CN101228642A - Semiconductor light emitting device and fabrication method thereof - Google Patents

Semiconductor light emitting device and fabrication method thereof Download PDF

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Publication number
CN101228642A
CN101228642A CNA2006800266329A CN200680026632A CN101228642A CN 101228642 A CN101228642 A CN 101228642A CN A2006800266329 A CNA2006800266329 A CN A2006800266329A CN 200680026632 A CN200680026632 A CN 200680026632A CN 101228642 A CN101228642 A CN 101228642A
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semiconductor layer
light emitting
electrode
layer
forms
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CN101228642B (en
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崔镇植
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Suzhou Lekin Semiconductor Co Ltd
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LG Innotek Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/36Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the electrodes
    • H01L33/38Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the electrodes with a particular shape
    • H01L33/382Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the electrodes with a particular shape the electrode extending partially in or entirely through the semiconductor body
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/005Processes
    • H01L33/0093Wafer bonding; Removal of the growth substrate
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/02Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
    • H01L33/20Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a particular shape, e.g. curved or truncated substrate
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/48Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor body packages
    • H01L33/64Heat extraction or cooling elements
    • H01L33/642Heat extraction or cooling elements characterized by the shape

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
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Abstract

A semiconductor light emitting device includes a first semiconductor layer having a bottom surface with uneven patterns, an active layer formed on the first semiconductor layer, a second semiconductor layer formed on the active layer, a second electrode formed on the second semiconductor layer, and a first electrode formed under the first semiconductor layer.

Description

Light emitting semiconductor device and manufacture method thereof
Technical field
The present invention relates to light emitting semiconductor device and manufacture method thereof.
Background technology
Usually, light emitting semiconductor device for example light-emitting diode has stacked structure, wherein piles up n-type semiconductor layer, luminous zone and p-type semiconductor layer on substrate.On p-type semiconductor layer and n-type semiconductor layer, form electrode.When from semiconductor layer injected electrons and hole-recombination, produce light from the luminous zone.The light that produces from the luminous zone is launched from the light-permeable electrode on the p-type semiconductor layer or from substrate.At this, be the light-permeable electrode that forms by thin metal layer or transparency conducting layer at the almost whole lip-deep light-permeable electrode of p-type semiconductor layer.
The color (being wavelength) of the light that sends from light-emitting diode is determined according to the semi-conducting material that is used to make light-emitting diode.This be because wavelength of light emitted corresponding to the band gap of semi-conducting material, described band gap is defined as electronics in the valence band and the energy difference between the electronics in the conduction band.
Fig. 1 is the schematic diagram of the structure of demonstration prior art light emitting semiconductor device.
As shown in Figure 1, existing light emitting semiconductor device comprises substrate 11, resilient coating 12, n-type cover layer 13, active layer 14, p-type cover layer 15, p-type contact layer 16, p-type electrode 17 and n-type electrode 18.
Because the stacked structure of light emitting semiconductor device is controlled on the atomic level, therefore implement substrate processing so that the substrate with minute surface flatness to be provided.Thus, Stacket semiconductor layer 12,13 and 15, active layer 14 and electrode 17 and 18 in parallel with each other on substrate 11.
Semiconductor layer has big refractive index, and makes up waveguide (waveguide) by the surface of p-type cover layer 15 and the surface of substrate 11.Therefore, when on the surface of surface that light is incident on p-type electrode 17 with predetermined critical angle or bigger angle or substrate 11, incident light is by the interface between p-type electrode 17 and the p-type cover layer 15 or by the surface reflection of substrate 11, and the inside of propagating the stacked structure that passes through semiconductor layer in the horizontal direction.In such communication process, light is limited in the waveguide and possible loss.Therefore, can not obtain as many as expected external quantum efficiency.
Light emitting semiconductor device has as shown in Figure 2 been proposed, as eliminating above-mentioned defective and a kind of method of improving external quantum efficiency.Fig. 2 is the schematic diagram that shows different examples of prior art light emitting semiconductor device.
As shown in Figure 2, improved light emitting semiconductor device comprises substrate 21, resilient coating 22, n-type cover layer 23, active layer 24, p-type cover layer 25, p-type contact layer 26, p-type electrode 27 and n-type electrode 28.
With compare at the prior art light emitting semiconductor device shown in Fig. 1, the substrate 21 of improved light emitting semiconductor device has the top surface that has inhomogeneous pattern.On the uneven surface of substrate 21, form resilient coating 22, and pile up n-type cover layer 23 thereon.
In the light emitting semiconductor device with flat substrate shown in Figure 1, when light was propagated in semiconductor layer in the horizontal direction, a part of light was absorbed in semiconductor layer or the electrode, and this causes the decay of the light that comes out from semiconductor layer.
Comparatively speaking, at the improved light emitting semiconductor device shown in Fig. 2, the light of Chuan Boing is scattered or diffraction in the horizontal direction.Therefore, can help to improve external quantum efficiency from upper semiconductor layer 22,23,24 and 25 or launch light efficiently from base substrate 21.
Under the situation of the improved light emitting semiconductor device shown in Fig. 2, the charge carrier of injection moves on surface and interface, produces conductivity thus.The high driving voltage that applies in being used for luminous presumptive area allows a large amount of injection charge carriers (electronics) to flow.At this, electric current flows through the thin layer of the n-type cover layer 23 that is positioned under the n-type electrode 28.The position of current density concentrated area is near n-type electrode 28.
In this zone, current crowding has taken place, this makes current density higher relatively.When producing this zone that CURRENT DISTRIBUTION wherein concentrates, temperature sharply raises.Then, the heat drop of generation hangs down luminous efficiency, and therefore reduces the reliability of device in long-time running.
And the vicinity of two electrodes makes light emitting semiconductor device be easy to be subjected to the influence of static.Because substrate is a dielectric substrate, do not improve heat radiation even therefore on substrate, adhere to radiator (heat sink) yet.
Therefore, the light emitting semiconductor device that can improve external quantum efficiency and heat radiation is studied.
Summary of the invention
Technical problem
The invention provides light emitting semiconductor device and manufacture method thereof, it can improve external quantum efficiency and heat radiation.
Technical scheme
The invention provides a kind of light emitting semiconductor device.Described light emitting semiconductor device comprises first semiconductor layer with the basal surface that has inhomogeneous pattern; The active layer that on first semiconductor layer, forms; Second semiconductor layer that on active layer, forms; Second electrode that on second semiconductor layer, forms; With first electrode that below described first semiconductor layer, forms.
The invention provides a kind of method of making light emitting semiconductor device.Described method is included in and forms first semiconductor layer on the substrate; On described first semiconductor layer, form active layer; On described active layer, form second semiconductor layer; Remove described substrate; On described first semiconductor layer, form inhomogeneous pattern; With forming first electrode on described first semiconductor layer and on described second semiconductor layer, forming second electrode.
Advantageous effects
According to the present invention, can improve external quantum efficiency and heat radiation.
Description of drawings
Fig. 1 is the schematic diagram of an example of the structure of demonstration prior art light emitting semiconductor device;
Fig. 2 is the schematic diagram of another example of the structure of demonstration prior art light emitting semiconductor device.
Fig. 3 is for showing the schematic diagram according to the structure of light emitting semiconductor device of the present invention.
Fig. 4 to 11 is for showing the view according to the method for manufacturing light emitting semiconductor device of the present invention; With
Figure 12 is for showing the schematic diagram according to another structure of light emitting semiconductor device of the present invention.
Embodiment
Should understand, when substrate, layer (film), zone, pattern or structure are called as in another substrate, layer, zone, pad or pattern " on/above/top/top (on/above/over/upper) " or " down/below/below/bottom (down/below/under/lower) ", they can directly contact described other substrate, layer, zone, pad or pattern, or also can have intermediate layer, zone, pad, pattern or structure.Must understand this connotation based on technical concept of the present invention.
Now with reference to accompanying drawing in detail embodiment of the present invention are described in detail.
Fig. 3 is for showing the schematic diagram according to the structure of light emitting semiconductor device of the present invention.
As shown in Figure 3, light emitting semiconductor device according to the present invention comprises the n-type cover layer 33 with the basal surface that has inhomogeneous pattern, active layer 34 that forms on n-type cover layer 33 and the p-type cover layer 35 that forms on active layer 34.
Also can be included in p-type electrode 37 that forms on the p-type cover layer 35 and the n-type electrode 38 that forms for 33 times at n-type cover layer according to light emitting semiconductor device of the present invention.Also can between p-type cover layer 35 and p-type electrode 37, form p-type contact layer 36.
N-type cover layer 33 can be that n-GaN cover layer and p-type cover layer 35 can be the p-GaN cover layers.Active layer 34 can have single quantum or multi-quantum pit structure.
Can be at regular intervals or different intervals form the inhomogeneous pattern of n-type cover layer 33.Can on the whole uneven surface of n-type cover layer 33, form n-type electrode 38.
Light emitting semiconductor device with this stacked structure according to the present invention has vertical stratification, and n-type electrode 38 and p-type electrode 37 are respectively formed at the bottom and the top of device in this structure.Therefore, can prevent near the concentrated problem of the current density n-type electrode of prior art planar structure.
That is, in light emitting semiconductor device according to the present invention, p-type electrode 37 and n-type electrode 38 are in the upper and lower stacked in parallel.Therefore, current density is not concentrated in the specific region, but can evenly distribute on corresponding to the whole zone of n-type electrode 38.By this form, prevent specific part generation current crowding at n-type electrode 38, prevent from thus sharply to raise in the temperature at place, described specific region.
And, owing to be set to have enough distances betwixt according to two electrodes in the light emitting semiconductor device of the present invention, so device has anlistatig performance.Also can improve the heat radiation of light emitting semiconductor device by for example on device, adhering to radiator.
In addition, in light emitting semiconductor device according to the present invention, the light of Chuan Boing is scattered or diffraction in the zone of the inhomogeneous pattern that is formed with n-type cover layer 33 in the horizontal direction.Therefore, can improve external quantum efficiency greatly.
Afterwards, describe according to the manufacture method with light emitting semiconductor device of this structure of the present invention with reference to Fig. 4 to 11.Fig. 4 to 11 is for showing the view according to the method for manufacturing light emitting semiconductor device of the present invention.
In the method for manufacturing light emitting semiconductor device according to the present invention, as shown in Figure 4, on substrate 31, pile up resilient coating 32, n-type cover layer 33, active layer 34 and p-type cover layer 35.Can not comprise resilient coating 32, but form resilient coating 32 as a kind of method of improving the semiconductor layer characteristic.N-type cover layer 33 can be that n-GaN cover layer and p-type cover layer 35 can be the p-GaN cover layers.
Then, as shown in Figure 5, remove substrate 31 from resulting structures.Available laser-stripping method separation is also removed described substrate 31.In laser-stripping method, can use excimer laser to separate and to remove substrate 31.
Shown in Fig. 6 and 7, remove resilient coating 32 to expose n-type cover layer 33.Can implement chemico-mechanical polishing or be etched with to remove resilient coating 32 and expose n-type cover layer 33.
As shown in Figure 8, on n-type cover layer 33, form photoresist layer 41 and implement patterning then thereon.Then, the photoresist layer 41 of etched patternization is to form inhomogeneous pattern 43 in n-type cover layer 33.Can be at regular intervals or different intervals form the inhomogeneous pattern 43 of n-type cover layer 33.
Then, remove photoresist layer 41.As shown in figure 10, be formed with therein and form n-type electrode 38 on the n-type cover layer 33 of inhomogeneous pattern, on p-type cover layer 35, form p-type electrode 37.N-type electrode 38 can be formed on the whole surface of n-type cover layer 33, and p-type electrode 37 can be formed on the whole surface of p-type cover layer 35.One in n-type electrode 38 that preferably forms on whole surface and the p-type electrode 37 forms transparency electrode.As shown in Figure 3, can between p-type cover layer 35 and p-type electrode 37, further form p-type contact layer 36.
As shown in figure 11, former stating in the light emitting semiconductor device that mode makes, the light of Chuan Boing is formed with therein in the zone of n-type cover layer 33 of inhomogeneous pattern 43 and is scattered or diffraction in the horizontal direction.Therefore, can improve external quantum efficiency to a great extent according to light emitting semiconductor device of the present invention.
And in the light emitting semiconductor device according to the present invention, p-type electrode 37 and n-type electrode 38 stacked in parallel are portion and bottom thereon.Therefore, current density is not concentrated in the specific region, but evenly distributes on corresponding to the whole zone of n-type electrode 38.Therefore, prevent from current crowding to take place, thereby the temperature that prevents this specific region sharply raises in the particular portion office of n-type electrode 38.
And, owing to be set to have enough distances betwixt according to two electrodes in the light emitting semiconductor device of the present invention, so device can be antistatic.Also can improve the heat dispersion of light emitting semiconductor device by the method for on device, adhering to radiator etc.
Though in the present embodiment, described and removed resilient coating 32, can not exclusively remove resilient coating 32 to expose the situation of n-type cover layer 33.That is, as shown in figure 12, can all form inhomogeneous pattern in the two at resilient coating 42 and n-type cover layer 33 by etching, and can form n-type electrode 38 thereon.Resilient coating 32 can be formed by electric conducting material.Figure 12 is for showing the schematic diagram according to another structure of light emitting semiconductor device of the present invention.
In the present embodiment, in n-type cover layer 35, form inhomogeneous pattern, be formed with formation n-type electrode 38 on the surface of inhomogeneous pattern.Yet, the invention is not restricted to this, this inhomogeneous pattern can form in p-type cover layer 35.
In the present embodiment, the light emitting semiconductor device of p-n junction structure has been described as an example, wherein form the n-N-type semiconductor N at top formation p-N-type semiconductor N and in the bottom.Yet light emitting semiconductor device can have the n-p-n junction structure that wherein further forms the n-type semiconductor layer on the p-type semiconductor layer.The n-p-n junction structure means that first electrode layer and the second electrode lay all form the n-type semiconductor layer, and forms the p-type semiconductor layer betwixt.On first electrode layer, n-type semiconductor layer, form first electrode, on the second electrode lay, n-type semiconductor layer, form second electrode.
Commercial Application
According to light emitting semiconductor device and manufacture method thereof, can improve external quantum efficiency and heat radiation.

Claims (21)

1. light emitting semiconductor device comprises:
Have first semiconductor layer of basal surface, described basal surface has inhomogeneous pattern;
The active layer that on described first semiconductor layer, forms;
Second semiconductor layer that on described active layer, forms;
Second electrode that on described second semiconductor layer, forms; With
First electrode that under described first semiconductor layer, forms.
2. light emitting semiconductor device according to claim 1, wherein said first semiconductor layer are that n-type semiconductor layer and described second semiconductor layer are the p-type semiconductor layer.
3. light emitting semiconductor device according to claim 1 wherein forms the described inhomogeneous pattern of described first semiconductor layer at regular intervals.
4. light emitting semiconductor device according to claim 1 wherein forms the described inhomogeneous pattern of described first semiconductor layer with different intervals.
5. light emitting semiconductor device according to claim 1, wherein described at least first electrode is formed on the whole surface of described first semiconductor layer, or described at least second electrode is formed on the whole surface of described second semiconductor layer.
6. light emitting semiconductor device according to claim 1, at least one in wherein said first electrode and second electrode is transparency electrode.
7. light emitting semiconductor device according to claim 1 also is included in the 3rd semiconductor layer that forms between described second semiconductor layer and described second electrode.
8. light emitting semiconductor device according to claim 7, wherein said first semiconductor layer and the 3rd semiconductor layer are that n-type semiconductor layer and described second semiconductor layer are the p-type semiconductor layer.
9. light emitting semiconductor device according to claim 1 also is included in the resilient coating that forms between the bossing of described inhomogeneous pattern of described first semiconductor layer and described first electrode.
10. method of making light emitting semiconductor device, described method comprises:
On substrate, form first semiconductor layer;
On described first semiconductor layer, form active layer;
On described active layer, form second semiconductor layer;
Remove described substrate;
On described first semiconductor layer, form inhomogeneous pattern; With
Form first electrode on described first semiconductor layer and on described second semiconductor layer, forming second electrode.
11. method according to claim 10, wherein said first semiconductor layer are that n-type semiconductor layer and described second semiconductor layer are the p-type semiconductor layer.
12. method according to claim 10 wherein forms the described inhomogeneous pattern of described first semiconductor layer at regular intervals.
13. method according to claim 10 wherein forms the described inhomogeneous pattern of described first semiconductor layer with different intervals.
14. method according to claim 10, wherein described at least first electrode is formed on the whole surface of described first semiconductor layer, or described at least second electrode is formed on the whole surface of described second semiconductor layer.
15. method according to claim 10 is wherein removed described substrate and is comprised and utilize laser-stripping method to separate and remove described substrate.
16. method according to claim 15, wherein said laser-stripping method utilizes excimer laser.
17. method according to claim 10 wherein forms described inhomogeneous pattern and comprises in described first semiconductor layer:
On described first semiconductor layer, form photoresist layer and the described photoresist layer of patterning;
Implementing to be etched with the inhomogeneous pattern of formation in described first semiconductor layer on the photoresist layer of described patterning; With
Remove described photoresist layer.
18. method according to claim 10 also is included on the described substrate and forms before first semiconductor layer, forms resilient coating on described substrate.
19. method according to claim 18 also is included in and removes after the described substrate, removes described resilient coating to expose described first semiconductor layer.
20. method according to claim 19 is wherein removed described resilient coating and is comprised and utilize a kind of in chemico-mechanical polishing and the etching to remove described resilient coating.
21. method according to claim 18, also be included in and remove after the described substrate, described resilient coating of etching and described first semiconductor layer to be to form inhomogeneous pattern in described first semiconductor layer, wherein form described resilient coating on the bossing of the described inhomogeneous pattern of described first semiconductor layer.
CN2006800266329A 2005-07-25 2006-07-25 Semiconductor light emitting device and fabrication method thereof Active CN101228642B (en)

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PCT/KR2006/002916 WO2007013757A1 (en) 2005-07-25 2006-07-25 Semiconductor light emitting device and fabrication method thereof

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CN102185070A (en) * 2011-05-06 2011-09-14 西安神光安瑞光电科技有限公司 Light emitting diode and preparation method thereof

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KR20070012930A (en) 2007-01-30
US9147797B2 (en) 2015-09-29
WO2007013757A1 (en) 2007-02-01
CN102569560B (en) 2015-02-25
US20080217638A1 (en) 2008-09-11
CN102569560A (en) 2012-07-11
US8742429B2 (en) 2014-06-03
CN101228642B (en) 2012-03-21
US20110001164A1 (en) 2011-01-06

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