CN101250460B - Nano metal self-restoring lubricating oil for mechanical sealing element and preparation method thereof - Google Patents
Nano metal self-restoring lubricating oil for mechanical sealing element and preparation method thereof Download PDFInfo
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- CN101250460B CN101250460B CN2007100208122A CN200710020812A CN101250460B CN 101250460 B CN101250460 B CN 101250460B CN 2007100208122 A CN2007100208122 A CN 2007100208122A CN 200710020812 A CN200710020812 A CN 200710020812A CN 101250460 B CN101250460 B CN 101250460B
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Abstract
The invention discloses nano-metal self-repairing lubricating oil for mechanical seal elements and the process for preparation, which comprises the following components, the weight percentage content which occupies the total amount of self-repairing lubricating oil is that nano-metal powder which is 0.07-0.15%, nano-metal powder body dispersing agent which is 0.2-1% and disperse medium 98.9-99.7%. The process for preparation of the invention comprises the following steps: adding nano-metal powder body dispersing agent which is needed by proposition into disperse medium to evenly stir, further adding nano-metal powder according to the above proposition, properly stirring till nano-metal powder has no obvious settlement, placing with a container into a KH-700 type ultra-audio wave oscillator to oscillate 20-30 minutes, wherein source of power is 500-600w, and getting product. The nano-metal self-repairing lubricating has low production cost, which is beneficial for popularizing, and can lead the gap between friction pairs to be optimized, and the nano-metal self-repairing lubricating oil can not be dropped off after a self-repairing layer is formed, operation with low friction factor of equipment is kept, and the nano-metal self-repairing lubricating oil is energy-saving and environmental-friendly, which can effectively prolong maintenance down periodic time, and lowers maintenance cost.
Description
Technical field
The present invention relates to a kind of novel nano metal self-restoring lubricating oil that is applicable to multiple friction pair in the mechanical sealing member, suitable friction pair comprises graphite/steel, steel/steel, Wimet/Wimet, SiC/SiC, tetrafluoroethylene/Al
2O
3, graphite/SiC.
Background technology
It is reported that 30～50% of the produced worldwide energy is lost in the frictional wear, China annual because of frictional wear cause with a toll of more than one hundred billion Renminbi.Therefore, reduce friction, reduce wearing and tearing, improve plant factor, increase the service life, be one of important content of countries in the world research always.In mechanical sealing member, the oil product of used seal lubrication is very big to product work-ing life and energy consumption influence.The friction of sealing section can consume mechanical power, reduces mechanical efficiency; The generation of wearing and tearing then can make friction pair parts forfeiture dimensional precision, causes seal failure, thereby leaks, and causes equipment scrapping.For reducing wearing and tearing, except that carrying out rational tribology Design, also can solve by good lubrication that improves the special lubricating oil realization of employing friction pair and wear-resistant, the antifriction performance that improves friction pair material.Because article one approach is subjected to many restrictions of the aspects such as cost, processing and working conditions of part in actual mechanical process, therefore, more use occasion still realizes antifriction between the friction pair and wear-resistant by developing lubricating oil efficiently.
In research and practical application, find, adopt lubricating oil merely, be difficult to satisfy the requirement of various different application occasions, particularly do not possess the requirement of wear surface being carried out selfreparing.It is to add the various organic and inorganic compound with difference in functionality lubricating oil is carried out modification in lubricating oil that the tradition of these lubricating oil is improved one's methods, to improve the physicochemical property of lubricant medium, improve the supporting capacity of lubricating oil (fat) film and reduce frictional coefficient.But also brought the part side effect simultaneously, in friction process, may produce objectionable constituent as part of compounds, particularly warm when higher when oil, may play corrosive nature to the bearing materials of non-ferrous metal, the easy decomposition and consumption of some oil soluble organic additive needs constantly to replenish.In addition, the synthesis technique complexity of this additive, some has chemical pollution, makes its development be subjected to certain limitation.But the analysis that has the acidic substance that produce after better suspension characteristic and neutral lubrication oil oxidation and the fuel combustion based on nanoparticle, the research of nanometer lubricating additive has in recent years caused the generally attention of countries in the world, and has developed multiple nano level slip additive.The JB automobile patron saint series that contains polymkeric substance as the production of U.S. Justicebrothers company; The anti-serial anti-wear agent of speeding of the peace that contains the unit molecule carbon compound that U.S. ER company produces; The Slick50 engine antifriction lubricant that contains the PTFE material that U.S. Petrolon produces.
The nano antiwear agent product of development emerges in large numbers gradually both at home and abroad, mostly the target market is locked on the vehicles.Yet industrial goods has more wide user group, and mechanical sealing member is the common running stores of industries such as chemical industry, agricultural, metallurgy, and too much damage causes maintain and replace frequent, has had a strong impact on the service efficiency of equipment.In addition, for the improvement of industrial goods, emphasis to consider cost, the cost raising too much is not suitable for promoting in the industry.
Summary of the invention
In order to overcome above-mentioned defective, the invention provides a kind of nano metal self-restoring lubricating oil for mechanical sealing element and preparation method thereof, this preparation method is simple, the cost increase less, pollution-free, the formed reconditioning layer hardness of this self-restoring lubricating oil agent height, frictional coefficient is little, rerum natura is stable.
The present invention for the technical scheme that solves its technical problem and adopt is: a kind of nano metal self-restoring lubricating oil for mechanical sealing element, be made up of Nano metal powder, nano metal powder dispersion agent and dispersion medium, the weight percentage of the shared nano metal self-restoring lubricating oil total amount of each component is as follows:
Nano metal powder 0.07～0.15%
Nano metal powder dispersion agent 0.2～1%
Dispersion medium 98.9～99.7%.
Nano metal powder is a kind of in copper nanoparticle, nanometer copper nickel composite powder and the nanometer copper bismuth composite powder, the mean particle size≤80nm of nickel, bismuth wherein, and the mean particle size≤60nm of copper, wherein the proportioning of copper nickel is 8: 2, the proportioning of copper bismuth is 8: 2.
The nano metal powder dispersion agent is at least a kind of in Sodium hexametaphosphate 99, oleic acid, hard ester acid and the silane coupling agent.
Dispersion medium is a machine oil.
The preparation method of nano metal self-restoring lubricating oil for mechanical sealing element the steps include:
1.. stir in earlier that proportioning is the required nano metal powder dispersion agent adding dispersion medium, further add Nano metal powder more according to the above ratio, agitation as appropriate to nano metal powder does not have obvious sediment;
2.. put in the KH-700 type ultrasonic oscillator together with container and to vibrate 20～30 minutes, power is 500～600W, product, can use in a conventional manner in mechanical sealing member, perhaps can to the container as sell goods.
The invention has the beneficial effects as follows: laboratory and the actual equipment test result that uses show, add the suitable Nano metal powder and the machine oil of dispersion agent, than the machine oil that does not add additive, mechanical sealing member normally uses in half an hour, the frictional coefficient of sealing section is reduced to 0.036 by 0.046, has reduced by 21.7%.And by adjusting component ratio applicable to multiple friction pair, can improve the friction pair gap, after this reconditioning layer forms, do not come off through behind the long-play, can in time repair the wearing and tearing that produce in the friction, effectively prolong stopping the cycle of repairing of use equipment, reduce that equipment running cost and preparation method are simple, the cost increase less, pollution-free etc.
Embodiment
Embodiment: a kind of nano metal self-restoring lubricating oil for mechanical sealing element, to form by Nano metal powder, nano metal powder dispersion agent and dispersion medium, the weight percentage of the shared nano metal self-restoring lubricating oil total amount of each component is as follows:
Nano metal powder 0.07～0.15%
Nano metal powder dispersion agent 0.2～1%
Dispersion medium 98.9～99.7%.
Nano metal powder is a kind of in copper nanoparticle, nanometer copper nickel composite powder and the nanometer copper bismuth composite powder, the mean particle size≤80nm of nickel, bismuth wherein, and the mean particle size≤60nm of copper, wherein the proportioning of copper nickel is 8: 2, the proportioning of copper bismuth is 8: 2.
The nano metal powder dispersion agent is at least a kind of in Sodium hexametaphosphate 99, oleic acid, hard ester acid and the silane coupling agent.
Dispersion medium is a machine oil.
The preparation method of nano metal self-restoring lubricating oil for mechanical sealing element the steps include:
1.. stir in earlier that proportioning is the required nano metal powder dispersion agent adding dispersion medium, further add Nano metal powder more according to the above ratio, agitation as appropriate to nano metal powder does not have obvious sediment;
2.. put into KH-700 type ultrasonic oscillator (also can be similar other ultrasonic oscillators certainly) vibration 20～30 minutes together with container, power is 500～600W, product, can use in a conventional manner in mechanical sealing member, perhaps can to the container as sell goods.
Claims (3)
1. nano metal self-restoring lubricating oil for mechanical sealing element, it is characterized in that: be made up of Nano metal powder, nano metal powder dispersion agent and dispersion medium, the weight percentage of the shared nano metal self-restoring lubricating oil total amount of each component is as follows:
Nano metal powder 0.07～0.15%,
Nano metal powder dispersion agent 0.2～1%,
Dispersion medium 98.9～99.7%;
Nano metal powder is a kind of in copper nanoparticle, nanometer copper nickel composite powder and the nanometer copper bismuth composite powder, the mean particle size≤80nm of nickel, bismuth wherein, and the mean particle size≤60nm of copper, wherein the proportioning of copper nickel is 8: 2, the proportioning of copper bismuth is 8: 2;
The nano metal powder dispersion agent is at least a kind of in Sodium hexametaphosphate 99, oleic acid, hard ester acid and the silane coupling agent.
2. nano metal self-restoring lubricating oil for mechanical sealing element according to claim 1 is characterized in that: dispersion medium is a machine oil.
3. the preparation method of the described nano metal self-restoring lubricating oil for mechanical sealing element of claim 1 is characterized in that: its step is,
1.. stir in earlier that proportioning is the required nano metal powder dispersion agent adding dispersion medium, further add Nano metal powder more according to the above ratio, agitation as appropriate to nano metal powder does not have obvious sediment;
2.. put into KH-700 type ultrasonic oscillator together with container and vibrated 20～30 minutes, power is 500～600W, gets product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007100208122A CN101250460B (en) | 2007-04-06 | 2007-04-06 | Nano metal self-restoring lubricating oil for mechanical sealing element and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2007100208122A CN101250460B (en) | 2007-04-06 | 2007-04-06 | Nano metal self-restoring lubricating oil for mechanical sealing element and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN101250460A CN101250460A (en) | 2008-08-27 |
| CN101250460B true CN101250460B (en) | 2010-12-22 |
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| CN2007100208122A Expired - Fee Related CN101250460B (en) | 2007-04-06 | 2007-04-06 | Nano metal self-restoring lubricating oil for mechanical sealing element and preparation method thereof |
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Families Citing this family (13)
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| CN101921655B (en) * | 2010-08-22 | 2012-12-26 | 广东三和化工科技有限公司 | Self-repairing environment-friendly diesel engine oil |
| CN105296054A (en) * | 2014-11-25 | 2016-02-03 | 重庆太鲁科技发展有限公司 | Antirust oil |
| CN105273801A (en) * | 2014-11-25 | 2016-01-27 | 重庆太鲁科技发展有限公司 | Lubricating oil having cleaning function |
| CN105296055A (en) * | 2014-11-25 | 2016-02-03 | 重庆太鲁科技发展有限公司 | Sealing paste |
| CN105623777A (en) * | 2016-01-12 | 2016-06-01 | 四川宣明节能环保科技有限公司 | Phosphorus-containing lubricating oil |
| CN109082328B (en) * | 2017-06-14 | 2021-08-10 | 英属开曼群岛商纳诺股份有限公司 | Engine oil composition and preparation method thereof |
| CN108559578A (en) * | 2018-04-04 | 2018-09-21 | 常熟理工学院 | A kind of lubricating oil preparation method of low sulfur content high-wearing feature |
| CN109022101A (en) * | 2018-07-09 | 2018-12-18 | 北方民族大学 | A kind of anti-attrition antiwear additive and its application in Reclaimed Base Oil |
| CN112899056A (en) * | 2019-12-03 | 2021-06-04 | 娄底市鼎宏自动化科技有限公司 | Lubricating oil for mining machinery |
| CN112480994B (en) * | 2020-12-01 | 2022-05-13 | 中铁工程装备集团有限公司 | Lubricating oil, preparation method and application |
| CN113845956B (en) * | 2021-11-10 | 2022-10-28 | 江苏智摩金属抗磨修复有限责任公司 | Wear-resistant self-repairing material for heavy-duty gear box and preparation method thereof |
| CN113862056B (en) * | 2021-11-10 | 2022-10-14 | 江苏智摩金属抗磨修复有限责任公司 | Wear-resistant self-repairing material for steam turbine bearing bush and preparation method thereof |
| CN114769612B (en) * | 2022-04-24 | 2024-04-12 | 河南大学 | Oil-soluble nickel nano-particles, in-situ synthesis method of oil-soluble nickel nano-particles in vegetable oil and application of oil-soluble nickel nano-particles as vegetable oil antiwear additive |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5523006A (en) * | 1995-01-17 | 1996-06-04 | Synmatix Corporation | Ultrafine powder lubricant |
| CN1190668A (en) * | 1998-02-23 | 1998-08-19 | 褚炎明 | Nm metal fine powder lubricating repairing agent |
| CN1380379A (en) * | 2002-05-31 | 2002-11-20 | 天津大学 | Repairing type lubricant additive and its preparation method |
| CN1858168A (en) * | 2005-05-08 | 2006-11-08 | 李远松 | Lipophilic nano copper powder lubricating repairing agent |
-
2007
- 2007-04-06 CN CN2007100208122A patent/CN101250460B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5523006A (en) * | 1995-01-17 | 1996-06-04 | Synmatix Corporation | Ultrafine powder lubricant |
| CN1190668A (en) * | 1998-02-23 | 1998-08-19 | 褚炎明 | Nm metal fine powder lubricating repairing agent |
| CN1380379A (en) * | 2002-05-31 | 2002-11-20 | 天津大学 | Repairing type lubricant additive and its preparation method |
| CN1858168A (en) * | 2005-05-08 | 2006-11-08 | 李远松 | Lipophilic nano copper powder lubricating repairing agent |
Non-Patent Citations (1)
| Title |
|---|
| 于鹤龙等.分散工艺对纳米铜颗粒摩擦学性能的影响.第六届全国表面工程学术会议.2006,850-853. * |
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Address after: 215300 Kunshan, Suzhou City, Yushan city town of Jade Road, No. 1 Patentee after: Miyou Group Co.,Ltd. Address before: 215316 Jiangsu Province, Kunshan City Road, No. 16 Patentee before: Kunshan MIyou Industrial Co., Ltd. |
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Application publication date: 20080827 Assignee: Jiangsu Zhong Zhong New Material Co., Ltd. Assignor: Miyou Group Co.,Ltd. Contract record no.: 2017320010012 Denomination of invention: Nano metal self-restoring lubricating oil for mechanical sealing element and preparation method thereof Granted publication date: 20101222 License type: Exclusive License Record date: 20170323 |
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