CN101258009A - Synergistic mixtures - Google Patents

Synergistic mixtures Download PDF

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Publication number
CN101258009A
CN101258009A CNA2006800329991A CN200680032999A CN101258009A CN 101258009 A CN101258009 A CN 101258009A CN A2006800329991 A CNA2006800329991 A CN A2006800329991A CN 200680032999 A CN200680032999 A CN 200680032999A CN 101258009 A CN101258009 A CN 101258009A
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CN
China
Prior art keywords
compound
mixture
triazolone
desinsection
timber
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CNA2006800329991A
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Chinese (zh)
Inventor
赖纳·布伦斯
马丁·库格勒
托马斯·耶切
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Lanxess Deutschland GmbH
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Lanxess Deutschland GmbH
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Publication of CN101258009A publication Critical patent/CN101258009A/en
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
    • A01N37/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/34—Organic impregnating agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/34—Organic impregnating agents
    • B27K3/343—Heterocyclic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/34—Organic impregnating agents
    • B27K3/50—Mixtures of different organic impregnating agents

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  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • Agronomy & Crop Science (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Toxicology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)

Abstract

The novel synergistic mixtures based on triadimefon and/or triadimenol and known insecticides are highly suitable for protecting commercial materials, in particular timber and wood materials, in addition to wood-plastic composites from being attacked, damaged and/or destroyed by biological pests.

Description

Synergistic mixtures
Technical field
The present invention relates to novel collaborative effective mixture, this mixture comprises: at first be triazolone (triadimefon) and/or Triadimenol (triadimenol), and secondly be multiple known pesticide; Relate to composition, and relate to these mixtures and composition is used for safeguard industries material, particularly timber and woodwork, and also have timber/plastic composite, avoid the purposes of attack, infringement and/or the destruction of harmful organism based on these mixtures.
Background technology
In principle, those skilled in the art can identify by basidiomycetes and, if timber be exposed to high humility or with environment that soil contacts under, the wood structure breaking-up that mould is caused and destroy the insect of timber and timber that termite is caused damages and the visual impairment of the timber that caused by wood-stain fungus.These destructions of timber and infringement have also been caused the reduction of intensity except other things and reduced the serviceability of timber generally.Therefore, protect timber and woodwork not to be subjected to the attack of harmful organism with pesticide in the time of with fungicide and suitably, prolong the serviceability and the service life of timber and woodwork with this.
Triazole type for example, as Tebuconazole (referring to EP-A254857) and cyproconazole (referring to EP-A554833), knownly is used to protect timber to avoid destroying the basidiomycetous infringement of timber.Their activity is hopeful very much in breadboard experiment separately; Yet, under the actual conditions, always can not guarantee enough protections, so that these active materials have to combine with metal species or metallic salt (particularly copper salt kind) in actual applications to timber.Thus, in fact usually with the triazole antifungal agents class with contain some compounds of heavy metal, for example as the compound of some copper, in conjunction with to provide the desinsection except that a kind of fungicidal final processing to protect.
Yet the composition that contains heavy metal owing to ecological reason use is used to protect timber to be considered to contentious.Therefore, still need be used to protect timber based on the improved composition of reactive compound, these reactive compounds need not to add heavy metal just can guarantee adequately protecting to timber.
Triazolone ((±)-1-(4-chlorophenoxy)-3,3-dimethyl-1-(1H-1,2, fourth-2-ketone) and Triadimenol ((±)-1-(4-chlorophenoxy)-3 the 4-triazol-1-yl), 3-dimethyl-1-(1H-1,2, the 4-triazol-1-yl) fourth-2-alcohol) be that the known protective plant that is used for is avoided the fungicide (referring to DE-A2552967) that fungi is attacked; Yet owing to have blank at the activation of microorganism spectrum (activity spectrum) relevant with wood protection, they can not use (referring to EP-A254857) separately in the protection of timber.Do not report effect as yet to insect.
(for example WO 00/71314) mentions triazolone or the Triadimenol possible mix as the different activities compound that is used to protect timber in some list of references; Yet, the mixture of these prior aries need in many aspects to improve and, because above-mentioned active blank, up to the present protection timber is not played any effect.Therefore, the mixture that still needs a kind of improved reactive compound based on triazolone and/or Triadimenol.
Summary of the invention
Unexpectedly, have now found that triazolone that itself is invalid or Triadimenol and certain pesticide activity in conjunction with the concertedness ground enhancing of having showed the harmful organism that antagonism is relevant with protection timber.
The invention provides mixture, these mixtures comprise the triazolone and/or the Triadimenol of cooperative effective quantity, and at least a pesticide, preferentially be selected from the group that is constructed as follows: phosphoric acid ester, carbamates, urea class, pyrethroid, pyroles, phenyl pyrazoles, diphenyl ether, two hydrazides class and nitro-methylene-types.
Mixture according to the present invention has shown a kind of synergistic activity at the harmful organism relevant with wood protection, and promptly the activity of these Synergistic mixtures is higher than the active separately summation of being discussed of these reactive compounds in a kind of unexpected mode.Thus, there is a kind of unpredictalbe cooperative effect, and is not only to be active stack.
The present invention provides the purposes according to Synergistic mixtures of the present invention in addition; this is to be used to protect timber, woodwork and timber/plasticity compound to avoid the harmful organism relevant with wood protection, particularly avoids destroying the bark beetle class of timber and the infringement of white ants.
The additional advantage that should collaborative activity that strengthens has is, owing in the lower use amount that is used for protecting a kind of composition fungicide of timber according to the present invention, not only obtained a kind of advantage economically, and reduced environmentally safe risk.
The specific embodiment
Preferred mixture comprises triazolone and/or Triadimenol, and at least a pesticide, and it is from the group that is constructed as follows:
Acetamiprid (acetamiprid), allethrin (allethrin), α-cypermethrin (alpha-cypermethrin), β-cyfloxylate (beta-cyfluthrin), Biphenthrin (bifenthrin), bioallethrin (bioallethrin), 4-chloro-2-(2-chloro-2-methyl-propyl)-5-[(6-iodo-3-pyridine radicals) methoxyl group]-3 (2H)-pyridazinones (CAS-RN:120955-77-3), chlorfenapyr (chlorfenapyr), chlorpyrifos (chlorpyrifos), thiophene worm amine (clothianidin), cyfloxylate (cyfluthrin), lambda-cyhalothrin (cyhalothrin), cypermethrin (cypermethrin), decis (deltamethrin), ether chrysanthemum ester (etofenprox), fenoxycarb (fenoxycarb), fluorine worm nitrile (fipronil), flufenoxuron (flufenoxuron), fluorine bell urea (hexaflumuron), Imidacloprid (imidacloprid), Nitenpyram (nitenpyram), Permethrin (permethrin), pyriproxyfen (pyriproxifen), silafluofene (silafluofen), worm hydrazides (tebufenozide), thiophene worm quinoline (thiacloprid), thiophene worm piperazine (thiamethoxam), tralomethrin (tralomethrin), kill bell urea (triflumuron).
Mixture very preferably is to comprise triazolone and/or Triadimenol, and at least a pesticide, and it is from the group that is constructed as follows:
Biphenthrin, chlorfenapyr, chlorpyrifos, thiophene worm amine, cyfloxylate, cypermethrin, decis, ether chrysanthemum ester, fluorine worm nitrile, flufenoxuron, Imidacloprid, Permethrin, thiophene worm quinoline, thiophene worm piperazine.
Especially preferred mixture is to comprise triazolone and/or Triadimenol, and at least a pesticide, and it is from the group that is constructed as follows:
Biphenthrin, chlorfenapyr, thiophene worm amine, cyfloxylate, cypermethrin, decis, Imidacloprid, Permethrin, thiophene worm quinoline.
In the mixture of this reactive compound, the weight ratio of these reactive compounds can change in a wide relatively scope.The scope of the weight ratio of preferred triazolone and/or Triadimenol and at least a mentioned pesticide is 1000: 1 to 1: 1, particularly preferably is from 100: 1 to 2: 1.
Especially preferred is to comprise that according to of the present invention the weight ratio of the active compound combinations of triazolone and/or Triadimenol and at least a mentioned pesticide is from 50: 1 to 5: 1.
Synergistic mixture according to the present invention has the extra high thing of killing livestock, particularly an antifungal and desinsection and also has the effect of killing termite, and combines the wide activity profile of the antagonism harmful organism relevant with material protection.The basidiomycetes and the insects (particularly destroying the coleoptera and the white ants of timber) of their antagonism destruction timber are especially effective.
By way of example but can not mention following microorganism as restriction:
Chaetomium globosum belongs to (Chaetomium globosum), Glenospora graphii, humicola lanuginosa (Humicola gisea), Petriella setifera, spiral pieces mould (Trichurusspiralis) and Lecythophora mutabilis (Lecythophora mutabilis), resists Trichoderma viride (Trichoderma viride), botryoidalis fringe mould (Stachybotrys cartarum), cephalosporium (Chephalosporium) and Acremonium (Acremoniumsp.) in addition;
Cellar fungus (Coniophora puteana), Coriolus (Coriolusversicolor), the brown gill fungus of needle (Gloeophyllum abietinum), gloeophyllum trabeum (Gloeophyllum trabeum), Lentinus tigrinus (Lentinus tigrinus), mountain region transverse hole fungus (Poria monticola), continuous rotten transverse hole fungus (Poria placenta), serpula lacrymans (Serpulalacrymans), the tough lead fungi of blood stain (Stereum sanguinolentum), knurl lid cheese bacteria (Tyromyces palustris).
By way of example but can not mention the insect of following destruction timber as restriction:
Coleoptera, all as if North America house longhorn beetle (Hylotrupes bajulus), the green brave longicorn of crinosity (Chlorophorus pilosis), furniture death watch beetle (Ahobium punctatum), report dead death watch beetle (Xestobium rufovillosum), Ptilinus pectinicornis (Ptilinus pecticornis), Dendrobium pertinex, serration fork-tail long moth-eaten (Ernobius mollis), Priobiumcarpini, Lyctus brunneus Stephens (Lyctus brunneus), Africa powder moth (Lyctus africanus), south powder moth (Lyctus planicollis), embrace flat moth (Lyctus linearis), fur powder moth (Lyctus pubescens), Trogoxylon aequale, minthea rugicollis (Minthesrugicollis), material bark beetle class (Xyleborus) and wooden bark beetle class (Trypodendron), coffee black long moth-eaten (Apate monachus), Bostrychus capucins, the different wing of palm fibre long moth-eaten (Heterobostrychus brunneus), long moth-eaten class (Sinoxylon) of two sour jujubes and bamboo moth (Dinoderus minutus);
Hymenoptera is such as blue-black wood wasp, big wood wasp, safe wood wasp and the Urocerus augur of strengthening;
White ants is for example as kalotermes flavicollis (Kalotermes flavicollis), a fiber crops sand termite (Cryptotermes brevis), the Indian-Pakistani different termite of structural wood (Heterotermesindicola), yellow limb reticulitermes flavipe (Reticulitermes flavipes), Sang Te reticulitermes flavipe (Reticulitermes santonensis), Europe reticulitermes flavipe (Reticulitermeslucifugus), Da Shi Australia termite (Mastotermes darwiniensis), termite (Zootermopsis nevadensis) is moved in the Nevada, Taiwan formosanes (Coptotermes formosanus).
Under the condition of humidity, except der Pilz, bacterium is for example as pyrolysis cellulose Pseudomonas (Caldocellulosiruptor), property bacterium (Anaerocellum) is sick of, clostridium class (Clostridium), such as Clostridium cellulovorans (Clostridium cellulovorans), Clostridium aldrichii, cellulomonas cartae class (Cellulomonas), streptomycete (streptomycetes), Micremonospora (Micromonospora), Thermomonospora (Thermomonospora), Microbispora (Microbispora) and also have Cytophaga (Cytophaga) and life spore Cytophaga (Sporocytophaga) class also can help cellulosic degraded.
For widening this activity profile or for obtaining effect more specifically, Synergistic mixtures of the present invention can combine with at least a other compound that microbiocidal activity is arranged.Specifically, this Synergistic mixtures may comprise at least a other reactive compound, and it is from the group of fungicide and antibacterial active compounds.
The mixture that also especially preferably contains one or more following microbicidel components:
Dichlofluanid (dichlofluanid), Tolylfluanid (tolylfluanid), carbendazim (carbendazim), butadiene morpholine (fenpropimorph), bethoxazin, thiocyano-methyl-thio-benzothiazole, normal-butyl carbamic acid-3-iodo-2-propynyl ester, pyrrole sulphur zinc, pyrrole sulphur copper, N-(3-aminopropyl)-N-dodecyl the third-1,3-diamines, Tebuconazole, propiconazole, cyproconazole and copper salt kind.
Especially preferably has following component according to mixture of the present invention (as other component): dichlofluanid, Tolylfluanid, bethoxazin, butyl carbamic acid-3-iodo-2-propynyl ester, pyrrole sulphur zinc or pyrrole sulphur copper, Tebuconazole, propiconazole, cyproconazole and copper salt kind, or the mixture of these components.
Also preferably have one or more following mixtures that kills cell component:
Phenmethylol list-(gathering)-hemiformal, formaldehyde ethylene hemiacetal, N-(2-hydroxypropyl) amino methanol, N-methyl isothiazoline-3-ketone, 5-chloro-N-methyl isothiazoline-3-ketone, 4,5-benzisothiazole ketone, formaldehyde, glutaraldehyde, benzalkonium chloride, chlorination benzyl dimethyl myristyl ammonium, chlorination benzyl dimethyl dodecyl ammonium, the salt of 3-methyl-4-chlorophenol and 2-benzyl-4-chlorophenol and their alkali metal and alkaline-earth metal, p-hydroxybenzoate, also have o-phenyl phenol and their alkali metal and alkali salt, bronopol, 2,2-two bromo-3-nitrile propionamides (2,2-dibromo-3-nitrilepropionamide) and silver compound.
Preferably according to the combination with reactive compound of following bactericide of the present invention:
Phenmethylol list-(gathering)-hemiformal, N-methylisothiazolinone-3-ketone, 5-chloro-N-methyl isothiazoline-3-ketone, 4,5-benzisothiazole ketone, glutaraldehyde, benzalkonium chloride, bronopol, the salt of 3-methyl-4-chlorophenol and 2-benzyl-4-chlorophenol and their alkali metal and alkaline-earth metal, o-phenyl phenol and their alkali metal and alkaline-earth metal salt, and silver compound.
The combination that very particularly preferably has the reactive compound of following bactericide:
Phenmethylol list-(gathering)-hemiformal, 4,5-benzisothiazole ketone, benzalkonium chloride, bronopol, 3-methyl-4-chlorophenol and also have 2-benzyl-4-chlorophenol and their sodium salt and sylvite, o-phenyl phenol and their sodium salt and sylvite, and silver (I) compound.
Generally contain 0.01% to 85% triazolone and/or Triadimenol by weight according to mixture of the present invention, by weight 0.001% to 15% at least a mentioned pesticide and, in the time of suitably, 0.01% to 80% at least a other compound that microbiocidal activity is arranged by weight is particularly from the group of above-mentioned reactive compound.
Preferably, mixture according to the present invention contains 0.1% to 40% triazolone and/or Triadimenol by weight, by weight 0.01% to 5% at least a mentioned pesticide and, in the time of suitably, 0.05% to 30% at least a other compound that microbiocidal activity is arranged by weight is particularly from the group of above-mentioned reactive compound.
Can prepare with a kind of known mode according to mixture of the present invention, for example by in a suitable device, these reactive compounds are milled and/or mix and/granulation.Also might be separately or dissolving in a kind of suitable solvent, dispersion or emulsification jointly with these reactive compounds, add other auxiliary agent and additive in the time of suitably, for example as emulsifying agent, and, in the time of suitably, by add other solvent or, in the time of suitably, by distillation that removal of solvents is extremely dry, and they are precipitated out.
The present invention further provides purposes according to the mixture of reactive compound of the present invention; this is to be used for safeguard industries material (particularly timber), woodwork and to also have timber/plastic composite to avoid harmful organism, particularly the attack of fungi and insect, infringement and/or destruction.
The mixture of these reactive compounds and reactive compound, the physics and/or the chemical characteristic that depend on them, can be transformed into conventional prescription, such as the microcapsules in solution, emulsion, suspension, powder, foam, paste, particle, gaseous solvents and the polymeric material.
The present invention also provides microbicidal composition in addition, the triazolone and/or Triadimenol and at least a mentioned pesticide and at least a diluent or the solvent that comprise a cooperative effective quantity, other auxiliary agent and additive and also having in the time of suitably, in the time of suitably, at least a above-mentioned other reactive compound.
These prescriptions can prepare with a kind of known mode, for example by reactive compound is sneaked into extender, be liquid flux, pressurized liquefied gas and/or the carrier of solid, use surfactant in the time of suitably, promptly emulsifying agent and/or dispersant and/or foam generate agent.If used extender is a water, also might use, for example, organic solvent is as secondary solvent.The liquid flux that is suitable for is in essence: aromatic compound class such as dimethylbenzene, toluene or Fluhyzon class, aliphatic hydrocarbon, such as cyclohexane or paraffin, mineral oil fractions for example, alcohols such as butanols or ethylene glycol, and their ether and ester, ketone such as acetone, methyl ethyl ketone, methyl iso-butyl ketone (MIBK) or cyclohexanone, intensive polar solvent as dimethyl formamide and dimethyl sulfoxide (DMSO), also has water.The gas extender or the carrier of liquefaction are interpreted as being meant under environment temperature and atmospheric pressure to be the liquid of gaseous state, for example gaseous solvents propellant such as halogenated hydrocarbon, and the dioxide that also has butane, propane, nitrogen and carbon.The solid carrier that is suitable for is: for example natural ground mineral substance, for example kaolin, clay, talcum, chalk, quartz, attapulgite, imvite or diatomite, and the synthetic inorganic matter in ground for example silica, alumina and the silicate of fine dispersion.The suitable solid carrier that is used for particle is: for example pulverize and the natural minerals of classification for example calcite, marble, float stone, sepiolite and dolomite, and the synthetic particle that also has inorganic and organic powder, and organic material particle for example sawdust, coconut husk, corncob and tobacco stems.Emulsifying agent that is suitable for and/or foam generate agent: for example nonionic and anionic emulsifying agent, for example polyoxyethylene fatty acid ester class, polyoxyethylene aliphatic alcohol ether class, for example alkaryl polyglycol ether, alkyl sulfonic ester, alkyl sulfate, aromatic yl sulphonate and also have protein hydrolysate.The dispersant that is suitable for is: for example lignosulphonic acid ester waste liquid and methylcellulose.
Tackifier are carboxymethyl cellulose and the natural and synthetic polymer that is in powder, particle or latex form for example; for example gum arabic, polyvinyl alcohol and polyvinyl acetate, for example cephalin and lecithin and synthetic phosphatide can use in prescription perhaps to also have natural phosphatide in addition.Other possible additives are mineral and vegetable oil.
Might use for example inorganic pigment of colouring agent, for example iron oxide, titanium oxide and Prussian blue, and organic dyestuff for example alizarin dyes, azo dyes and metal phthalocyanine dyestuff, and the trace nutrient salt of iron, manganese, boron, copper, cobalt, molybdenum and zinc for example.
These prescriptions comprise that generally the amount meter is preferably measured the combination of the reactive compound of meter between 0.5% and 50% by weight between 0.1% and 95% by weight.
These are used for the microbicidal composition of safeguard industries material or concentrate and comprise that concentration is by weight from 0.005% to 95%, preferred especially from 0.1% to 50% this reactive compound by weight or the combination of reactive compound.
The working concentration of the combination of employed this reactive compound or reactive compound depends on by the person's character of microorganism to be controlled and the situation of generation and forming of claimed material.Optimum use amount can be determined by campaign.In a word, based on claimed material, institute's working concentration is by weight from 0.001% to 10%, in preferred from 0.01% to 5% the scope by weight.
By making combination or the composition of utilization, might replace operational so far microbicidal composition with more effective composition in a kind of favourable mode according to reactive compound of the present invention.These compositions according to the present invention possess good stable and, in a kind of favourable mode, possess a wide activity profile.
Utilization is according to the mixture of these reactive compounds of the present invention or comprise the timber that their composition can be protected; woodwork and timber/plastic composite have as an example: construction timber; wooden frame; railroad tie; bridge member; jetty (jetties); wooden vehicle; case; supporting plate; container; electric pole; plank lagging; wooden window and door; glued board; medium density fibre board (MDF) (MDF); sawdust-board; oriented wood chipboard (OSB); wafer board; the woodwork that laminwood dermatotome (LVL) or those quite generally use in building construction or construction joiner, and also have timber/plastic composite.
These reactive compounds can use separately or as a kind of mixture of finishing, and employed form is their prescription form or type of service prepared therefrom, for example ready-made available solution, suspension, paste, soluble powder.Application is to handle this industrial materials in a kind of mode of routine with the mixture of independent reactive compound or formation or with a prescription or type of service prepared therefrom.If it is timber, woodwork or timber/plastic composite that material to be protected is arranged; then use with conventional method; for example by sprinkling, coating, immersion and mill retting method; for example vacuum, two vacuum or pressure application; and by adding glue or passing through to use cooperation machine or mixer, masterbatch (master batches) adds and uses in addition.
By the mill retting method, for example, vacuum, two vacuum or pressure application have realized a kind of especially effectively wood protection.
The present invention also provides a kind of method that is used to protect timber and woodwork in addition; wherein by coating, sprinkling, vacuum, two vacuum, pressure or immersion process; utilize triazolone and/or Triadimenol and at least a mentioned pesticide and at least a diluent or the solvent of a cooperative effective quantity; other auxiliary agent and additive and also having in the time of suitably; in the time of suitably, at least a mentioned other reactive compound floods this timber or woodwork.At this, this reactive compound triazolone and/or Triadimenol and at least a pesticide of mentioning can use separately or as a kind of mixture of finishing.
Biological example
Use is determined this synergy by the described method of people such as Kull (F.C.Kull, P.C.Eismann, H.D.Sylvestrowicz, R.L.Mayer, Applied Microbiology 9,538 to 541,1961).At this, be suitable for following relation:
QA/Qa+QB/Qb＝SI
The concentration of Qa=substance A, it is corresponding to MIC
The concentration of Qb=substance B, it is corresponding to MIC
The substance A concentration of QA=in the concentration of the A/B that suppresses growth of microorganism
The substance B concentration of QB=in the concentration of the A/B that suppresses growth of microorganism
The SI=index of cooperation
SI=1 means summation action
SI＞1 means antagonism
SI＜1 means synergy
Example 1:
To the chlorfenapyr (A) of variable concentrations, the mixture of triazolone (B) and these two kinds of reactive compounds has carried out the test of the Basidiomycetes gloeophyllum trabeum of antagonism destruction timber.Mycelium is beaten out from an organic bacterium colony that destroys timber and in the time of 26 ℃, cultivate at a kind of nutrient agar that contains mould fungus extract and peptone.Subsequently, the radial growth that adds and do not add the mycelia of reactive compound is compared.Said MIC is the least concentration that makes reactive compound in the series that the radial growth of this fungal filament suppressed fully.
Reactive compound Blending ratio MIC[ppm] SI
A ＞20
A∶B 1∶1 10 0.5
A∶B 4∶6 10 0.5
A∶B 3∶7 10 0.5
A∶B 2∶8 10 0.5
B 20
The data of the index of being measured show that according to triazolone of the present invention and chlorfenapyr combination has a kind of significant synergy of covering wide scope.
Example 2:
Make the Permethrin (A) of variable concentrations, the mixture of triazolone (B) and these two kinds of reactive compounds has carried out the test of the Basidiomycetes Lentinus tigrinus of antagonism destruction timber.Mycelium is beaten out from an organic bacterium colony that destroys timber and in the time of 26 ℃, cultivate at a kind of nutrient agar that contains mould fungus extract and peptone.Subsequently, the radial growth that adds and do not add the mycelia of reactive compound is compared.Said MIC is the least concentration that makes reactive compound in the series that the radial growth of this fungal filament suppressed fully.
Reactive compound Blending ratio MIC[ppm] SI
A ＞＞20
A∶B 4∶6 10 0.8
A∶B 3∶7 6 0.51
A∶B 2∶8 6 0.54
A∶B 1∶9 6 0.57
B 10
The data of the index of measuring show that according to triazolone of the present invention and Permethrin combination has a kind of significant synergy of covering wide scope.
Example 3:
Make the thiophene worm quinoline (A) of variable concentrations, the mixture of triazolone (B) and described two kinds of reactive compounds has carried out the test of the continuous rotten transverse hole fungus of Basidiomycetes of antagonism destruction timber.Mycelium is beaten out from an organic bacterium colony that destroys timber and in the time of 26 ℃, cultivate at a kind of nutrient agar that contains mould fungus extract and peptone.Subsequently, the radial growth that adds and do not add the mycelia of reactive compound is compared.Said MIC is the least concentration that makes reactive compound in the series that the radial growth of this fungal filament suppressed fully.
Reactive compound Blending ratio MIC[ppm] SI
A ＞＞20
A∶B 1∶1 3 0.4
A∶B 4∶6 3 0.66
A∶B 3∶7 3 0.74
A∶B 2∶8 3 0.83
A∶B 1∶9 3 0.92
B 3
The data of the index of measuring show that according to triazolone of the present invention and thiophene worm quinoline combination has a kind of significant synergy of covering wide scope.
Formulation examples
Example 1(technical grade concentrating agents):
10% triazolone, 0.5% Permethrin, 24.5% Texanol, 15% ethoxylated castor oil, the prepared product of 15% sodium ricinoleate (sodium rhizinolate)/neopelex, 35% dimethyl fatty acid amide.
Example 2(technical grade concentrating agents):
15% triazolone, 0.5% chlorfenapyr, 22.5% Texanol, the prepared product of sodium ricinoleate/neopelex of 13%, 14% fatty acid polyglycol glycol ether ester, 35% dimethyl fatty acid amide.
Example 3(technical grade concentrating agents):
7.5% triazolone, 0.25% Biphenthrin, the prepared product of sodium ricinoleate/neopelex of 16.25%, 27% ethoxylated castor oil, 49% Texanol.
Example 4(emulsion concentrate):
5.0% triazolone, 0.1% thiophene worm quinoline, 2.9% sodium ricinoleate/neopelex prepared product, 27% fatty acid polyglycol glycol ether ester, 65% Texanol.
Example 5(being used for impregnated compositions):
0.3% Triadimenol, 0.01% bromine nitrile chrysanthemum ester, 15% Worl é esol 31A (adhesive concentrating agents), the ethoxylated castor oil of 0.8% Additol VXW 4940,3.0%, 3.0% Texanol, 77.89% water.
Example 6(being used for impregnated compositions):
0.4% triazolone, 0.01% cyfloxylate, 4.0% alkyd resins, 4.0% Dowanol DPM, 91.59% white solvent naphtha.
Example 7(priming paint):
0.2% triazolone, 0.2% Tebuconazole, 0.4% Tolylfluanid, 0.05% cypermethrin, 6% Dowanol DPM, 10% alkyd resins, 83.2% white solvent naphtha.

Claims (11)

1. mixture comprises the triazolone and/or the Triadimenol and at least a for the activated compound of desinsection of cooperative effective quantity.
2. according to the mixture of claim 1, it is characterized in that this is to be selected from the group that is constructed as follows for the activated compound of desinsection: phosphoric acid ester, carbamates, urea class, pyrethroid, pyroles, phenyl pyrazoles, diphenyl ether, two hydrazides class and nitro-methylene-types.
3. according at least one mixture in claim 1 and 2, it is characterized in that this is to be selected from the group that is constructed as follows for the activated compound of desinsection: Acetamiprid, allethrin, α-cypermethrin, β-cyfloxylate, Biphenthrin, bioallethrin, 4-chloro-2-(2-chloro-2-methyl-propyl)-5-[(6-iodo-3-pyridine radicals) methoxyl group]-3 (2H)-pyridazinones (CAS-RN:120955-77-3), chlorfenapyr, chlorpyrifos, thiophene worm amine, cyfloxylate, lambda-cyhalothrin, cypermethrin, decis, ether chrysanthemum ester, fenoxycarb, fluorine worm nitrile, flufenoxuron, fluorine bell urea, Imidacloprid, Nitenpyram, Permethrin, pyriproxyfen, silafluofene, worm hydrazides, thiophene worm quinoline, thiophene worm piperazine, tralomethrin kills the bell urea.
4. according at least one mixture in the claim 1 to 3, it is characterized in that this is to be selected from the group that is constructed as follows for the activated compound of desinsection: Biphenthrin, chlorfenapyr, chlorpyrifos, thiophene worm amine, cyfloxylate, cypermethrin, decis, ether chrysanthemum ester, fluorine worm nitrile, flufenoxuron, Imidacloprid, Permethrin, thiophene worm quinoline, thiophene worm piperazine.
5. according at least one mixture in the claim 1 to 4, it is characterized in that triazolone and/or Triadimenol and be from 1000: 1 to 1: 1 for the weight ratio of the activated compound of desinsection.
6. according at least one mixture in the claim 1 to 5, it is characterized in that they comprise from fungicide and at least a other reactive compound of group of the compound of antibacterial activity is arranged.
7. according at least one mixture in the claim 1 to 6, it is characterized in that they comprise 0.01% to 85% triazolone and/or Triadimenol by weight, by weight 0.001% to 15% at least a for the activated compound of desinsection and, in the time of suitably, by weight 0.01% to 80% from fungicide and at least a other compound that microbiocidal activity is arranged of group of the compound of antibacterial activity is arranged.
8. microbicidal composition, the triazolone and/or the Triadimenol and at least a that comprise a cooperative effective quantity for the activated compound of desinsection and at least a diluent or solvent, other auxiliary agent and additive and also having in the time of suitably, in the time of suitably, from least a other reactive compound of fungicide with the group of the compound that antibacterial activity is arranged.
9. be used for the safeguard industries material according at least one a kind of mixture of reactive compound or a kind of composition according to Claim 8 in the claim 1 to 7; timber particularly, woodwork and timber/plastic composite are avoided the purposes of attack, infringement or the destruction of harmful organism.
10. be used to protect the method for timber and woodwork; it is characterized in that by coating, sprinkling, vacuum, two vacuum, pressure or immersion process; utilize the triazolone of cooperative effective quantity and/or Triadimenol and at least a for the activated compound of desinsection and also have at least a diluent or solvent; other auxiliary agent and additive in the time of suitably; and also have; in the time of suitably, this timber or this woodwork are flooded from least a other reactive compound in the group of fungicide and the compound that antibacterial activity is arranged.
11. industrial materials comprise the triazolone and/or the Triadimenol and at least a for the activated compound of desinsection of cooperative effective quantity.
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