CN101270478A - Metal cleaning agent - Google Patents

Metal cleaning agent Download PDF

Info

Publication number
CN101270478A
CN101270478A CNA2008100610416A CN200810061041A CN101270478A CN 101270478 A CN101270478 A CN 101270478A CN A2008100610416 A CNA2008100610416 A CN A2008100610416A CN 200810061041 A CN200810061041 A CN 200810061041A CN 101270478 A CN101270478 A CN 101270478A
Authority
CN
China
Prior art keywords
sodium
portions
oleic acid
trolamine
add
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CNA2008100610416A
Other languages
Chinese (zh)
Other versions
CN100554522C (en
Inventor
谭桂娥
何巧红
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhejiang University ZJU
Original Assignee
Zhejiang University ZJU
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Zhejiang University ZJU filed Critical Zhejiang University ZJU
Priority to CNB2008100610416A priority Critical patent/CN100554522C/en
Publication of CN101270478A publication Critical patent/CN101270478A/en
Application granted granted Critical
Publication of CN100554522C publication Critical patent/CN100554522C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Detergent Compositions (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Abstract

The invention provides a metal washing agent which is formed by the reactions of a surface promoting agent, oleic acid, sodium hydroxide, sodium nitrite, sodium molybdate, benztotriazole, trisodium phosphate, trolamine, polyether61 and distilled water. The weight portions of each component are: 10 to 15 portions of the surface promoting agent, 4 to 8 portions of the oleic acid, 0.5 to 1.1 portions of the sodium hydroxide, 0.1 to 0.5 portions of the sodium nitrite, 0.3 to 0.84 portions of the sodium molybdate, 0.08 to 0.15 portions of the benztotriazole, 1.5 to 2.5 portions of the trisodium phosphate, 1.5 to 3.0 portions of the trolamine, 0.5 to 0.9 portions of the polyether61 and the rest portions are the distilled water. The metal washing agent provided by the invention has good washing effect and can maintain the metal materials after being washed without rust in 15 to 20 days.

Description

Metal cleaner
Technical field
The present invention relates to metal cleaner.More specifically be meant the cleaning that is used for the metal material processing process and antirust.
Background technology
In mechanical processing technique, metallic substance is made mechanical component, most of cold machining process that relies on.According to the basic size requirement of part, sheet metal, bar, wire rod, section bar and cast blank, rough forging etc. are carried out cold working such as turning, drilling, milling, boring, grinding, up to size that is processed into regulation and precision.Course of processing branch work post is step by step carried out.Short then a couple of days of process-cycle, long then continue tens days, substep adds will be placed on man-hour in the warehouse and keeps in sometimes, and the metallic substance component surface can produce dirt.To carry out clean to the metallic substance component surface, to remove the various dirts that the metallic surface is adhered to, as acid, alkali, salt, organism, dust, smear metal, sweat stain, lubricated wet goods, behind the greasy dirt of removing metal material surface, carry out the operation of back again, as polishing, paint etc.Metallic surface after the cleaning is exposed in the air easily gets rusty, so will handle with rust-preventive agent when generally cleaning, scavenging period is long, the cost height.Technology generally adopts first cleaning at present, the antirust processing in back; Minority is cleaned with antirust and is handled simultaneously, and rust-proof effect is bad, rust staining just occurs after have several hours, also occurs rust staining after several days of favorable rust preventing effect.
Summary of the invention
The object of the invention provides a kind of metal cleaner, and cleaning performance is good, and metallic substance is exposed in the air after cleaning, and can keep long time non-corrosive, and is all effective to iron material, copper material, aluminium, composite material.
The invention provides metal cleaner, by tensio-active agent, oleic acid, sodium hydroxide, Sodium Nitrite, Sodium orthomolybdate, benzotriazole, tertiary sodium phosphate, trolamine, polyethers 61, distilled water reaction forms, set of dispense is than being the quality percentage composition: tensio-active agent 10~15, oleic acid 4~8, sodium hydroxide 0.5~1.1, Sodium Nitrite 0.1~0.5, Sodium orthomolybdate 0.3~0.8, benzotriazole 0.08~0.15, tertiary sodium phosphate 1.5~2.5, trolamine 1.5~3.0, polyethers 610.5~0.9, surplus is distilled water.
The invention provides the preparation method of metal cleaner, one, in reactor, add distilled water and sodium hydroxide, heating for dissolving is even; Two, stir and to add oleic acid down, maintain the temperature at about 80 ℃ 1 hour and make in the oleic acid and fully; Three, stop heating, add tensio-active agent and polyethers 61, dissolving is uniformly dispersed; Four, add tertiary sodium phosphate, Sodium Nitrite, Sodium orthomolybdate, dissolving is uniformly dispersed; Five, add trolamine and benzotriazole, dispersed with stirring is even.Six, canned.
The preparation method of metal cleaner of the present invention, tensio-active agent is fatty alcohol-polyoxyethylene ether (AEO 9) or polyoxyethylene nonylphenol ether (TX-10), consumption is to use 10~15 weight parts in 100 weight parts.
Metal cleaner provided by the invention, foam is low, can remove the difficult dirts of removing such as lubricating grease in the process of metal working like a cork, metallic substance is exposed in the air after cleaning simultaneously, can keep 15~20 days non-corrosives, all effective to iron material, copper material, aluminium, composite material, cost is relatively low.
Embodiment
The invention will be further described below in conjunction with embodiment:
(percentage composition is the quality percentage composition among each embodiment)
Embodiment 1
Oleic acid 5.0%
Sodium hydroxide 0.85%
Polyoxyethylene nonylphenol ether (TX-10) 15.0%
Polyethers 610.6%
Sodium Nitrite 0.1%
Sodium orthomolybdate 0.2%
Benzotriazole 0.1%
Tertiary sodium phosphate 2.0%
Trolamine 2.2%
Distilled water to 100
As follows by said components proportioning charging reaction step:
1, in reactor, add distilled water and sodium hydroxide, heating for dissolving is even;
2, stir and to add oleic acid down, maintain the temperature at about 80 ℃ 1 hour and make in the oleic acid and fully;
3, stop heating, add tensio-active agent polyoxyethylene nonylphenol ether (TX-10) and polyethers 61, dissolving is uniformly dispersed;
4, add tertiary sodium phosphate, Sodium Nitrite, Sodium orthomolybdate, dissolving is uniformly dispersed;
5, add trolamine and benzotriazole, dispersed with stirring is even;
6, it is canned to make metal cleaner.
The metal cleaner of present embodiment system is used for being exposed to air after metallic substance cleans, and can keep non-corrosive in 20 days.
Embodiment 2
Preparation process with reference to embodiment 1 prepares metal cleaner by following quality percentage composition set of dispense ratio:
Oleic acid 8.0%
Sodium hydroxide 0.5%
Fatty alcohol-polyoxyethylene ether (AEO 9) 12.0%
Polyethers 610.9%
Sodium Nitrite 0.5%
Sodium orthomolybdate 0.8%
Benzotriazole 0.15%
Tertiary sodium phosphate 2.5%
Trolamine 3.0%
Distilled water to 100.
Embodiment 3
Preparation process with reference to embodiment 1 prepares metal cleaner by following quality percentage composition set of dispense ratio:
Oleic acid 4.0%
Sodium hydroxide 1.1%
Fatty alcohol-polyoxyethylene ether 10.0%
Polyethers 610.5%
Sodium Nitrite 0.3%
Sodium orthomolybdate 0.5%
Benzotriazole 0.08%
Tertiary sodium phosphate 2.0%
Trolamine 2.0%
Distilled water to 100.

Claims (3)

1, a kind of metal cleaner is characterized in that by tensio-active agent, oleic acid, sodium hydroxide, Sodium Nitrite, Sodium orthomolybdate, benzotriazole, tertiary sodium phosphate, trolamine, polyethers 61, distilled water reaction forms, described set of dispense specific mass percentage composition is: tensio-active agent 10~15, oleic acid 4~8, sodium hydroxide 0.5~1.1, Sodium Nitrite 0.1~0.5, Sodium orthomolybdate 0.3~0.8, benzotriazole 0.08~0.15, tertiary sodium phosphate 1.5~2.5, trolamine 1.5~3.0, polyethers 610.5~0.9, surplus is distilled water.
2, metal cleaner according to claim 1 is characterized in that described tensio-active agent is respectively: fatty alcohol-polyoxyethylene ether or polyoxyethylene nonylphenol ether.
3, the described metal cleaner preparation method of claim 1 the steps include:
● in reactor, add distilled water and sodium hydroxide, heating for dissolving is even;
● stir adding oleic acid down, remained on 80 ℃ of temperature 1 hour, make in the oleic acid with complete;
● stop heating, add tensio-active agent and polyethers 61, dissolving is uniformly dispersed;
● add tertiary sodium phosphate, Sodium Nitrite, Sodium orthomolybdate, dissolving is uniformly dispersed;
● add trolamine and benzotriazole, dispersed with stirring is even;
● it is canned to make metal cleaner.
CNB2008100610416A 2008-04-25 2008-04-25 Metal cleaner Expired - Fee Related CN100554522C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNB2008100610416A CN100554522C (en) 2008-04-25 2008-04-25 Metal cleaner

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CNB2008100610416A CN100554522C (en) 2008-04-25 2008-04-25 Metal cleaner

Publications (2)

Publication Number Publication Date
CN101270478A true CN101270478A (en) 2008-09-24
CN100554522C CN100554522C (en) 2009-10-28

Family

ID=40004695

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB2008100610416A Expired - Fee Related CN100554522C (en) 2008-04-25 2008-04-25 Metal cleaner

Country Status (1)

Country Link
CN (1) CN100554522C (en)

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101407917B (en) * 2008-11-24 2010-07-14 夏光甫 High polymer composite synergistic activator
CN102161939A (en) * 2011-03-23 2011-08-24 天津市华阳新兴科技有限公司 Water-based industrial detergent capable of self-defoaminng at normal temperature and preparation method thereof
CN102807926A (en) * 2012-08-30 2012-12-05 中航工业哈尔滨轴承有限公司 Water aqua bearing cleaning agent and preparation method thereof
CN102978018A (en) * 2012-10-17 2013-03-20 张志明 Preparation method for detergent of smoke exhaust ventilator
CN102978025A (en) * 2012-10-17 2013-03-20 张志明 Detergent for smoke exhaust ventilator
CN102989712A (en) * 2012-10-17 2013-03-27 张志明 Range hood washing method
CN104073811A (en) * 2014-06-30 2014-10-01 铜陵市青铜时代雕塑有限责任公司 Bronze preservative
CN104149015A (en) * 2012-11-23 2014-11-19 江苏顺发电热材料有限公司 Electric heating pipe roller burnishing treatment process
CN104259978A (en) * 2012-11-23 2015-01-07 江苏顺发电热材料有限公司 Electrical heated tube tumbling process with passivating step
CN104726884A (en) * 2015-02-04 2015-06-24 常州工程职业技术学院 Environment-friendly water-based metal cleaner
CN105239086A (en) * 2015-11-10 2016-01-13 荆门市拓达科技有限公司 Multifunctional metal cleaner
CN102851661B (en) * 2012-09-18 2017-03-15 上海申和热磁电子有限公司 Water-soluble antirust dehydrant and preparation method and application
CN108060429A (en) * 2017-12-13 2018-05-22 临沂优盛新材料科技有限公司 A kind of thermal spraying special-purpose metal detergent and preparation method thereof
CN112795930A (en) * 2020-12-30 2021-05-14 李鸿佳 Low-foam metal cleaning agent for maintenance

Cited By (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101407917B (en) * 2008-11-24 2010-07-14 夏光甫 High polymer composite synergistic activator
CN102161939A (en) * 2011-03-23 2011-08-24 天津市华阳新兴科技有限公司 Water-based industrial detergent capable of self-defoaminng at normal temperature and preparation method thereof
CN102161939B (en) * 2011-03-23 2012-06-27 天津市华阳新兴科技有限公司 Water-based industrial detergent capable of self-defoaminng at normal temperature and preparation method thereof
CN102807926B (en) * 2012-08-30 2014-04-23 中航工业哈尔滨轴承有限公司 Preparation method of water aqua bearing cleaning agent
CN102807926A (en) * 2012-08-30 2012-12-05 中航工业哈尔滨轴承有限公司 Water aqua bearing cleaning agent and preparation method thereof
CN102851661B (en) * 2012-09-18 2017-03-15 上海申和热磁电子有限公司 Water-soluble antirust dehydrant and preparation method and application
CN102978025A (en) * 2012-10-17 2013-03-20 张志明 Detergent for smoke exhaust ventilator
CN102978018A (en) * 2012-10-17 2013-03-20 张志明 Preparation method for detergent of smoke exhaust ventilator
CN102978025B (en) * 2012-10-17 2014-05-07 张志明 Detergent for smoke exhaust ventilator
CN102978018B (en) * 2012-10-17 2014-07-09 张志明 Preparation method for detergent of smoke exhaust ventilator
CN102989712A (en) * 2012-10-17 2013-03-27 张志明 Range hood washing method
CN104149015A (en) * 2012-11-23 2014-11-19 江苏顺发电热材料有限公司 Electric heating pipe roller burnishing treatment process
CN104259978A (en) * 2012-11-23 2015-01-07 江苏顺发电热材料有限公司 Electrical heated tube tumbling process with passivating step
CN104073811A (en) * 2014-06-30 2014-10-01 铜陵市青铜时代雕塑有限责任公司 Bronze preservative
CN104726884A (en) * 2015-02-04 2015-06-24 常州工程职业技术学院 Environment-friendly water-based metal cleaner
CN105239086A (en) * 2015-11-10 2016-01-13 荆门市拓达科技有限公司 Multifunctional metal cleaner
CN105239086B (en) * 2015-11-10 2018-05-15 荆门市拓达科技有限公司 A kind of multi-function metal cleaning agent
CN108060429A (en) * 2017-12-13 2018-05-22 临沂优盛新材料科技有限公司 A kind of thermal spraying special-purpose metal detergent and preparation method thereof
CN108060429B (en) * 2017-12-13 2020-06-02 临沂优盛新材料科技有限公司 Special metal cleaning agent for thermal spraying and preparation method thereof
CN112795930A (en) * 2020-12-30 2021-05-14 李鸿佳 Low-foam metal cleaning agent for maintenance

Also Published As

Publication number Publication date
CN100554522C (en) 2009-10-28

Similar Documents

Publication Publication Date Title
CN100554522C (en) Metal cleaner
CN103695911B (en) Water-soluble metal polishing agent
CN103695912B (en) Metal polish
CN102732899B (en) Water-based anti-rusting type washing agent for metal parts
CN101113524B (en) Cleaning antirust agent and preparation method thereof
CN102534633A (en) Water-based metal cleaner
CN104004579B (en) Machining center rust coolant liquid
CN103374726A (en) Efficient multipurpose metal cleaning agent
CN102953071A (en) Highly-efficiently degreasing and rust-removal surface treating agent for metal
CN105780030A (en) Precision metal cleaning agent and preparation method thereof
CN101113305A (en) Nonferrous metal material surface cleaning rubbing paste and method for making same
CN108048826B (en) Rust removal phosphating solution for wire drawing and preparation method thereof
CN104388936A (en) Low-foam antirust polishing agent and its preparation method
CN1218069C (en) Phytic acid cleaning agent
CN104818492A (en) Aluminum alloy aqueous environment-friendly cleaning agent and preparation method of same
CN102220589A (en) Water based anti-rust cleaning agent
CN101285194A (en) Spent meal for treating surface of non-ferrous metal and method for preparing same
CN102168279B (en) Dusting cleaning antirusting agent and preparation method thereof
CN109082672A (en) Can derust the environmentally friendly steel surface cleaning agent to descale
CN103774168B (en) Manufacture again special dirt detergent and preparation method thereof
CN102212831A (en) Degreasing treatment process
CN102703913B (en) Cleaning agent for removing oil from grinding wheel ash
CN103898522A (en) Efficient mechanical equipment cleaning agent
CN104593794A (en) A cleaning agent for aluminum and alloys thereof
CN103668272A (en) Metal component detergent with antirust function

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C17 Cessation of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20091028

Termination date: 20100425