CN101280154B - Ultraviolet curing vacuum metallizing coating - Google Patents
Ultraviolet curing vacuum metallizing coating Download PDFInfo
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- CN101280154B CN101280154B CN2007100391791A CN200710039179A CN101280154B CN 101280154 B CN101280154 B CN 101280154B CN 2007100391791 A CN2007100391791 A CN 2007100391791A CN 200710039179 A CN200710039179 A CN 200710039179A CN 101280154 B CN101280154 B CN 101280154B
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Abstract
The invention provides ultraviolet curing vacuum plating coating which includes ultraviolet curing vacuum plating primer and ultraviolet curing vacuum plating surface coating; the ultraviolet curing vacuum plating primer part by weight comprises 5-70 portions of urethane acrylate resin, 10-80 portions of acrylate monomer, 2-10 portions of light initiator, 0.05-10 portions of leveling agent, 0.5-20 portions of other auxiliary agents; the ultraviolet curing vacuum plating surface coating part by weight comprises 0.5-50 portions of urethane acrylate resin, 5-40 portions of epoxy acrylic resin, 20-40 portions of butyl acetate, 10-30 portions of cyclohexanone, 5-20 portions of ethanol, 0.3-6 portions of adhesion promoter and 0.5-15 portions of light initiator. The ultraviolet curing vacuum plating coating in the invention has the advantages of high heat resistance, good adhesive force and good weatherability.
Description
Technical field
The present invention relates to paint field, more specifically, relate to the ultraviolet curing coating field, be meant a kind of ultraviolet curing vacuum metallizing coating and preparation method thereof especially.
Background technology
At present, the ultraviolet-curing vacuum coating coating technology has ubiquity with urethane acrylate as the matrix resin of base paint formulation, and its effect mainly provides the good kindliness of cured film and certain adhesive power; Usually also add epoxy acrylate so that hardness, fast setting performance and good adhesion property to be provided, but its too high fragility has limited its consumption in prescription again, so its consumption can not be too high; Because the monomeric vacuum volatilization character of single functionality can not transform again in system fully in addition, therefore the consumption of single functionality reactive thinner can not be too high in the prescription, and this causes dope viscosity excessive, uses inconvenient.
At home, Gong Jianzhong (Shanghai coating, the 1st phase of calendar year 2001 page 3) has reported the development of relevant vacuum plating ultraviolet curing coating, and advantage is that production process is simple, uses technology efficient, energy-conservation.Hunan Yada Chemical Building Material Co., Ltd also applied for the patent (number of patent application: 99115485.1) of vacuum plating ultraviolet curing coating, this patent has been described at the bottom of a kind of ultraviolet-curing vacuum coating, finish paint, priming paint is by acrylic acid modified bisphenol A epoxide resin, polyvalent alcohol and Hydroxyethyl acrylate and toluene two different hydrogen acid ether affixtures, reactive diluent, light trigger, auxiliary agent is formed, finish paint is by polyester acrylate, the phenolic aldehyde epoxy acrylate, reactive thinner, light trigger, adhesion promoter, auxiliary agent is formed, all by after certain weight percent proportioning, mixing and stirring makes above-mentioned composition.
Shortcomings such as but the vacuum plating ultraviolet curing coating that obtains generally speaking, and thermotolerance is not high, and sticking power is bad, and weathering resistance is bad.
Summary of the invention
Main purpose of the present invention is exactly the problems and shortcomings at above existence, and a kind of ultraviolet curing vacuum metallizing coating is provided, this coating thermotolerance height, and sticking power is good, good weatherability.
To achieve these goals, the technical scheme of employing of the present invention is: a kind of ultraviolet curing vacuum metallizing coating, comprise ultraviolet curing vacuum metallizing base paint and ultraviolet curing vacuum metallizing coating materials, be characterized in, described ultraviolet curing vacuum metallizing base paint comprises polyurethane acrylate resin, acrylate monomer, light trigger, flow agent and other auxiliary agent; Described ultraviolet curing vacuum metallizing coating materials comprises polyurethane acrylate resin, epoxy acrylic resin, N-BUTYL ACETATE, pimelinketone, ethanol, adhesion promoter and light trigger.
In the described ultraviolet curing vacuum metallizing base paint:
Described polyurethane acrylate resin 5～70 weight parts,
Described acrylate monomer 10～80 weight parts,
Described light trigger 2～10 weight parts,
Described flow agent 0.05～10 weight part,
Described other auxiliary agent 0.5～20 weight part;
In the described ultraviolet curing vacuum metallizing coating materials:
Described polyurethane acrylate resin 0.5～50 weight part,
Described epoxy acrylic resin 5～40 weight parts,
Described N-BUTYL ACETATE 20～40 weight parts,
Described pimelinketone 10～30 weight parts,
Described ethanol 5～20 weight parts,
Described adhesion promoter 0.3～6 weight part,
Described light trigger 0.5～15 weight part.
Described ultraviolet curing vacuum metallizing base paint also comprises the phenol aldehyde modified acrylate of 0～50 weight part, 0～60 weight part N-BUTYL ACETATE and 0～30 parts by weight of ethanol; Described ultraviolet curing vacuum metallizing coating materials also comprises the phenol aldehyde modified acrylate of 0～25 weight part, 0～25 parts by weight of acrylic acid ester monomer, 0～4.5 weight part defoamer, other auxiliary agent of 0～15 weight part.
Described acrylate monomer is with the various monomers based on acrylate after group modified.
A kind of method for preparing above-mentioned ultraviolet curing vacuum metallizing coating, described ultraviolet curing vacuum metallizing coating makes by even stirring, needs to filter before packing, and the filtration diameter of filter bag is less than 1 μ m, want lucifuge, heat after the packing, and prevent sharp impacts.
Beneficial effect of the present invention is as follows:
1. containing benezene solvent not in the prescription of the present invention, selected solvent relative environmental protection.
2. ultraviolet curing vacuum metallizing base paint of the present invention, polyurethane acrylate resin and acrylate diluting monomer have been optimized, also composite phenol aldehyde modified acrylate, improved adhesion property, made the product innovation of exploitation have higher resistance toheat and better weather resistance energy low surface tension substrate.
3. ultraviolet curing vacuum metallizing coating materials of the present invention, optimized polyurethane acrylate resin, epoxy acrylic resin and acrylate diluting monomer, also composite phenol aldehyde modified acrylate, with compound a small amount of adhesion promoter, improved adhesion property, made the product innovation of exploitation not only have higher resistance toheat and better weather resistance energy, also multiple base material has been had suitability low surface tension substrate.
Embodiment
Being used for polyurethane acrylate resin of the present invention and epoxy acrylic resin can directly buy, and used in the specific embodiment is that Belgian UCB. S.A. (BE) Bruxelles Belgium produces.Being used for phenol aldehyde modified acrylate of the present invention is to make or bought with ordinary method.
Be used for acrylate monomer of the present invention with various monomers after group modified based on acrylate, it can be the three-functionality-degree acrylate, as pentaerythritol triacrylate (PETA), Viscoat 295 (TMPTA), also can be two palace energy degree acrylate, as tri (propylene glycol) diacrylate (TPGDA), it can also be the single functionality acrylate, as Hydroxyethyl acrylate (HEA), butyl acrylate, vinylformic acid 2 one 2 basic ethyl esters, or their mixture, its main action-reaction thinner is a kind of reactive thinner.
Be used for the light trigger that light trigger of the present invention is a free radical, be selected from and adopt present technique field well-known a-hydroxyl ketone, as 1173, it mainly acts on and is subjected to produce free radical after the UV-irradiation and causes resin, monomeric crosslinking reaction.
Be used for flow agent of the present invention by reducing the additive that coating surface tension force reaches the levelling effect, can be selected from BYK, TEGO, it is wetting that it mainly acts on levelling.
Be used for the multiple few additive of addition that satisfies various objectives of other auxiliary agents of the present invention, mostly be compound, provided after compound by supplier's polycomponent, mainly be selected from modest, the TEGO of moral, it mainly acts on scratch resistance, increases cunning.
Be used for adhesion promoter of the present invention and select the vinylformic acid phosphoric acid ester for use, be mainly used in promotion and improve coating substrate surface sticking power.
Being used for defoamer of the present invention is the additive of eliminating the bubble that produces at production and construction coating, mainly is selected from BYK, TEGO, and it mainly acts on eliminates the bubble that produces in production, the construction.
Thereby being used for N-BUTYL ACETATE of the present invention, pure and mild ketone mainly plays diluting effect and produces certain volatilization gradient and guarantee the levelling effect.
Because ultraviolet curing vacuum metallizing coating of the present invention comprises ultraviolet curing vacuum metallizing base paint and ultraviolet curing vacuum metallizing coating materials, so need prepare ultraviolet curing vacuum metallizing base paint and ultraviolet curing vacuum metallizing coating materials respectively, when preparation ultraviolet curing vacuum metallizing base paint, choose a certain amount of above-mentioned polyurethane acrylate resin, acrylate monomer, light trigger, flow agent and other auxiliary agent, said components is mixed back lucifuge stirring and evenly mixing make the ultraviolet curing vacuum metallizing base paint, need to filter before packing, the filtration diameter of filter bag is less than 1 μ.Want lucifuge, heat after the packing, and prevent sharp impacts.
Preferable, above-mentioned each components contents of choosing is: the polyurethane acrylate resin of 5～70 weight parts, 10～80 parts by weight of acrylic ester monomer, the light trigger of 2～10 weight parts, 0.05 the flow agent of～10 weight parts, other auxiliary agent of 0.5～20 weight part.
In said components, can also add the phenol aldehyde modified acrylate of 0～50 weight part, 0～60 weight part N-BUTYL ACETATE, 0～30 parts by weight of ethanol, the performance of the ultraviolet curing vacuum metallizing base paint that obtains with further optimization.
When preparation ultraviolet curing vacuum metallizing coating materials, choose a certain amount of above-mentioned polyurethane acrylate resin, epoxy acrylic resin, N-BUTYL ACETATE, pimelinketone, ethanol, adhesion promoter and light trigger, said components is mixed back lucifuge stirring and evenly mixing make the ultraviolet curing vacuum metallizing coating materials, need to filter before packing, the filtration diameter of filter bag is less than 1 μ.Want lucifuge, heat after the packing, and prevent sharp impacts.
Preferable, above-mentioned each components contents of choosing: the polyurethane acrylate resin of 0.5～50 weight part, the epoxy acrylic resin of 5～40 weight parts, the N-BUTYL ACETATE of 20～40 weight parts, the pimelinketone of 10～30 weight parts, the ethanol of 5～20 weight parts, the adhesion promoter of 0.3～6 weight part, the light trigger of 0.5～15 weight part.
In said components, can also add the phenol aldehyde modified acrylate of 0～25 weight part, 0～25 parts by weight of acrylic acid ester monomer, 0～4.5 weight part defoamer, other auxiliary agent of 0～15 weight part, the performance of the ultraviolet curing vacuum metallizing coating materials that obtains with further optimization.
By the ultraviolet curing vacuum metallizing coating that aforesaid method obtains, its ultraviolet curing vacuum metallizing base paint and ultraviolet curing vacuum metallizing coating materials performance are as follows:
Ultraviolet curing vacuum metallizing base paint performance is as follows:
The light yellow transparent liquid of outward appearance
23 ± 0.5 ℃ of viscosity are coated with 4 glasss of 7-35 seconds
Solids content 25-100%
Thermotolerance 〉=70 ℃
With base material sticking power (cross-hatching) 100/100
Weathering resistance: salt spray resistance (3%NaCl) was greater than 24 hours
Anti-ethanol was greater than 1 hour
Anti-gasoline was greater than 30 minutes
Shelf lives 〉=6 month
Ultraviolet curing vacuum metallizing coating materials performance is as follows:
The light yellow transparent liquid of outward appearance
23 ± 0.5 ℃ of viscosity are coated with 4# cup 8-25 second
Solids content 15-85%
Pencil hardness 〉=2H (Mitsubishi's pencil)
With aluminium lamination sticking power (cross-hatching) 100/100
Glossiness (%, 60 ° of reflection angle) 〉=95
Weathering resistance: salt spray resistance (3%NaCl) was greater than 24 hours
Anti-ethanol was greater than 1 hour
Anti-gasoline was greater than 30 minutes
Shelf lives 〉=6 month
During the plastic wrapping product vacuum plating that utilizes the ultraviolet curing vacuum metallizing coating of aforesaid method production to can be used for plastic casing, the makeup of electronic product is produced, as the plastic wrapping product vacuum plating production of makeup.At first the ultraviolet curing vacuum metallizing base paint is plated the plastic wrapping product and forms priming paint, after the ultraviolet curing vacuum metallizing coating materials is plated the formation finish paint.Product sticking power behind the vacuum plating is good, fullness ratio good, heat resistance is good.
Be described further below in conjunction with specific embodiment.
Embodiment 1
1. prepare the ultraviolet curing vacuum metallizing base paint
Under normal temperature and normal pressure, the lucifuge stirring and evenly mixing was made the ultraviolet curing vacuum metallizing base paint after specified each component was mixed components such as polyurethane acrylate resin, acrylate monomer, light trigger, flow agent, other auxiliary agent in the according to the form below 1 respectively.Wherein light trigger is 1173.
2. prepare the ultraviolet curing vacuum metallizing coating materials
Under normal temperature and normal pressure, the lucifuge stirring and evenly mixing was made the ultraviolet curing vacuum metallizing coating materials after specified each component was mixed components such as polyurethane acrylate resin, epoxy acrylic resin, N-BUTYL ACETATE, pimelinketone, ethanol, adhesion promoter, light trigger in the according to the form below 1 respectively.Wherein light trigger is 1173.
3. performance test
Performance test methods and the results are shown in following table 2.
Embodiment 2
1. prepare the ultraviolet curing vacuum metallizing base paint
Under normal temperature and normal pressure, specified each component in the following table 1 is mixed back lucifuge stirring and evenly mixing make the ultraviolet curing vacuum metallizing base paint.Wherein light trigger is 1173.
2. prepare the ultraviolet curing vacuum metallizing coating materials
Under normal temperature and normal pressure, specified each component in the following table 1 is mixed back lucifuge stirring and evenly mixing make the ultraviolet curing vacuum metallizing coating materials.Wherein light trigger is 1173.
3. performance test
Performance test methods and the results are shown in following table 2.
Embodiment 3
1. prepare the ultraviolet curing vacuum metallizing base paint
Under normal temperature and normal pressure, specified each component in the following table 1 is mixed back lucifuge stirring and evenly mixing make the ultraviolet curing vacuum metallizing base paint.Wherein light trigger is 1173.
2. prepare the ultraviolet curing vacuum metallizing coating materials
Under normal temperature and normal pressure, specified each component in the following table 1 is mixed back lucifuge stirring and evenly mixing make the ultraviolet curing vacuum metallizing coating materials.Wherein light trigger is 1173.
3. performance test
Performance test methods and the results are shown in following table 2.
Embodiment 4
1. prepare the ultraviolet curing vacuum metallizing base paint
Under normal temperature and normal pressure, specified each component in the following table 1 is mixed back lucifuge stirring and evenly mixing make the ultraviolet curing vacuum metallizing base paint.Wherein light trigger is 1173.
2. prepare the ultraviolet curing vacuum metallizing coating materials
Under normal temperature and normal pressure, specified each component in the following table 1 is mixed back lucifuge stirring and evenly mixing make the ultraviolet curing vacuum metallizing coating materials.Wherein light trigger is 1173.
3. performance test
Performance test methods and the results are shown in following table 2.
Comparative Examples 1
1. prepare the ultraviolet curing vacuum metallizing base paint
Under normal temperature and normal pressure, specified each component in the following table 1 is mixed back lucifuge stirring and evenly mixing make the ultraviolet curing vacuum metallizing base paint.Wherein light trigger is 1173.
2. prepare the ultraviolet curing vacuum metallizing coating materials
Under normal temperature and normal pressure, specified each component in the following table 1 is mixed back lucifuge stirring and evenly mixing make the ultraviolet curing vacuum metallizing coating materials.Wherein light trigger is 1173.
3. performance test
Performance test methods and the results are shown in following table 2.
Comparative Examples 2
1. prepare the ultraviolet curing vacuum metallizing base paint
Under normal temperature and normal pressure, specified each component in the following table 1 is mixed back lucifuge stirring and evenly mixing make the ultraviolet curing vacuum metallizing base paint.Wherein light trigger is 1173.
2. prepare the ultraviolet curing vacuum metallizing coating materials
Under normal temperature and normal pressure, specified each component in the following table 1 is mixed back lucifuge stirring and evenly mixing make the ultraviolet curing vacuum metallizing coating materials.Wherein light trigger is 1173.
3. performance test
Performance test methods and the results are shown in following table 2.
Comparative Examples 3
1. prepare the ultraviolet curing vacuum metallizing base paint
Under normal temperature and normal pressure, specified each component in the following table 1 is mixed back lucifuge stirring and evenly mixing make the ultraviolet curing vacuum metallizing base paint.Wherein light trigger is 1173.
2. prepare the ultraviolet curing vacuum metallizing coating materials
Under normal temperature and normal pressure, specified each component in the following table 1 is mixed back lucifuge stirring and evenly mixing make the ultraviolet curing vacuum metallizing coating materials.Wherein light trigger is 1173.
3. performance test
Performance test methods and the results are shown in following table 2.
Comparative Examples 4
1. prepare the ultraviolet curing vacuum metallizing base paint
Under normal temperature and normal pressure, specified each component in the following table 1 is mixed back lucifuge stirring and evenly mixing make the ultraviolet curing vacuum metallizing base paint.Wherein light trigger is 1173.
2. prepare the ultraviolet curing vacuum metallizing coating materials
Under normal temperature and normal pressure, specified each component in the following table 1 is mixed back lucifuge stirring and evenly mixing make the ultraviolet curing vacuum metallizing coating materials.Wherein light trigger is 1173.
3. performance test
Performance test methods and the results are shown in following table 2.
The prescription of associative list 1, the test data explanation of the viscosity of the ultraviolet curing vacuum metallizing coating of each embodiment and Comparative Examples, thermotolerance, sticking power and weathering resistance in the following table 2, no matter on single performance, still on over-all properties, coating composition of the present invention all significantly is better than the coating composition of Comparative Examples.
The ultraviolet curing vacuum metallizing coating that utilizes the foregoing description prescription to be produced is used for the plastic wrapping product vacuum plating production of makeup, its workflow is: workpiece surface pre-treatment → spraying: UV primary coat → IR levelling → UV solidifies → vacuum aluminum-coated → spraying: the UV face is coated with → IR levelling → UV curing → check warehouse-in, and the product sticking power behind the vacuum plating is good, fullness ratio good, heat resistance is good.Specific performance such as following table 3.
The prescription of associative list 1, in the following table 3 hardness of the outward appearance of the product of the ultraviolet curing vacuum metallizing coating vacuum plating of each embodiment and Comparative Examples, finish paint and adhere to, the test data explanation of the adhering to of priming paint, viscosity and weathering resistance, no matter on single performance, still on over-all properties, the product of coating composition vacuum plating of the present invention all significantly is better than the product of the coating composition vacuum plating of Comparative Examples.
In sum, base paint of the present invention is to multiple base material, comprises difficult sticking polypropylene material, and it is good to have sticking power, good leveling property and fullness ratio height, the characteristic that oil-proofness is strong; Coating materials has the gloss height, hardness height, the heat-resisting and good characteristics of wear resistance, selected solvent relative environmental protection.
Need to prove, all quote in this application as a reference, just quoted as a reference separately as each piece document at all documents that the present invention mentions.Should understand in addition, above-described is specific embodiments of the invention and the know-why used, after having read above-mentioned teachings of the present invention, those skilled in the art can make various changes or modifications and not deviate from spirit of the present invention and scope the present invention, and these equivalent form of values fall within the scope of the invention equally.
Claims (4)
1. ultraviolet curing vacuum metallizing coating, comprise ultraviolet curing vacuum metallizing base paint and ultraviolet curing vacuum metallizing coating materials, it is characterized in that, described ultraviolet curing vacuum metallizing base paint comprises polyurethane acrylate resin, acrylate monomer, light trigger, flow agent and other auxiliary agent; Described ultraviolet curing vacuum metallizing coating materials comprises polyurethane acrylate resin, epoxy acrylic resin, and N-BUTYL ACETATE, pimelinketone, ethanol, adhesion promoter and light trigger, each component concentration is in the described ultraviolet curing vacuum metallizing base paint:
Described polyurethane acrylate resin 5～70 weight parts,
Described acrylate monomer 10～80 weight parts,
Described light trigger 2～10 weight parts,
Described flow agent 0.05～10 weight part,
Described other auxiliary agent 0.5～20 weight part;
Each component concentration is in the described ultraviolet curing vacuum metallizing coating materials:
Described polyurethane acrylate resin 0.5～50 weight part,
Described epoxy acrylic resin 5～40 weight parts,
Described N-BUTYL ACETATE 20～40 weight parts,
Described pimelinketone 10～30 weight parts,
Described ethanol 5～20 weight parts,
Described adhesion promoter 0.3～6 weight part,
Described light trigger 0.5～15 weight part.
2. ultraviolet curing vacuum metallizing coating as claimed in claim 1 is characterized in that, described ultraviolet curing vacuum metallizing base paint also comprises the phenol aldehyde modified acrylate of 0～50 weight part, 0～60 weight part N-BUTYL ACETATE and 0～30 parts by weight of ethanol; Described ultraviolet curing vacuum metallizing coating materials also comprises the phenol aldehyde modified acrylate of 0～25 weight part, 0～25 parts by weight of acrylic acid ester monomer, 0～4.5 weight part defoamer, other auxiliary agent of 0～15 weight part.
3. ultraviolet curing vacuum metallizing coating as claimed in claim 1 is characterized in that, described acrylate monomer is with the various monomers based on acrylate after group modified.
4. method for preparing ultraviolet curing vacuum metallizing coating as claimed in claim 1, it is characterized in that, described ultraviolet curing vacuum metallizing coating makes by even stirring, before packing, need to filter, the filtration diameter of filter bag is less than 1 μ m, want lucifuge, heat after the packing, and prevent sharp impacts.
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| CN2007100391791A CN101280154B (en) | 2007-04-06 | 2007-04-06 | Ultraviolet curing vacuum metallizing coating |
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| CN2007100391791A CN101280154B (en) | 2007-04-06 | 2007-04-06 | Ultraviolet curing vacuum metallizing coating |
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| CN101280154B true CN101280154B (en) | 2010-10-13 |
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Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103627312A (en) * | 2012-08-21 | 2014-03-12 | 上海大桥化工有限公司 | UV-curable coating |
| CN103160206A (en) * | 2013-03-28 | 2013-06-19 | 上海长悦涂料有限公司 | Vacuum electroplating primer as well as preparation method and application for same |
| CN103289558B (en) * | 2013-05-29 | 2015-08-26 | 江苏兰陵高分子材料有限公司 | A kind of ultraviolet-curing paint for steel surface and preparation method |
| CN105368297B (en) * | 2015-11-30 | 2020-01-31 | 江门市凌云涂料有限公司 | high-temperature-resistant vacuum plating UV coating and preparation method and application thereof |
| CN105670463B (en) * | 2016-04-11 | 2017-12-01 | 广东深展实业有限公司 | A kind of ultraviolet-curing vacuum coating metal primer of electrostatically sprayable |
| CN105647377B (en) * | 2016-04-11 | 2017-10-13 | 广东深展实业有限公司 | A kind of ultraviolet-curing vacuum coating metal finish paint of electrostatically sprayable |
| CN107227110A (en) * | 2017-06-28 | 2017-10-03 | 太仓市美航涂料有限公司 | A kind of high-performance vacuum coating UV finish paints |
| CN107418274A (en) * | 2017-08-04 | 2017-12-01 | 东莞市博友纳米材料有限公司 | A kind of nano-coating UV coating |
| CN108047854B (en) * | 2017-12-27 | 2020-04-21 | 江苏宏泰高分子材料有限公司 | Water-based ultraviolet-curing BMC high-temperature-resistant coating |
| CN114672222A (en) * | 2020-12-24 | 2022-06-28 | 汕头市紫光光电科技有限公司 | Scratch-resistant composite UV (ultraviolet) coating capable of automatically eliminating bubbles and preparation process thereof |
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| US4416750A (en) * | 1981-10-13 | 1983-11-22 | Desoto, Inc. | Ultraviolet curable basecoats for vacuum metallization |
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