is about 4000/cm3.Have tangible odor-resistant result, still have tangible odor-resistant result through 5 washings.
The present invention is applicable to the deodorization processing of various socks, and the deodorization that also can be used for underwear, underpants is handled.
Claims (4)
1, a kind of preparation method of stink prevention hosiery, it is characterized in that used special chemical article is a kind of mixed liquor, but not antibacterial material, can form a kind of network in the fiber surface condensation, it combines with fiber is close, rub resistance, wash resistant, under the condition of wearing, can constantly produce the oxygen supply anion, thereby for nearly all subenvironments provide abundant oxygen source, suppress the breeding of anaerobic bacteria effectively, avoid the generation of foul odour.Specifically, this class chemical substance is to contain many hydroxyizations silicon, titanium, or mixes the hydrosol that trace rare-earth element is arranged.
2, the preparation method of stink prevention hosiery according to claim 1, it is characterized in that also having selected for use a kind of certain hydrophilic film forming polymer that has, specifically, be a kind of flexibility polyacrylic ester microemulsion that does not contain formaldehyde, need not bake, contain more hydrophilic radical.
3, the preparation method of stink prevention hosiery according to claim 1 is characterized in that the prescription of mixed liquor of the present invention and every liter component are: water base Ludox (containing tetrahydrochysene silica 20%) or titanium hydrosol 5-30 grams per liter; Handtailor polypropylene acid esters microemulsion (solid content 30%) 50-70 grams per liter; The imperial essence of special Gu or other suitable essence microcapsule suspension (containing 20%) 5-30 grams per liters; Deionized water adds to 1 liter
4, the preparation method of stink prevention hosiery according to claim 1, it is characterized in that preparation technology of the present invention is: make mixed liquor by above-mentioned prescription and handle quilted stockings, dewater to liquid carrying rate about 80%, 100 ℃ of oven dry 3-4 minute, the oxygen supply anion was 4000-5000/cm
3About.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007100680382A CN101283839B (en) | 2007-04-13 | 2007-04-13 | Stink prevention hosiery preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007100680382A CN101283839B (en) | 2007-04-13 | 2007-04-13 | Stink prevention hosiery preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101283839A true CN101283839A (en) | 2008-10-15 |
| CN101283839B CN101283839B (en) | 2011-02-16 |
Family
ID=40056418
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007100680382A Expired - Fee Related CN101283839B (en) | 2007-04-13 | 2007-04-13 | Stink prevention hosiery preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101283839B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101403182B (en) * | 2008-11-06 | 2011-09-14 | 吴张江 | Skin-protection health-care fabric functional finishing agent and use thereof |
| CN103437159A (en) * | 2013-08-02 | 2013-12-11 | 吴江市七都镇庙港雅迪针织制衣厂 | Woolen sweater treatment fluid containing calcium carbonate |
| CN105155088A (en) * | 2015-08-18 | 2015-12-16 | 桐乡市瑞泰纺织有限公司 | Multifunctional environment-friendly cloth preparation method |
| CN106498602A (en) * | 2016-08-31 | 2017-03-15 | 诸暨市欧美特袜业有限公司 | A kind of production technology of stink prevention hosiery |
| CN107604651A (en) * | 2017-09-22 | 2018-01-19 | 南通优棉濠晨纺织品有限公司 | A kind of negative ion health fabric and its soaking agent and application |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61138776A (en) * | 1984-12-07 | 1986-06-26 | 第一工業製薬株式会社 | Production of moisture permeable and water-proof coated cloth |
| CN1757444A (en) * | 2004-10-08 | 2006-04-12 | 香港理工大学 | Method for forming coating of titanium dioxide on article surface |
| CN1632215A (en) * | 2004-11-03 | 2005-06-29 | 东华大学 | Sol-gel dressed nonwoven fabrics for generating negative ions, process for preparing same and use thereof |
| CN2872888Y (en) * | 2005-11-09 | 2007-02-28 | 泉耀新材料科技（上海）有限公司 | Bacteria controlling deodorizing mask |
-
2007
- 2007-04-13 CN CN2007100680382A patent/CN101283839B/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101403182B (en) * | 2008-11-06 | 2011-09-14 | 吴张江 | Skin-protection health-care fabric functional finishing agent and use thereof |
| CN103437159A (en) * | 2013-08-02 | 2013-12-11 | 吴江市七都镇庙港雅迪针织制衣厂 | Woolen sweater treatment fluid containing calcium carbonate |
| CN105155088A (en) * | 2015-08-18 | 2015-12-16 | 桐乡市瑞泰纺织有限公司 | Multifunctional environment-friendly cloth preparation method |
| CN106498602A (en) * | 2016-08-31 | 2017-03-15 | 诸暨市欧美特袜业有限公司 | A kind of production technology of stink prevention hosiery |
| CN107604651A (en) * | 2017-09-22 | 2018-01-19 | 南通优棉濠晨纺织品有限公司 | A kind of negative ion health fabric and its soaking agent and application |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101283839B (en) | 2011-02-16 |
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Granted publication date: 20110216 |